JP2015185278A - Rolled body of battery packaging material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a rolled body of a battery packaging material, appropriately controlled in defects causing the generation of pin holes, a method for producing the rolled body, and a method for inspecting defects of a battery packaging material.SOLUTION: A rolled body of a battery packaging material comprises a laminated film in which at least a base material layer 1, an adhesive layer 2, a metal layer 3, and a sealant layer 4 are laminated in the order. Foreign matters 7 having an area of 0.4 mmor more when viewed from the laminated direction of the laminated film are present in an interface portion of at least two layers included in the laminated film, and a mark is placed on the laminated film so that the position of the foreign matters can be recognized.

Description

  The present invention relates to a winding body for a battery packaging material, a method for manufacturing the winding body, and a defect inspection method for a battery packaging material.

  Conventionally, various types of batteries have been developed. In these batteries, a battery element composed of an electrode, an electrolyte and the like needs to be sealed with a packaging material or the like. Metal packaging materials are frequently used as battery packaging materials.

  In recent years, as electric vehicles, hybrid electric vehicles, personal computers, cameras, mobile phones, and the like have improved performance, batteries having various shapes have been demanded. The battery is also required to be thin and light. However, it is difficult to follow the diversification of battery shapes with metal packaging materials that have been widely used in the past. Further, since it is made of metal, there is a limit to reducing the weight of the packaging material.

  Therefore, a film-like laminated film in which a base material layer / metal layer / sealant layer are sequentially laminated has been proposed as a battery packaging material that can be easily processed into various shapes and can be reduced in thickness and weight. .

  For example, Patent Document 1 discloses a battery case including a biaxially stretched polyamide film layer as an outer layer, an unstretched thermoplastic resin film layer as an inner layer, and an aluminum foil layer disposed between the two film layers. A packaging material is disclosed.

  Such a battery packaging material is generally produced as a strip-shaped laminated film in a production line, and is stored, transported, etc. as a wound body wound up in a roll shape. And at the time of manufacture of a battery, the packaging material for batteries is unwound from a winding body, and it cuts and uses it so that it may become a predetermined shape according to the product specification of a battery.

JP 2008-287971 A

  Battery packaging materials are generally molded and used in order to enclose battery elements such as electrolytes and electrodes. However, at the time of molding, pinholes may occur in the stretched portion of the battery packaging material, and the insulation of the battery packaging material may be reduced. When a battery is manufactured using such a battery packaging material that generates a pinhole, the pinhole is found only when the battery packaging material is formed in the battery manufacturing process. For this reason, when the packaging material for a battery is cut out from a wound body of the packaging material for a battery whose defects causing the pinhole are not managed and used for the production of the battery, the yield of the battery production may be reduced. is there.

  The present invention has been made in view of such problems. That is, the present invention provides a winding body for a battery packaging material in which defects that cause pinholes are suitably managed, a method for manufacturing the winding body, and a method for inspecting defects in the battery packaging material. The main purpose.

The present inventor has intensively studied to solve the above problems. As a result, the following knowledge was obtained. That is, the battery packaging material is manufactured as a laminated film by laminating the layers constituting the battery packaging material. In such a manufacturing process, when laminating each layer of the laminated film, the foreign matter adhering to the device or the foreign matter scattered in the air falls on the layer in the laminating step, and the adjacent layer as it is. By being laminated, a foreign substance may be contained in the interface portion of the layer contained in the laminated film. In addition, foreign matters may adhere to the resin film, metal foil, and the like that are provided for lamination, which may be laminated as they are. Such foreign matter is, for example, dust or a metal piece. When a battery packaging material in which such foreign matter is present at the interface portion of the layer of the laminated film is molded, the portion where the foreign matter is present and other portions are formed. It has become clear that pinholes are likely to occur in areas where foreign matter exists due to differences in elongation. And when the inventor further examined, a foreign matter having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is particularly likely to cause pinholes due to molding, and is smaller than this. It became clear that it would be difficult to cause pinholes.

And this inventor is the winding body of the packaging material for batteries which consists of a laminated | multilayer film by which the base material layer, the contact bonding layer, the metal layer, and the sealant layer were laminated | stacked in this order at least, Comprising: In the case of the following (1) or (2), there is a foreign substance having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film at the interface part of at least two layers included Found that defects that cause pinholes can be properly managed. The present invention has been completed by further studies based on these findings.
(1) When the number of the above-mentioned foreign matters having an area of 0.4 mm ² or more is 1 or less per 100 m length of a laminated film having a width of 80 to 600 mm.
(2) When a mark is given to the laminated film so that the position of the foreign matter having an area of 0.4 mm ² or more can be recognized.

That is, this invention provides the invention of the aspect hung up below.
Item 1. At least a wound body of a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
In the interface portion of at least two layers included in the laminated film, there are foreign matters having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film,
A wound body of a battery packaging material in which a mark is given to the laminated film so that the position of the foreign matter can be recognized.
Item 2. The foreign matter is present at least at an interface portion between the base material layer and the adhesive layer, an interface portion between the adhesive layer and the metal layer, or an interface portion between the metal layer and the sealant layer. 1. A wound body of the battery packaging material according to 1.
Item 3. Item 3. The wound packaging material for battery according to Item 1 or 2, wherein the sealant layer is formed of a plurality of layers, and the foreign matter is present at an interface portion between the metal layer and the sealant layer.
Item 4. The laminated film has a coating layer on the side opposite to the adhesive layer of the base material layer,
Item 4. The wound body of the battery packaging material according to any one of Items 1 to 3, wherein the foreign matter is present at an interface portion between the coating layer and the base material layer.
Item 5. Item 5. The wound body for battery packaging material according to any one of Items 1 to 4, wherein the wound body is a roll having a length of the laminated film of 200 m or more and a diameter of a circular cross section of 150 mm or more.
Item 6. A method for producing a wound body of a battery packaging material according to any one of Items 1 to 5,
After obtaining a laminated film by a laminating step of laminating a base material layer, an adhesive layer, a metal layer, and a sealant layer,
The foreign matter contained in the interface part of at least two layers contained in the laminated film, the area when viewed from the lamination direction of the laminated film can recognize the position of the foreign matter of 0.4 mm ² or more, A mark applying step for applying a mark to the laminated film;
Winding the laminated film to obtain a wound body; and
The manufacturing method of the winding body of the packaging material for batteries provided with this.
Item 7. At least a wound body of a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
At the interface part of at least two layers included in the laminated film, the number of foreign matters having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is the length of the laminated film having a width of 80 to 600 mm. The winding body of the packaging material for batteries which is 1 or less per 100 m.
Item 8. The foreign matter is present at least at an interface portion between the base material layer and the adhesive layer, an interface portion between the adhesive layer and the metal layer, or an interface portion between the metal layer and the sealant layer. 8. A wound body of the battery packaging material according to 7.
Item 9. Item 9. The battery packaging material roll according to Item 7 or 8, wherein the sealant layer is formed of a plurality of layers, and the foreign matter is present at an interface portion between the metal layer and the sealant layer.
Item 10. The laminated film has a coating layer on the side opposite to the adhesive layer of the base material layer,
Item 10. The wound body for battery packaging material according to any one of Items 7 to 9, wherein the foreign matter is present at an interface portion between the coating layer and the base material layer.
Item 11. Item 11. The wound body for battery packaging material according to any one of Items 7 to 10, wherein the wound body has a roll shape in which the length of the laminated film is 200 m or more and the diameter of a circular cross section is 150 mm or more.
Item 12. It is a manufacturing method of the winding body of the packaging material for batteries in any one of claim | item 7-11,
After obtaining a laminated film by a laminating step of laminating a base material layer, an adhesive layer, a metal layer, and a sealant layer,
The foreign matter contained in the interface portion of at least two layers contained in the laminated film, the portion when the foreign matter having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is removed, A foreign matter removing step in which the number of foreign matters having an area of 0.4 mm ² or more is 1 or less per 100 m in length of the laminated film having a width of 80 to 600 mm;
Winding the laminated film to obtain a wound body; and
The manufacturing method of the winding body of the packaging material for batteries provided with this.
Item 13. Item 13. The battery packaging according to item 12, further comprising a mark applying step of applying a mark to the laminated film so that the position of the foreign material having the area of the laminated film of 0.4 mm ² or more can be recognized in the foreign matter removing step. A method of manufacturing a wound body of material.
Item 14. At least a defect inspection method for a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
The surface of the laminated film is imaged, and the position information of foreign matters having an area of 0.4 mm ² or more when viewed from the laminating direction of the laminated film is present at an interface portion of at least two layers included in the laminated film. Recording process;
In accordance with the position information, a mark applying step for applying a mark to the laminated film so that the position of the foreign matter having an area of 0.4 mm ² or more can be recognized;
A defect inspection method for battery packaging materials.

