JP2015150523A - Dehumidifier - Google Patents

Dehumidifier Download PDF

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JP2015150523A
JP2015150523A JP2014027510A JP2014027510A JP2015150523A JP 2015150523 A JP2015150523 A JP 2015150523A JP 2014027510 A JP2014027510 A JP 2014027510A JP 2014027510 A JP2014027510 A JP 2014027510A JP 2015150523 A JP2015150523 A JP 2015150523A
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dehumidifier
shoe
drying
silica gel
nonwoven fabric
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石田 侃
Akira Ishida
侃 石田
末冨 明孝
Akitaka Suetomi
明孝 末冨
昌悟 伊東
Shogo Ito
昌悟 伊東
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WAKOO KK
Ube Material Industries Ltd
Wako KK
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WAKOO KK
Ube Material Industries Ltd
Wako KK
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Abstract

PROBLEM TO BE SOLVED: To provide a dehumidifier excellent in moisture absorption efficiency and dehydration efficiency after moisture absorption.SOLUTION: A dehumidifier is formed by storing silica gel in a bag body formed of a nonwoven cloth in which air permeability is in the range of 50-1000 cm/cm-s, and a powdery carbonaceous material adheres on the surface.

Description

本発明は、除湿具に関し、特に靴内部の乾燥用として有用な除湿具に関する。   The present invention relates to a dehumidifier, and more particularly to a dehumidifier useful for drying inside a shoe.

靴は、一般に、内部に水が侵入しないように形成されており、靴の内部と外部との間は通気性が低い。このため、靴の使用時に靴内部に付着した汗などの水分は外部に揮発しにくい。靴の内部に付着している水は異臭やカビの発生原因となる。このため、使用後の靴の内部に除湿具を配置して、靴内部の水分を除湿具に吸湿させることによって、靴内部を乾燥することが行われている。   The shoes are generally formed so that water does not enter the inside, and the air permeability between the inside and the outside of the shoes is low. For this reason, moisture such as sweat attached to the inside of the shoe during use of the shoe is unlikely to volatilize outside. The water adhering to the inside of the shoe may cause off-flavors and mold. For this reason, the inside of a shoe is dried by disposing a dehumidifier inside the shoe after use and causing the moisture inside the shoe to absorb moisture.

特許文献1には、靴内部の乾燥用の除湿具としてフック付き靴用除湿剤が記載されている。この文献には、フック付き靴用除湿剤はシリカゲルなどを主成分とする除湿・乾燥剤を不織布製の袋部の内部に充填したものであること、このフック付き靴用除湿剤を1つずつ靴の内部に配置することにより、靴が含んでいる水分が吸収される旨が記載されている。また、この文献にはフック付き靴用除湿剤は乾燥させることで繰り返し使用できること、袋部の表面の略中央に吸湿状況及び要乾燥状況を色の変化で示すインディケータを取り付けることが記載されている。さらに、この文献には、袋部の上部にプラスチック製のフックを取り付けること、このフックは、フック付き靴用除湿剤を靴から取り出したり、乾燥させる際にもの干しなどにかけたりするときに用いる旨が記載されている。   Patent Document 1 describes a shoe dehumidifier with a hook as a dehumidifier for drying inside a shoe. In this document, a shoe dehumidifier with a hook is a non-woven bag part filled with a dehumidifier / desiccant mainly composed of silica gel or the like, and each shoe dehumidifier with a hook is one by one. It is described that the moisture contained in the shoe is absorbed by being placed inside the shoe. In addition, this document describes that the dehumidifying agent for shoes with hooks can be repeatedly used by drying, and that an indicator that indicates the moisture absorption state and the drying required state by color change is attached to the approximate center of the surface of the bag part. . Furthermore, this document states that a plastic hook is attached to the upper part of the bag portion, and that this hook is used for removing a dehumidifier for shoes with a hook from a shoe or hanging it on a clothesline when drying. Is described.

