JP2015180488A - Heat treatment method and heat treatment apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a heat treatment method and heat treatment apparatus which can raise the temperature of a heating object formed on a base material to a target temperature without damaging the base material.SOLUTION: A base material 5 of a resin is conveyed by a delivery roller 11 and a take-up roller 12 in a roll-to-roll manner. A functional layer is formed on part of the surface of the base material 5. Droplets of deionized water are discharged and supplied from a discharge head 20 to a supply area of the base material 5 including a temperature rise suppression area requiring the suppression of a temperature rise. When the surface of the base material 5 is irradiated with flash light from flash lamps FL, the temperature of the functional layer is raised to a target temperature in a temperature rise. On the other hand, water absorbs the heat of evaporation during the evaporation thereof in the temperature rise suppression area of the base material 5, so that a temperature rise beyond the boiling point of water is suppressed. As a result, the temperature of the functional layer formed on the base material 5 can be raised to the target temperature without damaging the base material 5.

Description

  The present invention relates to a heat treatment method and a heat treatment apparatus for raising the temperature of a heating object by irradiating light to a substrate having poor heat resistance such as a resin on which the heating object is formed.

  As a technique for heating the surface of a substrate in an extremely short time, a flash lamp annealing (FLA) technique using a flash lamp is known. The flash lamp has a light emission time of 1 second or less (typically several milliseconds to several tens of milliseconds), and irradiates the surface of the substrate with flash light (flash) having a very short irradiation time and high intensity. To instantaneously raise the temperature of the surface.

  For example, Patent Document 1 discloses a drying technique in which a liquid remaining on a substrate surface is boiled and evaporated by irradiating a flash light from a flash lamp onto a semiconductor substrate that has been subjected to surface cleaning treatment with a chemical solution and pure water. Is disclosed. Patent Document 2 discloses a technique for forming polycrystalline silicon by pulsing a silicon thin film by irradiating a silicon thin film on a substrate with flash light from a flash lamp.

  On the other hand, in recent years, with the practical application of electronic paper, attempts have been made to form semiconductor devices such as TFT elements on flexible resin films such as polyethylene terephthalate (PET). Even in the manufacturing process of such a flexible electronic device, it is essential to perform an annealing process on a target object in which a functional layer such as an electrode is laminated on the surface of a resin base material. Patent Document 3 discloses a technique for selectively heating only a transparent conductive film by irradiating flash light onto a transparent conductive sheet in which a transparent conductive film is formed on a transparent substrate such as PET.

JP 2008-128567 A Special table 2011-515833 gazette JP 2010-146757 A

  In the flash lamp annealing disclosed in Patent Document 3, in order to heat only the transparent conductive film, it is necessary to optimize the irradiation time and irradiation energy density of the flash light according to the film thickness. In the technique disclosed in Patent Document 3, a transparent conductive film is formed on the entire surface of the transparent substrate. However, in actual processes, the conductive film is often formed on a part of the transparent substrate. In such a case, even if the irradiation condition of the flash light is optimized, the region of the transparent substrate where the conductive film is not formed is directly exposed to the flash light. This may cause thermal damage to the transparent substrate.

  In particular, when the base material is a resin with poor heat resistance, such as PET, if the flash light is irradiated to such an extent that the conductive film can be heated to a predetermined target temperature, damage to the base material is avoided. On the contrary, there is a problem that the conductive film cannot be heated to a necessary target temperature by flash light irradiation that does not damage the substrate.

  The present invention has been made in view of the above problems, and provides a heat treatment method and a heat treatment apparatus capable of raising the temperature of a heating object formed on a base material to a target temperature without damaging the base material. The purpose is to do.

  In order to solve the above-mentioned problem, the invention of claim 1 is directed to a heating target of the heating object in a heat treatment method in which the heating object is heated by irradiating the base material on which the heating object is formed with light. A supply step of selectively supplying a phase change material that undergoes a phase transition at a temperature lower than a temperature to a supply region including at least a temperature increase suppression region that needs to suppress a temperature increase in the substrate; and the phase transition And a heating step of heating the object to be heated by irradiating light onto the substrate on which the substance is adhered.

  According to a second aspect of the present invention, in the heat treatment method according to the first aspect of the present invention, a transition temperature of the phase change material is lower than a temperature at which thermal damage is caused to the substrate.

  The invention of claim 3 is characterized in that, in the heat treatment method according to claim 1 or 2, the substrate is irradiated with flash light in the heating step.

  The invention of claim 4 is the heat treatment method according to any one of claims 1 to 3, characterized in that, in the supplying step, a liquid containing the phase change material is supplied to the substrate. To do.

  The invention according to claim 5 is the heat treatment method according to claim 4, further comprising a step of adding a thickener for increasing the viscosity of the liquid to the liquid containing the phase change material.

  The invention according to claim 6 is the heat treatment method according to the invention of claim 4, further comprising a step of imparting hydrophilicity to the supply region by applying a hydrophilic treatment.

  The invention of claim 7 is the heat treatment method according to the invention of claim 6, further comprising a step of performing water repellency treatment around the supply region and surrounding the supply region with the water repellent region. To do.

  The invention according to claim 8 is the heat treatment method according to any one of claims 4 to 7, wherein in the supplying step, a liquid containing the phase change material in a liquid phase is supplied to the substrate. It is characterized by.

  The ninth aspect of the invention is the heat treatment method according to the eighth aspect of the invention, further comprising the step of solidifying the phase change material in the liquid phase supplied to the substrate.

  The invention of claim 10 is the heat treatment method according to any one of claims 4 to 7, wherein in the supplying step, a liquid containing a solution in which the phase change material is dissolved in a solvent is applied to the substrate. It is characterized by supplying.

  The eleventh aspect of the present invention is the heat treatment method according to the tenth aspect of the present invention, further comprising a precipitation step of removing the solvent from the solution supplied to the substrate and precipitating the phase change material in the supply region. It is characterized by that.

  According to a twelfth aspect of the present invention, in the heat treatment method according to any one of the fourth to eleventh aspects, in the supplying step, a liquid containing the phase change material in a supply region from a nozzle that discharges droplets. It is characterized by discharging.

  The invention according to claim 13 is the heat treatment method according to any one of claims 1 to 3, wherein, in the supplying step, a solid containing the phase change material is supplied to the substrate. To do.

  The invention of claim 14 is the heat treatment method according to the invention of claim 13, wherein in the supplying step, a solid containing the phase change material in a solid phase is supplied to the substrate.

  Further, the invention of claim 15 is the heat treatment method according to claim 13 or claim 14, wherein a thickening agent for increasing the viscosity of the liquid generated when the solid containing the phase change material is melted is added to the solid. The method further includes the step of:

  According to a sixteenth aspect of the present invention, in the heat treatment method according to any one of the first to fifteenth aspects, the supplying step selectively attaches the phase change material to a pattern corresponding to the supplying region. A step of supplying the phase change material to the printing plate; and a step of transferring the phase change material adhered to the plate to the supply region of the substrate.

  The invention according to claim 17 is the heat treatment method according to any one of claims 1 to 16, wherein the removal step of removing the phase change material remaining on the substrate after the heating step. Is further provided.

  The invention of claim 18 is the heat treatment method according to any one of claims 1 to 17, wherein, in the supplying step, the first surface of the base material on which the heating object is formed is opposite. The phase change material is supplied to the second surface on the side.

  The invention according to claim 19 is the heat treatment method according to claim 18, wherein, in the supplying step, the supporting member carrying the phase change material is brought close to the second surface to supply the phase change material. It supplies to an area | region.

  According to a twentieth aspect of the present invention, in the heat treatment method according to any one of the first to nineteenth aspects, the phase change material is water.

  The invention according to claim 21 is the heat treatment method according to any one of claims 1 to 20, wherein the substrate is long.

  According to a twenty-second aspect of the present invention, in the heat treatment method according to any of the first to twentieth aspects, the substrate is plate-shaped or sheet-shaped.

  The invention of claim 23 is a heat treatment apparatus for raising the temperature of a heating object by irradiating the substrate on which the heating object is formed with a temperature lower than a temperature increase target temperature of the heating object. A supply portion that selectively supplies a phase change material that undergoes phase transition at a supply region including at least a temperature increase suppression region that needs to be suppressed in the substrate, and a group to which the phase change material is attached A heating unit that irradiates the material with light to heat the object to be heated.

  According to a twenty-fourth aspect of the present invention, in the heat treatment apparatus according to the twenty-third aspect of the present invention, a transition temperature of the phase change material is lower than a temperature at which thermal damage is caused to the substrate.

  According to a twenty-fifth aspect of the present invention, in the heat treatment apparatus according to the twenty-third or twenty-fourth aspect of the present invention, the heating section includes a flash lamp that irradiates a substrate with flash light.

  According to a twenty-sixth aspect of the present invention, in the heat treatment apparatus according to any one of the twenty-third to twenty-fifth aspects, the substrate is transported by winding the substrate fed from the first roller with the second roller. It further has a conveyance part.

  The invention according to claim 27 is the heat treatment apparatus according to any one of claims 23 to 25, wherein the base material is plate-shaped or sheet-shaped, and the transport unit transports the base material one by one. Is further provided.

  The invention of claim 28 is characterized in that, in the heat treatment apparatus according to any of claims 23 to 27, the supply section supplies a liquid containing the phase change material to the substrate. To do.

  According to a twenty-ninth aspect of the present invention, in the heat treatment apparatus according to the twenty-eighth aspect, the supply unit has a nozzle for discharging a liquid droplet containing the phase change material in the supply region. .

  The invention of claim 30 is characterized in that, in the heat treatment apparatus according to any of claims 23 to 27, the supply section supplies a solid containing the phase change material to the substrate. To do.

