JP2015045076A - Aluminum alloy sheet for beverage can body excellent in surface property - Google Patents

Aluminum alloy sheet for beverage can body excellent in surface property Download PDF

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JP2015045076A
JP2015045076A JP2013178131A JP2013178131A JP2015045076A JP 2015045076 A JP2015045076 A JP 2015045076A JP 2013178131 A JP2013178131 A JP 2013178131A JP 2013178131 A JP2013178131 A JP 2013178131A JP 2015045076 A JP2015045076 A JP 2015045076A
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aluminum alloy
aluminum
alloy plate
plate
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原田 俊宏
Toshihiro Harada
俊宏 原田
福増 秀彰
Hideaki Fukumasu
秀彰 福増
齊藤 充
Mitsuru Saito
充 齊藤
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MA Aluminum Corp
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Mitsubishi Aluminum Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a technology allowing for prevention of false detection of an inspection machine in optical inspection of an aluminum alloy sheet used for a can body.SOLUTION: There is provided an aluminum alloy sheet for a can body excellent in surface property which has: a composition containing, by mass%, Si:0.40% or less, Fe:0.30% to 0.60%, Cu:0.15 to 0.50%, Mn:0.90 to 1.20%, Mg:1.00 to 1.70%, Cr:0.05% or less, Zn:0.30% or less, Ti:0.15% or less and the balance aluminum with inevitable impurities; and a brightness L* of 72.5 or more and a color difference value ΔE* of 0 to 1.5 measured by using a spectral colorimeter.

Description

本発明は色差などの表面特性に優れる飲料缶ボディ用アルミニウム合金板に関する。   The present invention relates to an aluminum alloy plate for beverage can bodies having excellent surface characteristics such as color difference.

アルミニウム缶の缶ボディには、JIS3004(AA3004)またはJIS3104合金などの、Al−Mn−Mg系合金硬質板が用いられている。同合金硬質板には、容器として使用するために必要な強度や耐食性、美麗な外観、優れた成形性などが要求される。
前記合金硬質板は、一般的なアルミニウム合金板と同様、溶解・鋳造・均質化処理・均熱処理・熱間圧延・冷間圧延・中間焼鈍等の工程を経て製造される。そして通常、缶ボディ各部の強度や成形性のバランスが最適な状態に調質されている。即ち、アルミニウム合金板を圧延途中に一旦再結晶させ、軟質状態とした後、圧下率50〜90%程度の冷間圧延を行い、主として加工硬化により適度な強度としている。
For the can body of the aluminum can, an Al—Mn—Mg based alloy hard plate such as JIS3004 (AA3004) or JIS3104 alloy is used. The alloy hard plate is required to have strength and corrosion resistance necessary for use as a container, a beautiful appearance, and excellent formability.
The alloy hard plate is manufactured through processes such as melting, casting, homogenization treatment, soaking treatment, hot rolling, cold rolling, and intermediate annealing, as in the case of a general aluminum alloy plate. Usually, the balance of strength and formability of each part of the can body is tempered to an optimum state. That is, the aluminum alloy plate is recrystallized once in the course of rolling to be in a soft state, and then cold-rolled with a reduction rate of about 50 to 90% to obtain an appropriate strength mainly by work hardening.

また、蓋(エンド)と胴(ボディ)からなる2ピース缶であるならば、アルミニウム缶のボディは、缶ボディ用アルミニウム合金板からブランク材を打ち抜いて大径のカップを成形する工程と、絞り(DRAWING)としごき(IRONING)を組み合わせたDI成形工程によりDI缶が形成される。そして、このDI缶開口部のトリミング工程と、潤滑剤およびクーラントを除去する洗浄工程と、外面の塗装・印刷工程及び焼付け工程と、内部コーティングおよび焼付け工程がなされ、DI缶開口部のネッキングおよびフランジング工程がなされて缶ボディが形成される。   Also, if the can is a two-piece can consisting of a lid (end) and a trunk (body), the body of the aluminum can is formed by punching a blank from an aluminum alloy plate for the can body and forming a large-diameter cup, A DI can is formed by a DI molding process combining (DRAWING) and ironing (IRONING). Then, the DI can opening trimming process, the cleaning process for removing lubricant and coolant, the outer surface painting / printing process and baking process, the inner coating and baking process, and the DI can opening necking and flange are performed. The can body is formed by the bending process.

アルミニウム缶のボディには塗装や印刷が施され、あるいは樹脂被覆がなされるので、塗装や印刷の鮮明さの問題、樹脂被覆の接着性などの課題を解決する目的で、従来、アルミニウム合金板の表面粗さを規定し、表面に被覆する樹脂の吸光度比を規定し、アルミニウム合金板の表面の反射率や色味を規定する技術が知られている(特許文献1参照)。
この技術においては、アルミニウム合金板の表面粗さを0.5μm以下に規定し、被覆樹脂における異なる特定波長における赤外線スペクトル吸光度比を0.9以下に設定し、アルミニウム合金板の外表面の明度L*値を60以上、L*a*b*表色系色度で示すc*=(a*2+b*2)1/2で定義される彩度C*を5よりも小さくすることで問題を解決している。
また、アルミニウム合金板から缶ボディを製造した後、照明を当ててCCDカメラで撮影した画像からの画像処理を行う検査工程において、誤検査を防止する目的で板面の反射率を制御する技術が知られている(特許文献2参照)。
この技術においては、Mn、Mg、Cu、Si、Fe、Znの含有量を規定したアルミニウム合金からなるアルミニウム合金板に対し、圧延方向に対し90゜方向の粗さ曲線の平均長さRSmを50〜150μmとし、圧延方向0゜の正反射率35〜50%、90゜方向の正反射率10〜25%、これら異なる方向の正反射率の比を3.2以下とすることで検査時の誤検査を防止している。
The body of an aluminum can is painted, printed, or resin-coated, so the conventional aluminum alloy plate has been used for the purpose of solving problems such as the sharpness of painting and printing and the adhesiveness of the resin coating. A technique is known in which the surface roughness is defined, the absorbance ratio of the resin coated on the surface is defined, and the reflectance and color of the surface of the aluminum alloy plate are defined (see Patent Document 1).
In this technique, the surface roughness of the aluminum alloy plate is specified to be 0.5 μm or less, the infrared spectral absorbance ratio at different specific wavelengths in the coating resin is set to 0.9 or less, and the brightness L of the outer surface of the aluminum alloy plate is set. * Problem by reducing the saturation C * defined by c * = (a * 2 + b * 2) 1/2 that is 60 or more and L * a * b * color system chromaticity to less than 5. It has been solved.
In addition, after manufacturing the can body from an aluminum alloy plate, there is a technology that controls the reflectance of the plate surface for the purpose of preventing erroneous inspection in an inspection process in which an image is processed from an image taken with a CCD camera under illumination. It is known (see Patent Document 2).
In this technique, an average length RSm of a roughness curve in a 90 ° direction with respect to the rolling direction is 50 for an aluminum alloy plate made of an aluminum alloy in which the contents of Mn, Mg, Cu, Si, Fe, and Zn are defined. ˜150 μm, regular reflectance 35 to 50% in the rolling direction 0 °, regular reflectance 10 to 25% in the 90 ° direction, and ratio of the regular reflectance in these different directions to 3.2 or less. Prevents false inspections.

