JP2014214135A - Aqueous cleansing cosmetic - Google Patents
Aqueous cleansing cosmetic Download PDFInfo
- Publication number
- JP2014214135A JP2014214135A JP2013094302A JP2013094302A JP2014214135A JP 2014214135 A JP2014214135 A JP 2014214135A JP 2013094302 A JP2013094302 A JP 2013094302A JP 2013094302 A JP2013094302 A JP 2013094302A JP 2014214135 A JP2014214135 A JP 2014214135A
- Authority
- JP
- Japan
- Prior art keywords
- aqueous cleansing
- cleansing cosmetic
- aqueous
- glycol
- citrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 60
- -1 hydroxycarboxylic acid ester Chemical class 0.000 claims abstract description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 6
- 229940058015 1,3-butylene glycol Drugs 0.000 claims description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 4
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 4
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 claims description 3
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- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 claims description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 3
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical group CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 3
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 claims description 3
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- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims description 3
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- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
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- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
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- 239000011782 vitamin Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 150000003698 vitamin B derivatives Chemical class 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
- 239000011735 vitamin B7 Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Dermatology (AREA)
Abstract
Description
本発明は、水性クレンジング化粧料に好適な、クレンジング化粧料に関する。 The present invention relates to a cleansing cosmetic suitable for an aqueous cleansing cosmetic.
クレンジング化粧料は、皮脂などに起因する脂汚れやメークアップ化粧料等を落とすのに用いられる化粧料であり、通常の脂溶性成分を落とすことに注力した、オイル分を高濃度に含有する油性クレンジング化粧料と、水洗いにより、水性汚れを落とすと共に油性汚れを落とすことをめざした、水性クレンジング化粧料の２種が存在する。油性クレンジング化粧料には油性汚れに対しては優れた洗浄力を発揮するという長所があるものの、使用感が油っぽく、水性汚れを落としにくいという欠点があり、水性クレンジング化粧料には使用感はさっぱり優れている、水性汚れを落としやすいという長所がある反面、落としうる油性汚れに限度があるという欠点がある。現在では、使用感を優先した水性クレンジング化粧料が主流となっている。即ち、使用感に優れ、油性、水性の汚れの何れも充分に使用性良く落とすことのできる水性クレンジング化粧料の開発が望まれていた。 Cleansing cosmetics are cosmetics used to remove fat stains and makeup cosmetics caused by sebum, etc., and are oil-based with a high concentration of oil, focusing on removing normal fat-soluble ingredients. There are two types of cleansing cosmetics and water-based cleansing cosmetics that aim to remove water-based stains and oily stains by washing with water. Although oil-based cleansing cosmetics have the advantage of exhibiting excellent detergency against oil-based stains, they have the disadvantage of being oily and difficult to remove aqueous stains. While it has the advantage of being excellent in water and easy to remove aqueous dirt, it has the disadvantage that there is a limit to oily dirt that can be removed. At present, water-based cleansing cosmetics that give priority to the feeling of use are the mainstream. That is, there has been a demand for the development of an aqueous cleansing cosmetic that has excellent usability and can remove both oily and aqueous stains with sufficient usability.
一方、従来の水性クレンジング化粧料においては、油性汚れを落とすために溶媒効果を期待してオイル分を含有させるために、界面活性剤をさらに含有させることが必要であり、そのような水性クレンジング化粧料がこれまでに多数知られているが（例えば、特許文献１、特許文献２、特許文献３を参照）、界面活性剤によるべたつきを解消することは困難であった。そのため、界面活性剤を含有しない水性クレンジング化粧料は、これまでに全く知られていなかった。 On the other hand, in the conventional water-based cleansing cosmetic, it is necessary to further contain a surfactant in order to contain the oil component in order to remove the oily stain in order to expect a solvent effect. Many materials have been known so far (see, for example, Patent Document 1, Patent Document 2, and Patent Document 3), but it has been difficult to eliminate stickiness due to the surfactant. Therefore, an aqueous cleansing cosmetic that does not contain a surfactant has never been known so far.
