JP2015166501A - Method for producing false-twist textured yarn for black formal clothing and fabric - Google Patents

Method for producing false-twist textured yarn for black formal clothing and fabric Download PDF

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JP2015166501A
JP2015166501A JP2014040600A JP2014040600A JP2015166501A JP 2015166501 A JP2015166501 A JP 2015166501A JP 2014040600 A JP2014040600 A JP 2014040600A JP 2014040600 A JP2014040600 A JP 2014040600A JP 2015166501 A JP2015166501 A JP 2015166501A
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JP6259318B2 (en
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一廣 小森
Kazuhiro Komori
一廣 小森
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Unitika Trading Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a method for producing a false-twist textured yarn for black formal clothing capable of imparting aesthetic properties such as black color development, deep colorability, texture and drape properties, as well as an excellent and long-lasting heat insulation effect regardless of weather and indoor or outdoor to a fabric and to provide a fabric including a textured yarn produced by the method.SOLUTION: There is provided a method for producing a false-twist textured yarn that is composed of polyester filaments containing far-infrared radioactive fine particles and exothermic fine particles. The method for producing a false-twist textured yarn for black formal clothing includes: heat treating a polyester highly-oriented undrawn yarn without drawing; and then simultaneously drawing and false twisting the heat treated polyester highly-oriented undrawn yarn. There is also provided a fabric obtained by using the false-twist textured yarn.

Description

本発明は、布帛にしたとき優れた保温効果を発現するブラックフォーマル衣料用仮撚加工糸の製法と、その製法による仮撚糸を使用した布帛とに関するものである。   The present invention relates to a method for producing a false twisted yarn for black formal clothing that exhibits an excellent heat retaining effect when made into a fabric, and a fabric using a false twisted yarn produced by the method.

ポリエステルフィラメント糸は、物理的・化学的な特性に優れているため、イージーケア素材として、多くの衣料製品に使用されている。   Polyester filament yarns are excellent in physical and chemical properties, and are used as an easy care material in many clothing products.

衣料用途の中に、冠婚葬祭時に着用する礼服、ブラックフォーマル衣料という用途がある。使用素材として、メンズ用では、主にウールもしくはウール混素材が使用され、レディス用では、審美性に優れるポリエステル素材が主に使用されている。   Among the garments, there are garments worn during ceremonies and black formal garments. As a material used, for men, mainly wool or a wool blend material is used, and for ladies, a polyester material excellent in aesthetics is mainly used.

中でも、ポリエステル素材については、布帛にしたとき黒色の発色性や深色性などを十分発現させうるものが、ブラックフォーマル衣料向けには好ましいとされている。例えば、微細シリカを含有するポリマーを繊維化した後、これをアルカリ処理して繊維表面を粗面化する、又は糸加工により繊維間に空隙を設けるなどして、光散逸を抑えて深色性を与える方法などが提案されている。さらに、繊維布帛表面にフッ素系樹脂やシリコン系樹脂などを付与して深色性を発現させる方法なども提案されている。   Among them, polyester materials that can sufficiently develop black color developability and deep colorability when made into fabrics are preferred for black formal clothing. For example, after fiberizing a polymer containing fine silica, this is alkali-treated to roughen the fiber surface, or by providing voids between the fibers by thread processing, etc. to suppress light dissipation and deep color There have been proposed methods of giving In addition, a method has also been proposed in which a fluorine-based resin, a silicon-based resin, or the like is applied to the fiber fabric surface to develop deep color properties.

また、ブラックフォーマル衣料は、用途の点から、重ね着されることは通常あまりない。したがって、冬の屋外でブラックフォーマル衣料を着用する場合には、保温性や温感調節機能などが求められる。また屋外だけでなく屋内でも例えば葬儀場などでは、室温が特定の理由により低く調節されているから、屋外使用の場合と同様、同衣服には保温性や温感調節機能などが求められる。   Also, black formal garments are usually not often layered from the point of use. Therefore, when wearing black formal garments outdoors in winter, it is required to have heat retaining properties and a function to adjust warmth. In addition to indoors, for example, in a funeral hall, the room temperature is adjusted to be low for a specific reason. Therefore, as in the case of outdoor use, the clothing is required to have a heat retaining property and a temperature adjustment function.

布帛に保温性を付える方法としては、これまでに多くのものが提案されている。例えば、デッドエアー層や吸湿発熱機能を利用する方法、太陽光を熱に変換する吸光熱変換効果を利用する方法などが提案されている。   Many methods have been proposed so far to impart heat retention to fabrics. For example, a method using a dead air layer or a hygroscopic heat generation function, a method using an absorption heat conversion effect for converting sunlight into heat, and the like have been proposed.

しかしながら、デッドエアー層を利用して保温性を実現する方法とは、衣服内に溜まった空気を利用して放熱を抑えるという消極的な手法に過ぎないため、持続性に欠け、十分な保温性は期待できない。また、吸湿発熱機能の利用とは、発汗時の湿気などを吸収することにより発熱する繊維を使用し保温性を得ようとする手法であり、湿気を吸収した時には発熱するものの持続性に乏しく、すぐに放熱してしまうという問題がある。また、吸光熱変換効果に利用については、積極的な発熱作用により、晴天時の屋外においては十分な保温効果が認められる。しかし、太陽光の照射量の少ない雨天時や室内では、その効果がほとんど期待できないという問題がある。   However, the method of achieving heat retention using the dead air layer is merely a passive method of suppressing heat dissipation using air accumulated in clothes, so it lacks sustainability and has sufficient heat retention. Cannot be expected. In addition, the use of the moisture absorption heat generation function is a technique to obtain heat retention by using a fiber that generates heat by absorbing moisture at the time of sweating, and when it absorbs moisture, it generates heat but lacks sustainability. There is a problem of heat dissipation immediately. In addition, when used for the absorption heat conversion effect, a sufficient heat-retaining effect is observed outdoors in fine weather due to the positive heat generation. However, there is a problem that the effect can hardly be expected in rainy weather or indoors where the amount of sunlight is small.

近年、上記方法の他に、遠赤外線を利用する方法も提案されている。具体的には、遠赤外線領域の電磁波を受けることで身体内部の細胞組織が共鳴振動し、これにより血行が促進され、保温効果が得られるというものである。例えば、特許文献1には、遠赤外線放射性微粒子を含有する遠赤外線放射性複合繊維が記載されている。しかしながら、同繊維から放射される遠赤外線の放射量には限界があり、十分な保温効果が得られないという問題がある。   In recent years, besides the above method, a method using far infrared rays has been proposed. Specifically, by receiving electromagnetic waves in the far-infrared region, cellular tissues inside the body resonate and vibrate, thereby promoting blood circulation and obtaining a heat retaining effect. For example, Patent Document 1 describes a far-infrared radioactive composite fiber containing far-infrared radioactive fine particles. However, there is a limit to the amount of far-infrared radiation emitted from the fiber, and there is a problem that a sufficient heat retention effect cannot be obtained.