特許第3381137号公報Japanese Patent No. 338137 特開2008−274377号公報JP 2008-274377 A

前述のアルミニウム合金板から種々の工程を経て製造された缶ボディは、検査工程においてその表面が光学的に検査されている。例えば、缶口側からフランジ部、缶内面、缶底を照明装置で照らし、CCDカメラ等の光学機器により撮影し、画像処理により汚れや異物付着、割れ、表面性状等の検査がなされている。また缶を成形する途中の各工程において検査機を導入して画像処理により合金板の表面を検査することもある。   The surface of the can body manufactured from the above-described aluminum alloy plate through various processes is optically inspected in the inspection process. For example, the flange portion, the inner surface of the can, and the bottom of the can are illuminated from the can mouth side with an illuminating device, photographed with an optical device such as a CCD camera, and inspected for dirt, foreign matter adhesion, cracking, surface properties and the like by image processing. In addition, an inspection machine may be introduced in each process during the molding of the can to inspect the surface of the alloy plate by image processing.

アルミニウム缶のボディを撮影して異物等の検査を行うには、微小な異物や汚れなどの検査精度を上げるため、検査機の解像度の向上もなされているが、特に光沢を有する金属板表面の検査では異物や汚れなどが存在しないにも関わらず、検査機が誤検出して不良と判断、排出することがあった。
この誤検出の原因を調査したところ、アルミニウム合金板のような表面光沢の大きな金属板の検査では、照明光の反射の状態で部分的に輝度差や色差が大きくなり、異物や汚れ等の欠陥を生じていなくても、画像処理時の誤検出により欠陥品と判断してしまうことが判明した。このため本発明者は、光学的な検査機が上述の誤検出を生じないような表面状態のアルミニウム合金板の研究に鑑み、本願発明に到達した。
In order to inspect foreign objects by photographing the body of an aluminum can, the resolution of the inspection machine has been improved in order to increase the inspection accuracy of minute foreign objects and dirt, but especially on the surface of a glossy metal plate. In the inspection, although there is no foreign matter or dirt, the inspection machine erroneously detects it and determines that it is defective and discharges it.
As a result of investigating the cause of this false detection, in the inspection of a metal plate with a large surface gloss such as an aluminum alloy plate, the brightness difference and color difference partially increase in the reflected state of the illumination light, and there are defects such as foreign matter and dirt. It has been found that even if no defect occurs, it is determined as a defective product due to erroneous detection during image processing. For this reason, the present inventor arrived at the present invention in view of research on an aluminum alloy plate having a surface state in which an optical inspection machine does not cause the above-described erroneous detection.

本発明は、缶ボディ用に用いるアルミニウム合金板を光学的に検査する場合の検査機の誤検出を防止することができる技術の提供を目的とする。   An object of this invention is to provide the technique which can prevent the misdetection of the inspection machine in the case of optically inspecting the aluminum alloy plate used for can bodies.

本発明の表面特性に優れる飲料缶ボディ用アルミニウム合金板は、質量%でSi:0.40%以下、Fe:0.30%以上0.60%以下、Cu:0.15以上0.50%以下、Mn:0.90以上1.20%以下、Mg:1.00以上1.70%以下、Cr:0.05%以下、Zn:0.30%以下、Ti:0.15%以下を含有し、残部不可避不純物とアルミニウムの組成を有する缶ボディ用アルミニウム合金板であって、分光測色計を用いて測定される表面の明度L*が72.5以上で、コイル間の色差値ΔE*が0〜1.5であることを特徴とする。   The aluminum alloy plate for beverage can bodies having excellent surface characteristics according to the present invention is Si: 0.40% or less, Fe: 0.30% or more and 0.60% or less, Cu: 0.15 or more and 0.50% by mass%. Mn: 0.90 or more and 1.20% or less, Mg: 1.00 or more and 1.70% or less, Cr: 0.05% or less, Zn: 0.30% or less, Ti: 0.15% or less An aluminum alloy plate for a can body having a composition of the balance unavoidable impurities and aluminum, wherein the lightness L * of the surface measured using a spectrocolorimeter is 72.5 or more, and the color difference value ΔE between the coils * Is 0 to 1.5.

本発明の表面特性に優れる飲料缶ボディ用アルミニウム合金板は、前記組成のアルミニウム合金溶湯から鋳塊を得た後、熱間圧延と冷間圧延と中間焼鈍により作製され、熱間圧延の仕上板厚が2.0〜3.6mmの範囲、冷間圧延の仕上板厚が0.20〜0.27mmの範囲とされ、熱間圧延後の総冷間圧延率が86.5〜94.4%の範囲とされたことを特徴とする。   The aluminum alloy plate for beverage can bodies having excellent surface characteristics according to the present invention is produced by hot rolling, cold rolling and intermediate annealing after obtaining an ingot from the molten aluminum alloy having the above composition, and is a finish plate for hot rolling. The thickness is in the range of 2.0 to 3.6 mm, the finished sheet thickness in the cold rolling is in the range of 0.20 to 0.27 mm, and the total cold rolling ratio after hot rolling is 86.5 to 94.4. % Range.

本発明の缶ボディ用アルミニウム合金材の製造方法は、質量%でSi:0.40%以下、Fe:0.30%以上0.60%以下、Cu:0.15以上0.50%以下、Mn:0.90以上1.20%以下、Mg:1.00以上1.70以下、Cr:0.05%以下、Zn:0.30%以下、Ti:0.15%以下を含有し、残部不可避不純物とアルミニウムの組成を有する合金鋳塊を熱間圧延工程により仕上板厚2.0〜3.6mmのアルミニウム合金熱間圧延材を得、次いで冷間圧延工程により熱間圧延後の総冷間圧延率を86.5〜94.4%の範囲として仕上板厚0.20〜0.27mmとし、分光測色計を用いて測定される表面の明度L*が72.5以上で、コイル間の色差値ΔE*を0〜1.5としたアルミニウム合金材を得ることを特徴とする。   The method for producing an aluminum alloy material for a can body of the present invention includes Si: 0.40% or less, Fe: 0.30% or more and 0.60% or less, Cu: 0.15 or more and 0.50% or less, in mass%. Mn: 0.90 to 1.20%, Mg: 1.00 to 1.70, Cr: 0.05% or less, Zn: 0.30% or less, Ti: 0.15% or less, An alloy ingot having the balance of inevitable impurities and aluminum is obtained by a hot rolling process to obtain an aluminum alloy hot rolled material having a finished sheet thickness of 2.0 to 3.6 mm, and then the total amount after hot rolling is obtained by a cold rolling process. The cold rolling rate is in the range of 86.5-94.4% and the finished plate thickness is 0.20 to 0.27 mm, and the surface brightness L * measured using a spectrocolorimeter is 72.5 or more, An aluminum alloy material having a color difference ΔE * between coils of 0 to 1.5 can be obtained. The features.