  The invention according to claim 31 is the heat treatment apparatus according to any one of claims 23 to 30, wherein the supply section selectively attaches the phase change material to a pattern corresponding to the supply region. It has a printing cylinder which makes a printing plate contact | abut to the said base material, and transfers the said phase change substance to the said supply area | region.

  The invention according to claim 32 is the heat treatment apparatus according to any one of claims 23 to 31, further comprising a removing unit that removes the phase change material remaining on the substrate after heating. It is characterized by that.

  The invention according to claim 33 is the heat treatment apparatus according to any one of claims 23 to 32, characterized in that the phase change material is water.

  According to the inventions of claims 1 to 22, the phase change material that undergoes phase transition at a temperature lower than the temperature increase target temperature of the object to be heated is a temperature increase that requires at least suppression of temperature increase in the substrate. In order to heat the heating object by selectively supplying the supply area including the suppression area and irradiating light onto the substrate on which the phase change material adheres, the heating object is heated to the temperature increase target temperature. In the temperature rise suppression region, the temperature rise is suppressed to absorb the latent heat generated when the phase change material undergoes phase transition, and the heating target formed on the substrate is raised to the target temperature without damaging the substrate. Can be warmed.

  In particular, according to the invention of claim 2, since the transition temperature of the phase change material is lower than the temperature at which the base material is thermally damaged, it is possible to reliably prevent the base material from being damaged.

  In particular, according to the invention of claim 5, since the thickener for increasing the viscosity of the liquid is added to the liquid containing the phase change material, the flow of the supplied liquid can be suppressed.

  In particular, according to the inventions of claims 6 and 7, the supply region is subjected to a hydrophilization treatment to impart hydrophilicity, so that the flow of the supplied liquid can be suppressed.

  In particular, according to the invention of claim 18 and claim 19, since the phase change material is supplied to the second surface opposite to the first surface of the substrate on which the object to be heated is formed, the phase change material is heated. Contact with an object can be prevented.

  According to the invention of claim 23 to claim 33, the phase change material that undergoes phase transition at a temperature lower than the temperature increase target temperature of the object to be heated is a temperature increase that requires at least suppression of temperature increase in the substrate. In order to heat the heating object by selectively supplying the supply area including the suppression area and irradiating light onto the substrate on which the phase change material adheres, the heating object is heated to the temperature increase target temperature. In the temperature rise suppression region, the temperature rise is suppressed to absorb the latent heat generated when the phase change material undergoes phase transition, and the heating target formed on the substrate is raised to the target temperature without damaging the substrate. Can be warmed.

  In particular, according to the invention of claim 24, since the transition temperature of the phase change material is lower than the temperature at which the substrate is thermally damaged, it is possible to reliably prevent the substrate from being damaged.

It is a figure which shows the whole structure of the heat processing apparatus of 1st Embodiment. It is a perspective view of the heat processing apparatus of FIG. It is sectional drawing which shows the structure of a base material. It is a figure which shows the whole structure of the heat processing apparatus of 2nd Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 3rd Embodiment. It is a top view of the base material in which the hydrophilic treatment and the water repellent treatment were performed. It is a figure which shows the whole structure of the heat processing apparatus of 4th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 5th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 6th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 7th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 8th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 9th Embodiment. It is a figure which shows the state by which the support film which carry | supported the pure water in 9th Embodiment was bonded together by the base material. It is a figure which shows the whole structure of the heat processing apparatus of 10th Embodiment. It is a figure which shows the whole structure of the heat processing apparatus of 11th Embodiment. It is a top view which shows the whole structure of the heat processing apparatus of 12th Embodiment. It is an external appearance perspective view of the heat processing apparatus of 13th Embodiment. FIG. 18 is a bottom view of the ejection head of FIG. 17.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

<First Embodiment>
FIG. 1 is a diagram illustrating an overall configuration of a heat treatment apparatus 1a according to the first embodiment. FIG. 2 is a perspective view of the heat treatment apparatus 1a. In FIG. 1 and the subsequent drawings, the size and number of each part are exaggerated or simplified as necessary for easy understanding.

  This heat treatment apparatus 1a is a material for electrodes formed on one surface of a substrate by flash light irradiation while conveying a long resin film as a substrate by a roll-to-roll method. This is a device for raising the temperature of the functional layer. The heat treatment apparatus 1 a includes, as main elements, a transport unit 10 that transports the base material 5, a discharge head 20 that supplies water droplets to the base material 5, and an irradiation unit 50 that irradiates the base material 5 with flash light. Further, the heat treatment apparatus 1a includes a control unit 9 that controls various operation mechanisms provided in the apparatus to advance the process.

  The transport unit 10 includes a delivery roller (first roller) 11 and a take-up roller (second roller) 12. The feed roller 11 and the take-up roller 12 are rotated clockwise on the paper surface of FIG. 1 by a rotational drive mechanism (not shown) with the central axis along the longitudinal direction as the center of rotation. The base material 5 that has been wound around the feed roller 11 is fed by the rotation of the feed roller 11 and wound by the take-up roller 12. When the base material 5 fed from the feed roller 11 is taken up by the take-up roller 12, the belt-like base material 5 is continuously conveyed in a roll-to-roll manner in the order from the discharge head 20 to the irradiation unit 50. During processing, the substrate 5 is conveyed continuously or intermittently. A plurality of auxiliary rollers that support and guide the base material 5 along the conveyance path from the feed roller 11 to the take-up roller 12 may be installed.

  An ejection head 20 and an irradiation unit 50 are provided above the substrate 5 that is transported by the transport unit 10. The ejection head 20 ejects pure water droplets onto the substrate 5 transported by the transport unit 10. As shown in FIG. 2, the ejection head 20 is a full-line head that covers the entire width direction of the base material 5 transported by the transport unit 10. Therefore, the ejection head 20 is fixedly installed without being scanned along the width direction of the substrate 5.

  A plurality of nozzles (not shown) are formed on the bottom surface (the surface facing the substrate 5) of the discharge head 20. The plurality of nozzles are arranged and formed in a grid pattern on the bottom surface of the ejection head 20, for example. The number and interval (pitch) at which the plurality of nozzles are arranged are not particularly limited, and can be set appropriately.

  Each of the nozzles of the discharge head 20 is a so-called inkjet nozzle. In this embodiment, pure water droplets supplied from a pure water supply source (not shown) are generated and discharged. The nozzles of the ejection head 20 may be of a piezo type that applies a voltage to a piezo element (piezoelectric element) and deforms it to eject pure water droplets, or by energizing a heater to heat the pure water. A thermal system that discharges pure water droplets may be used. The pure water supplied from the pure water supply source is preferably deionized water from which ions are removed by an ion exchange resin membrane.

  The discharge head 20 can selectively supply pure water in accordance with a predetermined pattern shape by discharging pure water droplets from some of the plurality of nozzles under the control of the control unit 9. The ejection pattern is appropriately determined by the control unit 9.

  The irradiation unit 50 is provided on the downstream side of the ejection head 20 along the conveyance direction of the substrate 5 by the conveyance unit 10 and above the substrate 5 to be conveyed. The irradiation unit 50 includes a plurality of flash lamps FL (three for convenience of illustration in FIGS. 1 and 2, but is not limited to this) and a reflector 52 provided so as to cover the entire upper part. And comprising. The irradiation unit 50 irradiates the base material 5 conveyed by the conveyance unit 10 with flash light from the flash lamp FL.

  The flash lamp FL is a rod-shaped lamp having a long cylindrical shape. In the present embodiment, a xenon flash lamp is used as the flash lamp FL. The xenon flash lamp FL has a rod-shaped glass tube (discharge tube) in which xenon gas is sealed and an anode and a cathode connected to a capacitor at both ends thereof, and an outer peripheral surface of the glass tube. A trigger electrode. Since xenon gas is an electrical insulator, electricity does not flow into the glass tube under normal conditions even if electric charges are accumulated in the capacitor. However, when the insulation is broken by applying a high voltage to the trigger electrode, the electricity stored in the capacitor instantaneously flows into the glass tube due to the discharge between the electrodes at both ends, and the excitation of the xenon atoms or molecules at that time Light is emitted. In such a xenon flash lamp FL, the electrostatic energy stored in the condenser in advance is converted into an extremely short light pulse of 0.1 to 100 milliseconds, which is extremely in comparison with a continuously lit lamp. It has the feature that it can irradiate strong light.

  In addition, the reflector 52 is provided above the plurality of flash lamps FL so as to cover all of them. The basic function of the reflector 52 is to reflect downward the flash light emitted from the plurality of flash lamps FL.

  The controller 9 controls the various operating mechanisms provided in the heat treatment apparatus 1a. The configuration of the control unit 9 as hardware is the same as that of a general computer. That is, the control unit 9 stores a CPU that performs various arithmetic processes, a ROM that is a read-only memory that stores basic programs, a RAM that is a readable and writable memory that stores various information, control software, data, and the like. It is configured with a magnetic disk. The processing in the heat treatment apparatus 1a proceeds by the CPU of the control unit 9 executing a predetermined processing program.

  In addition to the above configuration, the heat treatment apparatus 1a may be appropriately provided with various components. For example, a mechanism for supplying an inert gas such as nitrogen gas to a region irradiated with flash light from the irradiation unit 50 may be provided.

  Next, the processing operation in the heat treatment apparatus 1a having the above configuration will be described. The base material 5 fed from the feed roller 11 is taken up by the take-up roller 12, whereby the belt-like base material 5 is conveyed. FIG. 3 is a cross-sectional view showing the structure of the substrate 5. As shown in the figure, a functional layer 7 is laminated on a part of the surface of the substrate 5. The base material 5 is a resin film. Polyethylene naphthalate (PEN), polyethylene terephthalate (PET), or the like can be employed as the resin for the base material 5. Since resin materials such as PEN and PET are soft and flexible, if this is used as the base material 5, the base material 5 can be conveyed from the feed roller 11 to the take-up roller 12 by a roll-to-roll method. . In the first embodiment, the transport unit 10 transports the base material 5 with the surface of the base material 5 on which the functional layer 7 is formed facing upward. The “surface” of the base material 5 is one surface (first surface) of the two surfaces of the base material 5, and the “back surface” is the other surface (second surface) on the opposite side. . That is, the front surface and the back surface of the base material 5 are notations for simply identifying both surfaces of the base material 5, and any specific surface is not limited to the front surface or the back surface.

