JP2014062735A - Decontamination method for buildings, soil, or plants contaminated with radioactive materials - Google Patents

Decontamination method for buildings, soil, or plants contaminated with radioactive materials Download PDF

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JP2014062735A
JP2014062735A JP2012147498A JP2012147498A JP2014062735A JP 2014062735 A JP2014062735 A JP 2014062735A JP 2012147498 A JP2012147498 A JP 2012147498A JP 2012147498 A JP2012147498 A JP 2012147498A JP 2014062735 A JP2014062735 A JP 2014062735A
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Hiroshi Fujii
洋 藤井
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PROBLEM TO BE SOLVED: To provide a decontamination method for buildings, plants, or soil that prevents radioactive materials from spreading peripherally, since a water jet, which is being considered to be used for decontamination of buildings in a wide area contaminated with radioactive materials generated by Fukushima Daiichi Nuclear Power Plant severely damaged by the Great East Japan Earthquake, has a risk of further spreading of radioactive materials.SOLUTION: When decontamination is conducted for buildings, plants, or soil, the following steps are carried out sequentially: a first step in which spray coating of a washing agent is applied to surfaces of buildings or the like to let it reach every corner of them without allowing it to spread peripherally; a second step in which the applied washing agent is removed to clean the buildings or the like; and a third step in which the removed washing agent mixed with radioactive materials is treated as radioactive waste. Thus, decontamination of the buildings or the like can be carried out easily at low cost without spreading of the radioactive materials in their circumference environment.

Description

本発明は、放射性物質に汚染された建築物、土壌、又は樹木や草花等の植物から放射性物質を周辺に飛散させることなく除去する方法に関する。   The present invention relates to a method for removing radioactive substances from buildings, soil, or plants such as trees and flowers contaminated with radioactive substances without scattering them around.

2011年3月11日の東日本大震災で破壊された福島第一原子力発電所原子炉の水素爆発や火災等の事故により、放射性物質が飛散し周辺の広範な地域が放射性物質に汚染された。その後半年以上経った現在、除染作業がクローズアップされており、その除染方法としてウォータージェットによる除染作業が行われている。しかし、ウォータージェットによる洗浄はその建物・施設は除染されても、放射性物質を隣家、大気中、周辺地域、あるいは側溝ひいては下水処理場へとさらに広範囲に拡散させる恐れがある。   The Fukushima Daiichi Nuclear Power Station reactor was destroyed by the Great East Japan Earthquake on March 11, 2011, and the radioactive material was scattered and the surrounding area was contaminated with radioactive material. More than half a year later, decontamination work is now close-up, and decontamination work using a water jet is performed as a decontamination method. However, cleaning with water jets may disperse radioactive materials more extensively to neighbors, the atmosphere, surrounding areas, or side trenches and even sewage treatment plants, even if the building or facility is decontaminated.

しかしながら、我が国においては、これまで原子力発電所の事故により放射性物質が発電所の施設外に飛散した経験がないため、建築物等に付着・堆積した放射性物質を周囲に飛散させることなく安全に除去する方法が提示されていないのが現状である。   However, in Japan, there is no experience of radioactive materials scattered outside the power plant facilities due to accidents at nuclear power plants so far, so that radioactive materials adhering to and deposited on buildings etc. can be safely removed without scattering to the surroundings. At present, no method has been presented.

本発明は、上に述べた状況において、建物、施設、工作物等の建築物等に付着・堆積した放射性物質を、周囲に飛散させることなく安全に除去する方法を提供することを目的とするものである。   An object of the present invention is to provide a method for safely removing radioactive substances adhering to and accumulating on buildings such as buildings, facilities and structures in the above-described situation without scattering them around. Is.

ウォータージェットにより除染する場合でも、建築物等の周りを養生シート等で覆い、前記建築物等を周囲から完全に隔離して実施すれば、放射性物質を近隣に飛散させる恐れは格段に小さくなる。しかし、これを実施するには莫大な費用と手間がかかり現実的ではない。本発明のもう一つの目的は、建築物等を隔離養生することなく、安価で手間のかからない建築物等の除染方法を提供することにある。   Even when decontaminating with a water jet, if the surroundings of the building are covered with a curing sheet, etc., and the building is completely isolated from the surroundings, the risk of scattering radioactive materials in the vicinity is greatly reduced. . However, implementing this is enormous and time consuming and not realistic. Another object of the present invention is to provide a decontamination method for buildings and the like that is inexpensive and hassle-free without isolating and curing the buildings and the like.

本発明は上記目的を達成するために、放射性物質に汚染された建築物の除染を行う際に、該建築物の表面に洗浄剤を周囲に飛散させずに吹き付け塗布し、隅々に隈なくいきわたらせる第一の工程、塗布された洗浄剤を除去し、クリーニングする第二の工程及び除去した放射性物質と洗浄剤との混合物を放射性廃棄物として処理する第三の工程、を順次実施するものである。   In order to achieve the above-mentioned object, the present invention, when decontaminating a building contaminated with radioactive substances, sprays the surface of the building without spraying it around the surface of the building and sprays it on every corner. The first step to disperse, the second step to remove and clean the applied cleaning agent, and the third step to treat the mixture of removed radioactive material and cleaning agent as radioactive waste, are carried out sequentially To do.

第一の工程は、放射性物質を周囲に飛散させる恐れのある最も危険な工程である。この工程において放射性物質を周囲に飛散させないためには、エアレス吹付け機を用いるのが好ましい。さらに、その吐出圧力は0.5MPa以下、好ましくは0.3MPa以下で洗浄剤を噴霧するのが好適である。吐出圧力が0.3MPaを超えると洗浄剤が周囲に飛び散る傾向が現れ、0.5MPaを超えるとその傾向が顕著になる。   The first step is the most dangerous step that may scatter radioactive materials around. In this step, it is preferable to use an airless sprayer so that radioactive materials are not scattered around. Further, it is suitable to spray the cleaning agent at a discharge pressure of 0.5 MPa or less, preferably 0.3 MPa or less. When the discharge pressure exceeds 0.3 MPa, the tendency of the cleaning agent to scatter appears around, and when the discharge pressure exceeds 0.5 MPa, the tendency becomes remarkable.

洗浄剤の塗布量については、廃棄物の量を最少にするため、また洗浄剤のたれ落ちを防止するためにはできるだけ少ない方がよいが、少なすぎれば除染の効果がなくなる。目安としては0.1〜2kg/mが好ましいが、最適な塗布量は対象となる建築物表面の材質、表面状態等によって異なるので、本発明はこの数値に限定されるものではない。 The amount of the cleaning agent applied is preferably as small as possible in order to minimize the amount of waste and to prevent the cleaning agent from falling off, but if it is too small, the effect of decontamination is lost. As a guideline, 0.1 to 2 kg / m 2 is preferable, but the optimum coating amount varies depending on the material, surface state, etc. of the target building surface, and the present invention is not limited to this value.

