JP2015078312A - Rubber composition for tire and run flat tire - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a rubber composition for tire having more improved low heat generation property and shape stability, and longer running distance during run flat running.SOLUTION: There is provided a rubber composition containing 100 pts.mass of diene rubber polymerized by a neodymium-based catalyst of 10 to 90 pts.mass of butadiene rubber and 1 to 30 pts.mass of a sulfur compound selected from compounds of the formula (1) and (2), where Ris an alkylene group, Ris a hydrogen atom, an alkyl group, an alkenyl group, A is a hetero atom, Ris an alkyl group, an alkenyl group and x is 1 to 4.

Description

  TECHNICAL FIELD The present invention relates to a rubber composition for tires and a run flat tire using a side pad obtained from the rubber composition.

  The run-flat tire is a pneumatic tire that can travel a certain distance even when the air pressure inside the tire is reduced due to a failure such as puncture and the air pressure becomes zero. As one of tire structures for enabling such run-flat running, a tire structure in which an inner surface of a sidewall portion is reinforced by a reinforcing rubber layer called a side pad is known.

  The side pad is required to have low heat buildup and high shape stability in order to improve durability during run flat running.

  In order to improve the exothermic property of rubber, it is generally only necessary to reduce the amount of filler. In this case, however, the reinforcing property is lowered and it is not suitable for a side pad of a run flat tire. To solve this problem, for example, Patent Document 1 proposes that two or more vulcanization accelerators are used and at least one of them is a sulfenamide accelerator. However, the exothermic reduction effect is not sufficient, and the shape stability is not improved.

  Patent Document 2 discloses a sulfur compound such as 2,2′-bis (benzimidazolyl-2) ethyl disulfide as a coupling agent for rubber and carbon black, which has a certain heat generation reducing effect. However, shape stability is not sufficient as a run-flat pad rubber.

JP 2002-155169 A JP 2013-23610 A

  The present invention has been made in view of the above, and a rubber composition for a tire from which a run-flat tire with improved low heat buildup and shape stability is obtained, and a run-flat running time using the composition. An object is to provide a run flat tire having a longer mileage.

In order to solve the above-mentioned problems, the rubber composition for tires of the present invention has the following general formula (100 parts by mass) based on 100 parts by mass of a diene rubber containing 10 to 90 parts by mass of a butadiene rubber polymerized using a neodymium catalyst. 1 to 30 parts by mass of a sulfur compound selected from the group consisting of the compound represented by 1) and the compound represented by the following general formula (2).

However, equation (1) and in formula (2), R ¹ represents an alkylene group having 1 to 6 carbon atoms, R ² is a hydrogen atom, a linear or branched alkyl or alkenyl having 1 to 6 carbon atoms A cyclic alkyl group or alkenyl group having 3 to 6 carbon atoms, A represents NH, NR ³ , O or S, and R ³ represents a linear or branched alkyl group having 1 to 6 carbon atoms. Alternatively, it represents an alkenyl group, or a cyclic alkyl group or alkenyl group having 3 to 6 carbon atoms. In formula (2), x shows the integer of 1-4.

  The rubber composition of the present invention preferably contains 30 to 80 parts by mass of carbon black and 1 to 15 parts by mass of sulfur with respect to 100 parts by mass of the diene rubber.

  The rubber composition of the present invention may contain 10 to 90 parts by mass of the modified butadiene rubber in a total amount of 100 parts by mass of the diene rubber with the butadiene rubber polymerized using the neodymium catalyst.

  The run flat tire of this invention shall have the side pad formed with the rubber composition of the said invention inside the carcass of a sidewall part.

  According to the rubber composition of the present invention, as described above, the compound represented by the formula (1) or the formula (2) is used in combination with a butadiene rubber polymerized using a neodymium catalyst at a predetermined ratio. A side pad for a run-flat tire can be obtained which exhibits remarkable exothermic properties and reduced compression set as an index of shape stability. Since the side pad occupies a large cross-sectional area in the sidewall portion, it is possible to greatly extend the travel distance during run-flat travel by using the side pad.

It is a half sectional view of a run flat tire concerning an embodiment.

  2 ... side wall part, 5 ... carcass, 9 ... side pad, 10 ... run flat tire

  Hereinafter, embodiments of the present invention will be described in detail.

  The diene rubber used in the present invention contains a butadiene rubber polymerized using a neodymium catalyst. According to the rubber composition of the present invention, low heat build-up and reduced compression set can be achieved by using a sulfur compound represented by formula (1) or formula (2) together with butadiene rubber polymerized using a neodymium catalyst. Can be obtained. This is considered to be due to the remarkable improvement in the dispersibility of carbon black and sulfur.