本発明によれば、表面の明度L*が72.5以上で、コイル間の色差値ΔE*を0〜1.5の範囲とした缶ボディ用アルミニウム合金材を得ることができるので、検査工程において照明をあてて光学的に検査した場合、検査工程で欠陥の無い良品を誤検出することがなくなり、検査精度が向上する効果がある。   According to the present invention, an aluminum alloy material for a can body having a surface brightness L * of 72.5 or more and a color difference value ΔE * between coils in the range of 0 to 1.5 can be obtained. When the optical inspection is performed by illuminating in FIG. 3, there is no erroneous detection of a non-defective product in the inspection process, and the inspection accuracy is improved.

以下、本発明に係る表面特性に優れる缶ボディ用アルミニウム合金板の製造方法について説明するが、初めに、缶ボディ用アルミニウム合金板の板厚と合金組成、表面特性について説明する。
本実施形態の缶ボディ用アルミニウム合金板は目標とする板厚が0.20mm以上0.27mm以下であり、質量%で、Si:0.40%以下、Fe:0.30%以上0.60%以下、Cu:0.15以上0.50%以下、Mn:0.90以上1.20%以下、Mg:1.00以上1.70%以下、Cr:0.05%以下、Zn:0.30%以下、Ti:0.15%以下を含有し、残部不可避不純物とアルミニウムの組成を有するアルミニウム合金からなる。
また、本実施形態の缶ボディ用アルミニウム合金板は、前記組成範囲のアルミニウム合金からなる鋳塊を、熱間圧延工程により仕上板厚2.0〜3.6mmのアルミニウム合金熱間圧延板を得、次いで冷間圧延工程により仕上板厚0.20〜0.27mmとし、熱間圧延後の総冷間圧延率を86.5〜94.4%の範囲として製造される。また、冷間圧延後に得られた本実施形態の缶ボディ用アルミニウム合金板は、分光測色計を用いて測定した表面の明度L*が72.5以上で、コイル間の色差値ΔE*が0〜1.5(0以上1.5以下)の範囲である。
Hereinafter, although the manufacturing method of the aluminum alloy plate for can bodies which is excellent in the surface characteristic which concerns on this invention is demonstrated, the board thickness, alloy composition, and surface characteristic of the aluminum alloy plate for can bodies are demonstrated first.
The aluminum alloy plate for can bodies of this embodiment has a target plate thickness of 0.20 mm or more and 0.27 mm or less, and by mass%, Si: 0.40% or less, Fe: 0.30% or more and 0.60. %: Cu: 0.15 or more and 0.50% or less, Mn: 0.90 or more and 1.20% or less, Mg: 1.00 or more and 1.70% or less, Cr: 0.05% or less, Zn: 0 .30% or less, Ti: 0.15% or less, and the balance is made of an aluminum alloy having a composition of inevitable impurities and aluminum.
Moreover, the aluminum alloy plate for can bodies of this embodiment obtains an aluminum alloy hot-rolled sheet having a finished sheet thickness of 2.0 to 3.6 mm by performing a hot rolling process on an ingot made of an aluminum alloy having the above composition range. Then, the finished sheet thickness is 0.20 to 0.27 mm by a cold rolling process, and the total cold rolling rate after hot rolling is manufactured in the range of 86.5 to 94.4%. In addition, the aluminum alloy plate for a can body of the present embodiment obtained after cold rolling has a surface brightness L * measured by using a spectrocolorimeter of 72.5 or more, and a color difference value ΔE * between coils is It is the range of 0-1.5 (0 or more and 1.5 or less).

[成分組成]
以下、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において限定する成分組成について説明する。なお、本明細書において記載する各元素の含有量は、特に規定しない限り質量%であり、また、特に規定しない限り範囲の記載は上限と下限を含むものとする。従って、例えば0.35〜0.55%との表記は0.35%以上0.55%以下を意味する。
[Ingredient composition]
Hereinafter, the component composition limited in the aluminum alloy plate for can bodies excellent in the surface characteristics of this embodiment will be described. In addition, content of each element described in this specification is mass% unless otherwise specified, and the description of the range includes an upper limit and a lower limit unless otherwise specified. Therefore, for example, the notation of 0.35 to 0.55% means 0.35% or more and 0.55% or less.

「Si」0.40%以下
Siは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、同時に含有されるMg等とともに化合物を形成し、析出硬化及び分散硬化作用で強度を向上させる他、Al−Mn−Fe系金属間化合物に含有されて、しごき成形時にダイスに対する焼き付きを防止する効果を有する。
Siの含有量が0.40%を越えると、強度が高くなりすぎ、缶ボディとして製缶した際に胴切れが生じ易くなり、加工性が劣化する。
また、Siの含有量が0.40%を越えると、Al−Mn−Fe系金属間化合物の量が多くなり、さらに、Mg、Cu、Alとの金属間化合物が溶体化できなくなり、靭性が低下し、ピンホールが生じやすくなる。従って、Siの含有量は、0.40%以下の範囲内とすることが好ましいが、少なすぎると十分な強度が得られ難くなるので、0.2%〜0.40%の範囲がより好ましい。
“Si” 0.40% or less Si forms a compound with Mg and the like contained at the same time in the aluminum alloy plate for can bodies having excellent surface characteristics of the present embodiment, and improves the strength by precipitation hardening and dispersion hardening action. In addition, it is contained in an Al—Mn—Fe intermetallic compound, and has an effect of preventing seizure against a die during ironing.
If the Si content exceeds 0.40%, the strength becomes too high, and when a can body is produced, it becomes easy to cause a cylinder to be cut and the workability deteriorates.
If the Si content exceeds 0.40%, the amount of Al-Mn-Fe intermetallic compounds increases, and further, intermetallic compounds with Mg, Cu, and Al cannot be solutionized, and the toughness is increased. The pinhole is likely to occur. Accordingly, the Si content is preferably within the range of 0.40% or less, but if it is too small, it is difficult to obtain sufficient strength, so the range of 0.2% to 0.40% is more preferable. .