特許文献2には、粉漏れ性、熱シール加工性、シール強度などに優れる袋体として、第1層の熱可塑性合成繊維層、第2層の極細繊維層、第3層が第1層の構成繊維の融点より30℃以上低融点である熱可塑性合成繊維を含む層を積層し、熱圧着で一体化した積層不織布を、さらに前記第3層を内側にして重ね合わせ、袋体になる周辺を熱シールして形成した袋体であって、該袋体を形成する前記積層不織布の通気性が1〜100cc/cm2/sec、最大開孔径が50μm以下、粉漏れ率が10%以下、破裂強度が100kPa以上、前記第3層のシール強度が10N/25mm以上である袋体が記載されている。そして、この文献の実施例14には、通気性が20cc/cm2/secの積層不織布から形成した袋体に、シリカゲルを充填した靴用乾燥材が記載されている。 In Patent Document 2, as a bag body excellent in powder leakage, heat sealing workability, sealing strength, etc., the first layer of thermoplastic synthetic fiber layer, the second layer of ultrafine fiber layer, and the third layer of the first layer Layers containing thermoplastic synthetic fibers that have a melting point of 30 ° C. or more lower than the melting point of the constituent fibers, and laminated with a laminated nonwoven fabric integrated by thermocompression bonding, with the third layer on the inside, and the periphery that becomes the bag body The laminated nonwoven fabric forming the bag body has a breathability of 1 to 100 cc / cm 2 / sec, a maximum pore diameter of 50 μm or less, a powder leakage rate of 10% or less, A bag body having a burst strength of 100 kPa or more and a seal strength of the third layer of 10 N / 25 mm or more is described. In Example 14 of this document, a desiccant for shoes in which a bag formed from a laminated nonwoven fabric with air permeability of 20 cc / cm 2 / sec is filled with silica gel is described.

特許文献3には、空気中の水分を吸収して除湿するための除湿シートとして、乾燥/除湿剤を小分けして2枚の不織布の間に保持しているものにおいて、前記2枚の不織布の少なくとも一方の表面に備長炭の粉末が塗布してある除湿シートが記載されている。   In Patent Document 3, as a dehumidifying sheet for absorbing and dehumidifying moisture in the air, a drying / dehumidifying agent is subdivided and held between two non-woven fabrics. A dehumidifying sheet is described in which a powder of Bincho charcoal is applied to at least one surface.

意匠登録第1146698号公報Design Registration No. 1146698 特開2007−197028号公報JP 2007-197028 A 実用新案登録第3096946号Utility model registration No. 3096946

靴の内部の乾燥に用いる除湿具は、靴内部に異臭やカビを発生させないようにするために、靴内部の水分を短時間で吸湿すること、即ち吸湿効率に優れることが好ましい。またさらに、吸湿した後の除湿具は短時間で再使用できるように、乾燥することによって短時間で水分を外部に放出すること、即ち乾燥効率に優れることが好ましい。
従って、本発明の目的は、吸湿効率と吸湿後の乾燥効率とに優れた除湿具を提供することにある。
It is preferable that the dehumidifier used for drying the inside of the shoe absorbs moisture inside the shoe in a short time, that is, has excellent moisture absorption efficiency, so as not to generate a strange odor or mold inside the shoe. Furthermore, it is preferable that the dehumidifying tool after absorbing moisture is dried to release moisture to the outside in a short time, that is, excellent in drying efficiency so that it can be reused in a short time.
Accordingly, an object of the present invention is to provide a dehumidifier having excellent moisture absorption efficiency and drying efficiency after moisture absorption.

本発明者は、通気性が50〜1000cm3/cm2・sの範囲にあって、表面に粉末状の炭素質材料が付着している不織布によって形成された袋体の中に、シリカゲルが収容されてなる除湿具は、通気性が20cm3/cm2・s程度の不織布によって形成された袋体の中に、シリカゲルが収容されてなる従来の除湿具と比較して、吸湿効率と吸湿後の乾燥効率とが顕著に向上することを見出して、本発明を完成させた。 The present inventor has silica gel accommodated in a bag formed of a non-woven fabric having air permeability in the range of 50 to 1000 cm 3 / cm 2 · s and having a powdery carbonaceous material attached to the surface. Compared with the conventional dehumidifier in which silica gel is contained in a bag formed of a non-woven fabric having a breathability of about 20 cm 3 / cm 2 · s, the dehumidifier thus obtained has a moisture absorption efficiency and after moisture absorption. As a result, the present invention was completed.