特開平9−59827号公報Japanese Patent Laid-Open No. 9-59827

以上のように、布帛としたとき黒色の発色性や深色性などを十分向上させて所望の審美性を得ると同時に、屋内外で優れた保温効果を持続性よく発現させる手法は未だ提案されていない。そして、布帛へこのような特性を与えうる糸並びにその糸を使用した布帛をブラックフォーマル衣料に適用した例も無論見当たらない。   As described above, there has been proposed a technique for sufficiently improving the black color developability and deep colorability to obtain desired aesthetics when used as a fabric, and at the same time, exhibiting an excellent heat retention effect indoors and outdoors. Not. Of course, there is no example of applying the yarn that can give such characteristics to the fabric and the fabric using the yarn to the black formal garment.

本発明はこのような従来技術の欠点を解消するものであり、黒色の発色性、深色性、風合い及びドレープ性などの審美性と共に、天候その他屋内外を問わず持続性ある優れた保温効果を布帛に与えることができるブラックフォーマル衣料用仮撚加工糸の製法と、その製法による加工糸を使用した布帛とを提供することを技術的課題とするものである。   The present invention eliminates the disadvantages of the prior art, and has an excellent heat retention effect that is durable regardless of the weather or other indoors and outdoors, as well as aesthetics such as black color development, deep color, texture and drape. It is a technical problem to provide a method for producing a false twisted yarn for black formal clothing that can be applied to a fabric, and a fabric using the processed yarn produced by the method.

本発明者は、上記課題を解決するべく鋭意検討した結果、赤外線放射性微粒子と発熱性微粒子とを含有するポリエステル高配向未延伸糸を特定の方法で仮撚加工することで、布帛に所定の審美性と優れた保温性とを付与できる加工糸が得られることを見出し、本発明をなすに至った。   As a result of intensive studies to solve the above-mentioned problems, the present inventor has performed a predetermined aesthetic treatment on a fabric by false twisting a polyester highly oriented unstretched yarn containing infrared radiation fine particles and exothermic fine particles by a specific method. As a result, it was found that a processed yarn capable of imparting good properties and excellent heat retaining properties was obtained, and the present invention was made.

すなわち、本発明は以下を要旨とするものである。   That is, this invention makes the following a summary.

(1)遠赤外線放射性微粒子と発熱性微粒子とを含有するポリエステルフィラメントから構成される仮撚加工糸の製造方法であって、ポリエステル高配向未延伸糸を延伸することなく熱処理した後、延伸同時仮撚りすることを特徴とするブラックフォーマル衣料用仮撚加工糸の製造方法。
(2)前記ポリエステルフィラメントの断面が芯鞘構造をなし、前記遠赤外線放射性微粒子が鞘成分に含まれ、前記遠赤外線放射性微粒子の含有量が鞘成分100質量部に対して0.1〜2.5質量部であり、かつフィラメントにおける芯鞘の質量比率(芯成分/鞘成分)が95/5〜15/85の範囲にあることを特徴とする(1)記載のブラックフォーマル衣料用仮撚加工糸の製造方法。
(3)前記発熱性微粒子が前記ポリエステルフィラメントの鞘成分100質量部に対して0.1〜2.5質量部含まれていることを特徴とする(2)記載のブラックフォーマル衣料用仮撚加工糸の製造方法。
(4)(1)〜(3)いずれかに記載の方法により得られたブラックフォーマル衣料用仮撚加工糸を用いてなる布帛であって、L*値が16以下であることを特徴とする布帛。
(1) A method for producing a false twisted yarn comprising polyester filaments containing far-infrared radioactive fine particles and exothermic fine particles, wherein the polyester highly oriented unstretched yarn is heat-treated without being stretched and then simultaneously stretched. A method for producing false twisted yarn for black formal clothing, characterized by twisting.
(2) The cross section of the polyester filament has a core-sheath structure, the far infrared radiation fine particles are contained in a sheath component, and the content of the far infrared radiation fine particles is 0.1-2. The false twisting process for black formal clothing according to (1), wherein the mass ratio of the core-sheath in the filament (core component / sheath component) is in the range of 95/5 to 15/85. Yarn manufacturing method.
(3) 0.1 to 2.5 parts by mass of the exothermic fine particles are contained in 100 parts by mass of the sheath component of the polyester filament. Yarn manufacturing method.
(4) A fabric using the false twisted yarn for black formal clothing obtained by the method according to any one of (1) to (3), wherein the L * value is 16 or less. Fabric.

本発明の製法によれば、布帛に対し黒色の発色性や深色性、風合い、ドレープ性などの審美性に加え、優れた保温性をも付与できるブラックフォーマル衣料用仮撚加工糸が提供できる。そして、本発明による加工糸を使用した布帛は、秋冬向けブラックフォーマル衣料に好適である。   According to the production method of the present invention, it is possible to provide a false twisted yarn for black formal clothing that can impart excellent heat retention in addition to aesthetic properties such as black color developability, deep color, texture, and drape on the fabric. . The fabric using the processed yarn according to the present invention is suitable for black formal clothing for autumn and winter.

以下、本発明を詳細に説明する。
本発明の製法では、ポリエステル高配向未延伸糸を特定の方法で延伸同時仮撚りする。ポリエステル高配向未延伸糸を構成するフィラメント(単糸)には、遠赤外線放射性微粒子と発熱性微粒子とが含有されている。
Hereinafter, the present invention will be described in detail.
In the production method of the present invention, a polyester highly oriented undrawn yarn is drawn and false-twisted by a specific method. The filament (single yarn) constituting the polyester highly oriented undrawn yarn contains far-infrared radiation fine particles and exothermic fine particles.