「Fe」0.30〜0.60%
Feは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、Al−Mn−Fe系金属間化合物の量を増加させ、結晶の微細化と、しごき成形加工時にダイスに対して焼き付きが生じるのを防止する効果を有する。
Feの含有量が0.30%未満であると、Al−Mn−Fe系金属間化合物の量が少なくなりすぎ、しごき金型への焼き付が生じやすくなる。Feの含有量が0.60%を超えると、Al−Mn−Fe系金属間化合物の量が多くなりすぎ、靭性低下によって加工性が劣化し、ピンホールが生じやすくなる。従って、Feの含有量は、0.30〜0.60%の範囲内とすることが好ましい。
"Fe" 0.30-0.60%
In the aluminum alloy plate for can bodies having excellent surface characteristics according to the present embodiment, Fe increases the amount of the Al—Mn—Fe intermetallic compound, so that the crystal is refined and seized against the die during the ironing process. It has the effect of preventing the occurrence.
When the Fe content is less than 0.30%, the amount of the Al—Mn—Fe-based intermetallic compound is too small, and seizure to the ironing mold is likely to occur. When the Fe content exceeds 0.60%, the amount of Al—Mn—Fe intermetallic compound is excessively increased, workability is deteriorated due to a decrease in toughness, and pinholes are easily generated. Therefore, the Fe content is preferably in the range of 0.30 to 0.60%.

「Cu」0.15〜0.50%
Cuは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、Mg等と金属間化合物を形成し、固溶硬化、析出硬化及び分散硬化作用で強度を高める効果を有する。
Cuの含有量が0.15%未満であると、充分な強度向上効果が得られない。Cuの含有量が0.50%を越えると、サイドクラックが発生し易くなり、圧延性が低下するとともに、強度が高くなりすぎ、缶ボディとして製缶した際に胴切れが生じ易くなる。また、Mg、Si、Alとの金属間化合物が溶体化できなくなり、靭性低下によって加工性が劣化し、ピンホールが生じやすくなる。従って、Cuの含有量は、0.15〜0.50%の範囲内とすることが好ましい。
"Cu" 0.15-0.50%
Cu forms an intermetallic compound with Mg and the like in the aluminum alloy plate for can bodies excellent in surface characteristics of this embodiment, and has an effect of increasing strength by solid solution hardening, precipitation hardening, and dispersion hardening.
If the Cu content is less than 0.15%, a sufficient strength improvement effect cannot be obtained. If the Cu content exceeds 0.50%, side cracks are likely to occur, the rolling property is lowered, the strength is too high, and the body is likely to be cut when it is manufactured as a can body. In addition, the intermetallic compound with Mg, Si, and Al cannot be in solution, and the workability deteriorates due to a decrease in toughness, and pinholes are likely to occur. Therefore, the Cu content is preferably in the range of 0.15 to 0.50%.

「Mn」0.90〜1.20%
Mnは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、Al−Mn−Fe系金属間化合物を形成し、晶出相及び分散相となって分散硬化作用を発揮するとともに、しごき成形加工時にダイスに対して焼き付きが生じるのを防止する効果を有する。
Mnの含有量が0.90%未満であると、Al−Mn−Fe系金属間化合物の量が少なくなりすぎて充分な硬化特性が得られず、しごき金型への焼き付が生じやすくなる。Mnの含有量が1.20%を越えると、Al−Mn−Fe系金属間化合物の量が多くなりすぎ、靭性低下によって加工性が劣化し、ピンホールが生じやすくなる。従って、Mnの含有量は、0.90〜1.20%の範囲内とすることが好ましい。
“Mn” 0.90 to 1.20%
Mn forms an Al-Mn-Fe intermetallic compound in the aluminum alloy plate for can bodies having excellent surface characteristics according to the present embodiment, exhibits a dispersion hardening action as a crystallization phase and a dispersed phase, and irons It has the effect of preventing seizure from occurring on the die during molding.
If the content of Mn is less than 0.90%, the amount of Al—Mn—Fe intermetallic compound becomes too small to obtain sufficient curing characteristics, and seizure to the ironing mold is likely to occur. . When the content of Mn exceeds 1.20%, the amount of Al—Mn—Fe intermetallic compound becomes too large, workability deteriorates due to a decrease in toughness, and pinholes are likely to occur. Therefore, the Mn content is preferably in the range of 0.90 to 1.20%.

「Mg」1.00〜1.70%
Mgは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、固溶体強化作用を有し、圧延加工時に加工硬化性を高めるとともに、SiやCuと共存することで分散硬化と析出硬化作用を発揮し、強度を向上させる。
Mgの含有量が1.00%未満であると、十分な強度が得られない。Mgの含有量が1.70%を超えると、サイドクラックが発生し易くなり、圧延性が低下するとともに、強度が高くなり過ぎて加工性が低下し、缶ボディとして製缶した際に胴切れやフランジ部の割れが生じ易くなる。従って、Mgの含有量は、1.00〜1.70%の範囲内とすることが好ましい。
"Mg" 1.00 to 1.70%
Mg has a solid solution strengthening action in the aluminum alloy plate for can bodies excellent in the surface characteristics of the present embodiment, enhances work hardenability at the time of rolling, and coexists with Si and Cu to achieve dispersion hardening and precipitation hardening action. To improve the strength.
If the Mg content is less than 1.00%, sufficient strength cannot be obtained. If the Mg content exceeds 1.70%, side cracks are likely to occur, the rollability is lowered, the strength is too high, the workability is lowered, and the can body is cut when it is made as a can body. And cracking of the flange portion is likely to occur. Therefore, the Mg content is preferably in the range of 1.00 to 1.70%.

