JP2014231916A - Duct with deodorization function - Google Patents

Duct with deodorization function Download PDF

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JP2014231916A
JP2014231916A JP2013111486A JP2013111486A JP2014231916A JP 2014231916 A JP2014231916 A JP 2014231916A JP 2013111486 A JP2013111486 A JP 2013111486A JP 2013111486 A JP2013111486 A JP 2013111486A JP 2014231916 A JP2014231916 A JP 2014231916A
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tubular portion
duct
deodorant
inner tubular
nonwoven fabric
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JP5931798B2 (en
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善春 西野
Yoshiharu Nishino
善春 西野
智朗 奥野
Tomoaki Okuno
智朗 奥野
功洋 川西
Katsuhiro Kawanishi
功洋 川西
信一郎 竹下
Shinichiro Takeshita
信一郎 竹下
進三 齋藤
Shinzo Saito
進三 齋藤
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TYLON CORP
Suminoe Textile Co Ltd
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TYLON CORP
Suminoe Textile Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a duct having sufficient heat insulation characteristics and sound absorbency characteristics as well as superior deodorization characteristics.SOLUTION: This invention comprises an inner tubular part 2 including span bond non-woven cloth with a thickness of 0.1 mm to 0.8 mm and basis weight of 30 g/mto 120 g/m, an intermediate tubular part 3 covering the inner tubular part 2 and an outer tubular part 4 covering the intermediate tubular part. The intermediate tubular part 3 includes glass wool with a thickness of 20 mm to 60 mm and a bulk density of 12 kg/mto 30 kg/m, deodorant fastening parts 5 having deodorant adhered through gravure printing are formed at a part of the inner circumferential surface of the inner tubular part 2 and a rate of area of a printed area 21 having deodorant printed in respect to an entire inner circumferential surface of the inner tubular part is in a range of 50% to 90%.

Description

本発明は、例えば、送気用ダクト、排気用ダクト等として用いられる、十分な断熱性、吸音性を備えている上に、消臭機能も備えたダクト(ダクトホース)に関する。   The present invention relates to a duct (duct hose) that is used as, for example, an air supply duct, an exhaust duct, and the like and has a sufficient heat insulating property and sound absorbing property and also has a deodorizing function.

通気性材料製テープを螺旋状に捲回しその側縁同士を連結するとともに硬質螺旋補強体でこれを保形するように形成した内壁の外周に、連続気泡構造の軟質発泡テープを螺旋状に捲回して形成した第1発泡層および独立気泡構造の軟質発泡テープを螺旋状に捲回して形成した第2発泡層を積層してなる吸音断熱層を設け、その外周に可撓性材料からなる外壁を設けてなるダクトホースが公知である(特許文献1参照)。   A flexible foam tape with an open-cell structure is spirally wound on the outer periphery of the inner wall that is formed by spirally winding a tape made of air-permeable material and connecting the side edges thereof and retaining the shape with a hard spiral reinforcement. An outer wall made of a flexible material is provided on the outer periphery of a sound-absorbing heat insulating layer formed by laminating a second foamed layer formed by spirally winding a first foamed layer formed by rotating and a soft foam tape having a closed cell structure. A duct hose provided with is known (see Patent Document 1).

上記従来のダクトホースでは、独立気泡構造の第2発泡層で断熱性を確保できるのでホースの外面に結露を生じることを防止できるし、主に連続気泡構造の第1発泡層で吸音できるので騒音も十分に低減することができる。   In the above conventional duct hose, heat insulation can be ensured by the second foam layer of the closed cell structure, so that it is possible to prevent condensation on the outer surface of the hose, and noise can be absorbed mainly by the first foam layer of the open cell structure. Can also be sufficiently reduced.

特開平8−219335号公報JP-A-8-219335

ところで、例えば、空調用設備に接続されるダクトは、このダクトホースを介して室内の空気を循環させているので、このダクト内を空気が通過する間に室内空気に含まれる臭気(タバコ由来の臭い、その他の臭い等)を消臭することができれば、室内をより快適な空間に維持することができる。   By the way, for example, a duct connected to an air conditioning facility circulates indoor air through this duct hose. Therefore, an odor (derived from tobacco) contained in indoor air while air passes through the duct. If odors and other odors can be eliminated, the room can be maintained in a more comfortable space.

しかるに、従来のダクトホースには、優れた消臭機能を有したものはなかったのが実状である。   However, the fact is that none of the conventional duct hoses has an excellent deodorizing function.

本発明は、かかる技術的背景に鑑みてなされたものであって、十分な断熱性と吸音性を備えていると共に、優れた消臭性を有するダクトを提供することを目的とする。   This invention is made | formed in view of this technical background, Comprising: While providing sufficient heat insulation and sound absorption property, it aims at providing the duct which has the outstanding deodorizing property.

前記目的を達成するために、本発明は以下の手段を提供する。   In order to achieve the above object, the present invention provides the following means.

[1]厚さ0.1mm〜0.8mmで目付が30g/m2〜120g/m2のスパンボンド不織布を含む内側管状部と、
前記内側管状部の外側に設けられて該内側管状部を被覆する中間管状部と、
前記中間管状部の外側に設けられて該中間管状部を被覆する外側管状部とを備え、
前記中間管状部は、厚さ20mm〜60mmで嵩密度が12kg/m3〜30kg/m3のグラスウールを含み、
前記内側管状部の内周面の一部に消臭剤がグラビア印刷により固着され、前記内側管状部の内周面の全体に対する前記消臭剤が印刷された印刷領域の面積の割合が50%〜90%の範囲であることを特徴とする消臭機能を有するダクト。
An inner tubular section containing [1] a basis weight in the thickness 0.1mm~0.8mm is a 30g / m 2 ~120g / m 2 spunbond nonwoven,
An intermediate tubular portion that is provided outside the inner tubular portion and covers the inner tubular portion;
An outer tubular portion provided outside the intermediate tubular portion and covering the intermediate tubular portion;
The intermediate tubular portion, the bulk density in thickness 20mm~60mm comprises glass wool of 12kg / m 3 ~30kg / m 3 ,
A deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion by gravure printing, and the ratio of the area of the print area where the deodorant is printed to the entire inner peripheral surface of the inner tubular portion is 50%. A duct having a deodorizing function, characterized by being in a range of ˜90%.

[2]前記消臭剤の固着量が1.5g/m2〜4.0g/m2である前項1に記載の消臭機能を有するダクト。 [2] duct having a deodorizing function according to the above 1 weight fixation of deodorant is 1.5g / m 2 ~4.0g / m 2 .

