JP2015013940A - Gas purification facility and coal gasification compound power generating unit - Google Patents

Abstract

PROBLEM TO BE SOLVED: To achieve both of impurity removal and collection of COin a dry type gas purification facility.SOLUTION: Steam is obtained by supplying water to a humidifying device 27, and CO is shift reacted with COby the obtained steam in a shift reaction device 28 for collecting CO. Without reducing heat efficiency and complicating the facility, removal of impurities such as a halogen compound, a sulfur constituent, an ammonia component, a mercury and the like, and collection of carbon dioxide (CO) are performed.

Description

  The present invention relates to a gas purification facility and a coal gasification combined power generation facility.

  Coal exists in a large area of the world, has a large recoverable reserve, and has a stable price, so it has a high supply stability and a low price per calorific value. As one type of thermal power generation using coal as a fuel, an integrated coal gasfication combined cycle (IGCC) is known. In coal gasification combined cycle power generation, electric power is obtained by driving a gas turbine using coal gasification gas as fuel, exhaust gas from the gas turbine is recovered to generate steam, and the generated steam drives the steam turbine to generate electric power. (See, for example, Patent Document 1).

  The coal gasification gas generated in the coal gasification furnace contains impurities such as halogen compounds and sulfur compounds (sulfides), impurities that affect the following equipment, and trace components. The fuel gas is obtained by removing impurities from the gasification gas.

  As gas purification equipment, various dry gas purification equipment that suppresses the rise and fall of temperature and pressure and purifies high-temperature coal gasification gas have been studied. By refine | purifying coal gasification gas by dry type, since coal gasification gas can be refine | purified with high temperature, the raise and lower of temperature and pressure can be suppressed, and fuel gas can be obtained.

On the other hand, in coal gasification combined cycle power generation, CO ₂ may be collected in advance in order to reduce CO ₂ discharged by the exhaust gas of the gas turbine. If carbon dioxide is reduced at the stage of the refined coal gasification gas, the absolute amount of CO ₂ contained in the exhaust gas discharged during power generation by the gas turbine is reduced, and CO _{2 is} recovered from the exhaust gas of the gas turbine. There is an advantage that the equipment for collecting CO ₂ can be made smaller than that for performing the process, and the power required for the collection can be reduced.

Under such circumstances, it is actually desired that CO ₂ can be recovered during the gas purification process in the dry gas purification facility. However, in order to recover CO ₂ , it is necessary to use a solvent or the like that absorbs CO _2, and the current situation is that application in a high-temperature dry gas purification facility has not been studied.

JP 2005-171148 A

The present invention has been made in view of the above situation, and it is possible to minimize the decrease in the temperature of the gasification gas without reducing the thermal efficiency and without complicating the facilities, and removing impurities and CO _2. An object of the present invention is to provide a gas purification facility capable of achieving both recovery.

In addition, the present invention has been made in view of the above situation, and it is possible to remove impurities without minimizing a decrease in the temperature of the gasification gas without reducing thermal efficiency and without complicating equipment. possible to achieve both the recovery of CO ₂ and an object thereof is to provide a coal gasification combined cycle power generation plant equipped with a gas purification equipment can.

  In order to achieve the above object, the gas purification equipment of the present invention according to claim 1 comprises a physical filtration means for circulating a gasification gas at a gas temperature exceeding a dew point temperature to remove impurities, and the physical filtration means. The gasification gas from which impurities have been removed is circulated at a gas temperature exceeding the dew point temperature, and the adsorption removal means for adsorbing and removing impurities by an adsorbent, and the gasification gas from which impurities have been removed by the adsorption removal means are represented by a dew point temperature. The catalyst conversion removing means for removing impurities by chemical conversion with a catalyst through circulation at a gas temperature exceeding the temperature, and the humidification by supplying water to the gasification gas from which impurities have been removed by the catalyst conversion removing means to increase the humidity A gas reaction gas that has been humidified by the humidification means, a shift reaction means that shifts carbon monoxide to carbon dioxide, and a gasification gas that has undergone a shift reaction by the shift reaction means. Characterized in that a carbon dioxide recovery means for recovering carbon dioxide.

