JP2014506381A5 - - Google Patents

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JP2014506381A5
JP2014506381A5 JP2013546211A JP2013546211A JP2014506381A5 JP 2014506381 A5 JP2014506381 A5 JP 2014506381A5 JP 2013546211 A JP2013546211 A JP 2013546211A JP 2013546211 A JP2013546211 A JP 2013546211A JP 2014506381 A5 JP2014506381 A5 JP 2014506381A5
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graphene
energy storage
storage device
carbon
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Priority claimed from US12/930,294 external-priority patent/US8859143B2/en
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（ａ）そこにリチウムを取り込み又は貯蔵し得る表面積を有するカソード活性材料を含むカソードと、
（ｂ）そこにリチウムを取り込み又は貯蔵し得る表面積を有するアノード活性材料を含むアノードと、
（ｃ）上記２つの電極間に配置された多孔性セパレータと、
（ｄ）上記２つの電極と物理的に接触するリチウム含有電解質とを備え、
前記アノード活性材料及び／又は前記カソード活性材料は、そこからリチウムイオンを受け取り又はそこにリチウムイオンを提供するために、前記電解質と直接物理的に接触する１００ｍ２／ｇ以上の比表面積を有し、
前記アノード活性材料及び前記カソード活性材料の一方又は両方は機能化され、前記２つの電極の少なくとも一方は、前記エネルギー貯蔵装置の最初の充電又は最初の放電サイクルの前にリチウム源を含むことを特徴とする表面媒介リチウムイオン交換エネルギー貯蔵装置。 (A) a cathode comprising a cathode active material having a surface area capable of taking up or storing lithium therein;
(B) an anode comprising an anode active material having a surface area capable of taking up or storing lithium therein;
(C) a porous separator disposed between the two electrodes;
(D) comprising a lithium-containing electrolyte in physical contact with the two electrodes,
The anode active material and / or the cathode active material has a specific surface area of 100 m 2 / g or more that is in direct physical contact with the electrolyte to receive or provide lithium ions thereto. ,
One or both of the anode active material and the cathode active material are functionalized, and at least one of the two electrodes includes a lithium source prior to the first charge or first discharge cycle of the energy storage device. Surface mediated lithium ion exchange energy storage device. 前記装置が充電状態にある場合には、前記リチウムの少なくとも８０％は、前記アノード活性材料の表面上に貯蔵され、前記アノード表面と直接接触し、前記装置が放電状態にある場合には、前記リチウムの少なくとも８０％は、前記カソード活性材料の表面上に貯蔵され、前記カソード表面と直接接触することを特徴とする請求項１に記載のエネルギー貯蔵装置。   When the device is in a charged state, at least 80% of the lithium is stored on the surface of the anode active material and is in direct contact with the anode surface, and when the device is in a discharged state, the The energy storage device of claim 1, wherein at least 80% of the lithium is stored on the surface of the cathode active material and is in direct contact with the cathode surface. 前記電解質は、初期量のリチウムイオンを含む液状電解質又はゲル状電解質であることを特徴とする請求項１に記載のエネルギー貯蔵装置。   The energy storage device according to claim 1, wherein the electrolyte is a liquid electrolyte or a gel electrolyte containing an initial amount of lithium ions. 前記アノード活性材料は、前記装置が作動している際には、リチウムでインターカレートされず又はデインターカレートされないことを特徴とする請求項１に記載のエネルギー貯蔵装置。   