  ADVANTAGE OF THE INVENTION According to this invention, the winding body of the packaging material for batteries by which the defect which causes pinhole generation was managed appropriately can be provided. Therefore, it is preferable that a battery having a pinhole is manufactured by cutting out the battery packaging material from the wound body of the battery packaging material of the present invention, molding the battery packaging material, and sealing the battery element. The yield of battery manufacturing can be improved.

It is a schematic sectional drawing of an example of the laminated film which comprises the winding body of the packaging material for batteries which concerns on this invention. It is a schematic sectional drawing of an example of the laminated film which comprises the winding body of the packaging material for batteries which concerns on this invention.

1. Winding body of first battery packaging material Winding body of the first battery packaging material of the present invention (hereinafter simply referred to as “first winding body”) is at least a base material A wound body of a battery packaging material comprising a laminated film in which a layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order, at an interface portion of at least two layers included in the laminated film, The number of foreign matters having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is 1 or less per 100 m of a laminated film having a width of 80 to 600 mm. Hereinafter, the winding body of the 1st packaging material for batteries of this invention is explained in full detail, referring FIG.1 and FIG.2.

1-1. The laminated structure of the battery packaging material constituting the first winding body The battery packaging material constituting the first winding body of the present invention is, for example, as shown in FIG. The adhesive layer 2, the metal layer 3, and the sealant layer 4 are formed of a laminated film in which the adhesive layer 2, the metal layer 3, and the sealant layer 4 are laminated in this order. As will be described later, the first winding body is obtained by winding the battery packaging material into a roll. The first wound body may be wound so that the sealant layer 4 of the battery packaging material is inside, or wound so that the base material layer 1 is inside. There may be.

  The battery packaging material only needs to include at least the base material layer 1, the adhesive layer 2, the metal layer 3, and the sealant layer 4, and may further include other layers. For example, as shown in FIGS. 1 and 2, the battery packaging material may have a coating layer 6 on the opposite side of the base material layer 1 from the adhesive layer 2 as necessary. In addition, as shown in FIG. 2, an adhesive layer 5 may be provided between the metal layer 3 and the sealant layer 4 as necessary for the purpose of improving these adhesive properties.

  In the battery packaging material, the base material layer 1 or the coating layer 6 is the outermost layer, and the sealant layer 4 is the innermost layer. That is, when the battery is assembled, the battery element is wrapped with the battery packaging material so that the sealant layer 4 of the battery packaging material is on the inside of the battery, and the sealant layers 4 positioned at the periphery of the battery element are heat-welded. The battery element is sealed by sealing the battery element.

1-2. Configuration of each layer of battery packaging material constituting first winding body [base material layer 1]
In the battery packaging material, the base material layer 1 is a layer serving as a base material for the battery packaging material. About the raw material which forms the base material layer 1, it does not restrict | limit especially as long as it is provided with insulation. Examples of the material for forming the base material layer 1 include polyester, polyamide, epoxy, acrylic, fluororesin, polyurethane, silicon resin, phenol, polyetherimide, polyimide, and a mixture or copolymer thereof.

  Specific examples of the polyester include polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene isophthalate, polycarbonate, copolymerized polyester mainly composed of ethylene terephthalate, butylene terephthalate as a repeating unit. Examples thereof include a copolymer polyester mainly used. The copolymer polyester mainly composed of ethylene terephthalate is a copolymer polyester that polymerizes with ethylene isophthalate mainly composed of ethylene terephthalate (hereinafter, polyethylene (terephthalate / isophthalate)). Abbreviated), polyethylene (terephthalate / isophthalate), polyethylene (terephthalate / adipate), polyethylene (terephthalate / sodium sulfoisophthalate), polyethylene (terephthalate / sodium isophthalate), polyethylene (terephthalate / phenyl-dicarboxylate) And polyethylene (terephthalate / decanedicarboxylate). In addition, as a copolymer polyester mainly composed of butylene terephthalate as a repeating unit, specifically, a copolymer polyester that polymerizes with butylene isophthalate having butylene terephthalate as a repeating unit (hereinafter referred to as polybutylene (terephthalate / isophthalate)). For example), polybutylene (terephthalate / adipate), polybutylene (terephthalate / sebacate), polybutylene (terephthalate / decanedicarboxylate), polybutylene naphthalate and the like. These polyesters may be used individually by 1 type, and may be used in combination of 2 or more type. Polyester has the advantage of being excellent in electrolytic solution resistance and less likely to cause whitening due to the adhesion of the electrolytic solution, and is suitably used as a material for forming the base material layer 1.

  Specific examples of polyamides include aliphatic polyamides such as nylon 6, nylon 66, nylon 610, nylon 12, nylon 46, and copolymers of nylon 6 and nylon 6,6; terephthalic acid and / or Nylon 6I, Nylon 6T, Nylon 6IT, Nylon 6I6T (I represents isophthalic acid, T represents terephthalic acid) and the like, which include a structural unit derived from isophthalic acid, Aromatic polyamides such as silylene adipamide (MXD6); alicyclic polyamides such as polyaminomethylcyclohexyl adipamide (PACM6); and lactam components and isocyanate components such as 4,4′-diphenylmethane-diisocyanate. Polymerized polyamide, co-weight Polyester amide copolymer and polyether ester amide copolymer is a copolymer of polyamide and polyester and polyalkylene ether glycol; copolymers thereof, and the like. These polyamides may be used individually by 1 type, and may be used in combination of 2 or more type. The stretched polyamide film is excellent in stretchability, can prevent whitening due to resin cracking of the base material layer 1 during molding, and is suitably used as a material for forming the base material layer 1.

  The base material layer 1 may be formed of a uniaxially or biaxially stretched resin film, or may be formed of an unstretched resin film. Among them, a uniaxially or biaxially stretched resin film, in particular, a biaxially stretched resin film has improved heat resistance by orientation crystallization, and thus is suitably used as the base material layer 1.

  Among these, as a resin film which forms the base material layer 1, Preferably nylon and polyester, More preferably, biaxially stretched nylon, biaxially stretched polyester, Most preferably, biaxially stretched nylon is mentioned.

  The base material layer 1 can also be laminated with resin films of different materials in order to improve pinhole resistance and insulation when used as a battery package. Specific examples include a multilayer structure in which a polyester film and a nylon film are laminated, and a multilayer structure in which a biaxially stretched polyester and a biaxially stretched nylon are laminated. When making the base material layer 1 into a multilayer structure, each resin film may be adhere | attached through an adhesive agent, and may be laminated | stacked directly without an adhesive agent. In the case of bonding without using an adhesive, for example, a method of bonding in a hot melt state such as a co-extrusion method, a sand lamination method, or a thermal laminating method can be mentioned. Moreover, when making it adhere | attach through an adhesive agent, the adhesive agent to be used may be a two-component curable adhesive, or a one-component curable adhesive. Further, the bonding mechanism of the adhesive is not particularly limited, and may be any of a chemical reaction type, a solvent volatilization type, a heat melting type, a hot pressure type, an electron beam curing type such as UV and EB, and the like. As an adhesive component, polyester resin, polyether resin, polyurethane resin, epoxy resin, phenol resin resin, polyamide resin, polyolefin resin, polyvinyl acetate resin, cellulose resin, (meth) acrylic resin Resins, polyimide resins, amino resins, rubbers, and silicon resins can be used.

  Although the thickness in particular of the base material layer 1 is not restrict | limited, For example, about 5 micrometers-50 micrometers, Preferably it can be set as about 12 micrometers-30 micrometers.

