JP2015143423A - Cold application-type lightweight pavement material composition - Google Patents

Cold application-type lightweight pavement material composition Download PDF

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JP2015143423A
JP2015143423A JP2014016693A JP2014016693A JP2015143423A JP 2015143423 A JP2015143423 A JP 2015143423A JP 2014016693 A JP2014016693 A JP 2014016693A JP 2014016693 A JP2014016693 A JP 2014016693A JP 2015143423 A JP2015143423 A JP 2015143423A
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aggregate
pavement
type lightweight
mass
asphalt
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到 西▲崎▼
Itaru Nishizaki
到 西▲崎▼
新田 弘之
Hiroyuki Nitta
弘之 新田
俊文 江向
Toshibumi Eko
俊文 江向
良一 新井田
Ryoichi Niida
良一 新井田
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National Research and Development Agency Public Works Research Institute
Maeda Road Construction Co Ltd
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Public Works Research Institute
Maeda Road Construction Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a cold application-type lightweight pavement material composition which is lightweight and rich in workability, and which has strength and durability, necessary for a road surface pavement application.SOLUTION: A cold application-type lightweight pavement material composition of the present invention includes an alkaline additive that saponification-reacts with a hardener by adding the hardener including any one of aggregate, asphalt, fats and oils and a fatty acid, and a hardening initiator. In the cold application-type lightweight pavement material composition, the aggregate has a bulk density of 0.5-1.9 g/cmand water absorption of 2-35%.

Description

本発明は、路面舗装に使用される常温施工型軽量舗装材組成物に関する。   The present invention relates to a room temperature construction type lightweight pavement composition used for road pavement.

ポットホールの補修等の路面舗装に際し、袋詰めされた常温施工型のアスファルト補修材が使用される。このアスファルト補修材には、かさ密度が2.5g/cm前後の骨材が一般的に用いられ、その重量は、1袋あたり20kg〜30kgのものが多い。交通量の多い路面舗装の現場では、近隣に車両を駐車することができず、離れた場所から前記アスファルト補修材を人力で運ばなければならないことが多く、また、災害復旧等の場面では、1日で数多くの場所を補修する必要があることから、1袋あたり20kg〜30kgの重量が、作業員に大きな負担をかけている。 When pavement repairs such as potholes, asphalt repair materials that are packed in room temperature are used. As this asphalt repair material, an aggregate having a bulk density of about 2.5 g / cm 3 is generally used, and the weight is often 20 to 30 kg per bag. In road pavement sites where there is a lot of traffic, vehicles cannot be parked nearby, and often the asphalt repair material has to be transported manually from a remote location. Since it is necessary to repair many places on a day, the weight of 20 kg to 30 kg per bag places a heavy burden on workers.

こうしたことから、1袋あたりの容量を減らし、1袋あたり10kg〜15kgの重量とするものも存在するが、1袋あたりの施工面積が減るため、作業効率を低下させることとなり、根本的な解決には、至っていない。
また、建築用コンクリートや土木用盛土材などでは軽量骨材が普及しつつあるが、前記軽量骨材は、舗装用途における強度や耐久性が劣るため、アスファルト舗装に使用される骨材として用いられてはいない。
For this reason, there are some that reduce the capacity per bag and have a weight of 10 kg to 15 kg per bag. However, the construction area per bag is reduced, so the work efficiency is reduced and the fundamental solution. It has not reached.
In addition, lightweight aggregates are becoming widespread in building concrete and civil engineering embankment materials, but the lightweight aggregates are inferior in strength and durability in paving applications, and are therefore used as aggregates used in asphalt pavement. Not.

ところで、舗装用途における強度や耐久性に優れた常温施工型の舗装材組成物として、骨材、アスファルト、油脂及び脂肪酸のいずれかを含む硬化剤、アルカリ性添加剤、及び前記硬化剤と前記アルカリ性添加剤との鹸化反応を生じさせる硬化開始剤を含むものが提案されている(特許文献1,2参照)。
この舗装材組成物では、骨材間に浸透させた前記硬化剤とアルカリ性添加剤とを前記硬化開始剤により鹸化反応させることで、強度や耐久性に優れた路面舗装が実現可能とされる。
By the way, as a pavement composition of room temperature construction type excellent in strength and durability in paving applications, a curing agent containing any of aggregate, asphalt, fats and fatty acids, an alkaline additive, and the curing agent and the alkaline addition There has been proposed one containing a curing initiator that causes a saponification reaction with an agent (see Patent Documents 1 and 2).
In this pavement composition, a road surface pavement excellent in strength and durability can be realized by saponifying the curing agent and the alkaline additive that have been infiltrated between aggregates with the curing initiator.

特開2010−248472号公報JP 2010-248472 A 国際公開第2011/086722号公報International Publication No. 2011-086722

本発明者は、前記常温施工型の舗装材組成物に含まれる前記骨材を一般のものから、かさ密度の低い軽量骨材に変更することで、軽量でありながら、路面舗装用途に必要な強度及び耐久性を有する舗装材組成物の開発を試みた。
前記試みの下、試行錯誤した結果、従来、前記アスファルト舗装への適用が困難とされてきた前記軽量骨材にあっても、所定の特徴を有する軽量骨材であれば、前記硬化剤と前記アルカリ性添加剤とが前記軽量骨材を構成する各骨材粒子中に浸透して、施工後の強度及び耐久性を向上させることが可能であるとの知見を得た。
The inventor changes the aggregate contained in the normal temperature construction type pavement composition from a general one to a lightweight aggregate having a low bulk density, and is necessary for road pavement applications while being lightweight. An attempt was made to develop a pavement composition having strength and durability.
Under the above trial, as a result of trial and error, even in the lightweight aggregate that has been conventionally difficult to apply to the asphalt pavement, if it is a lightweight aggregate having a predetermined characteristic, the curing agent and the It was found that the alkaline additive penetrates into each aggregate particle constituting the light-weight aggregate to improve the strength and durability after construction.

本発明は、従来技術における前記諸問題を解決し、軽量で作業性に富み、かつ、路面舗装用途に必要な強度及び耐久性を有する常温施工型軽量舗装材組成物を提供することを目的とする。   An object of the present invention is to solve the above-mentioned problems in the prior art, to provide a light-weight pavement material composition that can be applied at room temperature and has strength and durability that are light and have high workability, and are required for road pavement applications. To do.

本発明は、前記知見に基づくものであり、前記課題を解決するための手段としては、以下の通りである。即ち、
<1> 骨材、アスファルト、油脂及び脂肪酸のいずれかを含む硬化剤、及び硬化開始剤の添加により前記硬化剤と鹸化反応するアルカリ性添加剤を含む常温施工型軽量舗装材組成物において、前記骨材は、かさ密度が0.5g/cm〜1.9g/cmであり、かつ吸水率が2%〜35%であることを特徴とする常温施工型軽量舗装材組成物。
<2> 骨材のかさ密度が1.0g/cm〜1.6g/cmである前記<1>に記載の常温施工型軽量舗装材組成物。
<3> 骨材の吸水率が5%〜20%である前記<1>から<2>のいずれかに記載の常温施工型軽量舗装材組成物。
The present invention is based on the above knowledge, and means for solving the above problems are as follows. That is,
<1> A light-weight pavement composition for room temperature construction, comprising a hardener containing any of aggregate, asphalt, fats and oils, and an alkaline additive that saponifies with the hardener by adding a hardening initiator. wood has a bulk density of 0.5g / cm 3 ~1.9g / cm 3 , and cold construction type lightweight paving composition, wherein the water absorption is 2% to 35%.
<2> cold construction type lightweight paving material composition according to the bulk density of the aggregate is 1.0g / cm 3 ~1.6g / cm 3 <1>.
<3> The room temperature construction type lightweight pavement composition according to any one of <1> to <2>, wherein the aggregate has a water absorption rate of 5% to 20%.

本発明によれば、従来技術における前記諸問題を解決することができ、軽量で作業性に富み、かつ、路面舗装用途に必要な強度及び耐久性を有する常温施工型軽量舗装材組成物を提供することができる。   According to the present invention, it is possible to solve the above-mentioned problems in the prior art, and provide a light-weight pavement composition that can be applied at room temperature and has lightness, excellent workability, and strength and durability required for road pavement applications. can do.