  The functional layer 7 is, for example, a silver (Ag) nano-ink layer for electrode formation. The base material 5 on which the functional layer 7 is formed is transported by the transport unit 10, and the functional layer 7 is heated by irradiating the base material 5 with flash light from the irradiation unit 50. An electrode is formed on the substrate 5 by heating the functional layer 7 of the nano ink to a target processing temperature (temperature increase target temperature). That is, the functional layer 7 is an object to be heated in the heat treatment apparatus 1a.

  The target processing temperature of the functional layer 7 is about 180 ° C. if the functional layer 7 is a silver nano ink. On the other hand, the heat-resistant temperature of the base material 5 is about 120 ° C. if the base material 5 is PEN or PET. The heat resistant temperature of the base material 5 is a limit temperature at which the base material 5 is thermally damaged when the temperature is exceeded. Thus, in this embodiment, the target processing temperature of the functional layer 7 is higher than the heat resistant temperature of the base material 5. Accordingly, when the flash light is irradiated from the irradiation unit 50 to such an extent that the functional layer 7 is heated to the target processing temperature, the base material 5 is heated beyond the heat resistance temperature, and the base material 5 is thermally damaged. On the contrary, if the flash light is irradiated from the irradiation unit 50 to such an extent that the substrate 5 is not thermally damaged, the functional layer 7 cannot be raised to the target processing temperature.

  Therefore, in the present embodiment, pure water droplets are supplied from the ejection head 20 to a partial region of the substrate 5 before the flash light irradiation. As shown in FIG. 3, the functional layer 7 is not formed on the entire surface of the substrate 5, but is formed on a part of the surface. The region where the functional layer 7 is formed (the surface of the functional layer 7) is a temperature increase target region that requires a temperature increase to the target processing temperature. On the other hand, the surface region of the base material 5 on which the functional layer 7 is not formed is a region that does not require a temperature increase. The temperature increase unnecessary region includes a temperature increase suppression region where temperature increase must be suppressed because heat damage occurs, and a region where heat damage does not occur but process temperature increase is unnecessary. . For example, when a resin film having excellent heat resistance is laminated on a part of the surface of the PET substrate 5, the surface region of the substrate 5 on which the functional layer 7 is not formed is a temperature rise suppression region. Thus, the surface region of the resin film is a region that does not need to be heated in the process. And it is set as the temperature increase unnecessary area | region including both these area | regions.

  The ejection head 20 supplies pure water droplets to a supply region including at least the temperature rise suppression region of the substrate 5. In other words, the ejection head 20 may supply pure water droplets only to the temperature rise suppression region excluding the region where the temperature rise is not necessary in the process, or the temperature rise in the process with the temperature rise suppression region. Alternatively, the pure water droplets may be supplied to the entire area where the temperature increase is unnecessary, including the area where the temperature is unnecessary. However, the ejection head 20 does not supply pure water droplets to the temperature increase target region in which the functional layer 7 is formed.

  The ejection head 20 includes a plurality of inkjet nozzles, and can easily eject pure water droplets according to a predetermined pattern shape under the control of the control unit 9. Therefore, the discharge head 20 can selectively supply pure water droplets to a supply region including at least a temperature rise suppression region. Moreover, in 1st Embodiment, the base material 5 is conveyed facing the surface of the base material 5 in which the functional layer 7 was formed upwards, and the discharge head 20 is a pure water to the supply area | region of the surface of the base material 5. Supply droplets. The pure water supply flow rate from the ejection head 20 is such that the pure water droplets adhere to the supply region of the substrate 5.

  The base material 5 to which the pure water droplets are attached is conveyed below the irradiation unit 50 by the conveyance unit 10. The irradiation unit 50 irradiates the base material 5 with flash light from the flash lamp FL. Flash light (including flash light reflected by the reflector 52) emitted from the flash lamp FL is applied to the surface of the substrate 5 on which pure water droplets adhere. The flash light emitted from the flash lamp FL is a very short and strong flash light whose irradiation time is about 0.1 milliseconds or more and 100 milliseconds or less, in which electrostatic energy stored in advance is converted into an extremely short light pulse. .

  A functional layer 7 is formed on a part of the surface of the substrate 5. The flash light emitted from the flash lamp FL is applied to the entire surface of the substrate 5, that is, both the functional layer 7 and the temperature unnecessary region. The functional layer 7 that has absorbed the flash light is heated to a target processing temperature (about 180 ° C. in this embodiment), and necessary heat treatment is performed. On the other hand, in the supply region of the base material 5 (the region including at least the temperature increase suppression region in the temperature increase unnecessary region), the base material 5 is heated by absorbing the flash light. Since the water droplets adhere, the temperature rise exceeding 100 ° C. is suppressed.

  As is well known, the boiling point of water at normal pressure is about 100 ° C., and when the supply region reaches 100 ° C., the adhering pure water boils (evaporates from inside the droplet). When the pure water droplets evaporate, the evaporation heat is absorbed from the supply region of the substrate 5. For this reason, the temperature increase in the supply region of the base material 5 is suppressed, and the temperature of the supply region is hardly raised to 100 ° C. or more while the pure water droplets remain. Since the irradiation time of the flash light (that is, the flash heating time) is an extremely short time of 100 milliseconds or less, it is difficult for the pure water droplets adhering to the supply region to evaporate completely and continue during the heat treatment. Temperature rise can be suppressed.

  In this embodiment, since the heat resistant temperature of the base material 5 is about 120 ° C., the temperature of the supply region of the base material 5 is suppressed to the heat resistant temperature or lower during flash heating. As a result, heat damage to the base material 5 is prevented.

  Since the flash light irradiation time is extremely short, the temperature of the functional layer 7 is also rapidly lowered in a short time after reaching the target processing temperature. Then, the base material 5 that has passed through the irradiation unit 50 is taken up by the take-up roller 12. In this way, the processing in the heat treatment apparatus 1 is completed. Alternatively, the substrate 5 may be stepped by a certain length by the conveying unit 10 (repeating conveyance and stopping), and the flashing light may be irradiated from the irradiation unit 50 to the substrate 5 in the stopped state.

  In the first embodiment, water that evaporates at a temperature lower than the target temperature increase (about 180 ° C.) of the functional layer 7 that is the heating object needs to be suppressed at least in the base material 5. The functional layer 7 is heated by irradiating flash light from the flash lamp FL in a state of being selectively supplied to the supply region including the temperature increase suppression region. While the functional layer 7 is heated to the target temperature rise by flash light irradiation, the temperature rises above the boiling point of water in order to absorb the heat of evaporation when water evaporates in the temperature rise suppression region of the substrate 5. The temperature is suppressed. As a result, the functional layer 7 formed on the base material 5 can be heated to the target temperature without damaging the base material 5.

  The boiling point of water is lower than the temperature increase target temperature of the functional layer 7 and lower than the temperature (about 120 ° C.) at which the substrate 5 is thermally damaged. Therefore, even if the water adhering to the base material 5 is heated to the boiling point by irradiation with flash light, the temperature of the base material 5 is not further increased, and the base material 5 is surely damaged. Can be prevented.

Second Embodiment
Next, a second embodiment of the present invention will be described. FIG. 4 is a diagram illustrating an overall configuration of a heat treatment apparatus 1b according to the second embodiment. In FIG. 4, the same elements as those of the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1b of the second embodiment is different from the heat treatment apparatus 1a of the first embodiment in that a thickener addition unit 21 that increases the viscosity of pure water supplied from the ejection head 20 is provided.

  The thickener addition unit 21 adds a thickener to the pure water supplied to the discharge head 20 from a pure water supply source (not shown). As the thickener added by the thickener addition unit 21, for example, polyvinyl alcohol (PVA) that increases the viscosity of water can be used. As the thickener, a chemical that increases the viscosity of water, such as glycerin or a gelling agent, can be used instead of PVA.

  The ejection head 20 generates water droplets with increased viscosity by adding a thickener, and supplies the water droplets to a supply region including at least a temperature rise suppression region of the substrate 5. In the second embodiment, since the viscosity of the water droplets adhering to the supply region of the base material 5 is high, the flow of the liquid droplets can be prevented even when the base material 5 is transported by the transport unit 10. it can. Therefore, it is possible to prevent problems (for example, defective processing of the functional layer 7) due to the liquid droplets coming into contact with the functional layer 7 in advance.

  The remaining configuration and processing operations of the second embodiment except for adding a thickener are the same as those of the first embodiment. Even in the second embodiment, the functional layer 7 is heated to the target temperature rise by flash light irradiation, while absorbing heat of evaporation when water evaporates in the temperature rise suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, damage to the substrate 5 can be prevented, and the functional layer 7 formed on the substrate 5 can be raised to the target temperature.

  Moreover, in 2nd Embodiment, since the viscosity of a droplet is raised with the thickener, the malfunction resulting from a droplet flowing and contacting the functional layer 7 can be prevented.

<Third Embodiment>
Next, a third embodiment of the present invention will be described. FIG. 5 is a diagram illustrating an overall configuration of a heat treatment apparatus 1c according to the third embodiment. In FIG. 5, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1c according to the third embodiment is different from the heat treatment apparatus 1a according to the first embodiment in that it includes a hydrophilic treatment section 22 and a water repellent treatment section 23.