本発明は、この様な状況下為されたものであり、ヒドロキシカルボン酸エステルと、多価アルコールとを含有することを特徴とする、水性クレンジング化粧料を提供することを課題とする。 The present invention has been made under such circumstances, and an object of the present invention is to provide an aqueous cleansing cosmetic characterized by containing a hydroxycarboxylic acid ester and a polyhydric alcohol.
この様な状況に鑑みて、本発明者らは、水性クレンジング化粧料を求めて、鋭意努力を重ねた結果、ヒドロキシカルボン酸エステルと、多価アルコールとを含有することを特徴とする水性クレンジング化粧料が、べたつきといった使用感に優れ、油性、水性の汚れの何れも充分に良く落とすことができ、洗い流しが良いことを見出し、発明を完成させるに至った。即ち、本発明は以下に示すとおりである。
＜１＞ヒドロキシカルボン酸エステルと、多価アルコールとを含有することを特徴とする、水性クレンジング化粧料。
＜２＞前記ヒドロキシカルボン酸エステルを０．５質量％〜２０質量％含有することを特徴とする、＜１＞に記載の水性クレンジング化粧料。
＜３＞前記多価アルコールを１質量％〜５０質量％含有することを特徴とする、＜１＞又は＜２＞に記載の水性クレンジング化粧料。
＜４＞ヒドロキシカルボン酸エステルが、クエン酸トリエチル、リンゴ酸ジイソステアリル、β−ヒドロキシドデカン酸メチルエステル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸オクチルドデシル、クエン酸アセチルトリエチル、クエン酸アセチルトリブチル、クエン酸トリオクチル、クエン酸トリイソセチル、クエン酸トリオクチルドデシル、ヒドロキシステアリン酸2-エチルヘキシルの１種又は２種以上から選択されることを特徴とする、＜１＞〜＜３＞の何れかに記載の水性クレンジング化粧料。
＜５＞前記多価アルコールが、１，３−ブチレングリコール、１，２-ペンタンジオール、プロパンジオール、エチレングリコール、プロピレングリコール、イソプレングリコール、ジプロピレングリコール、ジエチレングリコール、ジプロピレングリコール、グリセリン、ペンタエリスリトール、ジグリセリン、ポリグリセリンの一種又は二種以上から選択されることを特徴とする、＜１＞〜＜４＞の何れかに記載の水性クレンジング化粧料。
＜６＞さらに実質的に界面活性剤を含有しないことを特徴とする、＜１＞〜＜５＞の何れかに記載の水性クレンジング化粧料。
＜７＞さらに、実質的にエタノールを含有しないことを特徴とする、＜１＞〜＜６＞の何れかに記載の水性クレンジング化粧料。
In view of such circumstances, the present inventors have sought for an aqueous cleansing cosmetic, and as a result of intensive efforts, the present invention contains an aqueous cleansing cosmetic characterized by containing a hydroxycarboxylic acid ester and a polyhydric alcohol. The material was excellent in feeling of stickiness, oily and aqueous stains could be removed sufficiently well, and it was found that it was washed away, and the present invention was completed. That is, the present invention is as follows.
<1> An aqueous cleansing cosmetic comprising a hydroxycarboxylic acid ester and a polyhydric alcohol.
<2> The aqueous cleansing cosmetic according to <1>, comprising 0.5% by mass to 20% by mass of the hydroxycarboxylic acid ester.
<3> The aqueous cleansing cosmetic according to <1> or <2>, wherein the polyhydric alcohol is contained in an amount of 1% by mass to 50% by mass.
