JP2014074878A - Developing device, image forming apparatus, and process unit - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a developing device capable of regulating developer with a regulating member in a more suitable manner and suppressing an increase in temperature of a contact part between the regulating member and a developer carrier, an image forming apparatus, and a process unit.SOLUTION: A developing device 4 includes a developer carrier such as a developing roller 42 that carries developer such as toner on the surface thereof where concave parts 42b and convex parts 42a are formed, and conveys the developer to a developing position arranged opposite to a latent image carrier 2 such as a photoreceptor; and a regulating member such as a doctor blade 45 that comes into contact with the developer carrier to regulate the amount of the developer conveyed to the developing position. A contact part of the regulating member with the developer carrier is covered with a material having the coefficient of dynamic friction with the developer carrier lower than that of the regulating member.

Description

  The present invention relates to a developing device, an image forming apparatus, and a process cartridge.

  In Patent Documents 1 and 2, irregularities having a regular pattern in which the height of the convex portion and the depth of the concave portion are constant on the surface of the developing roller that conveys the developer to the developing region that is the portion facing the photoconductor. A developing device is described. In this developing device, since the depth of the concave portion is constant and the formation pattern is regular, the regulating member is brought into contact with the convex portion, and the developer present on the convex portion is worn by the regulating member, thereby developing the concave portion. The developer on the roller surface is only the developer contained in the recess, and the developer carrying amount is stabilized. In such a developing device, a desired amount of developer can be transported to the developing region by setting the capacity of the recess to a capacity for carrying the desired amount of developer.

  In the developing devices described in Patent Documents 1 and 2, only the toner carried on the surface of the developing roller that is present in the recess passes through the position facing the regulating member, and when passing, Since no large pressure is applied, the occurrence of filming can be suppressed.

  However, in the developing devices described in Patent Documents 1 and 2, the temperature of the regulating member is increased due to friction between the developers in the layer thickness regulating portion, friction between the developer and the regulating member, friction between the regulating member and the developing roller, There is a possibility that the developer may adhere to the regulating member or adhere to the surface of the developing roller due to retention of the developer.

  For example, it is conceivable to reduce the friction between the developer and the regulating member and the friction between the regulating member and the developing roller by configuring the regulating member with a highly slidable resin such as a fluororesin. However, when the regulating member is made of fluororesin or the like, the regulating member becomes flexible. As described above, it is necessary to press the restricting member against the developing roller with a certain degree of strength in order to allow the restricting member to pass only what is present in the recess of the developing roller. However, if the restricting member is made of fluororesin or the like and the rigidity of the restricting member decreases, the restricting member cannot be strongly pressed against the developing roller, and the developer may not be well regulated by the restricting member. is there. Further, by increasing the thickness of the restricting member, the rigidity of the restricting member can be ensured, but the material cost and the like increase, leading to an increase in the cost of the apparatus.

  SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and an object of the present invention is to develop a developer that can be well regulated by a regulating member and that can suppress sticking of the developer to the regulating member or the developer carrying member. An apparatus, an image forming apparatus, and a process unit are provided.

  In order to achieve the above-mentioned object, the invention according to claim 1 is a developer for carrying a developer to a development position for developing a latent image by carrying the developer on its surface on which concave portions and convex portions are formed. In a developing device having a carrier and a regulating member that abuts the surface of the developer carrier and regulates the amount of developer conveyed to the development position, the developer carrying member of the regulating member The contact portion and / or the portion of the restricting member that contacts the developer is covered with a material having a higher slidability than the restricting member.

According to the present invention, the contact portion of the restricting member with the developer carrying member and / or the portion of the restricting member that contacts the developer are coated with a material having a higher slidability than the restricting member. And / or the frictional force between the regulating member and the developer carrying member can be reduced as compared with the regulating member not covered with the resin having high slidability. Thereby, the friction between the developer and the regulating member and the friction between the regulating member and the developer carrying member can be reduced. As a result, it is possible to prevent the developer from adhering to the regulating member or adhering to the surface of the developer carrying member due to frictional heat, developer stagnation, or the like.
Further, the restricting member can be made of a highly rigid member such as metal, and the restricting member can be strongly pressed against the developing roller. As a result, the developer can be well regulated by the regulating member.

FIG. 2 is a schematic configuration diagram of a developing device according to the first embodiment. 1 is a schematic configuration diagram of a copier according to a first embodiment. FIG. 3 is a first perspective explanatory view of the developing device according to the first embodiment. FIG. 3 is a second perspective explanatory view of the developing device according to the first embodiment. FIG. 3 is an explanatory cross-sectional view of the developing device according to the first embodiment. FIG. 3 is a perspective view illustrating a part of the developing device according to the first embodiment in a cross-sectional view. FIG. 3 is an enlarged perspective view of the vicinity of one end of the developing device, with the lower case not shown. FIG. 8 is an enlarged perspective view of the developing device from which the developing roller is omitted from the state of FIG. 7. FIG. 4 is an enlarged perspective view of the vicinity of the other end of the developing device, with the lower case not shown. FIG. 10 is an enlarged perspective view of the developing device from which the developing roller is omitted from the state of FIG. 9. FIG. The side view of a developing roller. Explanatory drawing of the surface shape of the developing roller, (a) is a schematic diagram of the entire developing roller, (b) is an enlarged view of a part of the surface of the developing roller, (c) is L11 or L13 in (b) Sectional drawing of the surface layer shown by (d), Sectional drawing of the surface layer shown by L12 or L14 in (b). The perspective explanatory view of a supply roller. The side view of a supply roller. The perspective explanatory drawing of a doctor blade. The side view of a doctor blade. FIG. Side view of paddle. FIG. 3 is an enlarged explanatory view of a doctor portion of a developing device in a state where a doctor blade is placed on the stomach. FIG. 3 is an enlarged explanatory view of a doctor unit of a developing device in a state where a doctor blade is in a tip contact state. The expanded sectional view of the surface of the developing roller whose angle which a convex part and a recessed part comprise is less than 90 [degree]. FIG. 4 is an enlarged cross-sectional view of the surface of a developing roller in which a part of an angle formed by a convex portion and a concave portion is less than 90 [°]. The expanded sectional view of the surface of the developing roller whose angle which a convex part and a recessed part make is 90 [°] or more. The expanded sectional view of the surface of the developing roller whose angle which a convex part and a recessed part make is 90 degrees. The expanded sectional view of the surface of the developing roller where a part of the angle formed by the convex part and the concave part is an obtuse angle (bumping state). FIG. 3 is an enlarged cross-sectional view of the surface of the developing roller in which a part of an angle formed by a convex part and a concave part is an obtuse angle (tip contact state). FIG. 3 is an enlarged view of the surface of the developing roller in which two sets of parallel lines on the top surface of the convex portion are parallel to the surface movement direction. Explanatory view of the contact state of the doctor blade with the developing roller, (a) is an explanatory view of the state where the blade is brought into contact with the tangential direction of the developing roller, (b) is a normal direction of the blade folder from the state of (a) Explanatory drawing of the state moved to (c), (c) is explanatory drawing of the state which moved the blade folder in the tangential direction from the state of (b). The graph which shows the experimental result of Experiment 1. The enlarged explanatory view of the state of edge contact. The graph which shows the experimental result of Experiment 2. Graph comparing the amount of doctor blade shaving due to differences in materials. 6 is a flowchart of a notification system that notifies replacement of a developing device. FIG. 3 is an enlarged explanatory view of a doctor blade and a developing roller of a developing device whose replacement time is approaching. FIG. 3 is a diagram illustrating a doctor blade and a developing roller according to the first embodiment. The figure which shows the contact part of the doctor blade of FIG. 36, and a developing roller. FIG. 4 is a schematic cross-sectional view of a main part of a printer according to a second embodiment. FIG. 3 is an enlarged sectional view of one of four process cartridges provided in the printer. FIG. 3 is an enlarged cross-sectional view in the vicinity of an end portion in the axial direction of the process cartridge. Sectional drawing along the axial direction of the image development apparatus with which the process cartridge is provided. The figure which shows the modification of a doctor blade. A graph showing the number of images until a defect (white streak) appears in an image when images are continuously output. The graph which represented the result of FIG. 43 by the relationship between dynamic friction coefficient (micro | micron | mu) and the number of output sheets. The figure which shows the modification of a developing device.

Embodiment 1
Hereinafter, a first embodiment (hereinafter referred to as Embodiment 1) of the present invention in which the present invention is applied to a copying machine (hereinafter referred to as a copying machine 500) as an image forming apparatus will be described.
FIG. 2 is a schematic configuration diagram of the copying machine 500 according to the first embodiment. The copying machine 500 includes a copying machine main body (hereinafter referred to as a printer unit 100), a paper feed table (hereinafter referred to as a paper feed unit 200), and a scanner (hereinafter referred to as a scanner unit 300) mounted on the printer unit 100.

The printer unit 100 includes a process cartridge 1 (Y, M, C, K) as four process units, an intermediate transfer member that is stretched by a plurality of stretching rollers and moves in the direction of arrow A in FIG. A transfer belt 7 is provided. Further, an exposure device 6 as an exposure unit, a fixing device 12 as a fixing unit, and the like are provided.
The suffixes Y, M, C, and K attached to the four process cartridges 1 indicate the specifications for yellow, magenta, cyan, and black. The four process cartridges 1 (Y, M, C, and K) have substantially the same configuration except that the colors of the toners to be used are different. Therefore, the subscripts K, Y, M, and C are omitted below. I will explain.

  The process cartridge 1 is a unit that integrally supports a photosensitive member 2 as a latent image carrier, a charging member 3 as a charging unit, a developing device 4 as a developing unit, and a photosensitive member cleaning device 5 as a cleaning unit. The configuration is shaped like Each process cartridge 1 can be attached to and detached from the copying machine 500 main body by releasing a stopper (not shown).

  The photoconductor 2 rotates in the clockwise direction in the figure as indicated by the arrow in the figure. The charging member 3 is a roller-shaped charging roller, is in pressure contact with the surface of the photoconductor 2, and is rotated by the rotation of the photoconductor 2. At the time of image formation, a predetermined bias is applied to the charging member 3 by a high voltage power source (not shown) to charge the surface of the photoreceptor 2. In the process cartridge 1 of the first embodiment, the roller-shaped charging member 3 that contacts the surface of the photoreceptor 2 is used as the charging unit. However, the charging unit is not limited to this, and non-contact such as corona charging. A charging method may be used.

The exposure device 6 exposes the surface of the photoconductor 2 on the surface of the photoconductor 2 based on the image information of the original image read by the scanner unit 300 or image information input from an external device such as a personal computer. An electrostatic latent image is formed. The exposure device 6 provided in the printer unit 100 uses a laser beam scanner system using a laser diode, but may have other configurations such as an exposure unit using an LED array.
The photoconductor cleaning device 5 cleans the transfer residual toner remaining on the surface of the photoconductor 2 that has passed the position facing the intermediate transfer belt 7.

  The four process cartridges 1 form toner images for the respective colors of yellow, cyan, magenta, and black on the photoreceptor 2. The four process cartridges 1 are arranged in parallel in the surface movement direction of the intermediate transfer belt 7 and transfer the toner images formed on the respective photoreceptors 2 in order to be superimposed on the intermediate transfer belt 7 in order. A visible image is formed on the belt 7.

  In FIG. 2, a primary transfer roller 8 serving as a primary transfer unit is disposed at a position facing each photoconductor 2 with the intermediate transfer belt 7 interposed therebetween. A primary transfer bias is applied to the primary transfer roller 8 by a high voltage power source (not shown) to form a primary transfer electric field with the photosensitive member 2. By forming a primary transfer electric field between the photosensitive member 2 and the primary transfer roller 8, the toner image formed on the surface of the photosensitive member 2 is transferred to the surface of the intermediate transfer belt 7. One of a plurality of stretching rollers that stretch the intermediate transfer belt 7 is rotated by a drive motor (not shown), so that the intermediate transfer belt 7 moves in the direction of arrow A in the figure. A full color image is formed on the surface of the intermediate transfer belt 7 by sequentially transferring the toner images of the respective colors on the surface of the intermediate transfer belt 7 moving on the surface.

  A secondary transfer nip is formed on the downstream side of the surface of the intermediate transfer belt 7 with respect to the position where the four process cartridges 1 face the intermediate transfer belt 7. The secondary transfer nip is formed by the secondary transfer roller 9 disposed at a position facing the secondary transfer counter roller 9a, which is one of the stretching rollers, with the intermediate transfer belt 7 interposed therebetween. A predetermined voltage is applied between the secondary transfer roller 9 and the secondary transfer counter roller 9a to form a secondary transfer electric field. A transfer sheet P, which is a transfer material fed from the sheet feeding unit 200 and conveyed in the direction of arrow C in FIG. 1, passes through the secondary transfer nip. At this time, the full-color image formed on the surface of the intermediate transfer belt 7 is transferred onto the transfer paper P by the secondary transfer electric field formed between the secondary transfer roller 9 and the secondary transfer counter roller 9a.

A fixing device 12 is disposed downstream of the secondary transfer nip in the conveyance direction of the transfer paper P. The transfer paper P that has passed through the secondary transfer nip reaches the fixing device 12, the full color image transferred onto the transfer paper P is fixed by heating and pressurization in the fixing device 12, and the transfer paper P on which the image is fixed is The data is output outside the copying machine 500.
On the other hand, the toner remaining on the surface of the intermediate transfer belt 7 without being transferred to the transfer paper P at the secondary transfer nip is collected by the transfer belt cleaning device 11.

As shown in FIG. 2, above the intermediate transfer belt 7, toner bottles 400 (Y, M, C, K) that store toners of various colors are detachably disposed on the copying machine 500 main body.
The toner stored in each color toner bottle 400 is supplied to each color developing device 4 by a toner replenishing device (not shown) corresponding to each color.

FIG. 1 is a schematic diagram illustrating a schematic configuration of the developing device 4 according to the first embodiment, and is a cross-sectional view as viewed from the back side of the paper surface in FIG. 2.
3 and 4 are perspective explanatory views of the developing device 4, and are perspective explanatory views of the developing device 4 as viewed obliquely from above in different directions.
The developing casing 41 that forms the outer shape of the developing device 4 is formed by combining an upper case 411, an intermediate case 412, and a lower case 413. The middle case 412 forms a toner accommodating portion 43, and the upper case 411 is formed with a toner replenishing port 55 that is a developer replenishing portion that communicates the toner accommodating portion 43 with the outside. The upper case 411 is provided with an inlet seal 47 that seals a gap between the developing roller 42 and the upper case 411.

  FIG. 5 is a cross-sectional explanatory view of the developing device 4 viewed from the same direction as FIG. 1, and FIG. 6 is an enlarged perspective view of a part of the developing device 4, and a part thereof is a ZX cross-sectional view. It is explanatory drawing shown.

The middle case 412 is provided with a developing roller 42, a supply roller 44, a doctor blade 45, a paddle 46, a supply screw 48, a remaining toner sensor 49, and the like.
The developing device 4 is provided with an opening 56 that communicates the inside and the outside along the longitudinal direction (Y-axis direction in the figure). A cylindrical developing roller 42 is provided in the opening 56 to carry and carry the toner from the inside to the outside (developing area α facing the photoconductor).

FIG. 7 is an enlarged perspective view of the vicinity of one end (the rear end in FIG. 2) of the developing device 4 in which the lower case 413 is not shown, and FIG. 8 shows the developing roller 42 from the state of FIG. FIG. 2 is an enlarged perspective view of the developing device 4 in which FIG.
FIG. 9 is an enlarged perspective view of the vicinity of the other end portion (the front side end portion in FIG. 2) of the developing device 4 in which the lower case 413 is omitted, and FIG. 10 shows the developing roller 42 from the state of FIG. FIG. 2 is an enlarged perspective view of the developing device 4 in which FIG.

In the developing device 4, the supply roller 44 rotates in the direction of arrow C in FIG. 1 (clockwise direction in FIG. 1) and moves on the surface, so that the toner T in the toner accommodating portion 43 faces the developing roller 42. Then, the toner is supplied to the surface of the developing roller 42. The developing roller 42 carries the supplied toner on the surface, rotates in the direction of arrow B in FIG. 1 (clockwise direction in FIG. 1), and moves on the surface, thereby removing the toner on the developing roller 42. The toner is conveyed to a portion facing the doctor blade 45 that is regulated to a predetermined amount. The doctor blade 45 is opposed to the developing roller 42 and is in a counter direction with respect to the surface movement direction of the developing roller 42 (the tip of the doctor blade 45 is upstream of the rotation direction of the developing roller 42 with respect to the base of the doctor blade 45). A). The toner regulated to a predetermined amount at the portion facing the doctor blade 45 reaches the developing area α which is the portion facing the photoreceptor 2 by the rotation of the developing roller 42.
In the supply nip β, the surface of the supply roller 44 moves from below to above, and the surface of the developing roller 42 moves from above to below. In the developing device 4 of this embodiment, the supply roller 44 and the development roller 42 are in contact with each other at the supply nip β.

In the developing area α, the toner T on the surface of the developing roller 42 is generated according to the developing electric field formed by the potential difference between the developing bias applied from the developing bias power source 142 to the developing roller 42 and the latent image on the surface of the photoreceptor 2. Moves to the surface of the photoreceptor 2. As a result, the toner adheres to the electrostatic latent image portion on the surface of the photoreceptor 2 and development is performed. The photoreceptor 2 rotates in the direction of arrow D in FIG. 1 without contact with the developing roller 42. For this reason, in the development area α, the surface movement direction of the developing roller 42 and the surface movement direction of the photosensitive member 2 are the same direction.
The developing bias power supply 142 is a voltage applying unit that applies an alternating voltage having a first voltage and a second voltage to the developing roller 42. The first voltage is a voltage for developing the latent image with the toner conveyed to the developing area α, and the second voltage is a voltage for directing the toner from the photoreceptor 2 to the developing roller 42.