  10-90 mass parts is preferable in 100 mass parts of diene rubbers, and, as for the compounding quantity of the butadiene rubber polymerized using the neodymium catalyst, 50-80 mass parts is more preferable. By containing butadiene rubber polymerized using a neodymium catalyst within this range, the effect of reducing compression set is excellent.

Here, the neodymium catalyst may be any of neodymium alone, a compound of neodymium and other metals, or an organic compound containing neodymium, and specific examples include NdCl ₃ , Et-NdCl _{2 and the} like. Butadiene rubber polymerized using a neodymium-based catalyst has a microstructure with a high cis content and a low vinyl content, so it was synthesized with another catalyst such as a cobalt-based catalyst by blending it with the rubber composition. It is thought that low heat generation performance that cannot be obtained with butadiene rubber can be obtained. The microstructure of butadiene rubber polymerized using a neodymium catalyst has a cis-1,4 bond content of 96% or more and a vinyl group (1,2-vinyl bond) content of 1.0% or less. Is preferred. Here, the cis-1,4 bond content and the vinyl group content are values calculated by the integration ratio of the ¹ H-NMR spectrum.

  Examples of diene rubbers other than butadiene rubber polymerized using the neodymium catalyst include natural rubber (NR), isoprene rubber (IR), butadiene rubber (BR), styrene-butadiene rubber (SBR), and styrene-isoprene. Examples thereof include rubber, butadiene-isoprene rubber, styrene-butadiene-isoprene rubber, and butyl rubber (IIR). These can be used alone or in combination of two or more. More preferably, it is NR, SBR, BR, or a blend rubber of two or more thereof.

  As the diene rubber, a modified diene rubber having a functional group at the molecular end or molecular chain can also be used. The functional group includes a hetero atom such as an oxygen atom, a nitrogen atom, a sulfur atom, a tin atom, or a halogen atom. For example, a hydroxyl group, an amino group, a carboxyl group, an alkoxy group, an alkoxysilyl group, an epoxy group, a thiol group , Tin-containing groups, halogens and the like. Each of these may be introduced alone or in combination of two or more. These functional groups interact with silanol groups (Si-OH) on the silica surface, that is, have reactivity such as reactivity or hydrogen bonding that can chemically bond with silanol groups. is there. Therefore, the dispersibility of silica can be improved and it can contribute to the improvement of fuel-efficient performance.

  Here, the amino group may be not only a primary amino group but also a secondary or tertiary amino group. Examples of the alkoxy group (-OR, where R is an alkyl group) include a methoxy group, an ethoxy group, a propoxy group, and a butoxy group. The alkoxysilyl group refers to a group in which at least one of the three hydrogens of the silyl group is substituted with an alkoxy group, and includes a trialkoxysilyl group, an alkyldialkoxysilyl group, and a dialkylalkoxysilyl group. Furthermore, examples of the halogen include fluorine, chlorine, bromine and iodine, with chlorine and bromine being preferred. Tin-containing groups can be introduced by modifying with a tin compound. Examples of tin compounds include tin tetrachloride, methyltin trichloride, dibutyldichlorotin, tributylchlorotin and other halogenated tin compounds, tetraallyl Examples include tin, diethyldiallyltin, and allyltin compounds such as tetra (2-octenyl) tin, tetraphenyltin, and tetrabenzyltin.

  Modified diene rubbers having such a functional group are known per se, and the production method thereof is not limited. For example, the functional group may be introduced by modifying a solution-polymerized styrene butadiene rubber or butadiene rubber synthesized by anionic polymerization with a modifier, or alternatively, the monomer having the functional group may be used as a base polymer. It may be introduced into the molecular chain of the rubber polymer by copolymerizing with butadiene or styrene, which are monomers constituting the.

  As the modified diene rubber, modified NR and modified SBR can be used, but modified butadiene rubber is preferred. When the modified butadiene rubber is used, its blending amount is not particularly limited, but it can be used in a total amount of 90 parts by mass or less, preferably 10 to 90 parts by mass with the butadiene rubber polymerized using a neodymium catalyst. Yes, more preferably 50 to 80 parts by mass.

