JP2015176655A - Cylindrical battery and method of manufacturing the same - Google Patents

Cylindrical battery and method of manufacturing the same Download PDF

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JP2015176655A
JP2015176655A JP2014050081A JP2014050081A JP2015176655A JP 2015176655 A JP2015176655 A JP 2015176655A JP 2014050081 A JP2014050081 A JP 2014050081A JP 2014050081 A JP2014050081 A JP 2014050081A JP 2015176655 A JP2015176655 A JP 2015176655A
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current collector
boss portion
hole
boss
sealant
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JP6397639B2 (en
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山崎 龍也
Tatsuya Yamazaki
龍也 山崎
秀典 都築
Shusuke Tsuzuki
秀典 都築
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FDK Energy Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a cylindrical battery in which liquid leakage can be more effectively prevented.SOLUTION: In a cylindrical battery which is configured so that a positive electrode drug combination, a separator and negative electrode gel are accommodated in a cylindrical positive electrode can having a bottom, and a negative electrode terminal plate is fitted in an opening of the positive electrode can through a sealing gasket 70, a rod-shaped power collection piece 51 fixedly provided to the negative electrode terminal is inserted in a through-hole of a boss portion 71 of the sealing gasket 70 so that the surface of a head portion 51a of the power collection piece 51 is brought into close contact with an upper surface 72 of the boss portion 71, and a sealing agent stock portion 73 for stocking sealing agent for forming a sealing layer for at least liquid-tightly sealing the gap between the power collection piece 51 and an inner peripheral surface 74 of the through-hole is formed at the inner peripheral end edge portion of the through-hole formed in the boss portion 71, which confronts the power collection piece 51.

Description

本発明は、筒型電池及び筒型電池の製造方法に関する。   The present invention relates to a cylindrical battery and a method for manufacturing a cylindrical battery.

筒型電池は、アルカリ電池等の一次電池として各種電気機器に広く使用されている。従来の一般的な筒型電池の構成例が、特許文献1(特開2013−54859)に示されている。この構成の詳細については、本願発明の実施形態に関して後述するが、概略有底円筒状の正極缶と、その内部に環状に配置されている正極合剤を有し、正極合剤の内側にはセパレータを介してゲル状負極合剤が充填されている。正極合剤内には、正極缶の開口側から棒状の集電子が挿入されるが、その集電子には負極端子板が固設されている。集電子には液漏れ等を防ぐとともに、電池の内圧が上昇した場合にこれを逃がして破裂を防ぐための封口ガスケットが嵌められる。具体的には、封口ガスケットは略円筒状のボス部とボス部から円盤状に展開する円盤部を備える。筒型電池の組み立てにあたっては、集電子を封口ガスケットのボス部に貫通させ、集電子をゲル状負極合剤内に差し込んだ状態で、封口ガスケット及び負極端子板をともに正極缶の開口縁でかしめつけて完成する。   Cylindrical batteries are widely used in various electrical devices as primary batteries such as alkaline batteries. A configuration example of a conventional general cylindrical battery is disclosed in Patent Document 1 (Japanese Patent Laid-Open No. 2013-54859). The details of this configuration will be described later with respect to the embodiment of the present invention, but it has a substantially bottomed cylindrical positive electrode can and a positive electrode mixture arranged in a ring shape inside, and inside the positive electrode mixture The gelled negative electrode mixture is filled through the separator. A rod-shaped current collector is inserted into the positive electrode mixture from the opening side of the positive electrode can, and a negative electrode terminal plate is fixed to the current collector. The current collector is fitted with a sealing gasket for preventing leakage and preventing explosion when the internal pressure of the battery rises to prevent explosion. Specifically, the sealing gasket includes a substantially cylindrical boss portion and a disk portion that expands into a disk shape from the boss portion. When assembling the cylindrical battery, the current collector is passed through the boss of the sealing gasket, and the current collector is inserted into the gelled negative electrode mixture. Complete by tightening.

封口ガスケットによる電池内部のシール性を確保するために、前記集電子は前記封口ガスケットのボス部に設けられている貫通孔に締まりばめ状態となるように圧入される。さらに、ボス部の端面と集電子頭部表面との境界面における封止性を高めるために、その境界面に封止剤を介在させるようにしている。この場合、封止剤は上記した電池組み立て時に集電子の外周表面に塗布される。集電子を封口ガスケットの貫通孔に挿通させると、集電子がボス部に圧入される際に封止剤はボス部の貫通孔内周縁によって上方へとかき取られていき、ボス部上面と集電子頭部との間に溜まって両者の境界面を封止するようになる。この場合、集電子の外周面と貫通孔内周面との間には、前記のかき取りにより封止剤はほとんど残留しないこととなっている。   In order to secure the sealing performance inside the battery by the sealing gasket, the current collector is press-fitted into a through-hole provided in the boss portion of the sealing gasket so as to be in a tight fit state. Furthermore, in order to improve the sealing performance at the boundary surface between the end surface of the boss portion and the current collector head surface, a sealing agent is interposed at the boundary surface. In this case, the sealant is applied to the outer peripheral surface of the current collector when the battery is assembled. When the current collector is inserted into the through hole of the sealing gasket, the sealing agent is scraped upward by the inner peripheral edge of the through hole of the boss portion when the current collector is press-fitted into the boss portion, and the upper surface of the boss portion and the collector are collected. It accumulates between the electronic head and seals the interface between the two. In this case, almost no sealant remains between the outer peripheral surface of the current collector and the inner peripheral surface of the through hole due to the scraping.

特開2013−54859号公報JP 2013-54859 A

しかしながら、以上説明したような、特許文献1に例示されているもの等の従来の筒型電池では、ボス部と集電子との間に封止剤が介在しないため、調達部品の問題、製造工程における問題等に起因して、封口ガスケットのボス部貫通孔内面、あるいは集電子外周面に傷が生じている場合、あるいは経時的にボス部と集電子との嵌め合い状態が緩んでくると、集電子をボス部に圧入したことによる封止効果が薄れてきて、電池内部の電解液がボス部と集電子との間の微小な隙間を通って外部に至り液漏れ状態となるおそれがあるという問題があった。   However, in the conventional cylindrical batteries such as those described in Patent Document 1 as described above, there is no sealing agent between the boss portion and the current collector, so there is a problem with the procured parts and the manufacturing process. Due to problems in the boss portion through-hole inner surface of the sealing gasket or the current collector outer peripheral surface, or when the fitting state of the boss portion and the current collector becomes loose over time, The sealing effect due to the press-fitting of the current collector into the boss portion is diminished, and there is a possibility that the electrolyte inside the battery reaches the outside through a minute gap between the boss portion and the current collector and enters a liquid leakage state. There was a problem.

