JP2014188838A - Guide device for thermosetting resin impregnated carbon fiber bundle, winding device for thermosetting resin impregnated carbon fiber bundle, method for manufacturing thermosetting resin impregnated carbon fiber bundle wound product, and device and method for manufacturing thermosetting resin impregnated carbon fiber bundle - Google Patents

Guide device for thermosetting resin impregnated carbon fiber bundle, winding device for thermosetting resin impregnated carbon fiber bundle, method for manufacturing thermosetting resin impregnated carbon fiber bundle wound product, and device and method for manufacturing thermosetting resin impregnated carbon fiber bundle Download PDF

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JP2014188838A
JP2014188838A JP2013066305A JP2013066305A JP2014188838A JP 2014188838 A JP2014188838 A JP 2014188838A JP 2013066305 A JP2013066305 A JP 2013066305A JP 2013066305 A JP2013066305 A JP 2013066305A JP 2014188838 A JP2014188838 A JP 2014188838A
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fiber bundle
carbon fiber
thermosetting resin
impregnated
winding
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Tsutomu Kihara
勉 木原
Yuichiro Hirano
佑一朗 平野
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Eneos Corp
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JX Nippon Oil and Energy Corp
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Abstract

PROBLEM TO BE SOLVED: To suppress the occurrence of fluff when a thermosetting resin impregnated carbon fiber bundle (tow prepreg) T is guided in contact with a guide body, such as a guide section 3, in the manufacture of a thermosetting resin impregnated carbon fiber bundle wound product or a thermosetting resin impregnated carbon fiber bundle.SOLUTION: The surface of a guide body is subjected to coating with a surface roughness Ra of 0.75-4.0 μm and a peak count PC of 10-100.

Description

本発明は、熱硬化性樹脂を含浸させた炭素繊維束を案内体に接触させて案内する案内装置に関する。本発明は、また、この案内装置を用いた熱硬化性樹脂含浸炭素繊維束を捲回するための熱硬化性樹脂含浸炭素繊維束捲回装置及び熱硬化性樹脂含浸炭素繊維束捲回製品の製造方法に関する。本発明は、更に、この案内装置を用いた樹脂含浸炭素繊維束(トウプリプレグ)の製造装置及び製造方法に関する。   The present invention relates to a guide device that guides a carbon fiber bundle impregnated with a thermosetting resin by bringing it into contact with a guide body. The present invention also provides a thermosetting resin-impregnated carbon fiber bundle winding device and a thermosetting resin-impregnated carbon fiber bundle winding product for winding a thermosetting resin-impregnated carbon fiber bundle using the guide device. It relates to a manufacturing method. The present invention further relates to a production apparatus and production method for a resin-impregnated carbon fiber bundle (toe prepreg) using this guide device.

例えば耐圧性等の機械的特性と軽量性とが要求される耐圧容器等の製品の製造方法として、フィラメント・ワインディング(FW)法と呼ばれる方法が利用される。FW法においては、ライナー等のコア部材、あるいは中空形状を形成するために成形時に使用されるマンドレルと呼ばれる中芯部材に、炭素繊維、ガラス繊維、アラミド繊維等の強化用の長繊維を引き揃えて構成される繊維束に熱硬化性樹脂を含浸させた熱硬化性樹脂含浸繊維束を捲回し、その後熱硬化性樹脂を硬化させて製品を得る。
なお、FW法においては、熱硬化性樹脂が含浸されていない繊維束と熱硬化性樹脂とを別々に調達し、FW法を実施する工程内で、繊維束に熱硬化性樹脂を含浸して熱硬化性樹脂含浸繊維束を形成せしめ、引き続いてこれを捲回する方法(湿式法)、又は、トウプリプレグ(TPP)と呼ばれる、熱硬化性樹脂が繊維束に予め含浸された熱硬化性樹脂含浸繊維束を調達し、これをそのまま捲回する方法(TPP法)が代表的な方法として利用される(特許文献1参照)。
For example, a method called a filament winding (FW) method is used as a method of manufacturing a product such as a pressure vessel that requires mechanical properties such as pressure resistance and light weight. In the FW method, carbon fibers, glass fibers, aramid fibers, and other reinforcing fibers are aligned on a core member such as a liner or a core member called a mandrel that is used during molding to form a hollow shape. A thermosetting resin-impregnated fiber bundle obtained by impregnating a fiber bundle constituted by a thermosetting resin is wound, and then the thermosetting resin is cured to obtain a product.
In the FW method, the fiber bundle not impregnated with the thermosetting resin and the thermosetting resin are separately procured, and the fiber bundle is impregnated with the thermosetting resin in the process of performing the FW method. A method of forming a thermosetting resin-impregnated fiber bundle and subsequently winding it (wet method), or a thermosetting resin in which a fiber bundle is pre-impregnated with a thermosetting resin called a tow prepreg (TPP) A method of procuring an impregnated fiber bundle and winding it as it is (TPP method) is used as a typical method (see Patent Document 1).

FW法においては、熱硬化性樹脂含浸繊維束の経路が設定され、該経路上にて該繊維束を回転可能なあるいは固定の案内体に接触させて案内している。また、前記TPP法に使用されるTPPを製造する工程、すなわち、繊維束に熱硬化性樹脂を含浸させてTPPを製造する工程においても、同様に熱硬化性樹脂含浸繊維束の経路において案内体を用いた案内が行われる。   In the FW method, a path of the thermosetting resin-impregnated fiber bundle is set, and the fiber bundle is guided in contact with a rotatable or fixed guide body on the path. Further, in the step of manufacturing the TPP used in the TPP method, that is, the step of manufacturing the TPP by impregnating the fiber bundle with the thermosetting resin, the guide body is similarly provided in the path of the thermosetting resin-impregnated fiber bundle. Guidance using is performed.

特許文献2には、特定の方法で炭素繊維糸条に樹脂を含浸させ、特定の条件で該糸条を巻き取ること(請求項1)、加えて炭素繊維および/またはトウプリプレグが接触する糸条位置規制ガイドおよび繊維束成形ガイドが、その表面が3S〜20Sの梨地処理されたクロムメッキからなり、前記ガイドを特定の位置関係とすること(請求項4)により、解舒時における炭素繊維の反転や幅バラツキが少なく、また炭素繊維の毛羽立ちが少ない等の特徴をもつトウプリプレグの製造方法が開示される。   In Patent Document 2, a carbon fiber yarn is impregnated with a resin by a specific method, and the yarn is wound under a specific condition (Claim 1), and in addition, a yarn in contact with carbon fiber and / or tow prepreg The strip position regulation guide and the fiber bundle forming guide are made of chrome plated surface treated with 3S-20S, and the guide has a specific positional relationship (Claim 4). A method for producing a tow prepreg having features such as less inversion and width variation and less fluffing of carbon fibers is disclosed.

