JP2014217305A - Panose-containing cocoa beverage - Google Patents
Panose-containing cocoa beverage Download PDFInfo
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- JP2014217305A JP2014217305A JP2013097908A JP2013097908A JP2014217305A JP 2014217305 A JP2014217305 A JP 2014217305A JP 2013097908 A JP2013097908 A JP 2013097908A JP 2013097908 A JP2013097908 A JP 2013097908A JP 2014217305 A JP2014217305 A JP 2014217305A
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- cocoa
- panose
- cocoa beverage
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- branched oligosaccharide
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- 235000009470 Theobroma cacao Nutrition 0.000 title claims abstract description 217
- 235000013361 beverage Nutrition 0.000 title claims abstract description 170
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- 229920002261 Corn starch Polymers 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
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- 208000008454 Hyperhidrosis Diseases 0.000 description 1
- AYRXSINWFIIFAE-SCLMCMATSA-N Isomaltose Natural products OC[C@H]1O[C@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)[C@@H](O)[C@@H](O)[C@@H]1O AYRXSINWFIIFAE-SCLMCMATSA-N 0.000 description 1
- CTEMZTQLPNKNKP-REGJXUDFSA-N Maltosyl trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O[C@@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)[C@@H](CO)O2)O)[C@@H](CO)O1 CTEMZTQLPNKNKP-REGJXUDFSA-N 0.000 description 1
- 241000486437 Panolis Species 0.000 description 1
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- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
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- 238000011033 desalting Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930182486 flavonoid glycoside Natural products 0.000 description 1
- 150000007955 flavonoid glycosides Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- DBTMGCOVALSLOR-AXAHEAMVSA-N galactotriose Natural products OC[C@@H]1O[C@@H](O[C@@H]2[C@@H](O)[C@H](CO)O[C@@H](O[C@H]3[C@@H](O)[C@H](O)O[C@@H](CO)[C@@H]3O)[C@@H]2O)[C@H](O)[C@H](O)[C@H]1O DBTMGCOVALSLOR-AXAHEAMVSA-N 0.000 description 1
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- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- FBJQEBRMDXPWNX-FYHZSNTMSA-N isomaltotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](OC[C@@H]2[C@H]([C@H](O)[C@@H](O)C(O)O2)O)O1 FBJQEBRMDXPWNX-FYHZSNTMSA-N 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 210000000496 pancreas Anatomy 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000020185 raw untreated milk Nutrition 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Confectionery (AREA)
- Non-Alcoholic Beverages (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
Abstract
Description
技術分野
本発明はココア飲料に関し、更に詳細には、パノースを含むココア飲料である。
TECHNICAL FIELD The present invention relates to a cocoa beverage, and more particularly a cocoa beverage comprising panose.
背景技術
現在、容器入り飲料は、スチール缶、アルミ缶、PET容器、またはガラス瓶等に封入されて流通し、小売店の店頭や自動販売機などで販売される。特に、冬季にはホットベンダー中で加温された状態で販売されることもあるため、その場合には飲料は容器中で長期間加温され続ける。
BACKGROUND ART Presently, beverages in containers are distributed in steel cans, aluminum cans, PET containers, glass bottles, etc., and sold at retail stores or vending machines. In particular, since it is sometimes sold in a hot bender in the winter, the beverage continues to be heated in the container for a long period of time.
ホットココアは冬季に需要が高く、ホットベンダー中でココア飲料を一定時間加温された状態で販売されることが多い。しかしながら、ココア飲料をホットベンダー等で一定時間以上加温された場合には、汗で蒸れたような好ましくない臭い(ムレ臭)が発生するとの問題があった。 Hot cocoa is in high demand in winter and is often sold in hot benders with the cocoa beverage heated for a certain period of time. However, when the cocoa beverage is heated by a hot bender or the like for a certain period of time, there is a problem that an unpleasant odor (swelling odor) such as stuffy with sweat is generated.
このムレ臭の発生により、ココア飲料の品質が劣化し、商品価値が低下してしまうことから、ココア飲料をホットベンダー等で一定時間以上加温された場合であってもムレ臭低減効果を有するココア飲料が希求されているといえる。 Since the quality of the cocoa beverage deteriorates and the commercial value is lowered due to the generation of the stuffy odor, the cocoa beverage has a stuffy odor reducing effect even when the cocoa beverage is heated by a hot bender or the like for a certain period of time or more. It can be said that cocoa beverages are in demand.
ここで、特開2007―135404号公報(特許文献1)には、イソマルトオリゴ糖とデンプン分解物の混合物を用いた飲料の風味の改善が開示されているが、ココア飲料のムレ臭低減効果については全く開示も示唆もなされていない。 Here, JP 2007-135404 A (Patent Document 1) discloses an improvement in beverage flavor using a mixture of isomaltoligosaccharide and starch degradation product. Is not disclosed or suggested at all.
また、特開2011―83248号公報(特許文献2)には、重合度5〜10の分岐糖類を含んでなる風味改善剤および製剤用マスキング剤が開示されているが、パノースを含むココア飲料において、ムレ臭を低減することについては全く開示も示唆もなされていない。 JP 2011-83248A (Patent Document 2) discloses a flavor improving agent and a masking agent for preparations containing branched sugars having a polymerization degree of 5 to 10, but in cocoa beverages containing panose, However, there is no disclosure or suggestion about reducing the odor.
更に、特開2007―49962号公報(特許文献3)には、マルトシルトレハロースを含有するココアドリンクがレトルト臭や、ムレ臭を低減することについて開示されているが、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含むココア飲料において、ムレ臭が低減されることについては全く開示も示唆もなされていない。 Furthermore, JP-A 2007-49962 (Patent Document 3) discloses that a cocoa drink containing maltosyl trehalose reduces retort odor and stuffy odor. However, a branch containing panose or panose is disclosed. There is no disclosure or suggestion that the stuffy odor is reduced in a cocoa beverage containing an oligosaccharide-containing composition.
本発明は、ココア飲料、特にココア成分や乳固形分の含有量が多いココア飲料において、加熱時、特に加熱保管時において発生する、ムレ臭が低減され、ココア飲料の品質が改善されたココア飲料を提供することを一つの目的とする。 The present invention relates to a cocoa beverage, particularly a cocoa beverage having a high content of cocoa components and milk solids, which has a reduced stuffy odor that occurs during heating, particularly during heating and storage, and has improved the quality of the cocoa beverage. One purpose is to provide
本発明者らは、ココア飲料、特にココア成分や乳固形分の含有量が多いココア飲料に、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させることにより、当該ココア飲料を一定時間加熱した場合であっても、ムレ臭の発生を抑えることができ、ココア飲料の品質が改善することを見出した。本発明はこれらの知見に基づくものである。 The inventors of the present invention heat a cocoa beverage for a certain period of time by including a branched oligosaccharide-containing composition containing panose or panose in a cocoa beverage, particularly a cocoa beverage having a high content of cocoa components and milk solids. Even in this case, it was found that the generation of stuffy odor can be suppressed and the quality of the cocoa beverage is improved. The present invention is based on these findings.