実施例3に係る常温施工型軽量舗装材組成物の骨材に対する硬化剤、アルカリ添加剤等の浸透状況を撮像した顕微鏡写真像である。It is the microscope picture image which imaged the penetration | invasion conditions, such as a hardening | curing agent with respect to the aggregate of the normal temperature construction type lightweight pavement composition which concerns on Example 3, and an alkali additive. 実施例3に係る常温施工型軽量舗装材組成物に用いた骨材のみを撮像した顕微鏡写真像である。It is the microscope picture image which imaged only the aggregate used for the normal temperature construction type lightweight pavement composition which concerns on Example 3. FIG.

本発明の常温施工型軽量舗装材組成物は、骨材、アスファルト、硬化剤、及びアルカリ性添加剤を含み、必要に応じて、その他の成分を含む。
なお、本明細書中、「常温施工」とは、20℃で施工を行うことができることを指し示す。
The room temperature construction-type lightweight pavement composition of the present invention includes aggregate, asphalt, a curing agent, and an alkaline additive, and includes other components as necessary.
In the present specification, “normal temperature construction” indicates that construction can be performed at 20 ° C.

<骨材>
前記骨材は、かさ密度が0.5g/cm〜1.9g/cmであり、かつ吸水率が2%〜35%である軽量骨材が用いられる。
前記かさ密度が0.5g/cm未満であると、前記骨材を構成する骨材粒子中に前記硬化剤及び前記アルカリ性添加剤が過剰に浸透して、組成物の常温での作業性が大きく損なわれ、施工不可もしくは施工不良が起こりやすくなり、1.9g/cmを超えると、軽量化が図れない。
また、前記吸水率が2%未満であると、前記骨材粒子中に前記硬化剤及び前記アルカリ性添加剤が十分に浸透せず、路面舗装に必要な強度及び耐久性が得られず、35%を超えると、前記骨材粒子中に前記硬化剤及び前記アルカリ性添加剤が過剰に浸透し、組成物の常温での作業性が大きく損なわれて施工不可になる、もしくは施工不良が起こりやすくなる。
前記常温施工型軽量舗装材組成物は、以上の知見に基づき、前記骨材の前記かさ密度及び前記吸水率を所定の範囲とすることを技術の核とする。中でも、前記骨材の前記かさ密度が1.0g/cm〜1.6g/cmであると、路面舗装に必要な強度及び耐久性をより一層向上させることができるとともに十分な軽量化を図ることができ、また、前記吸水率が5%〜20%であると、路面舗装に必要な強度及び耐久性をより一層向上させることができる。
なお、前記骨材に対する前記硬化剤及び前記アルカリ性添加剤の浸透性を「吸水率」で指標するのは、「吸水率」が前記骨材に対する液体の浸透性を指標するのに一般的に用いられるとともに、この「吸水率」に応じて、前記アルカリ性添加剤が分散された液状の前記硬化剤が前記骨材に浸透するためである。
<Aggregate>
The aggregate has a bulk density of 0.5g / cm 3 ~1.9g / cm 3 , and lightweight aggregate having a water absorption rate of 2% to 35% is used.
When the bulk density is less than 0.5 g / cm 3 , the curing agent and the alkaline additive excessively penetrate into the aggregate particles constituting the aggregate, and the workability of the composition at normal temperature is improved. It will be greatly damaged, making construction impossible or construction failure likely to occur, and if it exceeds 1.9 g / cm 3 , weight reduction cannot be achieved.
Further, if the water absorption is less than 2%, the curing agent and the alkaline additive do not sufficiently penetrate into the aggregate particles, and the strength and durability necessary for road pavement cannot be obtained, and 35% When the average particle size exceeds 50%, the curing agent and the alkaline additive excessively penetrate into the aggregate particles, and the workability at room temperature of the composition is greatly impaired, so that the work cannot be performed or the work is liable to occur.
Based on the above knowledge, the normal temperature construction type lightweight pavement composition has the core of the technology to set the bulk density and the water absorption rate of the aggregate within a predetermined range. Above all, when the bulk density of the aggregate is at 1.0g / cm 3 ~1.6g / cm 3 , a sufficient weight reduction it is possible to further improve the strength and durability required for road paving Moreover, the intensity | strength and durability which are required for road surface paving can be improved further as the water absorption is 5%-20%.
Note that the permeability of the curing agent and the alkaline additive to the aggregate is indicated by “water absorption”, and “water absorption” is generally used to indicate the permeability of the liquid to the aggregate. This is because the liquid curing agent in which the alkaline additive is dispersed penetrates into the aggregate according to the “water absorption rate”.

前記骨材の材料としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、頁岩、廃ガラス、石炭灰(フライアッシュ、クリンカアッシュ)、黒曜石系石材、及びこれらの加工物が挙げられ、前記頁岩の加工物としては、例えば、膨張性頁岩焼成加工物が挙げられ、前記石炭灰の加工物としては、例えば、フライアッシュ固化物が挙げられる。これらの中でも、前記硬化剤及び前記アルカリ性添加剤の浸透性の観点から、前記膨張性頁岩焼成加工物が好ましい。なお、これらは、1種単独で用いてもよく2種以上を併用してもよい。   There is no restriction | limiting in particular as a material of the said aggregate, According to the objective, it can select suitably, For example, shale, waste glass, coal ash (fly ash, clinker ash), obsidian stone, and these processed materials Examples of the processed product of shale include an expansive shale calcined product, and examples of the processed coal ash include fly ash solidified product. Among these, from the viewpoint of permeability of the curing agent and the alkaline additive, the expansive shale calcined product is preferable. In addition, these may be used individually by 1 type and may use 2 or more types together.

また、前記常温施工型軽量舗装材組成物に用いられる骨材としては、所定の前記かさ密度及び前記吸水率である前記骨材に加え、アスファルト舗装に用いられる前記かさ密度が大きい一般的な骨材を加えてもよい。ここでは、前記一般的な骨材を「通常骨材」と呼び、前記所定の前記かさ密度及び前記吸水率である前記骨材と区別する。
前記通常骨材を用いる場合の前記骨材に対する含有比率としては、特に制限はないが、前記通常骨材と前記骨材を含めた全骨材中に含まれる前記骨材の含有率が、25体積%以上であることが好ましく、50体積%以上であることがより好ましく、75体積%以上であることが特に好ましい。このような含有率であると、前記常温施工型軽量舗装材組成物の軽量化と両立させて強度及び耐久性の向上を図ることができる。なお、前記常温施工型軽量舗装材組成物では、前記通常骨材を用いず、前記骨材のみを用いることもできる(100体積%)。
Moreover, as an aggregate used for the light-weight pavement composition for room temperature construction type, a general bone having a large bulk density used for asphalt pavement in addition to the aggregate having the predetermined bulk density and the water absorption rate. Materials may be added. Here, the general aggregate is referred to as “normal aggregate” and is distinguished from the aggregate having the predetermined bulk density and the water absorption rate.
The content ratio with respect to the aggregate in the case of using the normal aggregate is not particularly limited, but the content ratio of the aggregate contained in the total aggregate including the normal aggregate and the aggregate is 25. The volume is preferably at least volume%, more preferably at least 50 volume%, particularly preferably at least 75 volume%. When the content ratio is such, the strength and durability can be improved while achieving a reduction in the weight of the room temperature construction-type lightweight pavement composition. In addition, in the said normal temperature construction type lightweight pavement composition, the said aggregate can be used without using the said normal aggregate (100 volume%).

前記アスファルト及び前記硬化剤を「バインダー」と称した場合の前記常温施工型軽量舗装材組成物における前記骨材の前記バインダーに対する含有比率としては、特に制限はないが、「前記骨材:前記バインダー」の質量比で、95:5〜70:30が好ましい。このような含有比率であると、前記硬化剤及び前記アルカリ性添加剤の浸透により強度及び耐久性を向上させた前記骨材を含む前記常温施工型軽量舗装材組成物を効率的に製造することができる。   The content ratio of the aggregate to the binder in the normal temperature construction type lightweight pavement composition when the asphalt and the curing agent are referred to as “binder” is not particularly limited, but “the aggregate: the binder” Is preferably 95: 5 to 70:30. With such a content ratio, it is possible to efficiently produce the room temperature construction type lightweight pavement composition containing the aggregate whose strength and durability are improved by the penetration of the curing agent and the alkaline additive. it can.

