JP2015124448A - Lining paper for wallpaper - Google Patents

Lining paper for wallpaper Download PDF

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JP2015124448A
JP2015124448A JP2013268289A JP2013268289A JP2015124448A JP 2015124448 A JP2015124448 A JP 2015124448A JP 2013268289 A JP2013268289 A JP 2013268289A JP 2013268289 A JP2013268289 A JP 2013268289A JP 2015124448 A JP2015124448 A JP 2015124448A
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paper
mass
wallpaper
backing paper
pulp
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悠生 川浪
Hisao Kawanami
悠生 川浪
直信 杉山
Naonobu Sugiyama
直信 杉山
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Oji Holdings Corp
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Oji Holdings Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a lining paper for a foamed wallpaper excellent in peeling suitability when the wallpaper is peeled from a wall surface, the wet tensile strength of the lining paper, the dimensional change rate in water of the lining paper, the curling property of the lining paper, and the mutual peeling property of the lining paper with a wallpaper.SOLUTION: The lining paper for a wallpaper produced from a paper substrate containing pulp is produced by papermaking the pulp in which a wet paper strengthening agent is contained in a content of 0.5 mass%-3.0 mass%; a rosin sizing agent is contained in a content of 0.05 mass%-0.3 mass%; kaolin is contained in a content of 5 mass%-25 mass%; and a yield improver is contained in a content of 0.001 mass%-0.035 mass%, and the lining paper has an aspect ratio of the tensile strength measured according to JIS P 8113 (2006) of 1.0-2.5 and a sizing degree measured by the Stockigt method specified in JIS P 8122 (2004) of 1-20 second(s).

Description

本発明は発泡壁紙等に用いられる壁紙用裏打ち紙に関し、特に壁面から壁紙を剥離する際のピール適性、裏打ち紙の湿潤引張強度、水中寸法安定性、カール、相剥ぎ性に優れる壁紙用裏打ち紙に関する。   BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a backing paper for wallpaper used for foamed wallpaper and the like, and in particular, a backing paper for wallpaper excellent in peelability when peeling the wallpaper from the wall surface, wet tensile strength of the backing paper, underwater dimensional stability, curl, and peelability. About.

ビニル発泡壁紙、紙発泡壁紙、オレフィン発泡壁紙等の発泡壁紙は、主に意匠性を付与する上層と、上層を支持して施工性を付与する裏打ち紙の2層構造より成っている。これらの発泡壁紙は、施工時、澱粉や酢酸ビニル等の水系の糊によって壁に貼合されるが、この糊付け工程で糊中の水が裏打ち紙に吸収され、発泡壁紙が柔らかくなったり、裏打ち紙が水分増加により伸びることがある。そして、これが原因で、カールの発生が大きくなったり、発泡壁紙の壁面への貼付作業が困難となったり、貼付後の壁紙の捲れが起き易い等の問題点があった。さらに、糊が乾燥すると裏打ち紙が収縮し、施工生産性の良いつきつけ貼りを行うと、隣接して貼り合わせた壁紙同士の繋ぎ目部分に隙間が生じる問題(目開き)があり、施工後の意匠性を損なう等の欠点があった。
このようなことから、糊付けしてもカールし難く、寸法安定性も改善された発泡壁紙用裏打ち紙として、抄紙工程の乾燥部が、いわゆるヤンキードライヤーで乾燥することによって抄紙された裏打ち紙が用いられてきている(特許文献1、特許文献2)。
Foamed wallpaper such as vinyl foamed wallpaper, paper foamed wallpaper, and olefin foamed wallpaper is mainly composed of a two-layer structure of an upper layer that imparts designability and a backing paper that supports the upper layer and imparts workability. These foamed wallpaper is pasted on the wall with water-based glue such as starch or vinyl acetate at the time of construction, but the water in the glue is absorbed by the backing paper in this gluing process, and the foamed wallpaper becomes soft or lining. Paper may stretch due to increased moisture. Further, due to this, there are problems such as the occurrence of curling becomes large, the work of sticking the foamed wallpaper to the wall surface becomes difficult, and the wallpaper after the sticking tends to curl. In addition, when the glue dries, the backing paper shrinks, and when performing sticking with good construction productivity, there is a problem (gap) that creates a gap in the joint portion between adjacent bonded wallpapers. There were drawbacks such as impaired designability.
For this reason, the backing paper made by making the drying part of the paper making process dry with a so-called Yankee dryer is used as the backing paper for foamed wallpaper which is difficult to curl even when glued and the dimensional stability is improved. (Patent Document 1, Patent Document 2).

また、裏打ち紙の毛羽立ちが少なく、印刷適性に優れ、壁面から壁紙を剥離する際のピール適性が良い裏打ち紙が提案されている(特許文献3)。
しかしながら、これらの発明においては、壁面から壁紙を剥離する際のピール適性に加え、湿潤引張強度、水中寸法安定性、カール、相剥ぎ性を同時に満足させる技術については考慮されておらず、前記特性については不十分であった。
Also, a backing paper has been proposed that has less fluffing of the backing paper, excellent printability, and good peelability when peeling wallpaper from a wall surface (Patent Document 3).
However, in these inventions, in addition to the peelability when peeling the wallpaper from the wall surface, no consideration is given to a technique that simultaneously satisfies wet tensile strength, underwater dimensional stability, curl, and phase peelability. Was not enough.

特開2005−82894号公報JP 2005-82894 A 特開2007−92223号公報JP 2007-92223 A 特開2009−242982号公報JP 2009-242982 A

したがって、本発明の目的は、壁紙用裏打ち紙に関し、壁面から壁紙を剥離する際のピール適性、裏打ち紙の湿潤引張強度、水中寸法安定性、カール、相剥ぎ性に優れる壁紙用裏打ち紙を提供することにある。   Accordingly, an object of the present invention relates to a backing paper for wallpaper, and provides a backing paper for wallpaper that is excellent in peelability when peeling the wallpaper from the wall surface, wet tensile strength of the backing paper, underwater dimensional stability, curl, and peelability. There is to do.

本発明者等は、上記の課題を解決すべく鋭意検討した結果、紙基材に填料としてのカオリン、湿潤紙力剤、ロジンサイズ剤を特定の範囲で含有させ、引張強度の縦横比、サイズ度を制御した場合には、良好な結果を得ることができることを見出し、本発明を完成させるに至った。   As a result of intensive studies to solve the above-mentioned problems, the present inventors have included kaolin, a wet paper strength agent, and a rosin sizing agent as fillers in a specific range, and have a tensile strength aspect ratio and size. It has been found that good results can be obtained when the degree is controlled, and the present invention has been completed.