In the present invention according to claim 1, steam is obtained by supplying water to the high-temperature gasification gas from which impurities have been removed by the catalytic conversion removing means, and carbon monoxide is converted into carbon dioxide by the shift reaction means by the obtained steam. It shifts to carbon and is recovered by carbon dioxide recovery means. For this reason, by reducing the temperature of the gasification gas to the operating temperature of the carbon dioxide recovery means, minimizing the temperature decrease, without reducing the thermal efficiency, and without complicating the equipment, impurities Removal of carbon dioxide and recovery of carbon dioxide (CO ₂ ) can be achieved.

  And the gas purification equipment of this invention which concerns on Claim 2 is equipped with the water-washing means which removes an impurity by washing with water the gasification gas which carried out the shift reaction by the said shift reaction means in the gas purification equipment of Claim 1. The gasification gas from which impurities have been washed by the water washing means is sent to the carbon dioxide recovery means.

  In the present invention according to claim 2, impurities such as ammonia and mercury are washed with water by the water washing means, and the gasification gas in a state where impurities that inhibit the dissolution of carbon dioxide and the like are removed is sent to the carbon dioxide recovery means.

  The gas purification facility of the present invention according to claim 3 is the gas purification facility according to claim 2, wherein the gasification gas subjected to the shift reaction by the shift reaction means is circulated at a gas temperature exceeding the dew point temperature. Reaction removal means for removing impurities by chemical reaction with an absorbent is provided, and gasified gas from which impurities have been removed by the reaction removal means is sent to the water washing means.

  In the present invention according to claim 3, before washing with water, impurities (for example, mercury) can be removed by reacting with an absorbent (for example, an absorbent mainly composed of copper) in a dry environment.

  The gas purification facility of the present invention according to claim 4 is the gas purification facility according to claim 3, further comprising a heat exchanger that cools the gasified gas shifted by the shift reaction means, and the heat exchange The cooling medium of the vessel is a gasification gas after the carbon dioxide is recovered by the carbon dioxide recovery means, and the gasification gas is heated to a predetermined temperature to become a fuel gas.

  In the present invention according to claim 4, even if the gasification gas is cooled in order to recover the carbon dioxide by the carbon dioxide recovery means, the temperature of the fuel gas can be raised without using external thermal energy.

  Further, the gas purification facility of the present invention according to claim 5 is the gas purification facility according to claim 1, wherein the impurities adsorbed and removed by the adsorption removal means include a halogen compound and are removed by the catalytic conversion removal means. The impurities include sulfur compounds. The gas purification facility of the present invention according to claim 6 is the gas purification facility according to claim 3, wherein the impurity removed by the reaction removing means is mercury.

  In the present invention according to claim 5, halogen compounds and sulfur compounds can be removed, and in the present invention according to claim 6, mercury can be removed.

  In order to achieve the above object, a combined coal gasification combined cycle facility according to the present invention includes a coal gasification furnace that generates coal gasification gas by a reaction of coal and an oxidant, and a coal gasification generated in the coal gasification furnace. A gas purification facility according to any one of claims 1 to 6, wherein a gas is purified to obtain a fuel gas, a combustion means for burning the fuel gas obtained by the gas purification facility, and the combustion means A gas turbine that obtains power by expanding the combustion gas of the gas turbine, and a steam turbine that obtains power by expanding the steam obtained by recovering the heat of the exhaust gas of the gas turbine. .

In the present invention according to claim 7, only the temperature of the gasification gas is lowered to the operating temperature of the carbon dioxide recovery means, the temperature drop is minimized, the thermal efficiency is not lowered, and the equipment is complicated. Therefore, it is possible to provide a combined coal gasification combined power generation facility equipped with a gas purification facility capable of achieving both the removal of impurities and the recovery of carbon dioxide (CO ₂ ).