特開2011−206933号公報JP 2011-206933 A 特開2012−184279号公報JP 2012-184279 A

しかしながら、熱硬化性樹脂含浸繊維束の捲回により製品を成形する工程、あるいは、TPPの製造工程において、熱硬化性樹脂含浸繊維束を回転可能なあるいは固定の案内体に接触させて案内する際、特に繊維として炭素繊維を用いる場合に、熱硬化性樹脂含浸繊維束の表面の一部が前記案内体との摩擦によって削り取られることにより、「毛羽」が発生することがある。そして、この毛羽が前記案内体に巻付くことにより、繊維束捲回製品の製造工程やTPPの製造工程において、ライン停止等の不具合をもたらすことがある。また、毛羽は、熱硬化性樹脂含浸繊維束を構成する長繊維の一部及び熱硬化性樹脂からなるものではあっても一種の異物であり、繊維束捲回製品へ混入する場合には製品に欠陥をもたらすおそれがあり、あるいは、製造するTPPへ混入する場合には、製品としてのTPPに欠陥をもたらすおそれがある。従って、毛羽の発生は極力抑制することが望まれる。   However, when the thermosetting resin-impregnated fiber bundle is guided in contact with a rotatable or fixed guide in the process of forming the product by winding the thermosetting resin-impregnated fiber bundle, or in the manufacturing process of TPP. In particular, when carbon fibers are used as the fibers, a part of the surface of the thermosetting resin-impregnated fiber bundle is scraped off by friction with the guide body, so that “fluff” may occur. And, when the fluff is wound around the guide body, there may be a problem such as a line stop in the manufacturing process of the fiber bundle wound product or the manufacturing process of the TPP. In addition, the fluff is a kind of foreign matter even if it is made of a part of the long fibers constituting the thermosetting resin impregnated fiber bundle and the thermosetting resin. In the case where it is mixed with the TPP to be manufactured, there is a possibility that the TPP as a product may be defective. Therefore, it is desired to suppress the generation of fluff as much as possible.

なお、本願において「毛羽」とは、前記により発生し、強化繊維の一部及び熱硬化性樹脂を含む、典型的には糸屑状である物品をいう。   In the present application, “fluff” refers to an article that is generated in the manner described above and includes a part of reinforcing fibers and a thermosetting resin, typically in the form of lint.

本発明は、熱硬化性樹脂樹脂含浸炭素繊維束を用いて炭素繊維束捲回製品を製造する工程、あるいは、TPPの製造工程等において、熱硬化性樹脂樹脂含浸炭素繊維束を案内体に接触させて案内する際の毛羽の発生を抑制し、毛羽の発生に起因する炭素繊維束捲回製品又はTPPの製造工程の不具合を低減すること、及びそれぞれの製品の品質を向上させることを目的とし、前記案内体として、特定の表面状態となるようにコーティングが施された部材を用いることにより、毛羽の発生を大幅に低減できるとの知見を得、この知見に基づいてなされたものである。   The present invention is to contact a thermosetting resin resin-impregnated carbon fiber bundle with a guide body in a process of manufacturing a carbon fiber bundle wound product using a thermosetting resin resin-impregnated carbon fiber bundle or a manufacturing process of TPP. The purpose is to suppress the generation of fluff when guiding it, to reduce defects in the production process of the carbon fiber bundle wound product or TPP caused by the generation of fluff, and to improve the quality of each product In addition, the present inventors have obtained a knowledge that the use of a member coated with a specific surface state as the guide body can greatly reduce the occurrence of fluff, and this has been made based on this finding.

上記の課題を解決するために、本発明に係る熱硬化性樹脂含浸繊維束の案内装置は、熱硬化性樹脂を含浸させた炭素繊維束を案内体に接触させて案内する装置であって、前記案内体の前記繊維束と接触する面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施したことを特徴とする。   In order to solve the above-mentioned problems, a thermosetting resin-impregnated fiber bundle guiding device according to the present invention is a device that guides a carbon fiber bundle impregnated with a thermosetting resin by contacting the guide body, The surface of the guide body that contacts the fiber bundle is coated with a surface roughness Ra of 0.75 to 4.0 μm and a peak count PC of 10 to 100.

また、本発明では、熱硬化性樹脂を含浸させた炭素繊維束を供給する供給部と、供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯部材に捲回する捲回部と、前記供給部と前記捲回部との間で熱硬化性樹脂を含浸させた炭素繊維束を案内する、上記案内装置を含む案内部と、を含んで構成される、熱硬化性樹脂含浸炭素繊維束捲回装置を提供する。   In the present invention, a supply unit for supplying a carbon fiber bundle impregnated with a thermosetting resin and a carbon fiber bundle impregnated with the supplied thermosetting resin are formed to form a core member or a hollow shape. A winding portion that winds around a core member, and a guide portion that includes the guide device that guides a carbon fiber bundle impregnated with a thermosetting resin between the supply portion and the winding portion. Provided is a thermosetting resin-impregnated carbon fiber bundle winding device.

また、本発明では、熱硬化性樹脂を含浸させた炭素繊維束を供給する供給工程と、供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯に捲回する捲回工程と、前記供給工程と前記捲回工程との間で、上記案内装置を用いて熱硬化性樹脂を含浸させた炭素繊維束を案内する案内工程と、前記捲回工程後に炭素繊維束に含浸された熱硬化性樹脂を硬化させる硬化工程と、を含んで構成される、炭素繊維束捲回製品の製造方法を提供する。   Further, in the present invention, a supply step of supplying a carbon fiber bundle impregnated with a thermosetting resin, and a carbon fiber bundle impregnated with the supplied thermosetting resin to form a core member or a hollow shape. A winding step of winding on a core, a guide step of guiding a carbon fiber bundle impregnated with a thermosetting resin using the guide device between the supplying step and the winding step, and the winding And a curing step of curing a thermosetting resin impregnated in the carbon fiber bundle after the step. A method for producing a carbon fiber bundle wound product is provided.

前記炭素繊維束捲回製品の製造方法においては、前記供給工程は、予め熱硬化性樹脂が炭素繊維束に含浸されてなるトウプリプレグを供給する工程であってよい。   In the method for producing a carbon fiber bundle wound product, the supplying step may be a step of supplying a tow prepreg in which a carbon fiber bundle is impregnated with a thermosetting resin in advance.

前記炭素繊維束捲回製品の製造方法においては、前記供給工程は、熱硬化性樹脂未含浸の炭素繊維束を繰り出す繰出工程と、繰り出された炭素繊維束を熱硬化性樹脂浴に浸漬して熱硬化性樹脂を含浸させた炭素繊維束を形成する樹脂浸漬工程と、を含んでよい。   In the method for producing the carbon fiber bundle wound product, the supplying step includes a feeding step of feeding out a carbon fiber bundle not impregnated with a thermosetting resin, and a step of immersing the fed carbon fiber bundle in a thermosetting resin bath. A resin dipping step of forming a carbon fiber bundle impregnated with a thermosetting resin.

更に、本発明では、炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸部と、熱硬化性樹脂を含浸させた炭素繊維束をボビンに巻取る巻取部と、前記樹脂含浸部と前記巻取部との間で熱硬化性樹脂を含浸させた炭素繊維束を案内する、上記案内装置を含む案内部と、を含んで構成される、熱硬化性樹脂含浸繊維束の製造装置を提供する。   Furthermore, in the present invention, a resin-impregnated portion for impregnating the carbon fiber bundle with a thermosetting resin, a winding portion for winding the carbon fiber bundle impregnated with the thermosetting resin around a bobbin, the resin-impregnated portion, and the winding There is provided a manufacturing apparatus for a thermosetting resin-impregnated fiber bundle, comprising: a guide portion including the guide device that guides a carbon fiber bundle impregnated with a thermosetting resin with a gripping portion. .