  The hydrophilic treatment unit 22 and the water repellent treatment unit 23 are provided on the upstream side of the ejection head 20 along the conveyance direction of the base material 5 by the conveyance unit 10. The hydrophilic treatment unit 22 is provided on the most upstream side, and the water repellent treatment unit 23 is provided between the hydrophilic treatment unit 22 and the ejection head 20.

  The hydrophilic treatment part 22 performs surface modification on the base material 5 to impart hydrophilicity. The hydrophilic treatment unit 22 imparts hydrophilicity to the surface of the substrate 5 by, for example, plasma treatment or ultraviolet irradiation. Alternatively, the hydrophilic treatment unit 22 may impart hydrophilicity to the surface of the substrate 5 by corona discharge treatment.

  The water repellent treatment unit 23 applies a water repellent material to the surface of the substrate 5 to impart water repellency. The water repellent treatment unit 23 imparts water repellency by, for example, applying a fluorine coating agent to the surface of the substrate 5. Hexamethyldisilazane (HMDS) may be used as the water repellent material.

  When processing in 3rd Embodiment, the hydrophilization process part 22 performs a hydrophilization process to the supply area | region including the temperature rising suppression area | region at least among the base materials 5, and provides hydrophilicity. Specifically, for example, the supply region is modified to impart hydrophilicity by masking the region other than the supply region on the surface of the substrate 5 and performing plasma treatment or the like.

  Subsequently, the water-repellent treatment unit 23 performs a water-repellent treatment around the supply region to which hydrophilicity is imparted, and surrounds the supply region with the water-repellent region. Specifically, for example, the supply region of the surface of the substrate 5 is masked to perform a water-repellent material coating process so that the supply region is surrounded by the water-repellent region.

  FIG. 6 is a plan view of the substrate 5 that has been subjected to a hydrophilic treatment and a water repellent treatment. A functional layer 7 is formed on a part of the surface of the substrate 5. A part of the surface area (the temperature increase unnecessary area) of the base material 5 where the functional layer 7 is not formed is the supply area 3. In the third embodiment, hydrophilicity is imparted to the supply region 3 by the hydrophilic treatment unit 22, and the water repellent treatment unit 23 performs water repellent treatment around the supply region 3 so that the supply region 3 is surrounded by the water repellent region 6. Yes.

  When pure water droplets are supplied to the supply region 3 from the ejection head 20, the droplets remain in the supply region 3 and do not easily flow into the water-repellent region 6. Therefore, even when the base material 5 is transported by the transport unit 10, it is possible to prevent the liquid droplets from flowing, and it is possible to prevent problems caused by the liquid droplets coming into contact with the functional layer 7.

  The remaining configuration and processing operation of the third embodiment excluding the hydrophilic treatment and the water repellent treatment are the same as those of the first embodiment. Even in the third embodiment, the functional layer 7 is heated to the temperature increase target temperature by flash light irradiation, and absorbs heat of evaporation when water evaporates in the temperature increase suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, the functional layer 7 formed on the base material 5 can be heated to the target temperature without damaging the base material 5.

  In the third embodiment, the surface modification prevents the droplets from flowing out of the supply region, so that the problems caused by the droplets flowing and contacting the functional layer 7 can be prevented. Can do. In the third embodiment, both the hydrophilization treatment and the water repellency treatment are performed. However, pure water droplets are prevented from flowing out of the supply region by only one of the treatments. be able to. However, it is possible to more reliably suppress the flow of droplets by performing both the hydrophilic treatment and the water repellent treatment.

<Fourth embodiment>
Next, a fourth embodiment of the present invention will be described. FIG. 7 is a diagram illustrating an overall configuration of a heat treatment apparatus 1d according to the fourth embodiment. In FIG. 7, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1d according to the fourth embodiment is different from the heat treatment apparatus 1a according to the first embodiment in that the heat treatment apparatus 1d includes a cooling unit 30 that cools the base material 5 on which pure water droplets adhere.

  The cooling unit 30 is provided between the ejection head 20 and the irradiation unit 50 along the conveyance direction of the base material 5 by the conveyance unit 10. The cooling unit 30 cools the base material 5 passing through the interior to below 0 ° C. (below freezing point). As the cooling unit 30, for example, a known refrigerator using a heat pump can be used.

  In the fourth embodiment, the pure water droplets supplied from the ejection head 20 are cooled to less than 0 ° C. when the base material 5 attached to the supply region passes through the cooling unit 30, and the pure water droplets. Solidifies. That is, pure water droplets become solid-phase ice. When flash light is emitted from the flash lamp FL to the base material 5 on which ice has adhered to the supply region, the functional layer 7 is heated to the target processing temperature, while the temperature increase in the supply region including the temperature increase suppression region is significantly suppressed. The In the supply region of the base material 5 at the time of flash light irradiation, first, the heat of fusion when the ice melts to become water is absorbed, and further the heat of evaporation when the water evaporates is absorbed. Therefore, the temperature of the supply region of the base material 5 is surely suppressed below the heat resistant temperature.

  The remaining configuration and processing operation of the fourth embodiment excluding the solidification of the droplets by the cooling unit 30 are the same as those of the first embodiment. Even in the case of the fourth embodiment, the functional layer 7 is heated to the target temperature rise by flash light irradiation, and absorbs heat of melting when the ice melts in the temperature rise suppression region of the substrate 5. Therefore, the temperature rise is remarkably suppressed. As a result, the functional layer 7 formed on the base material 5 can be heated to the target temperature without damaging the base material 5.

<Fifth Embodiment>
Next, a fifth embodiment of the present invention will be described. FIG. 8 is a diagram illustrating an overall configuration of a heat treatment apparatus 1e according to the fifth embodiment. In FIG. 8, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1e according to the fifth embodiment is different from the heat treatment apparatus 1a according to the first embodiment in that the heat treatment apparatus 1e includes a heating unit 31 that heats the base material 5 to which droplets adhere.

  In the fifth embodiment, a liquid containing a solution obtained by dissolving paradichlorobenzene in alcohol is supplied to the ejection head 20. The ejection head 20 generates droplets of the solution and supplies them to the supply region of the base material 5.

  The heating unit 31 is provided between the ejection head 20 and the irradiation unit 50 along the conveyance direction of the base material 5 by the conveyance unit 10. The heating unit 31 heats the base material 5 passing through the inside thereof, and evaporates and removes alcohol from the solution droplets attached to the supply region. By removing alcohol as the solvent from the solution adhering to the supply region of the substrate 5, paradichlorobenzene as a solute is deposited in the supply region. As the heating unit 31, for example, a known hot air drying furnace can be used.

  In the fifth embodiment, when the base material 5 on which the droplets of the solution supplied from the ejection head 20 are attached to the supply region passes through the heating unit 31, alcohol as a solvent is removed from the solution to the supply region. The solute paradichlorobenzene is deposited. Paradichlorobenzene is a solid phase substance that has sublimability at room temperature. That is, the sublimation point of paradichlorobenzene is lower than the target temperature rise of the functional layer 7 and lower than the temperature at which the substrate 5 is thermally damaged. When paradichlorobenzene undergoes phase transition directly from the solid phase to the gas phase by sublimation, the sublimation heat is absorbed from the supply region of the substrate 5.

  When the base material 5 on which the solid phase paradichlorobenzene is deposited in the supply region is irradiated with flash light from the flash lamp FL, the functional layer 7 is heated to the target processing temperature, while in the supply region including the temperature increase suppression region, paradichlorobenzene is used. The temperature rise is suppressed by absorbing the sublimation heat when sublimating. Therefore, the temperature of the supply region of the base material 5 is suppressed to the heat resistant temperature or lower.

  The remaining configuration and processing operation of the fifth embodiment excluding the solution supplied from the ejection head 20 and precipitation by the heating unit 31 are the same as those of the first embodiment. Even in the fifth embodiment, the functional layer 7 is heated to the target temperature increase by flash light irradiation, while the sublimation heat is absorbed when paradichlorobenzene sublimates in the temperature increase suppression region of the substrate 5. Therefore, the temperature rise is suppressed. As a result, the functional layer 7 formed on the base material 5 can be heated to the target temperature without damaging the base material 5.

<Sixth Embodiment>
Next, a sixth embodiment of the present invention will be described. FIG. 9 is a diagram illustrating an overall configuration of a heat treatment apparatus 1f according to the sixth embodiment. In FIG. 9, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1 f of the sixth embodiment is different from the heat treatment apparatus 1 a of the first embodiment in that a transfer unit 60 is provided instead of the ejection head 20.

  The transfer unit 60 includes a plate cylinder 61 and a supply roller 62. The plate cylinder 61 is a cylindrical drum, and its length along the axial direction is substantially the same as the width of the substrate 5. The plate cylinder 61 is rotated around the central axis of the cylinder by a rotation drive mechanism (not shown). A printing plate 63 is mounted on the outer peripheral surface of the plate cylinder 61. The plate 63 is, for example, an aluminum plate-like member, and a pattern corresponding to the supply region of the substrate 5 is formed on the surface thereof. The printing plate 63 may be a relief plate, an intaglio plate, a stencil plate, or a lithographic plate.

  The supply roller 62 is a cylindrical drum, and its length along the axial direction is the same as that of the plate cylinder 61. Pure water is uniformly supplied to the outer peripheral surface of the supply roller 62 from a pure water supply source (not shown). When the supply roller 62 comes into contact with the plate 63 mounted on the plate cylinder 61, pure water is selectively placed as an ink on the pattern of the plate 63. The pure water placed on the printing plate 63 is supplied to the substrate 5 by bringing the printing plate 63 into contact with the surface of the substrate 5 while the plate cylinder 61 rotates in synchronization with the conveyance of the substrate 5. It will be transferred to the area.