本発明によれば、以下の(1)〜(14)の発明が提供される。
(1)パノースを含む、ココア飲料。
(2)パノースを含有する分岐オリゴ糖含有組成物を含む、ココア飲料。
(3)パノースが、ココア飲料に対して、0.002〜0.2質量%含まれる、(1)または(2)に記載のココア飲料。
(4)パノースを含有する分岐オリゴ糖含有組成物が、マルミノース(登録商標)、パノックスA(登録商標)、パノリッチ(登録商標)、およびパノラップ(登録商標)からなる群から選択される一種または二種以上である、(2)または(3)に記載のココア飲料。
(5)カカオ分が、ココア飲料に対して、0.5以上10質量%未満含まれる、(1)〜(4)のいずれかに記載のココア飲料。
(6)ヤマモモ科植物抽出物を更に含む、(1)〜(5)のいずれかに記載のココア飲料。
(7)ヤマモモ科植物抽出物が、ココア飲料に対して、0.005〜0.1質量%含まれる、(6)に記載のココア飲料。
(8)容器入りである、(1)〜(7)のいずれかに記載のココア飲料。
(9)ココア飲料に、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を加える工程を含む、パノース含有ココア飲料の製造方法。
(10)ヤマモモ科植物抽出物を更に加える工程を含む、(9)に記載の製造方法。
(11)(9)または(10)に記載の製造方法により製造される、ココア飲料。
(12)(1)〜(8)または(11)のいずれかに記載のココア飲料を、40〜70℃で1時間以上保温する、保管方法。
(13)(12)に記載の保管方法により保管される、ココア飲料。
(14)パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させることを特徴とする、ココア飲料のムレ臭低減方法。
According to the present invention, the following inventions (1) to (14) are provided.
(1) A cocoa beverage containing panose.
(2) A cocoa beverage comprising a branched oligosaccharide-containing composition containing panose.
(3) The cocoa beverage according to (1) or (2), wherein the panose is contained in an amount of 0.002 to 0.2% by mass with respect to the cocoa beverage.
(4) One or two branched oligosaccharide-containing compositions containing panose are selected from the group consisting of malminose (registered trademark), panox A (registered trademark), panoric (registered trademark), and panorup (registered trademark). The cocoa drink according to (2) or (3), which is a seed or more.
(5) The cocoa beverage according to any one of (1) to (4), wherein the cacao content is 0.5 to less than 10% by mass with respect to the cocoa beverage.
(6) The cocoa drink according to any one of (1) to (5), further comprising an extract of a plant of the department of genus department.
(7) The cocoa beverage according to (6), wherein the bayberry plant extract is contained in an amount of 0.005 to 0.1% by mass with respect to the cocoa beverage.
(8) The cocoa beverage according to any one of (1) to (7), which is contained in a container.
(9) A method for producing a panose-containing cocoa beverage, comprising adding a panose or a branched oligosaccharide-containing composition containing panose to a cocoa beverage.
(10) The production method according to (9), further comprising a step of adding a plant extract.
(11) A cocoa beverage produced by the production method according to (9) or (10).
(12) A storage method in which the cocoa beverage according to any one of (1) to (8) or (11) is kept warm at 40 to 70 ° C for 1 hour or more.
(13) A cocoa beverage stored by the storage method according to (12).
(14) A method for reducing the stuffy odor of a cocoa beverage, which comprises panose or a branched oligosaccharide-containing composition containing panose.
本発明によれば、ココア飲料、特にココア成分や乳固形分の含有量が多いココア飲料に、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させることにより、好ましくはヤマモモ科植物抽出物を更に含有させることにより、ホットベンダー等で一定時間以上加熱、特に加熱保管されたされた場合であってもムレ臭が低減でき、ココア飲料の品質を改善することができる点で有利である。 According to the present invention, a cocoa beverage, particularly a cocoa beverage with a high content of cocoa components and milk solids, is preferably incorporated with a bayberry plant extract by containing a branched oligosaccharide-containing composition containing panose or panose. Furthermore, it is advantageous in that the stuffy odor can be reduced and the quality of the cocoa beverage can be improved even when heated by a hot bender or the like for a certain period of time, particularly when heated and stored.
<ココア飲料>
本発明のココア飲料は、パノース(3糖類の一種)(panose)を含むココア飲料である。以下、本発明のココア飲料について詳述する。
<Cocoa drink>
The cocoa drink of the present invention is a cocoa drink containing panose (a type of trisaccharide). Hereinafter, the cocoa beverage of the present invention will be described in detail.
パノースについて
本発明のココア飲料は、パノースが含まれる。ココア飲料にパノースを含有する分岐オリゴ糖含有組成物を含有させることにより、ココア飲料中にパノースを含有させてもよく、またパノースを単独でココア飲料に加えて含有させてもよい。
About Panose The cocoa beverage of the present invention includes panose. By containing a branched oligosaccharide-containing composition containing panose in the cocoa beverage, panose may be contained in the cocoa beverage, or panose alone may be added to the cocoa beverage.
従って、本発明のココア飲料は、パノースを含むココア飲料であってもよく、またパノースを含有する分岐オリゴ糖含有組成物を含むココア飲料であってもよい。 Therefore, the cocoa beverage of the present invention may be a cocoa beverage containing panose or a cocoa beverage containing a branched oligosaccharide-containing composition containing panose.
また、パノースは、市販のパノースを含有する分岐オリゴ糖含有組成物から単離および/または精製してココア飲料に含有させてもよく、またパノースが含まれた他の市販品をそのまま、もしくは該市販品を単離および/または精製してココア飲料に含有させても良い。 Further, panose may be isolated and / or purified from a branched oligosaccharide-containing composition containing commercially available panose and contained in a cocoa beverage, or other commercially available products containing panose may be used as they are, or You may isolate and / or refine | purify a commercial item, and you may make it contain in a cocoa drink.
ここで、本発明のパノースを含有する分岐オリゴ糖含有組成物は、少なくともパノースを含むものであり、またパノース以外の分岐オリゴ糖を含んでいてもよい。分岐オリゴ糖とは、イソマルトオリゴ糖およびその還元糖をいう。また、イソマルトオリゴ糖とは、ぶどう糖が2〜10個結合したもの(オリゴ糖)のうち、α-1,4結合以外の結合を少なくとも一箇所に有するものをいう。 Here, the branched oligosaccharide-containing composition containing panose of the present invention contains at least panose and may contain a branched oligosaccharide other than panose. The branched oligosaccharide refers to isomaltoligosaccharide and its reducing sugar. Moreover, isomalt-oligosaccharide means what has coupling | bondings other than (alpha) -1 and 4 coupling | bonding in at least one place among the thing (oligosaccharide) which 2-10 saccharides couple | bonded.
