JP2014017457A5 - - Google Patents
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- JP2014017457A5 JP2014017457A5 JP2012155970A JP2012155970A JP2014017457A5 JP 2014017457 A5 JP2014017457 A5 JP 2014017457A5 JP 2012155970 A JP2012155970 A JP 2012155970A JP 2012155970 A JP2012155970 A JP 2012155970A JP 2014017457 A5 JP2014017457 A5 JP 2014017457A5
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(3)コア内を伝送させる伝送路は単一モード伝送路であることが望ましく、極微細加工を実現させるためにコアのサイズを小さくし、コアと第1クラッド層の比屈折率差を大きくしている。そのためにコア内に屈折率を高くするための添加物を多く添加させているが、コアの外周の第1クラッド層との軟化温度の差が大きくなり、ファイバを製造する上で熱膨張係数の差が出てきて安定的な製造がしにくくなっている。
(3) The transmission path for transmission through the core is preferably a single-mode transmission path, and the core size is reduced in order to realize ultrafine processing, and the relative refractive index difference between the core and the first cladding layer is increased. doing. Therefore, many additives for increasing the refractive index are added in the core, but the difference in softening temperature between the core and the first cladding layer on the outer periphery of the core becomes large, and the coefficient of thermal expansion is increased in manufacturing the fiber. The difference comes out and it is difficult to make stable production.
また、高出力のレーザ光を得るためには、コアガラスは、その径が大きく、かつ信号増幅光における高次モードを抑制させるためにクラッドとの比屈折率差はあまり大きくない方が好ましい。そこで、SiO2系ガラスからなるクラッド内に複数の空孔を設けることにより、このクラッドの屈折率を等価的に下げることができ、しかも上記空孔の数量m、空孔径d、空孔間隔Λなどで上記等価屈折率を制御することができる。これにより、コアガラス内に添加する希土類元素の添加量を濃度消光を生じさせない範囲で最適化できるように、希土類元素を含んだSiO2系のコアガラス内に添加する屈折率を高めるための添加物(例えば、GeO2、P2O5、TiO2、Al2O3、BaO、ZrO2、Nなど)の量を低減し、調節することができるようになる。その結果、励起光による希土類イオンの励起効率の最適化が出来、励起光から信号光増幅へのエネルギー変換効率を向上させることができる。
また別の効果として、結果的にコアガラスの軟化温度をクラッドの軟化温度に近い値にすることができるので、ファイバ母材を高温状態に加熱してファイバを製造する際の軟化温度の差による形状変形を小さく抑えることができると共に、製造し易くなる。すなわち、ファイバ母材の形状に相似したファイバ形状を容易に実現することができる。特に、軟化温度を近づけることによってファイバ内に所望形状の空隙を保ったままのファイバ構造を実現するのに有効である。
In order to obtain a high-power laser beam, it is preferable that the core glass has a large diameter and that the relative refractive index difference with the cladding is not so large in order to suppress higher-order modes in the signal amplification light. Therefore, by providing a plurality of holes in the cladding made of SiO 2 glass, the refractive index of the cladding can be reduced equivalently, and the number m of the holes, the hole diameter d, the hole interval Λ The above-mentioned equivalent refractive index can be controlled by, for example. Thus, as the addition amount of the rare earth element added to the core glass can be optimized within a range that does not cause concentration quenching, to increase the refractive index to be added to the core glass of SiO 2 system including a rare earth element The amount of additives (eg, GeO 2 , P 2 O 5 , TiO 2 , Al 2 O 3 , BaO, ZrO 2 , N, etc.) can be reduced and adjusted. As a result, the excitation efficiency of the rare earth ions by the excitation light can be optimized, and the energy conversion efficiency from the excitation light to the signal light amplification can be improved.
As another effect, the softening temperature of the core glass can be made close to the softening temperature of the clad, resulting in a difference in softening temperature when the fiber preform is heated to a high temperature state. Shape deformation can be suppressed to a small level, and manufacturing becomes easy. That is, a fiber shape similar to the shape of the fiber preform can be easily realized. In particular, it is effective for realizing a fiber structure in which a desired shape of the air gap is maintained in the fiber by bringing the softening temperature closer.