本発明におけるポリエステル高配向未延伸糸は、ポリアルキレンテレフタレートに代表されるポリエステルから構成されるものであればよい。具体的には、ポリエチレンテレフタレート(PET)、ポリブチレンテレフタレート、ポリトリメチレンテレフタレートなどがあげられる。また、粘度、熱的特性、相溶性などに鑑みて、イソフタル酸、5−スルホイソフタル酸などの芳香族ジカルボン酸、アジピン酸、コハク酸、スベリン酸、セバシン酸、ドデカン二酸などの脂肪族ジカルボン酸、及びエチレングリコール、プロピレングリコール、1,4−ブタンジオール、1,4−シクロヘキサンジメタノールなどの脂肪族ジオールや、グリコール酸、ヒドロキシ酪酸、ヒドロキシ吉草酸、ヒドロキシカプロン酸、ヒドロキシペンタン酸、ヒドロキシヘプタン酸、ヒドロキシオクタン酸などのヒドロキシカルボン酸、ε−カプロラクトンなどの脂肪族ラクトンなどを共重合させてもよい。
遠赤外線放射微粒子としては、マイカ、方解石などの鉱物、酸化錫、アルミナ、二酸化珪素などの酸化物系セラミックス、炭化珪素、炭化ホウ素などの炭化物系セラミックス、白金、タングステンなどの金属類などがあげられる。中でも仮撚時のガイド摩耗を抑える観点から、マイカなどのような硬度の低いものが好ましい。
The polyester highly oriented unstretched yarn in the present invention may be any one composed of polyester represented by polyalkylene terephthalate. Specific examples include polyethylene terephthalate (PET), polybutylene terephthalate, and polytrimethylene terephthalate. In view of viscosity, thermal characteristics, compatibility, etc., aromatic dicarboxylic acids such as isophthalic acid and 5-sulfoisophthalic acid, and aliphatic dicarboxylic acids such as adipic acid, succinic acid, suberic acid, sebacic acid and dodecanedioic acid. Acids and aliphatic diols such as ethylene glycol, propylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, glycolic acid, hydroxybutyric acid, hydroxyvaleric acid, hydroxycaproic acid, hydroxypentanoic acid, hydroxyheptane Acids, hydroxycarboxylic acids such as hydroxyoctanoic acid, and aliphatic lactones such as ε-caprolactone may be copolymerized.
Examples of far-infrared radiation fine particles include minerals such as mica and calcite, oxide ceramics such as tin oxide, alumina and silicon dioxide, carbide ceramics such as silicon carbide and boron carbide, and metals such as platinum and tungsten. . In particular, from the viewpoint of suppressing guide wear during false twisting, a material having low hardness such as mica is preferable.

また、発熱性微粒子としては、太陽光などの電磁波を吸収し発熱するものであればどのようなものでも使用できる。具体的には、炭化ジルコニウムやカーボンなどが好ましい。   Any exothermic fine particles can be used as long as they absorb electromagnetic waves such as sunlight and generate heat. Specifically, zirconium carbide or carbon is preferable.

ポリエステル高配向未延伸糸を構成するフィラメントの構造は、特に限定されるものでないが、保温性の観点から、芯鞘構造をなし、かつ遠赤外線放射性微粒子がその鞘成分に所定量含有されているものが好ましい。これは、遠赤外線放射性微粒子を鞘成分に配することで、微粒子と人体との距離を短くすることができるから、結果として遠赤外線が人体に到達し易くなるからである。   The structure of the filament constituting the polyester highly oriented undrawn yarn is not particularly limited, but from the viewpoint of heat retention, it has a core-sheath structure, and far infrared radiation fine particles are contained in a predetermined amount in the sheath component. Those are preferred. This is because by disposing far-infrared radiation fine particles in the sheath component, the distance between the fine particles and the human body can be shortened, and as a result, far-infrared rays easily reach the human body.

また、本発明では、発熱性微粒子もフィラメント鞘成分に含有されていることが好ましい。これは、鞘成分すなわちフィラメント外側の方が光を受け易いからである。また、本発明では、発熱性微粒子が発する熱を、衣服内や人体に対し暖かさを付与することに利用できるだけでなく、遠赤外線放射性微粒子そのものの温度上昇にも利用でき、遠赤外線放射性微粒子からは、温度上昇に応じて多くの遠赤外線が発せられるため、結果として優れた保温効果が奏される。特に、上記の理由から両微粒子をフィラメント鞘成分に配した場合には、鞘成分において両微粒子が近接することになるから、発熱性微粒子が発する熱をより利用し易くなり、遠赤外線放射効果が一層効率的に奏されることとなる。   In the present invention, the exothermic fine particles are also preferably contained in the filament sheath component. This is because the sheath component, that is, the outside of the filament is more susceptible to light. Further, in the present invention, the heat generated by the exothermic fine particles can be used not only to give warmth to clothes or the human body, but also to increase the temperature of the far-infrared radioactive fine particles themselves. Since many far-infrared rays are emitted as the temperature rises, an excellent heat retention effect is achieved as a result. In particular, when both the fine particles are arranged in the filament sheath component for the above reasons, both the fine particles are close to each other in the sheath component. This is more efficient.

遠赤外線放射性微粒子及び発熱性微粒子の含有量としては、特に限定されないが、通常、フィラメント100質量部に対して各々0.1〜10質量部であることが好ましい。
高配向未延伸糸のコスト及び紡糸操業性などは、一般に微粒子の含有量が増えるほど悪化する傾向にあるから、微粒子の含有量は少ないほど好ましいといえる。この点、本発明では、遠赤外線放射性微粒子と発熱性微粒子とを併用することで、発熱性微粒子が発する熱を遠赤外線放射性微粒子の温度上昇に利用し、これにより遠赤外線放射効果が促進されるという相乗効果が奏されるから、両微粒子の含有量を多少減らしても一定レベルの遠赤外線放射効果が確保できる。すなわち、本発明では、高配向未延伸糸のコスト及び紡糸操業性などを考慮して、両微粒子の含有量を多少減らしても、十分な保温効果が確保できるのである。
Although it does not specifically limit as content of a far-infrared radiation fine particle and an exothermic fine particle, Usually, it is preferable that it is 0.1-10 mass parts with respect to 100 mass parts of filaments, respectively.
Since the cost and spinning operability of the highly oriented undrawn yarn generally tend to deteriorate as the content of fine particles increases, it can be said that the smaller the content of fine particles, the better. In this respect, in the present invention, by using the far-infrared radioactive fine particles and the exothermic fine particles in combination, the heat generated by the exothermic fine particles is used to increase the temperature of the far-infrared radioactive fine particles, thereby promoting the far-infrared radiation effect. Thus, a certain level of far-infrared radiation effect can be secured even if the content of both fine particles is somewhat reduced. That is, in the present invention, a sufficient heat retaining effect can be secured even if the contents of both fine particles are slightly reduced in consideration of the cost of the highly oriented undrawn yarn and the spinning operability.

本発明では、両微粒子がフィラメント鞘成分に含まれていることが、優れた遠赤外線放射効果を得るうえで好ましい。この場合、両微粒子の含有量としては、鞘成分100質量部に対して各々0.1〜2.5質量部であることが好ましい。両微粒子の少なくとも一方の含有量が0.1質量部未満になると、所望の相乗効果が発揮されない傾向にある。他方、両微粒子の少なくとも一方の含有量が2.5質量部を超えると、紡糸操業性が悪化する傾向にある。   In the present invention, it is preferable that both fine particles are contained in the filament sheath component in order to obtain an excellent far-infrared radiation effect. In this case, the content of both fine particles is preferably 0.1 to 2.5 parts by mass with respect to 100 parts by mass of the sheath component. When the content of at least one of both fine particles is less than 0.1 parts by mass, the desired synergistic effect tends not to be exhibited. On the other hand, if the content of at least one of both fine particles exceeds 2.5 parts by mass, the spinning operability tends to deteriorate.