「Cr」0.05%以下
Crは、析出物の微細化と、しごき成形加工時にダイスに対する焼き付きを防止する効果を発揮する。Cr含有量が0.05%を超えると脆くなり、加工性が劣化する傾向となるので、Cr含有量は0.05%以下であることが好ましい。なお、上述の効果を得るためには、Crを0.001%以上含有することが好ましい。
「Zn及びTi」Zn:0.30%以下、Ti:0.15%以下
本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板は、質量%でZn:0.30%以下、Ti:0.15%以下を含有する成分組成とすることができる。
Znは、析出するMg、Si、Cuの金属間化合物を微細化する作用を有するが、Znを含む場合は、原料として使用済みアルミ缶(UBC)やリサイクル材料を有効利用できる。Zn含有量が0.30%を越えると、耐食性が劣化する傾向がある。
Tiは、本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板において、結晶粒を微細化し、加工性を改善する効果を有する。Tiの含有量が0.15%を越えると、金属間化合物が多くなり過ぎて靭性が低下し、ピンホールが生じやすくなる。従って、Tiの含有量は、0.15%以下とすることが好ましい。
また、本実施形態に用いるアルミニウム合金板においてその他の元素を不純物として0.05%以下含有していても差し支えない。
“Cr” 0.05% or less Cr exhibits the effect of reducing the size of precipitates and preventing seizure on the die during ironing. If the Cr content exceeds 0.05%, it becomes brittle and the workability tends to deteriorate. Therefore, the Cr content is preferably 0.05% or less. In addition, in order to acquire the above-mentioned effect, it is preferable to contain 0.001% or more of Cr.
“Zn and Ti” Zn: 0.30% or less, Ti: 0.15% or less The aluminum alloy plate for a can body having excellent surface characteristics according to this embodiment is Zn: 0.30% or less, Ti: 0% by mass. The component composition may contain 15% or less.
Zn has the effect of refining the precipitated intermetallic compounds of Mg, Si, and Cu, but when it contains Zn, used aluminum cans (UBC) and recycled materials can be effectively used as raw materials. If the Zn content exceeds 0.30%, the corrosion resistance tends to deteriorate.
In the aluminum alloy plate for can bodies having excellent surface characteristics according to the present embodiment, Ti has an effect of refining crystal grains and improving workability. When the Ti content exceeds 0.15%, the amount of intermetallic compounds increases so much that the toughness decreases and pinholes are likely to occur. Therefore, the Ti content is preferably 0.15% or less.
Further, the aluminum alloy plate used in the present embodiment may contain 0.05% or less of other elements as impurities.

「アルミニウム合金板の製造方法」
本発明に係る缶ボディ用アルミニウム合金板は、この種のアルミニウム合金を製造する場合に適用される通常の溶解、鋳造、均質化処理、均熱処理、熱間圧延、冷間圧延を経て製造される。また冷間圧延のパス間に、300℃以上500℃以下の温度に1時間以上加熱する箱型焼鈍炉による焼鈍、または400℃以上、600℃以下の温度に1秒以上加熱する連続焼鈍炉による焼鈍を行うことが好ましい。またこの焼鈍は2回以上に分けて行ってもよい。
"Production method of aluminum alloy sheet"
The aluminum alloy plate for a can body according to the present invention is manufactured through ordinary melting, casting, homogenizing treatment, soaking treatment, hot rolling, and cold rolling applied when manufacturing this type of aluminum alloy. . Moreover, between passes of cold rolling, annealing by a box-type annealing furnace heated to a temperature of 300 ° C. or higher and 500 ° C. or lower for 1 hour or more, or by a continuous annealing furnace heated to a temperature of 400 ° C. or higher and 600 ° C. or lower for 1 second or longer It is preferable to perform annealing. Further, this annealing may be performed in two or more times.

「熱間圧延」
熱間圧延は、溶解、鋳造、均質化処理、均熱処理後、炉から取出したスラブを投入して熱間圧延を開始するが、圧延材が厚い間は、通常圧延機の前後に搬送テーブルが設置された1スタンドの可逆式熱間粗圧延機を用いて圧延を行い、圧延材の厚さがある程度薄くなると熱間仕上圧延機にて圧延を行う。なお熱間仕上圧延機は圧延機の前後に巻取り装置が設置された可逆式のシングルタイプと、3〜4組の圧延ロールを直列に並べた非可逆式のタンデムタイプがある。そして熱間仕上圧延後の板厚は2.0mm以上3.6mm以下であることが必要である。板厚が薄すぎる場合、板厚が大き過ぎる場合は、後述する冷間圧延において目的とする総冷間圧延率によって目的の最終板厚を実現できないという問題が生じる。
また熱間圧延板厚3.6mmを超える場合、熱間圧延最終パス後に巻き取った直後のコイル温度が高くなり熱間圧延直後および続く冷却過程において板表面の酸化が著しくなる。この酸化皮膜は熱間圧延に続く冷間圧延によって分断されていくが、熱間圧延板厚3.6mmを超える場合は最終的な板の表面を分光測色計を用いて測定した場合の明度L*値が72.5未満となる。この場合、後の検査工程において照明光をあてて工学的な検査を行った場合に暗く検出されて誤検出が増加する傾向があり、本願の目的を達成することが困難になる。
"Hot rolling"
In hot rolling, after melting, casting, homogenizing treatment, soaking treatment, slabs taken out from the furnace are put in and hot rolling is started, but while the rolled material is thick, there is usually a transport table before and after the rolling mill. Rolling is performed using a single stand reversible hot roughing mill installed, and rolling is performed with a hot finish rolling mill when the thickness of the rolled material is reduced to some extent. The hot finish rolling mill includes a reversible single type in which winding devices are installed before and after the rolling mill, and a non-reversible tandem type in which three to four sets of rolling rolls are arranged in series. And the plate | board thickness after hot finish rolling needs to be 2.0 mm or more and 3.6 mm or less. When the plate thickness is too thin or the plate thickness is too large, there arises a problem that the target final plate thickness cannot be realized by the target total cold rolling rate in the cold rolling described later.
On the other hand, when the thickness of the hot rolled sheet exceeds 3.6 mm, the coil temperature immediately after winding after the final hot rolling pass becomes high, and the oxidation of the sheet surface becomes remarkable immediately after hot rolling and in the subsequent cooling process. This oxide film is divided by cold rolling subsequent to hot rolling. When the thickness of the hot rolled plate exceeds 3.6 mm, the brightness when the final plate surface is measured using a spectrocolorimeter. L * value is less than 72.5. In this case, when an engineering inspection is performed by applying illumination light in a later inspection process, the detection is dark and the false detection tends to increase, and it is difficult to achieve the object of the present application.