洗浄剤塗布後、エアー吹き、はけ塗り、洗浄剤の追加噴霧等を適宜行うことにより、建築物の凹凸部、隅角部、開口部廻り、桟・横桁の上、軒天廻り等建築物の隅々にまで隈なく洗浄剤をいきわたらせる。   After the cleaning agent is applied, air blowing, brushing, additional spraying of the cleaning agent, etc. are performed as appropriate so that buildings such as uneven parts, corners, openings around buildings, tops of crosspieces, cross beams, and eaves Disperse the cleaning agent in every corner of the object.

第二の工程は、これが適切であるかどうかにより、除染作業の能率、周辺への放射性物質の飛散の有無、除染の結果が左右される点で非常に重要な工程である。本発明においては、建築物に塗布された洗浄剤と洗浄剤に捕捉された放射性物質を、耐水性掃除機を用いて吸引除去する。耐水性掃除機は、乾いたごみも湿ったゴミも水も1台で吸引するタイプの掃除機であり、また水で洗浄しながら廃水を吸引しそれを循環使用するタイプの水循環式掃除機も含まれる。   The second step is a very important step in that the efficiency of the decontamination work, the presence / absence of scattering of radioactive material to the surroundings, and the result of the decontamination depend on whether this is appropriate. In the present invention, the cleaning agent applied to the building and the radioactive material captured by the cleaning agent are removed by suction using a water-resistant vacuum cleaner. A water-resistant vacuum cleaner is a type of vacuum cleaner that sucks dry garbage, damp trash and water with a single unit, and a water-circulating type vacuum cleaner that sucks waste water and circulates it while washing with water. included.

これらの耐水性掃除機の中では、廃水容器を備えた吸水型掃除機が建築物の除染作業には最も適している。本発明においては、吸引する洗浄剤が界面活性剤を含んでおり、廃水容器内で泡立ちやすく、この泡が掃除機上部のモーターに接触すると漏電の原因になるため、泡が発生しても上部のモーターに接触できない構造の吸水掃除機、例えばサイクロン方式の吸水掃除機であればさらに好適である。また、廃水容器の底に予め消泡剤又は消泡剤溶液を張っておくことは、泡の発生を防ぐのに有効である。これにより、放射性物質を周囲に飛散させることなく、しかも能率よく行うことができる。   Among these water-resistant vacuum cleaners, a water-absorbing vacuum cleaner equipped with a waste water container is most suitable for decontamination work of buildings. In the present invention, the cleaning agent to be sucked contains a surfactant and easily foams in the waste water container. If this foam comes into contact with the motor at the top of the vacuum cleaner, it causes electric leakage. It is more suitable if it is a water-absorbing vacuum cleaner having a structure that cannot contact the motor, for example, a cyclone type water-absorbing vacuum cleaner. In addition, it is effective to prevent the generation of bubbles by applying an antifoaming agent or an antifoaming agent solution to the bottom of the wastewater container in advance. Thereby, it can carry out efficiently, without scattering a radioactive substance around.

さらに、吸水掃除機内の泡を最小限にするために、吸引口から吸水掃除機に至る途中に、貯留枡を設けるのが好ましい。この貯留枡には、溜まった廃水を取り除くために蓋が設けてある。当該蓋は、閉じた際に吸引を妨げないよう貯留枡と密閉される構造になっている。   Furthermore, in order to minimize bubbles in the water-absorbing cleaner, it is preferable to provide a storage tank on the way from the suction port to the water-absorbing cleaner. The storage tank is provided with a lid for removing the accumulated waste water. The lid is structured to be sealed with a storage tank so as not to prevent suction when closed.

第二の工程は、必要に応じて、水洗、ブラシがけ、拭き取り等によるクリーニング作業を行い、放射性物質に汚染された建築物を完全に除染する。   In the second step, cleaning work such as washing, brushing, wiping, etc. is performed as necessary to completely decontaminate the building contaminated with radioactive substances.

第三の工程は、最終段階の重要な工程であり、これがきちんとできなければこれまでの工程がすべて無駄になり、放射性物質を周辺に飛散させてしまう。拭き取りや清掃作業に使った紙、布、綿等は放射性廃棄物用容器又は袋に収納し密封する。また、掃除機の廃水容器に溜まった汚泥水、使用した装置、機器等を洗浄した廃水は放射性廃棄物用容器に収納密封する。そして放射性廃棄物用容器又は袋は所定の場所に保管する。使用した洗浄水や、給水掃除機の廃水タンクにたまった廃液をポリタンクに回収し、石灰、ゼオライト又は活性炭等を投入して、放射性物質を吸着させ沈殿させることができれば、沈殿物のみを放射性廃棄物とすることも可能である。   The third step is an important step in the final stage. If this step is not properly performed, all the steps so far are wasted and radioactive materials are scattered around. Paper, cloth, cotton, etc. used for wiping and cleaning work should be stored and sealed in a radioactive waste container or bag. Also, the sludge water collected in the waste water container of the vacuum cleaner, the waste water that has been used to clean the used devices and equipment, etc. are stored and sealed in a radioactive waste container. The radioactive waste container or bag is stored in a predetermined place. If the wash water used and the waste liquid collected in the waste water tank of the water supply vacuum cleaner are collected in a plastic tank and lime, zeolite, activated carbon, etc. are added to adsorb and precipitate the radioactive material, only the precipitate is radioactively discarded. It can also be a thing.

洗浄剤は放射性物質を捕捉するのに有効な成分を含有し、環境に対しても人体に対しても無害な液体でなければならない。本発明においては、洗浄剤は界面活性剤を主成分とする水溶液である。   The cleaning agent must contain a component that is effective for trapping radioactive materials and must be a liquid that is harmless to the environment and the human body. In the present invention, the cleaning agent is an aqueous solution containing a surfactant as a main component.

界面活性剤としては、脂肪酸塩、アルキル硫酸塩、アルキルベンゼンスルホン酸塩等のアニオン界面活性剤、第四級アンモニウム塩系のカチオン界面活性剤、脂肪酸系、高級アルコール系、アルキルフェノール系等のノ二オン界面活性剤、アミノ酸系、ベタイン系、アミンオキシド系等の両性界面活性剤のいずれも使用可能である。   Surfactants include anionic surfactants such as fatty acid salts, alkyl sulfates, and alkyl benzene sulfonates, quaternary ammonium salt cationic surfactants, fatty acid-based, higher alcohol-based, alkylphenol-based nonions, etc. Any of amphoteric surfactants such as surfactants, amino acids, betaines, and amine oxides can be used.

