JP2014511259A5 - - Google Patents
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- JP2014511259A5 JP2014511259A5 JP2013549930A JP2013549930A JP2014511259A5 JP 2014511259 A5 JP2014511259 A5 JP 2014511259A5 JP 2013549930 A JP2013549930 A JP 2013549930A JP 2013549930 A JP2013549930 A JP 2013549930A JP 2014511259 A5 JP2014511259 A5 JP 2014511259A5
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- mass
- catalyst
- production method
- particles
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- 238000004519 manufacturing process Methods 0.000 claims 12
- 239000003054 catalyst Substances 0.000 claims 10
- 239000002245 particle Substances 0.000 claims 10
- 150000001875 compounds Chemical class 0.000 claims 9
- 239000002243 precursor Substances 0.000 claims 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 229910052746 lanthanum Inorganic materials 0.000 claims 4
- 238000000197 pyrolysis Methods 0.000 claims 4
- 229910052718 tin Inorganic materials 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 229910052792 caesium Inorganic materials 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 239000000443 aerosol Substances 0.000 claims 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims 2
- OFYFURKXMHQOGG-UHFFFAOYSA-J 2-ethylhexanoate;zirconium(4+) Chemical compound [Zr+4].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O OFYFURKXMHQOGG-UHFFFAOYSA-J 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 claims 1
Claims (14)
（ｉ）二酸化ジルコニウムの前駆体化合物及び任意に酸化ケイ素の前駆体化合物を含有する溶液を調製する工程、
（ｉｉ）溶液をエアロゾルに変換する工程、
（ｉｉｉ）エアロゾルを、直接的又は間接的に加熱された熱分解領域に供給する工程、
（ｉｖ）熱分解を実行する工程、及び
（ｖ）熱分解ガスから生成される触媒担体粒子を分離する工程、
を含むことを特徴とする製造方法。 A process for producing catalyst support particles comprising zirconium dioxide and optionally silicon oxide,
(I) preparing a solution containing a zirconium dioxide precursor compound and optionally a silicon oxide precursor compound;
(Ii) converting the solution into an aerosol;
(Iii) supplying the aerosol to a directly or indirectly heated pyrolysis zone;
(Iv) a step of performing pyrolysis, and (v) a step of separating the catalyst carrier particles generated from the pyrolysis gas,
The manufacturing method characterized by including.
請求項１〜８の何れか１項に記載の工程（ｉ）〜（ｖ）を有し、
さらに、
（ｖｉ）白金及びスズ、並びにランタン及びセシウムから選択される一種以上の他の元素の化合物を含有する一種以上の溶媒で、生成された触媒担体粒子を含浸する工程と、
（ｖｉｉ）含浸された触媒担体粒子を乾燥及び焼成する工程と、
を有することを特徴とする製造方法。 A method for producing catalyst particles comprising a compound of one or more other elements selected from platinum and tin, and lanthanum and cesium on a zirconium dioxide-containing support,
It has process (i)-(v) of any one of Claims 1-8,
further,
(Vi) impregnating the produced catalyst support particles with one or more solvents containing a compound of one or more other elements selected from platinum and tin, and lanthanum and cesium;
(Vii) drying and calcining the impregnated catalyst support particles;
The manufacturing method characterized by having.