「冷間圧延」
熱間圧後冷却した後、圧下率86.5%以上94.4%以下の総冷間圧延率で冷間圧延を施す。本発明者の検討結果では、最終冷間圧延後の板厚を0.20mm以上0.27mm以下を得る場合、上述の熱間仕上圧延による板厚を2.0以上3.6mm以下の範囲とすることで、総冷間圧延率86.5%以上94.4%以下を得ることができる。この総冷間圧延率を86.5%以上94.4%以下の範囲とすることにより熱間圧延直後および続く冷却過程において表面に形成された酸化膜が分断される程度を一定の範囲内に収めることができる。このため最終的なアルミニウム合金板の表面を分光測色計を用いて測定した場合のコイル間の色差の値ΔE*を0〜1.5(0以上1.5以下)の範囲とすることが可能となる。アルミニウム合金板の冷間圧延の総冷間圧延率86.5%未満、94、4%超過の場合はコイル間の色差値ΔE*が0〜1.5(0以上1.5以下)の範囲よりも大きくなり、後の検査工程において照明光をあてて光学的な検査を行った場合の誤検出が増加する傾向があり、本願の目的を達成することが困難になる。
また総冷間圧延率86.5%未満の場合はL*値が72.5未満となり、同様に本題の目的を達成することが困難になる。
"Cold rolling"
After cooling after hot pressing, cold rolling is performed at a total cold rolling rate of 86.5% or more and 94.4% or less. As a result of the study by the present inventors, when the thickness after the final cold rolling is 0.20 mm or more and 0.27 mm or less, the thickness by hot finish rolling described above is in the range of 2.0 or more and 3.6 mm or less. By doing this, a total cold rolling reduction of 86.5% or more and 94.4% or less can be obtained. By setting the total cold rolling rate in the range of 86.5% or more and 94.4% or less, the degree of division of the oxide film formed on the surface immediately after hot rolling and in the subsequent cooling process is within a certain range. Can fit. For this reason, the value ΔE * of the color difference between the coils when the surface of the final aluminum alloy plate is measured using a spectrocolorimeter may be in the range of 0 to 1.5 (0 to 1.5). It becomes possible. When the total cold rolling rate of the aluminum alloy sheet is less than 86.5%, 94, and 4%, the color difference value ΔE * between the coils is in the range of 0 to 1.5 (0 to 1.5). The detection error tends to increase when an optical inspection is performed by illuminating illumination light in a later inspection process, making it difficult to achieve the object of the present application.
When the total cold rolling rate is less than 86.5%, the L * value is less than 72.5, and it is difficult to achieve the object of the present subject.

「缶ボディ用アルミニウム合金板の板厚」
本実施形態により最終的に得られる表面特性に優れる缶ボディ用アルミニウム合金板の板厚は、0.200mm以上0.270mm以下の範囲である。
板厚が0.200mm未満であると、製缶して缶ボディとした際の十分な耐圧強度が得られ難くなる。また、板厚が0.270mmを超えるようであると、缶ボディの底部の重量が重くなり、製造コストが上昇して経済的でなくなる。
本実施形態の表面特性に優れる缶ボディ用アルミニウム合金板の板厚は、0.230mm以上0.270mm以下の範囲が更に好ましい。
"Thickness of aluminum alloy sheet for can body"
The plate thickness of the aluminum alloy plate for can bodies that is finally excellent in surface characteristics according to the present embodiment is in the range of 0.200 mm to 0.270 mm.
When the plate thickness is less than 0.200 mm, it becomes difficult to obtain sufficient pressure resistance when canned to form a can body. On the other hand, if the plate thickness exceeds 0.270 mm, the weight of the bottom of the can body becomes heavy, which increases the manufacturing cost and is not economical.
The thickness of the aluminum alloy plate for can bodies having excellent surface characteristics according to this embodiment is more preferably in the range of 0.230 mm to 0.270 mm.

以上説明した熱間圧延工程と冷間圧延工程に従い、前述の組成比のアルミニウム合金からなるアルミニウム合金板を製造することにより、分光測色計を用いて測定した表面の明度L*が72.5以上で、コイル間の色差値ΔE*が0〜1.5(0以上1.5以下)の範囲のアルミニウム合金板を得ることができる。
このように表面の明度L*が72.5以上でコイル間の色差値ΔE*が0〜1.5のアルミニウム合金板であるならば、明度が十分にありかつ色差が十分に小さいので、アルミニウム合金板の表面に照明光をあてて画像読み取りにより欠陥を検出する検査工程において検査機が誤検出を出すおそれが少なく、検査精度を向上できる。即ち、アルミニウム合金板表面の明度があり誤って表面の汚れや凹凸不良などと判別して誤検出してしまうことがなく、また、色差が小さいので、アルミニウム合金板の表面からの反射光に色差に起因する色ムラや不均一性に伴う色変化が少なく、反射光を画像解析した場合、傷や凹凸などの欠陥のない良品のアルミニウム合金板を不良品と判別してしまう誤検出が少なくなる。
According to the hot rolling process and the cold rolling process described above, the surface lightness L * measured using a spectrocolorimeter is 72.5 by manufacturing an aluminum alloy plate made of an aluminum alloy having the composition ratio described above. With the above, an aluminum alloy plate having a color difference value ΔE * between coils in the range of 0 to 1.5 (0 or more and 1.5 or less) can be obtained.
Thus, if the surface lightness L * is 72.5 or more and the color difference value ΔE * between coils is 0 to 1.5, the aluminum alloy plate has sufficient lightness and sufficiently small color difference. In the inspection process in which the illumination light is applied to the surface of the alloy plate and the defect is detected by reading the image, the inspection machine is less likely to make a false detection, and the inspection accuracy can be improved. That is, the surface of the aluminum alloy plate has lightness, so that it is not mistakenly detected as a surface stain or irregularities in the surface, and the color difference is small, so that the color difference in reflected light from the surface of the aluminum alloy plate is small. Color variation due to color unevenness and non-uniformity caused by the surface is small, and when the reflected light is image-analyzed, there are fewer false detections that determine that a good aluminum alloy plate without defects such as scratches and irregularities is defective. .

また、得られたアルミニウム合金板については、缶ボディに加工後、通常、塗装焼付けを行うので、200〜220℃で加熱処理した後の耐力として、230〜320N/mm程度の耐力を有することが望ましい。 Moreover, about the obtained aluminum alloy plate, since it is normally baked after being processed into a can body, it has a proof strength of about 230 to 320 N / mm 2 as a proof strength after heat treatment at 200 to 220 ° C. Is desirable.