即ち、本発明は以下のような各発明を包含する。
(1)パルプを含有する紙基材からなる壁紙用裏打ち紙において、前記パルプに湿潤紙力剤を0.5〜3.0質量%、ロジンサイズ剤を0.05〜0.3質量%、カオリンを5〜25質量%、歩留向上剤を0.001〜0.035質量%含有させて抄紙し、JIS P 8113:2006に準じて測定した引張強度の縦横比が1.0〜2.5、JIS P 8122:2004に準じて測定したステキヒト法サイズ度が1〜20秒であることを特徴とする壁紙用裏打ち紙。
That is, the present invention includes the following inventions.
(1) In the backing paper for wallpaper which consists of a paper base material containing a pulp, 0.5-3.0 mass% of wet paper strength agents, 0.05-0.3 mass% of rosin sizing agents, Paper is made by containing 5 to 25% by mass of kaolin and 0.001 to 0.035% by mass of a yield improver, and the aspect ratio of tensile strength measured according to JIS P 8113: 2006 is 1.0 to 2. 5. A backing paper for wallpaper characterized in that the sizing degree of the Steecht method measured in accordance with JIS P 8122: 2004 is 1 to 20 seconds.

(2)前記パルプのJIS P 8121−2012に準じて測定したカナダ標準濾水度(CSF)が400〜600mlであることを特徴とする(1)に記載の壁紙用裏打ち紙。 (2) The backing paper for wallpaper according to (1), wherein the Canadian standard freeness (CSF) measured according to JIS P 8121-2012 of the pulp is 400 to 600 ml.

(3)前記紙基材のJAPAN TAPPI 紙パルプ試験方法No.27:2000に準じて測定した水中伸度が2.0%以下であることを特徴とする(1)または(2)に記載の壁紙用裏打ち紙。 (3) JAPAN TAPPI paper pulp test method no. 27: The backing paper for wallpaper according to (1) or (2), wherein the underwater elongation measured in accordance with 27: 2000 is 2.0% or less.

(4)前記紙基材の坪量が60〜100g/mであることを特徴とする(1)〜(3)のいずれか1項に記載の壁紙用裏打ち紙。 (4) The backing paper for wallpaper according to any one of (1) to (3), wherein the paper substrate has a basis weight of 60 to 100 g / m 2 .

本発明の壁紙用裏打ち紙は、高価な材料を使用しないにもかかわらず、壁面から壁紙を剥離する際のピール適性、裏打ち紙の湿潤引張強度、水中寸法安定性、カール、相剥ぎ性に優れた壁紙用裏打ち紙である。   The backing paper for wallpaper of the present invention is excellent in peelability when peeling the wallpaper from the wall surface, wet tensile strength of the backing paper, underwater dimensional stability, curl, and phase peelability, even though expensive materials are not used. A backing paper for wallpaper.

本発明の壁紙用裏打ち紙においては、湿潤紙力剤を、紙基材に対して0.5〜3.0質量%の範囲で含有させることが必要であるが、特に、0.7〜2.5質量%含有させることが好ましく、より好ましくは0.8〜2.0質量%である。湿潤紙力剤の含有量が0.5質量%未満であると水中寸法変化率やカールが大きく、壁紙を貼着する際の作業性が悪化する。湿潤紙力剤の含有量が3.0質量%を超えると水中寸法変化率は小さいものの、損紙の離解性が悪化するという、操業上の問題が生じる。   In the backing paper for wallpaper of the present invention, it is necessary to contain the wet paper strength agent in the range of 0.5 to 3.0% by mass with respect to the paper base material. It is preferable to make it contain 0.5 mass%, More preferably, it is 0.8-2.0 mass%. When the content of the wet paper strength agent is less than 0.5% by mass, the underwater dimensional change rate and curl are large, and the workability at the time of pasting the wallpaper deteriorates. When the content of the wet paper strength agent exceeds 3.0% by mass, the dimensional change rate in water is small, but the operational problem that the disaggregation property of the waste paper deteriorates occurs.

なお、湿潤紙力剤を通常よりも比較的高い割合で含有させることにより紙層間強度が高くなるため、貼替え時に壁面から壁紙を剥離する際の再剥離適性を向上させることができる。   In addition, since a paper interlayer strength becomes high by containing a wet paper strength agent in a relatively higher ratio than usual, it is possible to improve re-peelability when the wallpaper is peeled from the wall surface at the time of replacement.

本発明で使用する湿潤紙力剤としては、例えば、ポリアミド・エピクロロヒドリン、ポリアミン・エピクロロヒドリン、エポキシ樹脂、メラミン樹脂等が挙げられが、特にポリアミド・エピクロロヒドリン又はポリアミン・エピクロロヒドリンを使用することが好ましい。   Examples of the wet paper strength agent used in the present invention include polyamide / epichlorohydrin, polyamine / epichlorohydrin, epoxy resin, melamine resin and the like, and in particular, polyamide / epichlorohydrin or polyamine / epiamine. Preference is given to using chlorohydrin.

本発明で内添するロジンサイズ剤を通常よりも低い割合、すなわち0.05〜0.3質量%で含有させることが必要であるが、特に、0.07〜0.25質量%含有させることが好ましく、より好ましくは0.08〜0.22質量%である。ロジンサイズ剤の含有量が0.05質量%未満であると、水分の浸透性が大きくなり過ぎ、水中伸度やカールが大きくなり過ぎ、壁紙を貼着する際の作業性が悪化する。
一方、ロジンサイズ剤の含有量が0.3質量%を超えても、サイズ度がそれ以上向上しないので不経済である上、抄紙機の汚れの原因となる。ロジンサイズ剤は酸性用、中性用共に使用することが可能である。
It is necessary to contain the rosin sizing agent internally added in the present invention at a lower ratio than usual, that is, 0.05 to 0.3% by mass, and in particular, 0.07 to 0.25% by mass. Is more preferable, and 0.08 to 0.22 mass% is more preferable. When the content of the rosin sizing agent is less than 0.05% by mass, the water permeability becomes excessively high, the elongation in water and the curl become excessively large, and the workability at the time of pasting the wallpaper deteriorates.
On the other hand, even if the content of the rosin sizing agent exceeds 0.3% by mass, the degree of sizing does not improve any more, which is uneconomical and causes stains on the paper machine. The rosin sizing agent can be used for both acidic and neutral use.