<アスファルト>
前記アスファルトとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ストレートアスファルト40/60、60/80、80/100、100/120等を挙げることができる。なお、これらは、1種単独で用いてもよく2種以上を併用してもよい。
<Asphalt>
There is no restriction | limiting in particular as said asphalt, According to the objective, it can select suitably, For example, straight asphalt 40/60, 60/80, 80/100, 100/120 etc. can be mentioned. In addition, these may be used individually by 1 type and may use 2 or more types together.

<硬化剤>
前記硬化剤は、油脂及び脂肪酸のいずれかを含む。
前記硬化剤としては、特に制限はなく、目的に応じて適宜選択することができるが、トール油脂肪酸、大豆油脂肪酸、綿実油脂肪酸、米糠油脂肪酸、ナタネ油脂肪酸、ヒマワリ油脂肪酸などの植物由来の脂肪酸類及びこれらのエステルなどが好ましい。前記植物由来の脂肪酸類及びこれらのエステルを用いることにより、前記アスファルトのバインダとしての役割の一部をこのような植物由来の材料に置き換えることができ、環境負荷を低減させることができる。これらの中でも、舗装路面の強度及び耐久性に優れることから、前記トール油脂肪酸が好ましい。なお、これらは、1種単独で用いてもよく2種以上を併用してもよい。
前記常温施工型軽量舗装材組成物における前記硬化剤の含有比率は、「前記アスファルト:前記硬化剤」の質量比で、10:90〜90:10であることが好ましい。なお、前記硬化剤の添加量が増加するに伴い可使温度範囲も広がるため、前記硬化剤の添加量は、施工条件に合わせて決定することが好ましい。
<Curing agent>
The said hardening | curing agent contains either fats and oils and a fatty acid.
The curing agent is not particularly limited and may be appropriately selected depending on the intended purpose, but it is derived from plants such as tall oil fatty acid, soybean oil fatty acid, cottonseed oil fatty acid, rice bran oil fatty acid, rapeseed oil fatty acid, sunflower oil fatty acid and the like. Fatty acids and their esters are preferred. By using the plant-derived fatty acids and their esters, a part of the role of the asphalt as a binder can be replaced with such plant-derived materials, and the environmental burden can be reduced. Among these, the tall oil fatty acid is preferable because of excellent strength and durability of the paved road surface. In addition, these may be used individually by 1 type and may use 2 or more types together.
The content ratio of the curing agent in the room temperature construction type lightweight pavement composition is preferably 10:90 to 90:10 in mass ratio of “the asphalt: the curing agent”. In addition, since the usable temperature range is expanded as the addition amount of the curing agent is increased, it is preferable to determine the addition amount of the curing agent according to construction conditions.

<アルカリ性添加剤>
前記アルカリ性添加剤は、硬化開始剤(例えば、水)の添加により前記硬化剤と鹸化反応する成分である。
前記鹸化反応としては、脂肪酸アルカリ塩を生成させる反応であればよく、例えば、高級脂肪酸エステルにアルカリ水を加えることにより、脂肪酸アルカリ塩(石鹸)とグリセリンを生成する鹸化法や、高級脂肪酸をアルカリ水で中和する中和法等が挙げられる。
前記鹸化反応では、アルカリ成分を固形状態で添加した場合、水などの溶媒が存在しない限り、反応が開始しない。一方、水などの溶媒が存在する場合は、「前記硬化剤(油脂、脂肪酸)+アルカリ性添加剤+水=石鹸(固体)」の反応が起こり、石鹸が生成する。
前記鹸化反応の代表例として、高級脂肪酸エステルと水酸化ナトリウム(アルカリ)とを使用した鹸化法による反応例を下記式(1)に、高級脂肪酸と水酸化ナトリウムとを使用した中和法による反応例を下記式(2)に、それぞれ示す。
<Alkaline additive>
The alkaline additive is a component that undergoes a saponification reaction with the curing agent by adding a curing initiator (for example, water).
The saponification reaction may be a reaction that generates a fatty acid alkali salt. For example, a saponification method that generates a fatty acid alkali salt (soap) and glycerin by adding alkaline water to a higher fatty acid ester, The neutralization method etc. which neutralize with water are mentioned.
In the saponification reaction, when an alkali component is added in a solid state, the reaction does not start unless a solvent such as water is present. On the other hand, when a solvent such as water is present, a reaction of “the curing agent (oil and fat, fatty acid) + alkaline additive + water = soap (solid)” occurs to produce soap.
As a typical example of the saponification reaction, a reaction example by a saponification method using a higher fatty acid ester and sodium hydroxide (alkali) is represented by the following formula (1), and a reaction by a neutralization method using a higher fatty acid and sodium hydroxide. Examples are shown in the following formula (2), respectively.

前記常温施工型軽量舗装材組成物では、前記硬化開始剤の作用により生ずる前記硬化剤と前記アルカリ性添加剤との前記鹸化反応を利用して、前記骨材中に含まれる骨材粒子同士を強固に結合させるとともに、前記各骨材粒子中に前記硬化剤及び前記アルカリ性添加剤が浸透することにより前記各骨材粒子の強度及び耐久性を向上させる。
したがって、前記アルカリ性添加剤としては、前記硬化開始剤の作用により、前記鹸化反応の前記アルカリ成分となる化合物であれば、特に制限はないが、前記脂肪酸を効果的に中和する観点から、低い水素イオン濃度(即ち、pHが大きい)を呈するものが好ましい。
このようなアルカリ性添加剤としては、前記石鹸の生成に用いられる水酸化ナトリウムや水酸化カリウム等を用いることも可能であるが、環境的な観点より、一般的な土木材料として使用されるセメントの中でも、前記硬化開始剤の作用によって低い水素イオン濃度を呈する普通セメント(普通ポルトランドセメント)が好ましい。
前記普通ポルトランドセメントとしては、特に制限はなく、例えば、ケイ酸三カルシウム(3CaO・SiO)、ケイ酸二カルシウム(2CaO・SiO)、カルシウムアルミネート(3CaO・Al)、カルシウムアルミノフェライト(4CaO・Al・Fe)、硫酸カルシウム(CaSO・2HO)などを主成分とするものが挙げられる。
なお、前記アルカリ性添加剤としては、これら以外にも、ナトリウムイオン(Na)、カリウムイオン(K)、マグネシウムイオン(Mg2+)、カルシウムイオン(Ca2+)等の金属イオンを含む水溶液、水を添加することで前記各イオンに分解する金属塩を含む粉末、炭酸水素ナトリウム(NaHCO)、炭酸水素カリウム(KHCO)などを用いることができる。
前記常温施工型軽量舗装材組成物における前記アルカリ性添加剤の含有比率としては、「前記硬化剤:前記アルカリ性添加剤」の質量比で、100:10〜100:300であることが好ましい。
In the room temperature construction type lightweight pavement composition, the aggregate particles contained in the aggregate are strongly bonded by utilizing the saponification reaction of the curing agent and the alkaline additive generated by the action of the curing initiator. In addition, the strength and durability of each aggregate particle are improved by allowing the curing agent and the alkaline additive to penetrate into each aggregate particle.
Accordingly, the alkaline additive is not particularly limited as long as it is a compound that becomes the alkaline component of the saponification reaction by the action of the curing initiator, but is low from the viewpoint of effectively neutralizing the fatty acid. Those exhibiting a hydrogen ion concentration (that is, having a high pH) are preferred.
As such an alkaline additive, it is possible to use sodium hydroxide, potassium hydroxide or the like used for the production of the soap, but from an environmental viewpoint, cement used as a general civil engineering material is used. Among these, ordinary cement (ordinary Portland cement) exhibiting a low hydrogen ion concentration by the action of the curing initiator is preferable.
As the ordinary Portland cement is not particularly limited, for example, tricalcium silicate (3CaO · SiO 2), dicalcium silicate (2CaO · SiO 2), calcium aluminate (3CaO · Al 2 O 3) , calcium aluminosilicate Examples include ferrite (4CaO.Al 2 O 3 .Fe 2 O 3 ), calcium sulfate (CaSO 4 .2H 2 O) and the like as main components.
In addition to the above, the alkaline additive includes an aqueous solution containing metal ions such as sodium ion (Na + ), potassium ion (K + ), magnesium ion (Mg 2+ ), calcium ion (Ca 2+ ), water, it can be used such as a powder comprising decomposing metal salt in the each ion by the addition of sodium bicarbonate (NaHCO 3), potassium bicarbonate (KHCO 3).
The content ratio of the alkaline additive in the room temperature construction-type lightweight pavement composition is preferably 100: 10 to 100: 300 in terms of a mass ratio of “the curing agent: the alkaline additive”.

