JP5676152B2 - Optical fiber and manufacturing method thereof - Google Patents

Description

  The present invention can realize a rectangular flat top profile suitable for patterning of a line shape with higher dimensional accuracy, surface modification of a material surface, material annealing, material scribe processing, etc. by transmitting laser light. The present invention relates to an optical fiber having a rectangular core with a rectangular cross section and a method for manufacturing the same.

  Conventionally, an optical fiber is generally used which has a core with a circular section having a high refractive index and a clad with a low refractive index covering the outer periphery thereof. This optical fiber has a circular cross-sectional structure as a whole, and is used as a single mode fiber, multimode fiber, step index type fiber, focusing type fiber, etc., depending on the core diameter, the refractive index distribution between the core and the clad, the propagation mode, etc. It has been put to practical use in fields such as optical fiber sensors, optical measurement, optical information equipment, optical processing, and optical medicine as well as for optical communications.

  On the other hand, an optical fiber that can transmit a laser beam into an optical fiber to realize a rectangular flat top profile suitable for line-shaped patterning, surface modification of the material, material annealing, material scribe processing, etc. In particular, so-called rectangular core fibers having a rectangular core in cross section are attracting attention (see Patent Documents 1 and 2). And products have been announced by domestic wire manufacturers (Sumitomo Electric, Fujikura Electric, Furukawa Electric, Mitsubishi Electric, etc.). A typical structure of a rectangular core fiber is shown in FIGS.

The rectangular core fiber has a circular cross-sectional structure as a whole, the core 20 having a high refractive index and a rectangular cross section is made of quartz glass, and the cladding 21 having a low refractive index covering the outer periphery is made of SiO added with F (fluorine). ₂ glass. The core 20 shown in FIG. 11 has a square cross section, and the core 20 shown in FIG. 12 has a rectangular cross section.

Although the manufacturing method of these rectangular core fibers has not been published yet, it is considered that the manufacturing method is performed according to the procedure shown in FIG. 13 by applying the prior art. First, a quartz glass rod 22 is cut to form a quartz glass block 22 having a rectangular cross section, and then an SiO ₂ glass layer 23 to which F is added is formed on the outer periphery of the quartz glass block 22 to obtain a fiber preform 24. The glass layer 23 can be formed using a VAD (Vapor Phase Axial Deposition) method, an external method, or the like. Thereafter, the fiber preform 24 is inserted from the tip into the high-temperature electric furnace 25 at a speed P as indicated by an arrow 26, and the tip of the fiber preform 24 melted in the electric furnace 25 is indicated by an arrow 27. Thus, the rectangular core fiber 28 is obtained by stretching at a speed V, winding the drum 29 on the drum 29, and rotating the drum 29.

JP 2009-168914 A JP 2009-169110

The structure of the rectangular core fiber described above and the manufacturing method thereof have the following problems.
(1) The relative refractive index difference between the core and the clad Δ << Δ = [(core refractive index−cladding refractive index) / core refractive index] × 100% >> can only be about 0.5% at maximum. . Therefore, light confinement in the rectangular core is weak. As a result, when the fiber is bent or shaken during use of the fiber, the distribution of light in the core is likely to change or light leaks into the cladding. Moreover, it is difficult to accurately irradiate a workpiece with a rectangular laser beam.
(2) The coupling efficiency of the laser beam into the fiber is low, and it is difficult to effectively use the laser beam for processing.
(3) Since the optical confinement state in the core is likely to change when the fiber is bent, bending loss is likely to occur.
The problem to be solved by the present invention is to provide an optical fiber that can stably confine light in a core and has a small bending loss, and a method for manufacturing the same.

The first invention is a glass tube;
A glass core having a rectangular cross section disposed in the glass tube,
An optical fiber, wherein the glass core is in contact with an inner peripheral surface of the glass tube at at least two contact portions, and a gap extending between the glass core and the glass tube other than the contact portion extends in a longitudinal direction. It is.
In this case, the outer shape of the cross section of the glass tube is preferably substantially circular or rectangular. The glass core preferably has a value higher than the refractive index of the glass tube. Furthermore, the glass tube is preferably formed from high silicate glass (glass containing at least 96% SiO ₂ ), and SiO ₂ glass is preferably used for the rectangular glass core.
In the optical fiber according to the first invention, the gap functions as a cladding, and the optical signal propagates in the glass core.

  According to a second invention, in the first invention, the glass core is in contact with the inner peripheral surface of the glass tube at four contact portions.

According to a third invention, in the first or second invention, an SiO ₂ film to which F (fluorine) is added is formed on the inner peripheral surface of the glass tube, and the F (fluorine) is added to the glass core. The SiO ₂ film is in contact with at least two contact portions.

According to a fourth invention, in the first or second invention, an SiO ₂ film to which F is added is formed on the outer peripheral surface of the glass core, and the glass core passes through the SiO ₂ film to which the F is added. The glass tube is in contact with the inner peripheral surface of at least two contact portions.

  In the optical fibers according to the first to fourth inventions, the glass tube preferably has a rectangular or circular through-hole. Also, the outer shape of the cross section of the glass tube may be rectangular.