また、本発明では、炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸工程と、熱硬化性樹脂を含浸させた炭素繊維束をボビンに巻取る巻取工程と、前記樹脂含浸工程と前記巻取工程との間で、上記案内装置を用いて、熱硬化性樹脂を含浸させた炭素繊維束を案内する案内工程と、を含んで構成される、熱硬化性樹脂含浸炭素繊維束の製造方法を提供する。   In the present invention, a resin impregnation step for impregnating a carbon fiber bundle with a thermosetting resin, a winding step for winding the carbon fiber bundle impregnated with the thermosetting resin around a bobbin, the resin impregnation step, and the winding step. A guide step of guiding the carbon fiber bundle impregnated with the thermosetting resin using the guide device between the taking step and the manufacturing method of the thermosetting resin-impregnated carbon fiber bundle. I will provide a.

本発明によれば、上記の案内装置を用いることで、熱硬化性樹脂含浸炭素繊維束からの毛羽の発生を効果的に抑制することができる。従って、熱硬化性樹脂含浸炭素繊維束を用いた炭素繊維束捲回製品又はTPPの製造において、毛羽の発生に伴う製造工程の不具合を低減させることができ、また、それぞれ炭素繊維束捲回成形される製品又はTPPの品質を向上させることができる。   According to this invention, generation | occurrence | production of the fluff from a thermosetting resin impregnation carbon fiber bundle can be effectively suppressed by using said guide apparatus. Therefore, in the production of a carbon fiber bundle wound product or TPP using a thermosetting resin-impregnated carbon fiber bundle, it is possible to reduce defects in the production process associated with the generation of fuzz, and each carbon fiber bundle wound molding. The quality of the manufactured product or TPP can be improved.

本発明の第1実施形態を示す熱硬化性樹脂含浸炭素繊維束による炭素繊維束捲回装置の概略平面図The schematic plan view of the carbon fiber bundle winding apparatus by the thermosetting resin impregnation carbon fiber bundle which shows 1st Embodiment of this invention. 第1実施形態でのガイド部の正面図The front view of the guide part in 1st Embodiment 本発明の第1実施形態の別な態様を示す、湿式法を用いた熱硬化性樹脂含浸炭素繊維束による炭素繊維束捲回装置の概略平面図The schematic top view of the carbon fiber bundle winding apparatus by the thermosetting resin impregnation carbon fiber bundle using the wet method which shows another aspect of 1st Embodiment of this invention 本発明の第2実施形態を示す樹脂含浸繊維束の製造装置の概略側面図The schematic side view of the manufacturing apparatus of the resin impregnation fiber bundle which shows 2nd Embodiment of this invention 第2実施形態でのガイドローラの斜視図The perspective view of the guide roller in 2nd Embodiment 表面粗さRaの説明図Illustration of surface roughness Ra ピークカウントPCの説明図Illustration of peak count PC Ra及びPCと毛羽発生量との関係を示す図The figure which shows the relationship between Ra and PC and the amount of fluff generation

以下、本発明の実施の形態について、詳細に説明する。
図1は本発明の第1実施形態の一つの態様を示す、熱硬化性樹脂含浸炭素繊維束による炭素繊維束捲回装置(FW装置)の概略平面図である。ここでいう熱硬化性樹脂含浸炭素繊維束による炭素繊維束捲回装置とは、炭素繊維束捲回製品の製造に際し、熱硬化性樹脂含浸炭素繊維束を補強材としてコア部材又は中空形状を形成するために成形時に使用する中芯部材(マンドレル)に捲回して製品を成形するFW装置である。
Hereinafter, embodiments of the present invention will be described in detail.
FIG. 1 is a schematic plan view of a carbon fiber bundle winding device (FW device) using a thermosetting resin-impregnated carbon fiber bundle, showing one aspect of the first embodiment of the present invention. The carbon fiber bundle winding device using the thermosetting resin-impregnated carbon fiber bundle as used herein means that a core member or a hollow shape is formed by using the thermosetting resin-impregnated carbon fiber bundle as a reinforcing material in the production of the carbon fiber bundle winding product. This is an FW device that forms a product by winding around a core member (mandrel) used during molding.

図1は、容器内壁を構成するライナーをコア部材とし、予め熱硬化性樹脂が炭素繊維束に含浸された形態で供給されるTPPを用い、これを前記ライナーの外周に捲回して炭素繊維束捲回容器を製造する炭素繊維束捲回装置を示している。   FIG. 1 shows a case where a liner constituting the inner wall of a container is used as a core member, and TPP supplied in a form in which a carbon fiber bundle is impregnated with a thermosetting resin in advance is wound around the outer periphery of the liner. 1 shows a carbon fiber bundle winding device for producing a winding container.