イソマルトオリゴ糖としては、パノースの他にも例えば、イソマルトース、イソマルトトリオース、イソマルトテトラオース、またはイソマルトペンタオースが挙げられる。 Examples of isomaltoligosaccharides include isomaltose, isomaltotriose, isomalttetraose, and isomaltopentaose in addition to panose.
分岐オリゴ糖含有組成物は、常法により合成した上記分岐オリゴ糖を含有させ分岐オリゴ糖含有組成物としてもよく、また市販品を用いてもよい。分岐オリゴ糖含有組成物の市販品としては、例えば、マルミノース(登録商標)(昭和産業株式会社製)、パノックスA(登録商標)(昭和産業株式会社製)、パノリッチ(登録商標)(日本食品化工株式会社製)、およびパノラップ(登録商標)(株式会社林原製)が挙げられ、これらを一種または二種以上組み合わせて用いてもよい。分岐オリゴ糖含有組成物は、上述のように市販されているものを用いてもよいが、例えば、デンプン、一般的にはコーンスターチを酵素処理し糖化、脱塩、ろ過、濃縮等を行うことで製造することができる。 The branched oligosaccharide-containing composition may contain the branched oligosaccharide synthesized by a conventional method to form a branched oligosaccharide-containing composition, or a commercially available product may be used. Commercially available branched oligosaccharide-containing compositions include, for example, Marminose (registered trademark) (manufactured by Showa Sangyo Co., Ltd.), Panox A (registered trademark) (manufactured by Showa Sangyo Co., Ltd.), Panoric (registered trademark) (Nippon Food Chemicals). And Pano Wrap (registered trademark) (produced by Hayashibara Co., Ltd.), which may be used alone or in combination of two or more. Commercially available branched oligosaccharide-containing compositions may be used as described above. For example, starch, generally corn starch, is enzymatically treated to perform saccharification, desalting, filtration, concentration, etc. Can be manufactured.
本発明の好ましい態様によれば、パノースを含有する分岐オリゴ糖含有組成物を含み、かつ該分岐オリゴ糖含有組成物が、マルミノース(登録商標)、パノックスA(登録商標)、パノリッチ(登録商標)、およびパノラップ(登録商標)からなる群から選択される一種または二種以上である、ココア飲料が提供される。 According to a preferred embodiment of the present invention, the composition comprises a branched oligosaccharide-containing composition containing panose, and the branched oligosaccharide-containing composition is malminose (registered trademark), Panox A (registered trademark), Panorich (registered trademark). And a cocoa beverage that is one or more selected from the group consisting of Panolap (registered trademark).
本発明のココア飲料に含まれるパノースは、本発明の効果を奏する限り特に限定されるものではないが、ココア飲料に対して、好ましくは0.002〜0.2質量%含まれ、より好ましくは0.005〜0.05質量%含まれる。パノースが、ココア飲料に対して、0.005〜0.05質量%含まれることにより、ホットベンダー等で一定時間以上加熱、特に加熱保管された場合であってもムレ臭をより低減することができ、ココア飲料としての品質がより改善される。 Panose contained in the cocoa beverage of the present invention is not particularly limited as long as the effects of the present invention are exhibited, but is preferably contained in an amount of 0.002 to 0.2% by mass, more preferably, with respect to the cocoa beverage. 0.005-0.05 mass% is contained. By containing 0.005 to 0.05% by mass of panose with respect to the cocoa beverage, the odor can be further reduced even when heated by a hot bender or the like for a certain period of time, particularly when heated and stored. And the quality as a cocoa beverage is further improved.
本発明のココア飲料において、パノースを含有する分岐オリゴ糖含有組成物は、本発明の効果を奏する限り特に限定されるものではないが、ココア飲料に対して、好ましくは0.01〜1質量%含まれ、より好ましくは0.025〜0.25質量%含まれる。本発明のココア飲料に、パノースを含有する分岐オリゴ糖含有組成物が0.025〜0.25質量%含まれることにより、ホットベンダー等で一定時間以上加熱、特に加熱保管されたされた場合であってもムレ臭をより低減することができ、ココア飲料の品質がより改善される。 In the cocoa beverage of the present invention, the branched oligosaccharide-containing composition containing panose is not particularly limited as long as the effect of the present invention is exhibited, but is preferably 0.01 to 1% by mass with respect to the cocoa beverage. Contained, more preferably 0.025 to 0.25% by mass. When the cocoa beverage of the present invention contains 0.025 to 0.25% by mass of a branched oligosaccharide-containing composition containing panose, the cocoa beverage is heated for a certain period of time or more by a hot bender or the like, particularly when heated and stored. Even if it exists, the stuffy odor can be further reduced and the quality of the cocoa beverage is further improved.
本発明のパノースを含有する分岐オリゴ糖含有組成物において、パノースが、分岐オリゴ糖含有組成物に対して、好ましくは10〜80質量%含まれ、より好ましくは15〜30質量%含まれる。本発明の分岐オリゴ糖含有組成物に、パノースが15〜30質量%含まれることにより、ホットベンダー等で一定時間以上加熱、特に加熱保管された場合であってもムレ臭をより低減することができ、ココア飲料の品質がより改善される。 In the branched oligosaccharide-containing composition containing panose of the present invention, panose is preferably contained in an amount of 10 to 80% by mass, more preferably 15 to 30% by mass, based on the branched oligosaccharide-containing composition. By containing 15-30% by mass of panose in the branched oligosaccharide-containing composition of the present invention, it is possible to further reduce stuffy smell even when heated by a hot bender or the like for a certain period of time, particularly when heated and stored. And the quality of the cocoa beverage is improved.
本発明のココア飲料の好ましい態様によれば、パノースを含有する分岐オリゴ糖含有組成物が、単糖類を含み、かつ分岐オリゴ糖含有組成物中の単糖類、2糖類、および3糖類の合計含有量が、分岐オリゴ糖含有組成物に対して、10〜95質量%であり、好ましくは60〜90質量%であるココア飲料が提供される。分岐オリゴ糖含有組成物には、単糖類、2糖類、および3糖類以外に、4糖類、5糖類、および6糖類以上の糖類が含まれていてもよい。 According to a preferred embodiment of the cocoa beverage of the present invention, the branched oligosaccharide-containing composition containing panose contains a monosaccharide, and the total content of the monosaccharide, disaccharide, and trisaccharide in the branched oligosaccharide-containing composition. A cocoa beverage whose amount is 10 to 95% by weight, preferably 60 to 90% by weight, based on the branched oligosaccharide-containing composition is provided. In addition to monosaccharides, disaccharides, and trisaccharides, the branched oligosaccharide-containing composition may include tetrasaccharides, pentasaccharides, and saccharides of 6 or more saccharides.