従って、本発明は、通気性が50〜1000cm3/cm2・sの範囲にあって、表面に粉末状の炭素質材料が付着している不織布によって形成された袋体の中に、シリカゲルが収容されてなる除湿具にある。 Therefore, in the present invention, silica gel is contained in a bag formed of a nonwoven fabric having air permeability in the range of 50 to 1000 cm 3 / cm 2 · s and having a powdery carbonaceous material attached to the surface. The dehumidifier is housed.

本発明の除湿具の好ましい態様は次の通りである。
(1)不織布の通気性が105〜1000cm3/cm2・sの範囲にある。
(2)靴内部の乾燥用である。
Preferred embodiments of the dehumidifying tool of the present invention are as follows.
(1) The air permeability of the nonwoven fabric is in the range of 105 to 1000 cm 3 / cm 2 · s.
(2) For drying shoes.

本発明の除湿具は吸湿効率に優れているため、靴内部のような通気性が低い環境下での除湿具として有利に使用できる。また、本発明の除湿具は乾燥効率に優れているため、靴のように毎日使用される物品の除湿具として有利に使用できる。   Since the dehumidifying tool of the present invention is excellent in moisture absorption efficiency, it can be advantageously used as a dehumidifying tool in an environment with low air permeability such as the inside of a shoe. Further, since the dehumidifying tool of the present invention is excellent in drying efficiency, it can be advantageously used as a dehumidifying tool for articles used daily such as shoes.

本発明に従う靴内部の乾燥用の除湿具の一例の平面図である。It is a top view of an example of the dehumidification tool for drying inside the shoes according to the present invention. 図1のA−A線断面図である。It is the sectional view on the AA line of FIG.

本発明の除湿具は、通気性が50〜1000cm3/cm2・sの範囲と高く、かつその表面に粉末状の炭素質材料が付着している不織布によって形成された袋体の中に、シリカゲルが収容されてなる。 The dehumidifying tool of the present invention has a high air permeability in the range of 50 to 1000 cm 3 / cm 2 · s, and a bag formed of a nonwoven fabric having a powdery carbonaceous material attached to the surface thereof. Silica gel is contained.

本発明で用いる不織布の通気性は、105〜1000cm3/cm2・sの範囲にあることが好ましく、105〜500cm3/cm2・sの範囲にあることがより好ましい。なお、本発明において、不織布の通気性はJIS−L−1913:2010(一般不織布試験方法)の6.8.1フラジール形法に記載されている方法により測定した値である。不織布の材料としては、ポリエチレン、ポリプロピレンなどのポリオレフィンの繊維、ポリアミド6、ポリアミド66などのポリアミドの繊維、ポリエチレンテレフタレート、ポリブチレンテレフタレート、共重合ポリエステル、脂肪族ポリエステルなどのポリエステルの繊維を挙げることができる。 Breathable nonwoven fabric used in the present invention is preferably in the range of 105~1000cm 3 / cm 2 · s, and more preferably in the range of 105~500cm 3 / cm 2 · s. In addition, in this invention, the air permeability of a nonwoven fabric is the value measured by the method described in 6.8.1 Frazier form method of JIS-L-1913: 2010 (general nonwoven fabric test method). Examples of the material of the nonwoven fabric include polyolefin fibers such as polyethylene and polypropylene, polyamide fibers such as polyamide 6 and polyamide 66, and polyester fibers such as polyethylene terephthalate, polybutylene terephthalate, copolymer polyester, and aliphatic polyester. .

粉末状の炭素質材料は袋体の表面全体に対して50%以上の領域に付着していることが好ましく、80%以上の領域に付着していることが特に好ましい。粉末状炭素質材料の例としては、木炭粉末、竹炭粉末、活性炭粉末、カーボンブラック粉末及び黒鉛粉末を挙げることができる。粉末状炭素質材料は、吸湿性及び消臭性などの機能を有する多孔質炭素質材料の粉末であることが好ましい。粉末状炭素質材料は、木炭粉末であることが好ましく、特に備長炭粉末であること好ましい。粉末状炭素質材料を不織布の表面に付着させる方法としては、公知の塗布方法を用いることができる。不織布に備長炭粉末を塗布する方法としては、前記の特許文献3(実用新案登録第3096946号)に記載されている方法を利用することができる。   The powdery carbonaceous material is preferably attached to an area of 50% or more with respect to the entire surface of the bag body, and particularly preferably attached to an area of 80% or more. Examples of the powdery carbonaceous material include charcoal powder, bamboo charcoal powder, activated carbon powder, carbon black powder, and graphite powder. The powdery carbonaceous material is preferably a powder of a porous carbonaceous material having functions such as hygroscopicity and deodorization. The powdery carbonaceous material is preferably charcoal powder, and particularly preferably Bincho charcoal powder. As a method for attaching the powdery carbonaceous material to the surface of the nonwoven fabric, a known coating method can be used. As a method of applying the Bincho charcoal powder to the nonwoven fabric, the method described in Patent Document 3 (Utility Model Registration No. 3096946) can be used.

