JP2014124791A - Method for producing rubber tube and production device therefor - Google Patents

Method for producing rubber tube and production device therefor Download PDF

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JP2014124791A
JP2014124791A JP2012281424A JP2012281424A JP2014124791A JP 2014124791 A JP2014124791 A JP 2014124791A JP 2012281424 A JP2012281424 A JP 2012281424A JP 2012281424 A JP2012281424 A JP 2012281424A JP 2014124791 A JP2014124791 A JP 2014124791A
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rubber tube
cylindrical member
temperature fluid
manufacturing
path
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JP6194170B2 (en
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Koichi Yonezawa
浩一 米澤
Takumi Izumida
拓実 和泉田
Takeshi Asada
剛 浅田
Nobuyuki Takahashi
信行 高橋
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Sakura Rubber Co Ltd
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Sakura Rubber Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a method for producing a rubber tube in which dimensions and shape are stabilized.SOLUTION: The method for producing a rubber tube comprises: a step of inserting an un-crosslinked rubber tube G into a cylindrical member 20; a step of flowing heating steam into the rubber tube G to expand and crosslink the rubber tube G, and pressing the same against the inner wall of the cylindrical member 20; and a step of removing the heating steam from the inside of the rubber tube G to shrink the rubber tube G, and releasing the same from the inner wall of the cylindrical member 20.

Description

本発明は、ゴムチューブの製造方法及び製造装置に関し、特に寸法や形状の安定性を向上させる技術に関する。   The present invention relates to a method and an apparatus for manufacturing a rubber tube, and more particularly to a technique for improving the stability of dimensions and shape.

水道用のホースや可燃性ガスのホース等として、ゴムチューブが広く使用されている。ゴムチューブは適度な弾性を有することから、容易に変形させることが可能である。このため、上記用途に限らない様々な用途に利用されている。   Rubber tubes are widely used as hoses for water supply or flammable gases. Since the rubber tube has moderate elasticity, it can be easily deformed. For this reason, it is used for various purposes not limited to the above-mentioned purposes.

ゴムチューブの原料である生ゴムには、一般に知られるゴムのような弾性はほとんど無い。この生ゴムに弾性を付加する方法として、架橋が知られている(例えば、特許文献1参照。)。架橋は、原料の生ゴムに硫黄等を付加し、加熱することでゴムに所要の弾性を付加する方法である。ゴムチューブを架橋する場合、生ゴムに硫黄等を付加し、押し出し加工により所要の形状に加工した後に電気炉等に移送し、加熱する方法が知られている(例えば、特許文献2参照。)。   The raw rubber that is the raw material of the rubber tube has almost no elasticity like that of generally known rubber. Crosslinking is known as a method of adding elasticity to this raw rubber (see, for example, Patent Document 1). Crosslinking is a method of adding required elasticity to rubber by adding sulfur or the like to raw raw rubber and heating it. In the case of crosslinking a rubber tube, a method is known in which sulfur or the like is added to raw rubber, processed into a desired shape by extrusion, and then transferred to an electric furnace or the like and heated (see, for example, Patent Document 2).

特開2009−145665号公報(段落番号[0005]〜[0009])JP 2009-145665 A (paragraph numbers [0005] to [0009]) 特開平05−314823号公報(段落番号[0017]〜[0023])JP 05-314823 A (paragraph numbers [0017] to [0023])

上述したゴムチューブの製造方法では、次のような問題があった。すなわち、電気炉等に移送して加熱し、架橋する方法では、ゴムチューブが物理的に拘束されない状態で架橋されるため、自重等により変形した状態で架橋される。このため、架橋後のゴムチューブの寸法や形状にばらつきが生じるという問題があった。   The rubber tube manufacturing method described above has the following problems. That is, in the method of transferring to an electric furnace or the like, heating, and crosslinking, the rubber tube is crosslinked in a state where it is not physically constrained, and thus is crosslinked in a deformed state due to its own weight or the like. For this reason, there existed a problem that dispersion | variation produced in the dimension and shape of the rubber tube after bridge | crosslinking.

そこで本発明は、寸法や形状が安定したゴムチューブが得られるゴムチューブの製造方法及び製造装置を提供することを目的としている。   Then, this invention aims at providing the manufacturing method and manufacturing apparatus of a rubber tube from which the rubber tube with a stable dimension and shape is obtained.

