JP2014051063A - Metal-made pipe performed by vitreous enamel, and production method of the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a metal-made pipe performed by a vitreous enamel on interior exterior surfaces in which a vitreous enamel is formed on interior exterior surfaces of a metal-made pipe of cast iron or iron or the like, thereby for an interior surface, a main component is an inorganic substance, thereby adverse effect is not influenced to water quality at all, there is not water permeability, thereby durability for a long period can be maintained, moreover, for an exterior surface, a main component is an inorganic substance, thereby corrosion resistance is excellent, thereby anticorrosion performance can be maintained over a long period, and a metallographic structure of an exterior surface is integrated with a vitreous enamel, thereby impact resistance is excellent, moreover interior exterior surfaces same time vitreous enamel making can be performed, further slow cooling is performed after burning, thereby use can be performed immediately; and a production of the same.SOLUTION: A vitreous enamel 2 is formed on an interior surface of a metal-made pipe body 1a that composes a conduit line.

Description

  The present invention relates to a metal pipe with enamel and a manufacturing method thereof, and in particular, a metal pipe with at least an inner surface of a metal pipe main body made of cast iron or iron constituting the pipe and its manufacture. It is about the method.

  Conventionally, two-part liquid epoxy resin paint or epoxy resin powder paint is used for the inner surface coating of metal pipes used for water supply or sewage, etc. Liquid synthetic resin paint is used.

  Patent Document 1 (Japanese Patent Laid-Open No. 2003-11253) discloses a metal tube coated with an epoxy resin powder coating material in which an epoxy resin component is specified.

  When using epoxy resin powder paint for internal coating, the epoxy resin powder paint does not contain solvent and is applied to preheated metal pipes, so there is little concern about adverse effects on water quality. There is concern about environmental hormones due to bisphenol A type epoxy resins.

JP 2003-11253 A

  As described above, when two-part liquid epoxy resin paint is used for inner surface coating, since the liquid epoxy resin paint generally contains a solvent, it takes time to dry if thickly applied, and adversely affects water quality. There are concerns.

  On the other hand, as described above, the epoxy resin powder coating does not contain a solvent and is applied to a preheated metal tube, so there is little concern about adverse effects on water quality. In this case, an epoxy resin powder coating is used. However, when this is applied to external coating, it is unsuitable because the coating film is hard and impact resistance is low.

  On the other hand, as for exterior coating, generally used liquid synthetic resin paint is difficult to thickly coat, takes time to dry, and has low anticorrosion properties, so it is embedded in corrosive soil There are cases where metal pipes corrode in a short period of time and end their life in a short period of time.

  Conventionally, the inner and outer surfaces of the pipe cannot be simultaneously coated with the same paint, and the outer surface is generally coated after the inner surface is coated.

  Accordingly, the object of the present invention is to have an anticorrosion performance for a long period of time because it is integrated with the metal structure of the metal pipe main body constituting the pipe line without adversely affecting the water quality, and excellent Another object of the present invention is to provide a metal pipe excellent in hygiene and having a hollow on at least the inner surface and a method for producing the metal pipe.

  The inventor of the present application has made extensive studies in order to achieve the above object. As a result, the following findings were obtained.

  Since enamel does not contain organic substances or solvents and does not contain harmful substances such as environmental hormones, it does not adversely affect water quality. It is also possible to engrave the inner and outer surfaces of the tube at the same time, and when the tube is gradually cooled, it can be used immediately.

  The present invention has been made based on the above findings and is characterized by the following.

  The invention described in claim 1 is characterized in that a hollow is formed on at least the inner surface of the metal pipe main body constituting the pipe line.

  The invention described in claim 2 is characterized in that, in the invention described in claim 1, the content of silica in the enamel is in the range of 50 wt% to 100 wt%.

  The invention described in claim 3 is characterized in that, in the invention described in claim 1 or 2, the metal pipe body is made of cast iron or iron.

  The invention according to claim 4 is a method in which a metal pipe body is subjected to a surface finishing treatment, and then at least an inner surface of the metal pipe body subjected to the surface finishing treatment is coated with an enamel frit mainly composed of silica. It is characterized in that it is fired in a heating furnace and then slowly cooled, and thus enamel is applied to at least the inner surface of the metal pipe body.

  The invention according to claim 5 is characterized in that, in the invention according to claim 4, the content of silica in the enamel frit is in the range of 50 wt% to 100 wt%.

  The invention described in claim 6 is characterized in that, in the invention described in claim 4 or 5, the firing temperature of the metal pipe body is in the range of 600 ° C to 1000 ° C.

  The invention according to claim 7 is characterized in that, in the invention according to any one of claims 4 to 6, the firing time of the metal tube main body is within a range of 10 minutes to 180 minutes. is there.