本発明は、上記のような問題点を解決するためになされたもので、筒型電池において、より効果的に液漏れを防止する事が可能な筒型電池及び筒型電池の製造方法を提供することを一つの目的としている。   The present invention has been made to solve the above-described problems, and provides a cylindrical battery and a method of manufacturing the cylindrical battery that can more effectively prevent liquid leakage in the cylindrical battery. One purpose is to do.

前記の、及び他の問題点を解決するために、本発明の一つの態様は、有底円筒状の電池缶内に、環状の正極合剤と、当該正極合剤の内側に配置される有底円筒状のセパレータと、当該セパレータの内側に配置される負極ゲルとが収納されているとともに、前記電池缶の開口に負極端子板が封口ガスケットを介して嵌着されてなる筒型電池であって、前記封口ガスケットは、略円盤状に一体的に成形された樹脂からなり、前記円盤の中心にて上下方向に中空円筒状に突設されているボス部を有し、前記封口ガスケットの前記ボス部が有する貫通孔に前記負極端子板に固設されている棒状の集電子が、前記集電子端部に拡径部として形成されている頭部表面と前記ボス部の上面とが密接するように圧入状態で貫通挿入されており、前記ボス部に設けられている前記貫通孔の前記集電子に面する内周端縁部に、前記集電子と前記貫通孔内周面との間を少なくとも液密に封止する封止層を形成するための封止剤を貯留する封止剤貯留部が形成されていることを特徴とする。   In order to solve the above-mentioned and other problems, one aspect of the present invention provides an annular positive electrode mixture and a positive electrode mixture disposed inside the bottomed cylindrical battery can. A cylindrical battery in which a bottom cylindrical separator and a negative electrode gel disposed inside the separator are housed, and a negative terminal plate is fitted into an opening of the battery can via a sealing gasket. The sealing gasket is made of a resin integrally formed in a substantially disk shape, and has a boss portion protruding in a hollow cylindrical shape in the vertical direction at the center of the disk, and the sealing gasket The rod-shaped current collector fixed to the negative electrode terminal plate in the through hole of the boss portion is in close contact with the head surface formed as an enlarged diameter portion at the current collector end portion and the upper surface of the boss portion. So that it is inserted in the press-fitted state. A sealing layer for forming a sealing layer that at least liquid-tightly seals between the current collector and the inner peripheral surface of the through hole at an inner peripheral edge of the through hole facing the current collector. A sealant storage part for storing a stopper is formed.

また、本発明の他の態様は、有底円筒状の電池缶内に、環状の正極合剤と、当該正極合剤の内側に配置される有底円筒状のセパレータと、当該セパレータの内側に配置される負極ゲルとが収納されているとともに、前記電池缶の開口に負極端子板が封口ガスケットを介して嵌着されてなり、前記封口ガスケットは、略円盤状に一体的に成形された樹脂からなり、前記円盤の中心にて上下方向に中空円筒状に突設されているボス部を有し、前記封口ガスケットの前記ボス部が有する貫通孔に前記負極端子板に固設されている棒状の集電子が、前記集電子端部に拡径部として形成されている頭部表面と前記ボス部の上面とが密接するように圧入状態で貫通挿入されており、前記ボス部に設けられている前記貫通孔の前記集電子に面する内周端縁部に、前記集電子と前記貫通孔内周面との間を少なくとも液密に封止する封止層を形成するための封止剤を貯留する封止剤貯留部が形成されている筒型電池の製造方法であって、前記ボス部に前記集電子を挿入する際に、前記集電子外周部の前記頭部と前記ボス部上面との間の領域の少なくとも一部に前記封止剤を環状に塗布した後、前記ボス部上面を前記頭部表面に対して一時的に圧接させて、前記封止剤を前記集電子外周面と前記ボス部の前記貫通孔内周面との間に供給する工程を含むことを特徴とする。   In another aspect of the present invention, a cylindrical battery can with a bottom, an annular positive electrode mixture, a cylindrical separator with a bottom disposed inside the positive electrode mixture, and an inner side of the separator. The negative electrode gel to be disposed is housed, and a negative electrode terminal plate is fitted to the opening of the battery can via a sealing gasket, and the sealing gasket is a resin integrally formed in a substantially disc shape. A rod-shaped member having a boss projecting in the shape of a hollow cylinder in the vertical direction at the center of the disk, and fixed to the negative electrode terminal plate in a through hole of the boss of the sealing gasket Current collector is inserted in a press-fit state so that a head surface formed as an enlarged diameter portion at the current collector end portion and an upper surface of the boss portion are in close contact with each other, provided on the boss portion Inner peripheral edge of the through hole facing the current collector A cylindrical battery in which a sealing agent storage part for storing a sealing agent for forming a sealing layer for sealing at least liquid tightly between the current collector and the inner peripheral surface of the through hole is formed. In the manufacturing method, when the current collector is inserted into the boss portion, the sealant is annularly formed in at least a part of a region between the head portion of the current collector outer peripheral portion and the upper surface of the boss portion. After coating, the upper surface of the boss part is temporarily brought into pressure contact with the head surface, and the sealant is supplied between the outer peripheral surface of the current collector and the inner peripheral surface of the through hole of the boss part. Including a process.

本発明の一態様によれば、筒型電池において、より効果的に液漏れを防止することができる。   According to one embodiment of the present invention, liquid leakage can be more effectively prevented in a cylindrical battery.