前記課題を解決し目的を達成するために、本発明のゴムチューブの製造方法及び製造装置は次のように構成されている。   In order to solve the above problems and achieve the object, the rubber tube manufacturing method and manufacturing apparatus of the present invention are configured as follows.

本発明のゴムチューブの製造方法は、未架橋のゴムチューブを筒状部材の内部に挿入する工程と、上記ゴムチューブの内部に高温流体を流入させて上記ゴムチューブを膨張かつ架橋させ、上記筒状部材の内壁に押圧させる工程と、上記ゴムチューブの内部から上記加熱流体を除去して上記ゴムチューブを収縮させ、上記筒状部材の内壁から離型させる工程とを有する。   The rubber tube manufacturing method of the present invention includes a step of inserting an uncrosslinked rubber tube into a cylindrical member, a high temperature fluid flowing into the rubber tube to expand and crosslink the rubber tube, and the cylinder A step of pressing the inner wall of the cylindrical member, and a step of removing the heating fluid from the inside of the rubber tube to contract the rubber tube and releasing from the inner wall of the cylindrical member.

本発明のゴムチューブの製造装置は、未架橋のゴムチューブの架橋を行うゴムチューブの製造装置において、上記ゴムチューブを同軸的に収容する筒状部材と、上記筒状部材の一方の端部側に設けられ、上記ゴムチューブを着脱可能、かつ、上記ゴムチューブの内部と液密・気密に連通する着脱部と、上記筒状部材の他方の端部側に設けられ、上記ゴムチューブを閉塞する閉塞部と、高温流体を供給する供給部と、上記着脱部に連通されている流路と、上記流路と上記供給部の間に設けられ、上記供給部から上記着脱部に上記高温流体を案内する流入路と、上記流入路に設けられ、上記流入路の開閉を行う流入側バルブ部と、上記流路に連通され、上記着脱部から上記高温流体を排出する流出路と、上記流出路に設けられ、上記流出路の開閉を行う流出側バルブ部とを備える。   The rubber tube manufacturing apparatus of the present invention is a rubber tube manufacturing apparatus for cross-linking an uncrosslinked rubber tube, and a cylindrical member that coaxially houses the rubber tube, and one end side of the cylindrical member The rubber tube is attachable / detachable and communicates with the inside of the rubber tube in a liquid-tight / air-tight manner, and is provided on the other end side of the cylindrical member, and closes the rubber tube. A blocking portion; a supply portion for supplying a high temperature fluid; a flow channel communicating with the attachment / detachment portion; and a passage between the flow passage and the supply portion. The high temperature fluid is supplied from the supply portion to the attachment / detachment portion. An inflow path to be guided, an inflow side valve section provided in the inflow path for opening and closing the inflow path, an outflow path communicating with the flow path and discharging the high-temperature fluid from the attachment / detachment section, and the outflow path Opening and closing the outflow passage And a outflow-side valve unit that performs.

本発明によれば、寸法や形状が安定したゴムチューブの製造が可能となる。   According to the present invention, it is possible to manufacture a rubber tube having a stable size and shape.

本発明の一実施の形態に係るゴムチューブの製造方法が適用されるゴムチューブの製造装置を模式的に示す正面図。The front view which shows typically the manufacturing apparatus of the rubber tube to which the manufacturing method of the rubber tube which concerns on one embodiment of this invention is applied. 同ゴムチューブの製造装置の要部を示す縦断面図。The longitudinal cross-sectional view which shows the principal part of the manufacturing apparatus of the rubber tube. 同ゴムチューブの製造装置を用いたゴムチューブの製造工程を模式的に示す説明図。Explanatory drawing which shows typically the manufacturing process of the rubber tube using the manufacturing apparatus of the rubber tube. 同ゴムチューブの製造装置の変形例の要部を示す縦断面図。The longitudinal cross-sectional view which shows the principal part of the modification of the manufacturing apparatus of the rubber tube.

図1は本発明の一実施の形態に係るゴムチューブの製造方法を実施するためのゴムチューブの製造装置10を模式的に示す正面図、図2はゴムチューブの製造装置10の要部を拡大して示した縦断面図である。なお、図1中Gはゴムチューブ、GaはゴムチューブGの一方の端部、GbはゴムチューブGの他方の端部をそれぞれ示している。   FIG. 1 is a front view schematically showing a rubber tube manufacturing apparatus 10 for carrying out a rubber tube manufacturing method according to an embodiment of the present invention, and FIG. 2 is an enlarged view of a main part of the rubber tube manufacturing apparatus 10. It is the longitudinal cross-sectional view shown. In FIG. 1, G represents a rubber tube, Ga represents one end of the rubber tube G, and Gb represents the other end of the rubber tube G.