少なくともＳｎ、及び少なくともＬａ又はＣｓを含有する請求項１１〜１３の何れか１項に記載の触媒粒子。 30 to 99.5% by mass of ZrO 2 and 0.5 to 25% by mass of SiO 2 as a carrier, and 0.1 to 1% by mass of Pt, 0.1 to 10% by mass with respect to the mass of the carrier Sn, La, and / or Cs
The catalyst particle according to any one of claims 11 to 13, containing at least Sn and at least La or Cs.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11151958 | 2011-01-25 | ||
| EP11151958.3 | 2011-01-25 | ||
| PCT/IB2012/050303 WO2012101567A2 (en) | 2011-01-25 | 2012-01-23 | Catalyst support produced by flame spray pyrolysis and catalyst for autothermal propane dehydrogenation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014511259A JP2014511259A (en) | 2014-05-15 |
| JP2014511259A5 true JP2014511259A5 (en) | 2015-03-12 |
Family
ID=46581216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013549930A Withdrawn JP2014511259A (en) | 2011-01-25 | 2012-01-23 | Catalyst support from spray flame pyrolysis and autothermal propane dehydrogenation catalyst |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2667968A2 (en) |
| JP (1) | JP2014511259A (en) |
| KR (1) | KR20140006909A (en) |
| CN (1) | CN103379957A (en) |
| BR (1) | BR112013019047A2 (en) |
| WO (1) | WO2012101567A2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8933262B2 (en) | 2011-05-24 | 2015-01-13 | Basf Se | Process for preparing polyisocyanates from biomass |
| CN103566933B (en) * | 2012-08-08 | 2016-09-07 | 中国石油化工股份有限公司 | A kind of acetate preparation of ethanol by hydrogenating catalyst and preparation method thereof |
| CN104248953A (en) * | 2013-06-28 | 2014-12-31 | 中国石油化工股份有限公司 | Catalyst for preparation of ethanol by acetate hydrogenation and preparation method thereof |
| KR101814451B1 (en) | 2015-11-10 | 2018-01-04 | 희성촉매 주식회사 | A stabilized active metal complex based catalyst for dehydrogenation of straight-chain hydrocarbons |
| KR101716170B1 (en) | 2015-11-10 | 2017-03-14 | 희성촉매 주식회사 | A stabilized active metal complex based catalyst for dehydrogenation of light straight-chain hydrocarbons |
| CN106753391A (en) * | 2016-11-28 | 2017-05-31 | 新沂市中诺新材料科技有限公司 | A kind of nano material and preparation method for being passivated heavy metal in rehabilitating soil |
| CN111821996B (en) * | 2019-04-18 | 2022-11-29 | 清华大学 | Efficient hydrothermal-resistant and sulfur-resistant demercuration catalyst and preparation method and application thereof |
| CN115069246B (en) * | 2021-03-15 | 2023-08-15 | 中国石油化工股份有限公司 | Supported silver catalyst and preparation method and application thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3701805A (en) * | 1971-09-27 | 1972-10-31 | Pfizer | Preparation of citraconic and itaconic acids |
| US6057030A (en) * | 1997-07-21 | 2000-05-02 | Kanebo Ltd. | Porous ceramic body and kiln furniture made from a porous ceramic body |
| DE19937107A1 (en) * | 1999-08-06 | 2001-02-08 | Basf Ag | Catalyst with bimodal pore radius distribution |
| CN1513600A (en) * | 2003-08-19 | 2004-07-21 | 丁章云 | Catalyst active carrier and preparation thereof |
| CN101204654A (en) * | 2006-12-20 | 2008-06-25 | 中国科学院生态环境研究中心 | Supported noble metal catalyst for low-temperature catalytic oxidation benzene series and preparation method thereof |
| CN101433863B (en) * | 2007-11-15 | 2012-08-29 | 中国石油化工股份有限公司 | Composite oxide carrier and preparation method thereof |
-
2012
- 2012-01-23 WO PCT/IB2012/050303 patent/WO2012101567A2/en active Application Filing
- 2012-01-23 BR BR112013019047A patent/BR112013019047A2/en not_active IP Right Cessation
- 2012-01-23 KR KR1020137022258A patent/KR20140006909A/en not_active Application Discontinuation
- 2012-01-23 EP EP12739435.1A patent/EP2667968A2/en not_active Withdrawn
- 2012-01-23 CN CN2012800086618A patent/CN103379957A/en active Pending
- 2012-01-23 JP JP2013549930A patent/JP2014511259A/en not_active Withdrawn
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