[3]前記消臭剤は、前記内側管状部の内周面の一部にバインダー樹脂で固着され、
前記バインダー樹脂の固着量が0.6g/m2〜1.6g/m2である前項1または2に記載の消臭機能を有するダクト。
[3] The deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion with a binder resin,
Ducts amount sticking of the binder resin has a deodorizing function according to item 1 or 2 is 0.6g / m 2 ~1.6g / m 2 .

[4]前記スパンボンド不織布を構成する繊維は、ポリエステル系樹脂で形成され、前記バインダー樹脂としてウレタン系バインダー樹脂が用いられている前項3に記載の消臭機能を有するダクト。   [4] The duct having the deodorizing function according to item 3 above, wherein the fibers constituting the spunbonded nonwoven fabric are formed of a polyester resin, and a urethane binder resin is used as the binder resin.

[5]前記スパンボンド不織布を構成する繊維の太さが、7.5デシテックス〜15.0デシテックスの範囲である前項1〜4のいずれか1項に記載の消臭機能を有するダクト。   [5] The duct having the deodorizing function according to any one of the above items 1 to 4, wherein a thickness of a fiber constituting the spunbonded nonwoven fabric is in a range of 7.5 dtex to 15.0 dtex.

[6]前記内側管状部のスパンボンド不織布による多孔質構造と、前記中間管状部のグラスウールによる多孔質構造とが、相互の界面を介して連通しており、
前記グラスウールを構成する繊維の太さ(直径)が、1μm〜30μmの範囲である前項1〜5のいずれか1項に記載の消臭機能を有するダクト。
[6] The porous structure of the inner tubular portion made of spunbonded nonwoven fabric and the porous structure of the intermediate tubular portion made of glass wool are communicated with each other through an interface.
The duct which has a deodorizing function of any one of the preceding clauses 1-5 whose thickness (diameter) which comprises the said glass wool is the range of 1 micrometer-30 micrometers.

[1]の発明では、厚さ0.1mm〜0.8mmで目付が30〜120g/m2のスパンボンド不織布を含んでなる内側管状部を備えているから、十分な吸音性能を確保できる。また、スパンボンド不織布を用いているので、ダクトとしての保形性を向上させることができる。また、内側管状部の外側に配置された中間管状部は、厚さ20mm〜60mmで嵩密度が12kg/m3〜30kg/m3のグラスウールを含むので、十分な断熱性を確保できて、ダクトの外周面に結露を生じることを防止できる。更に、内側管状部の内周面に固着された消臭剤により、ダクト内の流路を通過する空気等の消臭を行うことができる。更に、内側管状部の内周面の一部に消臭剤がグラビア印刷により固着され、内側管状部の内周面の全体に対する消臭剤が印刷された印刷領域の面積の割合が50%〜90%の範囲であるから、十分な消臭性能を得ることができると共に、スパンボンド不織布層の内部への空気の移動を十分に確保することができて十分な吸音性能を得ることができる。 In the invention of [1], since the inner tubular portion including the spunbonded nonwoven fabric having a thickness of 0.1 mm to 0.8 mm and a basis weight of 30 to 120 g / m 2 is provided, sufficient sound absorbing performance can be secured. Moreover, since the spun bond nonwoven fabric is used, the shape retention as a duct can be improved. The intermediate tubular portion disposed on the outside of the inner tubular portion, since the bulk density in thickness 20mm~60mm comprises glass wool of 12kg / m 3 ~30kg / m 3 , it can be ensured a sufficient thermal insulation, duct It is possible to prevent dew condensation from occurring on the outer peripheral surface. Furthermore, the deodorizer fixed to the inner peripheral surface of the inner tubular portion can deodorize air or the like passing through the flow path in the duct. Further, the deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion by gravure printing, and the ratio of the area of the print region in which the deodorant is printed with respect to the entire inner peripheral surface of the inner tubular portion is 50% to Since it is in the range of 90%, a sufficient deodorizing performance can be obtained, and a sufficient movement of air to the inside of the spunbonded nonwoven fabric layer can be ensured to obtain a sufficient sound absorbing performance.

[2]の発明では、消臭剤の固着量が1.5g/m2〜4.0g/m2であり、1.5g/m2以上であることで消臭性能をより向上できると共に、4.0g/m2以下であることで軽量性を維持できる。 In the invention of [2], the deodorant fixing amount is 1.5 g / m 2 to 4.0 g / m 2 , and the deodorizing performance can be further improved by being 1.5 g / m 2 or more. Light weight can be maintained by being 4.0 g / m 2 or less.

[3]の発明では、消臭剤は、内側管状部の内周面の一部にバインダー樹脂で固着され、該バインダー樹脂の固着量が0.6g/m2〜1.6g/m2である。0.6g/m2以上であることで消臭剤の脱落を十分に防止できると共に、1.6g/m2以下であることで消臭剤の表面を十分に露出させることができて消臭性能をより向上できる。 In the invention [3], deodorant is a part of the inner peripheral surface of the inner tubular portion is secured with a binder resin, the amount sticking of the binder resin is at 0.6g / m 2 ~1.6g / m 2 is there. It is possible to sufficiently prevent the deodorant from falling off when it is 0.6 g / m 2 or more, and it is possible to sufficiently expose the surface of the deodorant when it is 1.6 g / m 2 or less. Performance can be improved.

[4]の発明では、スパンボンド不織布を構成する繊維は、ポリエステル系樹脂で形成され、バインダー樹脂としてウレタン系バインダー樹脂が用いられているから、このような組み合わせにより、消臭剤のスパンボンド不織布への固着力をさらに向上させることができて、より長期にわたって十分な消臭性能を確保できる。   In the invention of [4], the fibers constituting the spunbonded nonwoven fabric are formed of a polyester-based resin, and a urethane-based binder resin is used as the binder resin. It is possible to further improve the adhering force to the skin, and to secure a sufficient deodorizing performance over a longer period of time.

[5]の発明では、スパンボンド不織布を構成する繊維の太さが、7.5デシテックス〜15.0デシテックスの範囲であるから、内側管状部を形成するための成型加工が十分に可能になり(成型加工性が向上し)、消臭剤を固着できるための表面積を備えたものとなり、またスパンボンド不織布を介して中間管状部のグラスウールに対して十分な通気ができるのでグラスウールでの吸音作用効果も確保できる。   In the invention of [5], since the thickness of the fibers constituting the spunbonded nonwoven fabric is in the range of 7.5 dtex to 15.0 dtex, the molding process for forming the inner tubular portion is sufficiently possible. (Improved molding processability), it has a surface area that can fix the deodorant, and because it can ventilate the glass wool in the intermediate tubular part through the spunbonded nonwoven fabric, it absorbs sound with glass wool. The effect can be secured.