As will be described in detail later, the surface of the developing roller 42 has a regular uneven shape having a substantially constant height of the convex portion 42a and a depth of the concave portion 42b over the entire outer peripheral surface.
The toner T on the surface of the developing roller 42 that does not contribute to development in the developing area α and passes through the developing area α is collected by the supply roller 44 at the upstream side in the rotation direction of the developing roller 42 in the supply nip β, and developed. The surface of the roller 42 is reset. That is, the supply roller 44 also has a role as a collection roller.

The toner T carried in the concave portions 42b regularly formed on the surface of the developing roller 42 is difficult to be collected. Then, when the toner T that has passed through the developing region α passes through the supply nip β and remains carried on the developing roller 42, the toner T adheres to the developing roller 42 and toner filming occurs. When toner filming occurs, the charge amount per unit weight of the toner T on the developing roller 42 and the toner amount per unit area of the developing roller 42 become unstable, causing density unevenness during development.
In the developing device 4 of the first embodiment, the surface movement direction of the developing roller 42 and the surface movement direction of the supply roller 44 are opposite to each other in the supply nip β where the developing roller 42 and the supply roller 44 face each other. As a result, the linear velocity difference between the surface of the developing roller 42 and the surface of the supply roller 44 at the supply nip β increases, and the recovery performance of the supply roller 44 at the supply nip β can be improved. Therefore, it is possible to suppress the toner from being held on the developing roller 42, to suppress the toner from adhering to the surface of the developing roller 42, and to cause the developer to adhere to the surface of the developer carrying member. The occurrence of density unevenness during development can be suppressed.
Further, it is desirable that the linear velocity of the developing roller 42 is high. In the developing device 4 of the first embodiment, the linear speed ratio between the developing roller 42 and the supply roller 44 is the surface moving speed of the developing roller 42: the surface moving speed of the supply roller 44 = 1: 0.85. The linear speed ratio is not limited to this value.

  As shown in FIG. 1, in the developing device 4, the supply roller 44 is disposed above the toner storage portion 43, and at least a part of the supply roller 44 is in the toner storage portion 43 in a state where the rotation of the paddle 46 is stopped. The surface is above the surface of the toner T. An area downstream of the supply nip β with respect to the surface movement direction of the supply roller 44 (hereinafter referred to as a supply nip downstream area) is above the surface of the toner T. When the toner is filled in the downstream area of the supply nip as in the configuration shown in FIG. 4 of Patent Document 1, the toner filled in the downstream area of the supply nip is replaced with new toner in the downstream area of the supply nip. To prevent it from entering. As a result, the efficiency of collecting toner from the developing roller 42 in the supply nip β may be reduced. On the other hand, in the developing device 4 of the first embodiment, as shown in FIG. 1, the downstream area of the supply nip is above the surface of the toner T. Therefore, the toner is not filled in the downstream area of the supply nip, and the toner existing in the downstream area of the supply nip does not hinder the collection of the toner from the developing roller 42 in the supply nip β. Therefore, the toner can be efficiently collected and the toner resetting property can be improved.

Next, the developing roller 42 will be described.
FIG. 11 is an explanatory perspective view of the developing roller 42, and FIG. 12 is a side view of the developing roller 42. 13 is an explanatory diagram of the surface shape of the developing roller 42, FIG. 13A is a schematic diagram of the entire developing roller 42, and FIG. 13B is shown in FIG. 13A. 3 is an enlarged view of a part of the surface of the developing roller 42. FIG. FIG. 13C is a cross-sectional view of the surface layer 42f (see FIG. 31) of the developing roller 42 at a cross section indicated by L11 or L13 in FIG. 13B, and FIG. It is sectional drawing of the surface layer 42f of the developing roller 42 in the cross section shown by L12 or L14 in b).

The developing roller 42 has a configuration in which a developing roller cylindrical portion 420 that carries toner on the surface thereof is provided on the developing roller shaft 421, and the developing roller shafts in the vicinity of both axial end portions that are axially outside the developing roller cylindrical portion 420. A spacer 422 is provided at 421.
The developing roller 42 is provided so as to be rotatable about the developing roller shaft 421, and is arranged so that the axial direction of the developing roller shaft 421 is parallel to the longitudinal direction (Y-axis direction in the drawing) of the developing device 4. Yes. Both ends of the developing roller shaft 421 in the axial direction of the developing roller 42 are rotatably attached to the side wall portion 412s of the middle case 412. A part of the surface of the developing roller 42 is exposed to the outside of the developing device 4 from the opening 56, and the developing roller 42 is moved from the lower side to the upper side to convey the toner so that the toner is conveyed in FIG. It rotates in the direction of arrow B.
Further, in the developing roller 42, the distance between the surface of the developing roller cylindrical portion 420 and the surface of the photosensitive member 2 in the developing region α is obtained by the spacers 422 provided in the vicinity of both ends in the axial direction contacting the surface of the photosensitive member 2. (Development gap) is kept constant.

The developing roller 42 includes a base material 42g and a surface layer 42f formed on the outer peripheral surface of the base material 42g (see FIG. 31). The base 42g is made of a metal material sleeve such as an aluminum-based material such as 5056 aluminum alloy or 6063 aluminum alloy, or an iron-based material such as STKM.
The developing roller 42 is provided with a concavo-convex process on the surface of the metal sleeve that is the base material 42g, and nickel plating is applied to the metal material sleeve subjected to the concavo-convex process, thereby preventing corrosion of the developing roller 42, A surface layer 42f for assisting charging of the toner is formed.

As shown in FIG. 13A, the developing roller cylindrical portion 420 of the developing roller 42 is mainly divided into two portions (a groove forming portion 420a and a non-groove forming portion 420b) based on the difference in the surface structure. .
The groove forming portion 420a is a portion including a central portion in the axial direction of the developing roller 42, and is provided with a concavo-convex process on the surface thereof in order to properly carry the toner. In the first embodiment, so-called rolling processing is used as the concavo-convex processing, and the convex portion 42a is formed so as to be surrounded by the spiral first groove L1 and the second groove L2 having different winding directions. By forming spiral grooves with different winding directions, irregularities on the mesh are formed on the surface of the developing roller 42. As the rolling process, a conventionally known processing method can be employed. The first groove L1 and the second groove L2 are each at a predetermined angle with respect to the axial direction of the developing roller 42 (in the first embodiment, both L1 and L2 are 45 [°], but the present invention is not limited to this. Not).

The first groove L1 and the second groove L2 are both periodically formed with a predetermined periodic width in the inclined direction, so that the convex portion 42a is formed with the pitch width W1 in the axial direction. In addition, the first groove L1 and the second groove L2 can have different inclination angles and periodic widths. Further, the axial length W2 of the top surface 42t of the convex portion 42a is formed to be not less than ½ of the pitch width W1.
In the developing roller 42 of Embodiment 1, the pitch width W1 in the axial direction of the convex portion 42a is 80 [μm], and the axial length W2 of the top surface 42t of the convex portion 42a is 40 [μm]. Furthermore, the recess depth W3, which is the height from the recess 42b to the top surface 42t of the protrusion 42a, is 10 [μm]. The values of the pitch width W1, the axial length W2 of the top surface 42t, and the recess depth W3 are merely examples, and are not limited to these values.

  As for the developing roller 42, it is desirable that the surface layer 42f is made of a material that normally charges the toner. Even when the low-charged toner is produced by the filming, the low-charged toner knocked out by the jumped toner T can be charged at the portions where the convex portions 42a and the concave portions 42b are not filmed. For this reason, low-charge toner can be reduced, and the image density is stabilized. In the developing roller 42 of the first embodiment, the surface layer 42f is a material that normally charges the toner by applying nickel plating.

  Further, it is desirable that the surface material of the developing roller 42 is harder than the doctor blade 45 (blade member 450). This makes it difficult for the convex portion 42a on the surface of the developing roller 42 to be scraped by the doctor blade 45, so that the volume of the concave portion 42b surrounded by the convex portion 42a and the doctor blade 45 is difficult to change, and the M / A value (on the surface of the developing roller) The amount of toner carried per unit area) is stabilized.

  The height of the convex portion 42a of the developing roller 42 is desirably larger than the weight average particle diameter of the toner T to be used. Since the toner T having an average size is accommodated in the recess 42b, the selection of the particle size is difficult to occur, and the M / A value (the amount of toner carried per unit area on the surface of the developing roller) is stabilized over time. .

Next, the supply roller 44 will be described.
FIG. 14 is an explanatory perspective view of the supply roller 44, and FIG. 15 is a side view of the supply roller 44. A cylindrical supply roller 44 is provided on the developing roller 42 side above the toner container 43 inside the developing device 4. The supply roller 44 has a configuration in which a cylindrical foam material is wound around a supply roller shaft 441 that is a shaft portion thereof, and the cylindrical foam material becomes a supply roller cylindrical portion 440 that carries toner on the surface thereof. .

The supply roller 44 is configured to be rotatable about a supply roller shaft 441, and the shaft is attached to the side wall portion 412 s of the middle case 412 so as to be rotatable. The supply roller 44 is disposed so that a part of the outer peripheral surface of the supply roller cylindrical portion 440 is in contact with the outer peripheral surface of the developing roller cylindrical portion 420 of the developing roller 42 at the supply nip β. As shown in FIGS. 1 and 5, the supply roller shaft 441 is disposed above the developing roller shaft 421.
Further, as described above, the supply roller 44 rotates so that the surface moves in the direction opposite to the surface movement direction of the developing roller 42 at the supply nip β that is a portion facing the developing roller 42. Further, as shown in FIG. 1, the developing device 4 is arranged such that the position of the supply nip β is located above the contact position of the doctor blade 45 with respect to the developing roller 42.

  The supply roller 44 uses a foam material for the supply roller cylindrical portion 440, and the surface layer in contact with the developing roller 42 is a sponge layer in which a large number of micropores are dispersed on the surface. By making the surface layer of the supply roller 44 into a sponge shape, the supply roller 44 can easily reach the bottom of the recess 42b, so that the resetability of the toner on the developing roller 42 is improved.

  Further, the amount of biting of the supply roller 44 with respect to the development roller 42 (“radius of the development roller 42” + “radius of the supply roller 44” − “distance between the axes of the development roller 42 and the supply roller 44”) It is set to be larger than the height of the convex portion 42a. By making the amount of biting of the supply roller 44 larger than the height of the convex portion 42a, the toner resetting property in the concave portion 42b can be improved. Note that if the amount of biting of the supply roller 44 with respect to the developing roller 42 is too large relative to the height of the convex portion 42a, the toner will be pushed into the concave portion 42b and cause aggregation, so the amount of biting will not be too large. It is necessary to set as follows.

The foam material used for the supply roller cylindrical portion 440 of the supply roller 44 is set to an electric resistance value of 10 ³ to 10 ¹⁴ [Ω].
A supply bias is applied to the supply roller 44 by a supply bias power supply 144 to assist the operation of pressing the toner preliminarily charged at the supply nip β against the developing roller 42. The supply roller 44 rotates in the clockwise direction in FIGS. 1 and 5 to apply and supply the developer adhered on the surface to the surface of the developing roller 42.

  The voltage applied to the supply roller 44 by the supply bias power supply 144 is opposite to the normal charging polarity of the toner (negative polarity in the toner T of the first embodiment) with respect to the alternating voltage applied to the developing roller 42. Apply polarity (positive polarity) DC voltage. At this time, the voltage applied to the supply roller 44 is opposite in polarity (plus polarity) to the normal charging polarity of the toner than the voltage applied to the developing roller 42. As a result, an electric field in the direction in which the toner T is attracted toward the supply roller 44 with respect to the development roller 42 is formed in the supply nip β, and the resetability of the toner on the development roller 42 can be improved. Note that the configuration including the supply bias power supply 144 requires a separate DC power supply, which increases the cost. Therefore, the supply bias power supply 144 may not be provided according to the specifications of the developing device 4.

Next, the doctor blade 45 will be described.
FIG. 16 is an explanatory perspective view of the doctor blade 45, and FIG. 17 is a side view of the doctor blade 45.
As shown in FIGS. 5 to 10, a doctor blade 45 is provided in the middle case 412 that is located below the developing roller 42 and inside the lower case 413.
The doctor blade 45 includes a blade member 450 that is a thin plate-like metal member that constitutes a regulating member, and a metal base portion 452 to which one end of the blade member 450 is fixed. The other end side of the blade member 450 is configured to come into contact with the developing roller 42. Further, the contact portion of the blade member 450 with the developing roller 42 is covered with a material having a lower coefficient of dynamic friction with the developing roller than the blade member 450. The contact state of the blade member 450 with respect to the developing roller 42 may be any of a tip contact state in which the tip contacts (edge contact described later) and a stomach contact state in which a surface portion on the base side from the tip contacts.

  The blade member 450 of the doctor blade 45 is fixed to the pedestal portion 452 by a plurality of rivets 451. The pedestal portion 452 is made of a metal that is thicker than the blade member 450 and functions as a substrate for fixing the blade member 450 to the main body of the developing device 4 (side surface portion of the middle case 412). A pin hole 454 is provided at the longitudinal end of the pedestal portion 452, one is a perfect circular main reference hole 454 a, and the other is an elliptical secondary reference hole having a long diameter in the direction of the main reference hole 454 a. 454b. When a pin (not shown) enters the main reference hole 454a, the position of the pedestal portion 452 with respect to the main body of the developing device 4 is determined and supported by the sub reference hole 454b. The pedestal portion 452 to which the blade member 450 is fixed is fixed to the developing device 4 main body (inner case 412) with a doctor fixing screw 455, whereby the blade member 450 is fixed to the developing device 4.

  The blade member 450 of the doctor blade 45 is made of a metal plate spring material such as SUS304CSP, SUS301CSP, or phosphor bronze, and the free end is brought into contact with the surface of the developing roller 42 with a pressing force of 10 to 100 [N / m]. Is. Further, the toner passing under the pressing force is regulated to a predetermined amount, and an electric charge is given by frictional charging. Further, a bias may be applied to the blade member 450 from a doctor bias power source 145 in order to assist frictional charging.

  Further, the blade member 450 of the doctor blade 45 is desirably conductive. Since the blade member 450 is conductive, the charge amount of the toner T having a large Q / M value (charge amount per unit volume) can be lowered, and the Q / M value of the toner T can be made uniform. it can. Thereby, sticking of the toner T to the developing roller 42 can be prevented.

  The voltage applied to the blade member 450 of the doctor bias power supply 145 is configured such that a DC voltage can be applied in a range of ± 200 [V] with respect to the alternating voltage applied to the developing roller 42. A configuration in which the voltage value can be controlled may be employed. Thereby, it is possible to suppress fluctuations in the M / A value (toner carrying amount per unit area on the surface of the developing roller) due to environmental fluctuations.

Next, the paddle 46 will be described.
18 is a perspective explanatory view of the paddle 46, and FIG. 19 is a side view of the paddle 46. As shown in FIG.
A toner accommodating portion 43 is provided in the developing device 4 as a space for accommodating toner, and a paddle 46 is rotatably attached to the developing casing 41 in the toner accommodating portion 43.

The paddle 46 includes a paddle shaft 461 that is a shaft portion thereof, and paddle blades 460 as thin blade members made of an elastic sheet material such as Mylar. The paddle shaft 461 has two flat portions facing each other, and paddle blades 460 are respectively attached to the two flat portions. The two paddle blades 460 are fixed to the flat portion of the paddle shaft 461 so as to protrude in opposite directions around the paddle shaft 461.
The base portion of the paddle blade 460 is provided with a plurality of holes arranged in parallel so as to be parallel to the axial direction of the paddle shaft 461. The paddle shaft 461 has a plurality of protrusions so as to be parallel to the axial direction thereof. The parts are arranged side by side. Then, the paddle blades 460 are fixed to the paddle shafts 461 by inserting the convex portions of the paddle shafts 461 into the holes of the paddle blades 460 and performing heat caulking.

  The paddle 46 is disposed so that the axial direction of the paddle shaft 461 is parallel to the longitudinal direction of the developing device 4 (Y-axis direction in the figure). Both ends in the axial direction of the paddle shaft 461 are rotatably attached to the side wall portion 412s of the middle case 412.

In the paddle 46, the protruding amount of the paddle blade 460 is set to such a length that the tip of the paddle blade 460 extending from the paddle shaft 461 contacts the inner wall surface of the toner containing portion 43. As shown in FIGS. 1 and 5, the bottom surface portion 43 b of the toner storage portion 43 has an arc shape along the rotation direction of the paddle 46, and the paddle blade 460 is moved by the rubbing operation accompanying the rotation of the paddle 46. 43 is prevented from being caught by the bottom surface portion 43b.
On the developing roller 42 side of the toner containing portion 43, a side wall surface portion 43s that rises vertically from the bottom surface portion 43b is formed. The side wall surface portion 43 s is horizontal in the direction toward the roller parallel to the X axis at a level that is equal to or slightly lower than the center of the paddle shaft 461, and forms a stepped portion 50.

  The distance between the side wall surface portion 43s and the paddle shaft 461 is set shorter than the distance between the bottom surface portion 43b and the paddle shaft 461. Therefore, the paddle blade 460 that has rubbed the bottom surface portion 43b hits the side wall surface portion 43s and bends more greatly. Thereafter, when the tip of the paddle wing 460 reaches the stepped portion 50, there is nothing to hold the paddle wing 460, and the tip of the paddle wing 460 is released and jumps upward. By such movement of the paddle blade 460, the toner is splashed upward, and is stirred, conveyed, and supplied.