以下、実施例を示して、本発明に係る表面性状が良好な高強度缶ボディ用板材の製造方法について更に詳しく説明するが、本発明は以下の実施例に限定されるものでは無い。
Al−0.31%Si−0.44%Fe−0.39%Cu−0.99%Mn−1.35%Mg−0.02%Cr−0.14%Zn−0.04%Tiなる組成のアルミニウム合金を溶解し、脱ガスおよび溶湯ろ過後、半連続鋳造により厚さ600mm、幅1500mm、長さ4.5mのスラブに鋳造した。
次いで、スラブに565℃で均質化処理を施した後、熱間圧延により板厚3.20または3.19mmまで圧延し、その後、板厚0.70mmまで冷間圧延を行った。そして480℃〜590℃の温度範囲に1s〜60s加熱する連続焼鈍(IA−CAL)を施し、さらに0.252mmの最終板厚まで冷間圧延して表1の実施例1〜11の試料を得た。
熱間圧延仕上板厚と熱間圧延後の総冷間圧延率(%)、製缶後の洗浄・エッチング処理と同条件の前処理の実施有無、そして缶表面検査機での異常排出有無を測定し、以下の表1に記載し、得られたアルミニウム合金板の色彩特性結果を表2に記載する。なお、明度L*および色差値ΔE*について表1に併記する。
EXAMPLES Hereinafter, although an Example is shown and the manufacturing method of the board | plate material for high-strength can bodies with the favorable surface property based on this invention is demonstrated in detail, this invention is not limited to a following example.
Al-0.31% Si-0.44% Fe-0.39% Cu-0.99% Mn-1.35% Mg-0.02% Cr-0.14% Zn-0.04% Ti The aluminum alloy having the composition was melted, degassed and filtered with a molten metal, and then cast into a slab having a thickness of 600 mm, a width of 1500 mm, and a length of 4.5 m by semi-continuous casting.
Next, the slab was homogenized at 565 ° C., and then hot-rolled to a sheet thickness of 3.20 or 3.19 mm, and then cold-rolled to a sheet thickness of 0.70 mm. And the continuous annealing (IA-CAL) which heats to the temperature range of 480 degreeC-590 degreeC for 1 s-60 s is given, and also it cold-rolls to the final sheet thickness of 0.252 mm, and the sample of Examples 1-11 of Table 1 is carried out. Obtained.
The thickness of the hot-rolled finished sheet, the total cold rolling rate after hot rolling (%), whether or not pre-treatment under the same conditions as cleaning / etching after can-making, and abnormal discharge in a can surface inspection machine Measured and listed in Table 1 below, and the color characteristic results of the resulting aluminum alloy sheet are listed in Table 2. The lightness L * and the color difference value ΔE * are also shown in Table 1.

Figure 2015045076
Figure 2015045076

Figure 2015045076
Figure 2015045076

色差値ΔE*は、ミノルタ株式会社製、分光測色計 CM−508dを用いて測定した。測定条件において第一光源:D65、視野10゜として測定している。なお、L*a*b*表色系はJIS Z 8729で規定されている表示方法であり、JIS Z 8730の色差表示方法に基づいている。色差値ΔE*は、米国標準局で定めるNBS単位として知られており、0〜0.5、0.5〜1.5、1.5〜3.0、3.0〜6.0、6.0〜12、12以上などのようにランク分けされている指標である。
色差値(ΔE*)はNBS単位(米国標準局)で以下の表3に示す通りランク分けされている。
The color difference value ΔE * was measured using a spectrocolorimeter CM-508d manufactured by Minolta Co., Ltd. The measurement is performed under the first light source: D65 and a visual field of 10 ° under measurement conditions. The L * a * b * color system is a display method defined in JIS Z 8729 and is based on the color difference display method of JIS Z 8730. The color difference value ΔE * is known as an NBS unit determined by the US National Bureau of Standards. 0 to 0.5, 0.5 to 1.5, 1.5 to 3.0, 3.0 to 6.0, 6 It is an index that is ranked as 0 to 12, 12 or more.
Color difference values (ΔE *) are ranked in NBS units (US National Bureau of Standards) as shown in Table 3 below.

Figure 2015045076
Figure 2015045076

表1、表2において前処理あり(化成処理)とは、洗浄で取りきれないものを除去し、製缶後の塗膜密着性を向上するためにリン酸ジルコニウム系の処理液にて化成処理した試料を示す。表1、表2の試料において化成処理を行う試料と行わない試料を併記したのは、化成処理によって表面の状態を変えたことが、表面のΔE*の値に影響を与えるか否か把握するためである。   In Tables 1 and 2, “with pretreatment (chemical conversion treatment)” means that chemical removal treatment is carried out with a zirconium phosphate-based treatment solution to remove those that cannot be removed by washing and to improve coating film adhesion after canning. The sample was shown. In Table 1 and Table 2, the sample subjected to the chemical conversion treatment and the sample not subjected to the chemical conversion are written together to grasp whether the change in the surface state due to the chemical conversion treatment affects the value of ΔE * of the surface. Because.

「比較例」
比較例1〜3および5〜7はAl−0.29%Si−0.41%Fe−0.38%Cu−0.98%Mn−1.34%Mg−0.02%Cr−0.15%Zn−0.04%Tiなる組成のアルミニウム合金、比較例4はAl−0.29%Si−0.40%Fe−0.25%Cu−0.98%Mn−1.21%Mg−0.02%Cr−0.17%Zn−0.03%Tiなる組成のアルミニウム合金を溶解し、先の実施例と類似の構造工程を経てアルミニウム合金板を製造した。比較例1〜3および比較例5〜7の熱間圧延仕上板厚は5.43mm、熱間圧延後の総冷間圧延率は95.36%、比較例4の熱間圧延仕上板厚は2.60mm、熱間圧延後の総冷延率は84.62%である。
"Comparative example"
Comparative Examples 1-3 and 5-7 are Al-0.29% Si-0.41% Fe-0.38% Cu-0.98% Mn-1.34% Mg-0.02% Cr-0. Aluminum alloy having a composition of 15% Zn-0.04% Ti, Comparative Example 4 is Al-0.29% Si-0.40% Fe-0.25% Cu-0.98% Mn-1.21% Mg An aluminum alloy having a composition of -0.02% Cr-0.17% Zn-0.03% Ti was melted, and an aluminum alloy plate was manufactured through structural steps similar to those of the previous examples. The hot rolled finished sheet thicknesses of Comparative Examples 1 to 3 and Comparative Examples 5 to 7 are 5.43 mm, the total cold rolling rate after hot rolling is 95.36%, and the hot rolled finished sheet thickness of Comparative Example 4 is The total cold rolling ratio after hot rolling at 2.60 mm is 84.62%.

表1に記載した缶表面検査機とは、例えば倉敷紡績株式会社製のLED照明と高精度CCDカメラを組み合わせて欠陥を高速度、高精度で検出するような専用検査システムであり、これにより缶表面の画像を解析し、欠陥を検出を行う。この際の異常排出とは、異物や汚れなどが存在しないにも関わらず、検査機が誤検出して集中発生的に缶を排出してしまうことを意味する。
表2に示すΔL*、Δa*、Δb*の値は、基準試料が示す各値を基準に算出した値である。
The can surface inspection machine shown in Table 1 is a dedicated inspection system that detects defects with high speed and high accuracy by combining, for example, LED lighting manufactured by Kurashiki Boseki Co., Ltd. and a high-precision CCD camera. Analyzes the surface image and detects defects. The abnormal discharge at this time means that the inspection machine erroneously detects and discharges the cans in a concentrated manner even though there is no foreign matter or dirt.
The values of ΔL *, Δa *, and Δb * shown in Table 2 are values calculated based on each value indicated by the reference sample.