図1は、本発明の一実施形態に係る筒型アルカリ電池の集電子51と封口ガスケットボス部71との係合部の構成を例示する部分拡大断面図である。FIG. 1 is a partially enlarged cross-sectional view illustrating the configuration of an engaging portion between a current collector 51 and a sealing gasket boss portion 71 of a cylindrical alkaline battery according to an embodiment of the invention. 図2Aは、図1に例示する構成を有する筒型アルカリ電池の組み立て手順を示す模式図である。FIG. 2A is a schematic diagram illustrating a procedure for assembling a cylindrical alkaline battery having the configuration illustrated in FIG. 1. 図2Bは、図1に例示する構成を有する筒型アルカリ電池の組み立て手順を示す模式図である。FIG. 2B is a schematic diagram illustrating an assembly procedure of the cylindrical alkaline battery having the configuration illustrated in FIG. 1. 図2Cは、図1に例示する構成を有する筒型アルカリ電池の組み立て手順を示す模式図である。FIG. 2C is a schematic diagram illustrating an assembling procedure of the cylindrical alkaline battery having the configuration illustrated in FIG. 図3Aは、本発明の他の実施形態に係る、図1に例示する筒型アルカリ電池の集電子51と封口ガスケットボス部71との係合部の構成例を示す部分拡大断面図である。FIG. 3A is a partial enlarged cross-sectional view illustrating a configuration example of an engaging portion between the current collector 51 and the sealing gasket boss portion 71 of the cylindrical alkaline battery illustrated in FIG. 1 according to another embodiment of the present invention. 図3Bは、本発明の他の実施形態に係る、図1に例示する筒型アルカリ電池の集電子51と封口ガスケットボス部71との係合部の構成例を示す部分拡大断面図である。FIG. 3B is a partially enlarged cross-sectional view illustrating a configuration example of an engaging portion between the current collector 51 and the sealing gasket boss portion 71 of the cylindrical alkaline battery illustrated in FIG. 1 according to another embodiment of the present invention. 図3Cは、本発明の他の実施形態に係る、図1に例示する筒型アルカリ電池の集電子51と封口ガスケットボス部71との係合部の構成例を示す部分拡大断面図である。FIG. 3C is a partial enlarged cross-sectional view illustrating a configuration example of an engaging portion between the current collector 51 and the sealing gasket boss portion 71 of the cylindrical alkaline battery illustrated in FIG. 1 according to another embodiment of the present invention. 図4は、本発明の一実施形態に係る筒型アルカリ電池の全体構成例を示す模式図である。FIG. 4 is a schematic diagram showing an example of the overall configuration of a cylindrical alkaline battery according to an embodiment of the present invention.

以下に、添付図面を参照して、本発明の実施形態を更に具体的に説明する。なお、本発明は、それらの実施形態に限定されるものではない。   Hereinafter, embodiments of the present invention will be described more specifically with reference to the accompanying drawings. Note that the present invention is not limited to these embodiments.

まず、図4に、本実施形態に係る筒型アルカリ電池1の構成例を示す縦断面図を示している。このアルカリ電池1は、LR6タイプ(単3形)の電池である。   First, FIG. 4 shows a longitudinal sectional view showing a configuration example of the cylindrical alkaline battery 1 according to the present embodiment. The alkaline battery 1 is an LR6 type (AA) battery.

図4に示されるように、アルカリ電池1は、有底筒状の正極缶10(電池缶)と、その正極缶10の内面に沿って嵌着されたリング状の正極合剤20と、正極合剤20の内側に挿入される有底筒状のセパレータ30と、正極缶10の中心部となるセパレータ30の中空部に配置されるゲル状負極合剤40と、正極缶10の開口部10aに装着される封口体50とを備える。   As shown in FIG. 4, the alkaline battery 1 includes a bottomed cylindrical positive electrode can 10 (battery can), a ring-shaped positive electrode mixture 20 fitted along the inner surface of the positive electrode can 10, a positive electrode The bottomed cylindrical separator 30 inserted inside the mixture 20, the gelled negative electrode mixture 40 disposed in the hollow portion of the separator 30 that is the center of the positive electrode can 10, and the opening 10 a of the positive electrode can 10. And a sealing body 50 to be attached.

正極缶10は、例えばニッケルメッキ鋼板を有底筒状にプレス成形することによって形成され、その底部の中央に正極端子12が突設されている。正極合剤20は、例えば電解二酸化マンガン、黒鉛、水酸化カリウム、及びバインダを混合した正極合剤粉を整粒した後、これを円筒状にプレス成形することで作製される。   The positive electrode can 10 is formed, for example, by press-molding a nickel-plated steel plate into a bottomed cylindrical shape, and a positive electrode terminal 12 projects from the center of the bottom. The positive electrode mixture 20 is produced, for example, by adjusting the positive electrode mixture powder in which electrolytic manganese dioxide, graphite, potassium hydroxide, and a binder are mixed, and then press-molding the powder into a cylindrical shape.

セパレータ30は、正極合剤20とゲル状負極合剤40との間を電気的に分離する絶縁材料であり、ビニロン・レーヨン不織布、ポリオレフィン・レーヨン不織布などのセパレータ原紙を円筒状に巻回し、重なり合う部分を熱融着させることで作製される。   The separator 30 is an insulating material that electrically separates between the positive electrode mixture 20 and the gelled negative electrode mixture 40, and separator base paper such as vinylon / rayon nonwoven fabric or polyolefin / rayon nonwoven fabric is wound in a cylindrical shape and overlapped. It is produced by thermally fusing the part.

ゲル状負極合剤40は、水と酸化亜鉛と水酸化カリウムとを混ぜて溶解し、ポリアクリル酸などのゲル化剤と亜鉛粉とを混合することで作製される。   The gelled negative electrode mixture 40 is prepared by mixing water, zinc oxide and potassium hydroxide and dissolving them, and mixing a gelling agent such as polyacrylic acid and zinc powder.

封口体50は、負極端子板60、負極集電子51(以下「集電子51」)、及び封口ガスケット70を備えて構成されている。正極缶10の開口部10a付近には、封口体50を載置するためのビード部11が形成されている。そして、そのビード部11上に封口体50を載置した状態で、正極缶10の開口部10aにカール及び絞り加工を施すことにより、正極缶10が封口されている。言い換えると、アルカリ電池1の正極缶10は、開口部10aを径方向(横断方向)に収縮させてかしめることにより封口されている。   The sealing body 50 includes a negative electrode terminal plate 60, a negative electrode current collector 51 (hereinafter “current collector 51”), and a sealing gasket 70. In the vicinity of the opening 10 a of the positive electrode can 10, a bead portion 11 for placing the sealing body 50 is formed. The positive electrode can 10 is sealed by curling and drawing the opening 10 a of the positive electrode can 10 with the sealing body 50 placed on the bead portion 11. In other words, the positive electrode can 10 of the alkaline battery 1 is sealed by shrinking and crimping the opening 10a in the radial direction (transverse direction).

封口体50は、真鍮を用いて棒状に形成された胴部(後出の図1等において符号51bで示す。)を有する集電子51をその基端側の頭部(後出の図1等において符号51aで示す。)で負極端子板60の裏面に抵抗溶接するとともに、集電子51の頭部51aと胴部51bとの接続部分である首部に封口ガスケット70を嵌着することによって形成されている。集電子51の先端側は、ゲル状負極合剤40の中に挿入されている。   The sealing body 50 includes a current collector 51 having a body portion (indicated by reference numeral 51b in FIG. 1 and the like described later) formed in a rod shape using brass, and a head portion on the base end side (FIG. 1 and the like described later). In FIG. 5, resistance welding is performed on the back surface of the negative electrode terminal plate 60, and a sealing gasket 70 is fitted to a neck portion that is a connection portion between the head portion 51 a and the body portion 51 b of the current collector 51. ing. The front end side of the current collector 51 is inserted into the gelled negative electrode mixture 40.