The gas purification facility of the present invention minimizes the decrease in the temperature of the gasification gas, and does not reduce the thermal efficiency and does not complicate the facility, so that both the removal of impurities and the recovery of CO ₂ can be achieved. It becomes possible.

The coal gasification combined cycle power generation facility of the present invention minimizes a decrease in the temperature of the gasification gas, eliminates thermal efficiency, and does not complicate the facility, thereby removing impurities and recovering CO ₂ . It is possible to provide a combined coal gasification combined cycle power generation facility equipped with a gas purification facility capable of achieving both of the above.

1 is a schematic system diagram of a combined coal gasification combined cycle facility according to an embodiment of the present invention. 1 is a schematic system diagram of a gas purification facility according to an embodiment of the present invention. It is a schematic system diagram of the gas purification equipment which concerns on 2nd Example of this invention. It is a schematic system diagram of the gas purification equipment which concerns on 3rd Example of this invention.

The coal gasification combined power generation facility will be described with reference to FIG.
FIG. 1 shows a schematic system for explaining the overall configuration of a combined coal gasification combined power generation facility according to an embodiment of the present invention equipped with a dry gas purification facility.

  The combined coal gasification combined power generation facility 1 shown in the figure includes a coal gasification furnace 2, and a coal gasification gas g is generated in the coal gasification furnace 2 by a reaction between coal and an oxidizing agent (oxygen, air). The coal gasification gas g is dedusted by a dust removing means (not shown), adjusted to a predetermined temperature by the heat exchanger 3, impurities are removed by the dry gas refining equipment 4, and the fuel gas f is obtained.

  The fuel gas f is sent to the combustor 6 of the turbine equipment 5. That is, the turbine equipment 5 includes a compressor 16 and a gas turbine 7, and compressed air and fuel gas f compressed by the compressor 16 are sent to the combustor 6. In the combustor 6, the fuel gas f is combusted, and the combustion gas is sent to the gas turbine 7 and expanded to obtain power. The exhaust gas from the gas turbine 7 is heat recovered by the exhaust heat recovery boiler 8, and after the nitrogen oxide component is removed by the exhaust gas denitration device 9, it is discharged from the chimney 10 to the atmosphere.

  On the other hand, the compressor 16 and the gas turbine 7 and the steam turbine 11 are connected in a coaxial state, and the generator 12 is connected to the steam turbine 11. The exhaust heat recovery boiler 8 is supplied with condensate obtained by condensing the exhaust steam of the steam turbine 11 with a condenser (not shown), and the exhaust heat recovery boiler 8 generates steam by the exhaust gas of the gas turbine 7. The steam generated in the exhaust heat recovery boiler 8 is sent to the steam turbine 11 to obtain power.

  The generator 12 is driven by the power of the gas turbine 7 and the steam turbine 11 connected in series, and combined power generation by the gas turbine 7 and the steam turbine 11 is performed.

  In the coal gasification combined power generation facility 1 described above, the compressed air of the compressor 16 is extracted and supplied as the oxidant of the coal gasification furnace 2. A part of the condensate sent to the exhaust heat recovery boiler 8 is supplied to the heat exchanger 3 to generate steam by heat exchange with the coal gasification gas, and the generated steam is sent to the steam turbine 11. For this reason, a part of the compressed air of the turbine equipment 5 is used as an oxidant, and the output of the steam turbine 11 can be obtained with the steam generated from the exhaust heat recovery boiler 8 and the heat exchanger 3.

  In the combined coal gasification combined power generation facility 1 having the above-described configuration, the coal gasification gas g is purified by the dry gas refining facility 4 by dry refining to obtain the fuel gas f.

  A specific configuration of the dry gas purification equipment 4 will be described with reference to FIG. FIG. 2 shows a system for explaining a specific configuration of the dry gas purification facility.