図1の熱硬化性樹脂含浸炭素繊維束捲回装置(FW装置)は、トウプリプレグ供給部1と、第1ガイド部2と、第2ガイド部3と、ライナー4への捲回部5と、制御部8とを備える。
トウプリプレグ供給部1は、トウプリプレグTを供給する装置であり、トウプリプレグTが捲回された複数のボビン10を有する。この供給部1からのトウプリプレグTの供給速度は制御部8により制御される。
第1ガイド部2及び第2ガイド部3は、複数のボビン10からのトウプリプレグTを徐々に集束させるように案内する。
第2ガイド部3の詳細構造を図2により説明する。図2は第2ガイド部3の正面図であり、第2ガイド部3を図1の矢印A方向(トウプリプレグTの経路方向)に見ている。
第2ガイド部3は、上下一対の互いに平行な支持バー31、32を備え、各支持バー31、32はトウプリプレグTの経路方向と直角でかつ水平な方向に延びている。上下一対の支持バー31、32間には、複数の支軸33aが所定の間隔で配置され、各支軸33aは上下方向に延びている。そして、各支軸33aに円筒状の案内体33bが回転自在に支承されて、ガイドローラ33が構成されている。
ここにおいて、トウプリプレグTは、適宜のガイドローラ33、33間に引き通され、いずれか一方の案内体33bの円筒面に接触した状態で案内される。
捲回部5は、デリバリーアイ6と、ライナー駆動部7とを備える。
デリバリーアイ6は、供給部1から供給されたトウプリプレグTを集束させ、FWでライナー4に巻付ける装置であり、ライナー4の軸方向と平行な方向に往復移動可能に設けられている。トウプリプレグTの配向角度は、ライナー4の回転速度とデリバリーアイ6の移動速度との比により決定される。デリバリーアイ6の移動速度は制御部8により制御される。
ライナー駆動部7は、金属製の中空円筒部材であるライナー4をその軸線回りに回転駆動する。ライナー4の回転により、デリバリーアイ6を通過してきたトウプリプレグTはライナー4の外周面に捲回される。駆動部7によるライナー4の回転速度も制御部8により制御される。
制御部8は、上述したように、トウプリプレグ供給部1、デリバリーアイ6、ライナー駆動部7等を駆動制御する。
ここにおいて、例えば、第2ガイド部3のガイドローラ33の案内体33bについて、その表面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施すことにより、案内体33bとの接触によるトウプリプレグTからの毛羽の発生を抑制し、毛羽の発生に伴う製造工程の不具合を低減させると共に、製造される成形品の品質を向上させている。
A thermosetting resin-impregnated carbon fiber bundle winding device (FW device) in FIG. 1 includes a tow prepreg supply unit 1, a first guide unit 2, a second guide unit 3, and a winding unit 5 for a liner 4. And a control unit 8.
The tow prepreg supply unit 1 is a device that supplies a tow prepreg T, and includes a plurality of bobbins 10 around which the tow prepreg T is wound. The supply speed of the tow prepreg T from the supply unit 1 is controlled by the control unit 8.
The 1st guide part 2 and the 2nd guide part 3 guide so that the tow prepreg T from the some bobbin 10 may be converged gradually.
The detailed structure of the second guide portion 3 will be described with reference to FIG. FIG. 2 is a front view of the second guide portion 3, and the second guide portion 3 is viewed in the direction of arrow A (the path direction of the tow prepreg T) in FIG. 1.
The second guide portion 3 includes a pair of upper and lower support bars 31 and 32 that are parallel to each other, and each support bar 31 and 32 extends in a direction perpendicular to the path direction of the tow prepreg T and in a horizontal direction. A plurality of support shafts 33a are arranged at a predetermined interval between the pair of upper and lower support bars 31, 32, and each support shaft 33a extends in the up-down direction. A cylindrical guide body 33b is rotatably supported on each support shaft 33a to constitute a guide roller 33.
Here, the tow prepreg T is drawn between appropriate guide rollers 33 and 33 and is guided in contact with the cylindrical surface of one of the guide bodies 33b.
The winding unit 5 includes a delivery eye 6 and a liner driving unit 7.
The delivery eye 6 is a device that focuses the tow prepreg T supplied from the supply unit 1 and winds it on the liner 4 with FW, and is provided so as to be reciprocally movable in a direction parallel to the axial direction of the liner 4. The orientation angle of the tow prepreg T is determined by the ratio between the rotational speed of the liner 4 and the moving speed of the delivery eye 6. The moving speed of the delivery eye 6 is controlled by the control unit 8.
The liner driving unit 7 rotationally drives the liner 4, which is a metal hollow cylindrical member, about its axis. Due to the rotation of the liner 4, the tow prepreg T that has passed through the delivery eye 6 is wound around the outer peripheral surface of the liner 4. The rotation speed of the liner 4 by the drive unit 7 is also controlled by the control unit 8.
As described above, the control unit 8 drives and controls the tow prepreg supply unit 1, the delivery eye 6, the liner driving unit 7, and the like.
Here, for example, the guide body 33b of the guide roller 33 of the second guide portion 3 is coated on the surface thereof with a surface roughness Ra of 0.75 to 4.0 μm and a peak count PC of 10 to 100. As a result, generation of fluff from the tow prepreg T due to contact with the guide body 33b is suppressed, defects in the manufacturing process associated with the generation of fluff are reduced, and the quality of the manufactured molded product is improved.

本発明の第1の実施形態は、図1に示した例に限定されず、製品としては容器以外であってもよく、コア部材としてライナー以外、例えば中実部材を用いてもよい。また、コア部材に代えて、中空部の形状に相当するマンドレルに熱硬化性樹脂含浸炭素繊維束を捲回し、熱硬化性樹脂を硬化させた後にマンドレルを引き抜くことにより、コア部材を有さない中空形状の製品を得ることもできる。   The first embodiment of the present invention is not limited to the example shown in FIG. 1, and the product may be other than a container, and the core member may be other than a liner, for example, a solid member. Also, instead of the core member, the core member is not provided by winding the thermosetting resin-impregnated carbon fiber bundle around the mandrel corresponding to the shape of the hollow portion, and curing the thermosetting resin and then pulling out the mandrel. A hollow product can also be obtained.

また、案内装置としては図1の第2ガイド部3を例示したが、熱硬化性樹脂含浸炭素繊維束に接触する、回転可能なあるいは固定の案内体を有し、前記繊維束を案内する案内装置である限りにおいて、これに限定されない。   Moreover, although the 2nd guide part 3 of FIG. 1 was illustrated as a guide apparatus, it has a guide which can rotate or fix and contacts a thermosetting resin impregnation carbon fiber bundle, and guides the said fiber bundle As long as it is an apparatus, it is not limited to this.

図3は本発明の第1実施形態の別の態様を示すもので、図1に示すTPP法に代えて、湿式法を用いた熱硬化性樹脂含浸炭素繊維束による炭素繊維束捲回装置(FW装置)の概略平面図である。
図3の熱硬化性樹脂含浸炭素繊維束捲回装置(FW装置)は、熱硬化性樹脂含浸炭素繊維束の供給部20と、ガイド部3と、ライナー4への捲回部5と、制御部8とを備える。なお、図1と同一要素には同一符号を付して説明を省略する。
熱硬化性樹脂樹脂炭素繊維束の供給部20は、熱硬化性樹脂を含浸していない炭素繊維束C1を繰り出す供給ロール21と、供給ロール21からの炭素繊維束C1を集束させるように案内するガイド部22と、ガイド部22からの炭素繊維束C1を通過させることにより熱硬化性樹脂を含浸させる熱硬化性樹脂浴(レジンバス)23と、を含んで構成され、レジンバス23を通過して得られた熱硬化性樹脂含浸炭素繊維束C2を供給する。
前記供給部20から供給される熱硬化性樹脂含浸炭素繊維束C2は、ガイド部3を経て、ライナー4への捲回部5へ向かう。捲回部5では、図1に示したTPP法と同様に、ライナー4に捲回される。
ここにおいて、本発明に係る案内装置は、例えばガイド部3に、図1及び図2に示したものと同様の形態で利用される。
FIG. 3 shows another aspect of the first embodiment of the present invention. In place of the TPP method shown in FIG. 1, a carbon fiber bundle winding device using a thermosetting resin-impregnated carbon fiber bundle using a wet method ( It is a schematic plan view of FW apparatus.
The thermosetting resin-impregnated carbon fiber bundle winding device (FW device) of FIG. 3 includes a thermosetting resin-impregnated carbon fiber bundle supply unit 20, a guide unit 3, a winding unit 5 to the liner 4, and a control. Part 8. In addition, the same code | symbol is attached | subjected to the same element as FIG. 1, and description is abbreviate | omitted.
The thermosetting resin resin carbon fiber bundle supply unit 20 guides the supply roll 21 that feeds out the carbon fiber bundle C1 not impregnated with the thermosetting resin and the carbon fiber bundle C1 from the supply roll 21 to converge. It comprises a guide part 22 and a thermosetting resin bath (resin bath) 23 that impregnates a thermosetting resin by allowing the carbon fiber bundle C1 from the guide part 22 to pass through. The obtained thermosetting resin-impregnated carbon fiber bundle C2 is supplied.
The thermosetting resin-impregnated carbon fiber bundle C <b> 2 supplied from the supply unit 20 goes to the winding unit 5 to the liner 4 through the guide unit 3. In the winding unit 5, the winding unit 5 is wound around the liner 4 in the same manner as the TPP method shown in FIG. 1.
Here, the guide device according to the present invention is used, for example, in the guide unit 3 in the same form as that shown in FIGS.