負極端子板60は、正極缶10と同じくニッケルメッキ鋼板をプレス成形することによって作製され、封口ガスケット70を介して正極缶10の開口部10aを封止している。負極端子板60は、円形皿状に形成され、その外縁部60aはほぼ直角に折り曲げられている。負極端子板60の外周つば状の部位には、複数のガス抜き穴61が設けられている。   The negative electrode terminal plate 60 is produced by press-molding a nickel-plated steel plate in the same manner as the positive electrode can 10, and seals the opening 10 a of the positive electrode can 10 through a sealing gasket 70. The negative electrode terminal plate 60 is formed in a circular dish shape, and the outer edge portion 60a is bent substantially at a right angle. A plurality of gas vent holes 61 are provided in the outer peripheral collar portion of the negative electrode terminal plate 60.

封口ガスケット70は、樹脂材料を用いて射出成形された樹脂成形品である。封口ガスケット70の形成材料としては、6,12ナイロン樹脂、6,10ナイロン樹脂、6,6ナイロン樹脂などのポリアミド樹脂が好適に用いられる。封口ガスケット70は、中心部に配置されている筒状のボス部71と、ボス部71から径方向外方に展開するように設けられている環状の円盤部72とを備える。ボス部71の中心部には貫通孔が設けられ、集電子51が締まりばめ状態で挿通されている。封口ガスケット70は、電極ショート等によりガスが発生してアルカリ電池1内部の圧力が高まった場合に、例えば円盤部72とボス部71との薄い接続部分において、あらかじめ設定した所定の圧力値付近で破断するように構成されている。これにより、高まった電池内圧は、発生したガスが破断部から負極端子板60のガス抜き穴61を通じて外気に放出されることにより低減され、アルカリ電池1の破裂は防止される。   The sealing gasket 70 is a resin molded product that is injection-molded using a resin material. As a material for forming the sealing gasket 70, polyamide resins such as 6,12 nylon resin, 6,10 nylon resin, and 6,6 nylon resin are preferably used. The sealing gasket 70 includes a cylindrical boss portion 71 disposed in the center portion and an annular disk portion 72 provided so as to expand radially outward from the boss portion 71. A through hole is provided at the center of the boss 71, and the current collector 51 is inserted in an interference fit state. When a gas is generated due to an electrode short-circuit or the like and the pressure inside the alkaline battery 1 is increased, the sealing gasket 70 is, for example, near a predetermined pressure value set in advance at a thin connection portion between the disk portion 72 and the boss portion 71. It is configured to break. As a result, the increased battery internal pressure is reduced by releasing the generated gas to the outside air through the gas vent hole 61 of the negative electrode terminal plate 60 from the fractured portion, and the alkaline battery 1 is prevented from bursting.

次に、以上説明した筒型アルカリ電池1の全体構成例を前提として、本発明の一実施形態に係る筒型アルカリ電池1の本発明と関連する部分について説明する。図1に、本発明の一実施形態に係る筒型アルカリ電池1の集電子51と封口ガスケットボス部71との係合部の構成を例示する部分拡大断面図を示している。図1において、図4に図示した構成要素と同一の構成要素には同一の参照符号を付して示し、詳細な説明は省略する。これは以下の明細書中において同様とする。   Next, on the premise of the overall configuration example of the cylindrical alkaline battery 1 described above, a portion related to the present invention of the cylindrical alkaline battery 1 according to one embodiment of the present invention will be described. FIG. 1 is a partial enlarged cross-sectional view illustrating the configuration of the engaging portion between the current collector 51 and the sealing gasket boss portion 71 of the cylindrical alkaline battery 1 according to the embodiment of the invention. In FIG. 1, the same components as those illustrated in FIG. 4 are denoted by the same reference numerals, and detailed description thereof is omitted. This is the same in the following specification.

図1に例示する部分拡大断面図には、本発明の実施形態による筒型アルカリ電池1の集電子51と封口ガスケット70との組み付け関係が例示されている。集電子51は、前述のように、円形横断面を有する棒状の胴部51bと、胴部51bよりも大なる直径を有して胴部51bと同心にその一端部に一体的に形成されている肉厚円盤状の頭部51aとから構成されている。封口ガスケット70は貫通孔が設けられた略円筒状のボス部71を有し、集電子51は、頭部51aがボス部71の上面72に当接する状態となるようにボス部71に差し込まれている。   The partial enlarged cross-sectional view illustrated in FIG. 1 illustrates the assembly relationship between the current collector 51 and the sealing gasket 70 of the cylindrical alkaline battery 1 according to the embodiment of the present invention. As described above, the current collector 51 has a rod-like body 51b having a circular cross section, a diameter larger than that of the body 51b, and is formed integrally with one end of the body 51b. And a thick disk-shaped head 51a. The sealing gasket 70 has a substantially cylindrical boss portion 71 provided with a through-hole, and the current collector 51 is inserted into the boss portion 71 so that the head portion 51 a is in contact with the upper surface 72 of the boss portion 71. ing.

集電子51の胴部51bの直径は、ボス部71の内周面74によって画成される貫通孔の内径よりも大で、ボス部71の貫通孔に胴部51bが圧入されて締まりばめの関係となるように設定されている。これは、ボス部71の内周面74と集電子51の胴部51bとの境界面に空隙が生じ、封口ガスケット70によって封止されているゲル状負極合剤40が前記境界面を通じて外部に漏出することを防ぐためである。本実施形態では、さらにこの境界面を少なくとも液密に封止するための封止層を形成するようにしている。封止層は、境界面に介在する封止剤によって形成される。   The diameter of the body part 51b of the current collector 51 is larger than the inner diameter of the through hole defined by the inner peripheral surface 74 of the boss part 71, and the body part 51b is press-fitted into the through hole of the boss part 71 and is an interference fit. It is set to be the relationship. This is because a gap is generated at the boundary surface between the inner peripheral surface 74 of the boss portion 71 and the body portion 51b of the current collector 51, and the gelled negative electrode mixture 40 sealed by the sealing gasket 70 is exposed to the outside through the boundary surface. This is to prevent leakage. In the present embodiment, a sealing layer for sealing the boundary surface at least in a liquid-tight manner is formed. The sealing layer is formed by a sealing agent interposed on the boundary surface.