また、フィラメントの断面が芯鞘構造をなし、両微粒子をその鞘成分に含む場合、芯鞘の質量比率としては、95/5〜15/85の範囲が好ましく、85/15〜40/60の範囲がより好ましい。芯鞘の質量比率がこの範囲を満足すると、両微粒子が当該鞘成分に適度な量をもって配されることとなり、所定の保温効果を得るうえで有利となり、ひいては紡糸操業性も安定する。   Moreover, when the cross section of the filament has a core-sheath structure and both fine particles are included in the sheath component, the mass ratio of the core-sheath is preferably in the range of 95/5 to 15/85, and is 85/15 to 40/60. A range is more preferred. When the mass ratio of the core sheath satisfies this range, both fine particles are arranged in an appropriate amount to the sheath component, which is advantageous for obtaining a predetermined heat retaining effect, and thus spinning operability is also stabilized.

本発明の製法では、まず、上記した遠赤外線放射性微粒子と発熱性微粒子とを含有するポリエステルフィラメントから構成される高配向未延伸糸を用意する。次に、この高配向未延伸糸を延伸することなく熱処理する。この熱処理より、フィラメントの結晶化度のみが向上し、配向度は向上せず、むしろ低下していく。結晶化度が向上すると、次工程たる延伸同時仮撚り時にフィラメントが熱変形し難くなる。フィラメント断面の変形、扁平化を抑えることで、光沢の少ない布帛を得ることができるから、結果として所望の深色性が得られる。さらに、配向度が低くなると、フィラメントにおいて分散染料を吸尽・染着する非晶領域が増大し、分散染料をフィラメントにより多く吸尽させることができる。これにより、ブラックフォーマル衣料に適した発色性が得られる。   In the production method of the present invention, first, a highly oriented undrawn yarn composed of a polyester filament containing the above-described far-infrared radioactive fine particles and exothermic fine particles is prepared. Next, this highly oriented undrawn yarn is heat treated without drawing. By this heat treatment, only the degree of crystallinity of the filament is improved, and the degree of orientation is not improved, but rather decreases. When the degree of crystallinity is improved, the filament is less likely to be thermally deformed at the time of the simultaneous drawing and simultaneous twisting as the next step. By suppressing deformation and flattening of the filament cross section, a fabric with less gloss can be obtained, and as a result, desired deep color properties can be obtained. Further, when the degree of orientation is lowered, the amorphous region where the disperse dye is exhausted and dyed in the filament increases, and the disperse dye can be exhausted more in the filament. Thereby, the coloring property suitable for black formal clothing is obtained.

延伸同時仮撚りは、延伸しない通常の仮撚りと比べると、延伸する分、加撚ゾーンにおいて糸に大きな張力がかかる。このためフィラメントの断面は扁平化し易く、これにより布帛にしたとき光沢が生じ易くなる。さらに、通常の延伸同時仮撚りでは、大きな張力がかかった状態で仮撚ヒーターを通過するため、フィラメントの結晶化度、配向度が進み易く、結果、染料を吸尽し難くなり所望の深色性を得ることができない。ブラックフォーマル衣料に適した発色性、深色性を得ることは、分散染料をフィラメント内部に多く吸尽させ、かつ布帛の光沢を少なくすることにより可能であり、従来の延伸同時仮撚りでは、達成することができない。本発明における熱処理は、このような目的のために行うものである。   Compared with the normal false twist which does not extend | stretch, the extending | stretching simultaneous false twist applies a big tension | tensile_strength to a thread | yarn in a twisting zone by the part which extends | stretches. For this reason, the cross section of the filament is easily flattened, and thus gloss is easily generated when it is made into a fabric. Furthermore, in normal stretching simultaneous false twisting, it passes through the false twist heater in a state where a large tension is applied, so that the degree of crystallinity and orientation of the filament easily advances, and as a result, it becomes difficult to exhaust the dye and the desired deep color. I can't get sex. It is possible to obtain color development and deep color suitable for black formal clothing by exhausting a large amount of disperse dye inside the filament and reducing the gloss of the fabric. Can not do it. The heat treatment in the present invention is performed for such a purpose.

本発明では、延伸することなく熱処理した高配向未延伸糸を一旦巻き取り、その後仮撚機に導入することにより延伸同時仮撚りしてもよいが、通常は、コスト、糸質などを考慮し、熱処理装置を備えた仮撚機に高配向未延伸糸を導入し、熱処理後、糸を巻き取ることなく連続的に仮撚りすることが好ましい。この場合の熱処理装置としては、特殊なものは必要なく、通常は仮撚機備え付けのヒーターを用いて熱処理すればよい。仮撚加工機のヒーターとしては、非接触タイプのものが好ましい。また、仮撚機としては、特に限定されるものではないが、通常は、ピンタイプの低速仮撚機、ディスクタイプの高速仮撚機などが使用できる。   In the present invention, the highly oriented undrawn yarn that has been heat-treated without being drawn may be wound once, and then introduced into a false twisting machine to simultaneously draw the drawn false twist, but usually considering the cost, yarn quality, etc. It is preferable to introduce the highly oriented undrawn yarn into a false twisting machine equipped with a heat treatment apparatus, and continuously false twist after the heat treatment without winding the yarn. In this case, a special heat treatment apparatus is not required, and usually heat treatment may be performed using a heater provided with a false twister. As the heater of the false twisting machine, a non-contact type heater is preferable. Further, the false twisting machine is not particularly limited, but normally, a pin type low speed false twisting machine, a disk type high speed false twisting machine or the like can be used.

熱処理時の温度としては、最終的に得られる加工糸が、布帛としたときブラックフォーマル衣料に適した発色性、深色性などを発現できる温度であれば、特に限定されない。具体的には170℃〜230℃の範囲が好ましく、これに加えて、仮撚温度より10℃以上高いことがより好ましい。熱処理は、オーバーフィードをかけた状態で行うことが好ましく、このときのオーバーフィード率としては、0.5〜50%の範囲が好ましい。   The temperature at the time of the heat treatment is not particularly limited as long as the finally obtained processed yarn is a temperature at which color development and deep color suitable for black formal garments can be developed when made into a fabric. Specifically, a range of 170 ° C. to 230 ° C. is preferable, and in addition to this, it is more preferable that the temperature is higher by 10 ° C. than the false twisting temperature. The heat treatment is preferably performed with overfeed applied, and the overfeed rate at this time is preferably in the range of 0.5 to 50%.