[Coating layer 6]
In the battery packaging material, the coating layer 6 provided as necessary is a layer located on the outer side (outermost layer) of the base material layer 1 when the battery is assembled. In the present invention, the coating layer 6 is formed of, for example, a two-component curable resin for the purpose of mainly imparting an electrolytic solution resistance to the battery packaging material. The two-part curable resin for forming the coating layer 6 is not particularly limited as long as it has an electrolytic solution resistance. For example, the two-part curable urethane resin, the two-part curable polyester resin, and the two-part curable type An epoxy resin etc. are mentioned. The coating layer 6 may contain a matting agent.

  Examples of the matting agent include fine particles having a particle size of about 0.5 nm to 5 μm. The material of the matting agent is not particularly limited, and examples thereof include metals, metal oxides, inorganic substances, and organic substances. The shape of the matting agent is not particularly limited, and examples thereof include a spherical shape, a fiber shape, a plate shape, an indeterminate shape, and a balloon shape. Specific examples of the matting agent include talc, silica, graphite, kaolin, montmorilloid, montmorillonite, synthetic mica, hydrotalcite, silica gel, zeolite, aluminum hydroxide, magnesium hydroxide, zinc oxide, magnesium oxide, and aluminum oxide. , Neodymium oxide, antimony oxide, titanium oxide, cerium oxide, calcium sulfate, barium sulfate, calcium carbonate, calcium silicate, lithium carbonate, calcium benzoate, calcium oxalate, magnesium stearate, alumina, carbon black, carbon nanotubes, High melting point nylon, crosslinked acrylic, crosslinked styrene, crosslinked polyethylene, benzoguanamine, gold, aluminum, copper, nickel and the like can be mentioned. These matting agents may be used individually by 1 type, and may be used in combination of 2 or more type. Among these matting agents, silica, barium sulfate, and titanium oxide are preferable from the viewpoint of dispersion stability and cost. The matting agent may be subjected to various surface treatments such as insulation treatment and high dispersibility treatment on the surface.

  The method for forming the coating layer 6 is not particularly limited, and examples thereof include a method of applying a two-component curable resin for forming the coating layer 6 on one surface of the base material layer 1. When the matting agent is blended, the matting agent may be added to the two-component curable resin, mixed, and then applied.

  The coating layer 6 is preferably formed thin enough to exhibit resistance to an electrolytic solution, and the thickness is preferably 5 μm or less, more preferably 3 μm or less. From the viewpoint of resistance to electrolytic solution, the lower limit of the thickness of the coating layer 6 is usually about 2 μm.

[Adhesive layer 2]
In the battery packaging material, the adhesive layer 2 is a layer provided for the purpose of increasing the adhesive strength between the base material layer 1 and the metal layer 3.

  The adhesive layer 2 is formed of an adhesive capable of adhering the base material layer 1 and the metal layer 3. The adhesive used for forming the adhesive layer 2 may be a two-component curable adhesive or a one-component curable adhesive. Furthermore, the adhesive mechanism of the adhesive used for forming the adhesive layer 2 is not particularly limited, and may be any of a chemical reaction type, a solvent volatilization type, a heat melting type, a hot pressure type, and the like.

  Specific examples of the resin component of the adhesive that can be used to form the adhesive layer 2 include polyesters such as polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene isophthalate, polycarbonate, and copolyester. Resin; Polyether adhesive; Polyurethane adhesive; Epoxy resin; Phenol resin resin; Polyamide resin such as nylon 6, nylon 66, nylon 12, copolymer polyamide; polyolefin, acid-modified polyolefin, metal-modified polyolefin, etc. Polyolefin resin; polyvinyl acetate resin; cellulose adhesive; (meth) acrylic resin; polyimide resin; urea resin, melamine resin and other amino resins; chloroprene rubber, nitrile rubber, styrene - rubbers such as butadiene rubber, silicone resin; fluorinated ethylene propylene copolymer, and the like. These adhesive components may be used individually by 1 type, and may be used in combination of 2 or more type. The combination mode of two or more kinds of adhesive components is not particularly limited. For example, as the adhesive component, a mixed resin of polyamide and acid-modified polyolefin, a mixed resin of polyamide and metal-modified polyolefin, polyamide and polyester, Examples thereof include a mixed resin of polyester and acid-modified polyolefin, and a mixed resin of polyester and metal-modified polyolefin. Among these, extensibility, durability under high-humidity conditions, anti-hypertensive action, thermal deterioration-preventing action during heat sealing, etc. are excellent, and a decrease in lamination strength between the base material layer 1 and the metal layer 3 is suppressed. From the viewpoint of effectively suppressing the occurrence of delamination, a polyurethane two-component curable adhesive; polyamide, polyester, or a blended resin of these with a modified polyolefin is preferable.

  The adhesive layer 2 may be multilayered with different adhesive components. When the adhesive layer 2 is multilayered with different adhesive components, from the viewpoint of improving the lamination strength between the base material layer 1 and the metal layer 3, the adhesive component disposed on the base material layer 1 side is used as the base material layer 1. It is preferable to select a resin having excellent adhesion to the metal layer 3 and to select an adhesive component having excellent adhesion to the metal layer 3 as the adhesive component disposed on the metal layer 3 side. When the adhesive layer 2 is multilayered with different adhesive components, specifically, the adhesive component disposed on the metal layer 3 side is preferably an acid-modified polyolefin, a metal-modified polyolefin, a polyester and an acid-modified polyolefin. And a resin containing a copolyester.

  About the thickness of the contact bonding layer 2, 2-50 micrometers, for example, Preferably 3-25 micrometers is mentioned.

[Metal layer 3]
In the battery packaging material, the metal layer 3 is a layer that functions as a barrier layer for preventing moisture, oxygen, light, and the like from entering the battery, in addition to improving the strength of the battery packaging material. Specific examples of the metal constituting the metal layer 3 include aluminum, stainless steel, and titanium, and preferably aluminum. The metal layer 3 can be formed by metal foil or metal vapor deposition, preferably by metal foil, and more preferably by aluminum foil. From the viewpoint of preventing generation of wrinkles and pinholes in the metal layer 3 during the production of the battery packaging material, for example, by using a soft aluminum foil such as annealed aluminum (JIS A8021P-O, JIS A8079P-O). More preferably, it is formed.

  Although the thickness in particular of the metal layer 3 is not restrict | limited, For example, about 10 micrometers-200 micrometers, Preferably it can be set as about 20 micrometers-100 micrometers.

  The metal layer 3 is preferably subjected to chemical conversion treatment on at least one surface, preferably both surfaces, for the purpose of stabilizing adhesion, preventing dissolution and corrosion, and the like. Here, the chemical conversion treatment refers to a treatment for forming an acid-resistant film on the surface of the metal layer. As the chemical conversion treatment, for example, chromate chromate using chromic acid compounds such as chromium nitrate, chromium fluoride, chromium sulfate, chromium acetate, chromium oxalate, chromium biphosphate, chromic acetyl acetate, chromium chloride, potassium sulfate chromium, etc. Treatment; Phosphoric acid chromate treatment using a phosphoric acid compound such as sodium phosphate, potassium phosphate, ammonium phosphate, polyphosphoric acid; aminated phenol having a repeating unit represented by the following general formulas (1) to (4) Examples include chromate treatment using a polymer.

In general formulas (1) to (4), X represents a hydrogen atom, a hydroxyl group, an alkyl group, a hydroxyalkyl group, an allyl group or a benzyl group. R ¹ and R ² are the same or different and each represents a hydroxyl group, an alkyl group, or a hydroxyalkyl group. In the general formulas (1) to (4), examples of the alkyl group represented by X, R ¹ and R ² include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, C1-C4 linear or branched alkyl groups, such as a tert- butyl group, are mentioned. Examples of the hydroxyalkyl group represented by X, R ¹ and R ² include a hydroxymethyl group, a 1-hydroxyethyl group, a 2-hydroxyethyl group, a 1-hydroxypropyl group, a 2-hydroxypropyl group, 3- C1-C4 straight or branched chain in which one hydroxy group such as hydroxypropyl group, 1-hydroxybutyl group, 2-hydroxybutyl group, 3-hydroxybutyl group, 4-hydroxybutyl group is substituted An alkyl group is mentioned. In the general formulas (1) to (4), the alkyl group and hydroxyalkyl group represented by X, R ¹ and R ² may be the same or different. In the general formulas (1) to (4), X is preferably a hydrogen atom, a hydroxyl group or a hydroxyalkyl group. The number average molecular weight of the aminated phenol polymer having the repeating units represented by the general formulas (1) to (4) is preferably, for example, 500 to 1,000,000, more preferably about 1,000 to 20,000. preferable.