The energy storage device of claim 1, wherein the anode active material is not intercalated or deintercalated with lithium when the device is in operation. 前記装置は、１．０ボルト〜４．５ボルトの電圧範囲で作動することを特徴とする請求項１に記載のエネルギー貯蔵装置。   The energy storage device of claim 1, wherein the device operates in a voltage range of 1.0 volts to 4.5 volts. 前記２つの電極の少なくとも一方は、５００ｍ２／ｇ以上の、前記電解質と直接接触する比表面積を有することを特徴とする請求項１に記載のエネルギー貯蔵装置。 2. The energy storage device according to claim 1, wherein at least one of the two electrodes has a specific surface area in direct contact with the electrolyte of 500 m 2 / g or more. 前記装置が充電状態にある場合には、前記リチウムの２０％以下は、前記アノード活性材料のバルク中に貯蔵され、前記装置が放電状態にある場合には、前記リチウムの２０％以下は、前記カソード活性材料のバルク中に貯蔵されることを特徴とする請求項１に記載のエネルギー貯蔵装置。   When the device is in a charged state, no more than 20% of the lithium is stored in the bulk of the anode active material, and when the device is in a discharged state, no more than 20% of the lithium is The energy storage device of claim 1, wherein the energy storage device is stored in a bulk of the cathode active material. 前記装置の操作は、リチウムインターカレーション又はデインターカレーションを含まないことを特徴とする請求項１に記載のエネルギー貯蔵装置。   The energy storage device according to claim 1, wherein the operation of the device does not include lithium intercalation or deintercalation. 前記アノード活性材料は、リチウムで前処理されることを特徴とする請求項１に記載のエネルギー貯蔵装置。   The energy storage device of claim 1, wherein the anode active material is pretreated with lithium. 前記アノード活性材料は、
（ａ）ソフトカーボン、ハードカーボン、重合性カーボン又は炭化樹脂、メソフューズカーボン、コークス、炭化ピッチ、カーボンブラック、活性炭又は部分グラファイト化カーボンから選択される多孔性不規則カーボン材料、
（ｂ）グラフェンの単層シート又は多層プレートレット、酸化グラフェン、フッ化グラフェン、水酸化グラフェン、窒化グラフェン、ホウ素ドープグラフェン、窒素トープグラフェン、あるいは、化学的又は熱的還元酸化グラフェンから選択されるグラフェン材料、
（ｃ）剥離グラファイト、
（ｄ）メソ多孔性カーボン、
（ｅ）単壁カーボンナノチューブ又は多壁カーボンナノチューブから選択されるカーボンナノチューブ、
（ｆ）カーボンナノファイバ、金属ナノワイヤ、金属酸化物ナノワイヤ又はファイバ、あるいは、伝導性ポリマーナノファイバ、
（ｇ）カルボニル含有勇気又は重合性分子、
（ｈ）カルボニル基、カルボキシル基又はアミノ基を含む機能化グラフェン材料、
（ｉ）これらの組み合わせ
から選択されることを特徴とする請求項１に記載のエネルギー貯蔵装置。 The anode active material is
(A) a porous irregular carbon material selected from soft carbon, hard carbon, polymerizable carbon or carbonized resin, mesofuse carbon, coke, carbonized pitch, carbon black, activated carbon or partially graphitized carbon;
(B) Graphene selected from graphene single-layer sheets or multilayer platelets, graphene oxide, graphene fluoride, graphene hydroxide, graphene nitride, boron-doped graphene, nitrogen-top graphene, or chemically or thermally reduced graphene oxide material,
(C) Exfoliated graphite,
(D) mesoporous carbon,
(E) a carbon nanotube selected from single-walled carbon nanotubes or multi-walled carbon nanotubes,
(F) carbon nanofibers, metal nanowires, metal oxide nanowires or fibers, or conductive polymer nanofibers,
(G) a carbonyl-containing courage or polymerizable molecule,
