JP2014098128A5 - - Google Patents

Download PDF

Info

Publication number
JP2014098128A5
JP2014098128A5 JP2012251820A JP2012251820A JP2014098128A5 JP 2014098128 A5 JP2014098128 A5 JP 2014098128A5 JP 2012251820 A JP2012251820 A JP 2012251820A JP 2012251820 A JP2012251820 A JP 2012251820A JP 2014098128 A5 JP2014098128 A5 JP 2014098128A5
Authority
JP
Japan
Prior art keywords
meth
acrylate
pressure
sensitive adhesive
adhesive composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2012251820A
Other languages
Japanese (ja)
Other versions
JP2014098128A (en
JP6221091B2 (en
Filing date
Publication date
Application filed filed Critical
Priority claimed from JP2012251820A external-priority patent/JP6221091B2/en
Priority to JP2012251820A priority Critical patent/JP6221091B2/en
Priority to KR20130134208A priority patent/KR101511088B1/en
Priority to TW105136369A priority patent/TWI640592B/en
Priority to TW104118878A priority patent/TWI630268B/en
Priority to CN201310556382.1A priority patent/CN103820059A/en
Priority to TW102140934A priority patent/TWI491719B/en
Priority to CN201710881073.XA priority patent/CN108300365B/en
Publication of JP2014098128A publication Critical patent/JP2014098128A/en
Publication of JP2014098128A5 publication Critical patent/JP2014098128A5/ja
Publication of JP6221091B2 publication Critical patent/JP6221091B2/en
Application granted granted Critical
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Description

上記の課題を解決するため、本発明は、アクリル系ポリマーと、帯電防止剤を含有する粘着剤組成物であって、前記アクリル系ポリマーが、炭素数が4〜10のアルキル基を有するアルキル(メタ)アクリレートと、ヒドロキシル基含有の共重合性モノマーとを共重合させた共重合体であり、前記アクリル系ポリマーの100重量部に対して、前記アルキル(メタ)アクリレートを85〜99.5重量部と、前記ヒドロキシル基含有の共重合性モノマーを0.5〜15重量部と、架橋剤を0.1〜5重量部と、HLB値が7〜12であるポリエーテル変性シロキサン化合物を0.01〜0.5重量部と、を含有してなり、前記帯電防止剤が融点30〜50℃のイオン性化合物であることを特徴とする粘着剤組成物を提供する。 To solve the above problems, the present invention is an alkyl having an acrylic polymer, a PSA composition containing the antistatic agent, the acrylic polymer is an alkyl group having a carbon number of 4 to 10 (meth) acrylate, a copolymer obtained by copolymerizing a copolymerizable monomer containing hydroxyl groups, relative to 100 parts by weight of the acrylic polymer, the alkyl (meth) acrylate 85 to 99.5 and parts by weight and the 0.5 to 15 parts by weight copolymerizable monomers containing hydroxyl groups, and a crosslinking agent 0.1-5 parts by weight, the polyether-modified siloxane compound HLB value of 7-12 0 0.01 to 0.5 part by weight, and the antistatic agent is an ionic compound having a melting point of 30 to 50 ° C.

表3に、評価結果を示す。なお、表面抵抗率は、「m×10 +n 」を「mE+n」とする方式(ただし、mは任意の実数値、nは正の整数)により表記した。 Table 3 shows the evaluation results. The surface resistivity was expressed by a method in which “m × 10 + n ” is “mE + n” (where m is an arbitrary real value and n is a positive integer).

Claims (6)