<その他の成分>
前記その他の成分としては、本発明の作用効果を損なわない限り、特に制限はなく、アスファルト舗装の分野において、通常用いられるその他の添加剤を用いることができる。このような添加剤としては、例えば、フィラー、植物繊維、顔料、凍結防止剤などが挙げられる。
<Other ingredients>
There is no restriction | limiting in particular as long as the said other component does not impair the effect of this invention, The other additive normally used in the field | area of asphalt pavement can be used. Examples of such additives include fillers, plant fibers, pigments, antifreezing agents and the like.

<硬化開始剤>
前記常温施工型軽量舗装材組成物は、施工時に前記硬化開始剤を添加することにより、前記硬化剤と前記アルカリ性添加剤とを前記鹸化反応させる。
前記硬化開始剤としては、このような鹸化反応を生じさせるものであれば、特に制限はなく、目的に応じて適宜選択することができるが、水を好適に用いることができる。
<Curing initiator>
The room temperature construction type lightweight pavement composition causes the saponification reaction of the curing agent and the alkaline additive by adding the curing initiator during construction.
The curing initiator is not particularly limited as long as it causes such a saponification reaction, and can be appropriately selected according to the purpose, but water can be preferably used.

<調製方法>
前記常温施工型軽量舗装材組成物の調製方法としては、特に制限はなく、公知の方法により、各成分を均一になるまで添加・混合して調製することができる。例えば、加熱された状態の前記骨材及び前記アスファルト剤と、前記硬化剤及び前記アルカリ性添加剤と適宜添加して混合する方法が挙げられる。
ここで、前記骨材のドライミキシング時における加熱温度としては、特に制限はないが、100℃〜140℃が好ましく、110℃〜130℃がより好ましい。また、加熱時間としては、通常、1秒〜1分程度である。このような加熱温度及び加熱時間で前記ドライミキシングを行うことで、前記骨材に含まれる水分量を制御することができる。
また、前記アスファルトの加熱温度としては、130℃〜170℃が好ましく、140℃〜160℃がより好ましい。
なお、前記硬化剤としては、常温のまま添加してもよいが、寒冷期などには、15℃〜25℃程度に加温して用いることが好ましい。
<Preparation method>
There is no restriction | limiting in particular as a preparation method of the said normal temperature construction type light weight pavement composition, It can add and mix and prepare each component until it becomes uniform by a well-known method. For example, the aggregate and the asphalt agent in a heated state, the curing agent, and the alkaline additive may be appropriately added and mixed.
Here, although there is no restriction | limiting in particular as a heating temperature at the time of the dry mixing of the said aggregate, 100 to 140 degreeC is preferable and 110 to 130 degreeC is more preferable. The heating time is usually about 1 second to 1 minute. By performing the dry mixing at such a heating temperature and heating time, the amount of water contained in the aggregate can be controlled.
Moreover, as heating temperature of the said asphalt, 130 to 170 degreeC is preferable and 140 to 160 degreeC is more preferable.
The curing agent may be added as it is at room temperature, but it is preferably used after being heated to about 15 ° C. to 25 ° C. in the cold season.

<施工方法>
以上により得られる前記常温施工型軽量舗装材組成物としては、水分透過防止層及び熱融着層を備える袋内に充填し、次いで、熱融着層をヒートシーラーなどにより加熱圧着することで、熱融着層を熱融着することで袋内に密封し、保存することができる。
前記常温施工型軽量舗装材組成物による舗装路面の施工方法としては、例えば、前記袋を施工場所に運搬後、前記袋内から前記常温施工型軽量舗装材組成物を取り出し、前記硬化開始剤(例えば、水)を添加し、目的とする施工箇所に敷き均して締固める方法が挙げられる。
<Construction method>
As the room temperature construction type lightweight pavement composition obtained as described above, it is filled in a bag provided with a moisture permeation preventing layer and a heat sealing layer, and then the heat sealing layer is heated and pressure-bonded with a heat sealer or the like. The heat-sealing layer can be sealed and stored in the bag by heat-sealing.
As a construction method of the paved road surface by the room temperature construction type lightweight pavement composition, for example, after transporting the bag to a construction place, the room temperature construction type lightweight pavement composition is taken out from the bag, and the curing initiator ( For example, there is a method in which water) is added and spread on the target construction site and then compacted.

(実施例1)
骨材としてのスーパーソル(L4)(かさ密度:1.309g/cm、吸水率:3.8%、(株)トリム社製、廃ガラス加工物)80.1質量部、フィラー(奥多摩工業(株)社製、石粉)6.5質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)6.6質量部、硬化剤としてのトール油脂肪酸5.4質量部、及びアルカリ性添加剤としての普通ポルトランドセメント(太平洋セメント(株)社製)1.4質量部を、2軸パグミル型ミキサを用いて混合し、実施例1に係る常温施工型軽量舗装材組成物を調製した。なお、アスファルト及びトール油脂肪酸の総添加量を「バインダー量」とし、以降の実施例及び比較例では、バインダー量中のアスファルト及びトール油脂肪酸の含有比率を実施例1における含有比率から変更しないこととした。
また、骨材は、120℃に加熱された状態で混合し、アスファルトは、160℃に加熱された状態で混合し、その他の部材は、常温で混合した。なお、以降の実施例及び比較例においても、同様の温度条件で各成分の混合を行った。
Example 1
Supersol (L4) as aggregate (bulk density: 1.309 g / cm 3 , water absorption: 3.8%, manufactured by Trim Co., Ltd., waste glass processed product) 80.1 parts by mass, filler (Okutama Industry) Co., Ltd., stone powder) 6.5 parts by mass, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 6.6 parts by mass, tall oil fatty acid 5.4 parts by mass as a curing agent, And 1.4 parts by weight of ordinary Portland cement (manufactured by Taiheiyo Cement Co., Ltd.) as an alkaline additive are mixed using a biaxial pug mill type mixer, and the room temperature construction type lightweight pavement composition according to Example 1 is obtained. Prepared. The total addition amount of asphalt and tall oil fatty acid is “binder amount”. In the following examples and comparative examples, the content ratio of asphalt and tall oil fatty acid in the binder amount should not be changed from the content ratio in Example 1. It was.
The aggregate was mixed while being heated to 120 ° C, the asphalt was mixed while being heated to 160 ° C, and the other members were mixed at room temperature. In the following examples and comparative examples, each component was mixed under the same temperature conditions.

(実施例2)
骨材としてのメサライト(かさ密度:1.316g/cm、吸水率:7.5%、日本メサライト工業(株)社製、膨張性頁岩焼成加工物)78.3質量部、フィラー(奥多摩工業(株)社製、石粉)6.1質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)7.7質量部、硬化剤としてのトール油脂肪酸6.3質量部、及びアルカリ性添加剤としての普通ポルトランドセメント1.6質量部を、2軸パグミル型ミキサを用いて混合し、実施例2に係る常温施工型軽量舗装材組成物を調製した。なお、バインダー量の変更は、骨材の吸水率増加分に応じて、常温施工型軽量舗装材組成物の流動性等を実施例1におけるものと同等に調整するために行うものであり、以降の実施例及び比較例においても同じ目的である。
(Example 2)
Mesalite as an aggregate (bulk density: 1.316 g / cm 3 , water absorption: 7.5%, manufactured by Nippon Mesalite Industry Co., Ltd., calcined shale product) 78.3 parts by mass, filler (Okutama Industry) Co., Ltd., stone powder) 6.1 parts by mass, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 7.7 parts by mass, tall oil fatty acid 6.3 parts by mass as a curing agent, Then, 1.6 parts by mass of ordinary Portland cement as an alkaline additive was mixed using a biaxial pug mill type mixer to prepare a room temperature construction type lightweight pavement composition according to Example 2. In addition, the change in the amount of the binder is performed in order to adjust the fluidity and the like of the room temperature construction type lightweight pavement composition in the same manner as in Example 1 in accordance with the increase in the water absorption rate of the aggregate. This is the same purpose in the examples and comparative examples.