本発明のココア飲料の好ましい態様によれば、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含むムレ臭低減作用を有するココア飲料が提供される。ココア飲料は、時間の経過とともにココア飲料に特有の、すえ臭いような、汗臭いような不快な臭いを呈し、この臭いをムレ臭という。このムレ臭は、ココア飲料を、レトルト殺菌処理や、超高温瞬間滅菌(UHT殺菌)処理行った場合や、ホットベンダー等で一定時間以上加温処理されることにより、ムレ臭がより強くなる場合がある。ココア飲料に、上述のようなパノースまたはパノースを含有する分岐オリゴ糖含有組成物を加えることにより、ココア飲料のムレ臭を低減させることができる。 According to a preferred embodiment of the cocoa beverage of the present invention, there is provided a cocoa beverage having pancreas or panose-containing branched oligosaccharide-containing composition and having a curling odor reducing action. The cocoa beverage has an unpleasant odor, such as a sweaty odor, characteristic of the cocoa beverage over time, and this odor is called a stuffy odor. This stuffy odor is when the cocoa beverage is subjected to retort sterilization or ultra-high temperature flash sterilization (UHT sterilization), or when it is heated for more than a certain time with a hot bender, etc. There is. By adding the panose or the branched oligosaccharide-containing composition containing panose as described above to the cocoa beverage, the stuffy odor of the cocoa beverage can be reduced.
ヤマモモ科植物抽出物について
本発明のココア飲料の好ましい態様によれば、上記パノースまたはパノースを含有する分岐オリゴ糖含有組成物に加えて、更にヤマモモ科植物抽出物(以下、ヤマモモ抽出物と記載する場合もある)を含むココア飲料が提供される。本発明のヤマモモ科植物抽出物は、フラボノイド配糖体、特にミリシトリンを含む抽出物であり、好ましくはミリシトリンを主成分として含む。本発明のココア飲料に含まれるヤマモモ科植物抽出物としては、本発明の効果を奏する限り特に限定されるものではないが、市販品であるサンメリン(登録商標)(三栄源エフ・エフ・アイ株式会社製)(サンメリンYA−Fなど)を用いることが好ましい。また、本発明のココア飲料に含まれるヤマモモ科植物抽出物は、例えば、ヤマモモ科植物であるヤマモモまたはヤチヤナギを、有機溶媒浸漬法などの常法により抽出して用いてもよい。ココア飲料に、上記パノースまたはパノースを含有する分岐オリゴ糖含有組成物に加えて、ヤマモモ科植物抽出物を更に加えることにより、ココア飲料のムレ臭を更に低減させることができ、ココア飲料の品質を更に改善することができる。また、本発明のココア飲料に用いられるヤマモモ科植物抽出物は、油溶性を示す抽出物であっても、油溶性抽出物を酵素処理することにより水溶性化した抽出物であってもよいが、好ましくは水溶性化したヤマモモ科植物抽出物であることが好ましい。
According to a preferred embodiment of the cocoa drink of the present invention for Myricaceae plant extract, in addition to the branched oligosaccharide-containing composition containing the panose or panose, further Myricaceae plant extract (hereinafter referred to as bayberry extract A cocoa beverage comprising a (sometimes). The plant legume plant extract of the present invention is an extract containing a flavonoid glycoside, particularly myristitrin, and preferably contains mycitrin as a main component. The extract of the genus department of genus department contained in the cocoa beverage of the present invention is not particularly limited as long as the effects of the present invention are exhibited. However, Sanmerin (registered trademark) (San-Eigen FFI Co., Ltd.) is a commercially available product. (Made by company) (Sanmerin YA-F etc.) is preferably used. In addition, for example, a bayberry plant extract or a yam willow that is included in the cocoa beverage of the present invention may be extracted by a conventional method such as an organic solvent immersion method. In addition to the above-mentioned panose or the branched oligosaccharide-containing composition containing panose, in addition to the bayberry plant extract, the odor of the cocoa beverage can be further reduced, and the quality of the cocoa beverage can be improved. Further improvements can be made. In addition, the genus plant extract used in the cocoa beverage of the present invention may be an oil-soluble extract or an extract that has been water-solubilized by enzymatic treatment of the oil-soluble extract. Preferably, it is a water-soluble solanaceous plant extract.
本発明のココア飲料に含まれるヤマモモ科植物抽出物は、本発明の効果を奏する限り特に限定されないが、ココア飲料に対して、好ましくは0.005〜0.1質量%含まれ、より好ましくは0.01〜0.05質量%含まれる。本発明のココア飲料に含まれるヤマモモ科植物抽出物を、ココア飲料に対して、0.01〜0.05質量%含有させることにより、ココア飲料のムレ臭をより低減させることができ、ココア飲料として良好な品質に改善することができる。 The bayberry plant extract contained in the cocoa beverage of the present invention is not particularly limited as long as the effect of the present invention is exhibited, but is preferably contained in an amount of 0.005 to 0.1% by mass, more preferably, with respect to the cocoa beverage. 0.01-0.05 mass% is contained. By containing 0.01 to 0.05% by mass of the licorice plant extract contained in the cocoa beverage of the present invention with respect to the cocoa beverage, the stuffy odor of the cocoa beverage can be further reduced, and the cocoa beverage As a good quality can be improved.
本発明のココア飲料の好ましい態様によれば、ココア飲料に対して、パノースが0.002〜0.2質量%(好ましくは、0.005〜0.05質量%)含まれ、かつヤマモモ科植物抽出物が0.005〜0.1質量%(好ましくは、0.01〜0.05質量%)含まれるココア飲料が提供される。ヤマモモ科植物抽出物がココア飲料に含まれることにより、ココア飲料に含まれるパノースが少量であっても、ココア飲料のムレ臭をより低減させることができる。 According to a preferred embodiment of the cocoa beverage of the present invention, the panose is contained in an amount of 0.002 to 0.2% by mass (preferably 0.005 to 0.05% by mass) with respect to the cocoa beverage and A cocoa beverage containing 0.005 to 0.1% by mass (preferably 0.01 to 0.05% by mass) of the extract is provided. When the bayberry plant extract is contained in the cocoa beverage, the stuffy odor of the cocoa beverage can be further reduced even if the panose contained in the cocoa beverage is small.