[6]の発明では、内側管状部のスパンボンド不織布による多孔質構造と、中間管状部のグラスウールによる多孔質構造とが、相互の界面を介して連通している上に、グラスウールを構成する繊維の太さ(直径)が、1μm〜30μmの範囲であるから、グラスウール(中間管状部)において吸音性能も十分に発揮されるものとなり、スパンボンド不織布(内側管状部)の吸音効果とも相俟って、優れた吸音性能を確保できる。   In the invention of [6], the porous structure made of the spunbond nonwoven fabric in the inner tubular portion and the porous structure made of glass wool in the intermediate tubular portion communicate with each other via the mutual interface, and the fibers constituting the glass wool Since the thickness (diameter) of the fiber is in the range of 1 μm to 30 μm, the sound absorbing performance is sufficiently exhibited in the glass wool (intermediate tubular portion), which is also combined with the sound absorbing effect of the spunbond nonwoven fabric (inner tubular portion). Excellent sound absorption performance can be secured.

本発明に係る消臭機能を有するダクトの一実施形態を示す断面図である。It is sectional drawing which shows one Embodiment of the duct which has the deodorizing function which concerns on this invention.

本発明に係る消臭機能を有するダクト(ダクトホース)の一実施形態を図1に示す。本発明のダクト1は、スパンボンド不織布を含む内側管状部2と、前記内側管状部2の外側に設けられて該内側管状部2を被覆する中間管状部3と、前記中間管状部3の外側に設けられて該中間管状部3を被覆する外側管状部4とを備える。   One embodiment of a duct (duct hose) having a deodorizing function according to the present invention is shown in FIG. The duct 1 of the present invention includes an inner tubular portion 2 containing a spunbond nonwoven fabric, an intermediate tubular portion 3 provided outside the inner tubular portion 2 and covering the inner tubular portion 2, and an outer side of the intermediate tubular portion 3. And an outer tubular portion 4 that covers the intermediate tubular portion 3.

なお、図1において、10は、内側管状部2の内部空間であって、空気等の流路である。また、本実施形態では、前記内側管状部2のスパンボンド不織布による多孔質構造と、前記中間管状部3のグラスウールによる多孔質構造とが、相互の界面を介して連通している。   In FIG. 1, reference numeral 10 denotes an internal space of the inner tubular portion 2, which is a flow path such as air. Moreover, in this embodiment, the porous structure by the spun bond nonwoven fabric of the said inner side tubular part 2 and the porous structure by the glass wool of the said intermediate | middle tubular part 3 are connecting via the mutual interface.

前記内側管状部2は、厚さ0.1mm〜0.8mmで目付が30g/m2〜120g/m2のスパンボンド不織布を含有してなる。 The inner tubular section 2, the basis weight is contained 30g / m 2 ~120g / m 2 spunbond nonwoven with a thickness 0.1Mm~0.8Mm.

前記内側管状部2を構成するスパンボンド不織布の厚さTは0.1mm〜0.8mmに設定される。0.1mm未満では十分な吸音性能を得ることができないし、0.8mmを超えるとダクトの径が増大してコンパクト化が難しくなる。中でも、前記内側管状部2を構成するスパンボンド不織布の厚さTは0.15mm〜0.6mmに設定されるのが好ましく、さらに0.2mm〜0.4mmの範囲が特に好ましい。   The thickness T of the spunbonded nonwoven fabric constituting the inner tubular portion 2 is set to 0.1 mm to 0.8 mm. If it is less than 0.1 mm, sufficient sound absorbing performance cannot be obtained, and if it exceeds 0.8 mm, the diameter of the duct increases and it becomes difficult to make it compact. Among these, the thickness T of the spunbonded nonwoven fabric constituting the inner tubular portion 2 is preferably set to 0.15 mm to 0.6 mm, and more preferably in the range of 0.2 mm to 0.4 mm.

前記内側管状部2を構成するスパンボンド不織布の目付は30g/m2〜120g/m2の範囲に設定される。30g/m2未満では消臭剤を固着できるための十分な表面積を確保できないし(消臭剤を十分に固着できないし)、120g/m2を超えると軽量性を維持するのが困難となる。中でも、前記内側管状部2を構成するスパンボンド不織布の目付は35g/m2〜100g/m2の範囲に設定されるのが好ましく、さらに40g/m2〜80g/m2の範囲が特に好ましい。 Basis weight of the spunbonded nonwoven fabric constituting the inner tubular section 2 is set in a range of 30g / m 2 ~120g / m 2 . If it is less than 30 g / m 2 , a sufficient surface area for fixing the deodorant cannot be secured (the deodorant cannot be fixed sufficiently), and if it exceeds 120 g / m 2 , it becomes difficult to maintain light weight. . Above all, the basis weight of the spunbonded nonwoven fabric constituting the inner tubular portion 2 is preferably set in a range of 35g / m 2 ~100g / m 2 , particularly preferably further the range of 40g / m 2 ~80g / m 2 .

前記スパンボンド不織布を構成する繊維としては、特に限定されるものではないが、例えば、ポリエチレン繊維、ポリプロピレン繊維、ポリエステル繊維、ポリアミド繊維、レーヨン繊維等が挙げられる。   Although it does not specifically limit as a fiber which comprises the said spun bond nonwoven fabric, For example, a polyethylene fiber, a polypropylene fiber, a polyester fiber, a polyamide fiber, rayon fiber etc. are mentioned.

前記スパンボンド不織布を構成する繊維の太さは、7.5デシテックス〜15.0デシテックスの範囲であるのが好ましい。7.5デシテックス以上とすることで消臭剤の不織布に対する固着力を向上させることができて消臭性能の耐久性を高めることができると共に、15.0デシテックス以下とすることで吸音性能をより向上させることができる。中でも、前記スパンボンド不織布を構成する繊維の太さは、9.0デシテックス〜12.0デシテックスの範囲であるのが特に好ましい。   The thickness of the fibers constituting the spunbonded nonwoven fabric is preferably in the range of 7.5 dtex to 15.0 dtex. It is possible to improve the fixing power of the deodorant to the non-woven fabric by setting it to 7.5 decitex or more, and to enhance the durability of the deodorizing performance, and by reducing the deodorizing performance to 15.0 decitex or less, the sound absorbing performance is further improved. Can be improved. Especially, it is especially preferable that the thickness of the fiber which comprises the said spun bond nonwoven fabric is the range of 9.0 decitex-12.0 decitex.