本発明の壁紙用裏打ち紙に使用する紙基材には、不透明度を向上させるために、填料としてカオリンを紙基材当たり5〜25質量%含有させる必要があるが、7〜20質量%が好ましく、8〜18質量%であることがより好ましい。カオリンの含有量が5質量%未満であると、不透明度が不十分となり、しかも貼替え時に壁面から壁紙を剥離する際のピール適性が不十分となる。逆にカオリンの含有量が25質量%を超えると、湿潤引張強度が不十分となる。また、これら以外にも、デラミネーテッドカオリン、重質炭酸カルシウム、軽質炭酸カルシウム、軽質炭酸カルシウム−シリカ複合物、炭酸マグネシウム、炭酸バリウム、二酸化チタン、酸化亜鉛、酸化珪素、非晶質シリカ、水酸化アルミニウム、水酸化カルシウム、水酸化マグネシウム、水酸化亜鉛などの無機填料、尿素−ホルマリン樹脂、スチレン樹脂、フェノール樹脂等の有機填料を所望の効果を阻害しない範囲で併用してもよい。   In order to improve the opacity, the paper base material used for the wallpaper backing paper of the present invention needs to contain 5 to 25% by mass of kaolin as a filler, but 7 to 20% by mass is included. Preferably, it is 8-18 mass%. When the content of kaolin is less than 5% by mass, the opacity becomes insufficient, and the peelability at the time of peeling the wallpaper from the wall surface at the time of replacement becomes insufficient. Conversely, when the kaolin content exceeds 25 mass%, the wet tensile strength becomes insufficient. Other than these, delaminated kaolin, heavy calcium carbonate, light calcium carbonate, light calcium carbonate-silica composite, magnesium carbonate, barium carbonate, titanium dioxide, zinc oxide, silicon oxide, amorphous silica, water You may use together inorganic fillers, such as aluminum oxide, calcium hydroxide, magnesium hydroxide, and zinc hydroxide, and organic fillers, such as urea-formalin resin, a styrene resin, and a phenol resin, in the range which does not inhibit a desired effect.

ところで、壁紙の貼替え時に、壁紙を剥離する際、裏打ち紙の紙間が均一に破壊し、壁面に凹凸を作らないことが重要である。平板状のカオリンを裏打ち紙の填料として使用することにより、少量の添加で裏打ち紙の紙間強度を下げることができ、壁紙を剥離する際、均一に剥離することができる。   By the way, when the wallpaper is replaced, it is important that when the wallpaper is peeled off, the space between the backing papers is uniformly broken and the wall surface is not made uneven. By using a flat kaolin as a filler for the backing paper, the inter-sheet strength of the backing paper can be lowered with a small amount of addition, and the wallpaper can be peeled uniformly.

本発明で使用する歩留り向上剤としては、例えば、ポリアクリルアミド系化合物、ポリエチレングリコール系化合物、ポリビニルアミン系化合物が挙げられ、カチオン性ポリアクリルアミド系化合物が特に好ましい。填料をカオリンとする場合には、全体の歩留りが低下し生産性が低下しやすいため、生産性を維持するために適宜適当な歩留り剤を選択できる。
歩留り向上剤の含有量は0.001〜0.035質量%とする必要があるが、0.005〜0.030質量%が好ましく、0.008〜0.020質量%であることが好ましい。
Examples of the yield improver used in the present invention include polyacrylamide compounds, polyethylene glycol compounds, and polyvinylamine compounds, with cationic polyacrylamide compounds being particularly preferred. When kaolin is used as the filler, the overall yield decreases and the productivity tends to decrease. Therefore, an appropriate retention agent can be appropriately selected in order to maintain the productivity.
The content of the yield improver needs to be 0.001 to 0.035% by mass, preferably 0.005 to 0.030% by mass, and preferably 0.008 to 0.020% by mass.

本発明の壁紙用裏打ち紙に使用する紙基材は、針葉樹材の晒しクラフトパルプ(NBKP)、広葉樹材の晒しクラフトパルプ(LBKP)、砕木パルプ(GP)、サーモメカニカルパルプ(TMP)、ケミサーモメカニカルパルプ(CTMP)、脱墨パルプ(DIP)等を、単独、または適宜混合して調製したスラリーから抄紙したものである。   The paper substrate used for the wallpaper backing paper of the present invention includes softwood bleached kraft pulp (NBKP), hardwood bleached kraft pulp (LBKP), groundwood pulp (GP), thermomechanical pulp (TMP), chemithermo. Paper is made from a slurry prepared by mixing mechanical pulp (CTMP), deinked pulp (DIP), etc., alone or as appropriate.

本発明においては、使用するパルプのJIS P 8121−2012に準じて測定した濾水度(カナダ標準CSF)を400ml〜600mlに調整することが好ましい。パルプの濾水度は、前記した少なくとも1種のパルプを叩解して上記範囲に調整すればよい。2種類以上のパルプを使用する場合には、別々に叩解したパルプを混合して上記範囲にしても、予め混合したパルプを叩解して上記範囲に調整してもよい。パルプの濾水度が400mlより低いと、壁紙を水性の糊を用いて施工する際の伸びが大きくなり、また、乾燥時の収縮も大きくなるので、隣同士に貼った壁紙の目開き(隙間)が大きくなって好ましくない。パルプの濾水度が600mlより高いと紙力が低くなるために、湿潤強度が低下する上、基材に毛羽立ちが発生し易くなるので好ましくない。   In the present invention, it is preferable to adjust the freeness (Canadian standard CSF) measured according to JIS P 8121-2012 of the pulp to be used to 400 to 600 ml. The freeness of the pulp may be adjusted to the above range by beating at least one kind of pulp. When two or more types of pulp are used, the pulps beaten separately may be mixed to make the above range, or the premixed pulp may be beaten and adjusted to the above range. When the freeness of the pulp is lower than 400 ml, the elongation when the wallpaper is constructed with aqueous glue increases, and the shrinkage during drying also increases. ) Is undesirably large. When the freeness of the pulp is higher than 600 ml, the paper strength is lowered, so that the wet strength is lowered and fuzzing is likely to occur on the substrate, which is not preferable.

また、本発明の壁紙用裏打ち紙には、ロジンサイズ剤、湿潤紙力剤以外の内添薬品として、品質に影響のない範囲で、乾燥紙力剤、硫酸バンド、染料、顔料等を使用することができる。   Further, the backing paper for wallpaper of the present invention uses a dry paper strength agent, a sulfuric acid band, a dye, a pigment, etc. as an internal additive other than rosin sizing agent and wet paper strength agent, as long as the quality is not affected. be able to.

本発明の壁紙用裏打ち紙は、公知の抄紙機によって製造することができる。その抄紙条件は特に限定されるものではない。抄紙機としては、長網抄紙機、ツインワイヤー抄紙機、円網抄紙機等の公知のものを適宜使用することができる。   The backing paper for wallpaper of the present invention can be produced by a known paper machine. The paper making conditions are not particularly limited. As the paper machine, a known machine such as a long net paper machine, a twin wire paper machine, or a circular net paper machine can be appropriately used.