The said sulfur compound used by this embodiment is at least 1 sort (s) of the compound represented by the following general formula (1) or (2). The compound represented by the formula (1) is a thiol compound in which an aromatic condensed heterocycle is bonded to a mercapto group via an alkylene group, and the compound represented by the formula (2) is present at both ends of the sulfide group. It is a sulfur compound having a structure (bis structure) in which an aromatic condensed heterocyclic ring is bonded via an alkylene group.

In these formulas (1) and (2), R ¹ represents an alkylene group having 1 to 6 carbon atoms (that is, an alkanediyl group), and may be linear or branched. Specific examples of R ¹ include a methylene group, an ethylene group, a propylene group, a trimethylene group, a tetramethylene group, a pentamethylene group, and a hexamethylene group. Preferably, R ¹ is a linear alkylene group represented by — (CH ₂ ) _n —, where n is an integer of 1 to 6 (preferably an integer of n = 1 to 3).

R ² in the formulas (1) and (2) is a hydrogen atom, a linear or branched alkyl group or alkenyl group having 1 to 6 carbon atoms, or a cyclic alkyl group or alkenyl group having 3 to 6 carbon atoms. Indicates. Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, and an n-hexyl group. Are those having 1 to 4 carbon atoms. As an alkenyl group, a vinyl group, an allyl group, etc. are mentioned, for example, Preferably it is a C1-C4 thing. Examples of the cyclic alkyl group or alkenyl group include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and the like, and an alkyl group bonded to a ring carbon atom such as a 2-methylcyclopropyl group. It may have a substituent, and further may be a group formed by removing a hydrogen atom from a side chain, such as a cyclopropylmethyl group.

A in the formulas (1) and (2) represents NH, NR ³ , O or S. In the case of NH or NR ³ , the heterocyclic ring is a benzimidazolyl group, and in the case of O, the heterocyclic ring is a benzoxazolyl. In the case of S, the heterocyclic ring is a benzthiazolyl group. Among these, NH is particularly preferable from the viewpoint of physical bonding to the silanol group on the silica surface. R ³ represents a linear or branched alkyl group or alkenyl group having 1 to 6 carbon atoms, or a cyclic alkyl group or alkenyl group having 3 to 6 carbon atoms. Specific examples and preferred carbon numbers thereof are those described above for R Same as ² .

  X in Formula (2) is an integer of 1-4, More preferably, it is an integer of 2-4.

  Specific examples of the sulfur compound represented by the formula (1) include 2- (benzimidazolyl-2) ethane-1-thiol, 2- (5-methyl-benzimidazolyl-2) ethane-1-thiol, 2- (Benzimidazolyl-2) propane-1-thiol, 2- (5-methyl-benzimidazolyl-2) propane-1-thiol, 3- (benzimidazolyl-2) propane-1-thiol, 4- (benzimidazolyl- 2) Butane-1-thiol, 5- (benzimidazolyl-2) pentane-1-thiol, 6- (benzimidazolyl-2) hexane-1-thiol, 2- (benzoxazolyl-2) ethane-1- Thiol, 2- (Benzoxazolyl-2) propane-1-thiol, 3- (Benzoxazolyl-2) propane-1-thiol, 4- (Benzene Oxazolyl-2) butane-1-thiol, 5- (benzoxazolyl-2) pentane-1-thiol, 6- (benzoxazolyl-2) hexane-1-thiol, 2- (benzthiazolyl-2) ethane -1-thiol, 2- (benzthiazolyl-2) propane-1-thiol, 3- (benzthiazolyl-2) propane-1-thiol, 4- (benzthiazolyl-2) butane-1-thiol, 5- (benzthiazolyl-2) ) Pentane-1-thiol, 6- (benzthiazolyl-2) hexane-1-thiol, and the like, and these may be used alone or in combination of two or more.

  Specific examples of the sulfur compound represented by the formula (2) include bis (benzimidazolyl-2) methyl sulfide, 2,2′-bis (benzimidazolyl-2) ethyl sulfide, and 2,2′-bis (benzimidazolyl). -2) Ethyl disulfide, 2,2'-bis (benzimidazolyl-2) ethyl trisulfide, 2,2'-bis (benzimidazolyl-2) ethyl tetrasulfide, 3,3'-bis (benzimidazolyl-2) Propyl disulfide, 4,4′-bis (benzimidazolyl-2) butyl disulfide, 5,5′-bis (benzimidazolyl-2) pentyl disulfide, 6,6′-bis (benzimidazolyl-2) hexyl disulfide, 2, 2′-bis (1-methylbenzimidazolyl-2) ethyl disulfide, 2,2′-bi (Benzoxazolyl-2) ethyl disulfide, 2,2′-bis (benzoxazolyl-2) ethyl tetrasulfide, 2,2′-bis (4-methylbenzoxazolyl-2) ethyl disulfide, 2 , 2′-bis (benzthiazolyl-2) ethyl disulfide, 2,2′-bis (benzthiazolyl-2) ethyl tetrasulfide, and the like, which can be used alone or in combination of two or more.