(実施例3)
骨材としての太平洋カルストーンL(かさ密度:1.338g/cm、吸水率:12.7%、太平洋セメント(株)社製、膨張性頁岩焼成加工物)79.1質量部、フィラー(奥多摩工業(株)社製、石粉)5.3質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)7.7質量部、硬化剤としてのトール油脂肪酸6.3質量部、及びアルカリ性添加剤としての普通ポルトランドセメント1.6質量部を、2軸パグミル型ミキサを用いて混合し、実施例3に係る常温施工型軽量舗装材組成物を調製した。
(Example 3)
Taiheiyo Calstone L (bulk density: 1.338 g / cm 3 , water absorption: 12.7%, Taiheiyo Cement Co., Ltd., calcined shale fired product) 79.1 parts by mass, filler (as aggregate) Okutama Kogyo Co., Ltd., stone powder 5.3 parts by weight, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 7.7 parts by weight, tall oil fatty acid 6.3 parts by weight as a curing agent 1.6 parts by weight of ordinary Portland cement as an alkaline additive and a biaxial pug mill type mixer were mixed to prepare a room temperature construction type lightweight pavement composition according to Example 3.

(実施例4)
骨材としての太平洋アサノライト(かさ密度:1.285g/cm、吸水率:13.2%、太平洋セメント(株)社製、膨張性頁岩焼成加工物)78.8質量部、フィラー(奥多摩工業(株)社製、石粉)5.6質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)7.7質量部、硬化剤としてのトール油脂肪酸6.3質量部、及びアルカリ性添加剤としての普通ポルトランドセメント1.6質量部を、2軸パグミル型ミキサを用いて混合し、実施例4に係る常温施工型軽量舗装材組成物を調製した。
Example 4
Pacific asanolite as aggregate (bulk density: 1.285 g / cm 3 , water absorption: 13.2%, Taiheiyo Cement Co., Ltd., calcined shale fired product) 78.8 parts by mass, filler (Okutama) Industrial Co., Ltd., stone powder 5.6 parts by mass, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 7.7 parts by mass, tall oil fatty acid 6.3 parts by mass as a curing agent And 1.6 parts by mass of ordinary Portland cement as an alkaline additive were mixed using a biaxial pug mill type mixer to prepare a room temperature construction type lightweight pavement composition according to Example 4.

(実施例5)
骨材としてのフライクリーン(かさ密度:1.464g/cm、吸水率:23.5%、越智建設(株)社製、フライアッシュ固化物)80.0質量部、フィラー(奥多摩工業(株)社製、石粉)4.4質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)7.7質量部、硬化剤としてのトール油脂肪酸6.3質量部、及びアルカリ性添加剤としての普通ポルトランドセメント1.6質量部を、2軸パグミル型ミキサを用いて混合し、実施例5に係る常温施工型軽量舗装材組成物を調製した。
(Example 5)
Fly clean as aggregate (bulk density: 1.464 g / cm 3 , water absorption: 23.5%, manufactured by Ochi Construction Co., Ltd., solidified fly ash) 80.0 parts by mass, filler (Okutama Kogyo Co., Ltd.) ), Stone powder) 4.4 parts by mass, asphalt (manufactured by Showa Shell Sekiyu KK, straight asphalt 60/80) 7.7 parts by mass, tall oil fatty acid 6.3 parts by mass as a curing agent, and alkaline 1.6 parts by mass of ordinary Portland cement as an additive was mixed using a biaxial pug mill type mixer to prepare a room temperature construction type lightweight pavement composition according to Example 5.

(実施例6)
骨材としてのスーパーソル(L2)(かさ密度:0.553g/cm、吸水率:34.9%、(株)トリム社製、廃ガラス加工物)54.7質量部、フィラー(奥多摩工業(株)社製、石粉)14.1質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)15.4質量部、硬化剤としてのトール油脂肪酸12.6質量部、及びアルカリ性添加剤としての普通ポルトランドセメント3.2質量部を、2軸パグミル型ミキサを用いて混合し、実施例6に係る常温施工型軽量舗装材組成物を調製した。
(Example 6)
Supersol (L2) as aggregate (bulk density: 0.553 g / cm 3 , water absorption: 34.9%, manufactured by Trim Co., Ltd., waste glass processed product) 54.7 parts by mass, filler (Okutama Industry) Co., Ltd., stone powder 14.1 parts by mass, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 15.4 parts by mass, tall oil fatty acid 12.6 parts by mass as a curing agent, Then, 3.2 parts by weight of ordinary Portland cement as an alkaline additive was mixed using a biaxial pug mill type mixer to prepare a light-weight pavement composition at room temperature according to Example 6.

(比較例1)
骨材としてのナルトン(かさ密度:1.009g/cm、吸水率:53.2%、鳴門塩業(株)社製、石炭灰固化物)62.0質量部、フィラー(奥多摩工業(株)社製、石粉)4.6質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)16.5質量部、硬化剤としてのトール油脂肪酸13.5質量部、及びアルカリ性添加剤としての普通ポルトランドセメント3.4質量部を、2軸パグミル型ミキサを用いて混合し、比較例1に係る常温施工型軽量舗装材組成物を調製した。
(Comparative Example 1)
Narton (bulk density: 1.009 g / cm 3 , water absorption: 53.2%, manufactured by Naruto Salt Industry Co., Ltd., coal ash solidified product) 62.0 parts by mass, filler (Okutama Kogyo Co., Ltd.) ), Stone powder) 4.6 parts by weight, asphalt (manufactured by Showa Shell Sekiyu KK, straight asphalt 60/80) 16.5 parts by weight, tall oil fatty acid 13.5 parts by weight as a curing agent, and alkaline 3.4 parts by mass of ordinary Portland cement as an additive was mixed using a biaxial pug mill type mixer to prepare a room temperature construction type lightweight pavement composition according to Comparative Example 1.

(比較例2)
骨材としてのミラクルソル0.4(非吸水)(かさ密度:0.475g/cm、吸水率:61.9%、日本建設技術(株)社製、廃ガラス加工物)53.9質量部、フィラー(奥多摩工業(株)社製、石粉)14.9質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)15.4質量部、硬化剤としてのトール油脂肪酸12.6質量部、及びアルカリ性添加剤としての普通ポルトランドセメント3.2質量部を、2軸パグミル型ミキサを用いて混合し、比較例2に係る常温施工型軽量舗装材組成物を調製した。
(Comparative Example 2)
Miracle Sol 0.4 (non-water absorption) as aggregate (bulk density: 0.475 g / cm 3 , water absorption: 61.9%, manufactured by Nippon Construction Technology Co., Ltd., waste glass processed product) 53.9 mass Parts, filler (Okutama Kogyo Co., Ltd., stone powder) 14.9 parts by mass, asphalt (Showa Shell Sekiyu KK, straight asphalt 60/80) 15.4 parts by mass, tall oil fatty acid as a curing agent 12.6 parts by mass and 3.2 parts by mass of ordinary Portland cement as an alkaline additive were mixed using a biaxial pug mill type mixer to prepare a light-weight pavement composition for room temperature construction according to Comparative Example 2.

(比較例3)
骨材としてのミラクルソル0.4(吸水)(かさ密度:0.473g/cm、吸水率:63.1%、日本建設技術(株)社製、廃ガラス加工物)53.9質量部、フィラー(奥多摩工業(株)社製、石粉)14.9質量部、アスファルト(昭和シェル石油(株)社製、ストレートアスファルト60/80)15.4質量部、硬化剤としてのトール油脂肪酸12.6質量部、及びアルカリ性添加剤としての普通ポルトランドセメント3.2質量部を、2軸パグミル型ミキサを用いて混合し、比較例3に係る常温施工型軽量舗装材組成物を調製した。
(Comparative Example 3)
Miracle Sol 0.4 (water absorption) as aggregate (bulk density: 0.473 g / cm 3 , water absorption: 63.1%, manufactured by Nippon Construction Technology Co., Ltd., waste glass processed product) 53.9 parts by mass , 14.9 parts by weight of filler (Okutama Kogyo Co., Ltd., stone powder), 15.4 parts by weight of asphalt (manufactured by Showa Shell Sekiyu KK, straight asphalt 60/80), tall oil fatty acid 12 as a curing agent .6 parts by mass and 3.2 parts by mass of ordinary Portland cement as an alkaline additive were mixed using a biaxial pug mill type mixer to prepare a room temperature construction type lightweight pavement composition according to Comparative Example 3.