なお、図3に示す湿式法は、熱硬化性樹脂が未含浸の炭素繊維束に、FW工程と同一の工程中で熱硬化性樹脂を含浸して熱硬化性樹脂含浸炭素繊維束を形成しつつこれを捲回するため、TPP法に比較してコストを低減することが可能である。一方、湿式法においては、炭素繊維束を熱硬化性樹脂浴中に浸漬・通過させるという簡易な方法により含浸を行うため、低粘度の熱硬化性樹脂しか使用できず、熱硬化性樹脂含浸炭素繊維束に高いタック性を付与することができない等の制限がある。これに対して、図1に示すTPP法においては、コーター等の含浸装置を使用して高粘度の熱硬化性樹脂を含浸することも可能であるため、熱硬化性樹脂含浸炭素繊維束のタック性等の性状に大きな自由度を付与することが可能となる。   In the wet method shown in FIG. 3, a carbon fiber bundle not impregnated with a thermosetting resin is impregnated with a thermosetting resin in the same process as the FW process to form a thermosetting resin-impregnated carbon fiber bundle. However, since this is wound, it is possible to reduce the cost as compared with the TPP method. On the other hand, in the wet method, since the carbon fiber bundle is impregnated by a simple method of immersing and passing through the thermosetting resin bath, only a low-viscosity thermosetting resin can be used, and the thermosetting resin-impregnated carbon is used. There is a limitation that high tackiness cannot be imparted to the fiber bundle. On the other hand, in the TPP method shown in FIG. 1, it is possible to impregnate a thermosetting resin with high viscosity using an impregnation apparatus such as a coater. It becomes possible to give a large degree of freedom to properties such as properties.

図4は本発明の第2実施形態を示す樹脂含浸繊維束(トウプリプレグ)の製造装置の概略側面図である。
図4のトウプリプレグ製造装置は、炭素繊維束T1の繰り出し部51と、炭素繊維束T1を案内するガイド部53と、炭素繊維束T1に熱硬化性樹脂を含浸させる樹脂含浸部56と、熱硬化性樹脂を含浸させた繊維束(TPP)T2を案内するガイド部60と、TPP T2を巻取る巻取り部63と、を含んで構成される。
繰り出し部51は、炭素繊維束T1を供給する装置であり、炭素繊維束T1が巻回された複数のボビン52を備える。
ガイド部53は、上下一対の開繊バー54、55を含んで構成され、繰り出し部51からの炭素繊維束T1を樹脂含浸部56へ案内する。
樹脂含浸部56は、例えば一連のガイドローラ群57により構成され、樹脂槽58からギアポンプ59により熱硬化性樹脂が一つのローラに供給される。当該ローラには、例えば溝が形成され、この溝に炭素繊維束が通され、この溝にギアポンプ59から送り出される熱硬化性樹脂が供給され、場合により対向するローラにて圧縮することにより、炭素繊維束に熱硬化性樹脂を含浸する。
ガイド部60は、最終段のガイドローラ61と外部のガイドローラ62とを含んで構成され、樹脂含浸部56にて樹脂を含浸された繊維束T2を巻取部63へ案内する。
巻取部63は、樹脂を含浸された繊維束T2をボビンに巻取る装置であり、複数の巻取ボビン64を備える。
これにより、樹脂を含浸された繊維束T2がボビン64の形で、トウプリプレグとして製品化される。
ここにおいて、図5に樹脂含浸部56の最終段のガイドローラ61の斜視図を示す。このガイドローラ61は、支軸61aと、この支軸61aに回転自在に支承された円筒状の案内体61bとから構成されている。このガイドローラ61の案内体61bについては、その表面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施すことにより、案内体61bとの接触による樹脂含浸繊維束T2からの毛羽の発生を抑制し、製造されるトウプリプレグの品質を向上させている。
FIG. 4 is a schematic side view of an apparatus for producing a resin-impregnated fiber bundle (tow prepreg) showing a second embodiment of the present invention.
The tow prepreg manufacturing apparatus of FIG. 4 includes a feeding part 51 for the carbon fiber bundle T1, a guide part 53 for guiding the carbon fiber bundle T1, a resin impregnating part 56 for impregnating the carbon fiber bundle T1 with a thermosetting resin, It comprises a guide portion 60 for guiding a fiber bundle (TPP) T2 impregnated with a curable resin, and a winding portion 63 for winding TPP T2.
The feeding unit 51 is a device that supplies the carbon fiber bundle T1, and includes a plurality of bobbins 52 around which the carbon fiber bundle T1 is wound.
The guide portion 53 includes a pair of upper and lower opening bars 54 and 55, and guides the carbon fiber bundle T <b> 1 from the feeding portion 51 to the resin-impregnated portion 56.
The resin impregnated portion 56 is constituted by a series of guide roller groups 57, for example, and a thermosetting resin is supplied from a resin tank 58 to one roller by a gear pump 59. For example, a groove is formed in the roller, a carbon fiber bundle is passed through the groove, and a thermosetting resin fed from the gear pump 59 is supplied to the groove. The fiber bundle is impregnated with a thermosetting resin.
The guide unit 60 includes a final stage guide roller 61 and an external guide roller 62, and guides the fiber bundle T <b> 2 impregnated with the resin in the resin impregnating unit 56 to the winding unit 63.
The winding unit 63 is a device that winds the fiber bundle T <b> 2 impregnated with resin onto a bobbin, and includes a plurality of winding bobbins 64.
As a result, the fiber bundle T2 impregnated with the resin is commercialized as a tow prepreg in the form of the bobbin 64.
Here, FIG. 5 shows a perspective view of the guide roller 61 at the final stage of the resin impregnated portion 56. The guide roller 61 includes a support shaft 61a and a cylindrical guide body 61b rotatably supported on the support shaft 61a. The guide body 61b of the guide roller 61 is contacted with the guide body 61b by applying a coating with a surface roughness Ra of 0.75 to 4.0 μm and a peak count PC of 10 to 100 on the surface thereof. Generation | occurrence | production of the fluff from the resin impregnation fiber bundle T2 by this is suppressed, and the quality of the tow prepreg manufactured is improved.

本発明では、熱硬化性樹脂を含浸させた繊維束を案内体に接触させて案内する装置において、その案内体の表面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施すが、以下に実施例及び比較例によりその詳細を説明する。なお、本発明は以下の実施例に限定されるものではない。   In the present invention, in an apparatus for guiding a fiber bundle impregnated with a thermosetting resin by bringing it into contact with a guide body, the surface roughness Ra is 0.75 to 4.0 μm on the surface of the guide body, and the peak count PC The coating is applied in a range of 10 to 100, and the details thereof will be described below with reference to Examples and Comparative Examples. In addition, this invention is not limited to a following example.