前記中間管状部3は、厚さ20mm〜60mmで嵩密度が12kg/m3〜30kg/m3のグラスウールを含有してなる。 The intermediate tubular portion 3, a bulk density in a thickness 20mm~60mm is comprising glass wool 12kg / m 3 ~30kg / m 3 .

前記中間管状部3を構成するグラスウール層の厚さSは20mm〜60mmに設定される。20mm未満では十分な断熱性能を得ることができないし、60mmを超えるとダクトの径が増大してコンパクト化が難しくなる。中でも、前記中間管状部3を構成するグラスウール層の厚さSは25mm〜50mmに設定されるのが好ましい。   The thickness S of the glass wool layer constituting the intermediate tubular portion 3 is set to 20 mm to 60 mm. If it is less than 20 mm, sufficient heat insulating performance cannot be obtained, and if it exceeds 60 mm, the diameter of the duct increases and it becomes difficult to make it compact. Especially, it is preferable that the thickness S of the glass wool layer which comprises the said intermediate | middle tubular part 3 is set to 25 mm-50 mm.

前記中間管状部3を構成するグラスウール層の嵩密度(みかけ密度)は、12kg/m3〜30kg/m3の範囲に設定される。12kg/m3未満では十分な断熱性能を得ることができないし、30kg/m3を超えると軽量性を維持するのが困難となる。中でも、前記中間管状部3を構成するグラスウール層の嵩密度は15kg/m3〜25kg/m3の範囲に設定されるのが好ましい。 The bulk density (apparent density) of the glass wool layer constituting the intermediate tubular portion 3 is set in the range of 12kg / m 3 ~30kg / m 3 . If it is less than 12 kg / m 3 , sufficient heat insulating performance cannot be obtained, and if it exceeds 30 kg / m 3 , it is difficult to maintain light weight. Among them, the bulk density of the glass wool layer forming the intermediate tubular portion 3 is preferably set in the range of 15kg / m 3 ~25kg / m 3 .

前記グラスウール層を構成する繊維の太さ(直径)は、1μm〜30μmの範囲であるのが好ましい。   The thickness (diameter) of the fibers constituting the glass wool layer is preferably in the range of 1 μm to 30 μm.

前記外側管状部4としては、特に限定されるものではないが、例えば、ポリエチレンシート、ポリプロピレンシート、エチレン−メタクリル酸メチル共重合体樹脂シート等が挙げられ、前記中間管状部3を密閉状態に被覆できるものであれば特に限定されない。前記外側管状部4の厚さWは、0.05mm〜0.3mmに設定されるのが好ましい。   The outer tubular portion 4 is not particularly limited, and examples thereof include a polyethylene sheet, a polypropylene sheet, an ethylene-methyl methacrylate copolymer resin sheet, and the intermediate tubular portion 3 is covered in a sealed state. There is no particular limitation as long as it is possible. The thickness W of the outer tubular portion 4 is preferably set to 0.05 mm to 0.3 mm.

本発明では、前記内側管状部2の内周面の一部に消臭剤がグラビア印刷により固着されて消臭剤固着部5が形成されている(図1参照)。図1において、印刷領域21に消臭剤固着部5が形成されており、非印刷領域22には消臭剤固着部5は形成されていない。図1の実施形態では、ダクト1の長さ方向に沿って印刷領域21と非印刷領域22が交互に配置されている。前記印刷領域21には消臭剤が固着されているので、流路10を流れてきた空気が印刷領域21の消臭剤と接触して消臭が行われる。また、非印刷領域22には、消臭剤もバインダー樹脂も付着されていないので、流路10を流れてきた空気は、この非印刷領域22を介して内側管状部(スパンボンド不織布)2の内部に入り込んでここで吸音される。本実施形態では、内側管状部(スパンボンド不織布)2の内部には、消臭剤及びバインダー樹脂が付着されていないので、この内部に入り込んだ音はここで十分に吸音される。   In the present invention, a deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion 2 by gravure printing to form a deodorant fixing portion 5 (see FIG. 1). In FIG. 1, the deodorant fixing part 5 is formed in the printing area 21, and the deodorant fixing part 5 is not formed in the non-printing area 22. In the embodiment of FIG. 1, the print areas 21 and the non-print areas 22 are alternately arranged along the length direction of the duct 1. Since the deodorizing agent is fixed to the printing area 21, the air flowing through the flow path 10 comes into contact with the deodorizing agent in the printing area 21 and deodorization is performed. In addition, since the deodorizing agent and the binder resin are not attached to the non-printing region 22, the air flowing through the flow path 10 passes through the non-printing region 22 in the inner tubular portion (spunbond nonwoven fabric) 2. It gets inside and is absorbed here. In the present embodiment, since the deodorant and the binder resin are not attached to the inside of the inner tubular portion (spunbond nonwoven fabric) 2, the sound that has entered the inside is sufficiently absorbed here.

本発明において、前記内側管状部2の内周面の全体に対する前記消臭剤が印刷された印刷領域の面積の割合は50%〜90%の範囲に設定される。50%未満では十分な消臭効果を確保できなくなるし、90%を超えると十分な吸音効果を確保できない。中でも、前記内側管状部2の内周面の全体に対する前記消臭剤が印刷された印刷領域の面積の割合は60%〜80%の範囲であるのが好ましい。   In this invention, the ratio of the area of the printing area | region where the said deodorizer was printed with respect to the whole inner peripheral surface of the said inner side tubular part 2 is set to the range of 50%-90%. If it is less than 50%, a sufficient deodorizing effect cannot be secured, and if it exceeds 90%, a sufficient sound absorbing effect cannot be secured. Especially, it is preferable that the ratio of the area of the printing area | region where the said deodorizer was printed with respect to the whole inner peripheral surface of the said inner side tubular part 2 is the range of 60%-80%.

なお、グラビア印刷の印刷模様等は、特に限定されるものではなく、印刷領域の面積の割合を50%〜90%の範囲に設定できるものであれば、どのような模様であってもよく、図1に示すようなストライプ状の他、ドット状等を例示できる。   The gravure printing pattern is not particularly limited, and any pattern may be used as long as the ratio of the area of the printing region can be set in the range of 50% to 90%. In addition to the stripe shape as shown in FIG.