Solid impurities are removed from the coal gasification gas g adjusted to a predetermined temperature by the heat exchanger 3 of the coal gasification furnace 2 by the dust filter 19. The coal gasification gas g from which solid impurities have been removed is sent to the halide removing device 21 at about 450 ° C. (an operating temperature exceeding the dew point). In the halide removing device 21, sodium aluminate (NaAlO ₂ ), which is a sodium-based halide absorbent, is used as an alkali-based material in the form of pellets, and halides such as hydrogen chloride (HCl) and hydrogen fluoride ( HF) is removed simultaneously.

The coal gasification gas g from which the halide has been removed by the halide removing device 21 is sent to the desulfurization device 22 at about 450 ° C. (an operating temperature exceeding the dew point). In the desulfurization apparatus 22, a zinc ferrite desulfurization agent, which is a dry desulfurization agent, is used in a honeycomb shape, and hydrogen sulfide (H ₂ S) or carbonyl sulfide is brought into contact with the zinc ferrite desulfurization agent by contacting the coal gasification gas g. (COS) and the like are removed to a very low concentration. Since the zinc ferrite desulfurizing agent itself has the function of a hydrogenation catalyst, the performance can be exerted on organic sulfur compounds including carbonyl sulfide (COS).

The coal gasification gas g from which the sulfide has been removed is sent to a humidifier 27 as a humidifying means, and water is supplied to the coal gasification gas g to make a steam gas at about 300 ° C. (Moistened). The water vapor gas is sent to the shift reaction device 28, and carbon monoxide (CO) is shift-reacted to carbon dioxide (CO ₂ ). That is, the following reaction occurs in the shift reaction device 28.
CO + H ₂ O → H ₂ + CO ₂

The gas in which CO is changed to CO ₂ by the shift reaction is cooled by a heat exchanger (gas gas heater) 29 to about 40 ° C. As the refrigerant of the heat exchanger 29, a gas after CO ₂ has been absorbed by a CO ₂ absorption tower 32 as a carbon dioxide recovery means described later is used.

The gas cooled to about 40 ° C. by the heat exchanger 29 is washed with water by a washing tower 31 as a water washing means, and impurities that inhibit the dissolution of CO ₂ , such as ammonia and mercury, are washed away and removed. Gas which has been washed in the washing tower 31 CO ₂ is absorbed in the absorber the CO ₂ absorber 32 (e.g., CO ₂ is dissolved in a solvent), CO ₂ which is absorbed by the CO ₂ absorber 32 is collected to the outside Is done.

The gas from which CO ₂ has been removed (about 20 ° C.) is heated to a fuel gas f of about 280 ° C. by the heat exchanger 29, and the high-temperature fuel gas f is sent to the combustor 6 of the turbine equipment 5.

For this reason, it becomes possible to refine | purify the coal gasification gas g by a dry type in consideration of the influence with respect to the raise / lower of temperature and pressure, and the influence of the impurity to a subsequent apparatus. Then, CO ₂ can be recovered in the gas purification process.

Therefore, even in a high-temperature dry gas purification facility, it is possible to remove impurities without minimizing the decrease in the temperature of the coal gasification gas g without reducing the thermal efficiency and without complicating the facility. Carbon dioxide (CO ₂ ) can be recovered at the same time.

A second embodiment of the dry gas purification facility 4 will be described with reference to FIG.
FIG. 3 shows a system for explaining a specific configuration of the dry gas purification facility according to the second embodiment. In addition, the same code | symbol is attached | subjected to the same member as the structural member of the installation shown in FIG. 2, and the overlapping description is abbreviate | omitted.

  The second embodiment shown in FIG. 3 is different from the embodiment shown in FIG. 2 in that a mercury removing device 34 for removing mercury at an operating temperature exceeding the dew point is provided between the heat exchanger 29 and the washing tower 31. ing. In the mercury removing device 34, a copper-based absorbent that absorbs mercury mainly using copper is used, and mercury is absorbed and removed by bringing the coal-based absorbent g into contact with the copper-based absorbent at about 120 ° C.