界面活性剤の濃度は資源の節減という観点からすれば低いほど好ましく、概ね1重量%以下、できれば0.5重量%以下が好ましい。   The concentration of the surfactant is preferably as low as possible from the viewpoint of saving resources, and is generally 1% by weight or less, preferably 0.5% by weight or less.

上述のように、洗浄剤は界面活性剤を主成分とする水溶液であるが、本発明はそれに限定されるものではない。   As described above, the cleaning agent is an aqueous solution containing a surfactant as a main component, but the present invention is not limited thereto.

原子力発電所によって飛散される放射性物質としては、圧力容器や格納容器の破損がない限り、ヨウ素131、セシウム137、キセノン133、クリプトン88等である。これらの放射性物質の半減期は、ヨウ素131が8日、キセノン133が5.3日、クリプトン88が2.8時間であるのに対し、セシウム137は30年と圧倒的に長いため、主に除染の対象となるのはセシウム137と考えられる。セシウムは1族の元素でありアルカリ金属の仲間である。従って、洗浄剤に希塩酸、希硫酸、クエン酸、シュウ酸、酒石酸、等の酸を加えることは、酸がアルカリと反応し除染をより効果的にする合理的な根拠があるため、これらの酸を含有させてもよい。また、クエン酸ナトリウム、酒石酸ナトリウム、リン酸ナトリウム、炭酸アンモニウム、クエン酸アンモニウム、EDTA等の塩もしくはキレート剤が有効な場合があり、これらを含有させることもできる。   The radioactive material scattered by the nuclear power plant is iodine 131, cesium 137, xenon 133, krypton 88, etc., as long as the pressure vessel and the containment vessel are not damaged. The half-lives of these radioactive substances are mainly 8 days for iodine 131, 5.3 days for xenon 133 and 2.8 hours for krypton 88, whereas cesium 137 is overwhelmingly 30 years. The target of decontamination is considered to be cesium 137. Cesium is a group 1 element and a member of alkali metals. Therefore, adding an acid such as dilute hydrochloric acid, dilute sulfuric acid, citric acid, oxalic acid, tartaric acid, etc. to the cleaning agent has a reasonable basis for the acid to react with the alkali and make decontamination more effective. An acid may be contained. Further, salts or chelating agents such as sodium citrate, sodium tartrate, sodium phosphate, ammonium carbonate, ammonium citrate, EDTA may be effective, and these may be contained.

また、多孔性物質微粉末は粉塵を吸着させる作用があるため、洗浄剤に多孔性物質微粉末を含有させてもよい。多孔性物質にはゼオライト、珪藻土、活性炭等があり、これらはすべて使用可能である。   Further, since the porous substance fine powder has an action of adsorbing dust, the cleaning substance may contain the porous substance fine powder. Porous materials include zeolite, diatomaceous earth, activated carbon, etc., all of which can be used.

多孔性物質微粉末を含有させる場合には、沈降分離を防ぐために水溶性増粘剤を添加してもよい。水溶性増粘剤にはでんぷん等の多糖類、ポリビニルアルコール、メチルセルローズ、ポリアクリル酸ソーダ、等があり、すべて使用可能である。   When the porous substance fine powder is contained, a water-soluble thickener may be added to prevent sedimentation. Water-soluble thickeners include polysaccharides such as starch, polyvinyl alcohol, methylcellulose, sodium polyacrylate, etc., all of which can be used.

本発明の目的を達成するための好ましい方法は、放射性物質に汚染された建築物の除染を行う際に、該建築物の表面に泡沫化せしめた洗浄剤を塗布し、隅々に隈なくいきわたらせる第一の工程、塗布された洗浄剤を除去し、クリーニングする第二の工程及び除去した放射性物質と洗浄剤との混合物を放射性廃棄物として処理する第三の工程、を順次実施するものである。これにより本発明の目的はより効果的に実現することができる。   A preferable method for achieving the object of the present invention is to apply a foamed cleaning agent to the surface of the building when decontaminating the building contaminated with radioactive substances, and to remove all the corners. The first step of spreading, the second step of removing and cleaning the applied cleaning agent, and the third step of treating the mixture of the removed radioactive substance and the cleaning agent as radioactive waste are sequentially performed. Is. Thereby, the object of the present invention can be realized more effectively.

好ましい第一の工程は、洗浄剤を泡沫発生装置を用いて泡沫化せしめながら吹き付けるものである。   A preferable first step is to spray the cleaning agent while foaming it using a foam generating device.

泡沫発生装置としては、エアコンプレッサーの空気を泡沫発生装置の洗浄剤容器内に導入し、その圧力でノズルから泡沫化洗浄剤を噴射する圧力タンク式の泡沫発生装置、エアコンプレッサーの空気をエア駆動ポンプに送り込み、ポンプの駆動力によりノズルから泡沫化洗浄剤を噴射するエア駆動ポンプ式の泡沫発生装置があるが、いずれのタイプでも使用可能である。しかし、エア駆動ポンプの場合、脈動し、泡沫状態が不安定になりやすいので、本発明をよりよい形で実施するためには、圧力タンク式の泡沫発生装置が好ましい。泡沫化せしめた洗浄剤は、建築物の表面に吹き付けられたとき、衝突のエネルギーを吸収するため飛び散ることが少ない。しかも、泡沫化せしめた洗浄剤は微細な粉塵を捕捉する作用が大きいため、放射性物質を捕捉除去するには好適な洗浄剤である。   As the foam generation device, air from the air compressor is introduced into the cleaning agent container of the foam generation device, and the pressure tank type foam generation device that injects the foaming cleaning agent from the nozzle with that pressure, and the air of the air compressor is driven by air There is an air-driven pump type foam generating device that feeds into the pump and injects the foaming detergent from the nozzle by the driving force of the pump, but any type can be used. However, in the case of an air-driven pump, it pulsates and the foam state is likely to become unstable. Therefore, in order to implement the present invention in a better form, a pressure tank type foam generator is preferable. When the foamed cleaning agent is sprayed on the surface of the building, it absorbs the energy of collision and is less likely to scatter. Moreover, since the foamed cleaning agent has a large effect of capturing fine dust, it is a suitable cleaning agent for capturing and removing radioactive substances.

泡沫化せしめた洗浄剤の塗布後、エアー吹き、はけ塗り、洗浄剤の追加噴霧さらに消泡剤噴霧等を適宜行うことにより、建築物の凹凸部、隅角部、開口部廻り、桟・横桁の上、軒天廻り等建築物の隅々にまで隈なく洗浄剤をいきわたらせかつ消泡せしめる。中でも、エアコンプレッサーからエアホースを使って行うエア吹きは、塗布された泡沫化洗浄剤を簡単に建築物の細部まで行きわたらせることができるという点で極めて有効な方法である。   After application of the foamed detergent, air blowing, brushing, additional spraying of the cleaning agent and spraying of the defoaming agent, etc. are performed as appropriate, so that the irregularities, corners, openings around the building, Disperse the detergent and defoam all the way to the corners of the building. In particular, air blowing from an air compressor using an air hose is an extremely effective method in that the applied foaming detergent can be easily distributed to the details of the building.