封止層を形成するための具体的な構成例について以下説明する。図1に例示するように、ボス部71の上面72側の貫通孔内周端周縁部(開口周縁部)には貫通孔内方に凸なR部が設けられている。R部の寸法は、集電子51の頭部51aがボス部71の上面72と密接することが可能となるように設定する。その場合、集電子51の胴部51bをボス部71の貫通孔に挿通させてボス部71の上面72が集電子51の頭部51a表面と密接するようにすると、前記R部が形成されているために、ボス部71の貫通孔内周端縁部と、集電子51の頭部51a表面と、集電子51の胴部51b外周面とによって画成される略環状の空間73が画成される。本実施形態では、この空間73を、ボス部71の内周面74と集電子51の胴部51bとの境界面に封止剤を圧入して適切な封止層を形成するために用いている。以下、この空間73を「封止剤貯留部73」という。   A specific configuration example for forming the sealing layer will be described below. As illustrated in FIG. 1, an R portion that protrudes inward of the through hole is provided on the inner peripheral end peripheral portion (opening peripheral portion) of the through hole on the upper surface 72 side of the boss portion 71. The dimension of the R portion is set so that the head 51 a of the current collector 51 can be in close contact with the upper surface 72 of the boss portion 71. In that case, when the body portion 51b of the current collector 51 is inserted into the through hole of the boss portion 71 so that the upper surface 72 of the boss portion 71 is in close contact with the surface of the head portion 51a of the current collector 51, the R portion is formed. Therefore, a substantially annular space 73 defined by the inner peripheral edge of the through hole of the boss 71, the surface of the head 51 a of the current collector 51, and the outer peripheral surface of the body 51 b of the current collector 51 is defined. Is done. In this embodiment, this space 73 is used to press-fit a sealing agent into the boundary surface between the inner peripheral surface 74 of the boss portion 71 and the body portion 51b of the current collector 51 to form an appropriate sealing layer. Yes. Hereinafter, this space 73 is referred to as “sealing agent reservoir 73”.

次に、上記の構成を有する筒型アルカリ電池1において、前記の封止層を形成するために採用される組み立て手順の例を説明する。図2A〜図2Cに、封止層の形成に関連する組み立て手順例を模式的に示している。図2Aに示すように、頭部51aが負極端子板60に固設されている集電子51の胴部51bの周囲を実質的に一周するように封止剤Sを塗っておく。封止剤Sを塗る部位は、集電子51の頭部51aから胴部51bの先端に向かって、封口ガスケット70が有するボス部71の長さの範囲内とすることが適当である。これは、ボス部71の内周面74と集電子51の胴部51bとの間に封止層を形成するためである。胴部51bに塗る封止剤Sの量は、封止剤貯留部73の容積と、ボス部71の内周面74と集電子51の胴部51bとの間に形成すべき封止層の厚さ及び面積から理論的に算出される所要体積を満足するように設定すればよい。要は、封止剤貯留部73の容積を勘案して、ボス部71の内周面74と集電子51の胴部51bとの間を少なくとも液密に封止するに足るだけの封止剤Sを塗布すればよく、この技術思想に基づいて封止剤Sの塗布量及び封止剤貯留部73の断面形状、寸法は適宜に決定することができるものである。   Next, an example of an assembly procedure employed for forming the sealing layer in the cylindrical alkaline battery 1 having the above-described configuration will be described. FIG. 2A to FIG. 2C schematically show an assembly procedure example related to the formation of the sealing layer. As shown in FIG. 2A, the sealant S is applied so that the head 51 a substantially goes around the body 51 b of the current collector 51 fixed to the negative electrode terminal plate 60. It is appropriate that the portion where the sealing agent S is applied is within the range of the length of the boss portion 71 of the sealing gasket 70 from the head 51a of the current collector 51 toward the tip of the body 51b. This is because a sealing layer is formed between the inner peripheral surface 74 of the boss 71 and the body 51 b of the current collector 51. The amount of the sealing agent S applied to the trunk portion 51 b is that of the sealing layer to be formed between the volume of the sealing agent storage portion 73 and the inner peripheral surface 74 of the boss portion 71 and the trunk portion 51 b of the current collector 51. What is necessary is just to set so that the required volume calculated theoretically from thickness and an area may be satisfied. In short, considering the volume of the sealant reservoir 73, the sealant is sufficient to at least liquid-tightly seal between the inner peripheral surface 74 of the boss 71 and the body 51b of the current collector 51. S may be applied, and the application amount of the sealant S and the cross-sectional shape and dimensions of the sealant reservoir 73 can be determined as appropriate based on this technical idea.

次に、図2Bに例示するように、図2Aの状態から集電子51の胴部51bをボス部71の貫通孔に挿通させていく。そして、図示のように、ボス部71の上面72を集電子51の頭部51a表面に対して一時的に圧接させる。言い換えれば、頭部51aがボス部71の上面72に当接した後、さらに適宜の深さだけ頭部51aがボス部71の上面72を押圧変形させて沈み込むようにする。このとき、集電子51の胴部51b周囲に塗布されていた封止剤Sは、ボス部71の貫通孔内周面74が胴部51bの外周面に密接しながら上方に摺動していく過程で封止剤貯留部73内に集積される。そして、集電子51の頭部51aがボス部71の上面72に沈み込むように押し込まれる際に、封止剤貯留部73内に貯められていた封止剤Sはボス部71の貫通孔内周面74と集電子51の胴部51b外周面との間に圧入されて封止層を形成する。封止剤貯留部73内の封止剤Sは同時に集電子51の頭部51aとボス部71の上面72との間も埋めるように外方へ広がる。   Next, as illustrated in FIG. 2B, the body 51 b of the current collector 51 is inserted into the through hole of the boss 71 from the state of FIG. 2A. Then, as illustrated, the upper surface 72 of the boss 71 is temporarily brought into pressure contact with the surface of the head 51 a of the current collector 51. In other words, after the head portion 51a abuts on the upper surface 72 of the boss portion 71, the head portion 51a further presses and deforms the upper surface 72 of the boss portion 71 to sink by an appropriate depth. At this time, the sealant S applied around the trunk portion 51b of the current collector 51 slides upward while the through hole inner circumferential surface 74 of the boss portion 71 is in close contact with the outer circumferential surface of the trunk portion 51b. In the process, it is accumulated in the sealant reservoir 73. When the head 51 a of the current collector 51 is pushed so as to sink into the upper surface 72 of the boss portion 71, the sealing agent S stored in the sealing agent storage portion 73 is in the through hole of the boss portion 71. A sealing layer is formed by press-fitting between the peripheral surface 74 and the outer peripheral surface of the body 51 b of the current collector 51. The sealant S in the sealant reservoir 73 spreads outward so as to fill the space between the head 51 a of the current collector 51 and the upper surface 72 of the boss 71.