  The invention according to claim 8 is characterized in that, in the invention according to any one of claims 4 to 7, the thickness of the enamel is in the range of 0.1 mm to 1.0 mm. is there.

  The invention according to claim 9 is characterized in that, in the invention according to any one of claims 4 to 8, the cooling rate of the metal pipe body is 200 ° C./min or less.

  The invention described in claim 10 is characterized in that, in the invention described in any one of claims 4 to 9, the metal pipe main body is made of cast iron or iron.

  According to this invention, since the main component is inorganic, there is no adverse effect on water quality and there is no water permeability, so long-term durability can be maintained. In addition, the outer surface is excellent in corrosion resistance because the main component is inorganic, so that the anticorrosion performance can be maintained over a long period of time and the outer surface metal structure and enamel are integrated. Excellent impact. In addition, the inner and outer surfaces can be enameled simultaneously, and further, after firing, it can be used immediately by cooling slowly.

It is a fragmentary sectional view which shows the metal pipe | tube of this invention. It is process drawing which shows the manufacturing method of metal pipes of this invention.

  Next, an embodiment of the metal pipe of the present invention will be described with reference to the drawings, taking as an example the case where enamels are formed on the inner and outer surfaces of the cast iron pipe body.

  FIG. 1 is a partial sectional view showing a metal pipe of the present invention.

  As shown in FIG. 1, the metal pipe of the present invention fires a cast iron pipe main body 1 as a metal pipe main body, and a frit mainly composed of silica formed on the inner and outer surfaces of the cast iron pipe main body 1. It is comprised from the enamel 2 formed by.

  The content of silica in the enamel 2 is in the range of 50 wt% to 100 wt%. If the content of silica is less than 50 wt%, it is not sufficiently integrated with the metal structure of the cast iron pipe body 1, so that the adhesion is inferior and the impact resistance is also lowered.

  The firing temperature of the enamel 2 is in the range of 600 ° C to 1000 ° C. When the firing temperature is less than 600 ° C., the firing is incomplete, the integration with the metal structure is not sufficient, and the adhesion is poor. On the other hand, if the firing temperature exceeds 1000 ° C., the enamel 2 is overbaked, discoloration and solidification of the film occur, and the impact resistance is lowered.

  The enamel 2 firing time is in the range of 10 to 180 minutes. When the firing time is less than 10 minutes, the firing is incomplete, the integration with the metal structure is not sufficient, and the adhesion is poor. On the other hand, if the firing time exceeds 180 minutes, the enamel 2 becomes overbaked, discoloration and solidification of the film occur, and the impact resistance decreases.

  The thickness of the enamel 2 is in the range of 0.1 mm to 1.0 mm. If the thickness of the enamel 2 is less than 0.1 mm, the occurrence of pinholes increases and the corrosion resistance performance is significantly reduced. On the other hand, if it exceeds 1.0 mm, the film thickness of the enamel 2 becomes too thick and becomes brittle, and the impact resistance is lowered.

  The cooling rate of the enamel 2 is set to 200 ° C./min or less. If the cooling rate of the enamel 2 exceeds 200 ° C./min, the enamel 2 becomes brittle due to rapid cooling, and impact resistance decreases.

  The above is a case where the present invention is applied to a cast iron pipe, but the case where the present invention is applied to a metal pipe such as an iron pipe is the same as that of a cast iron pipe.

  Next, an embodiment of a method for producing a metal pipe according to the present invention will be described with reference to the drawings, taking as an example the case where enamel is applied to the inner and outer surfaces of a cast iron pipe body. The case where enamel is applied only to the inner surface of the cast iron pipe body is basically the same as the case where enamel is applied to the inner and outer surfaces.

  FIG. 2 is a process diagram showing a method of manufacturing a metal pipe according to the present invention.

  As shown in FIG. 2, in order to manufacture a metal pipe according to the present invention, first, an inner and outer surface finishing treatment is performed on a cast iron pipe body which has been cast and then annealed by a conventional method. This inner and outer surface finishing treatment is important, and the surface is blasted with grit blasting to remove rust and oxide scale from the inner and outer surfaces of the cast iron pipe body. The finishing degree is set to be Sa2 (1/2) or more. Next, the inner and outer surfaces of the cast iron pipe body subjected to the inner and outer surface finishing treatment are coated with a frit mainly composed of silica so that the thickness of the enamel becomes 0.1 mm to 1.0 mm by brushing or spraying. Next, the cast iron pipe body after painting is placed in a heating furnace, heated to a temperature range of 600 ° C. to 1000 ° C., baked within a range of 10 minutes to 180 minutes, and then gradually cooled at a cooling rate of 200 ° C./min or less. Cool down. After this, inspect and store.

  In this way, a cast iron pipe having high corrosion resistance and excellent water quality and hygiene can be manufactured with enamelled inner and outer surfaces.