高配向未延伸糸を延伸することなく熱処理した後は、延伸同時仮撚りする。これにより目的とする仮撚加工糸を得ることができる。延伸倍率としては、得られる加工糸の糸質物性を考慮して適宜設定してよく、特に限定されないが、通常は、糸切れ、延伸不良などを考慮して、1.2〜1.6倍の範囲が好ましい。さらに、仮撚温度(仮撚ヒーター温度)としては、仮撚りによって付与される撚歪みが固定できる温度であれば、特に限定されず、通常は、フィラメント間の融着を抑えながら形状固定できる温度を適宜選択すればよい。具体的には、160℃〜230℃が好ましい。   After heat-treating the highly oriented undrawn yarn without drawing, the drawing is simultaneously false twisted. Thereby, the target false twisted yarn can be obtained. The draw ratio may be appropriately set in consideration of the physical properties of the processed yarn to be obtained, and is not particularly limited, but is usually 1.2 to 1.6 times in consideration of yarn breakage, poor drawing, etc. The range of is preferable. Furthermore, the false twist temperature (false twist heater temperature) is not particularly limited as long as the twist strain imparted by false twist can be fixed. Usually, the temperature at which the shape can be fixed while suppressing fusion between filaments. May be appropriately selected. Specifically, 160 ° C to 230 ° C is preferable.

本発明により得られる仮撚加工糸のトータル繊度は、目的、性能に応じて適宜のものが選択可能であるが、通常は、布帛の風合い、深色性などを考慮して10〜440dtexが好ましく、30〜330dtexがより好ましく、50〜200dtexがさらに好ましい。また、加工糸の単糸繊度は、0.01〜10dtexが好ましく、0.1〜10dtexがより好ましく、0.1〜3dtexがさらに好ましい。   The total fineness of the false twisted yarn obtained according to the present invention can be appropriately selected according to the purpose and performance, but is usually preferably 10 to 440 dtex in consideration of fabric texture, deep color, and the like. 30 to 330 dtex is more preferable, and 50 to 200 dtex is more preferable. The single yarn fineness of the processed yarn is preferably 0.01 to 10 dtex, more preferably 0.1 to 10 dtex, and still more preferably 0.1 to 3 dtex.

仮撚加工糸を得た後は、生機を作製し、生機を染色加工することで本発明の布帛を得ることができる。布帛の組織としては、特に限定されない。例えば、織物の組織では、平織、斜文織、朱子織、多重織などが採用でき、編物の組織では、平編、パール編、リブ編、インターロック編などの丸編組織やハーフ編、デンビー編、アトラス編などの経編組織が採用できる。組織については、深色性の他、各種物性、堅牢度、ウォッシャブル性などを考慮し適切なものを選択すればよい。   After obtaining the false twisted yarn, the fabric of the present invention can be obtained by producing a raw machine and dyeing the raw machine. The structure of the fabric is not particularly limited. For example, plain weaving, oblique weaving, satin weaving, and multiple weaving can be used for woven fabrics. Circular knitting or half knitting such as flat knitting, pearl knitting, rib knitting, interlock knitting, denby, etc. Warp knitting organizations such as knitting and atlas knitting can be adopted. As for the organization, an appropriate one may be selected in consideration of various physical properties, fastness, and washability in addition to the deep color.

布帛には、本発明の効果を損なわない範囲で上記加工糸以外の糸が含まれていてもよい。上記加工糸以外の糸としては任意のものが使用できる。通常、布帛には、上記加工糸が全体の20〜100質量%の割合で含まれていることが好ましい。20質量%未満では、本発明の効果を得難い傾向にある。   The fabric may contain yarns other than the processed yarn as long as the effects of the present invention are not impaired. Any thread other than the processed thread can be used. Usually, it is preferable that the above-mentioned processed yarn is contained in a fabric in a proportion of 20 to 100% by mass. If it is less than 20 mass%, it tends to be difficult to obtain the effects of the present invention.

本発明では、布帛においてブラックフォーマル衣料に適した発色性、深色性及び風合いなどが発現するよう、予め仮撚加工糸の特性が調節されているので、染色加工は、通常の方法で行えばよい。黒色染料を使用して深みのある色彩を具現しようとする場合、従来の手法では、染料を10〜12%omf程度使用する必要があり、染色堅牢度にやや欠けるという問題があったが、本発明では、好ましくは10%omf未満、より好ましくは7%omf以上10%omf未満でも十分な発色性、深色性が期待でき、染料使用量を抑えることができるから、染色堅牢度も当然維持できる。   In the present invention, the properties of the false twisted yarn are adjusted in advance so that the cloth develops color development, deep color and texture suitable for black formal clothing. Good. When trying to realize a deep color using a black dye, the conventional method needs to use about 10 to 12% omf of the dye, and there is a problem that the color fastness is slightly lacking. In the invention, it is possible to expect sufficient color developability and deep color even if it is less than 10% omf, more preferably 7% omf or more and less than 10% omf, and the amount of dye used can be suppressed, so that the color fastness is naturally maintained. it can.

本発明の布帛では、明度を表わすL*値が16以下であることが好ましい。16を超える場合、特段の問題なく衣服に仕上げることができたとしても、ブラックフォーマル用途には適用し難くなる。明度は小さいほど発色性、深色性の点で好ましい。   In the fabric of the present invention, the L * value representing lightness is preferably 16 or less. If it exceeds 16, even if it can be finished into clothes without any particular problem, it will be difficult to apply to black formal use. Smaller lightness is preferable in terms of color developability and deep color.

本発明では、染色加工後、明度をさらに下げる目的で濃染加工してもよい。濃染加工としては公知の方法が採用できる。通常、フッ素系樹脂やシリコン系樹脂などを付与すれば、深色性をより発現させることができる。染色加工後にさらに濃染加工することにより、布帛のL*値を12以下程度まで下げることができる。   In the present invention, after dyeing, dark dyeing may be performed for the purpose of further reducing the brightness. A known method can be adopted as the deep dyeing process. Usually, if a fluorine-based resin, a silicon-based resin, or the like is added, deep color properties can be expressed more. By further deep dyeing after dyeing, the L * value of the fabric can be lowered to about 12 or less.

以下、実施例及び比較例をあげてさらに詳細に本発明を説明するが、本発明はこれらに限定されない。   EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is demonstrated in detail, this invention is not limited to these.

各測定方法及び評価方法は以下の通りである。   Each measuring method and evaluation method are as follows.