ゴムチューブの製造装置10は、ゴムチューブGを同軸的に収容する筒状部材20と、筒状部材20の一方の端部21側に設けられ、ゴムチューブGの一方の端部Gaを液密・気密に蓋する閉塞部30と、筒状部材20の他方の端部22側に設けられた着脱部40と、着脱部40と連通する筒状の流路50と、加熱蒸気(高温流体)をゴムチューブGに供給するボイラ(供給部)60と、流路50とボイラ60の間に設けられ、ボイラ60から流路50へ加熱蒸気を案内する筒状の流入路70と、流路50に連通され、加熱蒸気を排出する筒状の流出路90とを備えている。   The rubber tube manufacturing apparatus 10 includes a cylindrical member 20 that coaxially accommodates the rubber tube G, and one end portion 21 side of the cylindrical member 20, and the one end portion Ga of the rubber tube G is liquid-tight. The airtightly closed closing portion 30, the attaching / detaching portion 40 provided on the other end 22 side of the tubular member 20, the tubular flow channel 50 communicating with the attaching / detaching portion 40, and heating steam (high temperature fluid) Is provided between the boiler 60 and the flow path 50 and the boiler 60, and a cylindrical inflow path 70 that guides the heated steam from the boiler 60 to the flow path 50, and the flow path 50. And a cylindrical outflow passage 90 for discharging the heating steam.

筒状部材20は樹脂等の、ゴムチューブGを容易に離型できる材料からなる離型部110と、離型部110の外周に密着して設置されている繊維部120とを備えている。離型部110は、その内周部全面にわたって連続的に形成された凹凸形状111を有している。   The cylindrical member 20 includes a release part 110 made of a material such as resin that can easily release the rubber tube G, and a fiber part 120 that is installed in close contact with the outer periphery of the release part 110. The release part 110 has a concavo-convex shape 111 continuously formed over the entire inner peripheral part thereof.

着脱部40は筒状であり、着脱部40の一方の端部41はゴムチューブGの端部Gbと着脱可能であり、ゴムチューブGの内部と液密・気密に連通される。着脱部40の他方の端部42は流路50と液密・気密に連通されている。また、着脱部40には主バルブ部45が設けられており、ゴムチューブGの内部を密閉する機能を備える。   The detachable portion 40 is cylindrical, and one end 41 of the detachable portion 40 is detachable from the end Gb of the rubber tube G, and is communicated with the inside of the rubber tube G in a liquid-tight and air-tight manner. The other end 42 of the detachable portion 40 communicates with the flow path 50 in a liquid-tight and air-tight manner. The detachable portion 40 is provided with a main valve portion 45 and has a function of sealing the inside of the rubber tube G.

流入路70には流入側バルブ部80が設けられており、流入路70の開閉をすることで加熱蒸気の流入を制御する機能を備える。   The inflow path 70 is provided with an inflow side valve portion 80 and has a function of controlling the inflow of heating steam by opening and closing the inflow path 70.

流出路90には流出側バルブ部100が設けられており、流出路90の開閉をすることで加熱蒸気の流出を制御する機能を備える。   The outflow passage 90 is provided with an outflow side valve portion 100 and has a function of controlling the outflow of the heating steam by opening and closing the outflow passage 90.

次に、ゴムチューブの製造工程について説明する。図3はゴムチューブを製造する工程を模式的に示した説明図である。なお、ゴムチューブGと筒状部材20以外の構成要素は省略している。なお、着脱部40、流入路70、流出路90は、主バルブ部45、流入側バルブ部80、流出側バルブ部100によってそれぞれ閉じられている。   Next, the manufacturing process of a rubber tube is demonstrated. FIG. 3 is an explanatory view schematically showing a process of manufacturing a rubber tube. Components other than the rubber tube G and the cylindrical member 20 are omitted. The detachable portion 40, the inflow passage 70, and the outflow passage 90 are closed by the main valve portion 45, the inflow side valve portion 80, and the outflow side valve portion 100, respectively.

