JP2014237819A5 - - Google Patents

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JP2014237819A5
JP2014237819A5 JP2014117702A JP2014117702A JP2014237819A5 JP 2014237819 A5 JP2014237819 A5 JP 2014237819A5 JP 2014117702 A JP2014117702 A JP 2014117702A JP 2014117702 A JP2014117702 A JP 2014117702A JP 2014237819 A5 JP2014237819 A5 JP 2014237819A5
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layer
multilayer structure
high chroma
structural color
omnidirectional structural
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JP2014117702A
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JP2014237819A (en
JP6655278B2 (en
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Priority claimed from US13/913,402 external-priority patent/US10690823B2/en
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Claims (14)

多層スタックを含み、前記多層スタックは
コア層と、
前記コア層に亘って延在する誘電体層と、
界面を間に挟んで前記誘電体層に亘って延在する吸収層とを有し、
前記誘電体層と前記吸収層との間の前記界面は、第1の入射電磁波長にてほぼゼロの電界を有し、第2の入射電磁波長にて大きな電界を有し、前記第2の入射電磁波長は前記第1の入射電磁波長とは等しくなく、
前記多層スタックは、高クロマ全方向構造色をもたらす0°と45°との間の角度から見た際、可視スペクトルにおいて200nm未満の半値全幅(FWHM)の幅を有する単一の狭い反射帯域と、30°未満の色調シフトを有する最小の色変化とを有し、
前記誘電体層は、前記狭い反射帯域の中心波長の2・クォーターウェーブ(QW)以下の厚さを有する、
高クロマ全方向構造色多層構造。
A multi-layer stack, the multi-layer stack comprising a core layer;
A dielectric layer extending across the core layer;
An absorption layer extending across the dielectric layer with an interface therebetween,
The interface between the dielectric layer and the absorbing layer has a substantially zero electric field at a first incident electromagnetic wave length, a large electric field at a second incident electromagnetic wave length, and the second The incident electromagnetic wave length is not equal to the first incident electromagnetic wave length,
The multilayer stack is a single narrow reflection band having a full width at half maximum (FWHM) of less than 200 nm in the visible spectrum when viewed from an angle between 0 ° and 45 ° resulting in a high chroma omnidirectional structural color If, possess a minimum color change with the color tone shift of less than 30 °,
The dielectric layer has a thickness of 2 · quarter wave (QW) or less of the center wavelength of the narrow reflection band.
High chroma omnidirectional structure color multilayer structure.
前記コア層は、式RI=n+ikによって示される複素屈折率を有し、n<<kであり、式中RIは前記複素屈折率であり、nは前記コア層の屈折率でありは前記コア層の消衰係数であり、iは√−1である、請求項1に記載の高クロマ全方向構造色多層構造。 The core layer has a complex index of refraction represented by the formula RI 1 = n 1 + ik 1 , where n 1 << k 1 , where RI 1 is the complex index of refraction and n 1 is the core layer the refractive index of, k 1 is the extinction coefficient of the core layer, i is a √-1, high chroma omnidirectional structural color multilayer structure of claim 1. 前記コア層は、銀、銅、クロム、アルミニウム、金およびそれらの合金からなる群から選択される材料から形成される、請求項2に記載の高クロマ全方向構造色多層構造。   The high chroma omnidirectional structural color multilayer structure of claim 2, wherein the core layer is formed from a material selected from the group consisting of silver, copper, chromium, aluminum, gold and alloys thereof. 前記コア層は前記アルミニウムおよびその前記合金からなる群から選択される材料から形成される、請求項3に記載の高クロマ全方向構造色多層構造。   4. The high chroma omnidirectional structural color multilayer structure of claim 3, wherein the core layer is formed from a material selected from the group consisting of the aluminum and its alloys. 前記コア層は50nmと200nmとの間の厚さを有する、請求項4に記載の高クロマ全方向構造色多層構造。   5. The high chroma omnidirectional structural color multilayer structure of claim 4, wherein the core layer has a thickness between 50 nm and 200 nm. 前記誘電体層は、TiO、MgF、ZnS、HfO、Nb、Ta、SiOおよびそれらの組合せの少なくとも1つを含む、請求項に記載の高クロマ全方向構造色多層構造。 Said dielectric layer, TiO 2, MgF 2, ZnS , HfO 2, Nb 2 O 5, Ta 2 O 5, SiO 2 and at least one of their combinations, high chroma all directions according to claim 5 Structural color multilayer structure. 前記誘電体層はZnSである、請求項に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 6 , wherein the dielectric layer is ZnS. 前記吸収層は式RI=n+ikで示される複素屈折率を有し、n≒kであり、式中RIは前記複素屈折率であり、nは前記誘電体層の屈折率であり、kは前記吸収層の消衰係数である、請求項に記載の高クロマ全方向構造色多層構造。 The absorbing layer has a complex refractive index represented by the formula RI 2 = n 2 + ik 2 , an n 2 k 2, wherein RI 2 is the complex refractive index, n 2 is the dielectric layer The high chroma omnidirectional structural color multilayer structure according to claim 7 , wherein the refractive index is k 2 is an extinction coefficient of the absorbing layer. 前記吸収層は、クロム、タンタル、タングステン、モリブデン、チタン、窒化チタン、ニオブ、コバルト、ケイ素、ゲルマニウム、ニッケル、パラジウム、バナジウム、酸化鉄およびそれらの合金の少なくとも1つから選択される材料から形成される、請求項に記載の高クロマ全方向構造色多層構造。 The absorption layer is formed of a material selected from at least one of chromium, tantalum, tungsten, molybdenum, titanium, titanium nitride, niobium, cobalt, silicon, germanium, nickel, palladium, vanadium, iron oxide, and alloys thereof. The high chroma omnidirectional structural color multilayer structure according to claim 8 . 前記吸収層は、前記クロムおよびその前記合金の少なくとも1つから形成される、請求項に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 9 , wherein the absorbing layer is formed from at least one of the chromium and its alloys. 前記吸収層は5nmと20nmとの間の厚さを有する、請求項10に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 10 , wherein the absorption layer has a thickness between 5 nm and 20 nm. 前記吸収層の外面に亘って延在する別の誘電体層をさらに含む、請求項11に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 11 , further comprising another dielectric layer extending over an outer surface of the absorbing layer. 前記コア層と前記誘電体層との間に別の吸収層をさらに含む、請求項11に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 11 , further comprising another absorbing layer between the core layer and the dielectric layer. 前記コア層と前記誘電体層との間に別の吸収層をさらに含む、請求項12に記載の高クロマ全方向構造色多層構造。 The high chroma omnidirectional structural color multilayer structure of claim 12 , further comprising another absorbing layer between the core layer and the dielectric layer.
JP2014117702A 2013-06-08 2014-06-06 High chroma omnidirectional structure Color multilayer structure Expired - Fee Related JP6655278B2 (en)

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US13/913,402 2013-06-08
US13/913,402 US10690823B2 (en) 2007-08-12 2013-06-08 Omnidirectional structural color made from metal and dielectric layers

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