所望の壁紙用裏打ち紙を得るためには、基材のJIS P 8113:1998に準じて測定した引張強度の縦方向と横方向の比率(縦横比)を1.0〜2.5にする必要があるが、好ましくは1.3〜2.2、より好ましくは1.5〜2.0である。引張強度の縦横比が2.5を超えるとカールが発生し易く、糊付け後の膨れや皺が発生し易い。逆に引張強度の縦横比が1.0未満とすることは工業的な製造が困難である上に、抄紙時の操業性が低下する。   In order to obtain the desired backing paper for wallpaper, the ratio of the longitudinal direction and the transverse direction (aspect ratio) of the tensile strength measured according to JIS P 8113: 1998 of the substrate is required to be 1.0 to 2.5. However, it is preferably 1.3 to 2.2, more preferably 1.5 to 2.0. When the aspect ratio of the tensile strength exceeds 2.5, curling is likely to occur, and swelling and wrinkles after gluing are likely to occur. Conversely, when the aspect ratio of the tensile strength is less than 1.0, industrial production is difficult and the operability during papermaking decreases.

引張強度の縦横比を1.0〜2.5に制御する方法としては、例えば、抄紙の際のジェット/ワイヤー比を適宜に調整する方法、ヘッドボックスのL/b値を適宜に調整する方法(Lはスライスリップの上リップに対する下リップの突き出し長さ、bはスライス開度のことである。)、ワイヤーシェーキングのシェーキング強度を高くする方法、パルプ原料や叩解条件を適宜選択する方法等が挙げられる。ここで、ジェット/ワイヤー比とは、ヘッドボックスから噴出する原料の速度、すなわちスライスジェットの速度と、ワイヤーの速度との比のことである。一般に、ジェット/ワイヤー比のことを、J/W比と表記することもある。
これらの中でも、ワイヤーのシェーキング強度を20〜80、ジェット/ワイヤー比を0.950〜1.050の条件で抄紙することで、基材の引張強度の縦横比を1.0〜2.5に制御することができ、地合やカールに優れた壁紙用裏打ち紙を得ることができる。
シェーキングに関しては、TAPPI(1966)Vol.49,No.10に長網抄紙機の地合形成とシェーキング強度の関係が開示されており、シェーキング強度とは下記一般式1で定義されるものである。
As a method for controlling the aspect ratio of the tensile strength to 1.0 to 2.5, for example, a method for appropriately adjusting the jet / wire ratio at the time of papermaking, a method for appropriately adjusting the L / b value of the head box (L is the protruding length of the lower lip with respect to the upper lip of the slice lip, and b is the opening degree of the slice.), A method of increasing the shaking strength of wire shaking, a method of appropriately selecting pulp raw materials and beating conditions Etc. Here, the jet / wire ratio is the ratio of the speed of the raw material ejected from the head box, that is, the speed of the slice jet and the speed of the wire. Generally, the jet / wire ratio is sometimes expressed as a J / W ratio.
Among these, the aspect ratio of the tensile strength of the base material is 1.0 to 2.5 by making paper under the conditions of 20 to 80 for the shaking strength of the wire and 0.950 to 1.050 for the jet / wire ratio. Therefore, it is possible to obtain a backing paper for wallpaper having excellent texture and curling.
Regarding shaking, TAPPI (1966) Vol. 49, no. No. 10 discloses the relationship between the formation of the long paper machine and the shaking strength, and the shaking strength is defined by the following general formula 1.

一般式1 I=F×A/S
I:シェーキング強度〔回/分〕
F:振動数〔回/分〕
A:振幅〔インチ〕
S:抄紙機スピード〔フィート/分〕
Formula 1 I = F 2 × A / S
I: Shaking strength [ 2 times / minute]
F: Frequency [times / minute]
A: Amplitude [inch]
S: Paper machine speed [feet / min]

また、本発明の壁紙用裏打ち紙のJIS P 8122に準じて測定されるステキヒト法サイズ度を1〜20秒とする必要があり、1〜15秒であることが好ましく、1〜10秒であることがより好ましい。ステキヒト法サイズ度が1秒未満であると、水中変化率が大きくなり過ぎ、カールも大きくなり過ぎるという問題が発生する。逆にステキヒト法サイズ度が20秒を超えると相剥ぎ性が不十分となる。
壁紙の貼り作業は、施工時に水系の糊を付けてから、糊面を内側にして折り畳み、壁に貼るまで暫く放置し、その後に、壁貼り作業を行うのであるが、この貼り上げ完了までにはかなりの時間を必要とする。放置時における養生時間をオープンタイムと言い、このオープンタイムを越えて放置した場合には、相剥ぎと呼ばれる現象が生じやすい。この相剥ぎは、糊が乾くことにより、折り畳んだ壁紙の裏打紙同士がくっつき、紙層がはがれる現象をいい、壁貼り作業にとって大きな障害となる。
裏打ち紙のステキヒト法サイズ度が低い程、水系の糊が裏打ち紙に浸み込み易く、糊の水分が蒸散し難くなるため、相剥ぎが起こり難くなる。
Moreover, it is necessary to set the Steecht method sizing degree of the backing paper for wallpaper of the present invention according to JIS P 8122 to 1 to 20 seconds, preferably 1 to 15 seconds, and preferably 1 to 10 seconds. It is more preferable. If the Steecht method sizing degree is less than 1 second, there is a problem that the rate of change in water becomes too large and the curl becomes too large. On the other hand, when the Steecht method sizing degree exceeds 20 seconds, the phase peeling property becomes insufficient.
The wallpaper is affixed with water-based glue at the time of construction, folded with the glue side inside, left on the wall for a while, and then the wall is pasted. Need a lot of time. The curing time at the time of leaving is called open time, and when it is left beyond this open time, a phenomenon called phase peeling tends to occur. This delamination refers to a phenomenon in which the backing paper of the folded wallpaper sticks to each other due to drying of the glue, and the paper layer is peeled off.
The lower the sizing of the backing paper, the more easily the water-based glue soaks into the backing paper, and the moisture of the glue is less likely to evaporate.

本発明の壁紙用裏打ち紙の坪量は、50〜120g/mであることが好ましく、60〜100g/mであることがより好ましい。坪量が50g/m未満であると強度が低く、加工時に断紙が発生し易くなるおそれがある。また、坪量が120g/mを超えるとカールが大きくなるおそれがある。 The basis weight of wallpaper backing paper of the present invention is preferably 50 to 120 / m 2, and more preferably 60 to 100 / m 2. If the basis weight is less than 50 g / m 2 , the strength is low, and there is a possibility that paper breakage is likely to occur during processing. On the other hand, if the basis weight exceeds 120 g / m 2 , curling may increase.