<4> hydroxycarboxylic acid ester is triethyl citrate, diisostearyl malate, β-hydroxydodecanoic acid methyl ester, lauryl lactate, myristyl lactate, cetyl lactate, octyldodecyl lactate, acetyl triethyl citrate, acetyl tributyl citrate, <1> to <3>, characterized by being selected from one or more of trioctyl citrate, triisocetyl citrate, trioctyldodecyl citrate, and 2-ethylhexyl hydroxystearate Aqueous cleansing cosmetic.
<5> The polyhydric alcohol is 1,3-butylene glycol, 1,2-pentanediol, propanediol, ethylene glycol, propylene glycol, isoprene glycol, dipropylene glycol, diethylene glycol, dipropylene glycol, glycerin, pentaerythritol, The aqueous cleansing cosmetic according to any one of <1> to <4>, wherein the aqueous cleansing cosmetic is selected from one or more of diglycerin and polyglycerin.
<6> The aqueous cleansing cosmetic according to any one of <1> to <5>, further comprising substantially no surfactant.
<7> The aqueous cleansing cosmetic according to any one of <1> to <6>, further comprising substantially no ethanol.
本発明によれば、ヒドロキシカルボン酸エステルと、多価アルコールとを含有することを特徴とする、べたつきといった使用感に優れ、油性、水性の汚れの何れも充分に良く落とすことができ、洗い流しが良い水性クレンジング化粧料を提供することができる。 According to the present invention, which is characterized by containing a hydroxycarboxylic acid ester and a polyhydric alcohol, it is excellent in use feeling such as stickiness, oily and aqueous stains can be removed sufficiently well, and washing away A good aqueous cleansing cosmetic can be provided.
＜本発明のヒドロキシカルボン酸エステル＞
本発明の水性クレンジング化粧料は、必須成分としてヒドロキシカルボン酸エステルを含有することを特徴とする。ヒドロキシカルボン酸エステルとしては、１価アルコールの多価カルボン酸エステルが好ましく、その中ではクエン酸トリエチル、リンゴ酸ジイソステアリル、β−ヒドロキシドデカン酸メチルエステル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸オクチルドデシル、クエン酸アセチルトリエチル、クエン酸アセチルトリブチル、クエン酸トリオクチル、クエン酸トリイソセチル、クエン酸トリオクチルドデシル、ヒドロキシステアリン酸2-エチルヘキシルの１種又は２種以上から選択されることが好ましく、クエン酸トリエチルがさらに好ましい。本発明の水性クレンジング化粧料は、化粧料全量に対する含有量として０．５質量％〜２０質量％が好ましく、１質量％〜１０質量％がさらに好ましい。この範囲において、最も高い使用感、クレンジング効果及び洗い流し効果を奏する。
<Hydroxycarboxylic acid ester of the present invention>
The aqueous cleansing cosmetic composition of the present invention is characterized by containing a hydroxycarboxylic acid ester as an essential component. As the hydroxycarboxylic acid ester, a polyhydric carboxylic acid ester of a monohydric alcohol is preferable. Among them, triethyl citrate, diisostearyl malate, methyl β-hydroxydodecanoate, lauryl lactate, myristyl lactate, cetyl lactate, lactic acid Preferably, it is selected from one or more of octyl dodecyl, acetyl triethyl citrate, acetyl tributyl citrate, trioctyl citrate, triisocetyl citrate, trioctyl dodecyl citrate, 2-ethylhexyl hydroxystearate, citric acid More preferred is triethyl. 0.5 mass%-20 mass% are preferable as content with respect to the cosmetics whole quantity, and 1 mass%-10 mass% are more preferable as the aqueous cleansing cosmetics of this invention. In this range, the highest usability, cleansing effect and washing out effect are exhibited.