泡沫化せしめるための洗浄剤は、上記界面活性剤を主成分とする水溶液であってもよいし、上記水溶液に起泡剤を加えたものであってもよい。   The detergent for foaming may be an aqueous solution containing the surfactant as a main component or a solution obtained by adding a foaming agent to the aqueous solution.

起泡剤としては、洗剤等の界面活性剤、パイン油、ユーカリ油等の油類の水性エマルジョン、卵白、ゼラチン等があり、すべて使用可能である。   Examples of the foaming agent include surfactants such as detergents, aqueous emulsions of oils such as pine oil and eucalyptus oil, egg white, gelatin and the like, all of which can be used.

泡沫化せしめた洗浄剤の塗布量については、廃棄物の量を最少にするために、また洗浄剤のたれ落ちを防止するためにはできるだけ少ない方がよいが、少なすぎれば除染の効果がなくなる。目安としては0.05〜1kg/mが好ましいが、最適な塗布量は対象となる建築物表面の材質、表面状態等によって異なるので、本発明はこの数値に限定されるものではない。 The amount of foamed detergent applied should be as small as possible in order to minimize the amount of waste and to prevent the detergent from dripping. Disappear. As a guideline, 0.05 to 1 kg / m 2 is preferable, but the optimum coating amount varies depending on the material, surface state, etc. of the target building surface, and the present invention is not limited to this value.

消泡剤としては、脂肪酸系、高級アルコール系、アルキルフェノール系等のノ二オン界面活性剤、エチルアルコール等の親水性有機溶媒、シリコーンオイルまたはその水性エマルジョン、シリコーン樹脂微粉末等があり、すべて使用可能である。   Antifoaming agents include fatty acid-based, higher alcohol-based, alkylphenol-based nonionic surfactants, hydrophilic organic solvents such as ethyl alcohol, silicone oil or aqueous emulsions thereof, and silicone resin fine powder. Is possible.

土壌の除染を行う場合の詳細は下記のとおりである。放射性セシウムは、土壌の表面近傍に濃縮して固着している可能性が高い。また、空間線量率という数値で表わされる放射線量には、土壌表面近傍に存在する放射性セシウムによる影響が強い。従って、表面のごく薄い層の土壌を除去すれば、空間線量率は半分以下に下がる。本発明の好ましい第一の工程である洗浄剤を泡沫発生装置を用いて泡沫化せしめながら吹き付け、土壌表面に隈なくいきわたらせること、そして、好ましい第二の工程である吸水掃除機を使って泡沫化洗浄剤といっしょに表面のごく薄い層の土壌も吸引除去する。このように、本発明の方法により、簡便にかつ効果的に地面すなわち土壌の除染を行うことができる。しかも周囲に放射性物質を飛散させない。   The details of soil decontamination are as follows. There is a high possibility that radioactive cesium is concentrated and fixed near the surface of the soil. In addition, the radiation dose represented by the numerical value of the air dose rate is strongly influenced by radioactive cesium existing near the soil surface. Thus, removing very thin layers of soil reduces the air dose rate to less than half. The first cleaning step, which is a preferred first step of the present invention, is sprayed while foaming using a foam generating device, and is thoroughly distributed over the soil surface. A very thin layer of soil along with the foaming detergent is also removed by suction. As described above, the method of the present invention makes it possible to easily and effectively decontaminate the ground, that is, the soil. Moreover, radioactive materials are not scattered around.

さらに、樹木や草花等の植物の除染を行う場合の詳細は下記のとおりである。樹木や草花等の植物の場合、放射性セシウムは、枝葉もさることながら、その根元に濃縮して沈着している。従って、その根元の草や土壌を集中的に除染すれば、除染の効果は飛躍的に増大する。発明に使用する洗浄剤は、先に述べたように、界面活性剤を主成分とする水溶液である。この洗浄剤を使い、本発明の方法を実施すれば、植物の除染も行うことができる。すなわち、本発明の好ましい第一の工程である洗浄剤を泡沫発生装置を用いて泡沫化せしめながら植物本体及びその根元に吹き付ける。そして、好ましい第二の工程である、吸水掃除機を使って泡沫化洗浄剤といっしょに植物の根元の土壌を吸引除去する際に、植物本体及びその根元に噴霧器で水を噴霧することにより、植物に害を与えることなく、簡便かつ効果的に除染することができる。しかも周囲に放射性物質を飛散させない。   Further, details of decontamination of plants such as trees and flowers are as follows. In the case of plants such as trees and flowers, radioactive cesium is concentrated and deposited at the root of the plant, as well as the branches and leaves. Therefore, if the grass and soil at the base are intensively decontaminated, the effect of decontamination is dramatically increased. As described above, the cleaning agent used in the invention is an aqueous solution mainly composed of a surfactant. If this cleaning agent is used and the method of the present invention is carried out, the plant can be decontaminated. That is, the cleaning agent, which is a preferred first step of the present invention, is sprayed onto the plant body and its roots while foaming using a foam generator. And, when removing the soil at the root of the plant together with the foaming detergent using a water-absorbing vacuum cleaner, which is a preferred second step, by spraying water on the plant body and its root with a sprayer, It can be easily and effectively decontaminated without harming the plant. Moreover, radioactive materials are not scattered around.

上述したように、放射性物質に汚染された建築物等に洗浄剤を周囲に飛散させずに吹き付け塗布し、隅々に隈なくいきわたらせる第一の工程、塗布された洗浄剤を除去し、クリーニングする第二の工程及び除去した放射性物質と洗浄剤との混合物を放射性廃棄物として処理する第三の工程、を順次実施することにより、建物、施設、工作物等の建築物に付着・堆積した放射性物質を、周囲に飛散させることなく安全に、かつ安価で手間をかけずに行うという本発明の目的を達成することが可能になる。   As mentioned above, the spraying agent is sprayed and applied to buildings and the like contaminated with radioactive materials without splashing the surroundings, and the applied cleaning agent is removed in a first step that spreads all over the corner. Adhering to and depositing on buildings such as buildings, facilities, and buildings by sequentially performing the second step of cleaning and the third step of treating the mixture of removed radioactive material and cleaning agent as radioactive waste It is possible to achieve the object of the present invention to perform the radioactive material safely without being scattered around, without being troublesome.