  The remaining configuration and processing operation of the sixth embodiment excluding the aspect of supplying pure water to the substrate 5 are the same as those of the first embodiment. In the sixth embodiment, pure water is selectively supplied to the supply region of the substrate 5 by a so-called printing technique using the plate cylinder 61 and the supply roller 62. The base material 5 supplied with pure water is irradiated with flash light from the flash lamp FL of the irradiation unit 50. Even in the sixth embodiment, the functional layer 7 is heated to the temperature increase target temperature by flash light irradiation, and absorbs heat of evaporation when water evaporates in the temperature increase suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, damage to the substrate 5 can be prevented, and the functional layer 7 formed on the substrate 5 can be raised to the target temperature.

<Seventh embodiment>
Next, a seventh embodiment of the present invention will be described. FIG. 10 is a diagram illustrating an overall configuration of a heat treatment apparatus 1g according to the seventh embodiment. In FIG. 10, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1g of the seventh embodiment is different from the heat treatment apparatus 1a of the first embodiment in that an air knife 70 is provided.

  The air knife 70 is provided on the downstream side of the irradiation unit 50 along the conveyance direction of the substrate 5 by the conveyance unit 10 and above the substrate 5 to be conveyed. The air knife 70 discharges air in a curtain shape at a high pressure. Even with flash light irradiation from the flash lamp FL, the pure water adhering to the supply region of the substrate 5 may remain without being completely evaporated. After the flash light irradiation process from the flash lamp FL, the air knife 70 blows away moisture remaining in the supply area even after the flash heating by blowing high-pressure air on the surface of the substrate 5 in a curtain shape. To do.

  The remaining configuration and processing operation of the seventh embodiment except that the air knife 70 is provided and water remaining after flash heating is removed are the same as in the first embodiment. Even in the case of the seventh embodiment, the functional layer 7 is heated to the temperature increase target temperature by the flash light irradiation, and absorbs heat of evaporation when water evaporates in the temperature increase suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, damage to the substrate 5 can be prevented, and the functional layer 7 formed on the substrate 5 can be raised to the target temperature.

  Further, in the seventh embodiment, since the moisture remaining after flash heating is removed by the air knife 70, it is possible to prevent problems caused by such residual moisture coming into contact with the functional layer 7. .

<Eighth Embodiment>
Next, an eighth embodiment of the present invention will be described. FIG. 11 is a diagram illustrating an overall configuration of a heat treatment apparatus 1h according to the eighth embodiment. In FIG. 11, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1h according to the eighth embodiment is different from the heat treatment apparatus 1a according to the first embodiment in the arrangement relationship between the ejection head 20 and the irradiation unit 50.

  In the eighth embodiment, the transport unit 10 transports the base material 5 with the surface of the base material 5 on which the functional layer 7 is formed facing downward. The discharge head 20 is provided above the base material 5 conveyed by the conveyance part 10 similarly to 1st Embodiment. On the other hand, as shown in FIG. 11, the irradiation unit 50 is provided on the downstream side of the ejection head 20 along the conveyance direction of the substrate 5 by the conveyance unit 10 and below the substrate 5 to be conveyed. The irradiation unit 50 is provided upside down with respect to the first embodiment, and the reflector 52 is provided so as to cover the plurality of flash lamps FL. The irradiation unit 50 of the eighth embodiment irradiates flash light upward from the flash lamp FL.

  In the eighth embodiment, pure water droplets are selectively supplied from the ejection head 20 to the supply region on the back surface of the base material 5 that is transported by the transport unit 10. In other words, pure water droplets are supplied to the back surface opposite to the surface of the substrate 5 on which the functional layer 7 is formed. For this reason, the malfunction by a pure water contacting the functional layer 7 can be prevented reliably.

  Flash light is irradiated from the flash lamp FL to the base material 5 on which the pure water droplets adhere to the back surface. The flash light is applied to the surface of the substrate 5 from below the substrate 5. The functional layer 7 formed on the surface of the substrate 5 absorbs flash light and raises the temperature to the target processing temperature. On the other hand, the supply region of the base material 5 also rises in temperature by absorbing flash light. However, since the pure water droplets adhere to the supply region, the temperature increase exceeding 100 ° C. is suppressed. The

  The remaining configuration and processing operation of the eighth embodiment except for supplying pure water droplets to the back surface of the substrate 5 are the same as those of the first embodiment. Even in the case of the eighth embodiment, the functional layer 7 is heated to the temperature increase target temperature by flash light irradiation, and absorbs the heat of evaporation when water evaporates in the temperature increase suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, damage to the substrate 5 can be prevented, and the functional layer 7 formed on the substrate 5 can be raised to the target temperature.

  In the eighth embodiment, since pure water droplets are supplied to the back surface opposite to the surface of the base material 5 on which the functional layer 7 is formed, the pure water is in contact with the functional layer 7. It is possible to prevent problems caused by However, since the flash light is irradiated on the surface of the base material 5, the temperature rise suppression effect is higher when pure water is directly supplied to the surface of the base material 5 as in the first embodiment. Therefore, when the base material 5 is thick and heat conduction from the front surface to the back surface hardly occurs, it is preferable to supply pure water directly to the surface of the base material 5 as in the first embodiment.

<Ninth Embodiment>
Next, a ninth embodiment of the present invention will be described. FIG. 12 is a diagram illustrating an overall configuration of a heat treatment apparatus 1i according to the ninth embodiment. In FIG. 12, the same elements as those in the first embodiment are denoted by the same reference numerals. In the ninth embodiment, pure water is supplied to a film different from the substrate 5, and the film is bonded to the back surface of the substrate 5.

  As in the first embodiment, the base material 5 having the functional layer 7 formed on the surface is transported by the transport unit 10. The conveyance part 10 is conveying the surface of the base material 5 in which the functional layer 7 was formed facing the upper side. A heat treatment apparatus 1 i according to the ninth embodiment includes a film delivery roller 81 and a pair of bonding rollers 82. The film delivery roller 81 sends out a resin carrying film 85. The support film 85 is a belt-like film made of a resin material such as PEN or PET, like the substrate 5.

  In the ninth embodiment, pure water droplets are ejected from the ejection head 20 onto the carrier film 85 delivered from the film delivery roller 81. The discharge head 20 discharges pure water droplets according to the pattern shape of the supply region of the base material 5. The carrier film 85 to which the pure water droplets adhere and the substrate 5 are bonded together by a pair of bonding rollers 82.

  FIG. 13 is a view showing a state in which the supporting film 85 supporting pure water is bonded to the base material 5. A supporting film 85 supporting pure water is brought close to the back surface of the substrate 5 by a pair of bonding rollers 82 and bonded together. Since pure water droplets are ejected onto the support film 85 in accordance with the pattern shape of the supply region of the base material 5, the support film 85 is bonded to the back surface of the base material 5, so The pure water 88 is selectively brought into contact with the supply area on the back surface and supplied. Therefore, similarly to the eighth embodiment, it is possible to prevent problems caused by contact of pure water with the functional layer 7.

  Flash light is emitted from the flash lamp FL to the substrate 5 on which the support film 85 supporting pure water is bonded. The functional layer 7 formed on the surface of the substrate 5 absorbs flash light and raises the temperature to the target processing temperature. On the other hand, the supply region of the base material 5 also rises in temperature by absorbing flash light, but since the pure water droplets are in contact with the supply region, the temperature increase exceeding 100 ° C. is suppressed. The

  The remaining configuration and processing operation of the ninth embodiment except that pure water is supplied to the back surface of the substrate 5 by the support film 85 are the same as those of the first embodiment. Even in the ninth embodiment, the functional layer 7 is heated to the target temperature rise by flash light irradiation, while absorbing heat of evaporation when water evaporates in the temperature rise suppression region of the substrate 5. Therefore, the temperature rise exceeding the boiling point of water is suppressed. As a result, damage to the substrate 5 can be prevented, and the functional layer 7 formed on the substrate 5 can be raised to the target temperature.

  Moreover, in 9th Embodiment, since the pure water is supplied to the back surface on the opposite side to the surface of the base material 5 in which the functional layer 7 was formed, the malfunction by a pure water contacting with the functional layer 7 is carried out. Can be prevented.

<Tenth Embodiment>
Next, a tenth embodiment of the present invention will be described. FIG. 14 is a diagram illustrating an overall configuration of a heat treatment apparatus 1j according to the tenth embodiment. In FIG. 14, the same elements as those of the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1j according to the tenth embodiment is different from the heat treatment apparatus 1a according to the first embodiment in that a so-called single wafer method is employed in which the base material is conveyed one sheet at a time instead of the roll-to-roll method. Is a point.

  As will be described later, in the tenth embodiment, a sheet-like base material 500 is placed on a stage 101, and the base material 500 is conveyed by the stage 101. For the highly flexible sheet-like substrate 500, the method of this embodiment is suitable.

  The heat treatment apparatus 1j includes a moving mechanism 100 that moves the substrate 500, a discharge head 20 that supplies pure water droplets to the substrate 500, an irradiation unit 50 that irradiates the substrate 500 with flash light, and a substrate 500 that moves the substrate 500. Supply unit 103 and a discharge unit 104 that receives the substrate 500 from the moving mechanism 100. In addition, the heat treatment apparatus 1j includes a control unit 9 that controls various operation mechanisms provided in the apparatus to advance the process.

  The moving mechanism 100 circulates and conveys the plurality of stages 101 held by the guide 102 by rotating the annular guide 102 clockwise on the paper surface of FIG. As a mechanism for moving the annular guide 102 by the moving mechanism 100, for example, a known belt driving mechanism that drives a belt (not shown) provided in the guide 102 can be used. Each of the plurality of stages 101 sucks and holds one sheet-like base material 500.