〔表面粗さの測定〕
コーティング材の粗度測定については、Mahr社製ペルトメーターM4Piを用いて、コーティング表面のRa及びPCを測定した。
Raとは、図6に示されるように、粗さ曲線から、その平均線の方向に基準長さLだけ抜き取り、この抜き取り部分の平均線から測定曲線までの偏差の絶対値を合計し、平均した値である。これは算術平均粗さとも呼ばれ、1つの傷が測定値に及ぼす影響が非常に小さくなり、安定した結果が得られるという特徴がある。
PCとは、図7に示されるように、粗さ曲線での、単位長さL=10mm当たりの山の数であり、粗さ曲線を求め、その中心線と平行に上下それぞれに中心線からの距離が0.13μmの直線を設け、上側の直線を超えた後、下側の直線を超えたときに1カウントしたときの、測定長さ10mmに達するまでの総カウント数として測定される。
[Measurement of surface roughness]
For measuring the roughness of the coating material, Ra and PC on the coating surface were measured using a Pelometer M4Pi manufactured by Mahr.
As shown in FIG. 6, Ra is extracted from the roughness curve by the reference length L in the direction of the average line, and the absolute values of deviations from the average line of the extracted portion to the measurement curve are summed, and the average It is the value. This is also called arithmetic mean roughness, and has the feature that the influence of one scratch on the measured value is very small and a stable result can be obtained.
As shown in FIG. 7, the PC is the number of peaks per unit length L = 10 mm in the roughness curve. The roughness curve is obtained, and the center line is parallel to the center line and vertically from the center line. Is measured as the total number of counts until the measurement length of 10 mm is reached when a straight line having a distance of 0.13 μm is provided and the upper straight line is exceeded and then the lower straight line is counted.

〔実施例1〕
汎用エポキシ樹脂を含浸させた炭素繊維のトウプリプレグ(繊維:東レ社製T800SC‐24K、樹脂含量:29wt%)4本を、大阪ガスケミカル社製コーティングPC1215/620(Ra=2.87、PC=20)を施した2本の回転しない段違いバー(各Φ6mm、基材はSUS304)に互いに接触しないようにS字状に通し、張力3kgを掛けながら25m/分の速度で600m流した時に、バーに付着した全ての毛羽の重量を測定した。
[Example 1]
Carbon fiber tow prepreg impregnated with general-purpose epoxy resin (fiber: T800SC-24K manufactured by Toray Industries Inc., resin content: 29 wt%) 4 coatings made by Osaka Gas Chemical Co., Ltd. PC1215 / 620 (Ra = 2.87, PC = 20) Pass through two non-rotating uneven bars (6 mm each, SUS304) in a S shape so that they do not touch each other, and adhere to the bar when flowing 600 m at a speed of 25 m / min while applying a tension of 3 kg The weight of all fluff was measured.

〔実施例2〕
コーティングを、フッ素セラミックコーティング(Ra=0.77、PC=33)にした以外は実施例1と同じ条件で、バーに付着した全ての毛羽の重量を測定した。
[Example 2]
The weight of all fluff adhered to the bar was measured under the same conditions as in Example 1 except that the coating was a fluorine ceramic coating (Ra = 0.77, PC = 33).

〔実施例3〕
コーティングを、フッ素(PFA)コーティング(Ra=1.75、PC=85)にした以外は実施例1と同じ条件で、バーに付着した全ての毛羽の重量を測定した。
Example 3
The weight of all fluff adhering to the bar was measured under the same conditions as in Example 1 except that the coating was a fluorine (PFA) coating (Ra = 1.75, PC = 85).

〔比較例1〕
コーティングを、ブラストロンコーティング(Ra=0.69、PC=233)にした以外は実施例1と同じ条件で、バーに付着した全ての毛羽の重量を測定した。
[Comparative Example 1]
The weight of all fluff adhering to the bar was measured under the same conditions as in Example 1 except that the coating was a brasstron coating (Ra = 0.69, PC = 233).

〔比較例2〕
バーにコーティングを施さず(Ra=0.27、PC=280)、それ以外は実施例1と同じ条件で、バーに付着した全ての毛羽の量を測定した。
[Comparative Example 2]
The amount of all fluff adhering to the bar was measured under the same conditions as in Example 1 except that the bar was not coated (Ra = 0.27, PC = 280).

〔実施例4〕
汎用エポキシ樹脂を含浸させた炭素繊維のトウプリプレグ(繊維:東レ社製T800SC‐24K、樹脂含量:29wt%)5本を、大阪ガスケミカル社製コーティングPC1215/620(Ra=2.87、PC=20)を施した6本の回転ローラー(材質:アルミニウム、Φ8mm)の間に各1本ずつ通し、張力4kg、35m/分の速度で1200m流した時に、回転ローラーに付着した全ての毛羽の重量を測定した。
Example 4
Carbon fiber tow prepreg impregnated with general-purpose epoxy resin (fiber: T800SC-24K manufactured by Toray Industries, Inc., resin content: 29 wt%), 5 coatings made by Osaka Gas Chemical Co., Ltd. PC1215 / 620 (Ra = 2.87, PC = 20) Measure the weight of all fluff adhering to the rotating roller when it is passed through each of the six rotating rollers (material: aluminum, Φ8mm) and 1200m flowed at a tension of 4kg and a speed of 35m / min. did.

〔実施例5〕
コーティングを、フッ素セラミックコーティング(Ra=0.77、PC=33)にした以外は実施例4と同じ条件で、回転ローラーに付着した全ての毛羽の重量を測定した。
Example 5
The weight of all fluff adhering to the rotating roller was measured under the same conditions as in Example 4 except that the coating was a fluorine ceramic coating (Ra = 0.77, PC = 33).

〔比較例3〕
コーティングを、トシコ社製UNA-880GY(Ra=5.29、PC=103)にした以外は実施例4と同じ条件で回転ローラーに付着した全ての毛羽の重量を測定した。
[Comparative Example 3]
The weight of all fluff adhering to the rotating roller was measured under the same conditions as in Example 4 except that the coating was UNA-880GY (Ra = 5.29, PC = 103) manufactured by Toshiko.

上記の実施例及び比較例で採取した毛羽の重量(mg)の測定結果を表1に示す。   Table 1 shows the measurement results of the weight (mg) of the fluff collected in the above Examples and Comparative Examples.

また、上記の実施例及び比較例以外に、本発明者らは、各種コーティング材でのRa及びPCと、発生した毛羽の重量とを測定しており、その結果を上記実施例及び比較例の結果と共に表2に示す。   In addition to the above examples and comparative examples, the present inventors have measured Ra and PC in various coating materials and the weight of the generated fluff, and the results are the results of the above examples and comparative examples. It shows in Table 2 with a result.

図8は、Ra及びPCと毛羽発生量との関係を示す図であり、表1及び表2のデータに基づき、Raを横軸、PCを縦軸として、Ra、PCにより定まる位置に、発生した毛羽の重量に比例させた面積を持つ円を描いたものである。
これによると、図8に点線枠で示す、Ra=0.75〜4.00、PC=10〜100の範囲内では、毛羽の発生量に対応する円の面積が小さくなり、案内体の表面粗度の適正範囲であると考えられる。この範囲は、従来に比べ、Raはやや高いが、PCが小さい範囲となっている。
FIG. 8 is a diagram showing the relationship between Ra and PC and the amount of fluff generation. Based on the data in Tables 1 and 2, the occurrence occurs at a position determined by Ra and PC, with Ra as the horizontal axis and PC as the vertical axis. A circle with an area proportional to the weight of the fluff is drawn.
According to this, within the range of Ra = 0.75 to 4.00 and PC = 10 to 100, indicated by the dotted frame in FIG. 8, the area of the circle corresponding to the amount of fluff generation becomes small, and the surface of the guide body It is considered to be an appropriate range of roughness. This range is a range where Ra is slightly higher than in the conventional case, but the PC is small.