表1、表2に示す結果から、熱間圧延仕上板厚が3.20または3.19mm、熱間圧延後の総冷間圧延率が92.13または92.10%である実施例1〜11の試料は、いずれの試料であっても明度L*は73.10〜74.36の範囲、色差ΔE*=0.10〜0.92の範囲となった。即ち、本発明で規定するL*72.5以上、ΔE*=0〜1.5の範囲に収まった。このため、缶表面検査機において異常排出は生じなかった。   From the results shown in Tables 1 and 2, Examples 1 to 3 were hot-rolled finished sheet thicknesses of 3.20 or 3.19 mm, and the total cold rolling rate after hot rolling was 92.13 or 92.10%. In any of the 11 samples, the lightness L * was in the range of 73.10 to 74.36, and the color difference ΔE * was in the range of 0.10 to 0.92. That is, it was within the range of L * 72.5 or more and ΔE * = 0 to 1.5 defined in the present invention. For this reason, abnormal discharge did not occur in the can surface inspection machine.

これらに対し、熱間圧延仕上板厚が3.6mmを超えて熱間圧延後の総冷間圧延率が94.4%を超えている比較例1〜3および5〜7の試料、また、熱間圧延後の総冷間圧延率が86.5%を下回る比較例4の試料は、いずれもL*値が71.31〜72.45の範囲と72.5を下回り、ΔE*値が1.81〜2.61の範囲と1.5を超えており、欠陥の無いアルミニウム合金板を検査した場合であっても缶表面の検査機が誤検出して異常排出することが判明した。
また、化成処理を行って表面を清浄化した試料と、化成処理を施していない試料の比較では顕著な差異は認められなかった。従って、本実施例によるアルミニウム合金板によれば、表面を化成処理するか、しないかに関わらず、光学的検査機にて誤検査の生じ難い特徴を得ることができる。
On the other hand, the samples of Comparative Examples 1 to 3 and 5 to 7 in which the hot rolled finish plate thickness exceeds 3.6 mm and the total cold rolling rate after hot rolling exceeds 94.4%, As for the sample of the comparative example 4 in which the total cold rolling rate after hot rolling is less than 86.5%, L * value is less than the range of 71.31 to 72.45 and 72.5, and ΔE * value is The range of 1.81 to 2.61 and 1.5 were exceeded, and even when an aluminum alloy plate having no defects was inspected, it was found that the inspection machine on the surface of the can erroneously detected and abnormally discharged.
In addition, no significant difference was observed between the sample whose surface was cleaned by chemical conversion treatment and the sample which was not subjected to chemical conversion treatment. Therefore, according to the aluminum alloy plate of the present embodiment, it is possible to obtain a feature that is unlikely to cause an erroneous inspection with an optical inspection machine regardless of whether or not the surface is subjected to chemical conversion treatment.

Claims (3)

質量%でSi:0.40%以下、Fe:0.30%以上0.60%以下、Cu:0.15以上0.50%以下、Mn:0.90以上1.20%以下、Mg:1.00以上1.70以下、Cr:0.05%以下、Zn:0.30%以下、Ti:0.15%以下を含有し、残部不可避不純物とアルミニウムの組成を有する缶ボディ用アルミニウム合金板であって、分光測色計を用いて測定される表面の明度L*が72.5以上で、色差値ΔE*が0〜1.5であることを特徴とする表面特性に優れる飲料缶ボディ用アルミニウム合金板。   In mass%, Si: 0.40% or less, Fe: 0.30% or more and 0.60% or less, Cu: 0.15 or more and 0.50% or less, Mn: 0.90 or more and 1.20% or less, Mg: Aluminum alloy for can body containing 1.00 or more and 1.70 or less, Cr: 0.05% or less, Zn: 0.30% or less, Ti: 0.15% or less and having the balance of inevitable impurities and aluminum Beverage can excellent in surface characteristics, characterized in that the surface brightness L * measured using a spectrocolorimeter is 72.5 or more and the color difference value ΔE * is 0 to 1.5. Aluminum alloy plate for the body. 前記組成のアルミニウム合金溶湯から鋳塊を得た後、熱間圧延と冷間圧延と中間焼鈍により作製され、熱間圧延の仕上板厚が2.0〜3.6mmの範囲、冷間圧延の仕上板厚が0.2〜0.27mmの範囲とされ、熱間圧延後の総冷間圧延率が86.5〜94.4%の範囲とされたことを特徴とする請求項1に記載の表面特性に優れる飲料缶ボディ用アルミニウム合金板。   After obtaining an ingot from the molten aluminum alloy having the above composition, it is produced by hot rolling, cold rolling, and intermediate annealing, and the finished sheet thickness of hot rolling is in the range of 2.0 to 3.6 mm. The finished sheet thickness is in the range of 0.2 to 0.27 mm, and the total cold rolling ratio after hot rolling is in the range of 86.5 to 94.4%. Aluminum plate for beverage can bodies with excellent surface characteristics. 質量%でSi:0.40%以下、Fe:0.30%以上0.60%以下、Cu:0.15以上0.50%以下、Mn:0.90以上1.20%以下、Mg:1.00以上1.70%以下、Cr:0.05%以下、Zn:0.30%以下、Ti:0.15%以下を含有し、残部不可避不純物とアルミニウムの組成を有する合金鋳塊を熱間圧延工程により仕上板厚2.0〜3.6mmのアルミニウム合金熱間圧延材を得、次いで冷間圧延工程により熱間圧延後の総冷間圧延率を86.5〜94.4%の範囲として仕上板厚0.20〜0.27mmとし、分光測色計を用いて測定される表面の明度L*が72.5以上で、色差値ΔE*を0〜1.5としたアルミニウム合金冷間圧延材を得ることを特徴とする表面特性に優れる飲料缶ボディ用アルミニウム合金板の製造方法。   In mass%, Si: 0.40% or less, Fe: 0.30% or more and 0.60% or less, Cu: 0.15 or more and 0.50% or less, Mn: 0.90 or more and 1.20% or less, Mg: An alloy ingot containing 1.00 or more and 1.70% or less, Cr: 0.05% or less, Zn: 0.30% or less, Ti: 0.15% or less, and having the balance of inevitable impurities and aluminum An aluminum alloy hot rolled material having a finished sheet thickness of 2.0 to 3.6 mm is obtained by a hot rolling process, and then the total cold rolling ratio after hot rolling is 86.5 to 94.4% by a cold rolling process. The finished plate thickness is 0.20 to 0.27 mm, the surface brightness L * measured using a spectrocolorimeter is 72.5 or more, and the color difference value ΔE * is 0 to 1.5. Aluminum for beverage can bodies with excellent surface properties characterized by obtaining alloy cold-rolled material Manufacturing method of Umm alloy plate.
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