  The sulfur compound represented by the formula (1) is, for example, a 1,2-diaminobenzene compound, a 2-aminothiophenol compound, or a 2-aminophenol compound, and a mercaptocarboxylic acid compound. It can be synthesized by reacting in 4N hydrochloric acid. The sulfur compound represented by the formula (2) is, for example, a 1,2-diaminobenzene compound, a 2-aminothiophenol compound, or a 2-aminophenol compound, and a thiodicarboxylic acid compound. It can be synthesized by reacting in 4N hydrochloric acid.

  Examples of the 1,2-diaminobenzene compounds include 1,2-diaminobenzene, 2,3-tolylenediamine, 1,2-diamino-3-ethylbenzene, 1,2-diamino-3-n-propylbenzene. 1,2-diamino-3-isopropylbenzene, 1,2-diamino-3-n-butylbenzene and the like. Examples of the 2-aminothiophenol compound include 2-aminothiophenol, 2-amino-3-methylthiophenol, 2-amino-3-ethylthiophenol, 2-amino-3-n-propylthiophenol, 2 -Amino-4-methylthiophenol, 2-amino-4-ethylthiophenol, 2-amino-4-n-propylthiophenol, 2-amino-5-methylthiophenol, 2-amino-5-ethylthiophenol, 2 -Amino-5-n-propylthiophenol, 2-amino-6-methylthiophenol, 2-amino-6-ethylthiophenol, 2-amino-6-n-propylthiophenol and the like. Examples of 2-aminophenol compounds include 2-aminophenol, 2-amino-3-methylphenol, 2-amino-3-ethylphenol, 2-amino-3-n-propylphenol, and 2-amino-4. -Methylphenol, 2-amino-4-ethylphenol, 2-amino-4-n-propylphenol, 2-amino-5-methylphenol, 2-amino-5-ethylphenol, 2-amino-5-n- Examples include propylphenol, 2-amino-6-methylphenol, 2-amino-6-ethylphenol, and 2-amino-6-n-propylphenol. Examples of mercaptocarboxylic acid compounds include thioglycolic acid, mercaptopropionic acid, mercaptobutanoic acid, mercaptopentanoic acid, mercaptohexanoic acid, and the like. Examples of the thiodicarboxylic acid compound include thiodiglycolic acid, dithiodiglycolic acid, tetrathiodiglycolic acid, thiodipropionic acid, dithiodipropionic acid, trithiodipropionic acid, tetrathiodipropionic acid, dithiodibutyric acid. Tetrathiodibutyric acid, dithiodipentylic acid, tetrathiodipentylic acid, dithiodihexylic acid, tetrathiodihexylic acid and the like.

  The compounding amount of the sulfur compound is preferably in the range of 1 to 30 parts by mass and more preferably in the range of 5 to 15 parts by mass with respect to 100 parts by mass of the diene rubber. By setting it as this range, the compression set of the obtained tire can be greatly reduced.

  In the rubber composition according to the present invention, silica and / or carbon black is usually blended as a filler. Although the compounding quantity of a filler is not specifically limited, It is preferable that it is 30-100 mass parts with respect to 100 mass parts of said diene rubbers. When the rubber composition is used for a side pad of a run flat tire, the filler is preferably composed mainly of carbon black, that is, carbon black alone or a blend of carbon black and silica.

As carbon black, various carbon blacks used as a reinforcing filler for rubber can be used, and are not particularly limited. For example, carbon black having colloidal characteristics with a nitrogen adsorption specific surface area (N ₂ SA, measured according to JIS K6217-2) of 20 to 150 m ² / g is preferably used. When the rubber composition is used for a side pad of a run flat tire, it is preferable to use carbon black having a nitrogen adsorption specific surface area of 20 to 100 m ² / g, that is, GPF, FEF, HAF grade.

  Examples of the silica include wet silica, dry silica, colloidal silica, precipitated silica and the like, and it is particularly preferable to use wet silica containing hydrous silicic acid as a main component.