以上説明したように、本実施形態によれば、熱硬化性樹脂含浸炭素繊維束を案内体に接触させて案内する装置において、案内体の表面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施したことにより、熱硬化性樹脂含浸炭素繊維束からの毛羽の発生を効果的に抑制することができる。   As described above, according to the present embodiment, in the apparatus for guiding the thermosetting resin-impregnated carbon fiber bundle in contact with the guide body, the surface roughness Ra is 0.75-4. By applying the coating having a peak count PC of 10 to 100 at 0 μm, generation of fluff from the thermosetting resin-impregnated carbon fiber bundle can be effectively suppressed.

また、本実施形態での熱硬化性樹脂含浸炭素繊維束捲回装置は、熱硬化性樹脂を含浸させた炭素繊維束を供給する供給部と、供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯部材に捲回する捲回部と、前記供給部と前記捲回部との間で熱硬化性樹脂を含浸させた炭素繊維束を案内する上記コーティングの案内装置を含む案内部と、を含んで構成されるため、毛羽発生に伴う熱硬化性樹脂含浸炭素繊維束捲回工程の不具合を低減できると共に、成形される製品の品質を向上させることができる。なお、前記供給部は、予め炭素繊維束に熱硬化性樹脂を含浸させてなるトウプリプレグを供給してもよいし、炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸部を含んで構成され、炭素繊維束に熱硬化性樹脂を含浸させて熱硬化性樹脂含浸炭素繊維束を形成しこれを供給してもよい。   Further, the thermosetting resin-impregnated carbon fiber bundle winding device in the present embodiment includes a supply unit that supplies a carbon fiber bundle impregnated with a thermosetting resin, and a carbon impregnated with the supplied thermosetting resin. A winding part for winding the fiber bundle on a core member or a core member for forming a hollow shape, and a carbon fiber bundle impregnated with a thermosetting resin between the supply part and the winding part are guided. And a guide section including the above-mentioned coating guide device, so that it is possible to reduce defects in the thermosetting resin-impregnated carbon fiber bundle winding process due to the occurrence of fluff and improve the quality of the molded product Can be made. The supply unit may supply a tow prepreg obtained by impregnating a carbon fiber bundle with a thermosetting resin in advance, or may include a resin impregnation unit that impregnates the carbon fiber bundle with a thermosetting resin. Alternatively, a carbon fiber bundle may be impregnated with a thermosetting resin to form a thermosetting resin-impregnated carbon fiber bundle and supplied.

また、本実施形態での熱硬化性樹脂含浸炭素繊維束捲回方法は、熱硬化性樹脂を含浸させた炭素繊維束を供給する供給工程と、供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯部材に捲回する捲回工程と、前記供給工程と前記捲回工程との間で、上記コーティングの案内装置を用いて、熱硬化性樹脂を含浸させた炭素繊維束を案内する工程と、を含んで構成されるため、毛羽発生に伴う熱硬化性樹脂含浸炭素繊維束捲回工程の不具合を低減できると共に、成形される製品の品質を向上させることができる。   In addition, the thermosetting resin-impregnated carbon fiber bundle winding method in this embodiment includes a supply step of supplying a carbon fiber bundle impregnated with a thermosetting resin, and a carbon impregnated with the supplied thermosetting resin. Between the winding step of winding the fiber bundle on a core member or a core member for forming a hollow shape, and between the supplying step and the winding step, using the above-mentioned coating guide device, thermosetting And a step of guiding the carbon fiber bundle impregnated with the resin, so that it is possible to reduce defects of the thermosetting resin-impregnated carbon fiber bundle winding process due to the generation of fluff and to improve the quality of the molded product Can be improved.

また、本実施形態の熱硬化性樹脂含浸炭素繊維束(トウプリプレグ)の製造装置は、炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸部と、熱硬化性樹脂含浸炭素繊維束をボビンに巻取る巻取部と、前記樹脂含浸部と前記巻取部との間で熱硬化性樹脂含浸炭素繊維束を案内する上記コーティングの案内装置と、を含んで構成されるため、毛羽発生に伴うトウプリプレグ製造工程の不具合を低減できると共に、製品としてのトウプリプレグの品質を向上させることができる。   In addition, the manufacturing apparatus for the thermosetting resin-impregnated carbon fiber bundle (toe prepreg) according to the present embodiment includes a resin-impregnated portion for impregnating the carbon fiber bundle with the thermosetting resin, and the thermosetting resin-impregnated carbon fiber bundle as a bobbin. Since it is configured to include a winding unit for winding, and the coating guide device for guiding the thermosetting resin-impregnated carbon fiber bundle between the resin-impregnated unit and the winding unit, it is accompanied by generation of fluff. In addition to reducing defects in the tow prepreg manufacturing process, the quality of the tow prepreg as a product can be improved.

また、本実施形態の熱硬化性樹脂含浸炭素繊維束(トウプリプレグ)の製造方法は、炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸工程と、熱硬化性樹脂を含浸させた炭素繊維束をボビンに巻取る巻取工程と、前記樹脂含浸工程と前記巻取工程との間で、上記コーティングの案内装置を用いて、熱硬化性樹脂含浸炭素繊維束を案内する工程と、を含んで構成されるため、毛羽発生に伴うトウプリプレグ製造工程の不具合を低減できると共に、製品としてのトウプリプレグの品質を向上させることができる。   In addition, the manufacturing method of the thermosetting resin-impregnated carbon fiber bundle (toe prepreg) of the present embodiment includes a resin impregnation step of impregnating the carbon fiber bundle with the thermosetting resin, and a carbon fiber bundle impregnated with the thermosetting resin. A winding step of winding the wire around a bobbin, and a step of guiding the thermosetting resin-impregnated carbon fiber bundle using the coating guide device between the resin impregnation step and the winding step. Since it is comprised, while the defect of the tow prepreg manufacturing process accompanying fluff generation can be reduced, the quality of the tow prepreg as a product can be improved.

なお、図示の実施形態はあくまで本発明を例示するものであり、本発明は、説明した実施形態により直接的に示されるものに加え、特許請求の範囲内で当業者によりなされる各種の改良・変更を包含するものであることは言うまでもない。   The illustrated embodiment is merely an example of the present invention, and the present invention is not limited to the embodiment described directly, and includes various improvements and modifications made by those skilled in the art within the scope of the claims. Needless to say, it encompasses changes.

本発明は、熱硬化性樹脂含浸炭素繊維束からの毛羽の発生を抑制し、熱硬化性樹脂含浸炭素繊維束捲回工程、あるいはトウプリプレグ製造工程における毛羽の発生に伴う不具合を低減でき、FW法により成形される製品、あるいは製造されるトウプリプレグの品質を向上させることができ、産業上の利用可能性は大である。   The present invention suppresses the occurrence of fluff from the thermosetting resin-impregnated carbon fiber bundle, and can reduce problems associated with the occurrence of fluff in the thermosetting resin-impregnated carbon fiber bundle winding process or tow prepreg manufacturing process. The quality of the product molded by the method or the tow prepreg produced can be improved, and the industrial applicability is great.