最初に、未架橋のゴムチューブGを筒状部材20の内部に同軸的に収容する。図3中第1工程は未架橋のゴムチューブGが筒状部材20に収容されている状態を示している。ここで、ゴムチューブGの一方の端部Gaを閉塞部30で蓋し、ゴムチューブGの他方の端部Gbには着脱部40を取り付け、ゴムチューブGの内部と流入路70を連通する。   First, the uncrosslinked rubber tube G is accommodated coaxially inside the cylindrical member 20. The first step in FIG. 3 shows a state where the uncrosslinked rubber tube G is accommodated in the cylindrical member 20. Here, one end portion Ga of the rubber tube G is covered with the closing portion 30, and the detachable portion 40 is attached to the other end portion Gb of the rubber tube G so that the inside of the rubber tube G and the inflow path 70 are communicated.

次に、主バルブ部45及び流入側バルブ部80を開き、ボイラ60から加熱蒸気をゴムチューブG内部に流入させ、ゴムチューブGを膨張・加熱し、筒状部材20の内周部に押圧、架橋する。図3中第2工程は未架橋のゴムチューブGを架橋している様子を示している。ゴムチューブGを筒状部材20の内周部に押圧している状態で流入側バルブ部80及び主バルブ部45を閉じ、ゴムチューブGが膨張している状態を維持する。   Next, the main valve part 45 and the inflow side valve part 80 are opened, heating steam is caused to flow into the rubber tube G from the boiler 60, the rubber tube G is expanded and heated, and is pressed against the inner peripheral part of the tubular member 20. Crosslink. The 2nd process in FIG. 3 has shown a mode that the uncrosslinked rubber tube G is bridge | crosslinked. The inflow side valve portion 80 and the main valve portion 45 are closed while the rubber tube G is pressed against the inner peripheral portion of the cylindrical member 20, and the state where the rubber tube G is inflated is maintained.

所要時間経過後に、主バルブ部45及び流出側バルブ部100を開くことで、ゴムチューブGの内部から加熱蒸気を排出する。図3中第3工程はゴムチューブGの内部から加熱蒸気を排出した状態を示している。   After the required time has elapsed, the main valve portion 45 and the outflow side valve portion 100 are opened to discharge the heating steam from the inside of the rubber tube G. The third step in FIG. 3 shows a state in which the heating steam is discharged from the inside of the rubber tube G.

次に、ゴムチューブGから閉塞部30、着脱部40を取り外し、ゴムチューブGを筒状部材20内部から取り出す。図3中第4工程は筒状部材20から取り出された架橋処理済みのゴムチューブGを示している。これをもって、本実施の形態に係るゴムチューブGの製造工程が終了する。   Next, the blocking portion 30 and the detachable portion 40 are removed from the rubber tube G, and the rubber tube G is taken out from the cylindrical member 20. The fourth step in FIG. 3 shows the rubber tube G that has been subjected to the crosslinking treatment and has been taken out from the cylindrical member 20. With this, the manufacturing process of the rubber tube G according to the present embodiment is completed.

本実施の形態に係るゴムチューブの製造装置10によれば、ゴムチューブGを膨張・加熱し、筒状部材20の内周部にゴムチューブGを押圧することで、ゴムチューブGの形状を固定した状態で架橋をすることができ、架橋後のゴムチューブGの寸法や形状を安定させることが可能となる。また、筒状部材20の離型部110に樹脂等の、ゴムチューブGを容易に離型可能な材料を用いることにより、架橋後のゴムチューブGの筒状部材20からの取り出しを容易にすることができる。また、離型部110を繊維部120で覆うことで、ゴムチューブGの膨張による筒状部材20の変形を抑制することができ、架橋後のゴムチューブGの寸法や形状をさらに安定させることができる。   According to the rubber tube manufacturing apparatus 10 according to the present embodiment, the rubber tube G is expanded and heated, and the shape of the rubber tube G is fixed by pressing the rubber tube G against the inner peripheral portion of the cylindrical member 20. Cross-linking can be performed in a state in which the rubber tube G is cross-linked, and the size and shape of the rubber tube G after cross-linking can be stabilized. Further, by using a material such as resin that can easily release the rubber tube G for the release part 110 of the cylindrical member 20, the rubber tube G after crosslinking can be easily taken out from the cylindrical member 20. be able to. Moreover, by covering the mold release part 110 with the fiber part 120, the deformation of the cylindrical member 20 due to the expansion of the rubber tube G can be suppressed, and the size and shape of the rubber tube G after crosslinking can be further stabilized. it can.