上記のようにして製造した本発明の壁紙用裏打ち紙は、再離解させた際のカナダ標準濾水度(CSF)が400〜600mlであることが好ましい。再離解した際のカナダ濾水度が400mlより低いと、壁紙製品に水性の糊を塗工して施工する際に伸びが大きくなる上、乾燥時の収縮が大きくなるので、隣同士に貼った壁紙の目開き(隙間)が大きくなり好ましくない。
一方、再離解した際のカナダ濾水度が600mlより高いと、紙力が低くなるため、基材に毛羽立ちが発生し易くなり好ましくない。なお、壁紙用裏打ち紙が填料を含有する場合には、パルプ単独の濾水度より再離解した際の濾水度は低下するので、使用するパルプ単独のカナダ標準濾水度が400ml〜600mlとなる必要はない。
The backing paper for wallpaper of the present invention produced as described above preferably has a Canadian standard freeness (CSF) of 400 to 600 ml when re-disaggregated. If the Canadian freeness is less than 400ml when re-disaggregated, the wall paper product will be stretched when applied with water-based glue, and the shrinkage during drying will increase. Undesirably, the opening (gap) of the wallpaper becomes large.
On the other hand, if the Canadian freeness is higher than 600 ml at the time of re-disaggregation, the paper strength becomes low, which is not preferable because fluffing tends to occur on the base material. In addition, when the backing paper for wallpaper contains a filler, the freeness when re-disaggregated from the freeness of the pulp alone is lowered, so the Canadian standard freeness of the pulp used alone is 400 ml to 600 ml. There is no need to become.

本発明の壁紙用裏打ち紙の紙層間強度は10〜40N/mの範囲であることが好ましく、12〜30N/mであることがより好ましい。紙層間強度が10N/m未満であると、壁紙用裏打ち紙を壁に貼付後裏打ち紙層から捲れが生じ易くなり好ましくない。40N/mを超えると紙層間強度が強くなり過ぎ、壁に貼付後剥がす際に剥離が重く剥がし難いこと、及び上層の樹脂層が切れ易くなる等、作業効率が低下するので好ましくない。   The paper interlayer strength of the wallpaper backing paper of the present invention is preferably in the range of 10 to 40 N / m, and more preferably 12 to 30 N / m. When the paper interlayer strength is less than 10 N / m, the wallpaper backing paper is affixed to the wall, and then the paper backing layer tends to sag, which is not preferable. If it exceeds 40 N / m, the strength between the paper layers becomes too strong, and it is not preferable because the work efficiency decreases, for example, it is difficult to peel off when it is peeled off after being attached to the wall, and the upper resin layer is easily cut off.

また、本発明の壁紙用裏打ち紙は、カール防止や目開き防止の観点から、水中伸度が2.0%以下であることが好ましく、1.8%以下であることがより好ましく、1.5%以下であることがさらに好ましい。なお、水中伸度はJAPAN TAPPI 紙パルプ試験方法No.27:2000に準拠して測定された値である。   In addition, the backing paper for wallpaper of the present invention preferably has an underwater elongation of 2.0% or less, more preferably 1.8% or less, from the viewpoint of curling prevention and opening prevention. More preferably, it is 5% or less. In addition, the elongation in water is the value of JAPAN TAPPI paper pulp test method No. It is a value measured according to 27: 2000.

本発明の壁紙用裏打ち紙の上層に、化粧層を設けて壁紙とする。壁紙としては、例えば、化粧層としてビニル層を設けたビニル壁紙、オレフィン層を設けたオレフィン壁紙、織物層を設けた織物壁紙、紙層を設けた紙壁紙、無機質層を設けた無機質壁紙等の壁紙製品が挙げられる。何れの場合にも、化粧層となる層を設けた後に、必要に応じて印刷したり発泡処理やエンボス処理を行ったりして、化粧層とする。   A decorative layer is provided on the upper layer of the wallpaper backing paper of the present invention to obtain a wallpaper. As wallpaper, for example, vinyl wallpaper provided with a vinyl layer as a decorative layer, olefin wallpaper provided with an olefin layer, fabric wallpaper provided with a fabric layer, paper wallpaper provided with a paper layer, inorganic wallpaper provided with an inorganic layer, etc. Wallpaper products. In any case, after providing a layer to be a decorative layer, printing or foaming or embossing is performed as necessary to form a decorative layer.

以下に、実施例及び比較例によって本発明を更に詳細に説明するが、本発明はこれらによって限定されるものではない。
実施例及び比較例で作製した壁紙用裏打ち紙について、下記に示した方法によって、壁面から壁紙を剥離する際のピール適性、引張強度、湿潤引張強度、水中伸度、離解性、カール、ステキヒト法サイズ度、相剥ぎ性、填料歩留、地合を評価した。
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto.
About backing paper for wallpaper produced in Examples and Comparative Examples, peelability when peeling wallpaper from wall surface, tensile strength, wet tensile strength, elongation in water, disintegration, curl, steecht method Size, peelability, filler yield, and texture were evaluated.

<ピール適性>
裏打ち紙の片面に50μmのポリエステルラミネートフィルムをラミネートし、流れ方向5cm・幅方向11cmの短冊状サンプルとした。このサンプルの裏打ち紙側に壁紙用糊塗工機を用いて、壁紙用施工糊(ヤヨイ化学工業社製、商品名:「ルーアマイルド」)を塗工量120g/mで塗工する。ローラーを用いて該糊塗工面を石膏ボードに貼合せて、ピール適性評価用サンプルを得た。
上記ピール適性評価用サンプルを23℃、50%RHの条件下で24時間保持した後、ピール適性評価用サンプルを石膏ボードから剥がし、壁面の状態を下記基準にて評価した。
○:裏打ち紙が均一に紙間で剥がれており、壁面に凹凸が見られない。
×:裏打ち紙が不均一に剥がれ(破れ等発生)壁に凹凸が発生
<Peel aptitude>
A 50 μm polyester laminate film was laminated on one side of the backing paper to obtain a strip-shaped sample having a flow direction of 5 cm and a width direction of 11 cm. The wallpaper paste is applied to the backing paper side of this sample at a coating amount of 120 g / m 2 using wallpaper construction paste (manufactured by Yayoi Chemical Industry Co., Ltd., trade name: “Lure Mild”). The paste-coated surface was bonded to a gypsum board using a roller to obtain a peel suitability evaluation sample.
The peel aptitude evaluation sample was held at 23 ° C. and 50% RH for 24 hours, and then the peel aptitude evaluation sample was peeled off from the gypsum board, and the wall condition was evaluated according to the following criteria.
○: The backing paper is uniformly peeled between the papers, and no irregularities are seen on the wall surface.
×: The backing paper is peeled off unevenly (breaking, etc.).