(H) a functionalized graphene material containing a carbonyl group, a carboxyl group or an amino group,
(I) The energy storage device according to claim 1, wherein the energy storage device is selected from a combination thereof. 前記カソード活性材料は、
（ａ）ソフトカーボン、ハードカーボン、重合性カーボン又は炭化樹脂、メソフューズカーボン、コークス、炭化ピッチ、カーボンブラック、活性炭又は部分グラファイト化カーボンから選択される多孔性不規則カーボン材料、
（ｂ）グラフェンの単層シート又は多層プレートレット、酸化グラフェン、フッ化グラフェン、水酸化グラフェン、窒化グラフェン、ホウ素ドープグラフェン、窒素トープグラフェン、機能化グラフェン又は還元酸化グラフェンから選択されるグラフェン材料、
（ｃ）剥離グラファイト、
（ｄ）メソ多孔性カーボン、
（ｅ）単壁カーボンナノチューブ又は多壁カーボンナノチューブから選択されるカーボンナノチューブ、
（ｆ）カーボンナノファイバ、金属ナノワイヤ、金属酸化物ナノワイヤ又はファイバ、あるいは、伝導性ポリマーナノファイバ、
（ｇ）これらの組み合わせ、
（ｈ）カルボニル含有勇気又は重合性分子、
（ｉ）カルボニル基、カルボキシル基又はアミノ基を含む機能化グラフェン、
（ｊ）これらの組み合わせ
から選択されることを特徴とする請求項１に記載のエネルギー貯蔵装置。 The cathode active material is
(A) a porous irregular carbon material selected from soft carbon, hard carbon, polymerizable carbon or carbonized resin, mesofuse carbon, coke, carbonized pitch, carbon black, activated carbon or partially graphitized carbon;
(B) a graphene material selected from a single layer sheet or multilayer platelet of graphene, graphene oxide, graphene fluoride, graphene hydroxide, graphene nitride, boron-doped graphene, nitrogen-topped graphene, functionalized graphene or reduced graphene oxide,
(C) Exfoliated graphite,
(D) mesoporous carbon,
(E) a carbon nanotube selected from single-walled carbon nanotubes or multi-walled carbon nanotubes,
(F) carbon nanofibers, metal nanowires, metal oxide nanowires or fibers, or conductive polymer nanofibers,
(G) a combination of these,
(H) a carbonyl-containing courage or polymerizable molecule,
(I) a functionalized graphene containing a carbonyl group, a carboxyl group or an amino group,
(J) The energy storage device according to claim 1, wherein the energy storage device is selected from these combinations. 前記アノード活性材料又はカソード活性材料は、官能基を有しないグラフェン材料であることを特徴とする請求項１１に記載のエネルギー貯蔵装置。 The energy storage device according to claim 11 , wherein the anode active material or the cathode active material is a graphene material having no functional group. 機能的材料は、ポリ（２，５−ハイドロキシ−１，４−ベンゾキノン−３，６−メチレン）、ＬｉｘＣ６Ｏ６（ｘ＝１〜３）、Ｌｉ２（Ｃ６Ｈ２Ｏ４）、Ｌｉ２Ｃ８Ｈ４Ｏ４（Ｌｉテレフタレート）、Ｌｉ２Ｃ６Ｈ４Ｏ４（Ｌｉトランス−トランス−ムコネート）、３，４，９，１０−ペリレンテトラカルボン酸二無水物（ＰＴＣＤＡ）硫化物ポリマー、ＰＴＣＤＡ、１，４，５，８，−ナフタレン−テトラカルボン酸二無水物（ＮＴＣＤＡ）、ベンゼン−１，２，４，５−テトラカルボン酸二無水物、１，４，５，８−テトラ無水アントラキノン、テトラ無水−ｐ−ベンゾキノン及びこれらの組み合わせの一群から選択されることを特徴とする請求項１１に記載のエネルギー貯蔵装置。 Functional materials are poly (2,5-hydroxy-1,4-benzoquinone-3,6-methylene), Li x C 6 O 6 (x = 1 to 3), Li 2 (C 6 H 2 O 4 ). , Li 2 C 8 H 4 O 4 (Li terephthalate), Li 2 C 6 H 4 O 4 (Li trans-trans-muconate), 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) sulfide Polymer, PTCDA, 1,4,5,8, -naphthalene-tetracarboxylic dianhydride (NTCDA), benzene-1,2,4,5-tetracarboxylic dianhydride, 1,4,5,8 12. The energy storage device according to claim 11 , wherein the energy storage device is selected from the group consisting of: -tetraanhydroanthraquinone, tetraanhydro-p-benzoquinone and combinations thereof. 