シリカゲルは、B型シリカゲルであることが好ましい。シリカゲルは球状であることが好ましい。シリカゲルの粒子径は、不織布の孔から漏れ出ないサイズであればよく、一般に1〜10mmの範囲、好ましくは2〜8mmの範囲、特に好ましくは3〜5mmの範囲である。   The silica gel is preferably B-type silica gel. The silica gel is preferably spherical. The particle diameter of silica gel should just be a size which does not leak from the hole of a nonwoven fabric, and is generally the range of 1-10 mm, Preferably it is the range of 2-8 mm, Most preferably, it is the range of 3-5 mm.

次に、本発明の除湿具を、靴内部の乾燥用の除湿具を例にとって添付図面の図1と図2を参照しながら説明する。図1は、本発明に従う靴内部の乾燥用の除湿具の一例の平面図であり、図2は、図1のA−A線断面図である。   Next, the dehumidifier of the present invention will be described with reference to FIGS. 1 and 2 of the accompanying drawings, taking a dehumidifier for drying inside a shoe as an example. FIG. 1 is a plan view of an example of a dehumidifying tool for drying inside a shoe according to the present invention, and FIG. 2 is a cross-sectional view taken along line AA of FIG.

図1、2に示す除湿具において、袋体1は、二枚の不織布2a、2bを互いに重ね合わせ、その二枚の不織布2a、2bの周縁を接着してシール部3とすることによって形成されている。不織布2a、2bの表面には、粉末状の炭素質材料4が付着している。袋体1の中には、シリカゲル5が収容されている。袋体1は、靴内部のつま先にまで挿入し易くするために、一方の端部が先細りした形状となっている。また、袋体1の先細りした形状となっている端部とは反対側の端部にはフック6が取り付けられており、吸湿した除湿具を乾燥させる際には、フック6をもの干しなどに掛けることができるようにされている。袋体1は、シリカゲルの吸湿量を把握するために、吸湿量を色の変化で示すインディケータを取り付けてもよい。   In the dehumidifier shown in FIGS. 1 and 2, the bag 1 is formed by superimposing two non-woven fabrics 2a and 2b on each other and bonding the peripheral edges of the two non-woven fabrics 2a and 2b to form a seal portion 3. ing. The powdery carbonaceous material 4 is adhered to the surfaces of the nonwoven fabrics 2a and 2b. In the bag 1, silica gel 5 is accommodated. The bag body 1 has a shape in which one end is tapered in order to facilitate insertion into a toe inside the shoe. Moreover, the hook 6 is attached to the edge part on the opposite side to the taper-shaped edge part of the bag body 1, and when drying the moisture-removing dehumidifier, the hook 6 is used for drying things. You can hang it. In order to grasp the moisture absorption amount of the silica gel, the bag body 1 may be provided with an indicator that indicates the moisture absorption amount by a change in color.