アクリル系ポリマーと、帯電防止剤を含有する粘着剤組成物であって、前記アクリル系ポリマーが、炭素数が4〜10のアルキル基を有するアルキル(メタ)アクリレートと、ヒドロキシル基含有の共重合性モノマーとを共重合させた共重合体であり、前記アクリル系ポリマーの100重量部に対して、前記アルキル(メタ)アクリレートを85〜99.5重量部と、前記ヒドロキシル基含有の共重合性モノマーを0.5〜15重量部と、架橋剤を0.1〜5重量部と、HLB値が7〜12であるポリエーテル変性シロキサン化合物を0.01〜0.5重量部と、を含有してなり、前記帯電防止剤が融点30〜50℃のイオン性化合物であることを特徴とする粘着剤組成物。 A pressure-sensitive adhesive composition containing an acrylic polymer, an antistatic agent, the acrylic polymer is an alkyl (meth) acrylate the number of carbon atoms having an alkyl group of 4-10, copolymerization of a hydroxyl group-containing a copolymer obtained by copolymerizing a sexual monomer, per 100 parts by weight of the acrylic polymer, and said alkyl (meth) acrylate 85 to 99.5 parts by weight, copolymerizability with the hydroxyl group-containing Contains 0.5 to 15 parts by weight of monomer, 0.1 to 5 parts by weight of a crosslinking agent, and 0.01 to 0.5 part by weight of a polyether-modified siloxane compound having an HLB value of 7 to 12. The pressure-sensitive adhesive composition is characterized in that the antistatic agent is an ionic compound having a melting point of 30 to 50 ° C. 前記アルキル(メタ)アクリレートが、ブチル(メタ)アクリレート、イソブチル(メタ)アクリレート、ペンチル(メタ)アクリレート、ヘキシル(メタ)アクリレート、ヘプチル(メタ)アクリレート、オクチル(メタ)アクリレート、イソオクチル(メタ)アクリレート、2−エチルヘキシル(メタ)アクリレート、ノニル(メタ)アクリレート、イソノニル(メタ)アクリレート、デシル(メタ)アクリレートからなる化合物群の中から選択された1種以上であることを特徴とする請求項1に記載の粘着剤組成物。 The alkyl (meth) acrylate is butyl (meth) acrylate, isobutyl (meth) acrylate, pentyl (meth) acrylate, hexyl (meth) acrylate, heptyl (meth) acrylate, octyl (meth) acrylate, isooctyl (meth) acrylate, It is 1 or more types selected from the compound group which consists of 2-ethylhexyl (meth) acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, and decyl (meth) acrylate, The claim 1 characterized by the above-mentioned. Adhesive composition. 前記ヒドロキシル基含有の共重合性モノマーが、8−ヒドロキシオクチル(メタ)アクリレート、6−ヒドロキシヘキシル(メタ)アクリレート、4−ヒドロキシブチル(メタ)アクリレート、2−ヒドロキシエチル(メタ)アクリレート、N−ヒドロキシ(メタ)アクリルアミド、N−ヒドロキシメチル(メタ)アクリルアミド、N−ヒドロキシエチル(メタ)アクリルアミドからなる化合物群の中から選択された、少なくとも一種以上であることを特徴とする請求項1又は2に記載の粘着剤組成物。   The hydroxyl group-containing copolymerizable monomer is 8-hydroxyoctyl (meth) acrylate, 6-hydroxyhexyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, N-hydroxy. The at least 1 type selected from the compound group which consists of (meth) acrylamide, N-hydroxymethyl (meth) acrylamide, and N-hydroxyethyl (meth) acrylamide, The claim 1 or 2 characterized by the above-mentioned. Adhesive composition. 前記架橋剤が3官能以上のイソシアネート化合物であることを特徴とする請求項1〜3のいずれかに記載の粘着剤組成物。   The pressure-sensitive adhesive composition according to claim 1, wherein the crosslinking agent is a trifunctional or higher functional isocyanate compound. 請求項1〜4のいずれかに記載の粘着剤組成物を架橋してなる粘着剤層を、樹脂フィルムの片面または両面に形成してなることを特徴とする粘着フィルム。   A pressure-sensitive adhesive film formed by forming a pressure-sensitive adhesive layer obtained by crosslinking the pressure-sensitive adhesive composition according to claim 1 on one side or both sides of a resin film. 請求項1〜4のいずれかに記載の粘着剤組成物を架橋してなる粘着剤層を、樹脂フィルムの片面に形成してなることを特徴とする表面保護フィルム。   A surface protective film comprising a pressure-sensitive adhesive layer formed by crosslinking the pressure-sensitive adhesive composition according to claim 1 on one side of a resin film.
JP2012251820A 2012-11-16 2012-11-16 Surface protection film Active JP6221091B2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2012251820A JP6221091B2 (en) 2012-11-16 2012-11-16 Surface protection film
KR20130134208A KR101511088B1 (en) 2012-11-16 2013-11-06 Adhesive composition, adhesive film, and surface-protective adhesive film
CN201310556382.1A CN103820059A (en) 2012-11-16 2013-11-11 Adhesive composition, adhesive film, and surface-protective film
TW104118878A TWI630268B (en) 2012-11-16 2013-11-11 Adhesive composition, adhesive film, and surface-protective adhesive film
TW105136369A TWI640592B (en) 2012-11-16 2013-11-11 Adhesive composition, adhesive film, and surface-protective adhesive film
TW102140934A TWI491719B (en) 2012-11-16 2013-11-11 Adhesive composition, adhesive film, and surface-protective adhesive film
CN201710881073.XA CN108300365B (en) 2012-11-16 2013-11-11 Adhesive composition, adhesive film and surface protective film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012251820A JP6221091B2 (en) 2012-11-16 2012-11-16 Surface protection film

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2016026032A Division JP6131351B2 (en) 2016-02-15 2016-02-15 Adhesive layer, adhesive film and surface protective film

Publications (3)

Publication Number Publication Date
JP2014098128A JP2014098128A (en) 2014-05-29
JP2014098128A5 true JP2014098128A5 (en) 2015-06-18
JP6221091B2 JP6221091B2 (en) 2017-11-01

Family

ID=50755362

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2012251820A Active JP6221091B2 (en) 2012-11-16 2012-11-16 Surface protection film

Country Status (4)