また、放射性物質を除染する好ましい方法として、放射性物質に汚染された建築物、植物又は土壌の表面に泡沫化せしめた洗浄剤を塗布し、隅々に隈なくいきわたらせる第一の工程、塗布された洗浄剤を除去し、クリーニングする第二の工程及び除去した放射性物質と洗浄剤との混合物を放射性廃棄物として処理する第三の工程、を順次実施することにより、建物、施設、工作物等の建築物等に付着・堆積した放射性物質を、周囲に飛散させることなく安全に、かつ安価で手間をかけずに行うという本発明の目的をより効果的に達成することが可能になる。   In addition, as a preferable method for decontaminating radioactive substances, a first step of applying a foaming detergent on the surface of buildings, plants or soil contaminated with radioactive substances and spreading them all over the corners, By sequentially performing the second step of removing and cleaning the applied cleaning agent and the third step of treating the mixture of the removed radioactive material and the cleaning agent as radioactive waste, the building, facility, and work are performed. It is possible to more effectively achieve the object of the present invention in which radioactive materials attached to and accumulated on buildings such as objects are safely and inexpensively performed without being scattered around. .

本発明に係る方法による除染処理前後の放射線測定結果を示す。The radiation measurement result before and behind the decontamination process by the method which concerns on this invention is shown. 本発明に係る方法による除染処理前後の放射線測定結果を示す。The radiation measurement result before and behind the decontamination process by the method which concerns on this invention is shown.

以下、建築物の除染に関し本発明の実施の形態を説明する。但し、本発明は放射性物質に関するものであり、本発明の効果を実証する実験を行うことは極めて困難を極めたが、幸いにも本発明の目的を理解し協力してくれる人が現れ実現できたものである。   Hereinafter, embodiments of the present invention will be described with respect to decontamination of buildings. However, the present invention relates to radioactive substances, and it was extremely difficult to conduct experiments to demonstrate the effects of the present invention.Fortunately, people who understand and cooperate with the purpose of the present invention appear and can be realized. It is a thing.

実験は、福島第一原発から100kmほど離れており、放射性物質による汚染が比較的軽微な栃木県那須郡那須町にある2棟の農業用物置を借りて実施した。2棟の物置は1kmほど離れており、それらを仮にA棟、B棟と名付けると、A棟もB棟もスチール製の組立式プレハブ物置で周辺に建物はなく畑の中に孤立した状態で建っている。A棟は間口2.7m、奥行1.8m、高さ1.8m、表面積約26mであり、B棟は間口3.6m、奥行1.8m、高さ1.8m、表面積約33mである。いずれの物置も地面にコンクリートブロックを置き、その上に据え置いただけの簡易な構造である。 The experiment was carried out by borrowing two agricultural storage rooms in Nasu-machi, Nasu-gun, Tochigi Prefecture, which is about 100 km away from the Fukushima Daiichi nuclear power plant and is relatively lightly contaminated with radioactive materials. The two storerooms are about 1km apart, and if they are named A and B buildings, both buildings A and B are steel prefabricated prefab stores and there are no buildings in the surroundings and they are isolated in the field. It is built. A building is frontage 2.7 m, depth 1.8 m, a height 1.8 m, surface area of about 26m 2, B building is frontage 3.6 m, depth 1.8 m, height 1.8 m, at a surface area of about 33m 2 is there. Each storeroom has a simple structure in which a concrete block is placed on the ground and placed on it.

事前に物置とその周辺から発生する放射線量を、空間放射線量測定器(FLUKEサーベイメーター451P)により、できるだけ地面からの影響を避けるために次の位置で測定した。建物部分については、屋根は屋根面から50cmの高さで2か所、壁は壁面から50cm、地面から1.5mの位置で東西南北各1か所測定した。周辺については、建物から5m離れた高さ50cmの位置で東西南北各1か所測定した。結果を図1及び図2に示す。   In order to avoid the influence from the ground as much as possible, the radiation dose generated from the storage room and its surroundings was measured at the following position with a space radiation dose meter (FLUKE Survey Meter 451P). As for the building part, the roof was measured at two locations at a height of 50 cm from the roof surface, the wall was measured at 50 cm from the wall surface, and 1.5 m from the ground at one location in the east, west, south, and north. About the periphery, it measured one place each in the east, west, south, and north at the position of 50cm in height 5m away from the building. The results are shown in FIGS.

A棟では本発明請求項1の方法で除染を行った。まず物置まわりの地面に幅約4mのブルーシートを敷き、その上に必要な資機材を置いた。電力は小型自家発電機によりAC100Vの電源を確保した。吹付け作業の前に、まず洗浄剤として、カチオン界面活性剤であるノニルトリメチルアンモニウム塩0.5重量%、ゼオライト微粉末3重量%、増粘剤であるポリビニルアルコール5重量%を含有する水溶液を準備した。精和産業製エアレス吹付け機「とばなーいTB-7」の容器に洗浄剤水溶液を入れ、吹付け機の吐出圧力調整を行った。吐出圧力0.1MPaの場合、吐出量は2kg/分であった。塗布量は500g/mと設定し、目安としてA棟表面を累計で約7分吹付ければよいと計算した上で、屋根、軒天、壁と順次上から下へ吹付けた。吹付け終了後、小型ブロアーを吹いたり、はけ塗りを行い、洗浄剤が塗布されていない箇所には手動噴霧器により洗浄剤を追加噴霧し、洗浄剤を建物表面の隅々にまでいきわたらせた(第一の工程)。 In building A, decontamination was performed by the method of claim 1 of the present invention. First, a blue sheet with a width of about 4m was laid on the ground around the storeroom, and necessary materials and equipment were placed on it. As for the electric power, a power source of AC100V was secured by a small private generator. Before spraying, an aqueous solution containing 0.5% by weight of nonyltrimethylammonium salt as a cationic surfactant, 3% by weight of zeolite fine powder, and 5% by weight of polyvinyl alcohol as a thickener is first used as a cleaning agent. Got ready. A detergent aqueous solution was put into the container of Seiwa Sangyo's airless sprayer “Tobanai TB-7” and the discharge pressure of the sprayer was adjusted. When the discharge pressure was 0.1 MPa, the discharge rate was 2 kg / min. The coating amount was set to 500 g / m 2, and it was calculated that the surface of building A should be sprayed for a total of about 7 minutes as a guideline, and then the roof, eaves, and walls were sprayed sequentially from top to bottom. After spraying, a small blower was blown or brushed, and the area where the cleaning agent was not applied was sprayed with a manual sprayer to spread the cleaning agent to every corner of the building surface. (First step).