実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物の調製に用いた各骨材のかさ密度は、以下の方法により、測定した。
即ち、かさ密度の測定は、社団法人日本道路協会「舗装調査・試験法便覧 A001 粗骨材の密度および吸水率試験方法」に準拠して、次のように行った。
試験に使用する試料骨材量は、その最大寸法の(ミリメートル表示)の0.1倍をキログラムに表示した量とする。それを十分に水で洗浄し、20℃±2℃の水中で24時間吸水させる。その後、水を切り、表乾状態となるまで水分をぬぐい去る。表乾状態が保たれている内に、空中重量(B)を測定する。試料を金網かごに入れ、20℃±5℃の水中につけ、その水中重量(C)を測定する。水中から取り出した骨材を105℃〜110℃で一定質量となるまで乾燥したのち常温まで冷し、その質量(A)を測定する。これらの測定値を用いて次式により、かさ密度を求めた。
かさ密度=A/(B−C)
〔A:試料の乾燥後の質量、B:試料の表乾後の空中質量、C:試料の水中質量〕
The bulk density of each aggregate used for the preparation of each normal temperature construction type lightweight pavement composition according to Examples 1 to 6 and Comparative Examples 1 to 3 was measured by the following method.
That is, the measurement of the bulk density was performed as follows in accordance with the Japan Road Association “Pavement Survey and Test Method Handbook A001 Coarse Aggregate Density and Water Absorption Test Method”.
The amount of sample aggregate used in the test is the amount expressed in kilograms of 0.1 times its maximum dimension (in millimeters). It is thoroughly washed with water and absorbed in water at 20 ° C. ± 2 ° C. for 24 hours. After that, drain the water and wipe away the moisture until it is dry. While the surface dry state is maintained, the air weight (B) is measured. The sample is put in a wire mesh basket, placed in water at 20 ° C. ± 5 ° C., and the weight in water (C) is measured. The aggregate taken out from the water is dried at 105 ° C. to 110 ° C. to a constant mass, cooled to room temperature, and the mass (A) is measured. The bulk density was calculated | required by following Formula using these measured values.
Bulk density = A / (BC)
[A: Mass after drying sample, B: Air mass after surface drying of sample, C: Mass in water of sample]

また、実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物の調製に用いた各骨材の吸水率は、以下の方法により、測定した。
即ち、吸水率の測定は、社団法人日本道路協会「舗装調査・試験法便覧 A001 粗骨材の密度および吸水率試験方法」に準拠して、次のように行った。
試験に使用する試料骨材量は、その最大寸法の(ミリメートル表示)の0.1倍をキログラムに表示した量とする。それを十分に水で洗浄し、20℃±2℃の水中で24時間吸水させる。その後、水を切り、表乾状態となるまで水分をぬぐい去る。表乾状態が保たれている内に、空中重量(B)を測定する。その後、骨材を105℃〜110℃で一定質量となるまで乾燥したのち常温まで冷し、その質量(A)を測定する。これらの測定値を用いて次式により、吸水率を求めた。
吸水率=(B−A)/A×100(%)
〔A:試料の乾燥後の質量、B:試料の表乾後の空中質量〕
Moreover, the water absorption rate of each aggregate used for preparation of each normal temperature construction type lightweight pavement composition which concerns on Examples 1-6 and Comparative Examples 1-3 was measured with the following method.
That is, the water absorption rate was measured as follows in accordance with the Japan Road Association “Pavement Survey / Test Method Handbook A001 Coarse Aggregate Density and Water Absorption Test Method”.
The amount of sample aggregate used in the test is the amount expressed in kilograms of 0.1 times its maximum dimension (in millimeters). It is thoroughly washed with water and absorbed in water at 20 ° C. ± 2 ° C. for 24 hours. After that, drain the water and wipe away the moisture until it is dry. While the surface dry state is maintained, the air weight (B) is measured. Thereafter, the aggregate is dried at 105 ° C. to 110 ° C. to a constant mass, cooled to room temperature, and its mass (A) is measured. Using these measured values, the water absorption was determined by the following equation.
Water absorption rate = (B−A) / A × 100 (%)
[A: Mass after drying of sample, B: Air mass after surface drying of sample]

<骨材の割れ>
実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物に対して、以下の方法により、骨材の割れに関する測定を行った。
即ち、骨材の割れの測定は、マーシャル安定度試験終了後に割れた断面を観察することによって行った。マーシャル安定度試験は、社団法人日本道路協会「舗装調査・試験法便覧 B001 マーシャル安定度試験」に従って、次のように行った。
実施例1〜6及び比較例1〜3により混合し調製された、各常温施工型軽量舗装材組成物について、締固め後の供試体の高さが63.5±1.3mmになるように計量し、内径101.6mmの円筒形モールドに入れる。へら等で周囲にそって15回、中央部を10回突き、表面に丸みをつけてならす。その後、硬化開始剤としての水分を添加し、45.7cmの高さから案内棒に沿ってモールド内に自由落下する質量4.5kgの重錘ランマにより両面を50回締固め、室温20度、湿度60%の恒温室内で7日間養生する。供試体をモールドから抜き取り60℃±1℃の水槽中に30分〜40分入れる。供試体を水槽から取り出し、マーシャル安定度試験装置の下部載荷ヘッドに載せ、上部載荷ヘッドをかぶせて載荷装置に設置する。50±5mm/minの一様な変位速さで供試体に荷重を加える。載荷により割れた供試体の断面を目視により観察し、骨材の割れの状況を判定した。判定の結果は、以下の基準で整理した。
○:骨材の割れが少ない。
△:骨材の割れがやや多い。
×:骨材の大部分が割れている。
なお、本測定において、「測定不能」とは、60℃水浸中に供試体が崩壊し、試験が不可能になることにより、測定を行うことができなかったことを示す。
測定結果を後掲の表1に示す。
<Aggregate cracking>
With respect to each normal temperature construction type lightweight pavement composition according to Examples 1 to 6 and Comparative Examples 1 to 3, measurements on aggregate cracking were performed by the following method.
That is, the measurement of the crack of the aggregate was performed by observing the cross section that was cracked after the Marshall stability test was completed. The Marshall stability test was performed as follows according to the Japan Road Association “Pavement Survey and Test Method Handbook B001 Marshall Stability Test”.
About each normal temperature construction type lightweight pavement composition prepared by mixing in Examples 1 to 6 and Comparative Examples 1 to 3, the height of the specimen after compaction was 63.5 ± 1.3 mm. Weigh and place in a cylindrical mold with an inner diameter of 101.6 mm. Use a spatula etc. to strike the center 15 times and the center 10 times to round the surface. After that, water as a curing initiator was added, and both sides were compacted 50 times with a weight 4.5 kg weight ramper that freely dropped into the mold along the guide rod from a height of 45.7 cm. Cured for 7 days in a constant temperature room with 60% humidity. The specimen is removed from the mold and placed in a 60 ° C. ± 1 ° C. water bath for 30-40 minutes. The specimen is removed from the water tank, placed on the lower loading head of the Marshall stability test device, and placed on the loading device with the upper loading head covered. A load is applied to the specimen at a uniform displacement speed of 50 ± 5 mm / min. The cross section of the specimen that was cracked by loading was observed visually to determine the condition of the aggregate cracking. The judgment results are organized according to the following criteria.
○: There are few cracks of the aggregate.
Δ: Aggregate cracks a little.
X: Most of the aggregate is cracked.
In this measurement, “impossible to measure” means that the measurement could not be performed because the specimen collapsed during 60 ° C. water immersion and the test was impossible.
The measurement results are shown in Table 1 below.