  In addition, as a chemical conversion treatment method for imparting corrosion resistance to the metal layer 3, a metal oxide such as aluminum oxide, titanium oxide, cerium oxide, tin oxide, or barium sulfate fine particles dispersed in phosphoric acid is coated. A method of forming a corrosion-resistant treatment layer on the surface of the metal layer 3 by performing a baking treatment at 150 ° C. or higher can be mentioned. Further, a resin layer obtained by crosslinking a cationic polymer with a crosslinking agent may be further formed on the corrosion-resistant treatment layer. Here, examples of the cationic polymer include polyethyleneimine, an ionic polymer complex composed of a polymer having polyethyleneimine and a carboxylic acid, a primary amine graft acrylic resin obtained by graft polymerization of a primary amine on an acrylic main skeleton, and polyallylamine. Or the derivative, aminophenol, etc. are mentioned. As these cationic polymers, only one type may be used, or two or more types may be used in combination. Examples of the crosslinking agent include a compound having at least one functional group selected from the group consisting of an isocyanate group, a glycidyl group, a carboxyl group, and an oxazoline group, and a silane coupling agent. As these crosslinking agents, only one type may be used, or two or more types may be used in combination.

  As the chemical conversion treatment, only one type of chemical conversion treatment may be performed, or two or more types of chemical conversion treatment may be performed in combination. Furthermore, these chemical conversion treatments may be carried out using one kind of compound alone, or may be carried out using a combination of two or more kinds of compounds. Among the chemical conversion treatments, chromic acid chromate treatment, chromate treatment combining a chromic acid compound, a phosphoric acid compound, and an aminated phenol polymer are preferable.

The amount of the acid-resistant film formed on the surface of the metal layer 3 in the chemical conversion treatment is not particularly limited. For example, if the above chromate treatment is performed, a chromic acid compound is present per 1 m ² of the surface of the metal layer 3. About 0.5 mg to about 50 mg, preferably about 1.0 mg to about 40 mg in terms of chromium, about 0.5 mg to about 50 mg, preferably about 1.0 mg to about 40 mg in terms of phosphorus, and aminated phenol weight It is desirable that the coalescence is contained at a ratio of about 1 mg to about 200 mg, preferably about 5.0 mg to 150 mg.

  In the chemical conversion treatment, a solution containing a compound used for forming an acid-resistant film is applied to the surface of the metal layer by a bar coating method, a roll coating method, a gravure coating method, an immersion method, or the like, and then the temperature of the metal layer is 70. It is carried out by heating so as to have a temperature of from about 0C to about 200C. Further, before the chemical conversion treatment is performed on the metal layer, the metal layer may be previously subjected to a degreasing treatment by an alkali dipping method, an electrolytic cleaning method, an acid cleaning method, an electrolytic acid cleaning method, or the like. By performing the degreasing treatment in this way, it becomes possible to more efficiently perform the chemical conversion treatment on the surface of the metal layer.

[Adhesive layer 5]
In the battery packaging material, an adhesive layer 5 may be further provided between the metal layer 3 and the sealant layer 4 as necessary for the purpose of firmly bonding the metal layer 3 and the sealant layer 4. .

  The adhesive layer 5 is formed of an adhesive component capable of bonding the metal layer 3 and a sealant layer 4 described later. The adhesive used for forming the adhesive layer 5 may be a two-component curable adhesive or a one-component curable adhesive. Moreover, it does not specifically limit about the adhesion | attachment mechanism of the adhesive agent component used for formation of the contact bonding layer 5, For example, a chemical reaction type | mold, a solvent volatilization type | mold, a hot-melt type, a hot-pressure type etc. are mentioned.

  Specific examples of the adhesive component that can be used to form the adhesive layer 5 include polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene isophthalate, polycarbonate, copolymer polyester, and other polyester resins; polyethers Polyurethane adhesives; epoxy resins; phenol resin resins; polyamide resins such as nylon 6, nylon 66, nylon 12, copolymer polyamides; polyolefins such as polyolefins, carboxylic acid modified polyolefins, metal modified polyolefins Resin, polyvinyl acetate resin; cellulose adhesive; (meth) acrylic resin; polyimide resin; urea resin, melamine resin and other amino resins; chloroprene rubber, nitrile rubber, - styrene rubbers such as butadiene rubber; and silicone resins. These adhesive components may be used alone or in combination of two or more.

  Although the thickness in particular of the contact bonding layer 5 is not restrict | limited, For example, it is preferable to set it as about 1 micrometer-40 micrometers, and it is more preferable to set it as about 2 micrometers-about 30 micrometers.

[Sealant layer 4]
In the battery packaging material, the sealant layer 4 is a layer constituting the innermost layer of the battery packaging material when the battery is assembled. When the battery is assembled, the surfaces of the sealant layer 4 can be brought into contact with each other, and the contacted portion can be heat-welded to seal the battery element.

  The sealant layer 4 is preferably formed of a thermoplastic resin. Examples of the thermoplastic resin include polyolefin, cyclic polyolefin, carboxylic acid-modified polyolefin, carboxylic acid-modified cyclic polyolefin, and the like.

  Specific examples of polyolefins include polyethylene such as low density polyethylene, medium density polyethylene, high density polyethylene, and linear low density polyethylene; homopolypropylene, polypropylene block copolymers (for example, block copolymers of propylene and ethylene), polypropylene Crystalline or amorphous polypropylene such as random copolymers (eg, random copolymers of propylene and ethylene); ethylene-butene-propylene terpolymers, and the like. Among these polyolefins, polyethylene and polypropylene are preferable.

  Cyclic polyolefin is a copolymer of olefin and cyclic monomer. Examples of the olefin include ethylene, propylene, 4-methyl-1-pentene, styrene, butadiene, and isoprene. Examples of the cyclic monomer include cyclic alkenes such as norbornene; cyclic dienes such as cyclopentadiene, dicyclopentadiene, cyclohexadiene, norbornadiene, and the like. Among these polyolefins, a cyclic alkene is preferable, and norbornene is more preferable.

  A carboxylic acid-modified polyolefin is a polymer obtained by modifying a polyolefin with a carboxylic acid. Examples of the carboxylic acid used for modification include maleic acid, acrylic acid, itaconic acid, crotonic acid, maleic anhydride, itaconic anhydride and the like.

  The carboxylic acid-modified cyclic polyolefin is a copolymer obtained by copolymerizing a part of the monomer constituting the cyclic polyolefin in place of the α, β-unsaturated carboxylic acid or its acid anhydride, or α, β with respect to the cyclic polyolefin. -A polymer obtained by block polymerization or graft polymerization of an unsaturated carboxylic acid or its acid anhydride. The cyclic polyolefin to be modified with carboxylic acid can be the same as the above cyclic polyolefin. The carboxylic acid used for modification can be the same as that used for modification of the acid-modified cycloolefin copolymer.

  Among these thermoplastic resins, preferably crystalline or amorphous polyolefins, cyclic polyolefins, and blended polymers thereof; more preferably polyethylene, polypropylene, copolymers of ethylene and norbornene, and two of them The above blend polymer is mentioned.

  The sealant layer 4 may be formed from only one type of resin component, or may be formed from a blend polymer in which two or more types of resin components are combined. Furthermore, the sealant layer 4 may be formed of only one layer, or may be formed of a plurality of layers of two or more layers by the same or different resin components. When the sealant layer 4 is formed of a plurality of layers, the sealant layer 4 is preferably a laminate of a layer formed of carboxylic acid-modified polypropylene and a layer formed of polypropylene sequentially from the metal layer 3 side. The thing which was done is mentioned.

  The thickness of the sealant layer 4 is not particularly limited, but may be, for example, about 2 μm to 200 μm, preferably about 5 μm to 150 μm, and more preferably 10 μm to 100 μm.