(1)遠赤外線放射効果
各実施例及び比較例で得られた布帛の遠赤外線放射強度を測定した。測定は、赤外分光光度計FT−IR装置(パーキンエルマー社製「Spectrum GX FT−IR(商品名)」)を使用し、測定温度40℃、測定波長域5〜20μmで行った。その際、同条件における黒体の遠赤外線放射強度も測定し、各波長における黒体の放射強度を100%とした場合の各布帛の放射強度の比率(%)を求め、各波長で算出された比率の平均値を平均放射率(%)として算出した。
(1) Far-infrared radiation effect The far-infrared radiation intensity | strength of the fabric obtained by each Example and the comparative example was measured. The measurement was performed using an infrared spectrophotometer FT-IR apparatus (“Spectrum GX FT-IR (trade name)” manufactured by PerkinElmer) at a measurement temperature of 40 ° C. and a measurement wavelength range of 5 to 20 μm. At that time, the far-infrared radiant intensity of the black body under the same conditions is also measured, and the ratio (%) of the radiant intensity of each fabric when the radiant intensity of the black body at each wavelength is defined as 100% is calculated at each wavelength. The average value of the ratio was calculated as the average emissivity (%).

(2)発熱特性
温度が20℃、湿度が65%に保たれた室内において、布帛表面にレフランプから照度10000LUXの光を照射し、裏面温度を時間毎にサーモグラフィー(NEC三栄株式会社製「サーモトレーサTH7102MX(商品名)」)で測定し、その最高到達温度で評価した。
(2) Heat generation characteristics In a room maintained at a temperature of 20 ° C. and humidity of 65%, the fabric surface was irradiated with light with an illuminance of 10000 LUX from a reflex lamp, and the back surface temperature was thermographed every hour ("Thermo Tracer" manufactured by NEC Sanei Co., Ltd.). TH7102MX (trade name) ") and evaluated at the highest temperature reached.

(3)明度(L*値)
JIS Z8729に準拠した方法で測定し、L*a*b*表示系で表したL*値を採用した。
(3) Lightness (L * value)
The L * value was measured by a method according to JIS Z8729 and expressed in L * a * b * display system.

(実施例1)
ポリエチレンテレフタレート98質量部に、遠赤外線放射性微粒子として平均粒子径3μmのマイカを1.0質量部、及び発熱性微粒子として平均粒子径1.5μmの炭化ジルコニウムを1.0質量部練り込んだ樹脂組成物と、ポリエチレンテレフタレートからなる樹脂とを用意した。そして、両者を複合紡糸機に導入し、前者を鞘成分に、後者を芯成分にそれぞれ配しつつ両者の質量比率(芯成分/鞘成分)が80/20となるように複合紡糸し、89.7dtex24fの高配向未延伸糸を得た。なお、紡糸操業性は良好であった。
Example 1
A resin composition in which 98 parts by mass of polyethylene terephthalate is kneaded with 1.0 part by mass of mica having an average particle size of 3 μm as far-infrared radiation fine particles and 1.0 part by mass of zirconium carbide with an average particle size of 1.5 μm as exothermic fine particles. And a resin made of polyethylene terephthalate were prepared. Then, both are introduced into a compound spinning machine, and the former is used as the sheath component and the latter is used as the core component, and the composite spinning is performed so that the mass ratio between the two (core component / sheath component) is 80/20. A highly oriented undrawn yarn of .7 dtex 24f was obtained. The spinning operability was good.

次に、熱処理のためのヒーターを備えた仮撚機(三菱重工業株式会社製「LS−6(商品名)」)に上記高配向未延伸糸を導入し、まず温度180℃、オーバーフィード率2.5%なる条件で熱処理した。そして巻き取ることなく連続的に、延伸倍率1.515倍、仮撚数4236T/M、仮撚方向Z、仮撚ヒーター温度170℃なる条件で延伸同時仮撚りし、62.0dtex24fの仮撚加工糸を得た。   Next, the highly oriented undrawn yarn was introduced into a false twisting machine (“LS-6 (trade name)” manufactured by Mitsubishi Heavy Industries, Ltd.) equipped with a heater for heat treatment. First, the temperature was 180 ° C. and the overfeed rate was 2 Heat treatment was performed at a condition of 5%. And without drawing up, the draw ratio is 1.515 times, the number of false twists is 4236 T / M, the false twist direction is Z, the false twist heater temperature is 170 ° C., and the false twist is 62.0 dtex24f. I got a thread.

その後、ダブルツイスターを使用して、仮撚加工糸をS方向に2500T/M、Z方向に2500T/Mの撚数で撚糸し、撚糸後、75℃、45分間の条件で真空セットした。そして、S方向に撚糸した糸及びZ方向に撚糸した糸を2:2に配列したビームを整経した後、緯糸として上記各々の方向に撚糸した糸を2:2の繰り返しで打ち込み、平二重組織の生機を得た。生機密度は、経糸145本/インチ、緯糸130本/インチであった。   Then, using a double twister, the false twisted yarn was twisted at a twist number of 2500 T / M in the S direction and 2500 T / M in the Z direction, and after twisting, vacuum setting was performed at 75 ° C. for 45 minutes. Then, after warping a beam in which yarns twisted in the S direction and yarns twisted in the Z direction are arranged in a ratio of 2: 2, the yarn twisted in each of the above directions as a weft is driven repeatedly 2: 2, I got the life of a heavy tissue. The raw machine density was 145 warps / inch and 130 wefts / inch.

次に、生機を精練、プレセットした後、ダイスタージャパン株式会社製、黒色分散染料「Dianix Black GS−E(商品名)」を8%omf使用して、130℃、30分間の条件で染色した。染色後、ファイナルセットすることで布帛を得た。   Next, after scouring and pre-setting the raw machine, dyeing was performed at 130 ° C. for 30 minutes using 8% omf of a black disperse dye “Dianix Black GS-E (trade name)” manufactured by Dystar Japan Co., Ltd. did. After dyeing, a fabric was obtained by final setting.

(実施例2)
ポリエチレンテレフタレート98質量部に、遠赤外線放射性微粒子として平均粒子径3μmのマイカを1.0質量部、及び発熱性微粒子として平均粒子径1.5μmのカーボンを1.0質量部練り込んだ樹脂組成物と、ポリエチレンテレフタレートからなる樹脂とを用意した。そして、両者を複合紡糸機に導入し、前者を鞘成分に、後者を芯成分にそれぞれ配しつつ両者の質量比率(芯成分/鞘成分)が80/20となるように複合紡糸し、179.7dtex36fの高配向未延伸糸を得た。なお、紡糸操業性は良好であった。
(Example 2)
A resin composition in which 98 parts by mass of polyethylene terephthalate is kneaded with 1.0 part by mass of mica having an average particle diameter of 3 μm as far-infrared radiation fine particles and 1.0 part by mass of carbon having an average particle diameter of 1.5 μm as exothermic fine particles. And a resin made of polyethylene terephthalate were prepared. Then, both are introduced into a compound spinning machine, and the former is placed in the sheath component and the latter is placed in the core component, and the composite is spun so that the mass ratio between the two (core component / sheath component) is 80/20. A highly oriented undrawn yarn of .7 dtex 36f was obtained. The spinning operability was good.