  The step portion 50 is a horizontal plane parallel to the XY plane, and is formed to extend in the longitudinal direction of the developing device 4 (Y-axis direction in the drawing). In the developing device 4 of the first embodiment, the step portion 50 is provided in the entire region in the width direction, but may be provided in a part of the developing device 4 as long as the paddle blades 460 jump up.

  The supply screw 48 is a screw member that becomes a supply screw shaft 481 and a supply screw blade portion 480 which is a spiral blade portion fixed to the supply screw shaft 481. The supply screw shaft 481 is provided so as to be rotatable, and the axial direction of the supply screw shaft 481 is arranged so as to be parallel to the longitudinal direction of the developing device 4 (Y-axis direction in the drawing). Both axial ends of the supply screw shaft 481 are rotatably attached to the side wall portion 412s of the middle case 412.

  The end of the supply screw 48 in the axial direction is positioned below a toner supply port 55 formed at the end of the developing device 4 in the longitudinal direction. Then, when the supply screw 48 is rotated, the spiral supply screw blade 480 conveys the toner replenished from the toner replenishing port 55 toward the central portion of the developing device 4 in the longitudinal direction.

  A sheet member such as Mylar is attached as an inlet seal 47 along the longitudinal direction to the edge portion forming the opening 56 of the upper case 411. The inlet seal 47 is a substantially rectangular sheet, one end of which is affixed to the edge portion of the upper case 411, and the other end is a free end. The free end side of the inlet seal 47 protrudes toward the inside of the developing device 4, and is further provided so as to contact the developing roller 42. The inlet seal 47 is fixed to the upper case 411 on the upstream side in the rotational direction of the developing roller 42, and the downstream side in the rotational direction of the developing roller 42 is a free end, and the surface portion of the inlet seal 47 contacts the developing roller 42. It is arranged to do. Further, the inner side of the developing device 4 of the upper case 411 is curved so as to follow the upper shape of the supply roller 44, and the gap between the curved surface of the upper case 411 and the surface of the supply roller 44 is 1 0.0 [mm].

As shown in FIGS. 7 to 10, side seals 59 are attached to a part of the middle case 412 corresponding to both longitudinal ends of the opening 56 of the developing device 4. The side seal 59 is provided on the inner side in the axial direction with respect to the spacer 422 provided in the vicinity of both ends in the axial direction of the developing roller 42, and in a region where the axial end where the doctor blade 45 contacts the developing roller 42 overlaps. ing. Such a side seal 59 prevents the toner from leaking from the end portion in the longitudinal direction of the opening 56 in the developing casing 41.
A remaining toner sensor 49 provided in the middle case 412 detects the amount of toner in the toner storage unit 43.

Next, the movement of toner in the developing device 4 will be described.
The toner replenished into the developing device 4 from the toner replenishing port 55 is supplied to the toner accommodating portion 43 by the supply screw 48 and stirred by the paddle 46. Further, the paddle 46 is flipped up in the direction of the developing roller 42 and the supply roller 44 and conveyed. The toner supplied to the supply roller 44 is delivered to the surface of the developing roller 42 at a supply nip β where the supply roller 44 contacts the developing roller 42. Of the toner delivered to the surface of the developing roller 42, the amount of toner exceeding a predetermined amount conveyed to the developing area α is scraped off from the surface of the developing roller 42 by the doctor blade 45.

  The toner remaining on the surface of the developing roller 42 that has passed through the portion facing the doctor blade 45 is conveyed as it is in the surface movement direction by the rotation of the developing roller 42, and reaches the developing region α facing the photoreceptor 2. The toner that has passed through the development region α without being used for development passes through a position where the inlet seal 47 contacts, and is conveyed to the supply nip β that is a position facing the supply roller 44. The toner that has reached the supply nip β by the developing roller 42 is scraped off from the surface of the developing roller 42 by the supply roller 44 and conveyed by the supply roller 44.

  Next, toner used in the copier 500 according to the first embodiment will be described. As the toner used in the copying machine 500, a toner having high fluidity is used so as to be compatible with high-speed toner conveyance. Specifically, a toner having an accelerated aggregation degree of 40% or less is used. The accelerated aggregation degree is an index indicating the fluidity of the toner.

A method for measuring the accelerated aggregation degree of the toner is shown below.
<Measurement device>
・ Powder tester made by Hosokawa Micron <Measurement method>
・ Leave the sample to be measured in a thermostat (35 ± 2 [° C], 24 ± 1 [h])
・ Measured with a powder tester ・ Three types of sieves with different openings (for example, 75 [μm], 44 [μm], 22 [μm])
-Calculate from the remaining amount of toner when sieving, and obtain the degree of aggregation by the following calculation.
{(Weight of toner remaining on upper screen) / (sample amount)} × 100
{(Weight of toner remaining on middle screen) / (sample amount)} × 100 × 3/5
{(Weight of toner remaining on lower screen) / (sample amount)} × 100 × 1/5
The total of the above three calculated values is defined as the heat aggregation degree [%].

  As described above, the accelerated aggregation degree of the toner is an index obtained by stacking three types of meshes having different openings in the order of increasing openings, placing particles on the uppermost stage, sieving with constant vibration, and calculating from the toner weight on each mesh. .

In the first exemplary embodiment, toner having an average circularity of 0.90 or more (0.90 to 1.00 toner) is used.
In Embodiment 1, the value obtained from the following equation (1) is defined as circularity a. This circularity is an index of the degree of unevenness of the toner particles, and indicates 1.00 when the toner is a perfect sphere, and the circularity becomes smaller as the surface shape becomes more complicated.

Circularity a = L ₀ / L (1)
(L ₀ : circumference of a circle having the same projected area as the particle image, L: circumference of the projected image of the particle)

When the average circularity is in the range of 0.90 to 1.00, the surface of the toner particles is smooth, and the contact area between the toner particles and between the toner particles and the photoreceptor 2 is small, so that the transferability is excellent.
When the average circularity is in the range of 0.90 to 1.00, since the toner particles have no corners, the developer (toner) agitation torque in the developing device 4 is small, and the agitation drive is stabilized. Can be prevented.
In addition, since there are no angular toner particles in the toner that forms the dots, when the pressure is brought into contact with the transfer medium during transfer, the pressure is uniformly applied to the entire toner that forms the dots, and the transfer is not easily lost.
Further, since the toner particles are not angular, the abrasive power of the toner particles itself is small, and it is possible to prevent the surfaces of the photoreceptor 2 and the charging member 3 from being damaged or worn.

  Next, a method for measuring the circularity will be described. The circularity can be measured using a flow type particle image analyzer FPIA-1000 manufactured by Toa Medical Electronics.

  As a specific measuring method, a surfactant, preferably an alkylbenzene sulfonate, is added in an amount of 0.1 to 0.5 [100] as a dispersant in 100 to 150 [ml] of water from which impure solids have been removed in advance. ml] and about 0.1 to 0.5 [g] of a measurement sample is further added. The suspension in which the sample is dispersed is subjected to dispersion treatment with an ultrasonic disperser for about 1 to 3 minutes, and the shape and particle size of the toner are measured with the above apparatus with the dispersion concentration being 3000 to 10,000 [pieces / μl].

  In order to reproduce minute dots of 600 [dpi] or more, the weight average particle diameter (D4) of the toner is preferably 3 to 8 [μm]. In this range, since the toner particles have a sufficiently small particle size with respect to the minute latent image dots, the dot reproducibility is excellent. When the weight average particle diameter (D4) is less than 3 [μm], phenomena such as a decrease in transfer efficiency and a decrease in blade cleaning properties tend to occur.

  When the weight average particle diameter (D4) exceeds 8 [μm], it is difficult to suppress scattering of characters and lines. Moreover, it is preferable that ratio (D4 / D1) of a weight average particle diameter (D4) and a number average particle diameter (D1) exists in the range of 1.00-1.40. The closer (D4 / D1) is to 1.00, the sharper the particle size distribution. With such a toner having a small particle size and a narrow particle size distribution, the toner charge amount distribution is uniform, a high-quality image with little background fogging can be obtained, and the electrostatic transfer method has a high transfer rate. can do.

  Next, a method for measuring the particle size distribution of toner particles will be described. Examples of the measuring device for the particle size distribution of toner particles by the Coulter counter method include Coulter Counter TA-II and Coulter Multisizer II (both manufactured by Coulter). The measurement method is described below.

  First, 0.1 to 5 [ml] of a surfactant (preferably alkylbenzene sulfonate) is added as a dispersant to 100 to 150 [ml] of the electrolytic aqueous solution. Here, the electrolytic solution is prepared by preparing a 1% NaCl aqueous solution using primary sodium chloride, and for example, ISOTON-II (manufactured by Coulter) can be used. Here, 2 to 20 [mg] of a measurement sample is further added. The electrolytic solution in which the sample is suspended is subjected to a dispersion treatment with an ultrasonic disperser for about 1 to 3 minutes, and the measurement device is used to measure the weight and number of toner particles or toner using a 100 [μm] aperture as the aperture. Then, the weight distribution and the number distribution are calculated. From the obtained distribution, the weight average particle diameter (D4) and the number average particle diameter (D1) of the toner can be obtained.

  As a channel, it is less than 2.00-2.52 [micrometer]; 2.52-less than 3.17 [micrometer]; 3.17-less than 4.00 [micrometer]; 4.00-5.04 [micrometer] Less than 5.04 to 6.35 [μm]; 6.35 to less than 8.00 [μm]; 8.00 to less than 10.08 [μm]; 10.08 to less than 12.70 [μm]; 12.70 to less than 16.00 [μm]; 16.00 to less than 20.20 [μm]; 20.20 to less than 25.40 [μm]; 25.40 to less than 32.00 [μm]; Using 13 channels of 00 to less than 40.30 [μm], particles having a particle size of 2.00 [μm] or more to less than 40.30 [μm] are targeted.

  The toner used in Embodiment 1 is obtained by crosslinking, in an aqueous solvent, a toner material liquid in which at least a polyester prepolymer having a functional group containing a nitrogen atom, polyester, a colorant, and a release agent are dispersed in an organic solvent. And / or a toner obtained by an extension reaction, and is called a polymerized toner. Hereinafter, the constituent material and the manufacturing method of the toner will be described.

<Polyester>
The polyester is obtained by a polycondensation reaction between a polyhydric alcohol compound and a polycarboxylic acid compound. Examples of the polyhydric alcohol compound (PO) include dihydric alcohol (DIO) and trihydric or higher polyhydric alcohol (TO). (DIO) alone or a mixture of (DIO) and a small amount of (TO) preferable. Examples of the dihydric alcohol (DIO) include alkylene glycol (ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,6-hexanediol, etc.); alkylene ether glycol (diethylene glycol) , Triethylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, polytetramethylene ether glycol, etc.); alicyclic diols (1,4-cyclohexanedimethanol, hydrogenated bisphenol A, etc.); bisphenols (bisphenol A, bisphenol) F, bisphenol S, etc.); alkylene oxide (ethylene oxide, propylene oxide, butylene oxide, etc.) adduct of the above alicyclic diol; Alkylene oxide bisphenol (ethylene oxide, propylene oxide, butylene oxide, etc.), etc. adducts. Among them, preferred are alkylene glycols having 2 to 12 carbon atoms and alkylene oxide adducts of bisphenols, and particularly preferred are alkylene oxide adducts of bisphenols and alkylene glycols having 2 to 12 carbon atoms. It is a combined use. The trihydric or higher polyhydric alcohol (TO) includes 3 to 8 or higher polyhydric aliphatic alcohols (glycerin, trimethylolethane, trimethylolpropane, pentaerythritol, sorbitol, etc.); trihydric or higher phenols (Trisphenol PA, phenol novolak, cresol novolak, etc.); and alkylene oxide adducts of the above trivalent or higher polyphenols.

  Examples of the polyvalent carboxylic acid (PC) include divalent carboxylic acid (DIC) and trivalent or higher polyvalent carboxylic acid (TC). (DIC) alone and (DIC) with a small amount of (TC) Mixtures are preferred. Divalent carboxylic acids (DIC) include alkylene dicarboxylic acids (succinic acid, adipic acid, sebacic acid, etc.); alkenylene dicarboxylic acids (maleic acid, fumaric acid, etc.); aromatic dicarboxylic acids (phthalic acid, isophthalic acid, terephthalic acid) And naphthalenedicarboxylic acid). Of these, preferred are alkenylene dicarboxylic acids having 4 to 20 carbon atoms and aromatic dicarboxylic acids having 8 to 20 carbon atoms. Examples of the trivalent or higher polyvalent carboxylic acid (TC) include aromatic polycarboxylic acids having 9 to 20 carbon atoms (such as trimellitic acid and pyromellitic acid). In addition, as polyhydric carboxylic acid (PC), you may make it react with polyhydric alcohol (PO) using the above-mentioned acid anhydride or lower alkyl ester (Methyl ester, ethyl ester, isopropyl ester, etc.).

The ratio of the polyhydric alcohol (PO) to the polycarboxylic acid (PC) is usually 2/1 to 1/1, preferably as the equivalent ratio [OH] / [COOH] of the hydroxyl group [OH] and the carboxyl group [COOH]. Is 1.5 / 1 to 1/1, more preferably 1.3 / 1 to 1.02 / 1. The polycondensation reaction between polyhydric alcohol (PO) and polycarboxylic acid (PC) is heated to 150 to 280 [° C.] in the presence of a known esterification catalyst such as tetrabutoxy titanate or dibutyltin oxide, and reduced in pressure as necessary. The produced water is distilled off while obtaining a polyester having a hydroxyl group. The hydroxyl value of the polyester is preferably 5 or more, and the acid value of the polyester is usually 1 to 30, preferably 5 to 20. By giving an acid value, it tends to be negatively chargeable, and further, when fixing to a recording paper, the affinity between the recording paper and the toner is good and the low-temperature fixability is improved. However, when the acid value exceeds 30, there is a tendency to deteriorate with respect to the stability of charging, particularly environmental fluctuation.
The weight average molecular weight is 10,000 to 400,000, preferably 20,000 to 200,000. A weight average molecular weight of less than 10,000 is not preferable because offset resistance deteriorates. On the other hand, if it exceeds 400,000, the low-temperature fixability is deteriorated.

  In addition to the unmodified polyester obtained by the above polycondensation reaction, the polyester preferably contains a urea-modified polyester. The urea-modified polyester is obtained by reacting a terminal carboxyl group or hydroxyl group of the polyester obtained by the above polycondensation reaction with a polyvalent isocyanate compound (PIC) to obtain a polyester prepolymer (A) having an isocyanate group. It is obtained by cross-linking and / or extending the molecular chain by the reaction of the amine with amines.

  Examples of the polyvalent isocyanate compound (PIC) include aliphatic polyisocyanates (tetramethylene diisocyanate, hexamethylene diisocyanate, 2,6-diisocyanatomethylcaproate, etc.); alicyclic polyisocyanates (isophorone diisocyanate, cyclohexylmethane diisocyanate, etc.) ); Aromatic diisocyanates (tolylene diisocyanate, diphenylmethane diisocyanate, etc.); araliphatic diisocyanates (α, α, α ′, α′-tetramethylxylylene diisocyanate, etc.); isocyanates; Those blocked with caprolactam or the like; and combinations of two or more of these.

  The ratio of the polyvalent isocyanate compound (PIC) is usually 5/1 to 1/1, preferably as an equivalent ratio [NCO] / [OH] of the isocyanate group [NCO] and the hydroxyl group [OH] of the polyester having a hydroxyl group. 4/1 to 1.2 / 1, more preferably 2.5 / 1 to 1.5 / 1. When [NCO] / [OH] exceeds 5, low-temperature fixability deteriorates. When the molar ratio of [NCO] is less than 1, when a urea-modified polyester is used, the urea content in the ester is lowered and hot offset resistance is deteriorated.

  The content of the polyisocyanate compound (PIC) component in the polyester prepolymer (A) having an isocyanate group is usually 0.5 to 40 [wt%], preferably 1 to 30 [wt%], more preferably 2 to 20 [wt%]. If it is less than 0.5 [wt%], the hot offset resistance is deteriorated, and it is disadvantageous in terms of both heat-resistant storage stability and low-temperature fixability. On the other hand, if it exceeds 40 [wt%], the low-temperature fixability deteriorates.

  The number of isocyanate groups contained per molecule in the polyester prepolymer (A) having an isocyanate group is usually 1 or more, preferably 1.5 to 3 on average, more preferably 1.8 to 2 on average. Five. If it is less than 1 per molecule, the molecular weight of the urea-modified polyester will be low, and the hot offset resistance will deteriorate.

  Next, as amines (B) to be reacted with the polyester prepolymer (A), a divalent amine compound (B1), a trivalent or higher polyvalent amine compound (B2), an amino alcohol (B3), an amino mercaptan (B4) ), Amino acid (B5), and amino acid block of B1 to B5 (B6).

  Examples of the divalent amine compound (B1) include aromatic diamines (phenylenediamine, diethyltoluenediamine, 4,4′-diaminodiphenylmethane, etc.); alicyclic diamines (4,4′-diamino-3,3′-dimethyldicyclohexyl). Methane, diamine cyclohexane, isophorone diamine, etc.); and aliphatic diamines (ethylene diamine, tetramethylene diamine, hexamethylene diamine, etc.) and the like.

  Examples of the trivalent or higher polyvalent amine compound (B2) include diethylenetriamine and triethylenetetramine. Examples of amino alcohol (B3) include ethanolamine and hydroxyethylaniline. Examples of amino mercaptan (B4) include aminoethyl mercaptan and aminopropyl mercaptan.