  The supply unit 103 supplies a single sheet-like base material 500 to the stage 101 conveyed by the moving mechanism 100. The sheet-like substrate 500 delivered from the supply unit 103 to the stage 101 is moved from the ejection head 20 toward the irradiation unit 50 in the right direction on the paper surface of FIG. The discharge unit 104 receives the processed substrate 500 from the stage 101 conveyed by the moving mechanism 100.

  The substrate 500 is a sheet-like substrate having a cross-sectional structure similar to that shown in FIG. That is, also in the tenth embodiment, the functional layer 7 is formed on a part of the surface of the sheet-like base material 500, and the surface region of the base material 5 on which the functional layer 7 is not formed rises in temperature. A temperature rise suppression region that requires suppression of temperature rise due to thermal damage and a temperature rise unnecessary region that includes a region that does not cause thermal damage but do not require temperature rise in terms of process.

  The discharge head 20 supplies fine droplets of pure water to a supply region including at least a temperature rise suppression region of the sheet-like substrate 500. The functional layer 7 is heated by irradiating flash light from the flash lamp FL to the base material 500 in a state where water is selectively supplied to the supply region. While the functional layer 7 is heated to the target temperature rise by flash light irradiation, the temperature rises above the boiling point of water in order to absorb the heat of evaporation when water evaporates in the temperature rise suppression region of the substrate 500. The temperature is suppressed. As a result, the functional layer 7 formed on the base material 500 can be heated to the target temperature without damaging the base material 500.

  In this way, the single wafer method is adopted instead of the roll-to-roll method, and heat treatment is performed not only on the long base material 5 but also on a plurality of sheet-like base materials 500 by the technique according to the present invention. Can do.

<Eleventh embodiment>
Next, an eleventh embodiment of the present invention will be described. FIG. 15 is a diagram illustrating an overall configuration of a heat treatment apparatus 1k according to the eleventh embodiment. In FIG. 15, the same elements as those in the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 1k according to the eleventh embodiment is different from the heat treatment apparatus 1a according to the first embodiment in that a so-called single wafer method is employed in which the base material is conveyed one sheet at a time instead of the roll-to-roll method. Is a point.

  Similarly, in the tenth embodiment that adopts the single wafer method, the sheet-like base material 500 is placed on the stage 101 and conveyed, but in the eleventh embodiment, by a roller that directly contacts the main surface of the base material 500. The sheet-like base material 500 is conveyed. For the highly rigid sheet-like substrate 500 such as a glass substrate, the method of this embodiment is suitable.

  The heat treatment apparatus 1 k includes a moving mechanism 110 that moves the base material 500, a discharge head 20 that supplies water droplets of pure water to the base material 500, an irradiation unit 50 that irradiates the base material 500 with flash light, and a base material 500 that moves the base material 500. Supply unit 112 and a discharge unit 113 that receives the substrate 500 from the moving mechanism 100. In addition, the heat treatment apparatus 1k includes a control unit 9 that controls various operation mechanisms provided in the apparatus to advance the process.

  The moving mechanism 110 includes a plurality of rollers 111 arranged in a line along the horizontal direction and a roller rotation driving mechanism (for example, a motor) (not shown) that rotates them. Each of the plurality of rollers 111 is in contact with a main surface opposite to the main surface of the substrate 500 facing the ejection head 20. The moving mechanism 100 conveys the sheet-like substrate 500 along the horizontal direction by rotating the plurality of rollers 111.

  The supply unit 112 supplies the sheet-like base material 500 to the roller 111 of the moving mechanism 110. The sheet-like base material 500 supplied from the supply unit 112 is moved from the ejection head 20 toward the irradiation unit 50 in the right direction on the paper surface of FIG. The discharge unit 113 receives the processed base material 500 conveyed by the moving mechanism 110.

  The substrate 500 is a sheet-like substrate having a cross-sectional structure similar to that shown in FIG. That is, also in the eleventh embodiment, when the functional layer 7 is formed on a part of the surface of the sheet-like base material 500 and the surface area of the base material 5 where the functional layer 7 is not formed rises in temperature. A temperature rise suppression region that requires suppression of temperature rise due to thermal damage and a temperature rise unnecessary region that includes a region that does not cause thermal damage but do not require temperature rise in terms of process.

  The discharge head 20 supplies fine droplets of pure water to a supply region including at least a temperature rise suppression region of the sheet-like substrate 500. The functional layer 7 is heated by irradiating flash light from the flash lamp FL to the base material 500 in a state where water is selectively supplied to the supply region. While the functional layer 7 is heated to the target temperature rise by flash light irradiation, the temperature rises above the boiling point of water in order to absorb the heat of evaporation when water evaporates in the temperature rise suppression region of the substrate 500. The temperature is suppressed. As a result, the functional layer 7 formed on the base material 500 can be heated to the target temperature without damaging the base material 500.

  In this way, the single wafer method is adopted instead of the roll-to-roll method, and heat treatment is performed not only on the long base material 5 but also on a plurality of sheet-like base materials 500 by the technique according to the present invention. Can do.

<Twelfth embodiment>
Next, a twelfth embodiment of the present invention will be described. FIG. 16 is a plan view showing an overall configuration of a heat treatment apparatus 11 according to the twelfth embodiment. In FIG. 16, the same elements as those of the first embodiment are denoted by the same reference numerals. The heat treatment apparatus 11 of the twelfth embodiment is different from the heat treatment apparatus 1a of the first embodiment in that it is not a roll-to-roll system, and a substrate is conveyed to each treatment chamber one by one by a robot and sequentially processed. The robot transport system is adopted. In each processing chamber, a water supply process for supplying pure water to the substrate or a flash heating process for irradiating the substrate with flash light is performed.

  As will be described later, in the twelfth embodiment, the substrate is transported to the processing chamber one by one by the robot arm, and the water supply process and the flash heating process are performed independently in each processing chamber. Even if the tact time is significantly different, it can be handled. Further, for the plate-like substrate 500 having high rigidity such as a glass substrate, the method of the present embodiment is suitable.

  The heat treatment apparatus 11 includes a supply unit 122 that supplies an untreated base material 500, a water supply processing chamber 123 for performing pure water supply processing, a flash heat processing chamber 124 for performing flash heat processing, and a base material after processing. 500 and a robot arm 121 that carries the substrate 500 in and out of the processing chambers. The heat treatment apparatus 11 includes a control unit 9 that controls various operation mechanisms provided in the apparatus to advance the process.

  The supply unit 122 includes a shelf that stores a plurality of untreated base materials 500 in multiple stages. Similarly, the discharge unit 125 includes a shelf for storing a plurality of processed substrates 500 in multiple stages.

  In the water supply processing chamber 123, a mounting table (not shown) for mounting the base material 500 and a discharge head 20 for supplying pure water droplets to the base material 500 mounted on the mounting table are provided. ing. The ejection head 20 is slidable back and forth along a direction indicated by an arrow 126 in FIG. Thereby, water droplets of pure water can be supplied from the discharge head 20 to the entire surface of the base material 500 placed on the placement table.

  In the flash heat treatment chamber 124, a mounting table (not shown) for mounting the base material 500 and an irradiation unit 50 for irradiating the base material 500 mounted on the mounting table with flash light are provided. The irradiation unit 50 includes a plurality of flash lamps FL and a reflector (not shown) provided so as to cover the entire upper part of the flash lamps FL.

  As shown in FIG. 16, the robot arm 121 is disposed at the center of the supply unit 122, the discharge unit 125, the water supply processing chamber 123, and the flash heat processing chamber 124. The robot arm 121 can be moved up and down, swiveled, and moved back and forth along the turning radius direction. The robot arm 121 moves relative to the supply unit 122, the discharge unit 125, the water supply processing chamber 123, and the flash heating processing chamber 124. The base material 500 is carried in / out individually.

  The substrate 500 is a sheet-like substrate having a cross-sectional structure similar to that shown in FIG. That is, also in the twelfth embodiment, when the functional layer 7 is formed on a part of the surface of the sheet-like base material 500 and the surface region of the base material 5 where the functional layer 7 is not formed rises in temperature. A temperature rise suppression region that requires suppression of temperature rise due to thermal damage and a temperature rise unnecessary region that includes a region that does not cause thermal damage but do not require temperature rise in terms of process.

  In the processing procedure in the twelfth embodiment, first, the robot arm 121 takes out the untreated base material 500 from the supply unit 122 and carries it into the water supply processing chamber 123. A fine droplet of pure water is supplied to the base material 500 mounted on the mounting table in the water supply processing chamber 123 while the discharge head 20 moves. At this time, the ejection head 20 supplies fine droplets of pure water to the supply region including at least the temperature rise suppression region of the substrate 500.

  Next, the robot arm 121 unloads the base material 500 from the water supply processing chamber 123 and loads it into the flash heat processing chamber 124. The functional layer 7 is heated by irradiating the base material 500 mounted on the mounting table in the flash heat treatment chamber 124 with flash light from the flash lamp FL.

  Thereafter, the robot arm 121 carries the substrate 500 out of the flash heat treatment chamber 124 and stores it in the discharge unit 125. As described above, a series of processes in the twelfth embodiment is completed.

  Also in the twelfth embodiment, the flash layer is irradiated with flash light in a state where fine droplets of pure water are supplied to the supply region including at least the temperature rise suppression region of the base material 500, so that the functional layer 7 is raised by flash light irradiation. While the temperature is raised to the temperature target temperature, the temperature rise exceeding the boiling point of water is suppressed in order to absorb the heat of evaporation when water evaporates in the temperature rise suppression region. As a result, the functional layer 7 formed on the base material 500 can be heated to the target temperature without damaging the base material 500.

  As described above, the robot conveyance method is adopted instead of the roll-to-roll method, and the plate-like substrate 500 can be heat-treated by the technique according to the present invention.