[Foreign matter 7]
As described above, in the manufacturing process of the battery packaging material, when laminating each layer of the laminated film, the foreign matter adhering to the device or the foreign matter scattered in the air falls on the layer in the laminating step. In some cases, foreign matter may be included in the interface portion of the layer included in the laminated film by being laminated with the adjacent layer as it is. Moreover, the foreign material may adhere also to the resin film, metal foil, etc. which comprise each layer of a laminated | multilayer film. When a battery packaging material in which such foreign matter is present at the interface portion of the laminated film layer is molded, there are pinholes in the foreign matter part due to differences in elongation between the foreign matter part and other parts. It tends to occur. Among such foreign substances, the foreign substance 7 having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is particularly likely to cause pinholes during molding, and if it is a foreign substance smaller than this, It is unlikely to cause pinholes. Then, the number of area 0.4 mm ² or more foreign matter 7 is generally present one or more per length of 100m laminated film having a width 80～600Mm. On the other hand, in the 1st winding body of this invention, the number of the foreign materials 7 whose area is 0.4 mm < ² > or more is 1 or less per 100 m length of the laminated film with a width of 80 to 600 mm as described later. Is managed.

In this invention, the foreign material 7 whose area is 0.4 mm < ² > or more exists in the interface part of the at least 2 layer contained in a laminated film. Such foreign matter 7 is at least an interface part between the base material layer 1 and the adhesive layer 2, an interface part between the adhesive layer 2 and the metal layer 3 as shown in FIG. 3 and the sealant layer 4. Further, when the adhesive layer 5 is provided, the adhesive layer 5 may exist at an interface portion between the metal layer 3 and the adhesive layer 5, an interface portion between the adhesive layer 5 and the sealant layer 4 in the adhesive layer 5, and the like. Furthermore, when the coating layer 6 is provided, foreign matter may be present at the interface portion between the coating layer 6 and the base material layer 1. In addition, for example, when the sealant layer 4 is formed of a plurality of layers, the foreign matter 7 may also exist at an interface portion of at least two layers included in the sealant layer 4. In the present invention, the interface portion of each layer where foreign matter exists includes the interface and its vicinity, and the foreign matter existing at the interface portion includes not only foreign matter existing at the interface of the layer but also, for example, from the interface to the inside of the layer. Although it is buried in and located in the vicinity of the interface, it is not included in the interface. In addition, since the adhesive layer 2 and the adhesive layer 5 provided as necessary are usually formed very thin, there may be a case where foreign matter exists inside the adhesive layer 2 or the adhesive layer 5. The “interfacial portion of at least two layers” includes the adhesive layer 2 (inside the adhesive layer 2) and the adhesive layer 5 (inside the adhesive layer 5).

Among these interface portions in which the foreign matter 7 can be contained, in particular, when the foreign matter 7 having an area of 0.4 mm ² or more exists in the interface portion between the adhesive layer 2 and the metal layer 3 or in the adhesive layer 2, a pinhole Is likely to occur. This is considered to be caused by a large difference in tensile strength between the base material layer 1 and the metal layer 3. Specifically, since the tensile strength of the base material layer 1 is usually larger than the tensile strength of the metal layer 3, the base material layer 1 and the metal layer 3 are laminated rather than the case where the metal layer 3 is formed alone. The tensile strength when molding the battery packaging material is increased. Therefore, due to the presence of the foreign matter 7 in the interface portion between the adhesive layer 2 and the metal layer 3 or in the adhesive layer 2, the adhesion between the base material layer 1 and the metal layer 3 is appropriate at the portion where the foreign matter 7 exists. Otherwise, when the battery packaging material is stretched by molding, a large force applied to the metal layer 3 is likely to cause pinholes in the portion of the metal layer 3 where the foreign matter 7 exists. .

  Moreover, if the foreign material 7 exists between the metal layer 3 and the sealant layer 4, the metal layer 3 is damaged by the foreign material 7 when the battery packaging material is molded, which easily causes pinholes.

Although it does not specifically limit as the foreign material 7, Generally, they are dust, a metal piece, the oligomer of the resin which forms the base material layer 1, a carbide | carbonized_material, etc. The thickness of the foreign material 7 having an area of 0.4 mm ² or more is usually 2 μm or more and 50 μm or less. In addition, the thickness of the foreign material 7 means the thickness of the foreign material 7 in the lamination direction of the laminated film.

1-3. Configuration of First Winding Body The first winding body of the present invention is configured by winding the battery packaging material (laminated film) in a roll shape. The first wound body may be wound so that the sealant layer 4 of the battery packaging material is inside, or wound so that the base material layer 1 is inside. There may be.

In the first winding body, the number of foreign matters having an area of 0.4 mm ² or more when viewed from the laminating direction of the laminated film at the interface portion of the at least two layers included in the laminated film has a width of 80 It is managed to be 1 or less per 100 m length of a laminated film of ˜600 mm. Specifically, for example, as shown in a first winding body manufacturing method described later, after each layer is laminated to produce a belt-like laminated film, the area is 0.4 mm ² or more before winding the film. The part where the foreign matter is located is removed from the laminated film, and the number of the foreign matter 7 is set to one or less per 100 m of the length of the laminated film having a width of 80 to 600 mm. The number is managed. That is, in the 1st winding body, since the number of such foreign materials 7 is managed so that it may become 1 or less per 100 m length of a laminated film with a width of 80-600 mm, it arises with the said foreign materials 7. The occurrence of defects is suppressed. Therefore, by cutting out the battery packaging material unwound from the first winding body and sealing the battery element, it is possible to suitably suppress the production of a battery having a pinhole, thereby producing the battery. The yield can be improved. As will be described later, in the first winding body, the laminated film may be cut in the width direction so as to include the portion where the foreign material 7 is located, and the laminated film may be connected with a tape or the like.

  In the first winding body, the length of the laminated film constituting the battery packaging material is not particularly limited, and is, for example, 200 m or more, preferably about 200 to 600 m. Moreover, the width | variety of the said laminated | multilayer film is about 0.01-1m, for example, Preferably about 0.1-1m is mentioned. The thickness of the laminated film is, for example, 200 μm or less, preferably about 50 to 200 μm, more preferably about 65 to 130 μm. In the roll-shaped first winding body, the diameter of the circular cross section in the direction perpendicular to the width direction of the laminated film is preferably 150 mm or more, more preferably 220 mm or more. In addition, the upper limit of the diameter of the circular section is usually about 350 mm.

1-4. First Winding Body Manufacturing Method In the first winding body manufacturing method of the present invention, the above-described layers having a predetermined configuration are stacked, and a laminated film in which the number and size of the foreign matters 7 are controlled is wound. Although it does not restrict | limit as long as what was taken is obtained, For example, the following methods can be illustrated.

  First, at least the base material layer 1, the adhesive layer 2, the metal layer 3, and the sealant layer 4 are laminated in this order to obtain a laminated film. Specifically, for example, a laminated film is obtained as follows. First, the base material layer 1 and the metal layer 3 are laminated. This lamination can be performed by a dry laminating method using the above-described adhesive component for forming the adhesive layer 2 or the like. Next, the sealant layer 4 is laminated on the metal layer 3. This lamination can be performed by, for example, a dry lamination method. In addition, for the purpose of increasing the adhesive strength between the metal layer 3 and the sealant layer 4, an adhesive component for forming the adhesive layer 5 is applied on the metal layer 3 and dried as necessary. The sealant layer 4 may be formed from above. The sealant layer 4 can be formed, for example, by melt extrusion of a thermoplastic resin. Moreover, you may form the sealant layer 4 by laminating | stacking a resin film on the metal layer 3, for example. In addition, you may laminate | coat the coating layer 6 on the surface on the opposite side to the metal layer 3 of the base material layer 1 as needed. The coating layer 6 can be formed, for example, by applying the two-component curable resin for forming the coating layer 6 to the surface of the base material layer 1. The order of the step of laminating the metal layer 3 on the surface of the base material layer 1 and the step of laminating the coating layer 6 on the surface of the base material layer 1 are not particularly limited. For example, after forming the coating layer 6 on the surface of the base material layer 1, the metal layer 3 may be formed on the surface of the base material layer 1 opposite to the coating layer 6.