機能的材料は、ポリ（２，５−ハイドロキシ−１，４−ベンゾキノン−３，６−メチレン）、ＬｉｘＣ６Ｏ６（ｘ＝１〜３）、Ｌｉ２（Ｃ６Ｈ２Ｏ４）、Ｌｉ２Ｃ８Ｈ４Ｏ４（Ｌｉテレフタレート）、Ｌｉ２Ｃ６Ｈ４Ｏ４（Ｌｉトランス−トランス−ムコネート）、３，４，９，１０−ペリレンテトラカルボン酸二無水物（ＰＴＣＤＡ）硫化物ポリマー、ＰＴＣＤＡ、１，４，５，８，−ナフタレン−テトラカルボン酸二無水物（ＮＴＣＤＡ）、ベンゼン−１，２，４，５−テトラカルボン酸二無水物、１，４，５，８−テトラ無水アントラキノン、テトラ無水−ｐ−ベンゾキノン及びこれらの組み合わせの一群から選択され、この機能的材料は、ナノグラフェン、カーボンナノチューブ、不規則カーボン、ナノグラファイト、金属ナノワイヤ、伝導性ナノワイヤ、カーボンナノファイバ、重合性ナノファイバから選択されるナノ構造材料と組み合わされ又はナノ構造材料により支持されることを特徴とする請求項１１に記載のエネルギー貯蔵装置。 Functional materials are poly (2,5-hydroxy-1,4-benzoquinone-3,6-methylene), Li x C 6 O 6 (x = 1 to 3), Li 2 (C 6 H 2 O 4 ). , Li 2 C 8 H 4 O 4 (Li terephthalate), Li 2 C 6 H 4 O 4 (Li trans-trans-muconate), 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) sulfide Polymer, PTCDA, 1,4,5,8, -naphthalene-tetracarboxylic dianhydride (NTCDA), benzene-1,2,4,5-tetracarboxylic dianhydride, 1,4,5,8 -Selected from the group of tetraanhydroanthraquinone, tetraanhydro-p-benzoquinone and combinations thereof, this functional material comprising nanographene, carbon nanotubes, disordered carbon, nanographs Ito, metal nanowires, conductive nanowires, carbon nanofibers, energy storage device according to claim 11, characterized in that it is supported by the combination with nanostructured material selected from a polymerizable nanofibers or nanostructured material. 前記アノード活性材料又は前記カソード活性材料は、純粋なグラフェン、フッ化グラフェン、水酸化グラフェン、窒化グラフェン、ホウ素ドープグラフェン、窒素ドープグラフェン、あるいは、化学的又は熱的還元酸化グラフェンの単層シート又は多層プレートレットから選択される非機能化グラフェン材料であることを特徴とする請求項１２に記載のエネルギー貯蔵装置。 The anode active material or the cathode active material may be pure graphene, graphene fluoride, graphene hydroxide, graphene nitride, boron-doped graphene, nitrogen-doped graphene, or a single layer sheet or multilayer of chemically or thermally reduced graphene oxide 13. The energy storage device according to claim 12 , wherein the energy storage device is a non-functionalized graphene material selected from platelets. 前記機能的材料の少なくとも１つは、Ｒは炭化水素であり、−ＣＯＯＨ、＝Ｏ、−ＮＨ２、−ＯＲ、−ＣＯＯＲ、これらの組み合わせから選択される官能基を有することを特徴とする請求項１に記載のエネルギー貯蔵装置。 According at least one of the functional material, R is a hydrocarbon, the -COOH, = O, -NH 2, -OR, -COOR, and having a functional group selected from these combinations Item 4. The energy storage device according to Item 1. 前記電極での取り込み又は貯蔵は、前記活性材料の表面上におけるグラフェン本体との相互作用を含むことを特徴とする請求項１に記載のエネルギー貯蔵装置。 Uptake or storage at the electrode, the energy storage device according to claim 1, characterized in that it comprises the interaction of graphene body on the surface of the active material. 前記電極は、カソードであることを特徴とする請求項１７に記載のエネルギー貯蔵装置。
The energy storage device according to claim 17 , wherein the electrode is a cathode.