The gas from which mercury has been removed by the mercury removing device 34 is washed with water by the washing tower 31, and impurities that inhibit the dissolution of CO ₂ , such as ammonia, are washed away and removed. Gas which has been washed in the washing tower 31 CO ₂ is absorbed in the absorber the CO ₂ absorber 32 (e.g., CO ₂ is dissolved in a solvent), CO ₂ which is absorbed by the CO ₂ absorber 32 is collected to the outside Is done.

For this reason, before washing with water, it is possible to recover the carbon dioxide (CO ₂ ) by removing mercury absorbed by the absorbent in a dry environment.

A third embodiment of the dry gas purification facility 4 will be described with reference to FIG.
FIG. 4 shows a system for explaining a specific configuration of the dry gas purification facility according to the third embodiment. In addition, the same code | symbol is attached | subjected to the same member as the structural member of the installation shown in FIG. 2, FIG. 3, and the overlapping description is abbreviate | omitted.

  The third embodiment shown in FIG. 4 is different from the embodiment shown in FIG. 2 in that an ammonia decomposing apparatus 35 that decomposes and removes ammonia at an operating temperature above the dew point between the desulfurization apparatus 22 and the humidifier 27, and A mercury removing device 34 is provided for removing mercury at an operating temperature above the dew point.

  The coal gasification gas g from which the sulfide has been removed by the desulfurization device 22 is heat-exchanged from about 450 ° C. to about 250 ° C. by the first heat exchanger 37 and sent to the ammonia decomposition device 35. As the heat exchange medium of the first heat exchanger 37, a gas after heat exchange (temperature increase: about 230 ° C.) by a second heat exchanger 38 described later is used.

In the ammonia decomposing apparatus 35, the ammonia gas component is decomposed at a coal gasification gas g of about 250 ° C. (operating temperature exceeding the dew point), and, for example, a gas of about 350 ° C. is obtained by the exothermic reaction, and the second heat exchange It is sent to the vessel 38 and cooled to 220 ° C. In the ammonia decomposing apparatus 35, the Ni / Al ₂ O ₃ catalyst is formed into a pellet and used, and the ammonia component contained in the coal gasification gas g is decomposed into nitrogen (N ₂ ).

  The gas cooled to 220 ° C. in the second heat exchanger 38 is sent to the feed water heater 39 to be used as a heat medium for water (utilized for heating water). The gas that has been used as a heat medium for water by the feed water heater 39 and cooled to 120 ° C. is sent to the mercury removing device 34, and the mercury is removed by the mercury removing device 34 to obtain a gas at 100 ° C.

  As the refrigerant of the second heat exchanger 38, the gas at about 100 ° C. after the mercury is removed by the mercury removing device 34 is used, and the gas at about 100 ° C. after the mercury is removed by the mercury removing device 34 is The temperature is raised to about 230 ° C. in the second heat exchanger 38 by the gas at about 350 ° C. after decomposing the ammonia component.

The gas heated to about 230 ° C. by the second heat exchanger 38 is sent to the first heat exchanger 37, heated to 430 ° C. and sent to the humidifier 27. Water heated in the vessel 39 is supplied to the gas to be steam gas at about 280 ° C. (humidified). Thereafter, a shift reaction is performed in the shift reaction device 28, and the remaining ammonia and mercury are washed away with water in the washing tower 31 to be removed, CO ₂ is removed and recovered, and a fuel gas f of about 260 ° C. is supplied to the turbine equipment 5. It is sent to the combustor 6.

For this reason, before washing with water, it becomes possible to remove ammonia and mercury in a dry environment and recover carbon dioxide (CO ₂ ).

The above-described dry gas purification equipment 4 minimizes the decrease in the temperature of the gasification gas, reduces the thermal efficiency, and does not complicate the equipment. Halogen compounds, sulfur components, ammonia components, mercury It is possible to achieve both the removal of impurities such as CO _{2 and} the recovery of CO ₂ .