  Examples of the amino acid (B5) include aminopropionic acid and aminocaproic acid. Examples of B1 to B5 blocked amino groups (B6) include ketimine compounds and oxazolidine compounds obtained from the amines of B1 to B5 and ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, etc.). Among these amines (B), preferred are B1 and a mixture of B1 and a small amount of B2.

  The ratio of amines (B) is equivalent to the equivalent ratio [NCO] / [NHx] of isocyanate groups [NCO] in the polyester prepolymer (A) having isocyanate groups and amino groups [NHx] in amines (B). Is usually 1/2 to 2/1, preferably 1.5 / 1 to 1 / 1.5, more preferably 1.2 / 1 to 1 / 1.2.

  When [NCO] / [NHx] is more than 2 or less than 1/2, the molecular weight of the urea-modified polyester is lowered, and the hot offset resistance is deteriorated. The urea-modified polyester may contain a urethane bond together with a urea bond. The molar ratio of the urea bond content to the urethane bond content is usually 100/0 to 10/90, preferably 80/20 to 20/80, and more preferably 60/40 to 30/70. When the molar ratio of the urea bond is less than 10%, the hot offset resistance is deteriorated.

  The urea-modified polyester is produced by a one-shot method or the like. Polyhydric alcohol (PO) and polyhydric carboxylic acid (PC) are produced in the presence of a known esterification catalyst such as tetrabutoxy titanate and dibutyltin oxide at 150 to 280 [° C.] and, if necessary, reduced pressure. Water is distilled off to obtain a polyester having a hydroxyl group. Next, at 40 to 140 [° C.], this is reacted with polyvalent isocyanate (PIC) to obtain a polyester prepolymer (A) having an isocyanate group. Further, this (A) is reacted with amines (B) at 0 to 140 [° C.] to obtain a urea-modified polyester.

  When reacting the polyvalent isocyanate compound (PIC) and when reacting (A) and (B), a solvent may be used as necessary. Usable solvents include aromatic solvents (toluene, xylene, etc.); ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, etc.); esters (ethyl acetate, etc.); amides (dimethylformamide, dimethylacetamide, etc.) and ethers Inactive to polyvalent isocyanate compounds (PIC) such as benzene (such as tetrahydrofuran).

  In addition, in the crosslinking and / or elongation reaction between the polyester prepolymer (A) and the amines (B), a reaction terminator may be used as necessary to adjust the molecular weight of the resulting urea-modified polyester. Examples of the reaction terminator include monoamines (diethylamine, dibutylamine, butylamine, laurylamine, etc.), and those obtained by blocking them (ketimine compounds).

  The weight average molecular weight of the urea-modified polyester is usually 10,000 or more, preferably 20,000 to 10,000,000, and more preferably 30,000 to 1,000,000. If it is less than 10,000, the hot offset resistance deteriorates. The number average molecular weight of the urea-modified polyester or the like is not particularly limited when the above-mentioned unmodified polyester is used, and may be a number average molecular weight that can be easily obtained to obtain the weight average molecular weight. When the urea-modified polyester is used alone, its number average molecular weight is usually 2000-15000, preferably 2000-10000, more preferably 2000-8000. When it exceeds 20000, the low-temperature fixability and the glossiness when used in a full-color apparatus are deteriorated.

  By using the unmodified polyester and the urea-modified polyester in combination, the low-temperature fixability and the gloss when used in the copying machine 500 are improved. Therefore, it is preferable to use the urea-modified polyester alone. The unmodified polyester may include a polyester modified with a chemical bond other than a urea bond.

  The unmodified polyester and the urea-modified polyester are preferably at least partially compatible with each other in terms of low-temperature fixability and hot offset resistance. Therefore, it is preferable that the unmodified polyester and the urea-modified polyester have a similar composition.

  The weight ratio of unmodified polyester to urea-modified polyester is usually 20/80 to 95/5, preferably 70/30 to 95/5, more preferably 75/25 to 95/5, and particularly preferably 80 /. 20-93 / 7. When the weight ratio of the urea-modified polyester is less than 5 [%], the hot offset resistance is deteriorated, and it is disadvantageous in terms of both heat-resistant storage stability and low-temperature fixability.

  The glass transition point (Tg) of the binder resin containing unmodified polyester and urea-modified polyester is usually 45 to 65 [° C.], preferably 45 to 60 [° C.]. If the temperature is less than 45 [° C.], the heat resistance of the toner deteriorates, and if it exceeds 65 [° C.], the low-temperature fixability becomes insufficient.

  In addition, since the urea-modified polyester is likely to be present on the surface of the obtained toner base particles, the heat-resistant storage stability tends to be good even when the glass transition point is low as compared with known polyester-based toners.

<Colorant>
As the colorant, all known dyes and pigments can be used. For example, carbon black, nigrosine dye, iron black, naphthol yellow S, Hansa yellow (10G, 5G, G), cadmium yellow, yellow iron oxide, ocher , Yellow lead, titanium yellow, polyazo yellow, oil yellow, Hansa yellow (GR, A, RN, R), pigment yellow L, benzidine yellow (G, GR), permanent yellow (NCG), Vulcan fast yellow (5G, R), Tartrazine Lake, Quinoline Yellow Lake, Anthrazan Yellow BGL, Isoindolinone Yellow, Bengala, Red Dan, Lead Zhu, Cadmium Red, Cadmium Mercury Red, Antimon Zhu, Permanent Red 4R, Para Red, Phi Sayred, Parachlor Ortonito Aniline Red, Resol Fast Scarlet G, Brilliant Fast Scarlet, Brilliant Carmine B, Permanent Red (F2R, F4R, FRL, FRLL, F4RH), Fast Scarlet VD, Belkan Fast Rubin B, Brilliant Scarlet G, Resol Rubin GX, Permanent Red F5R , Brilliant Carmine 6B, Pigment Scarlet 3B, Bordeaux 5B, Toluidine Maroon, Permanent Bordeaux F2K, Helio Bordeaux BL, Bordeaux 10B, Bon Maroon Light, Bon Maroon Medium, Eosin Lake, Rhodamine Lake B, Rhodamine Lake Y, Alizarin Lake, Thio Indigo Red B, Thioindigo Maroon, Oil Red, Quinacridone Red, Pyrazolone Red Polyazo Red, Chrome Vermillion, Benzidine Orange, Perinone Orange, Oil Orange, Cobalt Blue, Cerulean Blue, Alkaline Blue Lake, Peacock Blue Lake, Victoria Blue Lake, Metal Free Phthalocyanine Blue, Phthalocyanine Blue, Fast Sky Blue, Indanthrene Blue (RS, BC), indigo, ultramarine blue, bitumen, anthraquinone blue, fast violet B, methyl violet lake, cobalt purple, manganese purple, dioxane violet, anthraquinone violet, chrome green, zinc green, chromium oxide, pyridian, emerald green, pigment Green B, Naphthol Green B, Green Gold, Acid Green Lake, Malachite Green Lake, Lid Russian nin green, anthraquinone green, titanium oxide, zinc white, litbon and mixtures thereof can be used. The content of the colorant is usually 1 to 15% [%], preferably 3 to 10% [%] based on the toner.

  The colorant can also be used as a master batch combined with a resin. As a binder resin to be kneaded together with the production of the master batch or the master batch, a polymer of styrene such as polystyrene, poly-p-chlorostyrene, polyvinyl toluene or the like, or a copolymer of these and a vinyl compound, Polymethyl methacrylate, polybutyl methacrylate, polyvinyl chloride, polyvinyl acetate, polyethylene, polypropylene, polyester, epoxy resin, epoxy polyol resin, polyurethane, polyamide, polyvinyl butyral, polyacrylic acid resin, rosin, modified rosin, terpene resin, fat Aromatic or alicyclic hydrocarbon resins, aromatic petroleum resins, chlorinated paraffins, paraffin waxes and the like can be mentioned, and these can be used alone or in combination.

<Charge control agent>
Known charge control agents can be used, such as nigrosine dyes, triphenylmethane dyes, chromium-containing metal complex dyes, molybdate chelate pigments, rhodamine dyes, alkoxy amines, quaternary ammonium salts (fluorine-modified 4 Secondary ammonium salts or compounds, tungsten simple substances or compounds, fluorine activators, salicylic acid metal salts, and metal salts of salicylic acid derivatives. Specifically, Bontron 03 of a nigrosine dye, Bontron P-51 of a quaternary ammonium salt, Bontron S-34 of a metal-containing azo dye, E-82 of an oxynaphthoic acid metal complex, E-84 of a salicylic acid metal complex , Phenolic condensate E-89 (above, Orient Chemical Industries, Ltd.), quaternary ammonium salt molybdenum complex TP-302, TP-415 (above, Hodogaya Chemical Co., Ltd.), quaternary ammonium salt copy Charge PSY VP2038, copy blue PR of triphenylmethane derivative, copy charge of quaternary ammonium salt NEG VP2036, copy charge NX VP434 (manufactured by Hoechst), LRA-901, LR-147 which is a boron complex (Nippon Carlit) Manufactured), copper phthalocyanine, perylene, quinacridone, azo series Fee, a sulfonic acid group, a carboxyl group, and polymer compounds having a functional group such as quaternary ammonium salts. Of these, substances that control the negative polarity of the toner are particularly preferably used.

  The amount of charge control agent used is determined by the type of binder resin, the presence or absence of additives used as necessary, and the toner production method including the dispersion method. Therefore, although it is not uniquely limited, Preferably it is used in the range of 0.1-10 weight part with respect to 100 weight part of binder resin. The range of 0.2 to 5 parts by weight is preferable. When the amount exceeds 10 parts by weight, the chargeability of the toner is too high, the effect of the charge control agent is reduced, the electrostatic attraction with the developing roller 42 is increased, the developer fluidity is reduced, and the image density is reduced. Incurs a decline.

<Release agent>
As the mold release agent, a low melting point wax having a melting point of 50 to 120 [° C.] is preferable. By using the low melting point wax, it works more effectively as a release agent in the dispersion with the binder resin between the fixing roller of the fixing device 12 and the toner interface. As a result, it is effective against high temperature offset without applying a release agent such as oil to the fixing roller. Examples of such a wax component include the following. Examples of waxes and waxes include plant waxes such as carnauba wax, cotton wax, wood wax, rice wax, animal waxes such as beeswax and lanolin, mineral waxes such as ozokerite and cercin, and paraffin, microcrystalline, And petroleum waxes such as petrolatum. In addition to these natural waxes, synthetic hydrocarbon waxes such as Fischer-Tropsch wax and polyethylene wax, and synthetic waxes such as esters, ketones, and ethers can be used. Furthermore, fatty acid amides such as 12-hydroxystearic acid amide, stearic acid amide, phthalic anhydride imide, chlorinated hydrocarbon, and low molecular weight crystalline polymer resin, poly-n-stearyl methacrylate, poly-n- A crystalline polymer having a long alkyl group in the side chain such as a homopolymer or copolymer of polyacrylate such as lauryl methacrylate (for example, a copolymer of n-stearyl acrylate-ethyl methacrylate, etc.) can also be used. .

  The charge control agent and the release agent can be melt-kneaded together with the masterbatch and the binder resin, or may be added when dissolved and dispersed in an organic solvent.

<External additive>
Inorganic fine particles are preferably used as an external additive for assisting the fluidity, developability and chargeability of the toner particles. The primary particle diameter of the inorganic fine particles is preferably 5 × 10 ⁻³ to 2 [μm], particularly preferably 5 × 10 ^{−3 to} 0.5 [μm]. Moreover, it is preferable that the specific surface area by BET method is 20-500 [m < ² > / g]. The use ratio of the inorganic fine particles is preferably 0.01 to 5 [wt%] of the toner, and particularly preferably 0.01 to 2.0 [wt%].

Specific examples of the inorganic fine particles include, for example, silica, alumina, titanium oxide, barium titanate, magnesium titanate, calcium titanate, strontium titanate, zinc oxide, tin oxide, quartz sand, clay, mica, wollastonite, diatomaceous earth. Examples include soil, chromium oxide, cerium oxide, bengara, antimony trioxide, magnesium oxide, zirconium oxide, barium sulfate, barium carbonate, calcium carbonate, silicon carbide, and silicon nitride. Among these, as the fluidity imparting agent, it is preferable to use hydrophobic silica fine particles and hydrophobic titanium oxide fine particles in combination. Particularly when both the fine particles have an average particle diameter of 5 × 10 ⁻² [μm] or less and are stirred and mixed, the electrostatic force and van der Waals force with the toner are remarkably improved. Accordingly, the fluidity imparting agent is not detached from the toner even by stirring and mixing inside the developing device 4 performed to obtain a desired charge level. Therefore, it is possible to obtain a good image quality that does not cause firefly and the like, and to further reduce the residual toner.

  Titanium oxide fine particles are excellent in environmental stability and image density stability, but have a tendency to deteriorate the charge rise characteristics. Therefore, if the amount of titanium oxide fine particles added is larger than the amount of silica fine particles added, this side effect is affected. It can be considered large.

  However, when the addition amount of the hydrophobic silica fine particles and the hydrophobic titanium oxide fine particles is in the range of 0.3 to 1.5 [wt%], the charge rising characteristics are not greatly impaired, and the desired charge rising characteristics can be obtained. Stable image quality can be obtained even when copying is repeated.

  Next, a toner manufacturing method will be described. Here, although a preferable manufacturing method is shown, it is not limited to this.

<Toner production method>
(1) A toner material solution is prepared by dispersing a colorant, unmodified polyester, a polyester prepolymer having an isocyanate group, and a release agent in an organic solvent. The organic solvent is preferably volatile with a boiling point of less than 100 [° C.] from the viewpoint of easy removal after toner base particle formation. Specifically, toluene, xylene, benzene, carbon tetrachloride, methylene chloride, 1,2-dichloroethane, 1,1,2-trichloroethane, trichloroethylene, chloroform, monochlorobenzene, dichloroethylidene, methyl acetate, ethyl acetate, methyl ethyl ketone, Methyl isobutyl ketone and the like can be used alone or in combination of two or more. In particular, aromatic solvents such as toluene and xylene and halogenated hydrocarbons such as methylene chloride, 1,2-dichloroethane, chloroform, and carbon tetrachloride are preferable. The usage-amount of an organic solvent is 0-300 weight part normally with respect to 100 weight part of polyester prepolymers, Preferably it is 0-100 weight part, More preferably, it is 25-70 weight part.

(2) The toner material liquid is emulsified in an aqueous medium in the presence of a surfactant and resin fine particles. The aqueous medium may be water alone or an organic solvent such as alcohol (methanol, isopropyl alcohol, ethylene glycol, etc.), dimethylformamide, tetrahydrofuran, cellosolves (methyl cellosolve, etc.), lower ketones (acetone, methyl ethyl ketone, etc.). It may be included.

  The amount of the aqueous medium used relative to 100 parts by weight of the toner material liquid is usually 50 to 2000 parts by weight, preferably 100 to 1000 parts by weight. If the amount is less than 50 parts by weight, the dispersion state of the toner material liquid is poor, and toner particles having a predetermined particle diameter cannot be obtained. If it exceeds 20000 parts by weight, it is not economical.

  Further, in order to improve the dispersion in the aqueous medium, a dispersant such as a surfactant and resin fine particles is appropriately added. As surfactants, anionic surfactants such as alkylbenzene sulfonates, α-olefin sulfonates, phosphate esters, alkylamine salts, amino alcohol fatty acid derivatives, polyamine fatty acid derivatives, amine salt types such as imidazoline, Quaternary ammonium salt type cationic surfactants such as alkyltrimethylammonium salts, dialkyldimethylammonium salts, alkyldimethylbenzylammonium salts, pyridinium salts, alkylisoquinolinium salts, benzethonium chloride, fatty acid amide derivatives, polyhydric alcohols Nonionic surfactants such as derivatives, for example, amphoteric surfactants such as alanine, dodecyldi (aminoethyl) glycine, di (octylaminoethyl) glycine and N-alkyl-N, N-dimethylammonium betaine And the like.

  Further, by using a surfactant having a fluoroalkyl group, the effect can be obtained in a very small amount. Preferred anionic surfactants having a fluoroalkyl group include fluoroalkyl carboxylic acids having 2 to 10 carbon atoms and metal salts thereof, disodium perfluorooctanesulfonyl glutamate, 3- [ω-fluoroalkyl (C6-C11 ) Oxy] -1-alkyl (C3-C4) sodium sulfonate, 3- [ω-fluoroalkanoyl (C6-C8) -N-ethylamino] -1-propanesulfonic acid sodium, fluoroalkyl (C11-C20) carvone Acids and metal salts, perfluoroalkylcarboxylic acids (C7 to C13) and metal salts thereof, perfluoroalkyl (C4 to C12) sulfonic acids and metal salts thereof, perfluorooctanesulfonic acid diethanolamide, N-propyl-N- ( 2-Hydroxyethyl) Perful Olooctanesulfonamide, perfluoroalkyl (C6-C10) sulfonamidopropyltrimethylammonium salt, perfluoroalkyl (C6-C10) -N-ethylsulfonylglycine salt, monoperfluoroalkyl (C6-C16) ethyl phosphate, etc. Can be mentioned.

  Product names include Surflon S-111, S-112, S-113 (Asahi Glass Co., Ltd.), Florard FC-93, FC-95, FC-98, FC-129 (Sumitomo 3M Co., Ltd.), Unidyne DS-101. DS-102 (manufactured by Daikin Industries, Ltd.), Megafac F-110, F-120, F-113, F-191, F-812, F-833 (manufactured by Dainippon Ink, Inc.), Xtop EF-102, 103, 104, 105, 112, 123A, 123B, 306A, 501, 201, 204 (manufactured by Tochem Products), and Fgentent F-100, F150 (manufactured by Neos).