＜本発明の多価アルコール＞
本発明の水性クレンジング化粧料は、必須成分として多価アルコールを含有することを特徴とする。多価アルコールとしては、１，３−ブチレングリコール、１，２-ペンタンジオール、プロパンジオール、エチレングリコール、プロピレングリコール、イソプレングリコール、ジプロピレングリコール、ジエチレングリコール、ジプロピレングリコール、グリセリン、ペンタエリスリトール、ジグリセリン、ポリグリセリンの１種又は２種以上から選択されることが好ましく、１，３−ブチレングリコール、１，２-ペンタンジオール、プロパンジオールの１種又は２種以上から選択されることがさらに好ましい。本発明の水性クレンジング化粧料における好ましい含有量は、１質量％〜５０質量％、より好ましくは、２質量％〜１０質量％である。この範囲において、最も高い使用感、クレンジング効果及び洗い流し効果を奏する。
<Polyhydric alcohol of the present invention>
The aqueous cleansing cosmetic composition of the present invention is characterized by containing a polyhydric alcohol as an essential component. Examples of the polyhydric alcohol include 1,3-butylene glycol, 1,2-pentanediol, propanediol, ethylene glycol, propylene glycol, isoprene glycol, dipropylene glycol, diethylene glycol, dipropylene glycol, glycerin, pentaerythritol, diglycerin, It is preferably selected from one or more of polyglycerols, more preferably selected from one or more of 1,3-butylene glycol, 1,2-pentanediol and propanediol. The preferable content in the aqueous cleansing cosmetic of the present invention is 1% by mass to 50% by mass, more preferably 2% by mass to 10% by mass. In this range, the highest usability, cleansing effect and washing out effect are exhibited.
＜本発明の水性クレンジング化粧料＞
本発明の水性クレンジング化粧料は、上記２種の必須成分を含有することを特徴とする。本発明の水性クレンジング化粧料の必須成分であるヒドロキシカルボン酸エステルと多価アルコールは、質量比として２：１〜１：５０の割合で含有することが好ましく、１：１〜１：5の割合で含有することがさらに好ましい。これはかかる質量比で本発明の水性クレンジング化粧料に含有せしめることにより、相溶性が良くなるためである。また本発明の水性クレンジング化粧料は、実質的に界面活性剤を含有しないことが好ましい。これによって、本発明の水性クレンジング化粧料はべたつきがなく、又皮膚への刺激を抑えることができるからである。さらに、本発明の水性クレンジング化粧料は実質的にエタノールを含有しないことが好ましい。エタノールを含有すると、界面活性剤と同様に皮膚への刺激が生じる場合があるためである。
<Aqueous cleansing cosmetic of the present invention>
The aqueous cleansing cosmetic composition of the present invention is characterized by containing the above two essential components. The hydroxycarboxylic acid ester and the polyhydric alcohol, which are essential components of the aqueous cleansing cosmetic of the present invention, are preferably contained in a mass ratio of 2: 1 to 1:50, and a ratio of 1: 1 to 1: 5. It is more preferable to contain. This is because the compatibility is improved when the aqueous cleansing cosmetic of the present invention is contained at such a mass ratio. Moreover, it is preferable that the aqueous cleansing cosmetic of the present invention does not substantially contain a surfactant. This is because the aqueous cleansing cosmetic of the present invention is not sticky and can suppress irritation to the skin. Furthermore, it is preferable that the aqueous cleansing cosmetic of the present invention does not substantially contain ethanol. This is because when ethanol is contained, irritation to the skin may occur as in the case of the surfactant.
本発明の水性クレンジング化粧料は、直接ウォッシュオフで使用することもできるし、シート含浸型のふきとり化粧料としても使用できる。又、二層分離タイプの水相にも適用可能である。 The aqueous cleansing cosmetic of the present invention can be used directly in a wash-off, or can be used as a sheet-impregnated wiping cosmetic. It is also applicable to a two-layer separation type aqueous phase.
本発明の水性クレンジング化粧料は、化粧料で通常使用されている任意成分を本発明の効果を損なわない範囲において、含有することができる。 The aqueous cleansing cosmetic composition of the present invention can contain optional components that are usually used in cosmetics as long as the effects of the present invention are not impaired.