次いで、日立産機システム製吸水掃除機(CV-980WF2)を用いて、屋根、軒天、壁と順次上から下へ洗浄剤と洗浄剤に捕捉された放射性物質の混合物を吸引除去した。この際、凹部や狭い部分にはそれに適した吸口を用いた。さらに、じょうろ等での水の噴霧、紙、布、綿等での拭き取り作業により、クリーニング及びポリッシュを行った(第二の工程)。   Next, using a vacuum cleaner manufactured by Hitachi Industrial Equipment Systems (CV-980WF2), the roof, eaves, and walls, and the mixture of the radioactive material trapped in the cleaning agent and the cleaning agent were sequentially removed from the top to the bottom. At this time, a suction port suitable for the concave portion or narrow portion was used. Furthermore, cleaning and polishing were carried out by spraying water with a watering can or the like, and wiping with paper, cloth, cotton or the like (second step).

最後に、吸水掃除機の容器に溜まった汚泥水、使用した装置、機器等の洗浄水を、紙、布、綿、吸水ポリマー等の吸水性物質に吸収させ、拭き取りに使った紙、布、綿等といっしょに放射性廃棄物用容器に収納密封した。壁面から垂れ落ちてブルーシートに少し溜まった洗浄剤も紙、布、綿等できれいに拭き取り、放射性廃棄物用容器に収納密封した。密封した放射性廃棄物用容器の保管は、実験に立ち会ってくれた地元の人に委ねた(第三の工程)。   Finally, the sludge water collected in the container of the water-absorbing vacuum cleaner, the cleaning water of the used equipment, equipment, etc. are absorbed into water-absorbing substances such as paper, cloth, cotton, water-absorbing polymer, and the paper, cloth, It was housed and sealed in a radioactive waste container together with cotton. The cleaning agent that fell from the wall surface and accumulated in the blue sheet was also wiped clean with paper, cloth, cotton, etc., and stored and sealed in a radioactive waste container. The storage of the sealed radioactive waste container was entrusted to the local person who attended the experiment (third step).

除染作業終了後、各場所における放射線量を測定した結果を図1に示す。我が国における自然放射線量はおよそ0.11μSv/hと言われているので、この値前後になれば除染は成功したということができる。建物部分については、屋根に比べて壁の放射線量が高いが、今回は地面の除染は行わなかったので、地面からの放射線の影響を受けたものと考えられる。屋根だけを見れば、処理前の0.41μSv/hから処理後の0.14μSv/hに低下しており、0.11μSv/hよりは若干高いが除染処理の効果は明らかである。周辺については、処理前後の放射線量は変らないか、心もち増えたかどうかという結果であるが、建物への洗浄剤吹付け時に若干の放射性物質の飛散があったのかもしれない。   The result of measuring the radiation dose at each place after the decontamination work is shown in FIG. Since the natural radiation dose in Japan is said to be about 0.11 μSv / h, it can be said that decontamination has been successful if the value is around this value. As for the building part, the radiation dose on the walls is higher than that on the roof, but this time the ground was not decontaminated, so it is considered that the building was affected by radiation from the ground. If only the roof is seen, it decreases from 0.41 μSv / h before the treatment to 0.14 μSv / h after the treatment, which is slightly higher than 0.11 μSv / h, but the effect of the decontamination treatment is clear. As for the surrounding area, the radiation dose before and after treatment did not change or the result increased in mind, but there may have been some scattering of radioactive material when spraying the cleaning agent on the building.

B棟では本発明請求項10の方法で除染を行った。まず物置まわりの地面に幅約4mのブルーシートを敷き、その上に必要な資機材を置いた。電力は小型自家発電機によりAC100Vの電源を確保した。吹付け作業の前に、まず洗浄剤として、カチオン界面活性剤であるノニルトリメチルアンモニウム塩0.5重量%の水溶液に、クエン酸1重量%、ゼラチン1重量%を加えてよく撹拌したものを準備した。また、消泡剤としてエチルアルコール25重量%の水溶液を準備した。泡沫化せしめた洗浄剤吹付け機として、本実験では市販の洗車用空気式気泡発生器を使用した。この装置の吐出圧力は0.4MPa、吐出量は約200g/分であった。塗布量は200g/mと設定し、目安としてB棟表面を累計で約33分吹付ければよいと計算した上で、屋根、軒天、壁と順次上から下へ吹付けた。吹付けが終った場所から順に、小型ブロアーを吹いたり、はけ塗りを行い、あるいは洗浄剤が塗布されていない箇所には泡沫化せしめた洗浄剤を追加噴霧したり、さらに手動噴霧器で消泡剤水溶液を吹付けて消泡せしめながら、洗浄剤を建物表面の隅々にまでいきわたらせた(第一の工程)。 In Building B, decontamination was performed by the method of claim 10 of the present invention. First, a blue sheet with a width of about 4m was laid on the ground around the storeroom, and necessary materials and equipment were placed on it. As for the electric power, a power source of AC100V was secured by a small private generator. Before spraying, first prepare a detergent with 1% by weight of citric acid and 1% by weight of gelatin in an aqueous solution of 0.5% by weight of nonyltrimethylammonium salt, a cationic surfactant. did. In addition, an aqueous solution of 25% by weight of ethyl alcohol was prepared as an antifoaming agent. In this experiment, a commercially available air bubble generator for car wash was used as a foaming detergent sprayer. The discharge pressure of this apparatus was 0.4 MPa, and the discharge rate was about 200 g / min. The coating amount was set to 200 g / m 2, and it was calculated that the surface of Building B should be sprayed for a total of approximately 33 minutes as a guideline, and then the roof, eaves, and walls were sprayed sequentially from top to bottom. In order from the place where spraying is finished, blow a small blower, apply brush, or spray a foamed detergent to the place where the detergent is not applied, or defoam with a manual sprayer The spray was sprayed to the corners of the building surface while spraying the aqueous solution to remove the bubbles (first step).

次いで、日立産機システム製吸水掃除機(CV-980WF2)を用いて、屋根、軒天、壁と順次上から下へ、洗浄剤と洗浄剤に捕捉された放射性物質の混合物を吸引除去した。この際、凹部や狭い部分にはそれに適した吸口を用いた。また、吸水掃除機の廃水容器には時々消泡剤を吹付け、容器中の泡沫を消した。さらに、じょうろ等での水の噴霧、紙、布、綿等での拭き取り作業により、クリーニング及びポリッシュを行った(第二の工程)。   Next, using a vacuum cleaner manufactured by Hitachi Industrial Equipment Systems (CV-980WF2), the cleaning agent and the mixture of radioactive materials captured by the cleaning agent were removed from the roof, eaves, and walls sequentially from top to bottom. At this time, a suction port suitable for the concave portion or narrow portion was used. Moreover, an antifoaming agent was sometimes sprayed to the waste water container of the water absorption cleaner, and the foam in the container was erased. Furthermore, cleaning and polishing were carried out by spraying water with a watering can or the like, and wiping with paper, cloth, cotton or the like (second step).