次いで、図2Cに例示するように、ボス部71をわずかに集電子51の胴部51b先端方向へ戻し、集電子51の頭部51aとボス部71の上面72がほぼ当接する位置となるようにする。以上の組み立て手順例によれば、封口ガスケット70のボス部71内周面74と集電子51の胴部51b外周面との間、及び集電子51の頭部51aとボス部71の上面72との間は液密状態となるように適切に封止される。   Next, as illustrated in FIG. 2C, the boss portion 71 is slightly returned toward the front end of the body portion 51 b of the current collector 51 so that the head portion 51 a of the current collector 51 and the upper surface 72 of the boss portion 71 are substantially in contact with each other. To. According to the above assembly procedure example, the boss portion 71 inner peripheral surface 74 of the sealing gasket 70 and the body 51b outer peripheral surface of the current collector 51, and the head portion 51a of the current collector 51 and the upper surface 72 of the boss portion 71, Is properly sealed so as to be in a liquid-tight state.

なお、以上の実施形態では、ボス部71の貫通孔開口周縁に貫通孔内方に凸なR部を設ける構成を例示したが、内方に凸なR部に代えて、図3Aに例示するように、貫通孔開口周縁に面取り部を設ける構成、図3Bに例示するように、貫通孔内方貫通孔開口周縁に適宜の寸法の座ぐり部を設ける構成(この場合、封止剤貯留部73の断面形状は矩形である。)、あるいは貫通孔開口周縁に貫通孔内方に凹なR部を設ける構成を採用して封止剤貯留部73を形成するようにしてもよい。その場合も、前記の技術思想にしたがって封止剤貯留部73が適切な容積となるように、形状と寸法を決定することができる。また、ボス部71の貫通孔開口周縁を上記以外の適宜の形状に加工することも自由である。   In the above embodiment, the configuration in which the through-hole inwardly protruding R portion is provided on the periphery of the through-hole opening of the boss portion 71 is illustrated, but instead of the inwardly protruding R portion, it is illustrated in FIG. 3A. As shown in FIG. 3B, a configuration in which a counterbore portion having an appropriate size is provided in the through-hole inner through-hole opening periphery (in this case, a sealant reservoir) 73 has a rectangular cross-sectional shape.) Alternatively, the sealant reservoir 73 may be formed by adopting a configuration in which a concave R portion is provided inwardly in the through hole at the periphery of the through hole opening. Also in that case, the shape and dimensions can be determined so that the sealant reservoir 73 has an appropriate volume in accordance with the above technical idea. Moreover, it is also free to process the through-hole opening periphery of the boss | hub part 71 in appropriate shapes other than the above.

次に、本実施形態に係るLR6タイプ(単3形)筒型アルカリ電池1において、図1に例示したボス部71の貫通孔内方に凸なR部を設けた場合の封止層形成の効果について、R部の寸法を変えて試験した結果を説明する。表1に示すように、R部の半径Rを0.1mmから0.9mmまで、0.1mmピッチで変えて、集電子51の胴部51bとボス部71の貫通孔内周面74との境界面の封止剤Sの塗布状態を調べた。調査の手法としては、それぞれ封口ガスケット70のボス部71と封口体50の集電子51とを前記の手順で組み付けた後、ボス部71を切り開いて境界面の封止剤塗布状態を調べることとした。なお、表1において、断面積は、対応するRの値に対する図1の網掛け部の断面積を、ボス部上面貫通孔開口直径(図1の符号φ)は、ボス部71の上面72における開口直径、言い換えれば、上面72において平面から貫通孔側の曲面に移行開始する境界点が描く円の直径を示しており、対応するRの値が大となれば同様に大となる。なお、試験に用いたLR6タイプ(単3形)筒型アルカリ電池では、集電子51の胴部51bの直径は1.3mm、頭部51aの直径(図1の符号φ)は2.8mmである。 Next, in the LR6 type (AA) cylindrical alkaline battery 1 according to this embodiment, a sealing layer is formed when a convex R portion is provided inward of the through hole of the boss portion 71 illustrated in FIG. About the effect, the result of having tested by changing the dimension of R part is demonstrated. As shown in Table 1, by changing the radius R of the R portion from 0.1 mm to 0.9 mm at a pitch of 0.1 mm, the body portion 51b of the current collector 51 and the through hole inner peripheral surface 74 of the boss portion 71 The application state of the sealing agent S on the boundary surface was examined. As a method of investigation, after assembling the boss part 71 of the sealing gasket 70 and the current collector 51 of the sealing body 50 in the above-described procedure, the boss part 71 is opened and the sealing agent application state on the boundary surface is examined. did. In Table 1, the cross-sectional area is the cross-sectional area of the shaded portion in FIG. 1 with respect to the corresponding R value, and the boss portion upper surface through-hole opening diameter (symbol φ 2 in FIG. 1) is the upper surface 72 of the boss portion 71. In other words, the diameter of the circle drawn by the boundary point at which the transition starts from the flat surface to the curved surface on the through hole side on the upper surface 72 is shown, and the corresponding R value increases as well. In the LR6 type (AA) cylindrical alkaline battery used in the test, the diameter of the body 51b of the current collector 51 is 1.3 mm, and the diameter of the head 51a (reference numeral φ 1 in FIG. 1 ) is 2.8 mm. It is.

Figure 2015176655
Figure 2015176655

表1に示すように、Rの値が0.2mm〜0.7mmの範囲では、封口ガスケット70のボス部71内周面74と集電子51の胴部51b外周面との境界面は適切に封止剤Sが塗布された状態であって、適切な封止状態が得られていることがわかった。一方、Rの値が0.1mmであった場合は境界面の封止剤塗布状態が適切でなかったが、これは、Rの値が小さすぎて封止剤貯留部73の容積が適切に確保できなかったため、境界面に十分な封止剤Sを供給することができなかったことが原因と考えられる。また、Rの値が0.8mm、0.9mmであった場合にも、境界面の封止剤塗布状態が適切でなかったと判定されたが、これは、対応するボス部上面貫通孔開口直径からも明らかなように、Rの値が大きすぎて当該開口直径が集電子51の頭部51aの直径より大となり、封止剤Sが頭部51aとボス部上面72との間隙から漏出したことが原因と考えられる。   As shown in Table 1, when the value of R is in the range of 0.2 mm to 0.7 mm, the boundary surface between the inner peripheral surface 74 of the boss portion 71 of the sealing gasket 70 and the outer peripheral surface of the trunk portion 51b of the current collector 51 is adequate. It was found that the sealant S was applied and an appropriate sealing state was obtained. On the other hand, when the value of R was 0.1 mm, the state of application of the sealant on the boundary surface was not appropriate, but this was because the value of R was too small and the volume of the sealant reservoir 73 was appropriate. It was thought that the reason was that sufficient sealant S could not be supplied to the boundary surface because it could not be secured. In addition, when the value of R was 0.8 mm and 0.9 mm, it was determined that the sealing agent application state on the boundary surface was not appropriate. As apparent from FIG. 4, the value of R is too large, the opening diameter becomes larger than the diameter of the head 51a of the current collector 51, and the sealant S leaks from the gap between the head 51a and the boss portion upper surface 72. This is thought to be the cause.