  When silica is blended, it is preferable to blend a silane coupling agent. The silane coupling agent is, for example, an organic silane compound having an organic part capable of reacting with a polymer such as sulfide, amino group, mercapto group, vinyl group, methacryl group or epoxy group, and a halogen or alkoxy group. Various silane coupling agents can be used. Preferably, a sulfide silane represented by the following general formula (i) or a protected mercaptosilane represented by the following general formula (ii) is used.

_{(C 2 H 5 O) 3} Si-C y H 2y -S x -C y H 2y -Si (OC 2 H 5) 3 ... (i)
_{(C n H 2n + 1 O} ) 3 Si-C m H 2m -S-CO-C k H 2k + 1 ... (ii)

  In said formula (i), y is an integer of 1-9, Preferably it is 2-5, x is 1-4, Preferably it is 2-4. Specifically, x has a normal distribution, that is, it is generally marketed as a mixture of different numbers of sulfur chain bonds, and x represents an average value thereof. Specific examples of preferred sulfide silanes represented by formula (i) include bis (3-triethoxysilylpropyl) tetrasulfide, bis (3-triethoxysilylpropyl) disulfide, and bis (2-triethoxysilylethyl) tetra. And sulfides.

  In said formula (ii), n is an integer of 1-3, m is an integer of 1-5, k is an integer of 5-9. Examples of the protected mercaptosilane represented by the formula (ii) include 3-octanoylthio-1-propyltriethoxysilane in which n = 2, m = 3, and k = 7, and n = 1, m = 3, k. Preferred examples include 3-propionylthiopropyltrimethoxysilane where = 2.

  The amount of the silane coupling agent is preferably 2 to 25 parts by mass, more preferably 5 to 15 parts by mass with respect to 100 parts by mass of silica.

  In addition to the components described above, the rubber composition according to the present invention is generally used in tire rubber compositions such as softeners, plasticizers, anti-aging agents, zinc white, stearic acid, vulcanizing agents, and vulcanization accelerators. Various additives used can be blended. The rubber composition can be produced by kneading the above essential components and appropriately added additive components using a commonly used mixer such as a Banbury mixer or a kneader.

  A side pad of a run flat tire can be obtained by vulcanizing and molding the rubber composition at, for example, 140 to 200 ° C. according to a conventional method.

  Next, an embodiment of the run flat tire of the present invention will be described with reference to the drawings. FIG. 1 is a half sectional view showing a run flat tire (10) according to an embodiment. The tire (10) includes a pair of left and right bead portions (1) to be rim-assembled, a pair of left and right sidewall portions (2) extending outward in the tire radial direction from the bead portion (1), and the pair of sidewall portions. (2) It is comprised from the tread part (3) earth | grounded on the road surface provided in between.

  A ring-shaped bead core (4) is embedded in the pair of bead portions (1). A carcass (5) made of a carcass ply using an organic fiber cord is folded around the bead core (4) and locked, and is provided so as to span between the left and right bead portions (1). Further, on the outer peripheral side of the tread portion (3) of the carcass (5), a belt (6) composed of two cross belt plies using a rigid tire cord such as a steel cord or an aramid fiber is provided.

  In the sidewall portion (2), a sidewall rubber (7) that forms the sidewall outer surface is provided on the tire outer surface side of the carcass (5). A rim strip (8) made of a rubber layer is provided so as to cover a contact area with the rim flange in the bead portion (1), and a sidewall rubber (7) is formed on the upper end of the rim strip (8). The lower end of the is overlapping.

  In the side wall portion (2), a side pad (9) is provided on the inner surface side of the carcass (5) over the region from the vicinity of the rim line (RL) in contact with the upper end of the rim flange to the end portion of the belt (6). It has been. The side pad (9) has a substantially crescent shape in a cross section in the tire width direction including the tire shaft in order to reinforce the sidewall portion (2).

  This side pad (9) is formed of a rubber composition containing a sulfur compound represented by the above formula (1) or formula (2) and a butadiene rubber polymerized using a neodymium catalyst. Since the side pad (9) occupies a large cross-sectional area in the side wall portion (2), the excellent low heat build-up of the rubber composition makes it possible to obtain a large effect that contributes to a reduction in rolling resistance during normal internal pressure running. become. Furthermore, it is possible to improve the durability by suppressing the heat generation of the side pad (9) while ensuring the shape stability during the run-flat running.

  In the above embodiment, an example in which the carcass is formed of one layer is shown. However, the side pad rubber may be divided into a plurality of layers, and a reinforcing fiber layer may be disposed therebetween. When the carcass is composed of two or more layers, a reinforcing pad rubber having a substantially crescent-shaped cross section may be disposed between the inner surface side of the carcass layer and the carcass layer.