<引張強度>
幅15mm×長さ250mmに断裁したサンプルについて、JIS P 8113:2006に準拠し、つかみ具の間隔を180mmとして壁紙用裏打ち紙の引張強度を測定し、kN/m単位で表示した。なお、引張強度は紙の縦方向および横方向について測定し、縦横比を評価した。
<Tensile strength>
About the sample cut | judged in width 15mm x length 250mm, based on JISP8113: 2006, the tension | tensile_strength of the backing paper for wallpaper was measured by setting the space | interval of a holding tool to 180 mm, and displayed it in kN / m unit. The tensile strength was measured in the longitudinal direction and the transverse direction of the paper, and the aspect ratio was evaluated.

<湿潤引張強度>
サンプルを流れ方向15mm×幅方向250mmに断裁したサンプルを110℃、10分間加熱乾燥後、20℃の水に10分間浸漬した。サンプル表面の余分な水を濾紙でふき取り、JIS P 8113:2006に準拠し、つかみ具の間隔を180mmとして壁紙用裏打ち紙の引張強度を測定し、kN/m単位で表示した。評価は下記基準にて行った。
◎:0.4以上
○:0.35kN/m以上0.4未満
×:0.3kN/m以下
<Wet tensile strength>
The sample cut into 15 mm in the flow direction and 250 mm in the width direction was dried by heating at 110 ° C. for 10 minutes and then immersed in water at 20 ° C. for 10 minutes. Excess water on the surface of the sample was wiped off with filter paper, and the tensile strength of the backing paper for wallpaper was measured according to JIS P 8113: 2006, with the interval between the grips being 180 mm, and displayed in kN / m units. Evaluation was performed according to the following criteria.
A: 0.4 or more B: 0.35 kN / m or more and less than 0.4 X: 0.3 kN / m or less

<水中伸度>
水中寸法安定性の指標として、JAPAN TAPPI 紙パルプ試験方法No.27:2000に準じて水中伸度を測定し、下記基準にて評価した。
◎:1.8%以下
○:1.9%以上2.0%以下
×:2.1%以上
<Underwater elongation>
As an index of dimensional stability in water, JAPAN TAPPI paper pulp test method No. 27: 2000, the underwater elongation was measured and evaluated according to the following criteria.
◎: 1.8% or less ○: 1.9% or more and 2.0% or less ×: 2.1% or more

<離解性>
JIS P 8209:1994 パルプ試験用手すき紙調整方法に示されている標準離解機(JAPAN TAPPI標準離解機使用:3000rpm)を用いて、常温の水道水に約2.5cm角の裏打ち紙をパルプ濃度が3%となる量を加えて、希水酸化ナトリウム水溶液にてpHを8.5に調整し、30℃で30分間離解を行った。評価は下記基準にて目視で判断した。
○:完全に離解する
×:未離解分がある
<Disaggregation>
JIS P 8209: 1994 Using a standard disintegrator shown in the method for adjusting handsheets for pulp testing (using JAPAN TAPPI standard disintegrator: 3000 rpm) Was added in an amount of 3%, pH was adjusted to 8.5 with dilute sodium hydroxide aqueous solution, and disaggregation was performed at 30 ° C. for 30 minutes. Evaluation was visually judged according to the following criteria.
○: Completely disaggregated ×: Undissolved portion

<カール>
裏打ち紙サンプルを流れ方向10cm×幅方向10cmとし、壁紙用裏打ち紙の片面に50μmのポリエステルラミネートフィルムをラミネートし、10cm×10cmのカール評価用サンプルを得た。このカール評価用サンプルを23℃の水に10分間浸漬した後、水から引上げ、カールの状態を目視で下記基準にて評価した。
◎:反りが無い
○:軽微な反りが見られた。
×:大きな反りが見られた。
<Curl>
The backing paper sample was 10 cm in the flow direction and 10 cm in the width direction, and a 50 μm polyester laminate film was laminated on one side of the backing paper for wallpaper to obtain a 10 cm × 10 cm curl evaluation sample. The curl evaluation sample was immersed in water at 23 ° C. for 10 minutes, then pulled up from the water, and the curl state was visually evaluated according to the following criteria.
A: There is no warping. O: A slight warping was observed.
X: A large warp was observed.

<ステキヒト法サイズ度>
JIS P 8122:2004に準じて、裏打ち紙のステキヒト法サイズ度を測定した。
<Stechicht method size>
In accordance with JIS P 8122: 2004, the Steecht method sizing degree of the backing paper was measured.

<相剥ぎ性>
裏打ち紙サンプルを流れ方向5cm×幅方向11cmの短冊とし、裏打ち紙の片面に50μmのポリエステルラミネートフィルムをラミネートし、5cm×11cmのサンプルとした。このサンプルの裏打ち紙側に壁紙用糊塗工機を用いて、壁紙用施工糊(ヤヨイ化学工業社製、商品名:「ルーアマイルド」)を塗工量120g/mで塗工した後、糊面を内側にして折り畳み、室温で放置して所定時間後に約30mm剥がし、紙層の破れの有無を観察した。該紙層の破れが発生しない時間を測定し下記基準にて評価した。
○:3時間以上
×:3時間未満
<Phase peelability>
The backing paper sample was a strip of 5 cm in the flow direction and 11 cm in the width direction, and a polyester laminate film of 50 μm was laminated on one side of the backing paper to obtain a sample of 5 cm × 11 cm. After applying the coating paste for wallpaper (made by Yayoi Chemical Industry Co., Ltd., trade name: “Lure Mild”) to the backing paper side of this sample at a coating amount of 120 g / m 2 , paste Folded with the surface inside, left at room temperature, peeled off about 30 mm after a predetermined time, and observed whether the paper layer was torn or not. The time during which the paper layer was not broken was measured and evaluated according to the following criteria.
○: 3 hours or more ×: less than 3 hours

<填料歩留>
内添薬品及び填料を添加し固形分濃度0.25%に調製したパルプスラリーを角型シートマシン(熊谷理機工業社製)にて均一に分散、搾水してシート化し、シートマシンのワイヤー上に填料歩留まり評価用サンプルを形成した。
該サンプルの灰分を測定し、下記計算式を用い填料歩留を算出した。評価は下記基準にて行った。
計算式:填料歩留(%)=填料歩留まり評価用サンプル中の灰分量/添加した填料量×100
○:70%以上
×:70%未満
<Filling yield>
Pulp slurry prepared by adding internal chemicals and filler to a solid content concentration of 0.25% is uniformly dispersed with a square sheet machine (manufactured by Kumagai Riki Kogyo Co., Ltd.). A filler yield evaluation sample was formed on top.
The ash content of the sample was measured, and the filler yield was calculated using the following formula. Evaluation was performed according to the following criteria.
Calculation formula: Filler yield (%) = Amount of ash in filler yield evaluation sample / Amount of added filler × 100
○: 70% or more ×: less than 70%