次に、表1の場合と同様のLR6タイプ(単3形)筒型アルカリ電池1において、図3Aに例示したボス部71の貫通孔内方に面取り部を設けた場合の封止層形成の効果について、面取り寸法を変えて試験した結果について説明する。表2に示すように、面取り寸法Cを0.1mmから0.9mmまで、0.1mmピッチで変えて、集電子51の胴部51bとボス部71の貫通孔内周面74との境界面の封止剤Sの塗布状態を調べた。調査の手法も表1の場合と同様である。なお、表2において、断面積は表1と同様であるが、ボス部上面貫通孔開口直径は、ボス部71の上面72における開口直径、言い換えれば、上面72において平面から面取り部の斜面に移行開始する境界点が描く円の直径を示しており、対応するCの値が大となれば同様に大となる。   Next, in the same LR6 type (AA) cylindrical alkaline battery 1 as in Table 1, a sealing layer is formed when a chamfered portion is provided inside the through hole of the boss portion 71 illustrated in FIG. 3A. About the effect, the result of having tested by changing the chamfer dimension will be described. As shown in Table 2, the chamfer dimension C is changed from 0.1 mm to 0.9 mm at a pitch of 0.1 mm, and the boundary surface between the body 51b of the current collector 51 and the inner peripheral surface 74 of the through hole of the boss 71 The application state of the sealing agent S was examined. The investigation method is the same as in Table 1. In Table 2, the cross-sectional area is the same as in Table 1, but the boss portion upper surface through-hole opening diameter is changed from the opening diameter on the upper surface 72 of the boss portion 71, in other words, from the flat surface to the slope of the chamfered portion on the upper surface 72. The diameter of the circle drawn by the starting boundary point is shown, and the corresponding C value increases as the corresponding C value increases.

Figure 2015176655
Figure 2015176655

表2に示すように、試験結果は表1の場合と同傾向であり、Cの値が0.2mm〜0.7mmの範囲では、封口ガスケット70のボス部71内周面74と集電子51の胴部51b外周面との境界面は適切に封止剤Sが塗布された状態であって、適切な封止状態が得られていることがわかった。一方、Cの値が0.1mmであった場合は境界面の封止剤塗布状態が適切でなかったが、これは、Cの値が小さすぎて封止剤貯留部73の容積が適切に確保できなかったため、境界面に十分な封止剤Sを供給することができなかったことが原因と考えられる。また、Cの値が0.8mm、0.9mmであった場合にも、境界面の封止剤塗布状態が適切でなかったと判定されたが、これは、対応するボス部上面貫通孔開口直径からも明らかなように、Cの値が大きすぎて当該開口直径が集電子頭部51aの直径より大となり、封止剤Sが頭部51aとボス部上面72との間隙から漏出したことが原因と考えられる。   As shown in Table 2, the test results have the same tendency as in Table 1. When the value of C is in the range of 0.2 mm to 0.7 mm, the inner peripheral surface 74 of the boss portion 71 of the sealing gasket 70 and the current collector 51. It was found that the boundary surface with the outer peripheral surface of the body portion 51b was in a state where the sealant S was appropriately applied, and an appropriate sealing state was obtained. On the other hand, when the value of C was 0.1 mm, the state of application of the sealant on the boundary surface was not appropriate, but this was because the value of C was too small and the volume of the sealant reservoir 73 was appropriate. It was thought that the reason was that sufficient sealant S could not be supplied to the boundary surface because it could not be secured. In addition, when the value of C was 0.8 mm and 0.9 mm, it was determined that the state of application of the sealant on the boundary surface was not appropriate. As apparent from FIG. 4, the value of C is too large, the opening diameter becomes larger than the diameter of the current collector head 51a, and the sealing agent S leaks from the gap between the head 51a and the boss portion upper surface 72. Possible cause.

なお、図3B、図3Cに例示したような、封止剤貯留部73の断面形状が異なる構成の筒型電池にあっても、その断面積の条件が表1、表2の結果と合致するように断面形状及び寸法を決定することにより、同様の効果を得ることができるものである。   In addition, even in the case of a cylindrical battery having a configuration in which the cross-sectional shape of the sealant reservoir 73 is different as illustrated in FIGS. 3B and 3C, the conditions of the cross-sectional area agree with the results in Tables 1 and 2. Thus, the same effect can be acquired by determining a cross-sectional shape and a dimension.

以上詳細に説明したように、本発明の実施形態に係る筒型アルカリ電池1によれば、集電子51と封口ガスケット70のボス部72との間を、封止剤Sによって形成された封止層をもって適切に封止することが可能となり、電池の液漏れを効果的に防止することが可能となる。   As described above in detail, according to the cylindrical alkaline battery 1 according to the embodiment of the present invention, the sealing formed by the sealing agent S between the current collector 51 and the boss portion 72 of the sealing gasket 70. It becomes possible to seal appropriately with the layer, and it is possible to effectively prevent battery leakage.

なお、本発明の実施形態について、LR6タイプ(単3形)筒型(円筒形)アルカリ電池1を例にとって説明したが、本発明は、アルカリ電池以外の形式の電池にも適宜適用することができる。また、適用する電池の容量タイプはLR6タイプ(単3形)以外であってもよく、その場合には集電子51の寸法に合わせて適宜封止剤貯留部73の断面形状、寸法を変更すれば、同様の効果を得ることが可能である。   The embodiment of the present invention has been described by taking the LR6 type (AA) cylindrical (cylindrical) alkaline battery 1 as an example, but the present invention can be applied to a battery of a type other than the alkaline battery as appropriate. it can. In addition, the capacity type of the battery to be applied may be other than the LR6 type (AA type). In that case, the cross-sectional shape and dimensions of the sealant reservoir 73 are appropriately changed in accordance with the dimensions of the current collector 51. In this case, the same effect can be obtained.