And in coal gasification combined cycle power generation equipment, the reduction of the temperature of gasification gas is minimized, and the removal of impurities and the recovery of CO ₂ are performed without reducing the thermal efficiency and without complicating the equipment. It becomes possible to make the combined coal gasification combined power generation facility 1 provided with the dry gas purification facility 4 that can be made compatible.

  The present invention can be used in the industrial fields of gas purification facilities and coal gasification combined power generation facilities.

DESCRIPTION OF SYMBOLS 1 Coal gasification combined cycle power generation equipment 2 Coal gasification furnace 3 Heat exchanger 4 Dry-type gas purification equipment 5 Turbine equipment 6 Combustor 7 Gas turbine 8 Waste heat recovery boiler 9 Flue gas denitrification device 10 Chimney 11 Steam turbine 12 Generator 16 Compression Machine 19 Dust filter 21 Halide removal device 22 Desulfurization device 27 Humidifier 28 Shift reaction device 29 Heat exchanger 31 Washing tower 32 CO ₂ absorption tower 34 Mercury removal device 35 Ammonia decomposition device 37 First heat exchanger 38 Second heat Exchanger 39 Feed water heater

Claims (7)

Physical filtration means for removing impurities by circulating gasified gas at a gas temperature exceeding the dew point temperature;
A gasification gas from which impurities have been removed by the physical filtration means, and a gas removal gas that circulates at a gas temperature exceeding the dew point temperature and adsorbs and removes the impurities by an adsorbent;
Gasification gas from which impurities have been removed by the adsorption removal means is circulated at a gas temperature exceeding the dew point temperature, and catalytic conversion removal means for removing impurities by chemical conversion with a catalyst;
Humidification means for supplying water to the gasification gas from which impurities have been removed by the catalyst conversion removal means to increase the humidity;
A shift reaction means for causing the gasification gas that has been humidified by the humidification means to flow and for causing a shift reaction of carbon monoxide to carbon dioxide;
A gas purification facility comprising carbon dioxide recovery means for recovering carbon dioxide from the gasification gas subjected to the shift reaction by the shift reaction means. The gas purification facility according to claim 1,
It comprises water washing means for removing impurities by washing the gasification gas that has undergone a shift reaction by the shift reaction means, and the gasification gas from which impurities have been washed by the water washing means is sent to the carbon dioxide recovery means. Gas purification equipment. The gas purification facility according to claim 2,
The gasification gas subjected to the shift reaction by the shift reaction means is circulated at a gas temperature exceeding the dew point temperature and chemically reacted with the absorbent to provide a reaction removal means for removing impurities, and the reaction removal means removes impurities. A gas purification facility characterized in that the gasified gas sent to the water washing means. In the gas purification equipment according to claim 3,
A heat exchanger that cools the gasification gas that has undergone a shift reaction by the shift reaction means;
The cooling medium of the heat exchanger is
A gas purification facility, which is a gasification gas after carbon dioxide is recovered by the carbon dioxide recovery means, and the gasification gas is heated to a predetermined temperature to become a fuel gas. The gas purification facility according to claim 1,
The gas purification facility characterized in that the impurities removed by adsorption by the adsorption removal means include a halogen compound, and the impurities removed by the catalyst conversion removal means contain a sulfur compound. In the gas purification equipment according to claim 3,
The gas purification facility characterized in that the impurity removed by the reaction removing means is mercury. A coal gasifier that generates coal gasification gas by reaction of coal and oxidant;
The gas purification equipment according to any one of claims 1 to 6, wherein a fuel gas is obtained by refining the coal gasification gas generated in the coal gasification furnace,
Combustion means for burning the fuel gas obtained in the gas purification facility;
A gas turbine that obtains power by expanding combustion gas from the combustion means;
A coal gasification combined power generation facility comprising: a steam turbine that obtains power by expanding steam obtained by recovering heat of exhaust gas of the gas turbine.

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