[実施例1]
通気性が140cm3/cm2・sの不織布の表面に備長炭粉末を塗布して、備長炭付き不織布を作成した。備長炭付き不織布の通気性は117cm3/cm2・sであった。
備長炭付き不織布を一方の端部が先細りした形状に裁断して、備長炭付き不織布片(長さ:23cm、幅:10cm)を作成した。備長炭付き不織布片は二枚作成した。二枚の備長炭付き不織布片を、備長炭を塗布した表面が外側となるように重ねて、不織布片の先細りした端部とは反対側の端部以外の辺をシールして、一方の端部が先細りし、先細りした端部とは反対側の端部が開口した袋体を作成した。袋体の開口部からB型シリカゲル(粒径:3〜5mm)150gを投入した後、袋体の開口部をシールした。そして、シールした開口部にフックを取り付けて、図1に示すような除湿具を製造した。
[Example 1]
Bincho charcoal powder was applied to the surface of a nonwoven fabric with air permeability of 140 cm 3 / cm 2 · s to create a non-woven fabric with Bincho charcoal. The air permeability of the non-woven fabric with Bincho charcoal was 117 cm 3 / cm 2 · s.
The non-woven fabric with Bincho charcoal was cut into a shape with one end tapered to create a non-woven fabric piece with Bincho charcoal (length: 23 cm, width: 10 cm). Two pieces of non-woven fabric with Bincho charcoal were prepared. Two pieces of non-woven fabric with Bincho charcoal are stacked so that the surface coated with Bincho charcoal is on the outside, and the side other than the tapered end of the non-woven fabric piece is sealed, and one end is sealed. A bag body having a tapered portion and an open end opposite to the tapered end was prepared. After introducing 150 g of B-type silica gel (particle size: 3 to 5 mm) from the opening of the bag, the opening of the bag was sealed. And the hook was attached to the sealed opening part, and the dehumidifier as shown in FIG. 1 was manufactured.

[比較例1]
不織布として通気性が24.0cm3/cm2・sの不織布を用い、不織布に備長炭粉末を塗布しなかったこと以外は、実施例1と同様にして除湿具を製造した。
[Comparative Example 1]
A dehumidifier was manufactured in the same manner as in Example 1 except that a non-woven fabric having an air permeability of 24.0 cm 3 / cm 2 · s was used as the non-woven fabric, and Bincho charcoal powder was not applied to the non-woven fabric.

[評価]
実施例1及び比較例1にて製造した除湿具について、吸湿効率と乾燥効率とを下記の方法により評価した。その結果を、下記の表1に示す。
[Evaluation]
About the dehumidification tool manufactured in Example 1 and Comparative Example 1, moisture absorption efficiency and drying efficiency were evaluated by the following methods. The results are shown in Table 1 below.

(1)吸湿効率の評価方法
試料の除湿具を50℃の温度で24時間乾燥し、乾燥後の試料の質量(W1)を測定する。試料を、温度が25℃で、相対湿度が90%に調整された恒温恒湿器に入れて24時間静置する。静置後、試料を恒温恒湿器から取り出して、試料の質量(W2)を測定する。試料の吸水率を下記式より算出する。
吸水率(質量%)=100×(W2−W1)/W1
(1) Evaluation Method of Moisture Absorption Efficiency A sample dehumidifier is dried at a temperature of 50 ° C. for 24 hours, and the mass (W 1 ) of the sample after drying is measured. The sample is placed in a thermo-hygrostat whose temperature is 25 ° C. and relative humidity is adjusted to 90%, and is allowed to stand for 24 hours. After standing, the sample is taken out of the constant temperature and humidity chamber, and the mass (W 2 ) of the sample is measured. The water absorption rate of the sample is calculated from the following formula.
Water absorption (mass%) = 100 × (W 2 −W 1 ) / W 1

(2)乾燥効率の評価方法
上記(1)吸湿効率の評価方法において、恒温恒湿器から取り出した試料を、キセノンウエザオメーターSX75(スガ試験機(株)製)に投入し、下記の試験条件にて6時間静置する。
試験条件:照射のみ、放射照度60W/m2(波長300〜400nm)、ブラックパネル温度63℃、温度25℃、湿度20%
静置後、試料をキセノンウエザオメーターSX75から取り出して、試料の質量(W3)を測定する。試料の水分減少率を下記式より算出する。
水分減少率(質量%)=100×(W3−W1)/(W2−W1
(2) Drying efficiency evaluation method In the above (1) Hygroscopic efficiency evaluation method, the sample taken out of the thermo-hygrostat is put into a xenon weatherometer SX75 (manufactured by Suga Test Instruments Co., Ltd.) and subjected to the following test. Let stand for 6 hours under conditions.
Test conditions: irradiation only, irradiance 60 W / m 2 (wavelength 300 to 400 nm), black panel temperature 63 ° C., temperature 25 ° C., humidity 20%
After standing, the sample is taken out from the xenon weatherometer SX75, and the mass (W 3 ) of the sample is measured. The moisture reduction rate of the sample is calculated from the following formula.
Moisture reduction rate (mass%) = 100 × (W 3 −W 1 ) / (W 2 −W 1 )