<13th Embodiment>
Next, a thirteenth embodiment of the present invention is described. FIG. 17 is an external perspective view of a heat treatment apparatus 1m according to the thirteenth embodiment. This heat treatment apparatus 1m supplies pure water on a plate-like substrate 500 by an ink jet method, and then performs heating by flash light. The base material 500 can be employed as long as it is a plate-like or sheet-like base material regardless of the presence or absence of plasticity.

  The heat treatment apparatus 1 m includes a main body 200 and a control unit 9. The main body 200 has a moving mechanism 130 that moves the base material 500 in a Y direction (hereinafter, also referred to as “main scanning direction”) parallel to the base material 500, and a fine droplet of pure water toward the moved base material 500. A discharge head 201 for discharging, and a light source unit 202 for introducing flash light into the discharge head 201 are provided. The control unit 9 controls the moving mechanism 130, the ejection head 201, and the light source unit 202.

  The moving mechanism 130 includes a stage 133 and a drive mechanism for the stage 133 accommodated in the base 131. A substrate 500 is held on the stage 133. The moving mechanism 130 moves the stage 133 along the Y direction by the driving mechanism. The position of the stage 133 in the Y direction with respect to the base 131 is detected by a position detection module 132 installed on the base 131.

  The ejection head 201 can also be moved in the X direction (hereinafter also referred to as “sub-scanning direction”) parallel to the substrate 500 and perpendicular to the Y direction by the moving mechanism 204. The light source unit 202 incorporates a flash lamp. The flash light emitted from the flash lamp is guided from the light source unit 202 to the inside of the ejection head 201 through a light guide line 203 in which a plurality of optical fibers are bundled. The form of flash light irradiation is not limited to this. For example, a flash lamp may be provided on the ejection head 201 itself, and the base 500 may be directly irradiated with flash light from the flash lamp.

  FIG. 18 is a bottom view of the ejection head 201. As shown in FIG. 18, a plurality of heads 211 arranged in a staggered manner and an irradiation unit 213 that irradiates the flash light guided from the light source unit 202 toward the substrate 500 on the bottom surface of the ejection head 201. Provided. In each head 211, a plurality of discharge ports 212 for discharging pure water micro droplets are arranged in a line along the X direction. As a result, the ejection head 201 as a whole has a plurality of ejection ports 212 arranged at a constant pitch in the sub-scanning direction, and is purely placed at an arbitrary position in the sub-scanning direction at each position in the main scanning direction on the substrate 500. Water droplets can be supplied.

  The substrate 500 is a plate-like substrate having the same cross-sectional structure as shown in FIG. That is, also in the thirteenth embodiment, the functional layer 7 is formed on a part of the surface of the substrate 500, and the surface region of the substrate 5 on which the functional layer 7 is not formed is thermally damaged when the temperature is increased. Therefore, a temperature increase suppression region that requires suppression of temperature increase and a temperature increase unnecessary region that includes a region that does not require temperature increase in terms of process, although it does not cause thermal damage.

  In the processing procedure in the thirteenth embodiment, a fine liquid of pure water is discharged from the discharge port 212 while moving the substrate 500 held on the stage 133 relative to the discharge head 201 in the (−Y) direction along the main scanning direction. The droplets are supplied to a supply region including at least a temperature rise suppression region of the substrate 500, and then the functional layer 7 is heated by irradiating the substrate 500 with flash light from the irradiation unit 213. Further, each time the movement of the base material 500 along the main scanning direction is repeated, the ejection head 201 moves along the sub scanning direction. That is, the moving mechanism 130 and the moving mechanism 204 are mechanisms that move the discharge head 201 relative to the base material 500 in parallel with the discharge of pure water from the discharge head 201.

  Also in the thirteenth embodiment, the flash layer is irradiated with flash light in a state where fine droplets of pure water are supplied to the supply region including at least the temperature rise suppression region of the base material 500. Therefore, the functional layer 7 is raised by the flash light irradiation. While the temperature is raised to the temperature target temperature, the temperature rise exceeding the boiling point of water is suppressed in order to absorb the heat of evaporation when water evaporates in the temperature rise suppression region. As a result, the functional layer 7 formed on the base material 500 can be heated to the target temperature without damaging the base material 500.

<Summary>
As described above, the first to thirteenth embodiments of the present invention have been described. When these are summarized, the heat treatment technique according to the present invention is performed at a temperature lower than the temperature increase target temperature of the functional layer 7 that is a heating target. A phase change material that undergoes phase transition is selectively supplied to a supply region including at least a temperature increase suppression region that requires suppression of temperature increase in the substrate 5, and flash light is applied to the substrate 5 to which the phase change material is attached. To heat the object to be heated.

  The phase change material selectively supplied to the supply region is a liquid phase or a solid phase. The “phase transition” in the technology according to the present invention is a state change between three states (solid phase, liquid phase, gas phase) of a substance. It is “evaporation”. If the phase change material is a solid phase, it is “melting” that changes to a liquid phase or “sublimation” that changes to a gas phase. Then, a phase transition material having a transition temperature of the phase transition (boiling point if the phase transition is evaporation, melting point if melting, sublimation point if sublimation) is lower than the target temperature of the object to be heated The gas is selectively supplied to a supply region including at least a temperature rise suppression region. Preferably, a phase change material whose transition temperature is lower than the temperature at which the substrate 5 is thermally damaged is selectively supplied to the supply region.

  When the heating object is heated by irradiating flash light onto the base material 5 that selectively supplies such a phase change material to the supply region, the heating object that is not in contact with the phase change material has a predetermined temperature increase target temperature. The temperature is raised to. On the other hand, when the supply region including the temperature increase suppression region attempts to increase in temperature, the phase change material supplied to the supply region undergoes a phase transition, and at that time, latent heat (if the phase transition is evaporation, evaporation heat is generated from the supply region). In order to absorb the heat of fusion in the case of melting and the heat of sublimation in the case of sublimation), the temperature of the supply region exceeding the transition temperature is suppressed at least while the phase transition material remains. As a result, the temperature increase of the supply region including the temperature increase suppression region is suppressed, damage to the base material 5 can be prevented, and the heating target formed on the base material 5 is heated to the target temperature. Can do.

<Modification>
While the embodiments of the present invention have been described above, the present invention can be modified in various ways other than those described above without departing from the spirit of the present invention. In the first embodiment and the like, water that is a liquid phase transition material absorbs heat of evaporation to suppress the temperature increase in the supply region of the base material 5, but isopropyl alcohol (IPA) or the like is used instead of water. Liquid phase transition materials such as alcohols, hydrofluoroether (HFE), and acetone can be used. The liquid phase transition material only needs to have a boiling point lower than the temperature increase target temperature of the object to be heated, and is preferably lower than the temperature at which the substrate 5 is thermally damaged. Further, as the liquid phase transition material, a material that does not easily affect the base material 5 and the functional layer 7 that is a heating target and that does not affect the environment even when evaporated is desirable.

  The liquid phase transition material is easily supplied to the supply region of the substrate 5 by ink-jet application (first embodiment) or printing technique (sixth embodiment) even if the pattern shape of the supply region is complicated. Can do. In addition, the liquid phase transition material is suitable as a material that suppresses the temperature increase in the supply region including the temperature increase suppression region because it has good adhesion to the supply region and relatively large latent heat.

  In the fourth embodiment, a liquid containing a phase change material is supplied to the supply region of the substrate 5, and the solid phase change material is finally attached to the supply region by solidifying the phase change material. Yes. Also in the fourth embodiment, a phase change material that solidifies by cooling instead of water may be used.

  In the fifth embodiment, a liquid containing a solution in which a phase change material is dissolved in a solvent is supplied to the supply region of the base material 5, and the solid phase change material as a solute is supplied to the supply region by heating the liquid. It is deposited. In the fifth embodiment, a solution in which paradichlorobenzene is dissolved in alcohol is used, but instead, a solution in which naphthalene is dissolved in alcohol may be used. Since naphthalene is also a solid phase transition material having sublimation properties, it absorbs sublimation heat from the supply region of the base material 5 when phase transition from the solid phase to the gas phase is performed, like paradichlorobenzene.

  Further, in the sixth embodiment, water, which is a liquid phase change material, is transferred to the supply region of the base material 5 by a printing technique using the printing plate 63, but the printing technique as in the sixth embodiment is used. Can be used to supply the solid phase transition material to the supply region of the substrate 5 in a solid state. For example, paradichlorobenzene powder is adhered to the pattern of the printing plate 63, and the printing plate 63 is brought into contact with the surface of the substrate 5, whereby paradichlorobenzene, which is a solid phase transition material, is formed on the substrate. 5 is transferred to the supply area. Even in this case, similarly to the case where paradichlorobenzene is precipitated in the supply region in the fifth embodiment, the temperature of the supply region is increased by absorbing the sublimation heat from the supply region during irradiation with flash light. Can be suppressed.

  The method of supplying the solid containing the phase change material to the supply region of the substrate 5 is not limited to the printing technique as in the sixth embodiment, and may be another method. In addition, naphthalene, ice, dry ice or the like can be used as the solid phase transition material instead of paradichlorobenzene. Naphthalene and dry ice having sublimation properties absorb sublimation heat from the supply region of the substrate 5 when irradiated with flash light. The ice melts to become water at the time of flash light irradiation, and absorbs heat of fusion from the supply region of the substrate 5. Furthermore, the solid containing the phase change material is not limited to being supplied as a powder, and may be supplied as a tangible solid.

  When ice is used as the phase transition material of the solid phase, it is preferable to add a thickener that increases the viscosity of the water to prevent flow when the ice melts into water. As such a thickener, polyvinyl alcohol (PVA), glycerin, a gelling agent, etc. can be used like 2nd Embodiment.

  Moreover, you may make it use together the application | coating by inkjet and a printing technique. That is, after the phase change material having a predetermined pattern is transferred to the supply region of the substrate 5 by the printing plate 63, the shape of the supply region may be finely adjusted by the discharge supply of the phase change material from the discharge head 20.