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Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US12/928,927 2010-12-23
US12/928,927 US9166252B2 (en) 2010-12-23 2010-12-23 Surface-controlled lithium ion-exchanging energy storage device
US12/930,294 US8859143B2 (en) 2011-01-03 2011-01-03 Partially and fully surface-enabled metal ion-exchanging energy storage devices
US12/930,294 2011-01-03
US13/199,450 2011-08-30
US13/199,450 US8889298B2 (en) 2011-08-30 2011-08-30 Surface-mediated lithium ion-exchanging energy storage device
PCT/US2011/064827 WO2012087698A1 (en) 2010-12-23 2011-12-14 Surface-mediated lithium ion-exchanging energy storage device

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Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2012378149B2 (en) 2011-12-21 2016-10-20 The Regents Of The University Of California Interconnected corrugated carbon-based network
AU2013230195B2 (en) 2012-03-05 2017-04-20 The Regents Of The University Of California Capacitor with electrodes made of an interconnected corrugated carbon-based network
DE102012005348A1 (en) * 2012-03-16 2013-09-19 Li-Tec Battery Gmbh Graphene-based separator for lithium-ion batteries
CN103794756A (en) * 2012-11-02 2014-05-14 海洋王照明科技股份有限公司 Lithium-pre-embedded graphene pole piece, preparation method thereof and applications thereof
EP2747175B1 (en) * 2012-12-21 2018-08-15 Belenos Clean Power Holding AG Self-assembled composite of graphene oxide and H4V3O8
US20150380176A1 (en) * 2013-02-08 2015-12-31 Lg Electronics Inc. Graphene lithium ion capacitor
KR102151663B1 (en) * 2013-03-04 2020-09-04 세키스이가가쿠 고교가부시키가이샤 Fine grain-flaked graphite composite body, lithium-ion secondary battery negative electrode material, manufacturing method for same, and lithium-ion secondary battery
CN104282918B (en) * 2013-07-02 2018-04-10 中国科学院上海硅酸盐研究所 Lithium-air battery negative electrode, lithium-air battery and the method for preparing lithium-air battery electrode
JP2017522725A (en) 2014-06-16 2017-08-10 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア Hybrid electrochemical cell
CN105336916A (en) * 2014-06-20 2016-02-17 东莞新能源科技有限公司 Lithium ion battery pole piece and preparation method thereof
JP6454740B2 (en) * 2014-07-08 2019-01-16 カーディアック ペースメイカーズ， インコーポレイテッド Method for stabilizing lithium / carbon monofluoride batteries during recharging
TWI604655B (en) 2014-08-08 2017-11-01 Kureha Corp Non-aqueous electrolyte secondary battery negative carbonaceous material
TWI599092B (en) 2014-08-08 2017-09-11 Kureha Corp Non-Aqueous Electrolyte Secondary Battery Negative Carbonaceous Material
TWI565654B (en) * 2014-08-08 2017-01-11 Kureha Corp Production method of carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery and carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery
CN113257582A (en) 2014-11-18 2021-08-13 加利福尼亚大学董事会 Porous interconnected corrugated carbon-based network (ICCN) composite
CN106469838A (en) * 2015-08-14 2017-03-01 深圳市比克动力电池有限公司 The charging method of cylinder power lithium-ion battery and device
US9741499B2 (en) * 2015-08-24 2017-08-22 Nanotek Instruments, Inc. Production process for a supercapacitor having a high volumetric energy density
CN108028377A (en) * 2015-09-16 2018-05-11 株式会社理光 Nonaqueous electrolyte charge storage element