<安定度>
実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物に対して、以下の方法により、安定度の測定を行った。
即ち、 安定度の測定は、社団法人日本道路協会「舗装調査・試験法便覧 B001 マーシャル安定度試験方法」に従って、次のように測定を行った。
実施例1〜6及び比較例1〜3により混合し調製された、各常温施工型軽量舗装材組成物について、締固め後の供試体の高さが63.5±1.3mmになるように計量し、内径101.6mmの円筒形モールドに入れる。へら等で周囲にそって15回、中央部を10回突き、表面に丸みをつけてならす。その後、硬化開始剤としての水分を添加し、45.7cmの高さから案内棒に沿ってモールド内に自由落下する質量4.5kgの重錘ランマにより両面を50回締固め、室温20度、湿度60%の恒温室内で7日間養生する。供試体をモールドから抜き取り60℃±1℃の水槽中に30分〜40分入れる。供試体を水槽から取り出し、マーシャル安定度試験装置の下部載荷ヘッドに載せ、上部載荷ヘッドをかぶせて載荷装置に設置する。50±5mm/minの一様な変位速さで供試体に荷重を加える。最大荷重に達した時の数値を読み取る。結果は、最大荷重をkN単位にまとめて安定度として示した。
なお、本測定において、「測定不能」とは、60℃水浸中に供試体が崩壊し、試験が不可能になることにより、測定を行うことができなかったことを示す。
測定結果を後掲の表1に示す。
<Stability>
Stability was measured by the following method with respect to each normal temperature construction type light pavement composition according to Examples 1 to 6 and Comparative Examples 1 to 3.
That is, the stability was measured according to the Japan Road Association “Pavement Survey / Test Method Handbook B001 Marshall Stability Test Method” as follows.
About each normal temperature construction type lightweight pavement composition prepared by mixing in Examples 1 to 6 and Comparative Examples 1 to 3, the height of the specimen after compaction was 63.5 ± 1.3 mm. Weigh and place in a cylindrical mold with an inner diameter of 101.6 mm. Use a spatula etc. to strike the center 15 times and the center 10 times to round the surface. After that, water as a curing initiator was added, and both sides were compacted 50 times with a weight 4.5 kg weight ramper that freely dropped into the mold along the guide rod from a height of 45.7 cm. Cured for 7 days in a constant temperature room with 60% humidity. The specimen is removed from the mold and placed in a 60 ° C. ± 1 ° C. water bath for 30-40 minutes. The specimen is removed from the water tank, placed on the lower loading head of the Marshall stability test device, and placed on the loading device with the upper loading head covered. A load is applied to the specimen at a uniform displacement speed of 50 ± 5 mm / min. Read the value when the maximum load is reached. The results are shown as stability with the maximum load in kN units.
In this measurement, “impossible to measure” means that the measurement could not be performed because the specimen collapsed during 60 ° C. water immersion and the test was impossible.
The measurement results are shown in Table 1 below.

<作業性>
実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物に対して、以下の方法により、作業性の評価を行った。
即ち、実施例1〜6及び比較例1〜3により混合し調製された、各常温施工型軽量舗装材組成物について、その作製直後から1日経過後の各試験における供試体作製時に、スコップやへら等で容易にかきほぐすことが可能であるかどうか判定した。判定の結果は、以下の基準で整理した。
○:容易にかきほぐすことができる。
△:若干の塊がみられるが、かきほぐすことができる。
×:塊が多くもしくは全体が固まり、容易にかきほぐすことができない。
評価結果を後掲の表1に示す。
<Workability>
The workability was evaluated by the following methods for each room temperature construction type lightweight pavement composition according to Examples 1 to 6 and Comparative Examples 1 to 3.
That is, with respect to each normal temperature construction type lightweight pavement composition prepared by mixing according to Examples 1 to 6 and Comparative Examples 1 to 3, a scoop or spatula was used at the time of specimen preparation in each test after 1 day from immediately after its production. It was determined whether or not it was possible to easily disentangle it by using the above method. The judgment results are organized according to the following criteria.
○: Can be easily cracked.
Δ: Although some lumps are seen, they can be loosened.
X: There are many lumps or the whole is hardened and cannot be easily disentangled.
The evaluation results are shown in Table 1 below.

<路面形状の変形量(DS)>
実施例1〜6及び比較例1〜3に係る各常温施工型軽量舗装材組成物に対して、以下の方法により、路面形状の変形量(DS)の測定を行った。
即ち、DSの測定は、社団法人日本道路協会「舗装調査・試験法便覧 B003 ホイールトラッキング試験方法」に従って、次のように測定を行った。
実施例1〜6及び比較例1〜3により混合し調製された、各常温施工型軽量舗装材組成物について、出来上り供試体寸法が、長さ300mm、幅300mm、厚さ50mmとなるような型枠に目標の密度(ここでは、マーシャル安定度試験によって得られた密度)に相当する質量の常温施工型軽量舗装材組成物を計量する。それを約半分型枠に入れ、四隅をスコップで突いた後、平らに均し、へら等で軽く押さえる。その後、残りを型枠の四隅に均等に入れ、四隅をへら等で各5回程度、斜め上から角に向かって突く。その後、型枠に沿って1周へら等で突き、押し固める。へら等の背中で表面整形をした後、硬化開始剤としての水分を添加し、振動タンパ等で予備転圧を行う。ローラコンパクタにより線圧29.4kN/mで5往復転圧する。その後マーシャル安定度試験によって求められた基準密度の100±1%の締固め度になるように締め固める。室温20度、湿度60%の恒温室内で7日間養生する。供試体を、試験用の型枠に移し固定し、試験開始5時間以上前にあらかじめ60±2℃に保った恒温室で養生する。中央部を走行位置とし、走行輪荷重686±10Nで直進走行させる。その際、走行方向は転圧方向と一致させる。変形量の測定は、最初に中央部を通過した時のダイアルゲージの読みを原点とし、測定開始45分と60分時の値を変形曲線の形状に応じて読み取る。これらの測定値を用いて次式により、DSを求めた。
DS(動的安定度:回/mm)=42×(t−t)/(d−d
〔t:45分、t:60分、d:45分における変形量(mm)、d:60分における変形量(mm)〕
なお、本測定において、「測定不能」とは、変形量が著しくなることにより、測定を行うことができなかったことを示す。
測定結果を下記表1に示す。
<Deformation amount of road surface shape (DS)>
The deformation amount (DS) of the road surface shape was measured by the following method for each room temperature construction type light pavement composition according to Examples 1 to 6 and Comparative Examples 1 to 3.
That is, DS was measured according to the Japan Road Association “Pavement Survey / Test Method Handbook B003 Wheel Tracking Test Method” as follows.
About each normal temperature construction type light-weight pavement material composition prepared by mixing in Examples 1 to 6 and Comparative Examples 1 to 3, the finished specimen dimensions are 300 mm in length, 300 mm in width, and 50 mm in thickness. A normal temperature construction type light pavement composition having a mass corresponding to a target density (here, a density obtained by a Marshall stability test) is weighed in a frame. Put it in about half the formwork, poke the four corners with a scoop, level it flat, and gently press it with a spatula. Then, the rest is put evenly in the four corners of the mold, and the four corners are struck from the diagonally upward to the corners about 5 times with a spatula or the like. Then, it is pushed and hardened with a spatula or the like along the mold. After surface shaping with the back of a spatula or the like, water as a curing initiator is added, and preliminary rolling is performed with a vibration tamper or the like. The roller compactor performs 5 reciprocating rollings at a linear pressure of 29.4 kN / m. After that, it is compacted so that the compaction degree is 100 ± 1% of the reference density determined by the Marshall stability test. Cured for 7 days in a constant temperature room at 20 ° C and 60% humidity. The specimen is transferred to a test form and fixed, and then cured in a thermostatic chamber maintained at 60 ± 2 ° C. at least 5 hours before the start of the test. The central portion is set as the travel position, and the vehicle travels straight at a traveling wheel load of 686 ± 10N. At that time, the traveling direction is made to coincide with the rolling direction. The deformation is measured by reading the dial gauge when it first passes through the center as the origin, and reading the values at 45 minutes and 60 minutes from the start of the measurement according to the shape of the deformation curve. DS was calculated | required by following Formula using these measured values.
DS (dynamic stability: times / mm) = 42 × (t 2 −t 1 ) / (d 2 −d 1 )
[T 1 : 45 minutes, t 2 : 60 minutes, d 1 : deformation (mm) at 45 minutes, d 2 : deformation (mm) at 60 minutes]
In this measurement, “unmeasurable” means that the measurement could not be performed due to the significant deformation.
The measurement results are shown in Table 1 below.

上掲の表1に示すように、実施例1〜6に係る各常温施工型軽量舗装材組成物は、軽量でありながらも、作業性に富み、路面舗装用途に必要な強度及び耐久性を向上させることができているのに対し、比較例1〜3に係る各常温施工型軽量舗装材組成物は、作業性に富み、路面舗装用途に必要な強度及び耐久性を向上させることができなかった。
即ち、比較例1〜3に係る各常温施工型軽量舗装材組成物では、骨材の割れや安定度が測定不能とされるように十分な強度が発現せず、また、作業性が悪く、更に、路面形状の変形量(DS)が測定不能とされるように、強度及び耐久性が乏しい結果となったが、実施例1〜6に係る各常温施工型軽量舗装材組成物では、このようなことがなく、十分実用に耐えられる結果となった。
As shown in Table 1 above, each of the normal temperature construction type lightweight pavement compositions according to Examples 1 to 6 is lightweight but rich in workability and has the strength and durability necessary for road pavement use. While being able to improve, each normal temperature construction type light pavement composition according to Comparative Examples 1 to 3 is rich in workability and can improve the strength and durability required for road pavement applications. There wasn't.
That is, in each normal temperature construction type lightweight pavement composition according to Comparative Examples 1 to 3, sufficient strength is not expressed so that the cracking and stability of the aggregate cannot be measured, and workability is poor. Furthermore, although the amount of deformation (DS) of the road surface shape could not be measured, the results were poor in strength and durability, but in each room temperature construction type lightweight pavement composition according to Examples 1 to 6, There was no such a thing, and the results were able to withstand practical use.