<地合>
裏打ち紙サンプルをシャーカステン上に一枚ずつ設置し、下記基準にて目視評価した。
○:均一な地合
×:不均一な地合
<Guide>
Lined paper samples were placed one by one on the Schaukasten and visually evaluated according to the following criteria.
○: Uniform formation ×: Non-uniform formation

<実施例1>
広葉樹晒クラフトパルプ(カナダ標準ろ水度(CSF):450ml)を80質量部、針葉樹晒クラフトパルプ(CSF:500ml)を20質量部配合したパルプスラリー中に、抄紙pHが4.5になるように硫酸バンドを0.5質量%添加した。次に、ロジンサイズ剤(商品名:「サイズパインN775」、固形分濃度50%、荒川化学工業社製)を、対パルプ絶乾重量あたりの固形分換算で0.1質量%添加し、更に、湿潤紙力剤としてポリアミド・エピクロロヒドリン樹脂(商品名:「アラフィックス255」、固形分濃度25%、荒川化学工業社製)を固形分換算で1.0質量%添加した。さらに、歩留向上剤としてカチオン性ポリアクリルアミド(商品名:「キースロックRP401L」、協和産業社製)を0.01質量%および填料としてカオリン(商品名:「UW90」、BASF社製)(体積平均粒子径:2.6μm、アスペクト比:10.0)を対パルプ絶乾質量あたり10%となるように添加し、ジェット/ワイヤー比を0.970に設定して抄紙し、坪量70g/mの本発明の壁紙用裏打ち紙を製造した。
<Example 1>
The papermaking pH is 4.5 in pulp slurry containing 80 parts by mass of hardwood bleached kraft pulp (Canadian standard freeness (CSF): 450 ml) and 20 parts by mass of softwood bleached kraft pulp (CSF: 500 ml). The sulfuric acid band was added to 0.5 mass%. Next, a rosin sizing agent (trade name: “Size Pine N775”, solid content concentration 50%, manufactured by Arakawa Chemical Industries, Ltd.) is added in an amount of 0.1% by mass in terms of solid content per dry pulp weight, and further, Polyamide-epichlorohydrin resin (trade name: “ARAFIX 255”, solid concentration 25%, manufactured by Arakawa Chemical Industries, Ltd.) as a wet paper strength agent was added in an amount of 1.0% by mass in terms of solid content. Furthermore, 0.01% by mass of cationic polyacrylamide (trade name: “Keith Rock RP401L”, manufactured by Kyowa Sangyo Co., Ltd.) as a yield improver and kaolin (trade name: “UW90”, manufactured by BASF Corp.) as a filler (volume) (Average particle diameter: 2.6 μm, aspect ratio: 10.0) was added so as to be 10% per the dry mass of pulp, paper was made with a jet / wire ratio set to 0.970, and a basis weight of 70 g / A m 2 backing paper for wallpaper of the present invention was produced.

<実施例2>
実施例1において、広葉樹晒クラフトパルプ(カナダ標準ろ水度(CSF):550ml)を70質量部、針葉樹晒クラフトパルプ(CSF:750ml)を30質量部配合したパルプを用いた以外は実施例1と同様にして本発明の壁紙用裏打ち紙を製造した。
<Example 2>
In Example 1, Example 1 was used except that 70 parts by mass of hardwood bleached kraft pulp (Canadian standard freeness (CSF): 550 ml) and 30 parts by mass of softwood bleached kraft pulp (CSF: 750 ml) were used. The wallpaper backing paper of the present invention was produced in the same manner as described above.

<実施例3>
実施例1において、広葉樹晒クラフトパルプ(カナダ標準ろ水度(CSF):350ml)を80質量部、針葉樹晒クラフトパルプ(CSF:450ml)を20質量部配合したパルプを用いた以外は実施例1と同様にして本発明の壁紙用裏打ち紙を製造した。
<Example 3>
Example 1 in Example 1 except that 80 parts by mass of hardwood bleached kraft pulp (Canadian standard freeness (CSF): 350 ml) and 20 parts by mass of softwood bleached kraft pulp (CSF: 450 ml) were used. The wallpaper backing paper of the present invention was produced in the same manner as described above.

<実施例4>
実施例1において、広葉樹晒クラフトパルプ(カナダ標準ろ水度(CSF):450ml)を80質量部、針葉樹晒クラフトパルプ(CSF:500ml)を20質量部配合したパルプを用いた以外は実施例1と同様にして抄紙し、坪量110g/mの本発明の壁紙用裏打ち紙を製造した。
<Example 4>
In Example 1, Example 1 except that 80 parts by mass of hardwood bleached kraft pulp (Canadian standard freeness (CSF): 450 ml) and 20 parts by mass of softwood bleached kraft pulp (CSF: 500 ml) were used. The paper was made in the same manner as above to produce a wallpaper backing paper of the present invention having a basis weight of 110 g / m 2 .

<実施例5>
実施例1において、広葉樹晒クラフトパルプ(カナダ標準ろ水度(CSF):450ml)を80質量部、針葉樹晒クラフトパルプ(CSF:500ml)を20質量部配合したパルプを用いた以外は実施例1と同様にして抄紙し、坪量50g/mの本発明の壁紙用裏打ち紙を製造した。
<Example 5>
In Example 1, Example 1 except that 80 parts by mass of hardwood bleached kraft pulp (Canadian standard freeness (CSF): 450 ml) and 20 parts by mass of softwood bleached kraft pulp (CSF: 500 ml) were used. The paper was made in the same manner as above to produce a backing paper for wallpaper of the present invention having a basis weight of 50 g / m 2 .

<比較例1>
実施例1において、湿潤紙力剤を4質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 1>
In Example 1, paper making was performed in the same manner as in Example 1 except that the wet paper strength agent was changed to 4% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例2>
実施例1において、湿潤紙力剤を0.3質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 2>
In Example 1, paper making was performed in the same manner as in Example 1 except that the wet paper strength agent was changed to 0.3% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例3>
実施例1において、ロジンサイズ剤を0.5質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 3>
In Example 1, paper was made in the same manner as in Example 1 except that the rosin sizing agent was changed to 0.5% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例4>
実施例1において、ロジンサイズ剤を0.01質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 4>
In Example 1, paper was made in the same manner as in Example 1 except that the rosin sizing agent was changed to 0.01% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例5>
実施例1において、カオリンを4質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 5>
In Example 1, paper was made in the same manner as in Example 1 except that kaolin was changed to 4% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例6>
実施例1において、カオリンを26質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 6>
In Example 1, paper was made in the same manner as in Example 1 except that kaolin was changed to 26% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例7>
実施例1において、歩留向上剤を0.05質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 7>
In Example 1, paper was made in the same manner as in Example 1 except that the yield improver was changed to 0.05% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例8>
実施例1において、歩留向上剤を0.0005質量%とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 8>
In Example 1, paper was made in the same manner as in Example 1 except that the yield improver was changed to 0.0005% by mass to produce a backing paper for wallpaper having a basis weight of 70 g / m 2 .