その他の成分
ココア飲料とは、ココアパウダー、カカオマス、カカオニブ、ココアバター、およびカカオエキスパウダーからなる群から選択される少なくとも1種以上の原料を用いた飲料であり、本発明のココア飲料にはこれらの原料が少なくとも一種以上含まれる。また、本発明のココア飲料には、副原料として、甘味料、乳原料、植物油脂、乳化剤、安定剤、pH調整剤、香料等が含まれていてもよい。
The other component cocoa drink is a drink using at least one ingredient selected from the group consisting of cocoa powder, cacao mass, cacao nibs, cocoa butter, and cacao extract powder. At least one kind of raw material is included. In addition, the cocoa beverage of the present invention may contain sweeteners, milk ingredients, vegetable oils, emulsifiers, stabilizers, pH adjusters, fragrances and the like as auxiliary ingredients.
本発明のココア飲料に含まれてもよい甘味料としては、例えばショ糖、ぶどう糖、果糖、キシリトール等の呈味性糖類や、ステビア、アスパルテーム、アセスルファムカリウム等の高甘味度甘味料が挙げられる。 Examples of the sweetener that may be included in the cocoa beverage of the present invention include taste-sweetening sugars such as sucrose, glucose, fructose, and xylitol, and high-intensity sweeteners such as stevia, aspartame, and acesulfame potassium.
本発明のココア飲料に含まれてもよい乳原料としては、例えば牛乳や、加工乳、ホエー、全粉乳、脱脂粉乳、ミルククラム、カゼインタンパク等、生乳を原料とし加工することで得られるもののことをいう。 Examples of milk materials that may be contained in the cocoa beverage of the present invention include milk, processed milk, whey, whole milk powder, skim milk powder, milk crumb, casein protein, and the like obtained by processing raw milk as raw materials. Say.
本発明のココア飲料に含まれるカカオ分の配合は、特に限定されるものではないが、カカオ分が、ココア飲料に対して、0.5質量%以上10質量%未満であることが好ましく、より好ましくは1.5質量%以上5.0質量%以下である。 The composition of the cocoa content contained in the cocoa beverage of the present invention is not particularly limited, but the cocoa content is preferably 0.5% by mass or more and less than 10% by mass with respect to the cocoa beverage, Preferably they are 1.5 mass% or more and 5.0 mass% or less.
また、本発明のココア飲料の別の態様として、本発明のココア飲料に含まれるカカオ分の配合は、カカオ分が、ココア飲料に対して、10質量%以上20質量%以下である(好ましくは、10質量%以上15質量以下である)ココア飲料が提供されてもよい。 Moreover, as another aspect of the cocoa beverage of the present invention, the cocoa content of the cocoa beverage of the present invention is such that the cocoa content is 10% by mass or more and 20% by mass or less based on the cocoa beverage (preferably A cocoa beverage (10% by mass to 15% by mass) may be provided.
このようにカカオ分の濃度が高いカカオ飲料であったとしても、本発明のココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物を加え、更にヤマモモ科植物抽出物を加えることにより、ホットベンダー等で一定時間加温した場合であっても、ココア飲料のムレ臭を低減させることができ、ココア飲料の品質を改善することができる。 Even if it is a cocoa beverage having a high concentration of cocoa in this way, adding a branched oligosaccharide-containing composition containing panose or panose to the cocoa beverage of the present invention, and further adding a bayberry plant extract, Even when it is heated for a certain time by a vendor or the like, the stuffy smell of the cocoa beverage can be reduced, and the quality of the cocoa beverage can be improved.
カカオ分とは、カカオニブ、カカオマス、ココアバター、ココアケーキ、ココアパウダー、またはカカオエキスパウダーなどから、これらに含まれる水分を除いた量をいう。 The cacao content means an amount obtained by removing moisture contained in cacao nibs, cacao mass, cocoa butter, cocoa cake, cocoa powder, cacao extract powder, and the like.
本発明のココア飲料の好ましい態様によれば、ココア飲料中の無脂固形カカオ分が1.5〜3質量%であることが好ましい。無脂固形カカオ分とは、カカオニブ、カカオマス、ココアパウダー、またはカカオエキスパウダーから、これらに含まれる油分を除いた固形分量をいう。 According to the preferable aspect of the cocoa drink of this invention, it is preferable that the non-fat solid cacao content in a cocoa drink is 1.5-3 mass%. The non-fat solid cacao content refers to the solid content obtained by removing the oil contained in cacao nibs, cacao mass, cocoa powder, or cacao extract powder.
本発明のココア飲料の好ましい別の態様によれば、本発明のカカオ飲料には、乳原料が含まれることが好ましい。本発明のカカオ飲料に乳原料を含有することにより、ココア飲料の加温保存中のムレ臭の発生がより顕著になることから、ムレ臭を低減する必要性が高まるが、ココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物を加え、更にヤマモモ科植物抽出物を加えることにより、この問題を解決することができる。ココア飲料に含まれる無脂乳固形分は、特に限定されないが、0.5〜5質量%であることが好ましい。 According to another preferable aspect of the cocoa beverage of the present invention, the cocoa beverage of the present invention preferably contains a milk raw material. By containing the milk raw material in the cacao beverage of the present invention, the occurrence of a stuffy odor during warm storage of the cocoa beverage becomes more prominent, increasing the need to reduce the stuffy odor. This problem can be solved by adding a branched oligosaccharide-containing composition containing panose and further adding a genus plant extract. Although the non-fat milk solid content contained in a cocoa drink is not specifically limited, It is preferable that it is 0.5-5 mass%.
本発明のココア飲料の好ましい別の態様によれば、本発明のココア飲料は、容器入りであることが好ましい。該容器としては、缶(スチール缶、アルミ缶など)、ガラス瓶、紙パック、またはペットボトル等のいずれの態様であってもよく、缶またはガラス瓶入りココア飲料として製造されたものをレトルト殺菌してもよく、また、殺菌処理したココア飲料を缶、ガラス瓶、紙パック、またはペットボトル等に無菌充填してもよい。 According to another preferable aspect of the cocoa beverage of the present invention, the cocoa beverage of the present invention is preferably contained in a container. The container may be any form such as a can (steel can, aluminum can, etc.), a glass bottle, a paper pack, or a plastic bottle. Alternatively, the sterilized cocoa beverage may be aseptically filled into a can, a glass bottle, a paper pack, a plastic bottle or the like.
<ココア飲料の製造方法>
本発明の製造方法は、ココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物を加える工程を含むパノース含有ココア飲料の製造方法である。また、本発明の製造方法の好ましい態様によれば、ココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物に加え、ヤマモモ科植物抽出物を更に加える工程を含む製造方法が提供される。
<Method for producing cocoa beverage>
The manufacturing method of this invention is a manufacturing method of the panose containing cocoa drink including the process of adding the branched oligosaccharide containing composition containing panose or panose to a cocoa drink. Moreover, according to the preferable aspect of the manufacturing method of this invention, in addition to the branched oligosaccharide containing composition which contains panose or panose in a cocoa drink, the manufacturing method which further includes the process of adding a bayberry plant extract is provided.