前記消臭剤固着部5は、消臭剤及びバインダー樹脂を含有する消臭剤組成物を前記スパンボンド不織布の片面(管状に形成した時に内周面になる面)にグラビア印刷により印刷した後、乾燥させることにより形成できる。   The deodorant fixing part 5 is printed with a deodorant composition containing a deodorant and a binder resin on one side of the spunbonded nonwoven fabric (the surface that becomes the inner peripheral surface when formed into a tubular shape) by gravure printing. It can be formed by drying.

前記消臭剤の固着量は1.5g/m2〜4.0g/m2であるのが好ましい。1.5g/m2以上であることで消臭性能をより向上できると共に、4.0g/m2以下であることで軽量性を維持できる。 Fixed amount of the deodorant is preferably 1.5g / m 2 ~4.0g / m 2 . The deodorizing performance can be further improved by being 1.5 g / m 2 or more, and the lightness can be maintained by being 4.0 g / m 2 or less.

前記バインダー樹脂の固着量は0.6g/m2〜1.6g/m2であるのが好ましい。0.6g/m2以上であることで消臭剤の脱落を十分に防止できると共に、1.6g/m2以下であることで消臭剤の表面を十分に露出させることができて消臭性能をより向上できる。 Fixed amount of the binder resin is preferably 0.6g / m 2 ~1.6g / m 2 . It is possible to sufficiently prevent the deodorant from falling off when it is 0.6 g / m 2 or more, and it is possible to sufficiently expose the surface of the deodorant when it is 1.6 g / m 2 or less. Performance can be improved.

なお、上記消臭剤の固着量(g/m2)を算出する際の(分母となる)面積は、内側管状部2の内周面の全体面積(印刷領域21の面積と非印刷領域22の面積の合計)である。上記バインダー樹脂の固着量(g/m2)についても同様である。 In addition, the area (which becomes the denominator) when calculating the fixed amount (g / m 2 ) of the deodorant is the entire area of the inner peripheral surface of the inner tubular portion 2 (the area of the printing region 21 and the non-printing region 22). Of the total area). The same applies to the fixing amount (g / m 2 ) of the binder resin.

前記消臭剤としては、特に限定されるものではないが、例えば、金属酸化物と、アミン化合物と、多孔質無機物質とを含む消臭剤が好適である。中でも、前記消臭剤としては、亜鉛酸化物及び鉄酸化物からなる群より選ばれる少なくとも1種の金属酸化物と、ヒドラジン誘導体と、シリカゲルと、を含む消臭剤を用いるのがより好ましく、この場合にはホルムアルデヒド臭、アミン臭を効率良く十分に消臭することができる。   Although it does not specifically limit as said deodorizer, For example, the deodorizer containing a metal oxide, an amine compound, and a porous inorganic substance is suitable. Among them, as the deodorant, it is more preferable to use a deodorant containing at least one metal oxide selected from the group consisting of zinc oxide and iron oxide, a hydrazine derivative, and silica gel, In this case, formaldehyde odor and amine odor can be efficiently and sufficiently deodorized.

前記バインダー樹脂としては、特に限定されるものではないが、例えば、ウレタン系樹脂、アクリル系樹脂、エチレン−酢酸ビニル共重合体樹脂等が挙げられる。   Although it does not specifically limit as said binder resin, For example, urethane type resin, acrylic resin, ethylene-vinyl acetate copolymer resin etc. are mentioned.

前記消臭剤組成物には、通常、消臭剤及びバインダー樹脂とともに溶媒が混合される。前記溶媒としては、特に限定されるものではないが、例えば、水、エタノール等が挙げられる。前記消臭剤組成物は、通常は、バインダー樹脂と溶媒とでエマルジョンが形成されていて、溶媒に消臭剤(粒子)が分散された液体である。   A solvent is usually mixed with the deodorant composition together with the deodorant and the binder resin. The solvent is not particularly limited, and examples thereof include water and ethanol. The deodorant composition is usually a liquid in which an emulsion is formed with a binder resin and a solvent, and the deodorant (particles) is dispersed in the solvent.

前記消臭剤組成物における消臭剤の含有率は、2質量%〜30質量%に設定されるのが好ましい。前記消臭剤組成物におけるバインダー樹脂の含有率は、0.8質量%〜12質量%に設定されるのが好ましい。   The content of the deodorant in the deodorant composition is preferably set to 2% by mass to 30% by mass. The binder resin content in the deodorant composition is preferably set to 0.8 mass% to 12 mass%.

次に、本発明の具体的実施例について説明するが、本発明はこれら実施例のものに特に限定されるものではない。   Next, specific examples of the present invention will be described, but the present invention is not particularly limited to these examples.

<実施例1>
太さ9.5デシテックスのポリエチレンテレフタレート繊維で形成され、厚さ0.25mmで目付が40g/m2のスパンボンド不織布と、太さ(直径)15μmのガラス繊維で形成され、厚さ25mmで嵩密度が16kg/m3のグラスウールをそれぞれ準備した。
<Example 1>
Formed with polyethylene terephthalate fiber with a thickness of 9.5 dtex, formed with a spunbond nonwoven fabric with a thickness of 0.25 mm and a basis weight of 40 g / m 2 , and a glass fiber with a thickness (diameter) of 15 μm. Glass wool having a density of 16 kg / m 3 was prepared.

次に、亜鉛酸化物7質量部、シリカゲル8質量部、ヒドラジン誘導体5質量部、ウレタン系バインダー樹脂8質量部、水72質量部からなる消臭剤組成物を、前記スパンボンド不織布の片面にストライプ状にグラビア印刷した後、乾燥させることによって、片面に部分的に消臭剤がウレタン系バインダー樹脂で固着されたスパンボンド不織布を得た。前記グラビア印刷されたスパンボンド不織布において、消臭剤の固着量は2.0g/m2であり、バインダー樹脂の固着量は0.8g/m2であった。 Next, a deodorant composition comprising 7 parts by mass of zinc oxide, 8 parts by mass of silica gel, 5 parts by mass of hydrazine derivative, 8 parts by mass of urethane binder resin, and 72 parts by mass of water is striped on one side of the spunbond nonwoven fabric. After gravure printing in a shape, drying was performed to obtain a spunbonded nonwoven fabric in which a deodorant was partially fixed on one side with a urethane-based binder resin. In the gravure printed spunbonded nonwoven fabric, the fixed amount of the deodorant was 2.0 g / m 2 and the fixed amount of the binder resin was 0.8 g / m 2 .