WO2017062950A1 (en) * 2015-10-08 2017-04-13 William Marsh Rice University High surface area porous carbon materials as electrodes
US10276856B2 (en) * 2015-10-08 2019-04-30 Nanotek Instruments, Inc. Continuous process for producing electrodes and alkali metal batteries having ultra-high energy densities
US9779882B2 (en) * 2015-11-23 2017-10-03 Nanotek Instruments, Inc. Method of producing supercapacitor electrodes and cells having high active mass loading
AU2016378400B2 (en) 2015-12-22 2021-08-12 The Regents Of The University Of California Cellular graphene films
KR102645603B1 (en) 2016-01-22 2024-03-07 더 리전트 오브 더 유니버시티 오브 캘리포니아 high-voltage device
FR3047843B1 (en) * 2016-02-12 2018-03-09 Commissariat A L'energie Atomique Et Aux Energies Alternatives ELECTROCHROME ELECTRODE FOR ENERGY STORAGE DEVICE
US11062855B2 (en) 2016-03-23 2021-07-13 The Regents Of The University Of California Devices and methods for high voltage and solar applications
BR112018068945B1 (en) 2016-04-01 2023-11-21 The Regents Of The University Of California SUPERCAPACITOR, AND, METHOD FOR MANUFACTURING A FUNCTIONALIZED ELECTRODE
US11097951B2 (en) 2016-06-24 2021-08-24 The Regents Of The University Of California Production of carbon-based oxide and reduced carbon-based oxide on a large scale
JP2018041710A (en) * 2016-08-31 2018-03-15 積水化学工業株式会社 Active material-carbon material composite, positive electrode for nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery and carbon material
WO2018044786A1 (en) 2016-08-31 2018-03-08 The Regents Of The University Of California Devices comprising carbon-based material and fabrication thereof
US10950861B2 (en) * 2017-02-13 2021-03-16 Global Graphene Group, Inc. Aluminum secondary battery having a high-capacity and high energy cathode and manufacturing method
US10651464B2 (en) * 2017-02-13 2020-05-12 Global Graphene Group, Inc. Alkali metal-sulfur secondary battery containing a nano sulfur-loaded cathode and manufacturing method
JP6853504B2 (en) * 2017-03-01 2021-03-31 スズキ株式会社 Negative electrode composite structure of lithium-air battery
US10122020B2 (en) * 2017-03-06 2018-11-06 Nanotek Instruments, Inc. Aluminum secondary battery cathode having oriented graphene
US10411291B2 (en) * 2017-03-22 2019-09-10 Nanotek Instruments, Inc. Multivalent metal ion battery having a cathode layer of protected graphitic carbon and manufacturing method
US10903519B2 (en) * 2017-03-27 2021-01-26 Global Graphene Group, Inc. Lithium secondary battery containing non-flammable electrolyte and manufacturing method
KR102563188B1 (en) 2017-07-14 2023-08-02 더 리전트 오브 더 유니버시티 오브 캘리포니아 A Simple Route from Carbon Nanoparticles to Highly Conductive Porous Graphene for Supercapacitor Applications
CN107634225A (en) * 2017-08-31 2018-01-26 福建新峰二维材料科技有限公司 A kind of Dual-ion cell preparation method using hard carbon positive electrode
CN109872882B (en) * 2017-12-01 2021-12-14 中国科学院大连化学物理研究所 Application of negative electrode material in lithium ion supercapacitor
CN109961967B (en) * 2017-12-26 2021-09-21 广州巨湾技研有限公司 Lithium ion capacitor and preparation method thereof
CN108155420A (en) * 2017-12-27 2018-06-12 成都市银隆新能源有限公司 A kind of battery core, battery and battery application method
JP7431175B2 (en) * 2018-05-15 2024-02-14 ハイドロ－ケベック Cellulose-based free-standing film for use in Li-ion batteries