パノースまたはパノースを含有する分岐オリゴ糖含有組成物およびヤマモモ科植物抽出物を加えるタイミングは、本発明の効果を奏する限り特に限定されるものではなく、ココア飲料の製造工程のいずれの工程に加えてもよい。また、このパノースは、本発明の効果を奏する限り特に限定されるものではないが、ココア飲料に対して、0.002〜0.2質量%となるように加えることが好ましく、0.005〜0.05質量%となるように加えることがより好ましい。 The timing of adding panose or a branched oligosaccharide-containing composition containing panose and a bayberry plant extract is not particularly limited as long as the effect of the present invention is exerted. In addition to any step of the cocoa beverage manufacturing process, Also good. Moreover, this panose is not particularly limited as long as the effect of the present invention is exhibited, but it is preferably added so as to be 0.002 to 0.2% by mass with respect to the cocoa beverage. It is more preferable to add so that it may become 0.05 mass%.
ココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物を加えるとは、ココア飲料にパノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させることができればどのような態様であってもよい。 Adding the branched oligosaccharide-containing composition containing panose or panose to the cocoa beverage may be in any form as long as the cocoa beverage can contain the branched oligosaccharide-containing composition containing panose or panose. .
本発明のココア飲料の製造方法として、例えば、缶入ココア飲料を製造するためには、ココアパウダーを始めとする原料を水に溶解または分散し、ココア飲料調合液を調製し、このココア調合液をホモジナイズして均質化して、缶容器に投入後、100〜150℃、好ましくは120〜140℃で加熱(殺菌)工程を行うことにより製造することができる。このような加熱工程は、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を加えた(好ましくは、更にヤマモモ科植物抽出物を加えた)後に行うことが好ましいが、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を加える(好ましくは、更にヤマモモ科植物抽出物を加える)前に行うことを妨げるものではない。 As a method for producing a cocoa beverage of the present invention, for example, in order to produce a canned cocoa beverage, a raw material including cocoa powder is dissolved or dispersed in water to prepare a cocoa beverage preparation solution, and this cocoa preparation solution Can be manufactured by performing a heating (sterilization) step at 100 to 150 ° C., preferably 120 to 140 ° C., after homogenizing and homogenizing. Such a heating step is preferably performed after adding panose or a branched oligosaccharide-containing composition containing panose (preferably, further adding a genus genus plant extract), but branching containing panose or panose is preferable. This does not prevent the oligosaccharide-containing composition from being added prior to the addition (preferably further adding the genus plant extract).
ココア飲料調合液の調製方法は、特に限定されるものではないが、使用原料の種類に応じ、例えば粉体分散液、副原料溶解液、液糖、仕込水等を分けて予め調合して、その後、最終工程でこれらを混合することによってココア飲料調合液を調製してもよい。ココア飲料調合液の調製温度は、50〜75℃であることが好ましい。 The preparation method of the cocoa beverage preparation liquid is not particularly limited, but according to the type of raw materials used, for example, powder dispersion, auxiliary raw material solution, liquid sugar, preparation water, etc. are prepared in advance, Then, you may prepare a cocoa drink preparation liquid by mixing these by the last process. The preparation temperature of the cocoa beverage preparation liquid is preferably 50 to 75 ° C.
本発明のココア飲料の殺菌方法としては、特に限定されるものではないが、例えばレトルト殺菌や、いわゆる超高温瞬間滅菌(UHT殺菌)等が行われる。UHT殺菌を行う場合は、ココア飲料を殺菌した後に缶等容器に封入することが好ましい。商業的無菌を担保するため、殺菌強度F0≧40となるような温度、殺菌時間を設定することが好ましい。本発明のココア飲料によれば、レトルト殺菌や、UHT殺菌等により発生する、ココア飲料のムレ臭であっても低減することができる。 Although it does not specifically limit as a sterilization method of the cocoa drink of this invention, For example, retort sterilization, what is called ultra high temperature instant sterilization (UHT sterilization), etc. are performed. When performing UHT sterilization, it is preferable to sterilize the cocoa beverage and then enclose it in a container such as a can. In order to ensure commercial sterility, it is preferable to set the temperature and sterilization time such that the sterilization strength F0 ≧ 40. According to the cocoa beverage of the present invention, even the stuffy smell of cocoa beverage generated by retort sterilization, UHT sterilization or the like can be reduced.
本発明の別の態様によれば、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を加える工程を含む製造方法により製造されるココア飲料が提供される。また、本発明の好ましい態様によれば、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を加える工程に、更にヤマモモ科植物抽出物を加える工程を含む製造方法により製造されるココア飲料が提供される。 According to another aspect of the present invention, there is provided a cocoa beverage produced by a production method comprising the step of adding panose or a branched oligosaccharide-containing composition containing panose. In addition, according to a preferred embodiment of the present invention, there is provided a cocoa beverage produced by a production method comprising a step of adding a bayberry plant extract to the step of adding panose or a branched oligosaccharide-containing composition containing panose. The
また、本発明の別の好ましい態様によれば、パノースまたはパノースを含有する分岐オリゴ糖含有組成物およびヤマモモ科植物抽出物を加える工程に、更に120〜140℃での加熱工程を含む製造方法により製造されるココア飲料が提供される。 Moreover, according to another preferable aspect of the present invention, the step of adding panose or a branched oligosaccharide-containing composition containing panose and a genus genus plant extract further includes a heating step at 120 to 140 ° C. A manufactured cocoa beverage is provided.
<ココア飲料の加温保管方法>
本発明の好ましい態様によれば、本発明のココア飲料および本発明の製造方法により製造されたココア飲料を、40〜70℃の品温で1時間以上、好ましくは50〜60℃の品温で3日以上、より好ましくは1週間以上、保温(加温)する保管方法が提供される。また、この保管方法においては、保管期間は1ヶ月までであることが好ましく、さらには2週間までであることがより好ましい。本発明のココア飲料は、上記のような条件で保管したとしても、ココア飲料のムレ臭を低減することができ、ココア飲料としての品質を保つことができる。加熱(殺菌)された缶入ココア飲料は、ホットベンダーに保管され、定常的に保温(加温)販売されており、この保温時に、ムレ臭が著しく発生する場合が多いが、本発明のココア飲料を用いることにより、このようなムレ臭を低減することができる。また、本発明のココア飲料および本発明の製造方法により製造されたココア飲料は、ホットベンダー用または加温販売用であることが好ましい。
<Warm storage method of cocoa beverage>
According to a preferred embodiment of the present invention, the cocoa beverage of the present invention and the cocoa beverage produced by the production method of the present invention are heated at a product temperature of 40 to 70 ° C for 1 hour or more, preferably at a product temperature of 50 to 60 ° C. There is provided a storage method for keeping warm (warming) for 3 days or more, more preferably for 1 week or more. In this storage method, the storage period is preferably up to 1 month, more preferably up to 2 weeks. Even if the cocoa beverage of the present invention is stored under the above conditions, the odor of the cocoa beverage can be reduced and the quality of the cocoa beverage can be maintained. The heated (sterilized) canned cocoa beverage is stored in a hot bender and is constantly kept warm (warmed), and the cocoa of the present invention often generates a noticeable odor when kept warm. By using a beverage, such a stuffy odor can be reduced. Moreover, the cocoa beverage of the present invention and the cocoa beverage produced by the production method of the present invention are preferably used for hot vendors or for warm sales.