1 筒型アルカリ電池 10 正極缶 10a 開口部
20 正極合剤 30 セパレータ 40 ゲル状負極合剤
50 封口体 51 負極集電子 51a 頭部 51b 胴部
60 負極端子板 70 封口ガスケット 71 ボス部
72 円盤部 73 封止剤貯留部 74 ボス部内周面
DESCRIPTION OF SYMBOLS 1 Cylindrical alkaline battery 10 Positive electrode can 10a Opening part 20 Positive electrode mixture 30 Separator 40 Gel-like negative electrode mixture 50 Sealing body 51 Negative electrode current collection 51a Head part 51b Trunk part 60 Negative electrode terminal board 70 Sealing gasket 71 Boss part 72 Disk part 73 Sealant storage part 74 Boss part inner peripheral surface

Claims (3)

有底円筒状の電池缶内に、環状の正極合剤と、当該正極合剤の内側に配置される有底円筒状のセパレータと、当該セパレータの内側に配置される負極ゲルとが収納されているとともに、前記電池缶の開口に負極端子板が封口ガスケットを介して嵌着されてなる筒型電池であって、
前記封口ガスケットは、略円盤状に一体的に成形された樹脂からなり、前記円盤の中心にて上下方向に中空円筒状に突設されているボス部を有し、
前記封口ガスケットの前記ボス部が有する貫通孔に前記負極端子板に固設されている棒状の集電子が、前記集電子端部に拡径部として形成されている頭部表面と前記ボス部の上面とが密接するように圧入状態で貫通挿入されており、
前記ボス部に設けられている前記貫通孔の前記集電子に面する内周端縁部に、前記集電子と前記貫通孔内周面との間を少なくとも液密に封止する封止層を形成するための封止剤を貯留する封止剤貯留部が形成されている、
ことを特徴とする筒型電池。
An annular positive electrode mixture, a bottomed cylindrical separator disposed inside the positive electrode mixture, and a negative electrode gel disposed inside the separator are housed in a bottomed cylindrical battery can. And a negative battery terminal plate fitted into the opening of the battery can via a sealing gasket,
The sealing gasket is made of a resin integrally formed in a substantially disc shape, and has a boss portion protruding in a hollow cylindrical shape in the vertical direction at the center of the disc,
A rod-shaped current collector fixed to the negative electrode terminal plate in a through hole of the sealing gasket has a head surface formed as an enlarged diameter portion at the current collecting end portion and the boss portion. It is inserted in a press-fit state so that the top surface is in close contact,
A sealing layer that at least liquid-tightly seals between the current collector and the inner peripheral surface of the through hole is provided on an inner peripheral edge of the through hole provided in the boss portion that faces the current collector. A sealant reservoir for storing a sealant for forming is formed,
A cylindrical battery characterized by that.
前記封止剤貯留部は、前記ボス部の前記貫通孔内周端縁部と、前記頭部表面と、前記集電子外周面とによって画成される略環状の空間として形成されることを特徴とする、請求項1記載の筒型電池。   The sealant storage part is formed as a substantially annular space defined by the inner peripheral edge of the through hole of the boss part, the head surface, and the outer peripheral surface of the current collector. The cylindrical battery according to claim 1. 有底円筒状の電池缶内に、環状の正極合剤と、当該正極合剤の内側に配置される有底円筒状のセパレータと、当該セパレータの内側に配置される負極ゲルとが収納されているとともに、前記電池缶の開口に負極端子板が封口ガスケットを介して嵌着されてなり、
前記封口ガスケットは、略円盤状に一体的に成形された樹脂からなり、前記円盤の中心にて上下方向に中空円筒状に突設されているボス部を有し、
前記封口ガスケットの前記ボス部が有する貫通孔に前記負極端子板に固設されている棒状の集電子が、前記集電子端部に拡径部として形成されている頭部表面と前記ボス部の上面とが密接するように圧入状態で貫通挿入されており、
前記ボス部に設けられている前記貫通孔の前記集電子に面する内周端縁部に、前記集電子と前記貫通孔内周面との間を少なくとも液密に封止する封止層を形成するための封止剤を貯留する封止剤貯留部が形成されている筒型電池の製造方法であって、
前記ボス部に前記集電子を挿入する際に、前記集電子外周部の前記頭部と前記ボス部上面との間の領域の少なくとも一部に前記封止剤を環状に塗布した後、前記ボス部上面を前記頭部表面に対して一時的に圧接させて、前記封止剤を前記集電子外周面と前記ボス部の前記貫通孔内周面との間に供給する工程を含む、
ことを特徴とする筒型電池の製造方法。
An annular positive electrode mixture, a bottomed cylindrical separator disposed inside the positive electrode mixture, and a negative electrode gel disposed inside the separator are housed in a bottomed cylindrical battery can. And a negative electrode terminal plate is fitted to the opening of the battery can via a sealing gasket,
The sealing gasket is made of a resin integrally formed in a substantially disc shape, and has a boss portion protruding in a hollow cylindrical shape in the vertical direction at the center of the disc,
A rod-shaped current collector fixed to the negative electrode terminal plate in a through hole of the sealing gasket has a head surface formed as an enlarged diameter portion at the current collecting end portion and the boss portion. It is inserted in a press-fit state so that the top surface is in close contact,
A sealing layer that at least liquid-tightly seals between the current collector and the inner peripheral surface of the through hole is provided on an inner peripheral edge of the through hole provided in the boss portion that faces the current collector. A method for manufacturing a cylindrical battery in which a sealant reservoir for storing a sealant for forming is formed,
When the current collector is inserted into the boss portion, the sealant is annularly applied to at least a part of a region between the head portion of the current collector outer peripheral portion and the upper surface of the boss portion, and then the boss Including a step of temporarily pressing a part upper surface against the head surface and supplying the sealant between the current collecting outer peripheral surface and the through hole inner peripheral surface of the boss portion;
A method of manufacturing a cylindrical battery.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106784448A (en) * 2016-12-22 2017-05-31 泰州久诺杰电子科技有限公司 A kind of battery rubber sheet gasket with positioning action
JP2017117670A (en) * 2015-12-24 2017-06-29 Fdkエナジー株式会社 Cylindrical battery and method of manufacturing cylindrical battery
JP2019129071A (en) * 2018-01-24 2019-08-01 Fdk株式会社 Alkaline battery

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JP2011119153A (en) * 2009-12-04 2011-06-16 Panasonic Corp Alkaline battery
JP2016517145A (en) * 2013-03-29 2016-06-09 ザ ジレット コンパニー End cap assembly for electrochemical cells

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Publication number Priority date Publication date Assignee Title
JP2011119153A (en) * 2009-12-04 2011-06-16 Panasonic Corp Alkaline battery
JP2016517145A (en) * 2013-03-29 2016-06-09 ザ ジレット コンパニー End cap assembly for electrochemical cells

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Publication number Priority date Publication date Assignee Title
JP2017117670A (en) * 2015-12-24 2017-06-29 Fdkエナジー株式会社 Cylindrical battery and method of manufacturing cylindrical battery
CN106784448A (en) * 2016-12-22 2017-05-31 泰州久诺杰电子科技有限公司 A kind of battery rubber sheet gasket with positioning action
JP2019129071A (en) * 2018-01-24 2019-08-01 Fdk株式会社 Alkaline battery
JP7122117B2 (en) 2018-01-24 2022-08-19 Fdk株式会社 alkaline battery

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