Country Link
JP (1) JP6221091B2 (en)
KR (1) KR101511088B1 (en)
CN (2) CN108300365B (en)
TW (3) TWI630268B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2891693B1 (en) 2013-06-19 2021-09-29 LG Chem, Ltd. Pressure-sensitive adhesive composition
WO2014204253A1 (en) 2013-06-19 2014-12-24 주식회사 엘지화학 Adhesive composition
JP6198275B2 (en) * 2014-08-29 2017-09-20 藤森工業株式会社 Antistatic surface protection film
CN107107543B (en) * 2014-10-30 2021-07-20 Agc株式会社 Substrate with antifouling film
WO2017145545A1 (en) * 2016-02-25 2017-08-31 株式会社寺岡製作所 Adhesive agent composition and adhesive tape
JP6952497B2 (en) * 2017-05-31 2021-10-20 日東電工株式会社 Adhesive composition, surface protective sheet, and optical member
JP6529203B2 (en) * 2018-05-10 2019-06-12 藤森工業株式会社 Release film for antistatic surface protection film
WO2021199359A1 (en) * 2020-03-31 2021-10-07 株式会社寺岡製作所 Crosslinking-type adhesive agent composition and adhesive tape

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI328029B (en) * 2004-10-21 2010-08-01 Lg Chemical Ltd Acrylic pressure sensitive adhesive with good antistatic property
TWI340161B (en) * 2005-01-19 2011-04-11 Lg Chemical Ltd Acrylic pressure-sensitive adhesive composition with good re-workability,adhesive sheet,and method of preparing the sheet
CN101243153B (en) * 2005-09-05 2010-10-06 日东电工株式会社 Adhesive composition, adhesive sheet and surface-protecting film
JP5091434B2 (en) * 2006-07-04 2012-12-05 日本カーバイド工業株式会社 Pressure-sensitive adhesive composition and optical member surface protective film
JP2009091406A (en) * 2007-10-04 2009-04-30 Nippon Carbide Ind Co Inc Pressure-sensitive adhesive composition and surface protection film
JP4963485B2 (en) 2008-04-07 2012-06-27 綜研化学株式会社 Adhesive composition for polarizing plate and method for producing the same
JP5311342B2 (en) * 2009-02-09 2013-10-09 綜研化学株式会社 Antistatic pressure-sensitive adhesive composition and antistatic film
JP5623020B2 (en) * 2009-02-27 2014-11-12 日東電工株式会社 Adhesive composition, adhesive layer, and adhesive sheet
JP2011168751A (en) * 2010-02-22 2011-09-01 Nitto Denko Corp Surface protective film
KR101177563B1 (en) * 2010-05-03 2012-08-27 (주)신명에이치엠에스 cutting device for welding bead of T-profile using a steel curtainwall
KR101279394B1 (en) * 2010-06-01 2013-07-04 동우 화인켐 주식회사 Adhesive composition and polarizing plate comprising the same
JP5723618B2 (en) * 2011-02-04 2015-05-27 日東電工株式会社 Adhesive sheet and surface protective film
JP5683370B2 (en) * 2011-04-22 2015-03-11 藤森工業株式会社 Adhesive composition and surface protective film
JP5683369B2 (en) * 2011-04-22 2015-03-11 藤森工業株式会社 Adhesive composition and surface protective film
CN102352206A (en) * 2011-09-06 2012-02-15 烟台德邦电子材料有限公司 Pressure-sensitive adhesive for polaroid
JP5906064B2 (en) * 2011-11-21 2016-04-20 藤森工業株式会社 Adhesive composition and surface protective film
JP5882774B2 (en) * 2012-02-13 2016-03-09 藤森工業株式会社 Adhesive composition, adhesive film and surface protective film
JP2013163783A (en) * 2012-02-13 2013-08-22 Fujimori Kogyo Co Ltd Adhesive composition, adhesive film and surface-protecting film
JP5879160B2 (en) * 2012-03-06 2016-03-08 藤森工業株式会社 Adhesive composition and surface protective film
JP5909137B2 (en) * 2012-04-05 2016-04-26 藤森工業株式会社 Adhesive composition and surface protective film
JP5879208B2 (en) * 2012-06-20 2016-03-08 藤森工業株式会社 Adhesive composition and surface protective film
JP6268407B2 (en) * 2012-07-27 2018-01-31 藤森工業株式会社 Adhesive composition and surface protective film

Similar Documents

Publication Publication Date Title
JP2014098128A5 (en)
JP2014025006A5 (en)
JP2013185007A5 (en)
JP2014001331A5 (en)
JP2013107977A5 (en)
JP2013163782A5 (en)
JP2013216739A5 (en)
JP2016536424A5 (en)
JP5000126B2 (en) Release agent composition and release material
JP2013107978A5 (en)
JP2015507040A5 (en)
JP2013185008A5 (en)
JP2010215923A5 (en)
JP2014001332A5 (en)
JP2014218672A5 (en)
JP2014025007A5 (en)
JP2010254979A5 (en)
MY160559A (en) Adhesive and adhesive sheet
EP2033998A3 (en) Pressure sensitive adhesive composition, product using the same, and display using the product
JP2012153772A5 (en)
EP1829947A3 (en) Pressure-sensitive adhesive sheet
JP2016094616A5 (en)
TW201612273A (en) Adhesive composition, adhesive film, and surface-protective adhesive film
MY164532A (en) Adhesive sheet
JP2009046535A5 (en)