<比較例9>
実施例1において、ジェット/ワイヤー比を0.920とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 9>
In Example 1, paper making was performed in the same manner as in Example 1 except that the jet / wire ratio was 0.920, and a backing paper for wallpaper having a basis weight of 70 g / m 2 was produced.

<比較例10>
実施例1において、ジェット/ワイヤー比を1.025とした以外は実施例1と同様にして抄紙し、坪量70g/mの壁紙用裏打ち紙を製造した。
<Comparative Example 10>
In Example 1, paper was made in the same manner as in Example 1 except that the jet / wire ratio was 1.025, and a wallpaper backing paper having a basis weight of 70 g / m 2 was produced.

Figure 2015124448
Figure 2015124448

Figure 2015124448
Figure 2015124448

表1、表2から明らかなように、紙基材に填料としてのカオリン、湿潤紙力剤、及びロジンサイズ剤を特定量含有させ、引張強度の縦横比、ステキヒト法サイズ度を制御した本発明の壁紙用裏打ち紙は、ピール適性、湿潤引張強度、水中寸法安定性、カール、相剥ぎ性を改善することのできることが実証された。 As is clear from Tables 1 and 2, the present invention includes a specific amount of kaolin, a wet paper strength agent, and a rosin sizing agent as fillers in the paper base material, and the aspect ratio of the tensile strength and the Steecht method sizing degree are controlled. It has been demonstrated that the paper backing paper can improve peelability, wet tensile strength, underwater dimensional stability, curl and peelability.

本発明の壁紙用裏打ち紙は、高価な材料を使用しないにもかかわらず、壁面から壁紙を剥離する際のピール適性、裏打ち紙の湿潤引張強度、水中寸法変化率、カール、相剥ぎ性に優れた裏打ち紙であり、産業上極めて有用である。 The backing paper for wallpaper of the present invention is excellent in peelability when peeling the wallpaper from the wall surface, wet tensile strength of the backing paper, dimensional change rate in water, curl, and phase peelability even though expensive materials are not used. This paper is very useful industrially.

Claims (4)

パルプを含有する紙基材からなる裏打ち紙において、前記パルプに湿潤紙力剤を0.5質量%〜3.0質量%、ロジンサイズ剤を0.05質量%〜0.3質量%、カオリンを5質量%〜25質量%、歩留向上剤を0.001質量%〜0.035質量%含有させて抄紙し、JIS P 8113:2006に準じて測定した引張強度の縦横比が1.0〜2.5、JIS P 8122:2004に準じて測定したステキヒト・サイズ度が1〜20秒であることを特徴とする壁紙用裏打ち紙。 A backing paper comprising a paper base material containing pulp, wherein the pulp has a wet paper strength agent of 0.5 mass% to 3.0 mass%, a rosin sizing agent of 0.05 mass% to 0.3 mass%, kaolin 5% by mass to 25% by mass and a yield improver 0.001% by mass to 0.035% by mass, and a tensile strength aspect ratio measured according to JIS P 8113: 2006 is 1.0. Backing paper for wallpaper, characterized in that the Steecht sizing degree measured according to JIS P 8122: 2004 is 1 to 20 seconds. 前記パルプのJIS P 8121−2012に準じて測定したカナダ標準濾水度(CSF)が400ml〜600mlであることを特徴とする請求項1に記載の壁紙用裏打ち紙。 The backing paper for wallpaper according to claim 1, wherein the Canadian standard freeness (CSF) measured according to JIS P 8121-2012 of the pulp is 400 ml to 600 ml. 前記紙基材のJAPAN TAPPI 紙パルプ試験方法No.27:2000に準じて測定した水中伸度が2.0%以下であることを特徴とする請求項1または請求項2に記載の壁紙用裏打ち紙。 JAPAN TAPPI paper pulp test method no. 27. The backing paper for wallpaper according to claim 1 or 2, wherein the underwater elongation measured according to 27: 2000 is 2.0% or less. 前記紙基材の坪量が60〜100g/mであることを特徴とする請求項1〜3のいずれか1項に記載の壁紙用裏打ち紙。 Wallpaper backing paper according to claim 1, wherein the basis weight of the paper substrate is 60 to 100 / m 2.
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JP2004043983A (en) * 2002-07-09 2004-02-12 Kanto Leather Co Ltd Wall covering material
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JP2005029920A (en) * 2003-07-11 2005-02-03 Kohjin Co Ltd Decorative sheet
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JP2005139571A (en) * 2003-11-05 2005-06-02 Kanto Leather Co Ltd Wall covering material and method for producing the same
JP2006097186A (en) * 2004-09-29 2006-04-13 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2008019539A (en) * 2006-07-14 2008-01-31 Chuetsu Pulp Kogyo Kk Backing paper for wallpaper, method for producing the same and the wallpaper
JP2009242982A (en) * 2008-03-31 2009-10-22 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2010196216A (en) * 2009-02-27 2010-09-09 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2011117118A (en) * 2009-03-30 2011-06-16 Nippon Paper Industries Co Ltd Method of manufacturing paper

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0673700A (en) * 1992-07-27 1994-03-15 Nippon Paper Ind Co Ltd Production of flame-retardant paper for wall paper to be readily repapered
JP2001288699A (en) * 2000-03-31 2001-10-19 Oji Paper Co Ltd Information-recording paper
JP2004043983A (en) * 2002-07-09 2004-02-12 Kanto Leather Co Ltd Wall covering material
JP2004195907A (en) * 2002-12-20 2004-07-15 Daio Paper Corp Ink jet recording paper sheet
JP2005029920A (en) * 2003-07-11 2005-02-03 Kohjin Co Ltd Decorative sheet
JP2005082894A (en) * 2003-09-04 2005-03-31 Nippon Paper Industries Co Ltd Wallpaper
JP2005139571A (en) * 2003-11-05 2005-06-02 Kanto Leather Co Ltd Wall covering material and method for producing the same
JP2006097186A (en) * 2004-09-29 2006-04-13 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2008019539A (en) * 2006-07-14 2008-01-31 Chuetsu Pulp Kogyo Kk Backing paper for wallpaper, method for producing the same and the wallpaper
JP2009242982A (en) * 2008-03-31 2009-10-22 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2010196216A (en) * 2009-02-27 2010-09-09 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2011117118A (en) * 2009-03-30 2011-06-16 Nippon Paper Industries Co Ltd Method of manufacturing paper

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