本発明の別の態様によれば、本発明のココア飲料および本発明の製造方法により製造されたココア飲料を、40〜70℃で1時間以上(好ましくは50〜60℃の品温で3日以上、より好ましくは1週間以上)保管されるココア飲料が提供される。 According to another aspect of the present invention, the cocoa beverage of the present invention and the cocoa beverage manufactured by the manufacturing method of the present invention are used at 40 to 70 ° C for 1 hour or longer (preferably at a product temperature of 50 to 60 ° C for 3 days. As described above, more preferably, a cocoa beverage to be stored is provided.
<ムレ臭低減方法>
また、本発明の別の態様によれば、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させることを特徴とするココア飲料のムレ臭低減方法が提供される。本発明の別の好ましい態様によれば、ココア飲料に、パノースまたはパノースを含有する分岐オリゴ糖含有組成物を含有させ、ヤマモモ科植物抽出物を更に含有させることを特徴とするココア飲料のムレ臭低減方法が提供される。これらの方法を用いることにより、ココア飲料をレトルト殺菌やUHT殺菌により加熱された場合であっても、更にホットベンダーに保管され、一定時間保温(加温)販売された場合であっても、ココア飲料のムレ臭を低減することができ、ココア飲料としての品質を保つことができる。
<Dampening odor reduction method>
Moreover, according to another aspect of the present invention, there is provided a method for reducing stuffy odor of a cocoa beverage characterized by containing panose or a branched oligosaccharide-containing composition containing panose. According to another preferred embodiment of the present invention, the cocoa beverage contains a panolis or a branched oligosaccharide-containing composition containing panose, and further contains a bayberry plant extract. A reduction method is provided. By using these methods, even if the cocoa beverage is heated by retort sterilization or UHT sterilization, it is stored in a hot bender and kept warm (warmed) for a certain period of time. The stuffy smell of the beverage can be reduced, and the quality as a cocoa beverage can be maintained.
以下、実施例により本発明をより具体的に説明するが、本発明の技術的範囲はこれらの例示に限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, the technical scope of this invention is not limited to these illustrations.
パノースを含有する分岐オリゴ糖含有組成物中の糖の重合度分布の分析
パノースを含む各種の分岐オリゴ糖含有組成物について、分岐オリゴ糖含有組成物に含まれる糖の重合度分布を分析した。分析方法は高速液体クロマトグラフィを使用し、定法に基づいて行った。
Analysis of the degree of polymerization of sugar in the branched oligosaccharide-containing composition containing panose The degree of polymerization of sugar contained in the branched oligosaccharide-containing composition was analyzed for various branched oligosaccharide-containing compositions containing panose. The analytical method used high performance liquid chromatography, and was performed based on a conventional method.
各分岐オリゴ糖含有組成物中の単糖類、2糖類、3糖類、4糖類、5糖類、および6糖類以上の糖類について、それらの分布を表に示した。パノラップ(登録商標)(株式会社林原製)、パノリッチ(登録商標)(日本食品化工株式会社製)、パノックスA(登録商標)(昭和産業株式会社製)、およびマルミノース(登録商標)(昭和産業株式会社製)は、単糖類、2糖類、および3糖類の合計が全て75質量%以上であるのに対し、ブランチオリゴ(登録商標)(日本食品化工株式会社製)は19質量%と著しく少なかった。その結果を下記表1に示す。 The distribution of monosaccharides, disaccharides, trisaccharides, tetrasaccharides, pentasaccharides, and hexasaccharides in each branched oligosaccharide-containing composition is shown in the table. Panorap (registered trademark) (manufactured by Hayashibara Co., Ltd.), Panoric (registered trademark) (manufactured by Nippon Shokuhin Kako Co., Ltd.), Panox A (registered trademark) (manufactured by Showa Sangyo Co., Ltd.), and Marminose (registered trademark) The total of monosaccharides, disaccharides, and trisaccharides was 75% by mass or more, whereas Branch Oligo (registered trademark) (manufactured by Nippon Shokuhin Kako Co., Ltd.) was significantly less as 19% by mass. . The results are shown in Table 1 below.
パノース含有量
各分岐オリゴ糖含有組成物のパノース含有量(質量%)を分析した。分析方法は高速液体クロマトグラフィを使用し、定法に基づいて行った。
Panose content The panose content (mass%) of each branched oligosaccharide-containing composition was analyzed. The analytical method used high performance liquid chromatography, and was performed based on a conventional method.
各分岐オリゴ糖組成物のパノース含有量を表に示した。パノラップ、パノリッチ、パノックスA、およびパノリッチのパノース含有量は19質量%以上であるのに対し、ブランチオリゴのパノース含有量は2質量%以下と著しく少なかった。その結果を下記表1に示す。
ココア飲料の調製
砂糖81質量部、全粉乳19質量部、ココアパウダー21質量部、牛乳19質量部、脱脂粉乳5質量部、乳化剤1質量部、結晶セルロース3質量部、香料1質量部、および水850質量部に、パノースを含有する各種分岐オリゴ糖含有組成物および/またはヤマモモ抽出物(商品名:サンメリンYA−F、三栄源エフ・エフ・アイ株式会社製)を下記表2〜6に記載の濃度となるように加え、混合、攪拌し、ココア飲料の調合液を得た。
パノースを含有する分岐オリゴ糖含有組成物としては、パノリッチ(登録商標)(日本食品化工株式会社製)、マルミノース(登録商標)(昭和産業株式会社製)、パノックスA(登録商標)(昭和産業株式会社製)、パノラップ(登録商標)(株式会社林原製)、およびブランチオリゴ(登録商標)(日本食品化工株式会社製)を用いた。
Preparation of Cocoa Beverage 81 parts by weight of sugar, 19 parts by weight of whole milk powder, 21 parts by weight of cocoa powder, 19 parts by weight of milk, 5 parts by weight of skim milk powder, 1 part by weight of emulsifier, 3 parts by weight of crystalline cellulose, 1 part by weight of perfume, and water In 850 parts by mass, various branched oligosaccharide-containing compositions containing panose and / or bayberry extract (trade name: Sanmerin YA-F, manufactured by Saneigen FFI Co., Ltd.) are listed in Tables 2 to 6 below. The resulting mixture was mixed and stirred to obtain a cocoa beverage preparation.