  The above is the case where the present invention is applied to a method for manufacturing a cast iron pipe, but the case where the present invention is applied to a method for manufacturing a metal pipe such as an iron pipe is the same as that of a cast iron pipe.

  Next, the present invention will be further described with reference to examples.

  The inner and outer surfaces of a cast iron pipe body made of a ductile cast iron pipe having a diameter of 100 mm, a wall thickness of 7.5 mm, and a length of 700 mm were blasted by grit blasting to remove rust and oxide scale from the inner and outer surfaces of the cast iron pipe body.

  Next, on the inner and outer surfaces of the cast iron pipe body subjected to the surface finishing treatment, 70 wt% silica and 30 wt% of the remaining glass powder and stone powder are contained by using an airless spray device so that the thickness of the enamel becomes 0.3 mm. Painted frit.

  Next, the cast iron pipe body coated with frit was placed in a heating furnace and heated at 850 ° C. for 30 minutes. Then, it took out from the heating furnace and cooled at a speed | rate of 100 degree-C / min.

  In this way, cast iron pipes with enamelled inner and outer surfaces were produced.

  And the composite cycle test was done with respect to the outer surface side of the said cast iron pipe. The test conditions are as follows.

Combined cycle test equipment: CPY-90 type manufactured by Suga Test Instruments.
Salt spray test: satisfying the performance specified in JIS Z 2371.
Drying test:
(A) Temperature conditions: (RT + 10 ° C.) to 70 ± 1 ° C.
(B) Humidity condition: 25 ± 5% rh at a temperature of 60 ° C.
Wet test (high temperature):
(A) Temperature conditions: (RT + 10 ° C.) to 50 ± 1 ° C.
(B) Humidity condition: 95% rh or more at a temperature of 50 ° C.
Outside air introduction test: About no outside air temperature / temperature and humidity control.
Test cycle: Cycle A in Annex C (normative) of JIS K 5600-7-9.
Number of test cycles: 360 cycles.

  As a result of this combined cycle test, it was confirmed that there was no occurrence of red rust and the like, which was good.

  As can be seen from the results, according to the cast iron pipe of the present invention, it was confirmed that high anticorrosion performance was maintained over a long period of time.

  Moreover, in order to confirm water quality hygiene, the leaching property test and the environmental hormone analysis test were performed on the inner surface side of the cast iron pipe. The test conditions were as follows.

Leachability test:
Test method: JWWA Z 108 (water supply equipment / leaching test method).
Test conditions: contact area ratio: 550 cm ² / L, leaching time: 16 hours,
Leaching temperature: 23 ° C, conditioning: none.
Analysis item: Ministry of Health and Welfare Ordinance No. 15 “Ministerial Ordinance Establishing Technical Standards for Water Supply Facilities”
Item 2 and JWWA K 139 (Ductile cast iron pipe for water supply
Items listed in the leachability of synthetic resin coatings.

  As a result of this leachability test, the quality standards were satisfied for all analysis items.

Environmental hormone analysis test:
Analysis method: Performed by gas chromatograph mass spectrometer (GC / MS).

  As a result of this analytical test, environmental hormones such as bisphenol A were not detected.

1: Cast iron pipe body 2: Enamel

Claims (10)

  An enameled metal pipe, characterized in that an enamel is formed on at least an inner surface of a metal pipe body constituting the duct.   2. The enameled metal pipe according to claim 1, wherein the content of silica in the enamel is in the range of 50 wt% to 100 wt%.   The metal pipe body according to claim 1 or 2, wherein the metal pipe body is made of cast iron or iron.   A metal pipe body is subjected to a surface finishing treatment, and then a hollow frit mainly composed of silica is applied to at least an inner surface of the metal pipe body subjected to the surface finishing treatment, and then fired in a heating furnace, A method for producing a metal pipe, characterized by gradually cooling and thus enforcing at least the inner surface of the metal pipe main body.   The method for producing a metal pipe according to claim 4, wherein the content of silica in the enamel frit is in the range of 50 wt% to 100 wt%.   The method for manufacturing a metal pipe according to claim 4 or 5, wherein a firing temperature of the metal pipe main body is in a range of 600 ° C to 1000 ° C.   The method for manufacturing a metal pipe according to any one of claims 4 to 6, wherein a firing time of the metal pipe main body is within a range of 10 minutes to 180 minutes.   The method of manufacturing a metal pipe according to any one of claims 4 to 7, wherein a thickness of the enamel is in a range of 0.1 mm to 1.0 mm.   The method for manufacturing a metal pipe according to any one of claims 4 to 8, wherein a cooling rate of the metal pipe main body is 200 ° C / min or less.   The method for manufacturing a metal pipe according to any one of claims 4 to 9, wherein the metal pipe main body is made of cast iron or iron.

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