表1
────────────────────────────────────────
吸湿効率[吸水率(質量%)] 乾燥効率[水分減少率(質量%)]
────────────────────────────────────────
実施例1 40.6 65.4
────────────────────────────────────────
比較例1 23.1 56.5
────────────────────────────────────────
Table 1
────────────────────────────────────────
Moisture absorption efficiency [Water absorption rate (% by mass)] Drying efficiency [Moisture reduction rate (% by mass)]
────────────────────────────────────────
Example 1 40.6 65.4
────────────────────────────────────────
Comparative Example 1 23.1 56.5
────────────────────────────────────────

表1の結果から、本発明に従う実施例1の除湿具は、比較例1の除湿具と比較して、吸湿効率が高く、さらに吸湿後の乾燥効率も高いことが分かる。   From the results in Table 1, it can be seen that the dehumidifying tool of Example 1 according to the present invention has higher moisture absorption efficiency and higher drying efficiency after moisture absorption than the dehumidifying tool of Comparative Example 1.

1 袋体
2a、2b 不織布
3 シール部
4 粉末状の炭素質材料
5 シリカゲル
6 フック
DESCRIPTION OF SYMBOLS 1 Bag 2a, 2b Nonwoven fabric 3 Seal part 4 Powdery carbonaceous material 5 Silica gel 6 Hook

Claims (3)

通気性が50〜1000cm3/cm2・sの範囲にあって、表面に粉末状の炭素質材料が付着している不織布によって形成された袋体の中に、シリカゲルが収容されてなる除湿具。 A dehumidifier having a breathability in the range of 50 to 1000 cm 3 / cm 2 · s and containing silica gel in a bag formed of a nonwoven fabric having a powdery carbonaceous material attached to the surface. . 不織布の通気性が105〜1000cm3/cm2・sの範囲にある請求項1に記載の除湿具。 Dividing Shimegu of claim 1, the air permeability of the nonwoven fabric is in the range of 105~1000cm 3 / cm 2 · s. 靴内部の乾燥用である請求項1に記載の除湿具。   The dehumidifying device according to claim 1, which is used for drying inside a shoe.
JP2014027510A 2014-02-17 2014-02-17 Dehumidifier Pending JP2015150523A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017217476A (en) * 2016-06-03 2017-12-14 宇部マテリアルズ株式会社 Deodorizing/dehumidifying sheet, method for producing the same, and deodorizing/dehumidifying method
CN109692552A (en) * 2018-11-07 2019-04-30 杨皓 A kind of energy-efficient wardrobe dehumidifier

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* Cited by examiner, † Cited by third party
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JPH04102622U (en) * 1990-12-17 1992-09-04 ユニチカ株式会社 Deodorizing/dehumidifying body
JP3009004U (en) * 1994-09-14 1995-03-28 富士シリシア化学株式会社 Dry bag for shoes
JPH07163509A (en) * 1993-10-05 1995-06-27 Chuo Kaorin Kk Dry odor suppressing bag for shoes
JP3096946U (en) * 2003-04-04 2004-01-08 ワコー株式会社 Dehumidification sheet
JP2009022924A (en) * 2007-07-23 2009-02-05 Asahi Kasei Fibers Corp Hygroscopic and deodorant sheet

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04102622U (en) * 1990-12-17 1992-09-04 ユニチカ株式会社 Deodorizing/dehumidifying body
JPH07163509A (en) * 1993-10-05 1995-06-27 Chuo Kaorin Kk Dry odor suppressing bag for shoes
JP3009004U (en) * 1994-09-14 1995-03-28 富士シリシア化学株式会社 Dry bag for shoes
JP3096946U (en) * 2003-04-04 2004-01-08 ワコー株式会社 Dehumidification sheet
JP2009022924A (en) * 2007-07-23 2009-02-05 Asahi Kasei Fibers Corp Hygroscopic and deodorant sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017217476A (en) * 2016-06-03 2017-12-14 宇部マテリアルズ株式会社 Deodorizing/dehumidifying sheet, method for producing the same, and deodorizing/dehumidifying method
CN109692552A (en) * 2018-11-07 2019-04-30 杨皓 A kind of energy-efficient wardrobe dehumidifier

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