Examples of the branched oligosaccharide-containing composition containing panose include Panorich (registered trademark) (manufactured by Nippon Shokuhin Kako Co., Ltd.), Marminose (registered trademark) (manufactured by Showa Sangyo Co., Ltd.), Panox A (registered trademark) (Showa Sangyo Co., Ltd.) Pano Wrap (registered trademark) (manufactured by Hayashibara Co., Ltd.), and Branch Oligo (registered trademark) (manufactured by Nippon Shokuhin Kako) were used.
上記得られたココア飲料の調合液の無脂固形カカオ分は1.9質量%、乳固形分は2.6質量%であった。得られた調合液をホモジナイズ処理により均質化した後、缶に充填、巻締し、F0≧40となるよう125℃、40分間のレトルト殺菌を行い、缶入りココア飲料を得た。 The above-obtained cocoa beverage preparation liquid had a non-fat solid cacao content of 1.9% by mass and a milk solid content of 2.6% by mass. The resulting preparation was homogenized by homogenization treatment, filled into a can and wound, and retort sterilized at 125 ° C. for 40 minutes so that F0 ≧ 40, to obtain a canned cocoa beverage.
得られた缶入りココア飲料を60℃で2週間保存した後、下記のとおり官能試験を行った。 The obtained canned cocoa beverage was stored at 60 ° C. for 2 weeks and then subjected to a sensory test as follows.
陰性対照
パノースを含有する分岐オリゴ糖含有組成物およびヤマモモ抽出物を全く含まない以外は、上記のココア飲料の調製と同様の方法で、缶入りココア飲料を得た。得られた缶入りココア飲料を60℃で2週間保存した後、上記のココア飲料と同様に、官能試験を行った。
A canned cocoa beverage was obtained in the same manner as in the preparation of the above cocoa beverage, except that it did not contain any branched oligosaccharide-containing composition containing a negative control panose and no bayberry extract. The obtained canned cocoa beverage was stored at 60 ° C. for 2 weeks, and then a sensory test was performed in the same manner as the above cocoa beverage.
下記の5段階の評価基準によりそれぞれのココア飲料を評価し、その官能試験結果を下記表2〜6に示した。評価基準における、ココア飲料として良好か否かの判断は、ムレ臭の抑制の有無に加え、金属臭や異味の有無なども考慮して、ココア飲料としての品質を総合的に判断した。なお、下記表2〜6における数値はココア飲料の調合液中の含有量を表す。
陰性対照では、加温保存前には感じられなかった、ムレ臭、酸味、苦味が強く、明らかに加温保存による品質劣化が見られ、著しく劣った品質となっていた(下記評価基準では「E」であった)。
評価基準
A:ココア飲料として、著しく良好である
B:ココア飲料として、良好である
C:ココア飲料として、やや良好である
D:ココア飲料として、やや劣る
E:ココア飲料として、著しく劣る
−:官能試験を行わなかった
Each cocoa beverage was evaluated according to the following five-stage evaluation criteria, and the sensory test results are shown in Tables 2 to 6 below. Judgment as to whether the cocoa beverage is good or not in the evaluation criteria was made by comprehensively judging the quality of the cocoa beverage in consideration of the presence or absence of suppression of the stuffy odor and the presence or absence of a metal odor or an unpleasant taste. In addition, the numerical value in following Table 2-6 represents content in the preparation liquid of a cocoa drink.
The negative control had a strong stuffy odor, sourness, and bitterness that was not felt before warming storage, and apparently quality deterioration due to warming storage was observed, resulting in extremely inferior quality. E ").
Evaluation criteria A: Remarkably good as a cocoa drink B: Good as a cocoa drink C: Good as a cocoa drink D: Slightly good as a cocoa drink E: Slightly inferior as a cocoa drink −: Sensory Did not test
パノースを含有する分岐オリゴ糖含有組成物をココア飲料に加えることにより、陰性対照に比べ、ココア飲料のムレ臭が低減され、ココア飲料として良好であることがわかった。
また、分岐オリゴ糖含有組成物と、ヤマモモ抽出物とを併用することにより、著しいムレ臭抑制効果が得られ、ココア飲料として良好な品質に改善できることがわかる。
一方で、上記表2の結果は、ココア飲料における分岐オリゴ糖含有組成物の配合率が高いほど、ムレ臭の抑制効果は高くなるが、分岐オリゴ糖含有組成物の配合率が高くなると、ココア飲料としての品質に問題となるものではないが、ココア飲料に若干異味が出てしまうことを示すものである。特に、ヤマモモ抽出物を配合せず、分岐オリゴ糖含有組成物のみ配合したココア飲料では、分岐オリゴ糖含有組成物の配合率の増加に伴い、ムレ臭抑制効果は増加するが、十分なムレ臭抑制効果が現れる前に若干異味が発生していた。また、ヤマモモ抽出物においても、ヤマモモ抽出物の配合率が高いほど、ムレ臭の抑制効果は高くなるが、ヤマモモ抽出物配合率が高くなると、金属臭が発生し、ココア自体の風味が若干減少する傾向があり、ココア飲料としての品質に問題となるものではないが、この傾向はヤマモモ抽出物が0.05質量%より高い濃度で特にみられた(データは示さず)。
It was found that by adding the branched oligosaccharide-containing composition containing panose to the cocoa beverage, the odor of the cocoa beverage was reduced compared to the negative control, and the cocoa beverage was good.
In addition, it can be seen that by using the branched oligosaccharide-containing composition and the bayberry extract in combination, a remarkable odor suppression effect can be obtained, and the quality can be improved as a cocoa beverage.
On the other hand, the results of Table 2 above show that the higher the blending ratio of the branched oligosaccharide-containing composition in the cocoa beverage, the higher the effect of suppressing the stuffy odor. Although it does not become a problem in the quality as a drink, it shows that a slightly different taste will come out to a cocoa drink. In particular, in a cocoa beverage containing only a branched oligosaccharide-containing composition without a bayberry extract, the odor control effect increases as the blending ratio of the branched oligosaccharide-containing composition increases, but sufficient odor A slight off-flavor occurred before the suppression effect appeared. In addition, in the bayberry extract, the higher the blending ratio of the bayberry extract, the higher the effect of suppressing the odor, but the higher the blending ratio of the bayberry extract, a metal odor is generated, and the flavor of the cocoa itself is slightly reduced. Although this is not a problem for quality as a cocoa beverage, this tendency was particularly observed when the bayberry extract was at a concentration higher than 0.05% by mass (data not shown).
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