上述したように、本発明によれば、ゴムチューブを筒状部材に収容した状態で、ゴムチューブ内部に高温流体を流入、架橋することで、形状や寸法の安定したゴムチューブを製造することが可能となる。   As described above, according to the present invention, a rubber tube having a stable shape and dimensions can be manufactured by injecting and bridging a high-temperature fluid into the rubber tube while the rubber tube is accommodated in the cylindrical member. It becomes possible.

図4は、上述したゴムチューブの製造装置10の変形例の、筒状部材20Aを示す縦断面図である。なお、図4において、図2と同一機能部分には同一記号を付し、詳細な説明は省略する。   FIG. 4 is a longitudinal sectional view showing a cylindrical member 20A of a modification of the rubber tube manufacturing apparatus 10 described above. 4, the same functional parts as those in FIG. 2 are denoted by the same reference numerals, and detailed description thereof is omitted.

筒状部材20Aは樹脂等の、ゴムチューブGを容易に離型できる材料からなる離型部110Aと、繊維部120とを備えている。離型部110Aは、その内周部全面に、間欠的に形成された(不連続の)凹凸形状111Aと、軸方向に沿って形成された直線模様(模様)112Aとを有している。   The cylindrical member 20 </ b> A includes a release part 110 </ b> A made of a material that can easily release the rubber tube G, such as resin, and a fiber part 120. 110 A of mold release parts have the uneven | corrugated shape 111A intermittently formed in the inner peripheral part whole surface, and the linear pattern (pattern) 112A formed along the axial direction.

本変形例によれば、上述した一実施の形態に係るゴムチューブの製造装置10と同様の効果を得ることが可能となる。   According to this modification, it is possible to obtain the same effects as those of the rubber tube manufacturing apparatus 10 according to the embodiment described above.

上述したように、本発明によれば、ゴムチューブを筒状部材に収容した状態で、ゴムチューブ内部に高温流体を流入、架橋することで、形状や寸法の安定したゴムチューブを製造することが可能となる。   As described above, according to the present invention, a rubber tube having a stable shape and dimensions can be manufactured by injecting and bridging a high-temperature fluid into the rubber tube while the rubber tube is accommodated in the cylindrical member. It becomes possible.

なお、本発明は前記実施の形態に限定されるものではない。例えば、上述した例では、筒状部材20は離型部110と繊維部120とで構成されているが、これらを金属材料等で形成した場合でも同様に適用できる。また、上述した例では、ゴムチューブの一方の端部から加熱蒸気の流入、流出をしているが、流入と流出を別々の端部からする場合にも適用できる。また、内周面に形成される模様は、上述した直線状の模様に限られず、曲線や文字であっても、本発明の効果を得ることが可能である。   The present invention is not limited to the above embodiment. For example, in the above-described example, the cylindrical member 20 includes the release part 110 and the fiber part 120. However, the present invention can be similarly applied even when these are formed of a metal material or the like. In the above-described example, the heating steam flows in and out from one end of the rubber tube. However, the present invention can be applied to the case where the inflow and outflow are performed from separate ends. The pattern formed on the inner peripheral surface is not limited to the linear pattern described above, and even if it is a curve or a character, the effect of the present invention can be obtained.

この他、本発明の要旨を逸脱しない範囲で種々変形実施可能であるのは勿論である。   Of course, various modifications can be made without departing from the scope of the present invention.

10…ゴムチューブの製造装置、20,20A…筒状部材、30…閉塞部、40…着脱部、45…主バルブ部、50…流路、60…ボイラ(供給部)、70…流入路、80…流入側バルブ部、90…流出部、100…流出側バルブ部、110,110A…離型部、120…繊維部、G…ゴムチューブ。   DESCRIPTION OF SYMBOLS 10 ... Rubber tube manufacturing apparatus, 20, 20A ... Cylindrical member, 30 ... Closure part, 40 ... Detachment part, 45 ... Main valve part, 50 ... Flow path, 60 ... Boiler (supply part), 70 ... Inflow path, 80 ... Inflow side valve part, 90 ... Outflow part, 100 ... Outflow side valve part, 110, 110A ... Mold release part, 120 ... Fiber part, G ... Rubber tube.