  Moreover, as the cationic surfactant, aliphatic quaternary ammonium such as aliphatic primary, secondary or secondary amic acid, perfluoroalkyl (C6-C10) sulfonamidopropyltrimethylammonium salt which has a right fluoroalkyl group is used. Salt, benzalkonium salt, benzethonium chloride, pyridinium salt, imidazolinium salt, trade names include Surflon S-121 (manufactured by Asahi Glass), Florard FC-135 (manufactured by Sumitomo 3M), Unidyne DS-202 (Daikin Industries) Smoke), Megafac F-150, F-824 (Dainippon Ink Co., Ltd.), Xtop EF-132 (Tochem Products), Footage F-300 (Neos), and the like.

  The resin fine particles are added to stabilize the toner base particles formed in the aqueous medium. For this reason, it is preferable to add so that the coverage which exists on the surface of a toner base particle becomes the range of 10-90 [%]. For example, polymethyl methacrylate fine particles 1 [μm] and 3 [μm], polystyrene fine particles 0.5 [μm] and 2 [μm], poly (styrene-acrylonitrile) fine particles 1 [μm], trade name is PB- 200H (manufactured by Kao Corporation), SGP (manufactured by Sokensha), technopolymer SB (manufactured by Sekisui Chemical Co., Ltd.), SGP-3G (manufactured by Sokensha), micropearl (manufactured by Sekisui Fine Chemical Co., Ltd.) and the like.

  In addition, inorganic compound dispersants such as tricalcium phosphate, calcium carbonate, titanium oxide, colloidal silica, and hydroxyapatite can also be used.

  As a dispersant that can be used in combination with the above resin fine particles and inorganic compound dispersant, the dispersed droplets may be stabilized by a polymer protective colloid. For example, acrylic acid, methacrylic acid, α-cyanoacrylic acid, α-cyanomethacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid or maleic anhydride and other (meth) acrylic monomers containing hydroxyl groups Bodies such as acrylic acid-β-hydroxyethyl, methacrylic acid-β-hydroxyethyl, acrylic acid-β-hydroxypropyl, methacrylic acid-β-hydroxypropyl, acrylic acid-γ-hydroxypropyl, methacrylic acid-γ-hydroxy Propyl, acrylic acid-3-chloro-2-hydroxypropyl, methacrylic acid-3-chloro-2-hydroxypropyl, diethylene glycol monoacrylate, diethylene glycol monomethacrylate, glycerol monoacrylate, glycerol monomethacrylate Luric acid esters, N-methylol acrylamide, N-methylol methacrylamide, etc., vinyl alcohol or ethers with vinyl alcohol, such as vinyl methyl ether, vinyl ethyl ether, vinyl propyl ether, or compounds containing vinyl alcohol and a carboxyl group Esters such as vinyl acetate, vinyl propionate, vinyl butyrate, acrylamide, methacrylamide, diacetone acrylamide or their methylol compounds, acid chlorides such as acrylic acid chloride, methacrylic acid chloride, vinyl pyridine, vinyl pyrrolidone, vinyl Nitrogen compounds such as imidazole and ethyleneimine, or homopolymers or copolymers such as those having a heterocyclic ring thereof, polyoxyethylene, poly Xoxypropylene, polyoxyethylene alkylamine, polyoxypropylene alkylamine, polyoxyethylene alkylamide, polyoxypropylene alkylamide, polyoxyethylene nonylphenyl ether, polyoxyethylene lauryl phenyl ether, polyoxyethylene stearyl phenyl ester, polyoxy Polyoxyethylenes such as ethylene nonylphenyl ester, celluloses such as methyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose can be used.

  The dispersion method is not particularly limited, and known equipment such as a low-speed shear method, a high-speed shear method, a friction method, a high-pressure jet method, and an ultrasonic wave can be applied. Among these, in order to make the particle size of the dispersion 2 to 20 [μm], a high-speed shearing method is preferable. When a high-speed shearing disperser is used, the number of rotations is not particularly limited, but is usually 1000 to 30000 [rpm], preferably 5000 to 20000 [rpm]. The dispersion time is not particularly limited, but in the case of a batch method, it is usually 0.1 to 5 [minutes]. The temperature during dispersion is usually 0 to 150 [° C.] (under pressure), preferably 40 to 98 [° C.].

(3) At the same time as the preparation of the emulsion, the amines (B) are added to cause a reaction with the polyester prepolymer (A) having an isocyanate group. This reaction involves molecular chain crosslinking and / or elongation. The reaction time is selected depending on the reactivity between the isocyanate group structure of the polyester prepolymer (A) and the amines (B), but is usually 10 minutes to 40 hours, preferably 2 to 24 hours. The reaction temperature is generally 0 to 150 [° C.], preferably 40 to 98 [° C.]. Moreover, a well-known catalyst can be used as needed. Specific examples include dibutyltin laurate and dioctyltin laurate.

(4) After completion of the reaction, the organic solvent is removed from the emulsified dispersion (reactant), washed and dried to obtain toner base particles. In order to remove the organic solvent, the temperature of the entire system is gradually raised in a laminar stirring state, and after giving strong stirring in a certain temperature range, the solvent base is removed to produce spindle-shaped toner base particles. . Further, when an acid such as calcium phosphate salt or an alkali-soluble material is used as the dispersion stabilizer, the calcium phosphate salt is dissolved from the toner base particles by a method such as dissolving the calcium phosphate salt with an acid such as hydrochloric acid and washing with water. Remove. It can also be removed by operations such as enzymatic degradation.

(5) A charge control agent is injected into the toner base particles obtained above, and then inorganic fine particles such as silica fine particles and titanium oxide fine particles are externally added to obtain a toner. The injection of the charge control agent and the external addition of the inorganic fine particles are performed by a known method using a mixer or the like. Thereby, a toner having a small particle size and a sharp particle size distribution can be easily obtained. Furthermore, by giving strong agitation in the process of removing the organic solvent, the shape between the true spherical shape and the rugby ball shape can be controlled, and the surface morphology is also controlled between the smooth shape and the umeboshi shape. be able to.

  As described above, on the surface of the developing roller 42 provided in the developing device 4 of Embodiment 1, irregularities having a regular pattern in which the height of the convex portion and the depth (W3) of the concave portion are constant are formed. . As a conventional one-component developing device, there is one in which a rough surface process such as a sound blast process is performed on the surface of a developing roller to form an uneven shape on the surface. As described above, the surface of the developing roller is roughened to improve the performance of the developing roller carrying and transporting toner. However, the unevenness formed on the surface of the developing roller by the rough surface treatment has irregularities in the height of the protrusions, the depth of the recesses, and the pattern of the unevenness. If the pattern and depth of the recesses are irregular, the toner carrying amount on the surface of the developing roller is not stable, and density unevenness may occur when the latent image on the photoreceptor is developed. On the other hand, in the developing device 4 of the first embodiment, since the depth (W3) of the concave portion is constant and the formation pattern is regular, the toner carrying amount on the surface of the developing roller 42 is stable, and density unevenness during development is obtained. Can be suppressed.

Here, the regular unevenness is sufficient as long as the unevenness is suppressed to the extent that density unevenness is suppressed without unevenness of the toner adhesion amount.
For example, paying attention to the latent image on the photosensitive member 2, the latent image has a latent image on dots formed in a region partitioned in a lattice shape, and the lattice can be formed at a plurality of pitches in the axial direction. It is. A pitch whose pitch in the axial direction of the back part is shorter than the longest pitch among a plurality of types of pitches in the lattice may be continuous.
In addition, the present invention can be effective even if the uneven shape on the surface of the developing roller 42 is other than regular unevenness, but it is preferable from the image surface if it has regular unevenness. .

  As shown in FIGS. 1 and 20, in the developing device 4 of the first embodiment, the developing roller 42 whose rotational direction is the arrow B direction in the drawing moves from above to below in the doctor portion. In such a case, since the downward force (Fg) is applied to the toner by its own weight acting on the toner T, the compressive force on the toner due to the stress (Fb) of the doctor blade 45 can be reduced. Therefore, it is possible to suppress the toner from aggregating at a portion (a portion 42c in FIG. 20) of the convex portion 42a of the developing roller 42 on the downstream side in the surface movement direction of the developing roller 42. As a result, the occurrence of filming can be suppressed, and fluctuations in the Q / M value and M / A value on the developing roller 42 can be suppressed.

  In addition, as the toner that is a developer used in the developing device 4, it is preferable to use a toner having an accelerated aggregation degree of 40% or less. By using such toner, it is possible to further alleviate the aggregation of toner at the portion of the convex portion 42a of the developing roller 42 on the downstream side in the surface movement direction of the developing roller 42 (portion 42c in FIG. 20). In the doctor section shown in FIG. 20, the doctor blade 45 is placed against the surface of the developing roller 42. As shown in FIG. 21, the contact state of the doctor blade 45 with the surface of the developing roller 42 can be used to scrape off the toner T present on the top surface 42t of the convex portion 42a. More preferred.

As shown in FIG. 22, when the angle γ formed by the convex portion 42a and the concave portion 42b of the developing roller 42 is less than 90 [°], the probability that the supply roller 44 contacts the entire concave portion 42b decreases. Further, as shown in FIG. 23, even when the angle formed by the convex portion 42a and the concave portion 42b is less than 90 [°], the probability that the supply roller 44 contacts the entire concave portion 42b is reduced.
On the other hand, in the developing roller 42 provided in the developing device 4 of Embodiment 1, the angle γ formed by the convex portion 42a and the concave portion 42b of the developing roller 42 is 90 ° or more as shown in FIG. As shown in FIG. 24, when the angle γ is 90 [°] or more, the probability that the supply roller 44 hits the toner on the developing roller 42 increases, so that the resetting property is improved.

FIG. 25 shows the angle γ formed by the convex portion 42a and the concave portion 42b on the downstream side in the surface movement direction of the developing roller 42 in the convex portion 42a and the upstream side in the surface movement direction of the developing roller 42 in the convex portion 42a. It is explanatory drawing of a structure whose angle (gamma) is both 90 [degree]. Hereinafter, the angle γ on the downstream side in the surface movement direction of the developing roller 42 in the convex portion 42a is referred to as “convex portion downstream angle γ1”. Further, the angle γ on the upstream side in the direction of surface movement of the developing roller 42 in the convex portion 42a is referred to as “convex portion upstream angle γ2”.
As shown in FIG. 25, the stress of the doctor blade 45 acts in the direction of arrow Fb in the figure. Since the developing roller 42 moves in the direction indicated by the arrow B in the figure, the toner T carried in the recess 42b is subjected to a compressive force indicated by the arrow Fa in FIG. For this reason, if the toner in contact with the wall surface of the convex portion 42a on the downstream side in the surface movement direction of the developing roller 42 is not replaced, the compression force is applied to the specific toner, and the toner may aggregate. is there.

  On the other hand, in the developing roller 42 provided in the developing device 4 of Embodiment 1, at least the convex downstream angle γ1 is an obtuse angle among the angles γ formed by the convex portions 42a and the concave portions 42b as shown in FIG. It is formed as follows. Since the convex portion downstream angle γ1 is an obtuse angle, the toner that contacts the wall surface of the convex portion 42a on the downstream side in the surface movement direction of the developing roller 42 is easily scraped by the supply roller 44, and the toner is replaced. Can be urged. By replacing the toner in contact with the wall surface, it is possible to prevent the compression force from acting on the specific toner and prevent the toner from aggregating.

  In the enlarged cross-sectional view of the surface of the developing roller 42 shown in FIG. As shown in FIG. 27, the contact state of the doctor blade 45 with the surface of the developing roller 42 allows the toner T present on the top surface 42t of the convex portion 42a to be worn off when the tip is in contact. More preferred.

In the configuration in which the convex portions 42a on the rhombus are formed on the surface of the developing roller 42, as shown in FIG. 28, either one of the two sets of parallel lines of the rhombic top surface 42t of the convex portion 42a is the developing roller. If it is parallel to the surface movement direction of 42, the following problems occur. In other words, the toner tends to be compressed at a portion of the convex portion 42a on the downstream side in the surface movement direction of the developing roller 42 (portion 42c in FIG. 28), so that the filming tends to increase.
On the other hand, as shown in FIG. 13B, the developing roller 42 provided in the developing device 4 of Embodiment 1 has both of two sets of parallel lines on the rhombic top surface 42t of the convex portion 42a. The shape has an angle with respect to the surface movement direction of the developing roller 42. For this reason, it is difficult for the toner to be compressed in the portion of the convex portion 42a on the downstream side in the surface movement direction of the developing roller 42 (portion 42c in FIG. 13B). In the developing device 4 of the first embodiment, the angle formed by the side of the rhombic top surface 42t of the convex portion 42a and the surface moving direction of the developing roller 42 is 45 [°].

In the developing device 4 of the first embodiment, the material of the doctor blade 45 (blade member 450), which is a restriction member, is made of metal.
In the developing devices described in Patent Document 1 and Patent Document 2, a rubber member is used as a regulating member that comes into contact with the developing roller on which a regular irregular shape is formed. However, in the configuration using the rubber regulating member, the amount of toner on the developing roller may vary when the protruding amount of the regulating member changes due to assembly tolerance at the time of manufacture or scraping of the blade used over time. Specifically, the toner on the developing roller becomes extremely small, the image density becomes thin, or conversely, the toner amount on the developing roller increases, charging failure occurs, and the background portion of the image becomes Occasionally, dirty soiling may occur.
On the other hand, by using a metal blade as the doctor blade 45 as in the developing device 4 of the first embodiment, even if the protruding amount of the doctor blade 45 changes within a certain range, The amount of toner can be stabilized.

  As the developing roller 42, a general-purpose material such as carbon steel (STKM or the like), Al (aluminum), or SUS can be used. Further, as the regulation blade, materials such as phosphor bronze (C5210), copper (C1202), beryllium copper (C1720), stainless steel (SUS301, SUS304) can be used.

[Experiment 1]
Next, when the metal blade is used as the doctor blade 45 and the rubber blade is used, the stability of the toner amount on the developing roller 42 with respect to the change in the protruding amount of the doctor blade 45 is compared. Experiment 1 will be described.
Here, a method of changing the protruding amount of the doctor blade 45 will be described with reference to FIG.

First, the doctor blade 45 is brought into contact with the developing roller 42 in a state of edge contact so that the doctor blade 45 extends in a tangential direction (vertical direction in FIG. 29) at the initial contact position Q1 with respect to the developing roller 42. . Here, the edge contact means that the edge part forming the ridge line between the opposing surface 45b and the tip surface 45a of the doctor blade 45 contacts the surface of the developing roller 42 (the top surface 42t which is the surface of the convex part 42a). State. Here, the edge part 45e shows the vicinity of the virtual straight line where two virtual planes obtained by extending the facing surface 45b of the doctor blade 45 and the tip surface 45a intersect each other. And as the edge part 45e which forms the ridgeline used as the virtual straight line vicinity, the ridgeline may be rounded or it may be chamfered.
More specifically, a corner (edge 45e, which may be rounded or chamfered) on the developing roller 42 side at the free end of the flat doctor blade 45 may be convex. What is necessary is just to come in contact with the part 42a.

As for the edge contact direction, as shown in FIGS. 1 and 21, the portion where the doctor blade 45 is fixed (blade folder 45 c) is more than the portion where the doctor blade 45 is in contact with the developing roller 42. It is located downstream in the rotation direction of the developing roller 42. That is, the free end is configured to abut against the rotation of the developing roller 42.
Here, as a method of bringing the doctor blade 45 into contact, there is a method in which a flat blade member is bent and the bent portion is brought into contact. However, as described above, the effect of scavenging the toner is the free end side of the blade member. The method in which the tips of the two are in contact is more effective and desirable. The doctor blade 45 protrudes from the downstream side in the surface movement direction of the developing roller 42 and is used as an edge.

  Next, the blade holder 45c (pedestal portion 452) that supports the base of the doctor blade 45 is moved along the normal direction of the developing roller 42 at the initial contact position Q1 (the direction indicated by the arrow X in FIG. 29A). Move to the side. As a result, as shown in FIG. 29 (b), the position of the doctor blade 45 that contacts the developing roller 42 moves to the base side, the doctor blade 45 bends, and the doctor blade 45 bends by abdominal contact. Contact in the state. Here, the stomach pad is a state in which the facing surface 45b of the doctor blade 45 facing the developing roller 42 is in contact and the edge portion is not in contact. Further, the contact position Q of the doctor blade 45 on the surface of the developing roller 42 at this time varies from the initial contact position Q1 upward in FIG.

  In the state shown in FIG. 29B, the blade folder 45c is moved away from the developing roller 42 along the direction (vertical direction in FIG. 29) perpendicular to the normal direction at the initial contact position Q1 (arrow in FIG. 29). When it is moved in the Z direction), the amount of protrusion gradually decreases. And as shown in FIG.29 (c), it will be in the state of edge contact in the state in which the doctor blade 45 has bent. When the blade folder 45c is moved in the Z direction so that the protruding amount is further decreased from the state shown in FIG. 29C, the amount of deflection of the doctor blade 45 is increased until the doctor blade 45 is separated from the developing roller. The edge contact state is maintained while decreasing.

  The change in the toner conveyance amount on the developing roller 42 when the protrusion amount is changed between the case where the doctor blade 45 is a metal blade (phosphor bronze) and the case where the doctor blade 45 is a rubber blade made of urethane rubber. The measured experimental results are shown in FIG. The amount of protrusion was changed by the method of changing the amount of protrusion described with reference to FIG.