図5に本発明のファイバの第4実施例を示す。このファイバは、その中心部に希土類元素を含んだSiO2系の矩形状構造のコアガラス1を有し、その外周に断面矩形状のSiO2ガラスからなる低屈折率のクラッド2dを有し、該クラッド2dの外周を8角形の構造をしたFを添加したSiO2ガラス4dで囲み、該Fを添加したSiO2ガラス4dをSiO2ガラス5dで覆ったことを特徴とするファイバである。このファイバも矩形状構造のSiO2ガラスからなる低屈折率のクラッド2dの外周が広い面積の空隙3dで覆われているので、励起光の伝送する伝送路のNAを高くすることができる。なお、Fを添加したSiO2ガラス4dは、クラッド2dの角部が4箇所(6−1、6−2、6−3、6−4)で接した状態で該クラッド2dを覆っており、該Fを添加したSiO2ガラス4dの外周をSiO2ガラス5dで覆っている。
このような構造のファイバも、母材を線引してファイバ化すると矩形状構造のSiO2ガラスからなる低屈折率のクラッド2dの4つの角はわずかに丸くなるが、これも許容できるものである。また、8角形構造のFを添加したSiO2ガラス4dの8つの角は、ファイバ線引時にわずかに丸くなるが、これはファイバの特性に影響を与えることは少ないので、十分に許容できるものである。
FIG. 5 shows a fourth embodiment of the fiber of the present invention. This fiber has a core glass 1 having a SiO 2 -based rectangular structure containing a rare earth element at its center, and a low refractive index clad 2d made of SiO 2 glass having a rectangular cross section on the outer periphery thereof. enclosed in SiO 2 glass 4d with the addition of F in which the octagonal structure the outer periphery of the cladding 2d, is a fiber which is characterized in that covering the SiO 2 glass 4d with the addition of the F in SiO 2 glass 5d. In this fiber, the outer periphery of the low refractive index clad 2d made of SiO 2 glass having a rectangular structure is covered with a wide space 3d, so that the NA of the transmission path for transmitting the excitation light can be increased. Note that the SiO 2 glass 4d to which F is added covers the cladding 2d in a state where the corners of the cladding 2d are in contact with each other at four locations (6-1, 6-2, 6-3, 6-4). The outer periphery of the SiO 2 glass 4d to which the F is added is covered with the SiO 2 glass 5d.
In the fiber having such a structure, when the base material is drawn into a fiber, the four corners of the low refractive index clad 2d made of SiO 2 glass having a rectangular structure are slightly rounded. This is also acceptable. is there. In addition, the eight corners of the SiO 2 glass 4d to which F having an octagonal structure is added are slightly rounded when the fiber is drawn, but this is sufficiently acceptable because it hardly affects the fiber characteristics. is there.
この製造方法を用いると、希土類元素を添加したSiO2系コアガラス1の外周に密着性良くSiO2ガラスからなる低屈折率のクラッド2を形成することができるので、コアガラス1の外周の構造不均一性による散乱損失を低減させることができる。
また、上記SiO2ガラスからなる低屈折率のクラッド2と共に上記最外周のSiO2ガラス5も液体原料の出発原料を固化、加熱して一緒に形成することにより母材を低コストで製造することができる。上記において、希土類元素を添加したコアガラス1はVAD法で製造したGeO2とAl2O3を添加した多孔質のSiO2ガラスロッドにYbCl 3 の水溶液を含浸させた後に乾燥、塩素雰囲気中での高温加熱によって製造した。そして、その希土類元素を添加したコアガラス1の外周にSiO2ガラスを20μmの厚みに形成して製造したガラスロッド13である。
When this manufacturing method is used, the low refractive index clad 2 made of SiO 2 glass can be formed on the outer periphery of the SiO 2 -based core glass 1 to which the rare earth element is added. Scattering loss due to non-uniformity can be reduced.
Further, solidifying the starting material of low refractive index the outermost SiO 2 glass 5 also liquid source with the cladding 2 made of the SiO 2 glass, to manufacture a preform at a low cost by forming together by heating Can do. In the above, the core glass 1 to which the rare earth element is added is impregnated with an aqueous solution of YbCl 3 on a porous SiO 2 glass rod to which GeO 2 and Al 2 O 3 added by the VAD method are added, and then dried in a chlorine atmosphere. Produced by high temperature heating. Then, a glass rod 13 produced by forming a SiO 2 glass in a thickness of 20μm on the outer circumference of the core glass 1 with the addition of the rare earth elements.