最後に、吸水掃除機の容器に溜まった汚泥水、使用した装置、機器等の洗浄水を、紙、布、綿、吸水ポリマー等の吸水性物質に吸収させ、拭き取りに使った紙、布、綿等といっしょに放射性廃棄物用容器に収納密封した。泡沫化せしめた洗浄剤の垂れ落ちは殆んどなかったが、地面に敷いたブルーシートの汚れを紙、布、綿等できれいに拭き取り、放射性廃棄物用容器に収納密封した。密封した放射性廃棄物用容器の保管は、実験に立ち会ってくれた地元の人に委ねた(第三の工程)。   Finally, the sludge water collected in the container of the water-absorbing vacuum cleaner, the cleaning water of the used equipment, equipment, etc. are absorbed into water-absorbing substances such as paper, cloth, cotton, water-absorbing polymer, and the paper, cloth, It was housed and sealed in a radioactive waste container together with cotton. There was almost no dripping off of the foamed cleaning agent, but the dirt on the blue sheet laid on the ground was wiped clean with paper, cloth, cotton, etc., and stored and sealed in a container for radioactive waste. The storage of the sealed radioactive waste container was entrusted to the local person who attended the experiment (third step).

除染作業終了後、各場所における放射線量を測定した結果を図2に示す。我が国における自然放射線量は0.11μSv/hと言われているので、この値前後になれば除染は成功したということができる。建物部分については、屋根に比べて壁の放射線量が高いが、今回は地面の除染は行わなかったので、地面からの放射線の影響を受けたものと考えられる。屋根だけを見れば、処理前の0.48μSv/hから処理後は自然放射線量と同じ0.11μSv/hにまで低下しているので、狙い通り完全に除染することができた。周辺については、処理前後の放射線量は全く変らないが、これは、建物への洗浄剤吹付け時に放射性物質が周辺に飛散しなかったことを意味するものと考えられる。また上にも述べたように、泡沫化せしめた洗浄剤の垂れ落ちが殆んどなかったことは注目すべき利点である。   FIG. 2 shows the result of measuring the radiation dose at each place after the decontamination work. Since the natural radiation dose in Japan is said to be 0.11 μSv / h, it can be said that decontamination has been successful if it is around this value. As for the building part, the radiation dose on the walls is higher than that on the roof, but this time the ground was not decontaminated, so it is considered that the building was affected by radiation from the ground. If only the roof is seen, it decreased from 0.48 μSv / h before the treatment to 0.11 μSv / h, which is the same as the amount of natural radiation after the treatment, so that it was possible to completely decontaminate as intended. In the surrounding area, the radiation dose before and after treatment does not change at all, but this is considered to mean that radioactive materials were not scattered around the building when spraying the cleaning agent on the building. Also, as mentioned above, it is a noteworthy advantage that there was little dripping of the foamed cleaning agent.

次に本発明による放射性物質の除染方法を地面に適用した場合について具体的に説明する。   Next, the case where the radioactive substance decontamination method according to the present invention is applied to the ground will be described in detail.

地面に対する除染の方法は、基本的には上記に述べた建築物の場合の方法と同様であるが、下記の点に留意して除染を行う。
1)地面の汚染土壌が軟らかい場合は、地面に泡沫化洗浄剤を吹付けた後この洗浄剤を表土と一緒に吸引除去する。この方法により、人力による表土削り取りの作業を省略し、作業効率を向上することができる。
2)一方、地面の汚染土壌が硬い場合等、上記方法では除染が不充分な場合は、表土の削り取り、放射能汚染されていない土による汚染土壌の被覆、放射能汚染された上層の土壌と汚染されていない下層の土壌との入れ替え等の処理のいずれか、あるいはこれらの処理を組み合わせて行う。
The method of decontamination on the ground is basically the same as the method described above for buildings, but decontamination is performed with the following points in mind.
1) If the contaminated soil on the ground is soft, spray the foaming detergent onto the ground, and then remove the detergent together with the topsoil by suction. By this method, the work of topsoil cutting by human power can be omitted and the work efficiency can be improved.
2) On the other hand, when decontamination is insufficient by the above method, such as when the soil contaminated on the ground is hard, scraping off the top soil, covering the contaminated soil with soil that is not radioactively contaminated, and the upper soil contaminated with radiation And any of the treatments such as replacement with uncontaminated lower soil, or a combination of these treatments.

次に本発明による放射性物質の除染方法を樹木や草花等の植物に適用した場合について具体的に説明する。   Next, the case where the radioactive substance decontamination method according to the present invention is applied to plants such as trees and flowers will be described in detail.

樹木や草花等の植物に対する除染の方法は、基本的には上記に述べた建築物の場合の方法と同様であるが、下記の点に留意して除染を行う。
1)樹木、草花等の植物は酸に弱いので植物に対しては酸性の洗浄剤を使用できない。この為、植物に対しては酸を含まない洗浄剤を用いる。
2)植物において放射線量は水の溜まりやすい窪地で高くなる傾向にあり、この為上部の枝葉よりも根本の除染を優先して行う。
3)枝葉への洗浄剤の吹付けは雨に濡れやすい表面よりも雨に濡れにくい枝葉内部への吹付を優先的に行う。
4)植物の場合の洗浄剤の吹付量に関しては建築物の壁面などの平面の場合と異なり、三次元的に凹凸が激しいので、次の計算式を用いて算出する。
植物の場合の洗浄剤の適正吹付量=α×仮想面積×β ・・・(1)
ここで、αは壁面などの堅固な平面に対する洗浄剤の単位面積当たりの適正吹付量、仮想面積は植物の地面への投影面積、βは洗浄剤の吹付対象である植物の凹凸による実効面積の増加を考慮した割り増し係数であり、1.5を基準とするが必ずしもこの値に限定されない。
5)洗浄剤の植物への影響を少なくするため、酸を含まない洗浄剤を植物に吹付け後、植物の根元の汚泥水を吸水掃除機で吸引しながら、植物に対して十分に水の噴霧を行い植物本体及び根元から完全に洗浄剤を除去する。
The decontamination method for plants such as trees and flowers is basically the same as that for buildings described above, but decontamination is performed with the following points in mind.
1) Since plants such as trees and flowers are vulnerable to acid, acidic detergents cannot be used for plants. For this reason, detergents that do not contain acids are used for plants.
2) In plants, the radiation dose tends to be higher in depressions where water tends to accumulate. Therefore, decontamination of the roots is given priority over the upper branches and leaves.
3) Spraying the cleaning agent onto the branches and leaves gives priority to spraying the inside of the branches and leaves that are not easily wetted with rain over the surface that is easily wetted with rain.
4) The amount of spraying cleaning agent in the case of plants differs from the case of a flat surface such as a wall surface of a building, because it has three-dimensional unevenness, and is calculated using the following formula.
Appropriate spraying amount of cleaning agent in the case of plants = α × virtual area × β (1)
Where α is the appropriate spray amount per unit area of the cleaning agent for a solid surface such as a wall, the virtual area is the projected area of the plant on the ground, and β is the effective area due to the unevenness of the plant to which the cleaning agent is sprayed. This is a premium coefficient considering the increase and is based on 1.5, but is not necessarily limited to this value.
5) In order to reduce the influence of the cleaning agent on the plant, spray the cleaning agent that does not contain acid on the plant, and then suck the sludge water at the base of the plant with a water-absorbing vacuum cleaner. Spray to completely remove the cleaning agent from the plant body and roots.