中でも、実施例1〜6に係る各常温施工型軽量舗装材組成物では、骨材の吸水率が5%未満である実施例1に係る常温施工型軽量舗装材組成物に比べ、骨材の吸水率が5%〜20%である実施例2〜4に係る各常温施工型軽量舗装材組成物の方が、骨材の割れが少なく、また、路面形状の変形量(DS)を大幅に低減できており、また、骨材の吸水率が20%を超える実施例5,6に係る各常温施工型軽量舗装材組成物に比べ、骨材の吸水率が5%〜20%である実施例2〜4に係る各常温施工型軽量舗装材組成物の方が、骨材の割れが少なく、安定度を大幅に向上させ、作業性を向上させ、また、路面形状の変形量(DS)を大幅に低減できている。
したがって、骨材の吸水率としては、5%〜20%が特に好ましい。
なお、実施例2,4に係る各常温施工型軽量舗装材組成物では、安定度が実施例1に係る常温施工型軽量舗装材組成物よりも低い結果となっているが、一般に、9.0以上であれば、必要十分である。
Especially, in each normal temperature construction type lightweight pavement composition which concerns on Examples 1-6, compared with the normal temperature construction type lightweight pavement composition which concerns on Example 1 whose water absorption rate of aggregate is less than 5%, Each normal temperature construction type light pavement composition according to Examples 2 to 4 having a water absorption rate of 5% to 20% has less aggregate cracking and greatly reduces the amount of deformation (DS) of the road surface shape. Compared with each normal temperature construction type light pavement composition according to Examples 5 and 6 in which the water absorption rate of the aggregate exceeds 20%, the aggregate water absorption rate is 5% to 20%. Each normal temperature construction type light pavement composition according to Examples 2 to 4 has less cracking of aggregate, greatly improves stability, improves workability, and the amount of deformation of the road surface shape (DS) Can be greatly reduced.
Therefore, the water absorption rate of the aggregate is particularly preferably 5% to 20%.
In addition, although each room temperature construction type lightweight pavement composition according to Examples 2 and 4 has a lower stability than the room temperature construction type light pavement composition according to Example 1, in general, 9. If it is 0 or more, it is necessary and sufficient.

ここで、本発明の常温施工型軽量舗装材組成物における骨材に対する硬化剤、アルカリ性添加剤等の浸透状況について、図1,2を用いて説明する。
図1は、実施例3に係る常温施工型軽量舗装材組成物の骨材に対する硬化剤、アルカリ添加剤等の浸透状況を撮像した顕微鏡写真像である。また、図2は、実施例3に係る常温施工型軽量舗装材組成物に用いた骨材のみを撮像した顕微鏡写真像である。
これら顕微鏡写真の撮像には、蛍光顕微鏡(Nikon社製、ECLIPSE TE2000−U)を用い、フィルタブロックを行うことで、硬化剤、アルカリ添加剤等が明るく撮像され、骨材が暗く撮像されるように設定を行っている。
図1、図2に示すように、硬化剤、アルカリ性添加剤等を用いない骨材のみの場合と異なり、実施例3に係る常温施工型軽量舗装材組成物では、硬化剤、アルカリ性添加剤等が多孔質の骨材粒子の表面をコーティングするとともに骨材粒子の内部にまで浸透していることが確認される。
Here, the penetration | invasion condition of the hardening | curing agent with respect to the aggregate in the normal temperature construction type lightweight pavement composition of this invention, an alkaline additive, etc. is demonstrated using FIG.
FIG. 1 is a photomicrograph of an image of the penetration of a curing agent, an alkali additive, and the like into an aggregate of a room temperature construction type lightweight pavement composition according to Example 3. FIG. 2 is a photomicrograph of only the aggregates used in the room temperature construction type lightweight pavement composition according to Example 3.
These microphotographs are imaged using a fluorescent microscope (Nikon, ECLIPSE TE2000-U) and filter blocking, so that the curing agent, the alkali additive, etc. are imaged brightly and the aggregate is imaged darkly. Has been set.
As shown in FIGS. 1 and 2, unlike the case of only aggregates that do not use a curing agent, an alkaline additive, etc., the room temperature construction type lightweight pavement composition according to Example 3 has a curing agent, an alkaline additive, etc. Is coated on the surface of the porous aggregate particles and penetrates into the aggregate particles.

以上のように、本発明の常温施工型軽量舗装材組成物では、軽量でありながら、作業性に富み、かつ、強度及び耐久性に優れることから、アスファルト舗装の分野において、広く利用することができる。特に、ポットホール等の補修に好適に用いることができる。   As described above, the light-weight pavement composition of ordinary temperature construction type of the present invention is lightweight, rich in workability, and excellent in strength and durability, so that it can be widely used in the field of asphalt pavement. it can. In particular, it can be suitably used for repairing potholes and the like.

Claims (3)

骨材、アスファルト、油脂及び脂肪酸のいずれかを含む硬化剤、及び硬化開始剤の添加により前記硬化剤と鹸化反応するアルカリ性添加剤を含む常温施工型軽量舗装材組成物において、
前記骨材は、かさ密度が0.5g/cm〜1.9g/cmであり、かつ吸水率が2%〜35%であることを特徴とする常温施工型軽量舗装材組成物。
In a room temperature construction type lightweight pavement composition containing an aggregate, an asphalt, a hardener containing any of fats and oils, and an alkaline additive that saponifies with the hardener by adding a curing initiator,
The aggregate has a bulk density of 0.5g / cm 3 ~1.9g / cm 3 , and cold construction type lightweight paving composition, wherein the water absorption is 2% to 35%.
骨材のかさ密度が1.0g/cm〜1.6g/cmである請求項1に記載の常温施工型軽量舗装材組成物。 Cold construction type lightweight paving composition of claim 1 bulk density of the aggregate is 1.0g / cm 3 ~1.6g / cm 3 . 骨材の吸水率が5%〜20%である請求項1から2のいずれかに記載の常温施工型軽量舗装材組成物。   The composition for lightweight pavement construction at room temperature according to any one of claims 1 to 2, wherein the aggregate has a water absorption of 5% to 20%.
JP2014016693A 2014-01-31 2014-01-31 Cold application-type lightweight pavement material composition Pending JP2015143423A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5916937B1 (en) * 2015-12-21 2016-05-11 前田道路株式会社 Asphalt mixture, method for producing the same, and pavement method using the same
JP5916938B1 (en) * 2015-12-21 2016-05-11 前田道路株式会社 Asphalt mixture, method for producing the same, and pavement method using the same
KR101923921B1 (en) * 2016-08-24 2018-11-30 주식회사 상민건설 A method of construction for mending road
WO2021010053A1 (en) * 2019-07-12 2021-01-21 富士フイルム株式会社 Curing accelerator aqueous solution for asphalt, asphalt mixture, paving set, and paving method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5916937B1 (en) * 2015-12-21 2016-05-11 前田道路株式会社 Asphalt mixture, method for producing the same, and pavement method using the same
JP5916938B1 (en) * 2015-12-21 2016-05-11 前田道路株式会社 Asphalt mixture, method for producing the same, and pavement method using the same
US9617426B1 (en) 2015-12-21 2017-04-11 Maeda Road Construction Co., Ltd. Asphalt mixture, process for production of same, and paving method using same
US9617425B1 (en) 2015-12-21 2017-04-11 Maeda Road Construction Co., Ltd. Asphalt mixture, process for production of same, and paving method using same
KR101923921B1 (en) * 2016-08-24 2018-11-30 주식회사 상민건설 A method of construction for mending road
WO2021010053A1 (en) * 2019-07-12 2021-01-21 富士フイルム株式会社 Curing accelerator aqueous solution for asphalt, asphalt mixture, paving set, and paving method
JPWO2021010053A1 (en) * 2019-07-12 2021-01-21

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