In the graph shown in FIG. 30, the position of the doctor blade 45 in the state shown in FIG. 29C in which the doctor blade 45 is changed from the stomach contact state to the edge contact state is set to zero. The displacement when the blade folder 45c is moved in the direction of the arrow Z in FIG. 29 from the zero position is − (minus), and when the blade folder 45c is moved in the direction opposite to the direction of the arrow Z in FIG. The displacement is shown as + (plus). In other words, the right side of the drawing in FIG.
A graph indicated by a broken line in FIG. 30 is an experimental result when a rubber blade is used, and a graph indicated by a solid line is an experimental result when a metal blade is used.

As shown in FIG. 30, when the position of the doctor blade 45 is in the + (plus) direction, the toner conveyance amount increases as the positions of both the metal blade and the rubber blade become positive.
On the other hand, when the position of the doctor blade 45 is in the − (minus) direction, a metal blade (solid line) has a region showing a stable conveyance amount as shown in FIG. 30. On the other hand, in the case of the rubber blade used in the conventional developing device (broken line), the toner was hardly conveyed onto the developing roller 42 at the position in the − (minus) direction.

According to Experiment 1 described with reference to FIG. 30, the amount of toner on the developing roller 42 is desired for the metal doctor blade 45 rather than the rubber for the amount of protrusion with respect to the developing roller 42 having a regular uneven shape on the surface. It was found that the range of the amount of protrusion as a quantity is wide.
Therefore, by using a metal blade as the doctor blade 45 as in the present embodiment, the margin of design tolerance in the Z direction in FIG. 29 when the doctor blade 45 is attached is increased, and assembling is improved. . Furthermore, the margin of mechanical tolerances is increased, and the cost of parts can be reduced.

FIG. 31 is an enlarged explanatory view of the contact position Q between the doctor blade 45 and the developing roller 42 in the edge contact state.
As described with reference to FIG. 30, when a metal blade is used as the doctor blade 45, the region where the toner amount is stable is obtained because the edge portion 45 e at the tip of the doctor blade 45 contacts the developing roller 42. It is to do. Specifically, as shown in FIG. 31, when the edge portion 45 e hits, the toner T is thinned so as to be worn by the doctor blade 45, so that the regular concave-convex concave portion 42 b of the developing roller 42 is formed. Only the buried toner T is conveyed. For this reason, the amount of toner on the surface of the developing roller 42 can be set to a desired amount according to the volume of the recess 42b, and the amount of toner transported by the developing roller 42 can be stabilized. Further, a metal blade has a certain degree of rigidity. Therefore, it is less likely to bite into the recess 42b of the developing roller 42 due to its elasticity and scrape out the toner in the recess 42b than that of a resin such as rubber, and the amount of toner transported by the developing roller 42 can be stabilized. .

  In addition, by using a metal blade, the contact pressure with the developing roller is higher than that of a resin such as rubber, and the toner T on the top surface 42t can be satisfactorily worn. Only the toner T buried in the regular concave-convex concave portion 42b is conveyed. For this reason, the amount of toner on the surface of the developing roller 42 can be set to a desired amount according to the volume of the recess 42b, and the amount of toner transported by the developing roller 42 can be stabilized. In addition, compared to a resin such as rubber, a stable contact pressure can be maintained over time, and the amount of toner conveyed by the developing roller 42 can be stabilized over time.

[Experiment 2]
Next, by using a metal blade as the doctor blade 45, the range of the position of the doctor blade 45 that can maintain the edge contact when the value of the movement distance X1 in the normal direction at the initial contact position Q1 in FIG. The measured experiment 2 will be described.

FIG. 32 is a graph showing the experimental results of Experiment 2.
In the graph of FIG. 32, when the doctor blade 45 is in the tangential direction of the surface of the developing roller 42 at the contact position Q, the blade folder from FIG. 29A to FIG. The horizontal axis represents the value of the movement distance X1 of 45c. In the graph of FIG. 32, the blade folder 45c is moved from the state shown in FIG. 29B in the direction of arrow Z in the figure, and when the state shown in FIG. 29C is reached, the vertical axis is zero. Then, the blade folder 45c is further moved in the arrow Z direction in the drawing from the state shown in FIG. 29C, and the movement distance of the blade folder 45c in the Z direction in the drawing until the doctor blade 45 is separated from the surface of the developing roller 42. Is the vertical axis.

  From the graph shown in FIG. 32, when the moving distance X1 is zero or more, the doctor blade 45 can maintain the edge contact as the moving distance X1 in the normal direction of the surface of the developing roller 42 at the initial contact position Q1 increases. The range can be expanded. When the movement distance X1 is equal to or greater than zero, the doctor blade 45 is disposed so as to be bent by contact with the developing roller 42. By arranging in this way, when attaching the doctor blade 45, the margin of design tolerance in the vertical direction in FIG. 29 is increased, so that the assembling property is improved. Furthermore, the margin of mechanical tolerances is increased, and the cost of parts can be reduced.

[Experiment 3]
Next, as a metal blade used for the doctor blade 45, whether or not a streak image was generated was confirmed depending on whether the material was phosphor bronze or stainless steel (SUS). In this experiment, the Vickers hardness of the surface layer (surface layer 42f) of the developing roller 42 is set larger than phosphor bronze and smaller than stainless steel. Specifically, a developing roller 42 having a surface layer made of aluminum was used. In addition, as a measuring method of Vickers hardness, the method prescribed | regulated to JISZ2244 can be used.
The Vickers hardness of the phosphor bronze used in this experiment is 80 [Hv]. If a metal blade having a hardness lower than this is used as the doctor blade 45, it is considered that the doctor blade 45 has an effect of suppressing sticking similarly to the doctor blade 45 using phosphor bronze in this experiment. Regarding the hardness, Vickers hardness is adopted in this experiment, but comparison may be made by a method of measuring Brinell hardness and Rockwell hardness according to the material and shape.

In Experiment 3, the doctor blades 45 made of the respective materials are arranged in the state shown in FIG. 29C, and a solid image is formed using the copying machine 500 of the first embodiment to check whether or not a streak image is generated. confirmed. As a result of Experiment 3, no streak image was generated when phosphor bronze was used as the material of the metal blade, and a streak image was generated when SUS was used.
Here, the doctor blade 45 used in Experiment 3 was confirmed. As a result, the toner was fixed to the SUS doctor blade 45 in which the streak image was generated, and the doctor blade made of phosphor bronze in which the streak image was not generated. In 45, toner adhesion was hardly confirmed.

  Such toner fixation is considered to occur as follows. That is, when a metal blade is used, the blade edge portion 45e slightly enters the concave portion 42b of the developing roller, and the rhombic convex portion 42a collides immediately thereafter. For this reason, the edge part 45e of a braid | blade is shaved in the location where the contact start part (diamond corner | angular part) of the convex part 42a contact | abuts, and it is easy to produce a micro dent. If the toner adheres to the concave portion thus formed, it cannot move from there, and the toner gradually accumulates. Since the accumulated toner continues to receive frictional heat between the blade and the developing roller in the vicinity, the toner is gradually melted and firmly fixed. When such sticking grows, a gap is formed between the blade and the developing roller, and the regulation becomes insufficient, resulting in a partial excess of the transport amount on the developing roller, resulting in streaks on the image. It is thought that I will let you.

FIG. 33 is a graph showing the results of measuring the amount of scraping of the doctor blade 45 with respect to the rotation time of the developing roller 42 for the doctor blade 45 of each material used in Experiment 3. A graph indicated by a broken line in FIG. 33 indicates a scraping amount when a SUS blade is used, and a graph indicated by a solid line is a scraping amount when a phosphor bronze blade is used.
It can be seen from FIG. 33 that phosphor bronze is easier to cut than SUS.
When the doctor blade 45 made of phosphor bronze is used, even if the toner is slightly fixed, the toner fixed together with the doctor blade 45 is scraped by sliding with the developing roller 42 before the toner fixing grows. . Therefore, it is considered that the sticking does not grow and the streak that causes a problem in the image does not occur.

When the blade is made of a relatively strong material such as SUS and the hardness of the surface layer portion (surface layer 42f) of the developing roller 42 is higher than the hardness of the contact portion of the doctor blade 45, the action of cutting the doctor blade 45 is achieved. As a result, the effect of facilitating the elimination of sticking occurs as described above.
Here, nickel plating or the like may be applied to increase the hardness of the surface layer of the developing roller 42. Further, even when the hardness of the surface layer of the developing roller 42 is increased, it is considered that phosphor bronze is more preferable for fixing toner because phosphor bronze is more easily scraped than stainless steel. Further, it is considered that a metal having a lower hardness than that of phosphor bronze (Vickers hardness of 80 [Hv] or less) has an effect of suppressing sticking.

As described in Experiment 3, as a configuration for preventing the generation of a streak image in the developing device 4 according to the first embodiment, the toner in the lightly fixed state is scraped off together with the doctor blade 45 by rubbing against the developing roller 42. . Therefore, it is necessary to cut the entire area of the doctor blade 45 in the width direction.
The developing roller 42 according to the first exemplary embodiment has the following characteristics in the width direction (direction perpendicular to the surface movement direction) on the surface of the groove forming portion 420a that is a surface carrying the toner supplied to the photoreceptor 2. That is, at any position in the width direction, one or more top surfaces 42t, which are the uppermost surfaces in the height direction of the convex portions 42a, exist at one or more places in the surface movement direction of the developing roller 42. It is a feature.

  As a configuration satisfying such a condition, the concave and convex shape on the surface at a position (such as the position of L11) of the developing roller 42 is such that convex portions 42a and concave portions 42b are arranged in a periodic row in the width direction. And the uneven | corrugated shape of the position (L12 position etc.) adjacent to the surface moving direction with respect to this position is set to an arrangement in which the regular arrangement of rows is shifted by a half cycle (see FIG. 13). In other words, the rows L12 and L14 adjacent to the row L11 and the row L13 in the rotation direction have a shape in which the period of the unevenness in the width direction is shifted by a half cycle. Further, the axial length W2 of the top surface 42t is formed to be not less than ½ of the pitch width W1. The surface shape is such that such a shape is repeated in the rotation direction of the developing roller 42.

  With such a configuration, in the doctor blade 45, when the position of L11 of the developing roller 42 is in contact with the position of the top surface 42t, the top surface 42t is in contact with the position of L12. With such a configuration, it is possible to realize a configuration in which the top surface 42t of the developing roller 42 is brought into contact once over the entire region in the width direction of the doctor blade 45 while the developing roller 42 makes one round. As described above, the top surface 42t is in contact with the developing roller 42 during one rotation regardless of the position of the doctor blade 45 in the width direction. Therefore, it is possible to efficiently scrape the doctor blade 45, and it is possible to more reliably prevent the occurrence of a streak image due to toner adhesion.

  In the configuration in which development is performed with the surface of the developing roller 42 in contact with the photosensitive member 2, the developing roller 42 and the photosensitive member 2 are both inelastic. And a portion where the developing roller 42 does not come into contact with each other. In that case, the toner is not developed only in the portion where the photosensitive member 2 and the developing roller 42 are not in contact with each other, and image loss occurs. In order to prevent this, in the developing device 4 of the first embodiment, the developing roller 42 is disposed so as to form a gap with respect to the photoreceptor 2, and the developing roller 42 is connected to the developing roller 42 by the developing bias power supply 142. A voltage in which is superimposed is applied. Accordingly, the latent image is developed by jumping the toner T from the developing roller 42 to the photosensitive member 2, and image loss can be prevented regardless of the accuracy of the position of the developing roller 42 with respect to the photosensitive member 2.

In addition, the copier 500 as the image forming apparatus according to the first exemplary embodiment includes a notification system that notifies the user of replacement of the developing device 4 that has reached a preset life depending on the driving state of the developing device 4. Also good.
FIG. 34 is a flowchart of a notification system that notifies the replacement of the developing device 4. FIG. 35 is an enlarged explanatory view of the doctor blade 45 and the developing roller 42 included in the developing device 4 whose replacement time is approaching.

  As shown in FIG. 34, the driving time of the developing device 4 is counted (S1), and if it is determined that a predetermined driving time has been reached (Y in S1), the developing device 4 is assumed to have reached the end of its life. The user is informed of replacement or that the developing device has reached the end of life (S3). Specifically, the notification is made via a notification device such as a lamp or a liquid crystal screen. Here, regarding the parameter for determining the life, the driving time of the developing roller 42, the number of sheets to be passed, the energizing time to the developing device, and the like can be considered.

  As shown in FIG. 35, the doctor blade 45 edge-contacted with the developing roller 42 provided in the developing device 4 of Embodiment 1 has a contact portion (a portion indicated by a broken line “45d” in FIG. 35) by the developing roller 42. It will be shaved. Here, it is desirable that the thickness of the doctor blade 45 is set so that the tip surface 45a remains when the replacement notification based on the service life is performed. That is, the thickness is set with a margin with respect to the parameter so that the tip face 45a remains even if the parameter for determining the lifetime reaches the lifetime. If the tip surface 45a disappears due to cutting, the contact position between the doctor blade 45 and the developing roller 42 may change thereafter. Further, the tip of the doctor blade 45 having an acute angle may bite into the developing roller 42. Therefore, it is desirable to replace the doctor blade 45 with the tip end surface 45a remaining.

The developing device 4 of Embodiment 1 carries a toner T, which is a non-magnetic or magnetic one-component developer, on the surface, and the surface moves endlessly. A developing roller 42 is provided as a developer carrying member for supplying the toner T to the latent image on the surface of the photosensitive member 2 and developing the latent image on the surface of the photosensitive member 2 in the developing region α facing the photosensitive member 2 serving as the latent image carrier. The developing device 4 is a plate-like member supported by a blade folder 45c, one end of which is a support member. The free end of the developing device 4 is in contact with the surface of the developing roller 42, and the amount of toner T toward the developing region α is measured. It has a doctor blade 45 which is a regulating member for regulating. Furthermore, the developing device 4 includes a concave portion 42 b and a convex portion 42 a that are concave and convex shapes on the surface of the developing roller 42. In such a developing device 4, the material of the doctor blade 45 that is a restricting member is made of metal, and an edge portion 45 e that is a free end side is in contact with the surface of the developing roller 42.
In the developing device 4, the material of the portion of the doctor blade 45 made of metal that contacts the developing roller 42 is preferably a material whose hardness is lower than that of the surface of the developing roller 42.

Next, feature points of the first embodiment will be described.
Due to the friction between the doctor blade 45 and the developing roller 42, the contact portion of the doctor blade 45 with the developing roller 42 generates heat. Therefore, when a low melting point toner or the like is used, there is a possibility that the toner is softened by the heat of the contact portion of the doctor blade 45 and is fixed to the doctor blade 45 or to the surface of the developing roller.
Therefore, in the first embodiment, as shown in FIG. 36, at least the contact portion of the doctor blade 45 with the developing roller 42 is covered with a material having a lower coefficient of dynamic friction with the developing roller 42 than the blade member 450. 450a. Specifically, at least a contact portion of the metal blade member 450 with the developing roller 42 was coated with a fluororesin to form a covering portion 450a. At this time, the dynamic friction force between the coated blade member 450 and the developing roller 42 is equal to or less than the dynamic friction force between the blade member made of phosphor bronze (or SUS) and the developing roller 42. As another example of the covering portion, low friction can be realized even if a DLC (diamond-like carbon) coating or a molybdenum coating is used.

  The formation range of the covering portion 450a may be only the contact portion with the developing roller 42, but may cover the entire blade member. In that case, processing becomes easier, and the component cost can be reduced. Further, the directionality of the parts is lost, and the assembling property to the pedestal portion 452 can be improved, so that the overall cost and the productivity of the parts are improved. Further, as shown in FIG. 36, it is desirable that the covering portion 450a is covered not only on the surface on the abutting portion side but also on at least the side surface and the back surface at the front end. By covering the tip of the blade member so as to wrap, the covering portion 450a can be firmly fixed to the blade member 450, and it is difficult to peel off even if it receives a frictional force with the developing roller 42. To improve. Further, the surface of the blade member 450 that is covered with the covering portion 450a is appropriately roughened. Thereby, while making a mutual contact area large, an adhesive force becomes strong because a mutual material meshes with an uneven surface. In particular, since the resistance force in the sliding direction with the developing roller 42 becomes strong, it is possible to prevent the covering portion 450a from being peeled off.

  As described above, at least a contact portion of the blade member 450 with the developing roller 42 is covered with a material having a lower dynamic friction coefficient with the developing roller 42 than the blade member 450, so that the friction between the blade member 450 and the developing roller 42 is achieved. Can be suppressed. Thereby, the temperature rise of the contact part with the developing roller 42 of the blade member 450 by frictional heat can be suppressed. Accordingly, it is possible to suppress the toner from being softened by the heat of the contact portion of the blade member 450 and being fixed to the blade member 450 and the developing roller 42.

Further, when the contact portion of the metal blade member 450 with the developing roller 42 is not covered, when the blade member 450 is in contact with the developing roller, a part of the scratch is burred (convex). If it becomes like a scratch, it will rub against the developing roller. This may cause scratches on the developing roller side.
On the other hand, by covering the contact portion of the blade member 450 with the developing roller 42 as in the first embodiment, it is possible to prevent the occurrence of burrs (convex scratches) as described above. There will be no scratches on the side. As a result, it is possible to prevent the damaged developing roller from damaging the inlet seal and the supply roller, which can greatly contribute to the extension of the unit life.