このような任意成分としては、例えば、マカデミアナッツ油、アボカド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等、ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン、アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類、ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類、グアガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、ペクチン、マンナン、デンプン、キサンタンガム、カードラン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、コンドロイチン硫酸、デルマタン硫酸、グリコーゲン、ヘパラン硫酸、ヒアルロン酸、ヒアルロン酸ナトリウム、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、ヒドロキシエチルグアガム、カルボキシメチルグアガム、デキストラン、ケラト硫酸，ローカストビーンガム，サクシノグルカン、カロニン酸、キチン、キトサン、カルボキシメチルキチン、寒天、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、ポリアクリル酸ナトリウム、ポリエチレングリコール等の増粘剤、表面を処理されていても良い、マイカ、シリカ、炭酸カルシウム、炭酸マグネシウム、酸化アルミニウム、硫酸バリウム等の粉体類、表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青、酸化チタン、酸化亜鉛の無機顔料類、表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類、レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類、ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類、パラアミノ安息香酸系紫外線吸収剤、アントラニル酸系紫外線吸収剤、サリチル酸系紫外線吸収剤、桂皮酸系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、糖系紫外線吸収剤、２−（２'−ヒドロキシ−５'−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４'−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類、ビタミンＡ又はその誘導体、ビタミンＢ6塩酸塩、ビタミンＢ6トリパルミテート、ビタミンＢ6ジオクタノエート、ビタミンＢ2又はその誘導体、ビタミンＢ12、ビタミンＢ15又はその誘導体等のビタミンＢ類、α−トコフェロール、β−トコフェロール、γ−トコフェロール、ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類等、フェノキシエタノール等の抗菌剤等が好ましく例示できる。 Examples of such optional ingredients include macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, and hardened coconut oil. Oil, wax, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, oil, wax, liquid wax, liquid paraffin, squalane, bean wax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax , Hydrocarbons such as microcrystalline wax, higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostear Higher alcohols such as alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol, etc., chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopenta Oils such as silicone oils such as siloxanes, cyclic polysiloxanes such as dodecamethylcyclohexanesiloxane, amino-modified polysiloxanes, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, and modified polysiloxanes such as fluorine-modified polysiloxanes, sodium pyrrolidone carboxylate , Moisturizing ingredients such as lactic acid, sodium lactate, guar gum, quince seed, carrageenan, galactan, gum arabic, pectin, man , Starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, chondroitin sulfate, dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, Hydroxyethyl guar gum, carboxymethyl guar gum, dextran, keratosulfuric acid, locust bean gum, succinoglucan, carolinic acid, chitin, chitosan, carboxymethylchitin, agar, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, sodium polyacrylate, polyethylene Thickener such as glycol, surface may be treated, mica, silica , Calcium carbonate, magnesium carbonate, aluminum oxide, barium sulfate and other powders, surface may be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide Inorganic pigments, surface may be treated, pearl agents such as titanium mica, fish phosphorus foil, bismuth oxychloride, red 202, red 228, red 226, yellow 4 which may be raked No., Blue 404, Yellow No. 5, Red No. 505, Red No. 230, Red No. 223, Orange No. 201, Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Organic dyes such as red 204, polyethylene powder, polymethyl methacrylate, nylon powder, organic powders such as organopolysiloxane elastomer, paraaminobenzoic acid type External absorber, anthranilic acid UV absorber, salicylic acid UV absorber, cinnamic acid UV absorber, benzophenone UV absorber, sugar UV absorber, 2- (2'-hydroxy-5'-t-octyl) Phenyl) benzotriazole, UV absorbers such as 4-methoxy-4′-t-butyldibenzoylmethane, vitamin A or derivatives thereof, vitamin B 6 hydrochloride, vitamin B 6 tripalmitate, vitamin B 6 dioctanoate, vitamin B 2 or derivatives thereof, vitamin B 12 such as vitamin B 12 , vitamin B 15 or derivatives thereof, α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E such as vitamin E acetate, vitamin D, vitamin H, Vitamins such as pantothenic acid, panthetin, pyrroloquinoline quinone, phenoxyethano Antibacterial agents such as Le can be preferably exemplified.