  In the seventh embodiment, the water remaining in the supply region after flash heating is removed by air blowing from the air knife 70. However, the remaining phase change material is removed by air blowing. There is no limitation, and other methods may be used. For example, if the phase change material evaporates or sublimates by heating, such as water, alcohol, or dry ice, a heating process may be provided after the flash light irradiation to remove the phase change material. Alternatively, when the phase change material adhering to the supply region of the base material 5 cannot be removed only by air blowing (for example, when a thickener is added as in the second embodiment), flushing is performed. A cleaning process may be provided after the light irradiation, and the phase change material adhering to the supply region may be removed by a cleaning process.

  In each of the above embodiments, the PEN or PET substrate 5 having the silver nanoink functional layer 7 formed thereon is irradiated with flash light. However, the present invention is not limited to this, and various variations are possible. Is possible. For example, as the substrate 5, other resin materials such as polyimide and polycarbonate may be used. Since these resin materials are also flexible, the base material 5 can be conveyed from the feed roller 11 to the take-up roller 12 by a roll-to-roll method.

  Moreover, the base material 5 is not limited to a resin material, A metal foil may be sufficient. As the metal foil, for example, copper foil, aluminum foil, stainless steel foil or the like can be used. In general, a metal material lacks flexibility compared to a resin material, but if the foil is sufficiently thin, it can be wound around the feed roller 11 and the take-up roller 12 and is roll-to-roll. Can be transported. Furthermore, the base material 5 may be a flexible glass substrate (so-called flexible glass). Such flexible glass can be conveyed by a roll-to-roll method depending on conditions such as a roller diameter.

  Further, the functional layer 7 formed on the substrate 5 is not limited to silver nano ink, and may be nano ink (or nano wire) of other metal such as copper. Alternatively, the functional layer 7 may be amorphous silicon, IGZO (oxide semiconductor), ITO (indium tin oxide), or the like.

  In addition, the tenth to thirteenth embodiments show forms in which the pure water supply and the flash heating in the first embodiment are realized by a transport method different from the first embodiment. However, the transport method of the tenth embodiment to the thirteenth embodiment is not limited to the pure water supply using the discharge head of the first embodiment, and instead of the discharge head, for example, as in the sixth embodiment. It can also be applied to transfer using a simple plate cylinder. Also, in the tenth to thirteenth embodiments, a cooling unit (fourth embodiment) may be provided to solidify the supplied liquid, or a thickener addition unit (second embodiment) or Further, a hydrophilic treatment section and a water repellent treatment section (third embodiment) may be provided.

  In each of the above embodiments, the flash lamp FL is not limited to a xenon flash lamp, and may be a krypton flash lamp. Further, the irradiation unit 50 may heat the functional layer 7 by irradiating the base material 5 with light from a halogen lamp instead of the flash lamp FL.

  The heat treatment apparatus and heat treatment method according to the present invention can be applied to various objects to be heated formed on a substrate having poor heat resistance, and in particular, flexible devices, flexible displays, used for electronic paper, etc. It can be suitably used for flat panel displays (FPD), electronic devices, solar cells, fuel cells, semiconductor devices and the like.

1a, 1b, 1c, 1d, 1e, 1f, 1g, 1h, 1i, 1j, 1k, 1l, 1m Heat treatment apparatus 3 Supply area 5,500 Base material 6 Water repellent area 7 Functional layer 9 Control section 10 Conveyance section 11 Delivery Roller 12 Winding roller 20, 201 Discharge head 21 Thickener addition unit 22 Hydrophilization processing unit 23 Water repellent processing unit 30 Cooling unit 31 Heating unit 50 Irradiation unit 52 Reflector 60 Transfer unit 61 Plate cylinder 62 Supply roller 63 Printing plate 70 Air knife 85 Carrier film 100, 110, 130 Moving mechanism 103, 112, 122 Supply unit 104, 113, 125 Discharge unit 121 Robot arm 123 Water supply processing chamber 124 Flash heat processing chamber 202 Light source unit FL Flash lamp

Claims (33)

A heat treatment method for raising the temperature of a heating object by irradiating light onto a substrate on which the heating object is formed,
A phase change material that undergoes a phase transition at a temperature lower than the temperature increase target temperature of the object to be heated is selectively supplied to a supply region including at least a temperature increase suppression region that needs to suppress temperature increase in the base material. A supply process,
A heating step of heating the object to be heated by irradiating the base material to which the phase change material is attached;
A heat treatment method comprising: The heat treatment method according to claim 1,
The heat treatment method according to claim 1, wherein a transition temperature of the phase change material is lower than a temperature at which thermal damage occurs in the substrate. In the heat processing method of Claim 1 or Claim 2,
In the heating step, the substrate is irradiated with flash light. In the heat processing method in any one of Claims 1-3,
In the supplying step, a liquid containing the phase change material is supplied to the base material. The heat treatment method according to claim 4, wherein
A heat treatment method, further comprising the step of adding a thickening agent for increasing the viscosity of the liquid to the liquid containing the phase change material. The heat treatment method according to claim 4, wherein
A heat treatment method, further comprising a step of imparting hydrophilicity by performing a hydrophilic treatment on the supply region. The heat treatment method according to claim 6, wherein
A heat treatment method, further comprising a step of performing water repellency treatment around the supply region to surround the supply region with the water repellent region. In the heat treatment method according to any one of claims 4 to 7,
In the supplying step, a liquid containing the liquid phase transition material is supplied to the substrate. The heat treatment method according to claim 8, wherein
A heat treatment method, further comprising a step of solidifying the phase change material in a liquid phase supplied to the substrate. In the heat treatment method according to any one of claims 4 to 7,
In the supplying step, a liquid containing a solution obtained by dissolving the phase change material in a solvent is supplied to the substrate. The heat treatment method according to claim 10, wherein
A heat treatment method, further comprising a precipitation step of removing the solvent from the solution supplied to the substrate and precipitating the phase change material in the supply region. The heat treatment method according to any one of claims 4 to 11,
In the supplying step, a liquid containing the phase change material is discharged from a nozzle for discharging droplets to the supply region. In the heat processing method in any one of Claims 1-3,
In the supplying step, a solid containing the phase change material is supplied to the base material. The heat treatment method according to claim 13,
In the supplying step, a solid phase containing the solid phase transition material is supplied to the substrate. In the heat processing method of Claim 13 or Claim 14,
A heat treatment method, further comprising a step of adding to the solid a thickener that increases a viscosity of a liquid generated when the solid containing the phase change material is melted. In the heat processing method in any one of Claims 1-15,
The supply step includes
Supplying the phase change material to a printing plate on which the phase change material selectively adheres to a pattern corresponding to the supply region;
Transferring the phase change material attached to the printing plate to the supply region of the substrate;
A heat treatment method comprising: The heat treatment method according to any one of claims 1 to 16,
A heat treatment method, further comprising a removal step of removing the phase change material remaining on the substrate after the heating step. The heat treatment method according to any one of claims 1 to 17,
In the supplying step, the phase change material is supplied to a second surface opposite to the first surface of the base material on which the heating object is formed. The heat treatment method according to claim 18,
In the supplying step, the phase change material is supplied to the supply region by bringing a supporting member supporting the phase change material close to the second surface. The heat treatment method according to any one of claims 1 to 19,
The heat treatment method, wherein the phase change material is water. The heat treatment method according to any one of claims 1 to 20,
The heat treatment method, wherein the substrate is long. The heat treatment method according to any one of claims 1 to 20,
The heat treatment method, wherein the substrate is plate-shaped or sheet-shaped. A heat treatment apparatus that raises the temperature of the heating object by irradiating light onto the substrate on which the heating object is formed,
A phase change material that undergoes a phase transition at a temperature lower than the target temperature rise of the heating object is selectively supplied to a supply region including a temperature rise suppression region that needs to suppress temperature rise in at least the base material A supply section to
A heating unit that heats the object to be heated by irradiating light onto the substrate to which the phase change material is attached;
A heat treatment apparatus comprising: The heat treatment apparatus according to claim 23,
The heat treatment apparatus, wherein a transition temperature of the phase change material is lower than a temperature at which thermal damage is caused to the substrate. In the heat treatment apparatus according to claim 23 or claim 24,
The heating unit includes a flash lamp that irradiates a substrate with flash light. The heat treatment apparatus according to any one of claims 23 to 25,
The heat processing apparatus characterized by further providing the conveyance part which conveys a base material by winding up the base material sent out from the 1st roller with a 2nd roller. The heat treatment apparatus according to any one of claims 23 to 25,
The substrate is plate-shaped or sheet-shaped,
The heat processing apparatus characterized by further providing the conveyance part which conveys the said base material 1 sheet | seat at a time. In the heat treatment apparatus according to any one of claims 23 to 27,
The supply unit supplies a liquid containing the phase change material to the substrate. The heat treatment apparatus according to claim 28,
The supply unit includes a nozzle that discharges liquid droplets containing the phase change material in the supply region. In the heat treatment apparatus according to any one of claims 23 to 27,
The said supply part supplies the solid containing the said phase change substance to the said base material, The heat processing apparatus characterized by the above-mentioned. The heat treatment apparatus according to any one of claims 23 to 30,
The supply unit has a plate cylinder for transferring the phase change material to the supply region by bringing the printing plate having the phase change material selectively attached to the pattern corresponding to the supply region into contact with the substrate. A heat treatment apparatus characterized by The heat treatment apparatus according to any one of claims 23 to 31,
A heat treatment apparatus, further comprising a removing unit that removes the phase change material remaining on the base material after heating. The heat treatment apparatus according to any one of claims 23 to 32,
The heat treatment apparatus, wherein the phase change material is water.

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