  Further, the covering portion 450a can be prevented from being scraped by making the covering portion 450a a material having a lower coefficient of dynamic friction with the developing roller than the blade member 450. However, if the thickness of the covering portion 450a is thin, the metal blade is exposed at an early stage and comes into contact with the developing roller 42, and the frictional heat suppressing effect by the covering portion 450a cannot be obtained over time. In the first embodiment, the thickness of the covering portion 450a is set to about 0.5 mm to 1.0 mm. However, when the covering portion 450a is made of a material that is more flexible than a metal such as fluororesin, the contact portion of the doctor blade 45 with the developing roller 42 becomes flexible. When the contact portion of the doctor blade 45 with the developing roller 42 becomes flexible, the blade edge portion 45e enters the concave portion 42b of the developing roller 42 and then collides with the convex portion 42a. However, by being elastically deformed, it is possible to prevent the edge portion 45e of the blade from being scraped at a location where the contact start portion (diamond corner) of the convex portion 42a abuts. However, there is a high possibility that the elasticity will bite into the recess 42b of the developing roller 42 and scrape out the toner in the recess 42b. As a result, the amount of toner transported by the developing roller 42 may not be stabilized. Furthermore, if the edge portion 45e has a shape close to a right angle as shown in FIG. 31 above, the corners are locally broken and are easily chipped, and a uniform thin layer cannot be formed.

  Therefore, in the first embodiment, as shown in FIG. 37, the edge portion 1450 of the covering portion 450a has an R shape (R chamfering). The size of R was set to about three times the developing roller convex pitch P. Thus, by making the edge part 1450 of the coating | coated part 450a into R shape, even if the recessed part 42b passes, it can be made to hardly affect the attitude | position of a braid | blade. Therefore, it is possible to prevent the edge portion 1450 of the covering portion 450 from irregularly entering the concave portion 42b, scraping out the toner in the concave portion 42b, and changing the amount of toner conveyed by the developing roller 42. Further, the edge portion 1450 of the covering portion 450 can be prevented from colliding with the convex portion 42a, the covering portion 450 can be prevented from being locally damaged locally, and the durability can be increased. it can. The R shape of the edge portion 1450 can be easily molded by resin insert molding or the like. In the first embodiment, the R of the edge portion 1450R is set to be three times the developing roller convex pitch P. However, if the R is set to be equal to or larger than the developing roller convex pitch P, the above effect can be obtained. Can do.

  In the first embodiment, the blade member 450 is a metal blade. Therefore, compared with the case where the blade member 450 is made of a resin such as rubber, the contact pressure with the developing roller 42 can be increased, and the toner T on the top surface 42t can be worn out well. Only the toner T buried in the concave-convex concave portion 42b can be conveyed. In addition, a stable contact pressure can be maintained over time, and the amount of toner transported by the developing roller 42 can be stabilized over time.

  Further, in the regulation system in which the doctor blade 45 is brought into contact with the developing roller 42 and the toner on the convex portion 42a passes through only the concave portion 42b, the toner on the convex portion 42a scraped off by the doctor blade 45 is as follows. Move. In other words, the toner on the convex portion 42 a scraped by the doctor blade 45 is pushed by the subsequent toner and moves in the direction away from the developing roller 42 along the tip surface 45 a of the blade member 450. Thereafter, the blade member 450 moves along a non-facing surface opposite to the facing surface 45b (see FIGS. 31 and 35) facing the developing roller 42 due to the influence of its own weight. Here, if the coefficient of dynamic friction between the blade member 450 and the toner is large, the movement of the toner moving along the non-facing surface of the blade member 450 may stop or become slow due to friction with the blade member 450. End up. As a result, toner stays in the vicinity of the front end surface 45 a of the blade member 450. The toner staying at the front end surface 45a of the blade member 450 is pressed against the front end surface 45a of the blade member 450 by the subsequent toner. As a result, the toner adheres to the front end surface 45 a of the blade member 450. In particular, when a low-melting-point toner that easily adheres to a member and has poor fluidity is used, the above sticking and aggregation are likely to occur.

  Therefore, as shown in FIG. 42, the portion of the blade member 450 that contacts the toner may be covered with a material having a lower coefficient of dynamic friction with the toner than the blade member 450. Specifically, a covering portion 450a made of the above material was formed on the non-facing surface 45f of the blade member 450, where the toner regulated by the doctor blade 45 of the blade member 450 rubs. Examples of the material having a lower coefficient of dynamic friction with the toner than the blade member 450 include PTFE (polytetrafluoroethylene). PTFE is a substance having a very small coefficient of dynamic friction with toner as will be described later. Therefore, by covering the non-facing surface 45f of the blade member 450 with PTFE, the toner regulated by the doctor blade 45 moves smoothly along the non-facing surface 45f of the blade member 450. Thereby, it is possible to suppress the toner from staying on the front end surface 45a of the blade member 450. Therefore, it is possible to suppress toner sticking to the front end surface 45a of the blade member 450. The material for covering the contact portion of the blade member 450 with the toner is not limited to PTFE, and other low friction coefficient materials can be used.

Next, Experiment 4 conducted by the present invention will be described.
[Experiment 4]
In Experiment 4, the material shown in Table 1 was coated on the portion of the blade member 450 that contacts the toner, the image was output, and the number of sheets until an abnormal image occurred was examined.

The friction coefficient μ shown in Table 1 is a dynamic friction coefficient with the toner, and was measured using an atomic force microscope.
The outline of the atomic force microscope and the method of measuring the dynamic friction coefficient using it will be described below.
There are many known documents (for example, Appl. Phys. Lett. 56, 1758 (1990)) regarding the principle of operation of an atomic force microscope (AFM). The following measurement can be performed by using a cantilever having a tip (probe tip, hereinafter also referred to as a tip) having a material surface such as silicon nitride or silicon dioxide at the tip and bringing the tip close to the surface of the measurement sample. . That is, the adhesion force (surface force) acting between the sample surfaces and the probe tip and the friction force between the sample and the cantilever. A typical AFM operating principle is to measure the cantilever warpage or deflection using the reflection of a photodiode, and connect it to feedback control as a signal. Specifically, the distance between the chip and the sample surface is feedback controlled by a piezo element.

  When measuring adhesion force or friction force using an atomic force microscope, the cantilever must be decorated. Specifically, the target powder is attached to the cantilever tip with an adhesive such as an epoxy resin. The attaching operation can be performed by using a dedicated device as described in JP-A-2002-62253 or by AFM.

The dynamic friction coefficient μ was calculated based on SII Nanotechnology Co., Ltd. Application Brief SPI no.37 “Quantitative Friction Characteristic Evaluation by Friction Curve I”. The measurement conditions are shown below.
・ Measurement conditions (frictional curve method):
Atomic force microscope (AFM): scanning probe microscope SPI4000, multifunctional unit SPA400 (manufactured by SII Nanotechnology)
・ Measurement mode: AFM mode
・ Cantilever: Silicon cantilever SI-DF20 manufactured by SII Nano Technology Co., Ltd., spring constant: 20 [N / m]
・ Scanning condition: 100000 [nm], reciprocating scan at 0.2Hz
-Load conditions: Set the target to be 0, 1500, 5000 [nN] of the pressing load between the cantilever tip and the sample surface.
-Toner particle size at the tip of the cantilever: 6 [μm]
・ Carrier type: Toner manufactured by Ricoh Co., Ltd.
・ Friction force calculation method: SII Nano Technology Co., Ltd. Application Brief SPI no.37 Calculated according to the contents of “Quantitative Friction Characteristics Evaluation I by Frictional Curve I” ・ Dynamic Friction Coefficient Calculation Method: Primary change of friction force against pressing load Calculation

When the dynamic friction coefficient of each coating material shown in Table 1 was measured by the above measurement method, the results shown in Table 1 were obtained.
Each coating material was coated on the non-facing surface 45f of the blade member 450 as shown in FIG.

FIG. 43 is a graph showing the number of images until a defect (white streak) appears in an image when image output is continuously performed. For image output, A4 paper was passed, and printing was performed with an area ratio of 5% on A4 paper.
As can be seen from FIG. 43, it can be seen that the number of durable sheets until a defect appears on the image differs depending on the coating material. Further, the defect in the image is a white streak, and when the white streak appears on the image, the blade member 450 was observed, and in all experiments, the toner was fixed to the front end surface 45a of the blade member 450. .

  The mechanism by which the white streaks are generated by the toner fixing to the tip of the blade member 450 is not yet known in detail, but it is considered that the white streaks have occurred for the following reason. That is, when the toner adheres to the front end surface 45a of the blade member 450, a minute convex portion is formed on the front end surface 45a of the blade member 450. The toner fixing part itself fixed to the front end surface 45a of the blade member 450 is very small. For this reason, the toner fixing portion slightly enters the concave portion 42b of the concave portion 42b after passing through the convex portion 42a of the developing roller 42, and pushes the toner in the concave portion 42b to the surroundings. Specifically, it is swept in the left-right direction along a portion (42c in FIG. 13) on the downstream side in the surface movement direction of the developing roller 42 in the convex portion 42a. As a result, the toner amount in the recess 42b after passing through the sticking occurrence portion of the blade member 450 is smaller than the surrounding area. Therefore, it is considered that toner is insufficient (development capability is reduced) in the development area at the toner fixing portion, the color is lost, and white stripes are formed.

  As shown in FIG. 43, the doctor blades of Experiment No. 1 to No. 4 coated with a coating material having a lower coefficient of dynamic friction with the toner than the blade member 450 have a higher image quality than the doctor blade of Experiment No. 5 not coated with the coating material. There are many output sheets until white streaks are confirmed. As a result, it was found that toner adhesion can be suppressed by coating with a coating material having a lower dynamic friction coefficient with the toner than the blade member 450 compared to the case of not coating.

FIG. 44 is a graph showing the result of FIG. 43 in relation to the dynamic friction coefficient μ and the number of output sheets.
As can be seen from FIG. 44, by coating with a material having a dynamic friction coefficient of 0.4 or less, a stable image could be obtained even after outputting 25k sheets.

  As shown in FIG. 42, the covering portion 450a is formed only on the non-facing surface 45f of the blade member, but the covering portion 450a may also be formed on the tip surface 45a that is a contact portion with the toner. With this configuration, the toner pressed against the front end surface 45a by the subsequent toner can easily move away from the developing roller 42. As a result, toner adhesion to the blade member front end surface can be suppressed. In this case, the entire blade member may be covered. This facilitates processing, reduces component costs, eliminates component orientation, and improves assembly to the pedestal 452, which is preferable. Accordingly, the contact portion with the developing roller can also be covered with a low friction material, and generation of heat due to friction with the developing roller can be suppressed.

  Further, the non-opposing surface 45f covered with the covering portion 450a of the blade member 450 may be appropriately roughened to increase the adhesive force.

In FIG. 45, the doctor blade 45 is installed with the tip of the doctor blade 45 inclined toward the toner accommodating portion 43 side with respect to the direction of gravity (the vertical direction in the figure).
In the developing device shown in FIG. 45, the doctor blade 45 is installed at an angle of θ with respect to the direction of gravity so that the tip of the doctor blade 45 is positioned closer to the toner accommodating portion 43 than the other portions. . By installing in this way, the weight of the toner regulated by the doctor blade 45 acts in a direction away from the non-facing surface 45f of the blade member 450. As a result, the pressure of the toner blade member 450 against the non-facing surface 45f is reduced, and the frictional force is reduced. Thereby, toner retention due to the non-facing surface 45f of the blade member 450 can be suppressed.

  It is also preferable to rotate the paddle 46 in the direction of the arrow P shown in the figure. By rotating the paddle 46 in such a direction, the direction of toner circulation in the toner accommodating portion 43 is changed from the front end of the doctor blade 45 to the root direction. Therefore, the toner is likely to flow along the non-facing surface 45f of the blade member 450 that is regulated by the doctor blade 45. As a result, toner retention near the front end surface of the blade member can be suppressed, and toner adhesion to the front end surface 45a can be suppressed.

[Embodiment 2]
Hereinafter, a second embodiment (hereinafter referred to as a second embodiment) of the present invention in which the present invention is applied to a printer (hereinafter referred to as a printer 600) as an image forming apparatus will be described.
FIG. 38 is a schematic cross-sectional view of a main part of the printer 600 according to the second embodiment. As shown in FIG. 38, the printer 600 includes a process cartridge 1 as four process units. Further, an intermediate transfer belt 7 as an intermediate transfer member that is stretched by a plurality of stretching rollers and moves in the direction of arrow A in FIG. 36, an exposure device 6 as an exposure unit, a fixing device 12 as a fixing unit, and the like. It has.

  Each process cartridge 1 includes a drum-shaped photoreceptor 2 as a latent image carrier, a charging member 3 as a charging unit, and a developing device 4 that develops a latent image on the photoreceptor 2 using toner T as a developer. It has. The photoconductor cleaning device 5 is also provided, and is configured to be integrally supported and unitized. Each process cartridge 1 can be attached to and detached from the printer 600 main body by releasing a stopper (not shown).

  The photoconductor 2 rotates in the clockwise direction in the figure as indicated by the arrow in the figure. The charging member 3 is a roller-shaped charging roller, is in pressure contact with the surface of the photoconductor 2, and is rotated by the rotation of the photoconductor 2. At the time of image formation, a predetermined bias is applied to the charging member 3 by a high voltage power source (not shown) to charge the surface of the photoreceptor 2. In the process cartridge 1 of the second embodiment, the roller-shaped charging member 3 that contacts the surface of the photoreceptor 2 is used as the charging unit. However, the charging unit is not limited to this, and non-contact such as corona charging. A charging method may be used.

  The exposure device 6 exposes the surface of the photoreceptor 2 based on image information, and forms an electrostatic latent image on the surface of the photoreceptor 2. The exposure apparatus 6 provided in the printer 600 uses a laser beam scanner system using a laser diode, but other configurations such as an exposure unit using an LED array may be used.

  The photoconductor cleaning device 5 cleans the transfer residual toner remaining on the surface of the photoconductor 2 that has passed the position facing the intermediate transfer belt 7.

  The four process cartridges 1 form toner images for the respective colors of yellow, cyan, magenta, and black on the photoreceptor 2. The four process cartridges 1 are arranged in parallel in the surface movement direction of the intermediate transfer belt 7 and transfer the toner images formed on the respective photoreceptors 2 in order to be superimposed on the intermediate transfer belt 7 in order. A visible image is formed on the belt 7.

  In FIG. 38, a primary transfer roller 8 serving as a primary transfer unit is disposed at a position facing each photoconductor 2 with the intermediate transfer belt 7 interposed therebetween. The primary transfer roller 8 is driven by a high voltage power source (not shown). A primary transfer bias is applied to form a primary transfer electric field with the photoreceptor 2. By forming a primary transfer electric field between the photosensitive member 2 and the primary transfer roller 8, the toner image formed on the surface of the photosensitive member 2 is transferred to the surface of the intermediate transfer belt 7. One of a plurality of stretching rollers that stretch the intermediate transfer belt 7 is rotated by a drive motor (not shown), so that the intermediate transfer belt 7 moves in the direction of arrow A in the figure. A full color image is formed on the surface of the intermediate transfer belt 7 by sequentially transferring the toner images of the respective colors on the surface of the intermediate transfer belt 7 moving on the surface.

  A secondary transfer nip is formed on the downstream side of the surface of the intermediate transfer belt 7 with respect to the position where the four process cartridges 1 face the intermediate transfer belt 7. The secondary transfer nip is formed by the secondary transfer roller 9 at a position facing the secondary transfer counter roller 9a, which is one of the stretching rollers, with the intermediate transfer belt 7 interposed therebetween. The transfer paper P, which is a transfer material conveyed in the direction of arrow B in FIG. 38, passes through the secondary transfer nip. At this time, the full-color image formed on the surface of the intermediate transfer belt 7 is transferred by the secondary transfer electric field formed by applying a predetermined voltage between the secondary transfer roller 9 and the secondary transfer counter roller 9a. Transferred to paper P.

  A fixing device 12 is disposed downstream of the secondary transfer nip in the conveyance direction of the transfer paper P. The transfer paper P that has passed through the secondary transfer nip reaches the fixing device 12, the full color image transferred onto the transfer paper P is fixed by heating and pressurization in the fixing device 12, and the transfer paper P on which the image is fixed is The data is output outside the printer 600.

  On the other hand, the toner T remaining on the surface of the intermediate transfer belt 7 without being transferred to the transfer paper P at the secondary transfer nip is collected by the transfer belt cleaning device 11.

  Next, the developing device 4 provided in the process cartridge 1 will be described with reference to FIGS. 39 and 40 are enlarged cross-sectional views of one of the four process cartridges 1. FIG. 39 is a cross-sectional view in the vicinity of the central portion in the axial direction of the developing roller 42. FIG. 40 is in the vicinity of the end portion in the axial direction. It is sectional drawing in the position where the side seal 59 of this is arrange | positioned. 41 is a cross-sectional explanatory view of the developing device 4 in the vicinity of the rotation shafts of the toner conveying member 106, the toner agitating member 108, and the supply roller 44 that are arranged substantially linearly in the vertical direction. .

  The developing device 4 includes a toner storage chamber 101 that stores toner T, which is a developer, and a toner supply chamber 102 provided below the toner storage chamber 101. The toner storage chamber 101 and the toner supply chamber 102 are separated from each other. A partition member 110 is provided so as to partition. As shown in FIG. 41, the partition member 110 is provided with a plurality of openings. As a plurality of openings of the partition member 110, a supply port 111 that supplies the toner T in the toner storage chamber 101 to the toner supply chamber 102 and a return port 107 that returns the toner T in the toner supply chamber 102 to the toner storage chamber 101. And are provided.