Claims (15)

建築物、土壌又は植物の表面に洗浄剤を周囲に飛散させずに吹き付け塗布し、隅々に隈なくいきわたらせる第一の工程、
放射性物質と前記洗浄剤との混合物を除去し、クリーニングする第二の工程及び
除去した放射性物質と洗浄剤との混合物を放射性廃棄物として回収処理する第三の工程、
とから成ることを特徴とする放射性物質に汚染された建築物、土壌又は植物を除染する方法。
The first step of spraying and applying the cleaning agent to the surface of the building, soil or plant without splashing it around,
A second step of removing and cleaning the mixture of the radioactive substance and the cleaning agent and a third step of recovering and treating the mixture of the removed radioactive substance and the cleaning agent as radioactive waste;
A method for decontaminating a building, soil or plant contaminated with a radioactive material, characterized by comprising:
前記洗浄剤が泡沫化した洗浄剤であることを特徴とする請求項1に記載の建築物、土壌又は植物を除染する方法。 The method for decontaminating a building, soil, or plant according to claim 1, wherein the cleaning agent is a foamed cleaning agent. 前記第一の工程が、エアレス吹付け機を用いて0.5MPa以下の吐出圧力で前記洗浄剤を噴霧して行われることを特徴とする請求項1記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The building contaminated with a radioactive substance according to claim 1, wherein the first step is performed by spraying the cleaning agent at a discharge pressure of 0.5 MPa or less using an airless sprayer. A method of decontaminating soil or plants. 前記第二の工程のクリーニングが、前記洗浄剤と前記洗浄剤に捕捉された放射性物質を耐水性掃除機を用いて吸引除去し、水洗・ブラシがけ又は/及び拭き取りを行うことを特徴とする請求項1又は請求項2に記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The cleaning in the second step is performed by sucking and removing the cleaning agent and the radioactive material trapped in the cleaning agent with a water-resistant vacuum cleaner, and performing washing with water, brushing and / or wiping. A method for decontaminating a building, soil, or plant contaminated with the radioactive material according to claim 1 or claim 2. 前記第三の工程が、廃水及び前記洗浄水を、クリーニングに用いた吸水性物質と共に放射性廃棄物用容器又は袋に収納密封することを特徴とする請求項1又は請求項2に記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The radioactive substance according to claim 1 or 2, wherein the third step stores and seals the waste water and the washing water in a radioactive waste container or bag together with the water-absorbing substance used for cleaning. A method of decontaminating buildings, soil, or plants contaminated with water. 前記耐水性掃除機が廃水容器を備えた吸水型掃除機であることを特徴とする請求項4記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 5. The method for decontaminating a building, soil or plant contaminated with a radioactive substance according to claim 4, wherein the water-resistant vacuum cleaner is a water-absorbing type vacuum cleaner provided with a waste water container. 前記吸水型掃除機が貯留枡を備えており、吸引された廃水が掃除機内部に入る前に廃水は前記貯留枡にいったん留まるようにされており、前記貯留枡には蓋が設けてあり、前記蓋は閉じた際に吸引を妨げないよう貯留枡を密閉するようにされていることを特徴とする請求項4に記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The water-absorbing type vacuum cleaner is provided with a storage tank, and the waste water is temporarily retained in the storage tank before the sucked waste water enters the vacuum cleaner, and the storage tank is provided with a lid, 5. The method for decontaminating a building, soil, or plant contaminated with radioactive material according to claim 4, wherein the lid is sealed so as not to prevent suction when closed. . 前記吸水掃除機が、前記給水掃除機のモータが廃水容器内の泡と接触しない構造を備えることを特徴とする請求項6記載の建築物、土壌又は植物を除染する方法。 The method for decontaminating a building, soil, or plant according to claim 6, wherein the water-absorbing vacuum cleaner has a structure in which a motor of the water supply vacuum cleaner does not come into contact with bubbles in a waste water container. 前記吸水掃除機の廃水容器に予め消泡剤又は消泡剤溶液が投入されることを特徴とする請求項6記載の建築物、土壌又は植物を除染する方法。 The method for decontaminating a building, soil, or plant according to claim 6, wherein an antifoaming agent or an antifoaming agent solution is put in advance in a waste water container of the water-absorbing vacuum cleaner. 前記洗浄剤が、界面活性剤を主成分とする水溶液であることを特徴とする請求項1又は請求項2記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The method for decontaminating a building, soil, or plant contaminated with a radioactive substance according to claim 1 or 2, wherein the cleaning agent is an aqueous solution containing a surfactant as a main component. 前記洗浄剤が、酸を含有することを特徴とする請求項1又は請求項2記載の放射性物質に汚染された建築物又は土壌を除染する方法。 3. The method for decontaminating a building or soil contaminated with a radioactive substance according to claim 1, wherein the cleaning agent contains an acid. 前記洗浄剤が、酸を含有しないことを特徴とする請求項1又は請求項2記載の放射性物質に汚染された植物を除染する方法。 3. The method for decontaminating a plant contaminated with a radioactive substance according to claim 1, wherein the cleaning agent does not contain an acid. 前記洗浄剤が多孔性物質微粉末を含むことを特徴とする請求項10記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 The method for decontaminating a building, soil, or plant contaminated with a radioactive substance according to claim 10, wherein the cleaning agent contains fine powder of a porous substance. 前記第一の工程が、前記洗浄剤を泡沫発生装置を用いて泡沫化せしめながら吹き付けることを特徴とする請求項2記載の放射性物質に汚染された建築物、土壌又は植物を除染する方法。 3. The method of decontaminating a building, soil or plant contaminated with a radioactive substance according to claim 2, wherein the first step is sprayed while foaming the cleaning agent using a foam generating device. 前記泡沫発生装置は、エアコンプレッサーの空気を前記泡沫発生装置の洗浄剤容器内に導入し、その圧力でノズルから泡沫化洗浄剤を噴射することを特徴とする請求項14記載の建築物、土壌又は植物を除染する方法。 15. The building and soil according to claim 14, wherein the foam generating device introduces air from an air compressor into a cleaning agent container of the foam generating device, and jets the foaming cleaning agent from the nozzle at the pressure. Or a method of decontaminating plants.
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