前記消臭剤固着スパンボンド不織布を用いて消臭剤固着面が内周面になるようにして形成した内側管状部2の外側を、前記グラスウールからなる中間管状部3で被覆し、さらに該中間管状部の外側を、厚さ0.1mmのポリエチレン樹脂製シートからなる外側管状部4で被覆することによって、図1に示す消臭機能を有するダクト(内径100mm、外形150mm、長さ10m)を得た。   The outside of the inner tubular portion 2 formed using the deodorant-fixed spunbond nonwoven fabric so that the deodorant-fixing surface is an inner peripheral surface is coated with the intermediate tubular portion 3 made of the glass wool, and further By covering the outer side of the tubular part with the outer tubular part 4 made of a polyethylene resin sheet having a thickness of 0.1 mm, the duct (inner diameter 100 mm, outer diameter 150 mm, length 10 m) having a deodorizing function shown in FIG. Obtained.

得られたダクトにおいて、内側管状部の内周面の全体に対する前記消臭剤が印刷された印刷領域21の面積の割合は70%であり、前記消臭剤が印刷されていない非印刷領域22の面積の割合は30%であった。   In the obtained duct, the ratio of the area of the printing region 21 on which the deodorant is printed to the entire inner peripheral surface of the inner tubular portion is 70%, and the non-printing region 22 on which the deodorant is not printed. The area ratio was 30%.

<実施例2>
グラビア印刷の際の印刷面積の設定を変更することによって、印刷領域の面積の割合を55%、非印刷領域の面積の割合を45%とした以外は、実施例1と同様にして、消臭機能を有するダクトを得た。
<Example 2>
Deodorizing in the same manner as in Example 1 except that the ratio of the area of the printing region was changed to 55% and the area ratio of the non-printing area was changed to 45% by changing the setting of the printing area during gravure printing. A functional duct was obtained.

<実施例3>
グラビア印刷の際の印刷面積の設定を変更することによって、印刷領域の面積の割合を85%、非印刷領域の面積の割合を15%とした以外は、実施例1と同様にして、消臭機能を有するダクトを得た。
<Example 3>
Deodorizing in the same manner as in Example 1 except that the ratio of the area of the print area is 85% and the area ratio of the non-print area is 15% by changing the setting of the print area during gravure printing. A functional duct was obtained.

<比較例1>
グラビア印刷の際の印刷面積の設定を変更することによって、印刷領域の面積の割合を10%、非印刷領域の面積の割合を90%とした以外は、実施例1と同様にして、消臭機能を有するダクトを得た。
<Comparative Example 1>
Deodorizing in the same manner as in Example 1 except that the ratio of the area of the print area is changed to 10% and the area ratio of the non-print area is changed to 90% by changing the setting of the print area at the time of gravure printing. A functional duct was obtained.

<比較例2>
グラビア印刷の際の印刷面積の設定を変更することによって、印刷領域の面積の割合を95%、非印刷領域の面積の割合を5%とした以外は、実施例1と同様にして、消臭機能を有するダクトを得た。
<Comparative example 2>
Deodorizing in the same manner as in Example 1 except that the ratio of the area of the printing region was changed to 95% and the area ratio of the non-printing area was changed to 5% by changing the setting of the printing area at the time of gravure printing. A functional duct was obtained.

<比較例3>
実施例1の消臭剤組成物液中に、実施例1と同一構成のスパンボンド不織布を含浸せしめた後、該不織布を取り出して乾燥させることによって、消臭剤がウレタン系バインダー樹脂で固着されたスパンボンド不織布を得た以外は、実施例1と同様にして、消臭機能を有するダクトを得た。この比較例3における消臭剤の固着量は算出していない。
<Comparative Example 3>
The deodorant composition liquid of Example 1 was impregnated with a spunbonded nonwoven fabric having the same structure as Example 1, and then the nonwoven fabric was taken out and dried to fix the deodorant with the urethane-based binder resin. A duct having a deodorizing function was obtained in the same manner as in Example 1 except that the spunbond nonwoven fabric was obtained. The fixed amount of the deodorant in Comparative Example 3 is not calculated.

<比較例4>
スパンボンド不織布に代えて、太さ8デシテックスのポリプロピレン繊維で形成され、厚さ1.0mmで目付が70g/m2のニードルパンチ不織布を用いて実施例1と同様にしてダクトの成型を行ったが、成型時にニードルパンチ不織布が破断してしまい、内側管状部を成型することができず、ダクトを得ることはできなかった。従って、この比較例4について後述する各種評価は行っていない。また、この比較例4における消臭剤の固着量は算出していない。
<Comparative example 4>
In place of the spunbond nonwoven fabric, a duct was formed in the same manner as in Example 1 using a needle punched nonwoven fabric formed of polypropylene fiber having a thickness of 8 dtex and a thickness of 1.0 mm and a basis weight of 70 g / m 2 . However, the needle punched nonwoven fabric was broken at the time of molding, and the inner tubular portion could not be molded, and a duct could not be obtained. Therefore, various evaluations described later with respect to Comparative Example 4 are not performed. Moreover, the fixed amount of the deodorant in Comparative Example 4 was not calculated.

<比較例5>
スパンボンド不織布に代えて、太さ20デシテックスのポリエチレンテレフタレート繊維で形成され、厚さ5.0mmで目付が150g/m2のケミカルボンド不織布を用いた以外は、実施例1と同様にして、消臭機能を有するダクトを得た。
<Comparative Example 5>
In place of the spunbond nonwoven fabric, the same as in Example 1 except that a chemical bond nonwoven fabric formed of polyethylene terephthalate fiber having a thickness of 20 dtex and having a thickness of 5.0 mm and a basis weight of 150 g / m 2 was used. A duct having an odor function was obtained.

Figure 2014231916
Figure 2014231916

上記のようにして得られた各ダクトについて下記評価法に基づいて評価を行った。その結果を表1に示す。   Each duct obtained as described above was evaluated based on the following evaluation method. The results are shown in Table 1.