  Below the toner supply chamber 102, a developing roller 42 as a developer carrier is provided. In the toner supply chamber 102, a supply roller 44, which is a developer supply member that supplies toner T to the surface of the developing roller 42, is provided in contact with the surface of the developing roller 42. Further, the toner supply chamber 102 is supplied onto the surface of the developing roller 42 by a supply roller 44. A doctor blade 45 as a regulating member that regulates the amount (layer thickness) of the toner T toward the facing portion between the photoreceptor 2 and the developing roller 42 is provided in contact with the surface of the developing roller 42.

  The developing roller 42 is disposed in a non-contact manner with respect to the photoreceptor 2 and is applied with a predetermined bias from a high voltage power source (not shown).

  A toner conveying member 106 that conveys the toner T in the toner accommodating chamber 101 in a direction parallel to the rotation axis of the photosensitive member 2 (a direction orthogonal to the paper surface in FIG. 39) is provided in the toner accommodating chamber 101.

  Further, as the toner T stored in the toner storage chamber 101, a toner prepared by a polymerization method is used. The toner T is, for example, a toner T having an average particle diameter of 6.5 [μm], a circularity of 0.98, an angle of repose of 33 [°], and strontium titanate as an external additive. The toner T used in the printer 600 according to the second embodiment is not limited to this.

  As shown in FIG. 41, the toner conveying member 106 provided in the toner storage chamber 101 is a member having a rotating shaft in which a conveying screw shape portion 106a and a conveying plate shape portion 106b are combined. The toner conveying member 106 is configured to convey the toner T in the toner storage chamber 101 in a substantially horizontal direction (in the direction of arrow H in FIG. 41) parallel to the rotation axis of the toner conveying member 106 by the rotation operation of the conveying screw shape portion 106a. It has become. The developing device 4 includes a conveyance screw shape portion 106 a that conveys the toner T in a direction parallel to the rotation axis of the toner conveyance member 106. However, the developer conveying member is not limited to this, and a developer having a conveying function such as a conveying belt or a coiled rotating body can be used. Furthermore, what has these conveyance functions and what has a loosening function, such as a paddle formed by bending a plate member such as a blade or a wire, may be combined.

  In the developing device 4 according to the second embodiment, the toner T is transported from the toner storage chamber 101 toward the supply roller 44 in a direction perpendicular to the rotation axis of the toner transport member 106 and substantially vertically downward. It has become. The toner T may be transported in a substantially horizontal direction perpendicular to the rotation axis of the toner transport member 106 as the transport direction of the toner T.

  A toner stirring member 108 is disposed in the toner supply chamber 102 vertically below the partition member 110. As shown in FIG. 41, the toner agitating member 108 is a member having a rotating shaft in which an agitating screw shape portion 108a and an agitating plate shape portion 108b are combined. The toner agitating member 108 conveys the toner T in the toner supply chamber 102 in a substantially horizontal direction (in the direction of arrow I or J in FIG. 41) parallel to the rotation axis of the toner agitating member 108 by the rotation operation of the agitating screw shape portion 108a. It can be configured.

  As shown in FIG. 41, the agitating screw-shaped portion 108a of the toner agitating member 108 spirals so as to convey the toner T in the direction toward the outside (the direction of arrow I in FIG. 41) across the supply port 111 in the axial direction. Shaped wings are provided. Further, the stirring screw-shaped portion 108a of the toner stirring member 108 has spiral wings on the outside and inside of the two return ports 107 in the axial direction. For this reason, the toner T supplied from the supply port 111 to the toner supply chamber 102 is conveyed outward in the axial direction (in the direction of arrow I) by the rotation of the stirring screw shape portion 108a of the toner stirring member 108. In addition, the toner T that has reached the outside of the return port 107 is conveyed toward the return port 107 (in the direction of arrow J) by the stirring screw-shaped portion 108a whose wings are reversely wound. The conveying direction of the toner T by the stirring screw-shaped portion 108 a is opposite between the outside and the inside in the axial direction across the return port 107, and a conveying force is applied to the toner T toward the return port 107. Therefore, the toner T is collected from both sides in the axial direction below the return port 107 and pushed up in a mountain shape. As a result, when the amount of toner T supplied from the toner storage chamber 101 through the supply port 111 or the return port 107 to the toner supply chamber 102 is excessive, the toner T pushed up in the mountain shape by the return port 107 becomes the toner. The toner is returned from the supply chamber 102 to the toner storage chamber 101 through the return port 107. The toner agitating member 108 has a role of agitating the toner T in the toner supply chamber 102 and further supplying the toner T to the supply roller 44 and the developing roller 42 below.

The surface of the supply roller 44 is covered with a foam material having a structure having pores (cells), and the toner T supplied to the toner supply chamber 102 is efficiently attached and taken in, and the surface of the supply roller 44 is connected to the developing roller 42. Deterioration of the toner T due to pressure concentration at the contact portion is prevented. In addition, this foaming material is set to an electrical resistance value of 10 ³ to 10 ¹⁴ [Ω]. A supply bias is applied to the supply roller 44 and assists the operation of pressing the toner T preliminarily charged at the supply nip β in contact with the development roller 42 against the development roller 42. The supply roller 44 rotates in the counterclockwise direction in FIG. 39 as indicated by an arrow in FIG. 39 and supplies the toner T adhered to the surface so as to be applied to the surface of the developing roller 42.

  A doctor blade 45 as a regulating member is disposed so as to come into contact with the surface of the developing roller 42 on the downstream side in the surface movement direction of the developing roller 42 with respect to the supply nip β. The toner T supplied from the supply roller 44 to the surface of the developing roller 42 is conveyed to a position where the doctor blade 45 contacts with the rotation of the developing roller 42.

  As the doctor blade 45, a metal leaf spring material such as SUS304CSP, SUS301CSP, or phosphor bronze can be used. The free end is brought into contact with the surface of the developing roller 42 with a pressing force of 10 to 100 [N / m]. By passing the toner T on the developing roller 42 under the pressing force, the toner layer is thinned and a charge is applied to the toner T by frictional charging. In addition, a bias is applied to the doctor blade 45 by a bias power source (not shown) in order to assist the frictional charging of the toner T.

  The photoreceptor 2 is not in contact with the developing roller 42 and rotates in the clockwise direction in FIG. For this reason, in the developing region α where the developing roller 42 and the photosensitive member 2 face each other, the surface moving direction of the developing roller 42 and the surface moving direction of the photosensitive member 2 are the same direction.

  The thinned toner layer on the developing roller 42 is conveyed to the developing area α by the rotation of the developing roller 42. Then, in accordance with the bias applied to the developing roller 42 and the latent image electric field formed by the electrostatic latent image on the photosensitive member 2, it moves to the surface of the photosensitive member 2 and the electrostatic latent image on the surface of the photosensitive member 2. The image is developed.

  A discharge neutralization seal 109 as a lower seal member, which is a developer neutralization member, is developed at a location where the toner T that is not used for development in the development region α and remains on the developing roller 42 returns to the toner supply chamber 102 again. It is provided in contact with the roller 42. Accordingly, the toner T is sealed so as not to leak out of the developing device 4. A bias is applied to the static elimination seal 109 from a bias power source (not shown) to assist the static elimination capability.

  In the developing device 4 described above, the development of the latent image on the photoreceptor 2 using the toner T on the developing roller 42 is performed as follows. The toner T supplied onto the surface of the developing roller 42 at the supply nip β is conveyed from the supply nip β toward the developing region α as the developing roller 42 rotates, and passes through a doctor blade 45 in the middle thereof. , Regulated to a predetermined amount. The toner T restricted to a predetermined amount is further transported to the developing area α, and the electrostatic latent image on the surface of the photosensitive member 2 is developed by the developing electric field between the developing roller 42 and the electrostatic latent image on the photosensitive member 2. It adheres to the image area and is developed. For the developing electric field, an AC bias is used such that a voltage in which the toner is directed toward the photosensitive member 2 and a voltage in which the toner returns to the developing roller 42 are alternately repeated. In the second embodiment, a rectangular wave with f = 500 to 10000 [Hz], Vpp = 500 to 3000 [V], and Duty = 50 to 90 [%] was used. Thereafter, the toner T that has not contributed to the development is further conveyed by the rotation of the developing roller 42, and the toner T returns to the toner supply chamber 102 and is repeatedly used.

  In the developing device 4 according to the second embodiment, the configuration including the developing roller 42 and the doctor blade 45 described in the first embodiment and the features of the present invention can be applied. That is, the contact portion of the doctor blade 45 with the developing roller 42 is covered with a material having a lower dynamic friction coefficient than a base material made of a metal plate spring material such as SUS304CSP, SUS301CSP, or phosphor bronze.

What has been described above is an example, and the present invention has a specific effect for each of the following aspects.
(Aspect 1)
A developer carrying member such as a developing roller 42 that carries a developer such as toner on its surface on which the concave portion 42b and the convex portion 42a are formed, and a developing position facing a latent image carrier such as a photosensitive member; In the developing device 4 having a regulating member such as a doctor blade 45 that abuts the developer carrying member and regulates the amount of the developer conveyed to the developing position, the abutting portion of the regulating member with the developer carrying member And / or the part of the regulating member that contacts the developer is coated with a material having a higher slidability than the regulating member.
With this configuration, as described in the embodiment, the developer adheres to the regulating member such as the doctor blade 45 due to frictional heat or the retention of the developer such as toner, or the developer carrying such as the developing roller 42. It can suppress sticking to the body surface.

(Aspect 2)
Further, in the developing device described in (Aspect 1), the contact portion of the regulating member such as the doctor blade 45 with the developer carrying member such as the developing roller 42 may have a coefficient of dynamic friction with the developer carrying member rather than the regulating member. Covered with low material.
With such a configuration, friction between the regulating member such as the doctor blade 45 and the developer such as toner and friction between the developer carrying member and the regulating member can be reduced, and temperature rise due to friction of the regulating member is suppressed. can do. Thereby, it can suppress that a developing agent adheres to a regulating member or a developer carrier.

(Aspect 3)
Further, in the developing device described in (Aspect 2), the front ends of the regulating members such as the doctor blade 45 are covered with a material having a low dynamic friction coefficient.
With such a configuration, as described in the embodiment, the covering portion 450a made of a material having a low dynamic friction coefficient can be firmly fixed to the doctor blade 45, and is peeled off even when receiving a frictional force with the developing roller 42. It becomes difficult and durability can be improved dramatically.

(Aspect 4)
In the developing device according to any one of (Aspect 1) to (Aspect 3), the edge portion of the covering portion covered with a material having a low dynamic friction coefficient is formed in an R shape.
By adopting such a configuration, as described in the embodiment, even when a material softer than metal is used as a material having a low dynamic friction coefficient, the edge portion of the covering portion can be prevented from entering the recess. it can.

(Aspect 5)
In the developing device described in (Aspect 4), the uneven shape on the surface in the surface movement direction of the developer carrying member in the cross section perpendicular to the axial direction of the developer carrying member such as the developing roller 42 is the above-described convex shape. As described in the embodiment, the portion 42a and the concave portion 42b are arranged in a periodic row, and the R shape R of the covering portion is set to be equal to or longer than one pitch of the convex portion. Thus, it can suppress favorably that the edge part 1450 of a coating | coated part enters a recessed part.

(Aspect 6)
(Aspect 1) to (Aspect 5) In any one of the development apparatuses, a portion of the regulating member such as the doctor blade 45 that contacts the developer such as toner is covered with a material having a lower coefficient of dynamic friction with the developer than the regulating member. did.
By providing such a configuration, as described in the embodiment, it is possible to prevent the developer such as toner from staying in the vicinity of the tip of the regulating member such as the doctor blade 45, and the developer to the regulating member can be prevented. Sticking can be suppressed.

(Aspect 7)
In the developing device of (Aspect 6), a portion of the regulating member such as the doctor blade 45 that contacts the developer such as toner is covered with a material having a coefficient of dynamic friction with the developer of 0.4 or less.
With this configuration, as described in Experiment 4, it is possible to suppress the occurrence of white stripes over time.

(Aspect 8)
In the developing device according to (Aspect 6) or (Aspect 7), the regulating member is arranged so that the moving direction of the developer such as toner regulated by the regulating member such as the doctor blade 45 by its own weight is away from the regulating member. Arranged.
With such a configuration, as described with reference to FIG. 45, it is possible to suppress the retention of developer such as toner.

(Aspect 9)
Further, in any of the developing devices of (Aspect 6) to (Aspect 8), the regulating member such as the doctor blade 45 constitutes a part of the wall surface, and the developer such as the toner accommodating portion 43 that accommodates the developer such as toner. And a stirrer such as a paddle 46 that stirs the developer in the developer container. The stirrer moves the developer in the developer container from the front end of the regulating member toward the root. To stir.
With this configuration, as described with reference to FIG. 45, the developer such as toner regulated by a regulating member such as the doctor blade 45 can easily flow, and the retention of the developer is suppressed. Can do.

(Aspect 10)
In the developing device according to any one of (Aspect 1) to (Aspect 9), the entire regulating member such as the doctor blade 45 is covered with a material having a higher slidability than the regulating member.
By providing such a configuration, as described in the embodiment, the overall cost and the productivity of parts can be improved.

(Aspect 11)
Further, in the developing device according to any one of (Aspect 1) to (Aspect 10), the surface of the portion covered with a material having a higher slidability than the restriction member of the restriction member such as the doctor blade 45 is roughened.
By providing such a configuration, as described in the embodiment, peeling of the covering portion 450a can be prevented.

(Aspect 12)
In an image forming apparatus having a latent image carrier such as a photosensitive member 2 that carries a latent image and a developing unit such as a developing device 4 that develops the latent image on the latent image carrier, Any one of the developing devices described in Aspect 1) to (Aspect 11) is used.
With such a configuration, a good image can be formed as described in the embodiment.

(Aspect 13)
In addition, the image forming apparatus includes a latent image carrier such as the photosensitive member 1 that carries a latent image, and a developing device 4 that develops the latent image carried on the surface of the latent image carrier. In the process unit that is integrally attached to and detached from the image forming apparatus main body while the latent image carrier is held by a common holding body, the developing device according to any one of (Aspect 1) to (Aspect 11) is used as a developing device. A process unit characterized by using an apparatus.
With this configuration, as described in the above embodiment, the latent image carrier and the developing device can be detached from the apparatus main body, and the developing device can be easily replaced.

DESCRIPTION OF SYMBOLS 1 Process cartridge 2 Photoconductor 3 Charging member 4 Developing device 6 Exposure device 7 Intermediate transfer belt 12 Fixing device 41 Developing casing 42 Developing roller 42a Convex portion 42b Concave portion 42g Base material 42f Surface layer 42t Top surface 44 Supply roller 45 Surface 45e Edge portion 45b Opposing surface 45c Blade folder 100 Printer portion 142 Development bias power supply 200 Paper feed portion 300 Scanner portion 450 Blade member 450a Cover portion 500 Copier 600 Printer 1450 Cover portion edge portion L1 First groove L2 Second groove P Transfer paper Q Contact position Q1 Initial contact position T Toner W1 Pitch width W2 Axial length

JP 2007-178901 A JP 2007-121951 A

Claims (13)

A developer carrier that carries the developer on its surface where the concave and convex portions are formed, and conveys the developer to a development position for developing the latent image;
A developing device having a regulating member that contacts the surface of the developer carrying member and regulates the amount of the developer conveyed to the developing position;
A development characterized in that a contact portion of the restriction member with the developer carrying member and / or a portion of the restriction member that contacts the developer is covered with a material having a higher sliding property than the restriction member. apparatus. The developing device according to claim 1.
The developing device according to claim 1, wherein a contact portion of the regulating member with the developer carrying member is covered with a material having a lower coefficient of dynamic friction with the developer carrying member than the regulating member. The developing device according to claim 2.
A developing device characterized in that the front end of the regulating member is covered with a material having a low dynamic friction coefficient. The developing device according to claim 2 or 3,
The developing device according to claim 1, wherein an edge portion of the covering portion covered with the material having a low dynamic friction coefficient is formed in an R shape. The developing device according to claim 4.
In a cross section orthogonal to the developer carrier axis direction,
The uneven shape on the surface in the surface movement direction of the developer carrier is such that the convex portions and the concave portions are arranged in a periodic row,
A developing device characterized in that the R-shape R of the covering portion is equal to or greater than the length of one pitch of the convex portion. The developing device according to any one of claims 1 to 5,
A developing device, wherein a portion of the regulating member that contacts the developer is covered with a material having a lower coefficient of dynamic friction with the developer than the regulating member. The developing device according to claim 6.
The developing device, wherein a portion of the regulating member that contacts the developer is coated with a material having a coefficient of dynamic friction with the developer of 0.4 or less. The developing device according to claim 6 or 7,
The developing device, wherein the regulating member is arranged such that a moving direction of the developer regulated by the regulating member under its own weight is a direction away from the regulating member. The developing device according to any one of claims 6 to 8,
The regulating member constitutes a part of a wall surface, and a developer accommodating portion for accommodating the developer;
A stirring member for stirring the developer in the developing container,
The developing device, wherein the agitating member agitates the developer in the developing container so that the developer moves from the tip of the regulating member toward the root. The developing device according to any one of claims 1 to 9,
A developing device characterized in that the entire regulating member is covered with a material having a higher slidability than the regulating member. The developing device according to any one of claims 1 to 10,
A developing device characterized in that a surface of a portion of the regulating member that is covered with a material having a higher slidability than the regulating member is roughened. A latent image carrier for carrying a latent image;
In an image forming apparatus having a developing unit for developing a latent image on the latent image carrier,
An image forming apparatus using the developing device according to claim 1 as the developing means. The image forming apparatus includes a latent image carrier that carries a latent image and a developing device that develops the latent image carried on the surface of the latent image carrier. In a process unit that is integrally attached to and detached from the image forming apparatus main body while being held by a common holder,
A process unit using the developing device according to claim 1 as the developing device.

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