  In order to improve the adhesiveness of each layer in the obtained laminated film, an aging treatment or the like may be performed. The aging treatment can be performed, for example, by heating the laminated film at a temperature of about 30 to 100 ° C. for 1 to 200 hours. Furthermore, the obtained laminated film may be heated at a temperature equal to or higher than the melting point of the sealant layer 4 in order to further improve the adhesion of each layer in the obtained laminated film. The temperature at this time is preferably the melting point of the sealant layer 4 + 5 ° C. or higher and the melting point + 100 ° C. or lower, more preferably the melting point + 10 ° C. or higher and the melting point + 80 ° C. or lower. In the present invention, the melting point of the sealant layer refers to an endothermic peak temperature in differential scanning calorimetry of the resin component constituting the sealant layer. Heating in the aging treatment and heating above the melting point of the sealant layer 4 can be performed by, for example, a hot roll contact method, a hot air method, a near or far infrared method, and the like.

  In the battery packaging material, each layer constituting the laminated film improves or stabilizes film forming properties, lamination processing, suitability for final product secondary processing (pouching, embossing), etc., as necessary. In addition, surface activation treatment such as corona treatment, blast treatment, oxidation treatment, and ozone treatment may be performed.

Next, the foreign matter contained in the interface portion of at least two layers contained in the laminated film, the portion where the foreign matter 7 having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is located is removed. Then, a foreign matter removing step is performed in which the number of foreign matters 7 having an area of 0.4 mm ² or more is set to one or less per 100 m length of a laminated film having a width of 80 to 600 mm. The size, position, and number of the foreign matter can be detected by, for example, a defect inspection method described later. That is, imaging the surface of the laminated film, recording the position information of the foreign substance 7 having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film, and recognizing the position of the foreign substance according to the position information As can be done, the size, position, and number of the foreign substances can be grasped by performing the step of applying a mark to the laminated film. Next, in accordance with the obtained position information, the foreign matter 7 having an area of 0.4 mm ² or more is removed so that the number is 1 or less per 100 m of a laminated film having a width of 80 to 600 mm. The portion where the foreign matter 7 having an area of 0.4 mm ² or more is located may be cut out or removed only from that portion or the laminated film may be cut in the width direction including the portion where the foreign matter 7 is located. The laminated film may be connected with a tape or the like.

  Next, the winding process which winds up a laminated | multilayer film and obtains a 1st winding body is performed. The method for winding the laminated film is not particularly limited as long as the belt-like laminated film is wound in a roll shape, and may be wound on a roll or the like using a known film winder or the like.

2. Winding body of second battery packaging material The winding body of the second battery packaging material of the present invention (hereinafter sometimes simply referred to as “second winding body”) is at least a substrate. A wound body of a battery packaging material comprising a laminated film in which a layer 1, an adhesive layer 2, a metal layer 3, and a sealant layer 4 are laminated in this order, and at least two layers included in the laminated film In the interface portion, there is a foreign matter having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film, and a mark is given to the laminated film so that the position of the foreign matter can be recognized. It is characterized by. Hereinafter, the winding body of the 2nd packaging material for batteries of this invention is explained in full detail.

2-1. Laminated structure of battery packaging material constituting second winding body The battery packaging material constituting the second winding body of the present invention is the battery packaging constituting the first winding body described above. It has a layered structure similar to the material. That is, for example, as shown in FIG. 1, at least a base material layer 1, an adhesive layer 2, a metal layer 3, and a sealant layer 4 are made of a laminated film laminated in this order.

2-2. Configuration of each layer of battery packaging material constituting second winding body Configuration of each layer of battery packaging material constituting second winding body, that is, coating layer 6 and base material layer provided as necessary 1, the structure of the adhesive layer 2, the metal layer 3, the adhesive layer 5 provided as needed, and the sealant layer 4 are the structure of each layer of the battery packaging material constituting the first winding body described above. It is the same. However, the number of foreign substances 7 having an area of 0.4 mm ² or more is different in the following points.

In said 1st winding body, when the laminated film is seen from the lamination direction, the number of foreign matters 7 having an area of 0.4 mm ² or more is 1 or less per 100 m of the laminated film having a width of 80 to 600 mm. It is managed to become. On the other hand, in the laminated film in the second winding body, the number of foreign substances 7 having such a size is not necessarily managed, but the laminated film can be recognized so that the position of the foreign substance 7 can be recognized. By providing the mark, the position of the foreign object 7 is managed. In addition, also in the 2nd winding body, it is preferable to manage so that it may become 1 or less per 100m length of the laminated film of width 80-600mm. Therefore, in the second wound body, the number of foreign matters 7 having an area of 0.4 mm ² or more when the laminated film is viewed from the lamination direction is usually 1 per 100 m of the laminated film having a width of 80 to 600 mm. It is preferable that it is one or less.

2-3. Configuration of Second Winding Body The second winding body of the present invention is configured by winding the battery packaging material (laminated film) into a roll shape. Similarly to the first wound body, the second wound body may be wound so that the sealant layer 4 of the battery packaging material is on the inside, or the base material layer 1 is on the inside. It may be wound so as to be.

In the second winding body, a mark is given to the laminated film so that the position of the foreign substance 7 having an area as viewed from the lamination direction of the laminated film of 0.4 mm ² or more can be recognized. The position of is managed. Specifically, as shown in a method for producing a second wound body described later, etc., after each layer is laminated to produce a strip-like laminated film, the area of the laminated film is reduced to 0. The position of the foreign matter 7 is managed by providing a mark on the laminated film so that the position of the foreign matter 7 of 4 mm ² or more can be recognized. That is, in the 2nd winding body, since it manages so that the position of such a foreign material 7 in a laminated | multilayer film can be recognized, it can also recognize easily the position of the defect produced by the foreign material 7 in the case of shaping | molding. . Therefore, when the battery packaging material unwound from the second winding body is cut out and used for sealing the battery element, the battery can be manufactured while avoiding the defective portion, and the yield of battery manufacturing can be reduced. Can be improved. In the second winding body, a mark attached so that the position of the foreign matter 7 can be recognized may be provided on the foreign matter 7 or may be provided in the vicinity of the foreign matter 7. . Moreover, such a mark can be provided using, for example, ink.

  In the second wound body, the length of the laminated film constituting the battery packaging material is not particularly limited, and is, for example, 200 m or more, preferably about 200 to 600 m. Moreover, the width | variety of the said laminated | multilayer film is about 0.01-1m, for example, Preferably about 0.1-1m is mentioned. The thickness of the laminated film is, for example, 200 μm or less, preferably about 50 to 200 μm, more preferably about 65 to 130 μm. In the roll-shaped second wound body, the diameter of the circular cross section in the direction perpendicular to the width direction of the laminated film is preferably 150 mm or more, more preferably 220 mm or more. In addition, the upper limit of the diameter of the circular section is usually about 350 mm.

2-4. Second Winding Body Manufacturing Method The second winding body manufacturing method of the present invention is the same as the above-described first winding body manufacturing method until a laminated film is obtained.

Next, it is possible to recognize the position of the foreign matter 7 included in the interface portion of at least two layers included in the laminated film and having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film. Then, a mark applying step for applying a mark to the laminated film is performed. The size, position, and number of the foreign matter 7 can be detected by, for example, a defect inspection method described later. That is, imaging the surface of the laminated film, recording the position information of the foreign material 7 having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film, and the position of the foreign material 7 according to the position information A step of applying a mark to the laminated film so as to be recognized.

  Next, the winding process which winds up a laminated | multilayer film and obtains a 2nd winding body is performed. The method for winding the laminated film is not particularly limited as long as the belt-like laminated film is wound in a roll shape, and may be wound on a roll or the like using a known film winder or the like.

3. Defect inspection method for battery packaging material The defect inspection method for battery packaging material of the present invention (hereinafter sometimes simply referred to as “defect inspection method”) includes at least a base material layer 1, an adhesive layer 2, and a metal layer. 3 and a sealant layer 4 are inspected for a defect in a packaging material for a battery comprising a laminated film laminated in this order. The surface of the laminated film is imaged, and an interface portion of at least two layers contained in the laminated film is obtained. The step of recording the position information of the foreign matter having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film, and the position of the foreign matter having an area of 0.4 mm ² or more can be recognized according to the position information. Thus, it is provided with the mark provision process which provides a mark to a laminated | multilayer film.