1 トウプリプレグ供給部
2 第1ガイド部
3 第2ガイド部
4 ライナー
5 捲回部
6 デリバリーアイ
7 ライナー駆動部
8 制御部
10 トウプリプレグTのボビン
20 熱硬化性樹脂含浸炭素繊維束の供給部
21 供給ロール
22 ガイド部
23 熱硬化性樹脂浴(レジンバス)
31、32 支持バー
33 ガイドローラ
33a 支軸
33b 案内体
51 繰り出し部
52 ボビン
53 ガイド部
54、55 開繊バー
56 樹脂含浸部
57 ガイドローラ
58 樹脂槽
59 ギアポンプ
60 ガイド部
61 ガイドローラ
61a 支軸
61b 案内体
62 ガイドローラ
63 巻取部
64 巻取ボビン
DESCRIPTION OF SYMBOLS 1 Toe prepreg supply part 2 1st guide part 3 2nd guide part 4 Liner 5 Winding part 6 Delivery eye 7 Liner drive part 8 Control part 10 Bobbin 20 of tow prepreg T Supply part 21 of thermosetting resin impregnation carbon fiber bundle Supply roll 22 Guide part 23 Thermosetting resin bath (resin bath)
31, 32 Support bar 33 Guide roller 33a Support shaft 33b Guide body 51 Feeding portion 52 Bobbin 53 Guide portion 54, 55 Opening bar 56 Resin impregnation portion 57 Guide roller 58 Resin tank 59 Gear pump 60 Guide portion 61 Guide roller 61a Support shaft 61b Guide body 62 Guide roller 63 Winding part 64 Winding bobbin

Claims (7)

熱硬化性樹脂を含浸させた炭素繊維束を案内体に接触させて案内する装置であって、
前記案内体の前記繊維束と接触する面に、表面粗さRaが0.75〜4.0μmで、ピークカウントPCが10〜100であるコーティングを施したことを特徴とする、熱硬化性樹脂含浸炭素繊維束の案内装置。
An apparatus for guiding a carbon fiber bundle impregnated with a thermosetting resin by bringing it into contact with a guide body,
A thermosetting resin, characterized in that a coating with a surface roughness Ra of 0.75 to 4.0 μm and a peak count PC of 10 to 100 is applied to a surface of the guide body that contacts the fiber bundle. Guide device for impregnated carbon fiber bundle.
熱硬化性樹脂を含浸させた炭素繊維束を供給する供給部と、
供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯部材に捲回する捲回部と、
前記供給部と前記捲回部との間で熱硬化性樹脂を含浸させた炭素繊維束を案内する、請求項1記載の案内装置を含む案内部と、
を含んで構成される、熱硬化性樹脂含浸炭素繊維束捲回装置。
A supply unit for supplying a carbon fiber bundle impregnated with a thermosetting resin;
A winding section for winding a carbon fiber bundle impregnated with a supplied thermosetting resin around a core member or a core member for forming a hollow shape;
A guide unit including a guide device according to claim 1, which guides a carbon fiber bundle impregnated with a thermosetting resin between the supply unit and the winding unit;
A thermosetting resin-impregnated carbon fiber bundle winding device comprising:
熱硬化性樹脂を含浸させた炭素繊維束を供給する供給工程と、
供給される熱硬化性樹脂を含浸させた炭素繊維束をコア部材又は中空形状を形成するための中芯部材に捲回する捲回工程と、
前記供給工程と前記捲回工程との間で、請求項1記載の案内装置を用いて、熱硬化性樹脂を含浸させた炭素繊維束を案内する案内工程と、
前記捲回工程後に炭素繊維束に含浸された熱硬化性樹脂を硬化させる硬化工程と、
を含んで構成される、炭素繊維束捲回製品の製造方法。
Supplying a carbon fiber bundle impregnated with a thermosetting resin;
A winding step of winding a carbon fiber bundle impregnated with a supplied thermosetting resin around a core member or a core member for forming a hollow shape;
Between the supplying step and the winding step, using the guide device according to claim 1, guiding the carbon fiber bundle impregnated with a thermosetting resin,
A curing step of curing the thermosetting resin impregnated in the carbon fiber bundle after the winding step;
The manufacturing method of a carbon fiber bundle winding product comprised including.
前記供給工程は、予め熱硬化性樹脂が炭素繊維束に含浸されてなるトウプリプレグを供給する工程である、請求項3記載の炭素繊維束捲回製品の製造方法。   The method for producing a carbon fiber bundle wound product according to claim 3, wherein the supplying step is a step of supplying a tow prepreg in which a carbon fiber bundle is impregnated with a thermosetting resin in advance. 前記供給工程は、
熱硬化性樹脂未含浸の炭素繊維束を繰り出す繰出工程と、
繰り出された炭素繊維束を熱硬化性樹脂浴に浸漬して熱硬化性樹脂を含浸させた炭素繊維束を形成する樹脂浸漬工程と、
を含む、請求項3記載の炭素繊維束捲回製品の製造方法。
The supply step includes
A feeding step of feeding out a carbon fiber bundle not impregnated with a thermosetting resin;
A resin dipping step in which the drawn carbon fiber bundle is immersed in a thermosetting resin bath to form a carbon fiber bundle impregnated with a thermosetting resin;
The manufacturing method of the carbon fiber bundle winding product of Claim 3 containing this.
炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸部と、
熱硬化性樹脂を含浸させた炭素繊維束をボビンに巻取る巻取部と、
前記樹脂含浸部と前記巻取部との間で熱硬化性樹脂を含浸させた炭素繊維束を案内する、請求項1記載の案内装置を含む案内部と、
を含んで構成される、熱硬化性樹脂含浸炭素繊維束の製造装置。
A resin-impregnated portion for impregnating a carbon fiber bundle with a thermosetting resin;
A winding unit for winding a carbon fiber bundle impregnated with a thermosetting resin around a bobbin;
A guide unit including a guide device according to claim 1, which guides a carbon fiber bundle impregnated with a thermosetting resin between the resin-impregnated unit and the winding unit;
An apparatus for producing a thermosetting resin-impregnated carbon fiber bundle, comprising:
炭素繊維束に熱硬化性樹脂を含浸させる樹脂含浸工程と、
熱硬化性樹脂を含浸させた炭素繊維束をボビンに巻取る巻取工程と、
前記樹脂含浸工程と前記巻取工程との間で、請求項1記載の案内装置を用いて、熱硬化性樹脂を含浸させた炭素繊維束を案内する案内工程と、
を含んで構成される、熱硬化性樹脂含浸炭素繊維束の製造方法。
A resin impregnation step of impregnating a carbon fiber bundle with a thermosetting resin;
A winding step of winding a carbon fiber bundle impregnated with a thermosetting resin around a bobbin;
Between the resin impregnation step and the winding step, the guide step of guiding the carbon fiber bundle impregnated with the thermosetting resin using the guide device according to claim 1;
A method for producing a thermosetting resin-impregnated carbon fiber bundle, comprising:
JP2013066305A 2013-03-27 2013-03-27 Guide device for thermosetting resin impregnated carbon fiber bundle, winding device for thermosetting resin impregnated carbon fiber bundle, method for manufacturing thermosetting resin impregnated carbon fiber bundle wound product, and device and method for manufacturing thermosetting resin impregnated carbon fiber bundle Pending JP2014188838A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015093448A (en) * 2013-11-13 2015-05-18 トヨタ自動車株式会社 High pressure tank production device
JP2017193135A (en) * 2016-04-22 2017-10-26 トヨタ自動車株式会社 Filament winding device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015093448A (en) * 2013-11-13 2015-05-18 トヨタ自動車株式会社 High pressure tank production device
JP2017193135A (en) * 2016-04-22 2017-10-26 トヨタ自動車株式会社 Filament winding device

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