以下に、実施例を挙げて、本発明について更に詳細に説明を加えるが、本発明が、かかる実施例にのみ限定されないことはいうまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it goes without saying that the present invention is not limited to such examples.
＜実施例１〜７＞
下記に示す表１の処方に従って、本発明の水性クレンジング化粧料を作製した。即ち、表１に示す各成分を合わせ、本発明の水性クレンジング化粧料である実施例１〜６、及び比較例１、２を作製した。
<Examples 1-7>
The aqueous cleansing cosmetic composition of the present invention was prepared according to the formulation shown in Table 1 below. That is, the components shown in Table 1 were combined to produce Examples 1 to 6 and Comparative Examples 1 and 2, which are aqueous cleansing cosmetics of the present invention.
＜試験例＞
上記で得られた各実施例及び比較例の水性クレンジング化粧料について、クレンジング力、使用性について評価した。即ち、下記表２に示す処方のリップカラーを上腕内側部に２ｃｍ×４ｃｍの大きさに塗り、この部位に実施例１〜６及び比較例１、２の水性クレンジング化粧料を使用して評価した。尚、それぞれの水性クレンジング化粧料に対して独立に試験部位を設定して試験を実施した。評価項目はクレンジング効果、洗い流し効果、洗い流し後のべたつき感の３項目であった。評価の基準は、◎：非常によい、○：良い、△：やや良い、×：良くない、の４段階評価とした。結果を表１下段に示す。
<Test example>
About the aqueous cleansing cosmetics of each Example and Comparative Example obtained above, the cleansing power and usability were evaluated. That is, the lip color of the prescription shown in Table 2 below was applied to the inner side of the upper arm in a size of 2 cm × 4 cm, and this part was evaluated using the aqueous cleansing cosmetics of Examples 1 to 6 and Comparative Examples 1 and 2. . In addition, the test site | part was independently set with respect to each water-based cleansing cosmetic, and the test was implemented. The evaluation items were three items: a cleansing effect, a wash-out effect, and a sticky feeling after the wash-out. The evaluation criteria were a four-step evaluation: ◎: very good, ○: good, △: slightly good, x: not good. The results are shown in the lower part of Table 1.
表１の評価結果より、本発明の水性クレンジング化粧料は、クレンジング効果、洗い流し効果、洗い流し後のべたつき感全てにおいて優れていることが判る。 From the evaluation results of Table 1, it can be seen that the water-based cleansing cosmetic composition of the present invention is excellent in all of the cleansing effect, the washing-out effect, and the stickiness after washing.
Claims (7)
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2001316218A (en) * | 2000-05-11 | 2001-11-13 | Daizo:Kk | Cosmetic and aerosol type cosmetic |
| JP2005529159A (en) * | 2002-06-04 | 2005-09-29 | ザ プロクター アンド ギャンブル カンパニー | Conditioning shampoo composition containing a selective cationic conditioning polymer |
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| JP2001316218A (en) * | 2000-05-11 | 2001-11-13 | Daizo:Kk | Cosmetic and aerosol type cosmetic |
| JP2005529159A (en) * | 2002-06-04 | 2005-09-29 | ザ プロクター アンド ギャンブル カンパニー | Conditioning shampoo composition containing a selective cationic conditioning polymer |
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| WO2019177140A1 (en) * | 2018-03-16 | 2019-09-19 | 高級アルコール工業株式会社 | Solid-form cosmetic |
| JP2019156808A (en) * | 2018-03-16 | 2019-09-19 | 高級アルコール工業株式会社 | Solid-form cosmetic |
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