In the defect inspection method of the present invention, the configuration of the battery packaging material used for the inspection is the same as the configuration of the battery packaging material constituting the first winding body described above. However, the number of foreign substances 7 having an area of 0.4 mm ² or more is different in the following points. That is, in the first winding body, the number of foreign matters 7 having an area of 0.4 mm ² or more when viewed from the lamination direction is 1 or less per 100 m of a laminated film having a width of 80 to 600 mm. In contrast, in the battery packaging material that is the object of the defect inspection method of the present invention, such management is not performed. Therefore, in the battery packaging material to be subjected to the defect inspection method of the present invention, the number of foreign matters 7 having an area of 0.4 mm ² or more when the laminated film is viewed from the laminating direction is the laminated film having a width of 80 to 600 mm. There may be one or more per 100 m in length.

In the defect inspection method of the present invention, first, the surface of the laminated film 4 of such a battery packaging material is imaged using a camera or the like, and the area when viewed from the lamination direction of the laminated film is 0.4 mm ^2. A recording process for recording the position information of the foreign matter 7 is performed. At this time, it is preferable to record information such as the size and height of the foreign matter 7. Such a recording process for recording the position information of the foreign matter 7 can be performed by using a known defect inspection apparatus used for defect inspection such as fish eye in the film. A commercial item can be used as such a defect inspection apparatus.

Next, in accordance with the position information obtained in the recording process, a mark applying process for applying a mark to the laminated film is performed so that the position of the foreign material 7 having an area of 0.4 mm ² or more can be recognized. The position of the mark is not particularly limited as long as it is provided so that the position of the foreign object 7 can be recognized. For example, the mark may be provided on the foreign object 7 or may be provided in the vicinity of the foreign object 7. May be. Such a mark application process can also be performed by using a known defect inspection apparatus as described above. The type of the mark is not particularly limited as long as the position can be recognized. For example, an ink or the like used for a general film defect inspection apparatus can be used in the present invention.

  As described above, the defect inspection method of the present invention makes it possible to manage the position, size, number, and the like of the foreign material 7 of the laminated film having defects that cause pinholes. That is, for example, by applying the defect inspection method of the present invention to a battery packaging material, the position of such foreign matter 7 in the laminated film can be recognized as in the second winding body of the present invention. It is possible to easily recognize the position of the defect caused by the foreign material 7 during molding. Therefore, when the battery packaging material unwound from the second winding body is cut out and used for sealing the battery element, it is possible to manufacture a battery while avoiding a defective portion that causes pinholes. And the yield of battery manufacturing can be improved.

  In addition, by applying the defect inspection method of the present invention, the foreign material 7 of the sealant layer 4 that can be recognized by such a mark as in the first winding body of the present invention is removed from a laminated film having a width of 80 to 600 mm. It can be removed so that there is no more than one per 100 m in length. Therefore, by cutting out the battery packaging material unwound from the first winding body and sealing the battery element, it is possible to suitably suppress the production of a battery having a defect that causes pinholes. And the yield of battery manufacturing can be improved.

4). Use of Winding Body for Battery Packaging Material The winding body for battery packaging material of the present invention is a battery element such as a positive electrode, a negative electrode, an electrolyte, etc. by unwinding the battery packaging material and cutting it to an appropriate size. It is used as a package for hermetically sealing. That is, the battery packaging material unwound from the winding body is deformed in accordance with the shape of the battery element, and can be a packaging body that houses the battery element.

  Specifically, a battery element including at least a positive electrode, a negative electrode, and an electrolyte is formed with a flange (sealant layer) on the periphery of the battery element in a state in which a metal terminal connected to each of the positive electrode and the negative electrode protrudes outward. A region where the two come into contact with each other can be formed and covered with the battery packaging material. Next, the battery sealed with the battery packaging material (packaging body) is provided by heat-sealing and sealing the sealant layers of the flange portion. When the battery element is accommodated using the package, the sealant layer 4 of the battery packaging material is used so as to be on the inner side (surface in contact with the battery element).

  The battery packaging material unwound from the wound body of the present invention can be used for either a primary battery or a secondary battery, but is particularly suitable for use in a secondary battery. The type of the secondary battery to which the battery packaging material is applied is not particularly limited. Examples include iron storage batteries, nickel / zinc storage batteries, silver oxide / zinc storage batteries, metal-air batteries, multivalent cation batteries, capacitors and capacitors. Among these secondary batteries, lithium ion batteries and lithium ion polymer batteries can be cited as suitable applications of battery packaging materials that are unwound from the wound body of the present invention.

  Hereinafter, the present invention will be described in detail with reference to examples. However, the present invention is not limited to the examples.

[Manufacture of battery packaging materials]
On the base material layer 1 made of a stretched nylon film (thickness 25 μm), a metal layer 3 made of an aluminum foil (thickness 40 μm) subjected to chemical conversion treatment on both surfaces was laminated by a dry lamination method. Specifically, a two-component curable urethane adhesive (a polyol compound and an aromatic isocyanate compound) was applied to one surface of the aluminum foil to form an adhesive layer 2 (thickness 4 μm) on the metal layer 3. Next, after bonding the adhesive layer 2 and the base material layer 1 on the metal layer 3 under pressure and heating, an aging treatment is carried out at 40 ° C. for 24 hours, whereby base material layer 1 / adhesive layer 2 / metal layer 3 A laminate was prepared. In addition, the chemical conversion treatment of the aluminum foil used as the metal layer 3 is performed by rolling a treatment liquid composed of a phenol resin, a chromium fluoride compound, and phosphoric acid so that the coating amount of chromium is 10 mg / m ² (dry weight). The coating was applied to both surfaces of the aluminum foil and baked for 20 seconds under the condition that the film temperature was 180 ° C. or higher.

  Next, the resin component (mixed resin of acid-modified polypropylene resin and propylene resin) that forms the sealant layer 4 on the metal layer 3 side of the laminate is extruded in a molten state (250 ° C.), thereby the sealant on the metal layer 3. Layer 4 (thickness 45 μm) was laminated. Thus, a band-shaped battery packaging material comprising a laminated film in which the base material layer 1 / adhesive layer 2 / metal layer 3 / sealant layer 4 were laminated in order was obtained.

[Defect inspection of battery packaging materials]
For the battery packaging material obtained above, using a commercially available film defect inspection apparatus, the position information of the foreign matter in the range of 0.03 to 3.1 mm ² as viewed from the lamination direction of the laminated film is recorded, Marks were provided in the vicinity of these foreign substances so that the positions could be recognized.

[Measurement of the number of pinholes generated by molding A]
From the position of the mark of the battery packaging material obtained above, one foreign material having the size shown in Table 1 is located in the center, and the battery packaging material is sized to 100 mm × 100 mm. Cut out and used as a test sample. As the test sample, a sample in which foreign matter was present at the interface portion (including the inside of the adhesive layer) between the adhesive layer and the metal layer was used. Next, a straight mold composed of a 20 × 30 mm rectangular male mold and a female mold with a clearance of 0.5 mm between the male mold and the female mold so that the thermal adhesive resin layer side is located on the male mold side. The test sample was placed on top, and the test sample was pressed with a presser pressure (surface pressure) of 0.4 MPa so as to have a molding depth of 6 mm, and cold-molded (drawn one-stage molding). The presence or absence of pinholes in the metal layer in the molded battery packaging material was confirmed, and the number of pinholes generated was measured. The number of occurrences of pinholes is determined as follows: moldings with pinholes recognized after molding are identified as defective moldings (x), and those with no pinholes identified as moldings with good moldings (◯). The presence or absence of pinholes was confirmed. The results are shown in Table 1.

[Measurement of the number of pinholes generated by molding B]
From the position of the mark of the battery packaging material obtained above, each position is located at two foreign matters having the sizes shown in Table 2 (both included in the interface portion between the adhesive layer and the metal layer (including in the adhesive layer)). The measurement A described above, except that the battery packaging material was cut into a size of 100 mm × 100 mm to be a test sample and the number of test samples was 5 respectively. In the same manner as above, the number of pinholes generated by molding was measured. The results are shown in Table 2.

[Measurement of the number of pinholes generated by molding C]
In the production of battery packaging materials, except that a sealant layer in which two layers of a carboxylic acid-modified polypropylene layer (22.5 μm) and a polypropylene layer (22.5 μm) are laminated in this order from the metal layer side is used. A battery packaging material was prepared in the same manner as described above. The battery packaging material obtained here was marked in the vicinity of the foreign matter in the same manner as in the above defect inspection. Next, from the position of the obtained mark, a foreign matter having a size shown in Table 3 (located at the interface portion between the sealant layer and the metal layer) is positioned at the center portion, and the size is 100 mm × 100 mm. The number of pinholes generated by molding was measured in the same manner as in measurement A, except that the battery packaging material was cut into a test sample. The results are shown in Table 3.