次に、熱処理のためのヒーターを備えた仮撚機(三菱重工業株式会社製「LS−6(商品名)」)に上記高配向未延伸糸を導入し、まず温度180℃、オーバーフィード率2.0%なる条件で熱処理した。そして巻き取ることなく連続的に、延伸倍率1.38倍、仮撚数2750T/M、仮撚方向Z、仮撚ヒーター温度170℃なる条件で延伸同時仮撚りし、132.0dtex36fの仮撚加工糸を得た。   Next, the highly oriented undrawn yarn was introduced into a false twisting machine (“LS-6 (trade name)” manufactured by Mitsubishi Heavy Industries, Ltd.) equipped with a heater for heat treatment. First, the temperature was 180 ° C. and the overfeed rate was 2 Heat treatment was performed under the condition of 0.0%. And without winding, it is continuously false twisted under the conditions of draw ratio 1.38 times, false twist number 2750 T / M, false twist direction Z, false twist heater temperature 170 ° C., and false twisting of 132.0 dtex 36f I got a thread.

その後、ダブルツイスターを使用して、仮撚加工糸をZ方向に1800T/Mの撚数で撚糸し、撚糸後、70℃、45分間の条件で真空セットした。そして、28Gの編機でモックロディ組織の生機を製編した後、精練、プレセットし、後にダイスタージャパン株式会社製、黒色分散染料「Dianix Black GS−E(商品名)」を8%omf使用して、130℃、30分間の条件で染色した。染色後、ファイナルセットすることで布帛を得た。   Thereafter, using a double twister, the false twisted yarn was twisted in the Z direction at a twist number of 1800 T / M, and after twisting, vacuum setting was performed at 70 ° C. for 45 minutes. And after knitting the raw material of the mock-rod organization with a 28G knitting machine, scouring and pre-setting, and using 8% omf of the black disperse dye “Dianix Black GS-E (trade name)” manufactured by Daistar Japan And it dye | stained on 130 degreeC and the conditions for 30 minutes. After dyeing, a fabric was obtained by final setting.

(実施例3)
ポリエチレンテレフタレートの含有量を96質量部、マイカの含有量を3.0質量部及びカーボンの含有量を3.0質量部に各々変更する以外は、実施例2と同様に行い、高配向未延伸糸、仮撚加工糸及び布帛を得た。なお、紡糸操業性は、実施例2の場合と比べやや劣るものであった。高配向未延伸糸の繊度は181.4dtex36fであり、仮撚加工糸の繊度は134.0dtex36fであった。
(Example 3)
Except for changing the content of polyethylene terephthalate to 96 parts by mass, the content of mica to 3.0 parts by mass and the content of carbon to 3.0 parts by mass, respectively, the same procedure as in Example 2 was performed, and highly oriented unstretched Yarn, false twisted yarn and fabric were obtained. The spinning operability was slightly inferior to that in Example 2. The fineness of the highly oriented undrawn yarn was 181.4 dtex36f, and the fineness of the false twisted yarn was 134.0 dtex36f.

(実施例4)
ポリエチレンテレフタレートの含有量を99.9質量部、マイカの含有量を0.05質量部及びカーボンの含有量を0.05質量部に各々変更する以外は、実施例2と同様に行い、高配向未延伸糸、仮撚加工糸及び布帛を得た。なお、紡糸操業性は良好であった。高配向未延伸糸の繊度は180.4dtex36fであり、仮撚加工糸の繊度は133.2dtex36fであった。
Example 4
High orientation is carried out in the same manner as in Example 2 except that the content of polyethylene terephthalate is changed to 99.9 parts by mass, the content of mica is changed to 0.05 parts by mass, and the content of carbon is changed to 0.05 parts by mass. Undrawn yarn, false twisted yarn and fabric were obtained. The spinning operability was good. The fineness of the highly oriented undrawn yarn was 180.4 dtex36f, and the fineness of the false twisted yarn was 133.2 dtex36f.

(比較例1)
延伸同時仮撚り前の熱処理を省略すること、及び延伸倍率を1.42倍に変更すること以外は、実施例2と同様に行い、仮撚加工糸及び布帛を得た。仮撚加工糸の繊度は126.6dtex36fであった。
(Comparative Example 1)
A false twisted yarn and a fabric were obtained in the same manner as in Example 2 except that the heat treatment before the simultaneous simultaneous false twisting was omitted and the draw ratio was changed to 1.42. The fineness of the false twisted yarn was 126.6 dtex36f.

(比較例2)
熱処理時のオーバーフィード率を−1.8%に変更すること、及び延伸同時仮撚り時の延伸倍率を1.36倍に変更すること以外は、実施例2と同様に行い、仮撚加工糸及び布帛を得た。仮撚加工糸の繊度は127.8dtex36fであった。
(Comparative Example 2)
The false twisted yarn was carried out in the same manner as in Example 2 except that the overfeed rate during heat treatment was changed to -1.8%, and the draw ratio during simultaneous drawing was changed to 1.36 times. And a fabric was obtained. The fineness of the false twisted yarn was 127.8 dtex36f.

(比較例3)
ポリエチレンテレフタレートの含有量を100質量部とし、マイカ、カーボンを省く以外は、実施例2と同様に行い、高配向未延伸糸、仮撚加工糸及び布帛を得た。なお、紡糸操業性は良好であった。高配向未延伸糸の繊度は182.0dtex36fであり、仮撚加工糸の繊度は131.9dtex36fであった。
(Comparative Example 3)
Except for the content of polyethylene terephthalate being 100 parts by mass and omitting mica and carbon, the same procedure as in Example 2 was carried out to obtain a highly oriented undrawn yarn, false twisted yarn and fabric. The spinning operability was good. The fineness of the highly oriented undrawn yarn was 182.0 dtex36f, and the fineness of the false twisted yarn was 131.9 dtex36f.