<消臭性能評価法>
送風機の送出口に長さ10mのダクトを接続したもの(ダクト接続送風機)を、容積12m3のステンレス製チャンバー内に配置した。次に、チャンバー内を、ホルムアルデヒドを10ppm、トリメチルアミンを10ppmの濃度で含有する空気で満たしてチャンバーを気密状態にした後、送風機を運転することにより、チャンバー内の空気を送風機の送出口を介してダクト内に風速6.0m/秒で3時間送気し続けた。ダクト内に3時間送気した後、チャンバー内のホルムアルデヒドの濃度、トリメチルアミン濃度をガス検知管によって測定し、下記算出式により臭気除去率(%)を求めた。なお、下記算出式において、「h」は、3時間送気後のホルムアルデヒド濃度(ppm)であり、「t」は、3時間送気後のトリメチルアミン濃度(ppm)である。
<Deodorization performance evaluation method>
A 10 m long duct connected to the outlet of the blower (duct connection blower) was placed in a stainless steel chamber having a volume of 12 m 3 . Next, after the chamber is filled with air containing formaldehyde at 10 ppm and trimethylamine at a concentration of 10 ppm to make the chamber airtight, the air in the chamber is passed through the outlet of the fan by operating the fan. Air was continuously supplied into the duct at a wind speed of 6.0 m / sec for 3 hours. After the gas was fed into the duct for 3 hours, the concentration of formaldehyde and trimethylamine in the chamber were measured with a gas detector tube, and the odor removal rate (%) was determined by the following formula. In the following calculation formula, “h” is the formaldehyde concentration (ppm) after 3 hours of air supply, and “t” is the trimethylamine concentration (ppm) after 3 hours of air supply.

ホルムアルデヒド除去率(%)={(10−h)/10}×100
トリメチルアミン除去率(%)={(10−t)/10}×100
(判定基準)
「○」…ホルムアルデヒド除去率とトリメチルアミン除去率の平均値が90%以上である。
「△」…ホルムアルデヒド除去率とトリメチルアミン除去率の平均値が70%以上90%未満である。
「×」…ホルムアルデヒド除去率とトリメチルアミン除去率の平均値が70%未満である。
Formaldehyde removal rate (%) = {(10−h) / 10} × 100
Trimethylamine removal rate (%) = {(10−t) / 10} × 100
(Criteria)
“◯”: The average value of the formaldehyde removal rate and the trimethylamine removal rate is 90% or more.
“Δ”: The average value of formaldehyde removal rate and trimethylamine removal rate is 70% or more and less than 90%.
“X”: The average value of the formaldehyde removal rate and the trimethylamine removal rate is less than 70%.

<吸音性能評価法>
長さ10mのダクトの一端開口部を、運転中の空調設備の騒音発生部(90dBの大きさの音が発生)に近接せしめた状態とし、ダクト内部の他端開口部から10cm内方に入った位置において聴取される音の大きさを測定し、下記判定基準に基づきダクトの吸音性能を評価した。
(判定基準)
「○」…ダクトの他端開口部での聴取音の大きさが55dB以下である。
「△」…ダクトの他端開口部での聴取音の大きさが55dBを超えて75dB以下である。
「×」…ダクトの他端開口部での聴取音の大きさが75dBを超えている。
<Sound absorption performance evaluation method>
One end opening of the duct with a length of 10m is brought close to the noise generating part of the air-conditioning equipment in operation (a sound with a magnitude of 90 dB is generated), and enters 10 cm inward from the other end opening inside the duct. The loudness of the sound heard at each position was measured, and the sound absorption performance of the duct was evaluated based on the following criteria.
(Criteria)
“◯”... Listening sound at the opening at the other end of the duct is 55 dB or less.
“Δ”: The volume of the listening sound at the opening at the other end of the duct is more than 55 dB and 75 dB or less.
“X”: The volume of the listening sound at the opening at the other end of the duct exceeds 75 dB.

<断熱性能評価法>
25℃の室内雰囲気(空気)中において、長さ10mのダクト1内に−10℃の冷風を風速6m/秒で12時間流し続けた後、ダクトの外周面における結露の発生の有無を調べ、下記判定基準に基づき評価した。
(判定基準)
「○」…ダクトの外周面に結露は認められなかった。
「△」…ダクトの外周面に結露が少し認められた。
「×」…ダクトの外周面に結露が顕著に認められた。
<Insulation performance evaluation method>
In a 25 ° C. indoor atmosphere (air), after −10 ° C. cold air was allowed to flow at a wind speed of 6 m / second for 12 hours in a 10 m long duct 1, the presence or absence of condensation on the outer peripheral surface of the duct was examined. Evaluation was made based on the following criteria.
(Criteria)
“◯”: No condensation was observed on the outer peripheral surface of the duct.
“△”: Some condensation was observed on the outer peripheral surface of the duct.
“×”: Condensation was remarkably observed on the outer peripheral surface of the duct.

表から明らかなように、実施例1〜3のダクトは、十分な断熱性と吸音性を備え、さらに優れた消臭性を有している。   As is apparent from the table, the ducts of Examples 1 to 3 have sufficient heat insulating properties and sound absorbing properties, and further have excellent deodorizing properties.

これに対し、印刷領域の面積の割合が本発明の規定範囲の下限より小さい比較例1では、十分な消臭性能が得られなかった。また、印刷領域の面積の割合が本発明の規定範囲の上限より大きい比較例2では、十分な消臭性能は得られるものの、吸音性能が良好ではなかった。含浸法により消臭剤を固着せしめた比較例3では、十分な吸音性能が得られなかった。ニードルパンチ不織布で内側管状部を形成した比較例4では、不織布の引張強度が不足しているので、成型時に不織布が破断してしまい、ダクト形状に成形できないという問題があった。また、ケミカルボンド不織布で内側管状部を形成した比較例5では、不織布の通気度が十分でないために、断熱性能及び吸音性能に劣っていた。   On the other hand, in Comparative Example 1 in which the ratio of the area of the printing region is smaller than the lower limit of the specified range of the present invention, sufficient deodorizing performance was not obtained. Further, in Comparative Example 2 in which the area ratio of the printing region is larger than the upper limit of the specified range of the present invention, although sufficient deodorizing performance can be obtained, the sound absorbing performance is not good. In Comparative Example 3 in which the deodorant was fixed by the impregnation method, sufficient sound absorbing performance was not obtained. In Comparative Example 4 in which the inner tubular portion was formed of a needle punched nonwoven fabric, there was a problem that the nonwoven fabric was broken at the time of molding because the nonwoven fabric was insufficient in tensile strength and could not be molded into a duct shape. Moreover, in the comparative example 5 which formed the inner side tubular part with the chemical bond nonwoven fabric, since the air permeability of the nonwoven fabric was not enough, it was inferior to heat insulation performance and sound absorption performance.

本発明に係る消臭機能を有するダクトは、例えば、空調設備用ダクト等として使用されるが、特にこのような用途に限定されるものではない。   The duct having a deodorizing function according to the present invention is used as, for example, a duct for air conditioning equipment, but is not particularly limited to such an application.