Claims (18)
該Fを添加したSiO2ガラス層の外周の大部分を空隙で覆い、該空隙の外周にFを添加したSiO2ガラスを該Fを添加したSiO 2 ガラス層の外周の少なくとも3箇所で接して覆う構造とし、前記Fを添加したSiO2ガラスの外周をFを添加しないSiO2系ガラスで覆ったことを特徴とするファイバ。 A high refractive index core glass made of SiO 2 glass containing rare earth elements in the center of the fiber, a clad made of SiO 2 glass not containing rare earth elements provided on the outer periphery of the core glass, and an outer periphery of the cladding And a SiO 2 glass layer added with F,
Most of the outer periphery of the SiO 2 glass layer to which F has been added is covered with a gap, and the SiO 2 glass to which F has been added is in contact with the outer periphery of the gap at at least three locations on the outer periphery of the SiO 2 glass layer to which the F has been added. a structure for covering the fiber, characterized in that the outer periphery of the SiO 2 glass doped with the F is covered with SiO 2 glass without addition of F.
該Fを添加したSiO2ガラス層の外周の大部分を空隙で覆い、該空隙の外周にFを添加しないSiO2系ガラスを該Fを添加したSiO 2 ガラス層の外周の少なくとも3箇所で接して覆う構造としたことを特徴とするファイバ。 A high refractive index core glass made of SiO 2 glass containing rare earth elements in the center of the fiber, a clad made of SiO 2 glass not containing rare earth elements provided on the outer periphery of the core glass, and an outer periphery of the cladding And a SiO 2 glass layer added with F,
Covered with voids most of the outer periphery of the SiO 2 glass layer with the addition of the F, contact with SiO 2 glass without addition of F on the outer periphery of the void in at least three places of the outer periphery of the SiO 2 glass layer with the addition of the F A fiber characterized by having a structure to cover.
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CN105487171A (en) * | 2014-10-08 | 2016-04-13 | 中兴通讯股份有限公司 | Bended multi-mode optical waveguide and manufacturing method thereof |
KR101708259B1 (en) * | 2015-04-30 | 2017-02-21 | 한국광기술원 | double-clad fiber and fiber laser using the same |
CN106876850A (en) * | 2015-12-14 | 2017-06-20 | 泰科电子(上海)有限公司 | Dielectric waveguide |
CN109143464B (en) * | 2018-11-29 | 2019-03-12 | 中聚科技股份有限公司 | A kind of rear-earth-doped glass optical fiber and preparation method thereof |
CN111552028B (en) * | 2020-04-21 | 2021-04-20 | 中国科学院西安光学精密机械研究所 | Radiation-resistant erbium-doped optical fiber for space and preparation method thereof |
EP4160832A4 (en) * | 2020-06-05 | 2023-12-13 | National University Corporation Saitama University | Mode-locking method selectively using two different wavelengths, and laser device using said method |
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JP2003329869A (en) * | 2002-05-17 | 2003-11-19 | Mitsubishi Cable Ind Ltd | Double-clad fiber and method for manufacturing the same |
JP2004356318A (en) * | 2003-05-28 | 2004-12-16 | Fujikura Ltd | Photoexciting method of optical amplification medium fiber, photoexcited light incidence structure to optical amplification medium fiber, optical fiber amplifier and optical fiber laser |
JP2005289766A (en) * | 2004-04-02 | 2005-10-20 | Nippon Sheet Glass Co Ltd | Preform for optical element, optical element manufactured using the same, and method for manufacturing preform for optical element |
JP5102979B2 (en) * | 2006-06-12 | 2012-12-19 | 三菱電線工業株式会社 | Laser beam emission method |
JP2009168914A (en) * | 2008-01-11 | 2009-07-30 | Mitsubishi Cable Ind Ltd | Optical fiber and method for manufacturing the same |
JP5227038B2 (en) * | 2008-01-16 | 2013-07-03 | 三菱電線工業株式会社 | Optical fiber |
JP2010129886A (en) * | 2008-11-28 | 2010-06-10 | Hitachi Cable Ltd | Optical fiber for fiber laser, and fiber laser |
JP5676152B2 (en) * | 2010-06-15 | 2015-02-25 | 湖北工業株式会社 | Optical fiber and manufacturing method thereof |
JP5555134B2 (en) * | 2010-10-26 | 2014-07-23 | 湖北工業株式会社 | Optical fiber |
WO2012172996A1 (en) * | 2011-06-16 | 2012-12-20 | 古河電気工業株式会社 | Multicore amplifying optical fiber |
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