[Measurement of the number of pinholes generated by molding D]
From the position of the mark of the battery packaging material obtained above, two foreign matters each having the size shown in Table 4 (both located at the interface portion between the sealant layer and the metal layer) are located in the central portion. Thus, the pinhole by molding was performed in the same manner as in the above measurement A, except that the battery packaging material was cut into a size of 100 mm × 100 mm to obtain a test sample, and the number of test samples was five. The number of occurrences was measured. The results are shown in Table 4.

From the results shown in Tables 1 to 4, it was revealed that pinholes due to molding are less likely to occur when foreign matter having an area smaller than 0.4 mm ² is present at the interface portion of the laminated film. On the other hand, when foreign matter having an area of 0.4 mm ² or more is present at the interface portion of the laminated film, it has become clear that pinholes due to molding are likely to occur. From this result, in the wound body of the packaging material for batteries, a battery in which pinholes are easily generated by managing the size of the foreign matter present at the interface portion of the laminated film so that the area is 0.4 mm ² or less. It can be seen that manufacturing the battery using the packaging material can be suitably avoided, and the production efficiency of the battery can be improved.

[Production of Winding Body A for Battery Packaging Material]
In the same manner as in the above-described manufacturing and defect inspection of the battery packaging material, the battery packaging material No. 1A to 12A were produced. Next, using a commercially available film winder, the battery packaging material No. 1A-12A was wound up so that the sealant layer was inside. Battery packaging material No. As 1A-12A, the thing in which the foreign material exists in the interface part (including in the contact bonding layer) of the contact bonding layer and a metal layer among the laminated films produced by said method was selected.

Battery packaging material No. For the wound bodies of 1A to 12A, the number of foreign matters having an area of 0.4 mm ² or more per 100 m of laminated film, the number of shots obtained from the wound body, the number of defective shots, the ratio of defective shots, the wound body, Table 5 shows the size of the molded part formed on the battery packaging material as a result of the determination as to whether or not the product can be obtained. Note that a shot is a unit of battery packaging material required to produce one battery. In 1A to 12A, a length of 100 mm was taken as one shot. Therefore, for example, a battery packaging material (5000 shots) for producing 5000 batteries in theory can be obtained from a battery packaging material having a length of 500 m, but a foreign matter having an area of 0.4 mm ² or more is located. A shot to be performed becomes defective. Winding bodies with many defective shots greatly reduce the production efficiency of the battery. Therefore, in order to use the winding body as a product, the number of foreign matters having an area per 100 m of laminated film of 0.4 mm ² or more is one. It is desirable to manage the following. Further, a battery element is placed in the molded part of the battery packaging material in the battery manufacturing process.

  In the determination of product availability in Table 1, when there were few defects and the wound body could be used as a product as it was, (◯), and when there were many defects and the wound body could not be used as a product as it was, it was marked as (X).

[Production of Winding Body B for Battery Packaging Material]
In the same manner as described above, each of the battery packaging material No. 1B to 12B were produced. Next, using a commercially available film winder, the battery packaging material No. 1B-12B was wound up so that the sealant layer was inside. Battery packaging material No. As 1B-12B, the thing in which the foreign material exists in the interface part of a metal layer and a sealant layer among the laminated films produced by said method was selected.

Battery packaging material No. For the wound bodies of 1B to 12B, the number of foreign matters having an area of 0.4 mm ² or more per 100 m of laminated film, the number of shots obtained from the wound body, the number of defective shots, the ratio of defective shots, the wound body, Table 6 shows the size of the molded part formed in the battery packaging material as a result of the determination as to whether or not the product can be obtained.

DESCRIPTION OF SYMBOLS 1 ... Base material layer 2 ... Adhesive layer 3 ... Metal layer 4 ... Sealant layer 5 ... Adhesive layer 6 ... Coating layer

Claims (14)

At least a wound body of a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
In the interface portion of at least two layers included in the laminated film, there are foreign matters having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film,
A wound body of a battery packaging material in which a mark is given to the laminated film so that the position of the foreign matter can be recognized.   The foreign matter is present at least in an interface portion between the base material layer and the adhesive layer, in the adhesive layer, in an interface portion between the adhesive layer and the metal layer, or in an interface portion between the metal layer and the sealant layer. The winding body for battery packaging material according to claim 1.   The wound body for a battery packaging material according to claim 1 or 2, wherein the sealant layer is formed of a plurality of layers, and the foreign matter is present at an interface portion between the metal layer and the sealant layer. The laminated film has a coating layer on the side opposite to the adhesive layer of the base material layer,
The winding body of the packaging material for batteries in any one of Claims 1-3 in which the said foreign material exists in the interface part of the said coating layer and the said base material layer.   The said winding body is a winding body of the packaging material for batteries in any one of Claims 1-4 whose length of the said laminated | multilayer film is a roll shape whose diameter of a circular cross section is 150 mm or more. It is a manufacturing method of the winding body of the packaging material for batteries in any one of Claims 1-5,
After obtaining a laminated film by a laminating step of laminating a base material layer, an adhesive layer, a metal layer, and a sealant layer,
The foreign matter contained in the interface part of at least two layers contained in the laminated film, the area when viewed from the lamination direction of the laminated film can recognize the position of the foreign matter of 0.4 mm ² or more, A mark applying step for applying a mark to the laminated film;
Winding the laminated film to obtain a wound body; and
The manufacturing method of the winding body of the packaging material for batteries provided with this. At least a wound body of a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
At the interface part of at least two layers included in the laminated film, the number of foreign matters having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is the length of the laminated film having a width of 80 to 600 mm. The winding body of the packaging material for batteries which is 1 or less per 100 m.   The foreign matter is present at least in an interface portion between the base material layer and the adhesive layer, in the adhesive layer, in an interface portion between the adhesive layer and the metal layer, or in an interface portion between the metal layer and the sealant layer. The wound body for battery packaging material according to claim 7.   The wound body of a battery packaging material according to claim 7 or 8, wherein the sealant layer is formed of a plurality of layers, and the foreign matter is present at an interface portion between the metal layer and the sealant layer. The laminated film has a coating layer on the side opposite to the adhesive layer of the base material layer,
The wound body of the battery packaging material according to any one of claims 7 to 9, wherein the foreign matter is present at an interface portion between the coating layer and the base material layer.   The said wound body is a wound body of the packaging material for batteries in any one of Claims 7-10 whose length of the said laminated | multilayer film is a roll shape whose diameter of a circular cross section is 150 mm or more. It is a manufacturing method of the winding body of the packaging material for batteries in any one of Claims 7-11,
After obtaining a laminated film by a laminating step of laminating a base material layer, an adhesive layer, a metal layer, and a sealant layer,
The foreign matter contained in the interface portion of at least two layers contained in the laminated film, the portion when the foreign matter having an area of 0.4 mm ² or more when viewed from the lamination direction of the laminated film is removed, A foreign matter removing step in which the number of foreign matters having an area of 0.4 mm ² or more is 1 or less per 100 m in length of the laminated film having a width of 80 to 600 mm;
Winding the laminated film to obtain a wound body; and
The manufacturing method of the winding body of the packaging material for batteries provided with this. The battery according to claim 12, further comprising a mark applying step of applying a mark to the laminated film so that the position of the foreign material having the area of the laminated film of 0.4 mm ² or more can be recognized in the foreign matter removing step. A method for manufacturing a wound body of packaging material. At least a defect inspection method for a battery packaging material comprising a laminated film in which a base material layer, an adhesive layer, a metal layer, and a sealant layer are laminated in this order,
The surface of the laminated film is imaged, and the position information of foreign matters having an area of 0.4 mm ² or more when viewed from the laminating direction of the laminated film is present at an interface portion of at least two layers included in the laminated film. Recording process;
In accordance with the position information, a mark applying step for applying a mark to the laminated film so that the position of the foreign matter having an area of 0.4 mm ² or more can be recognized;
A defect inspection method for battery packaging materials.