1…ダクト
2…内側管状部
3…中間管状部
4…外側管状部
5…消臭剤固着部
21…印刷領域
22…非印刷領域
DESCRIPTION OF SYMBOLS 1 ... Duct 2 ... Inner tubular part 3 ... Intermediate tubular part 4 ... Outer tubular part 5 ... Deodorant fixed part 21 ... Print area 22 ... Non-print area

Claims (6)

厚さ0.1mm〜0.8mmで目付が30g/m2〜120g/m2のスパンボンド不織布を含む内側管状部と、
前記内側管状部の外側に設けられて該内側管状部を被覆する中間管状部と、
前記中間管状部の外側に設けられて該中間管状部を被覆する外側管状部とを備え、
前記中間管状部は、厚さ20mm〜60mmで嵩密度が12kg/m3〜30kg/m3のグラスウールを含み、
前記内側管状部の内周面の一部に消臭剤がグラビア印刷により固着され、前記内側管状部の内周面の全体に対する前記消臭剤が印刷された印刷領域の面積の割合が50%〜90%の範囲であることを特徴とする消臭機能を有するダクト。
An inner tubular portion containing 30g / m 2 ~120g / m 2 spunbond nonwoven having a basis weight in the thickness 0.1Mm~0.8Mm,
An intermediate tubular portion that is provided outside the inner tubular portion and covers the inner tubular portion;
An outer tubular portion provided outside the intermediate tubular portion and covering the intermediate tubular portion;
The intermediate tubular portion, the bulk density in thickness 20mm~60mm comprises glass wool of 12kg / m 3 ~30kg / m 3 ,
A deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion by gravure printing, and the ratio of the area of the print area where the deodorant is printed to the entire inner peripheral surface of the inner tubular portion is 50%. A duct having a deodorizing function, characterized by being in a range of ˜90%.
前記消臭剤の固着量が1.5g/m2〜4.0g/m2である請求項1に記載の消臭機能を有するダクト。 Ducts amount fixation of the deodorant has a deodorizing function according to claim 1 is 1.5g / m 2 ~4.0g / m 2 . 前記消臭剤は、前記内側管状部の内周面の一部にバインダー樹脂で固着され、
前記バインダー樹脂の固着量が0.6g/m2〜1.6g/m2である請求項1または2に記載の消臭機能を有するダクト。
The deodorant is fixed to a part of the inner peripheral surface of the inner tubular portion with a binder resin,
Ducts amount sticking of the binder resin has a deodorizing function according to claim 1 or 2 is 0.6g / m 2 ~1.6g / m 2 .
前記スパンボンド不織布を構成する繊維は、ポリエステル系樹脂で形成され、前記バインダー樹脂としてウレタン系バインダー樹脂が用いられている請求項3に記載の消臭機能を有するダクト。   The duct which has the deodorizing function of Claim 3 in which the fiber which comprises the said spun bond nonwoven fabric is formed with a polyester-type resin, and the urethane type binder resin is used as the said binder resin. 前記スパンボンド不織布を構成する繊維の太さが、7.5デシテックス〜15.0デシテックスの範囲である請求項1〜4のいずれか1項に記載の消臭機能を有するダクト。   The duct having the deodorizing function according to any one of claims 1 to 4, wherein a thickness of a fiber constituting the spunbonded nonwoven fabric is in a range of 7.5 dtex to 15.0 dtex. 前記内側管状部のスパンボンド不織布による多孔質構造と、前記中間管状部のグラスウールによる多孔質構造とが、相互の界面を介して連通しており、
前記グラスウールを構成する繊維の太さが、1μm〜30μmの範囲である請求項1〜5のいずれか1項に記載の消臭機能を有するダクト。
The porous structure made of spunbonded nonwoven fabric of the inner tubular part and the porous structure made of glass wool of the intermediate tubular part are communicated with each other via the mutual interface,
The duct having the deodorizing function according to any one of claims 1 to 5, wherein a thickness of the fiber constituting the glass wool is in a range of 1 µm to 30 µm.
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Cited By (1)

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DE102015117841A1 (en) 2014-11-14 2016-05-19 Toyota Jidosha Kabushiki Kaisha Fuel cell system, vehicle with fuel cell mounted thereon, and method of controlling the fuel cell system

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JPH07217980A (en) * 1994-02-04 1995-08-18 Kawai Musical Instr Mfg Co Ltd Air supply and exhaust ducts
JPH09166278A (en) * 1995-12-15 1997-06-24 Kuraray Plast Kk Heat insulated duct
JPH1183144A (en) * 1997-07-15 1999-03-26 Fujimori Sangyo Kk Flexible duct
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JP2007034254A (en) * 2005-06-23 2007-02-08 Bridgestone Kbg Co Ltd Porous material-based sound absorbing material with improved sound absorbing performance
JP2008224180A (en) * 2007-03-15 2008-09-25 Totaku Industries Inc Duct hose
JP2008267690A (en) * 2007-04-20 2008-11-06 Kuraray Plast Co Ltd Fireproof or fire-retardant heat insulating resin duct
JP2008281276A (en) * 2007-05-10 2008-11-20 Fujimori Sangyo Kk Air conditioning duct, or component for air conditioning duct

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Publication number Priority date Publication date Assignee Title
JPH07217980A (en) * 1994-02-04 1995-08-18 Kawai Musical Instr Mfg Co Ltd Air supply and exhaust ducts
JPH09166278A (en) * 1995-12-15 1997-06-24 Kuraray Plast Kk Heat insulated duct
JPH1183144A (en) * 1997-07-15 1999-03-26 Fujimori Sangyo Kk Flexible duct
JP2004347298A (en) * 2003-05-26 2004-12-09 Suminoe Textile Co Ltd Air cleaning system
JP2007034254A (en) * 2005-06-23 2007-02-08 Bridgestone Kbg Co Ltd Porous material-based sound absorbing material with improved sound absorbing performance
JP2008224180A (en) * 2007-03-15 2008-09-25 Totaku Industries Inc Duct hose
JP2008267690A (en) * 2007-04-20 2008-11-06 Kuraray Plast Co Ltd Fireproof or fire-retardant heat insulating resin duct
JP2008281276A (en) * 2007-05-10 2008-11-20 Fujimori Sangyo Kk Air conditioning duct, or component for air conditioning duct

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015117841A1 (en) 2014-11-14 2016-05-19 Toyota Jidosha Kabushiki Kaisha Fuel cell system, vehicle with fuel cell mounted thereon, and method of controlling the fuel cell system

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