Claims (4)

未架橋のゴムチューブを筒状部材の内部に挿入する工程と、
上記ゴムチューブの内部に高温流体を流入させて上記ゴムチューブを膨張かつ架橋させ、上記筒状部材の内壁に押圧させる工程と、
上記ゴムチューブの内部から上記高温流体を除去して上記ゴムチューブを収縮させ、上記筒状部材の内壁から離型させる工程とを有するゴムチューブの製造方法。
Inserting an uncrosslinked rubber tube into the inside of the cylindrical member;
Injecting a high temperature fluid into the rubber tube to expand and bridge the rubber tube, and pressing the inner wall of the cylindrical member;
Removing the high-temperature fluid from the inside of the rubber tube to shrink the rubber tube and releasing it from the inner wall of the cylindrical member.
上記筒状部材は樹脂で形成され、上記筒状部材の外周の少なくとも一部を密着した状態で覆う伸縮性を有する繊維部材を有することを特徴とする請求項1に記載のゴムチューブの製造方法。   2. The method of manufacturing a rubber tube according to claim 1, wherein the cylindrical member is formed of a resin and has a stretchable fiber member that covers at least a part of the outer periphery of the cylindrical member in close contact. . 上記筒状部材は、内周の少なくとも一部に凹凸形状、又は模様を有することを特徴とする請求項1または2に記載のゴムチューブの製造方法。   The method for manufacturing a rubber tube according to claim 1, wherein the cylindrical member has a concavo-convex shape or a pattern on at least a part of an inner periphery thereof. 未架橋のゴムチューブの架橋を行うゴムチューブの製造装置において、
上記ゴムチューブを同軸的に収容する筒状部材と、
上記筒状部材の一方の端部側に設けられ、上記ゴムチューブを着脱可能、かつ、上記ゴムチューブの内部と液密・気密に連通する着脱部と、
上記筒状部材の他方の端部側に設けられ、上記ゴムチューブを閉塞する閉塞部と、
高温流体を供給する供給部と、
上記着脱部に連通されている流路と、
上記流路と上記供給部の間に設けられ、上記供給部から上記着脱部に上記高温流体を案内する流入路と、
上記流入路に設けられ、上記流入路の開閉を行う流入側バルブ部と、
上記流路に連通され、上記着脱部から上記高温流体を排出する流出路と、
上記流出路に設けられ、上記流出路の開閉を行う流出側バルブ部とを備えることを特徴とするゴムチューブの製造装置。
In a rubber tube manufacturing apparatus for crosslinking an uncrosslinked rubber tube,
A cylindrical member that coaxially accommodates the rubber tube;
An attachment / detachment portion provided on one end side of the cylindrical member, detachable from the rubber tube, and in fluid-tight and air-tight communication with the inside of the rubber tube;
A closing portion that is provided on the other end side of the cylindrical member and closes the rubber tube;
A supply section for supplying a high-temperature fluid;
A flow path communicating with the detachable portion;
An inflow path that is provided between the flow path and the supply section and guides the high-temperature fluid from the supply section to the detachable section;
An inflow side valve portion that is provided in the inflow path and opens and closes the inflow path;
An outflow path communicating with the flow path and discharging the high-temperature fluid from the attachment / detachment portion;
An apparatus for manufacturing a rubber tube, comprising: an outflow side valve portion that is provided in the outflow path and opens and closes the outflow path.
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JPS50151279A (en) * 1974-05-22 1975-12-04
JPS5571542A (en) * 1978-11-25 1980-05-29 Kinugawa Rubber Ind Co Ltd Method of manufacturing tubular or rod-like molded rubber product
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JPS62275712A (en) * 1985-10-23 1987-11-30 Toyoda Gosei Co Ltd Method for press-curing reinforced rubber hose
JPH01320112A (en) * 1988-06-22 1989-12-26 Nissei Denki Kk Vulcanization method of electrically insulating rubber tube
JPH04164624A (en) * 1990-10-29 1992-06-10 Honda Motor Co Ltd Manufacture of rubber tube
JPH07117106A (en) * 1993-10-26 1995-05-09 Toyoda Gosei Co Ltd Method for blow-forming rubber material
JPH07251421A (en) * 1994-01-28 1995-10-03 Sumitomo Rubber Ind Ltd Manufacture of re-treaded tire and vulcanizing mold used in manufacture
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