US11038195B2 (en) 2018-06-01 2021-06-15 Global Graphene Group, Inc. Multi-level graphene-protected anode active material particles for battery applications
US10727479B2 (en) 2018-06-01 2020-07-28 Global Graphene Group, Inc. Method of producing multi-level graphene-protected anode active material particles for battery applications
US11018336B2 (en) 2018-06-06 2021-05-25 Global Graphene Group, Inc. Multi-level graphene-protected anode active material particles for fast-charging lithium-ion batteries
WO2020002550A1 (en) * 2018-06-27 2020-01-02 Imertech Surface-functionalized carbonaceous particles, methods of making, and applications of the same
US11870051B2 (en) 2018-07-18 2024-01-09 Global Graphene Group, Inc. Method of improving fast-chargeability of a lithium-ion battery
WO2020018731A1 (en) * 2018-07-18 2020-01-23 Nanotek Instruments, Inc. Fast-chargeable lithium battery electrodes
KR102365086B1 (en) 2018-12-03 2022-02-18 주식회사 엘지에너지솔루션 Non-destructive method for measuring active area of active material
WO2020178058A1 (en) * 2019-03-01 2020-09-10 Blue Solutions Cell for a hybrid electrical energy storage device, method for obtaining such a cell, and hybrid supercapacitor comprising at least one such cell
BR112021019457A2 (en) * 2019-03-29 2021-11-30 Volta Pty Ltd Supercapacitor
US10938032B1 (en) 2019-09-27 2021-03-02 The Regents Of The University Of California Composite graphene energy storage methods, devices, and systems
WO2021100360A1 (en) * 2019-11-19 2021-05-27 テイカ株式会社 Pre-doped sheet for power storage device and production method therefor
WO2022058099A2 (en) * 2020-09-18 2022-03-24 Shell Oil Company Battery supercapacitors hybrid systems
CN114944286A (en) * 2022-05-17 2022-08-26 中国电子科技集团公司第十八研究所 Electrochemical activation method of graphene-based positive electrode material and lithium ion capacitor
CN115566157B (en) * 2022-08-31 2023-09-15 阜阳隆能科技有限公司 Long cycle life power battery

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3047409B2 (en) * 1989-09-07 2000-05-29 株式会社デンソー Lithium secondary battery
AU2002212716B2 (en) * 2000-11-17 2006-10-05 Asahi Kasei Kabushiki Kaisha Nonaqueous lithium secondary cell
US20040048157A1 (en) * 2002-09-11 2004-03-11 Neudecker Bernd J. Lithium vanadium oxide thin-film battery
US20040234844A1 (en) * 2003-05-20 2004-11-25 Phoenix Innovation, Inc. Novel carbon nanotube lithium battery
JP4803978B2 (en) * 2004-01-15 2011-10-26 旭化成株式会社 Non-aqueous lithium storage element
US20070190422A1 (en) * 2006-02-15 2007-08-16 Fmc Corporation Carbon nanotube lithium metal powder battery
US7745047B2 (en) * 2007-11-05 2010-06-29 Nanotek Instruments, Inc. Nano graphene platelet-base composite anode compositions for lithium ion batteries
US8435676B2 (en) * 2008-01-09 2013-05-07 Nanotek Instruments, Inc. Mixed nano-filament electrode materials for lithium ion batteries
JP5218963B2 (en) * 2008-03-31 2013-06-26 日本ケミコン株式会社 Composite electrode
WO2009134707A2 (en) * 2008-04-27 2009-11-05 Board Of Regents, The University Of Texas System Ultracapacitors and methods of making and using
US9991391B2 (en) * 2008-07-25 2018-06-05 The Board Of Trustees Of The Leland Stanford Junior University Pristine and functionalized graphene materials
US9406985B2 (en) * 2009-01-13 2016-08-02 Nokia Technologies Oy High efficiency energy conversion and storage systems using carbon nanostructured materials

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