  Examples of the present invention will be described below, but the present invention is not limited to these examples. The blending ratios shown below are based on mass (“parts by mass”, “mass%”, etc.) unless otherwise specified.

  Using a Banbury mixer, according to the formulation (parts by mass) shown in Table 1 below, first, in the non-pro mixing step, components other than sulfur and vulcanization accelerator are added and mixed (discharge temperature = 160 ° C.), and then obtained. A rubber composition for tire treads was prepared by adding and mixing sulfur and a vulcanization accelerator (discharge temperature = 90 ° C.) in the professional mixing step. The details of each component in Table 1 are as follows.

[raw materials]
・ NR: RSS No. 3 ・ BR01: “Hi-Sis BR” manufactured by JSR Corporation
・ Neodymium catalyst BR: “BR730” manufactured by JSR Corporation
・ Modified BR: “BR1250H” (tertiary amine modified) manufactured by Nippon Zeon Co., Ltd.
・ Carbon black N550: “Dia Black E” manufactured by Mitsubishi Chemical Corporation
Sulfur compound A: 2,2′-bis (benzimidazolyl-2) ethyl disulfide (synthesized according to Reference Example 1 in paragraph 0033 in JP2013-23610)
・ Stearic acid: “Lunac S-20” manufactured by Kao Corporation
・ Zinc flower: "Zinc flower No. 1" manufactured by Mitsui Mining & Smelting Co., Ltd.
Anti-aging agent: “Antigen 6C” manufactured by Sumitomo Chemical Co., Ltd.
・ Vulcanization accelerator: “Noxeller NS-P” manufactured by Ouchi Shinsei Chemical Co., Ltd.
・ Sulfur: “Muclon OT-20” manufactured by Shikoku Kasei Co., Ltd.

  About each obtained rubber composition, it vulcanized | cured at 150 degreeC x 30 minutes, the test piece was produced, and low heat-generating performance and shape stability (compression set) were measured and evaluated. The results are shown in Table 1. Each evaluation method is as follows.

Low heat generation performance: According to JIS K6394, the loss factor tan δ was measured under the conditions of a temperature of 70 ° C., a frequency of 10 Hz, a static strain of 10%, and a dynamic strain of 2%, and displayed as an index with the value of Comparative Example 1 being 100. . The smaller the index is, the smaller the tan δ is, and the lower the heat generation performance is, and the better the fuel efficiency is due to the reduction in rolling resistance.

Compression set: Measured after heat treatment at 100 ° C. for 70 hours in accordance with JIS K6301, and indicated as an index with the value of Comparative Example 1 being 100. A smaller index means a smaller compression set and better shape stability.

  From the results shown in Table 1, in each Example in which the sulfur compound represented by the formula (1) or (2) and a butadiene rubber polymerized using a neodymium-based catalyst are used in a predetermined ratio, low exothermic property is obtained. It can be seen that both the shape stability is remarkably excellent.

Claims (4)

The compound represented by the following general formula (1) and the compound represented by the following general formula (2) with respect to 100 parts by mass of the diene rubber containing 10 to 90 parts by mass of butadiene rubber polymerized using a neodymium catalyst. The rubber composition for tires containing 1-30 mass parts of sulfur compounds which are at least 1 sort (s) selected from the group which consists of these.

In Formula (1) and Formula (2), R ¹ represents an alkylene group having 1 to 6 carbon atoms, R ² represents a hydrogen atom, a linear or branched alkyl group or alkenyl group having 1 to 6 carbon atoms, Or a cyclic alkyl group or alkenyl group having 3 to 6 carbon atoms, A represents NH, NR ³ , O or S, and R ³ represents a linear or branched alkyl group or alkenyl group having 1 to 6 carbon atoms. A cyclic alkyl group or an alkenyl group having 3 to 6 carbon atoms. In formula (2), x shows the integer of 1-4.   The tire rubber composition according to claim 1, comprising 30 to 80 parts by mass of carbon black and 1 to 15 parts by mass of sulfur with respect to 100 parts by mass of the diene rubber.   The modified butadiene rubber comprises 10 to 90 parts by mass in 100 parts by mass of a diene rubber in a total amount with a butadiene rubber polymerized using the neodymium-based catalyst. Rubber composition.   The run flat tire which has a side pad formed with the rubber composition of any one of Claims 1-3 inside the carcass of a side wall part.

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