(実施例5〜8、比較例4〜6)
下記処方1に示す組成の処理液を用いて、実施例1〜4、比較例1〜3における布帛を濃染加工した。濃染加工は、パディング法により行い、絞り率60%、乾燥130℃×5分間、熱処理180℃×30秒間の条件で行った。実施例1〜4、比較例1〜3それぞれの布帛に対する実験例を順次実施例5〜8、比較例4〜6とした。
(Examples 5-8, Comparative Examples 4-6)
Using the treatment liquid having the composition shown in the following prescription 1, the fabrics in Examples 1 to 4 and Comparative Examples 1 to 3 were deep-dyed. The deep dyeing process was performed by a padding method under the conditions of a drawing ratio of 60%, drying at 130 ° C. for 5 minutes, and heat treatment at 180 ° C. for 30 seconds. Experimental examples for the fabrics of Examples 1 to 4 and Comparative Examples 1 to 3 were sequentially designated as Examples 5 to 8 and Comparative Examples 4 to 6, respectively.

処方1
バソテックスFS−370E(明成化学工業株式会社製、フッ素系濃染化剤) 40g/L
パラレヂンBYS(大原パラジウム化学株式会社製、シリコン系濃染化剤) 10g/L
デレクトールMAP(明成化学工業株式会社製、帯電防止剤) 15g/L
テキスポートSN−10(日華化学株式会社製、浸透剤) 2g/L
Formula 1
Vasotex FS-370E (manufactured by Meisei Chemical Industry Co., Ltd., fluorine-based thickening agent) 40 g / L
Pararesin BYS (Ohara Palladium Chemical Co., Ltd., silicon-based thickening agent) 10g / L
Delectol MAP (manufactured by Meisei Chemical Industry Co., Ltd., antistatic agent) 15g / L
Textport SN-10 (manufactured by Nikka Chemical Co., Ltd., penetrant) 2 g / L

以上で得た編物の評価結果を表1に示す。   The evaluation results of the knitted fabric obtained above are shown in Table 1.

実施例にかかる布帛は、いずれも天候に左右されない持続性ある保温効果を有していた。また、明度が低く、黒色の発色性、深色性に優れていることが実証できた。そして、布帛を濃染加工すると明度が一段と下がり、ブラックフォーマル用途に一層適用し易くなることも確認できた。染色堅牢度も良好であった。   The fabrics according to the examples all had a long-lasting heat retaining effect that was not affected by the weather. Further, it was proved that the brightness was low and the black color development and deep color were excellent. It was also confirmed that when the fabric was deep-dyed, the brightness was further lowered and it was easier to apply to black formal applications. The dyeing fastness was also good.

これに対し、延伸同時仮撚り前に熱処理を省略するか(比較例1)又は熱処理しても延伸してしまうと(比較例2)、明度が高くなり、所望の発色性、深色性が得られないことが確認できた。さらに、遠赤外線放射性微粒子及び発熱性微粒子の使用を省いてしまうと、保温効果が奏されないことも確認できた(比較例3)。
On the other hand, if the heat treatment is omitted before the simultaneous simultaneous false twisting (Comparative Example 1) or if the film is stretched even after the heat treatment (Comparative Example 2), the brightness increases, and the desired color developability and deep color are obtained. It was confirmed that it could not be obtained. Furthermore, if the use of far-infrared radioactive fine particles and exothermic fine particles was omitted, it was also confirmed that the heat retaining effect was not achieved (Comparative Example 3).

Claims (4)

遠赤外線放射性微粒子と発熱性微粒子とを含有するポリエステルフィラメントから構成される仮撚加工糸の製造方法であって、ポリエステル高配向未延伸糸を延伸することなく熱処理した後、延伸同時仮撚りすることを特徴とするブラックフォーマル衣料用仮撚加工糸の製造方法。 A process for producing false twisted yarn composed of polyester filaments containing far-infrared emitting fine particles and exothermic fine particles, and heat-treating a polyester highly oriented undrawn yarn without drawing, and simultaneously drawing and false twisting simultaneously A process for producing false twisted yarn for black formal clothing. 前記ポリエステルフィラメントの断面が芯鞘構造をなし、前記遠赤外線放射性微粒子が鞘成分に含まれ、前記遠赤外線放射性微粒子の含有量が鞘成分100質量部に対して0.1〜2.5質量部であり、かつフィラメントにおける芯鞘の質量比率(芯成分/鞘成分)が95/5〜15/85の範囲にあることを特徴とする請求項1記載のブラックフォーマル衣料用仮撚加工糸の製造方法。 The cross section of the polyester filament has a core-sheath structure, the far-infrared radioactive fine particles are included in the sheath component, and the content of the far-infrared radioactive fine particles is 0.1 to 2.5 parts by mass with respect to 100 parts by mass of the sheath component. The mass ratio of the core-sheath in the filament (core component / sheath component) is in the range of 95/5 to 15/85, The production of false twisted yarn for black formal clothing according to claim 1 Method. 前記発熱性微粒子が前記ポリエステルフィラメントの鞘成分100質量部に対して0.1〜2.5質量部含まれていることを特徴とする請求項2記載のブラックフォーマル衣料用仮撚加工糸の製造方法。 The production of false twisted yarn for black formal clothing according to claim 2, wherein the exothermic fine particles are contained in an amount of 0.1 to 2.5 parts by mass with respect to 100 parts by mass of the sheath component of the polyester filament. Method. 請求項1〜3いずれかに記載の方法により得られたブラックフォーマル衣料用仮撚加工糸を用いてなる布帛であって、L*値が16以下であることを特徴とする布帛。
A fabric using the false twisted yarn for black formal clothing obtained by the method according to any one of claims 1 to 3, wherein the L * value is 16 or less.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016027212A (en) * 2014-06-27 2016-02-18 日本エステル株式会社 Functional fiber

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JPS57199825A (en) * 1981-05-27 1982-12-07 Unitika Ltd Stretching and false twisting process of unstretched polyester garn
JPH02102474U (en) * 1989-02-02 1990-08-15
JPH04163330A (en) * 1990-10-22 1992-06-08 Unitika Ltd Production of heat-insulating finished yarn having composite structure
JP2002138372A (en) * 2000-10-30 2002-05-14 Toray Ind Inc Woven or knitted fabric and method for producing the same
JP2010138497A (en) * 2008-12-09 2010-06-24 Toray Ind Inc Woven or knitted fabric

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57199825A (en) * 1981-05-27 1982-12-07 Unitika Ltd Stretching and false twisting process of unstretched polyester garn
JPH02102474U (en) * 1989-02-02 1990-08-15
JPH04163330A (en) * 1990-10-22 1992-06-08 Unitika Ltd Production of heat-insulating finished yarn having composite structure
JP2002138372A (en) * 2000-10-30 2002-05-14 Toray Ind Inc Woven or knitted fabric and method for producing the same
JP2010138497A (en) * 2008-12-09 2010-06-24 Toray Ind Inc Woven or knitted fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016027212A (en) * 2014-06-27 2016-02-18 日本エステル株式会社 Functional fiber

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