  According to a fifth aspect of the present invention, a glass core material having a rectangular cross section is inserted into the through-hole portion of the glass tube material having a through-hole extending from one end side to the other end side so as to contact at least two places with the glass tube material. An optical fiber comprising: a step of obtaining a fiber preform; and a step of heating and melting the tip of the fiber preform and drawing the optical fiber while drawing the tip of the preform at a predetermined speed. It is a manufacturing method.

A sixth invention is the step of forming the SiO ₂ film F is added to the inner peripheral surface of the glass tube material having a through hole extending from one end to the other end,
A step of obtaining a fiber preform by inserting a glass core material having a rectangular cross section so as to be in contact with the SiO ₂ film to which the F is added in at least two places in the glass tube material, and a tip of the fiber preform A method of manufacturing an optical fiber, comprising: heating and melting, and drawing the optical fiber while drawing the tip of the preform at a predetermined speed.

A seventh aspect of the invention, the step of cross-section to form a SiO ₂ film doped with F in the outer periphery of the rectangular glass core material,
The glass core material having the SiO ₂ film formed on the outer periphery is inserted into a glass tube material having a through hole extending from one end side to the other end side so as to be in contact with the inner peripheral surface of the glass tube material at at least two locations. Obtaining a fiber preform;
A method of manufacturing an optical fiber, comprising: heating and melting the tip of the fiber preform, and drawing the optical fiber while drawing the tip of the preform at a predetermined speed.

The eighth invention comprises a thin tube having a through hole extending from one end side toward the other end side;
A transverse section having a polygonal core disposed in the through hole of the thin tube,
The optical fiber is characterized in that the core is in contact with the inner peripheral surface of the thin tube at at least two contact portions, and is a gap portion extending in the longitudinal direction between the core other than the contact portion and the thin tube. is there. The narrow tube and the core can be formed using glass or resin.

The present invention has the following effects.
First, in the first invention, a glass core having a rectangular cross section is arranged inside the glass tube so as to be in contact with the inner peripheral surface of the glass tube at at least two contact portions, and the other portions than the contact portions extend in the longitudinal direction. It was made to be a void. Therefore, the outer periphery of most of the rectangular glass core through which the optical signal propagates becomes a void, that is, an air layer. For example, when the glass core is formed from SiO ₂ glass, the ratio of the glass core to the void The difference in refractive index is about 30%. Therefore, most of the optical signal is confined in the rectangular glass core and propagates so that the light distribution in the cross section of the glass core has a substantially uniform rectangular pattern, and is irradiated onto the processed object surface. Therefore, the processed object surface can be processed into a rectangular shape with high dimensional accuracy. When SiO ₂ glass added with B (boron) or SiO ₂ glass is used as the material of the glass tube, the difference in refractive index between the glass tube and the rectangular glass core is small or almost not. Since the contact portion with the glass core is almost close to line contact, the contact area is extremely small as compared with the gap portion. Therefore, most of the optical signal is confined in the rectangular glass core and propagates in the glass core with a substantially uniform rectangular light distribution.

  Here, like the optical fiber of the second invention, a rectangular glass core is ideally arranged in the glass tube so as to be in contact with the inner peripheral surface of the glass tube at the four contact portions. The structure which becomes a space | gap except a contact part is the most preferable. However, the rectangular glass core can be held on the inner peripheral surface of the glass tube even in a configuration where the two contact portions are in contact with each other.

As in the third invention, when the SiO ₂ film to which F is added is formed on the inner peripheral surface of the glass tube, the refractive index difference at the contact portion can be made slightly larger than in the first invention. Therefore, the optical signal can be further confined in the rectangular glass core and propagated in the glass core with a substantially uniform rectangular light distribution.

As in the fourth invention, when an SiO ₂ film to which F is added is formed on the outer periphery of a rectangular glass core, an optical signal can be more tightly confined and transmitted in the rectangular glass core. In addition, by covering the rectangular glass core with the SiO ₂ film to which F is added, it is possible to prevent moisture in the air from being mixed into the rectangular glass core from the gap for a long time. . Furthermore, it can suppress that the impurity in air adheres to the surface of a rectangular glass core, and increases optical loss.

  In the first to fourth inventions, when the glass tube has a through-hole having a circular cross section, the rectangular glass core is easily held so as to be in contact with the inner surface of the glass tube at at least two contact portions. In addition to the contact portion, it is possible to form a void portion having a large area other than the contact portion. Therefore, the optical signal can be confined in the glass core and propagated with a substantially uniform rectangular light distribution, and the processed object surface can be processed with high dimensional accuracy.

  In addition, even when the glass tube has a through-hole having a rectangular cross section, it is easy to hold the rectangular glass core so as to contact the inner surface of the glass tube with at least two or four contact portions. Can do. And since it can be set as the space | gap part of a large area except a contact part, an optical signal can be confined and propagated in a rectangular glass core.

  When manufacturing the above optical fiber, a glass tube material having a through hole and a glass core material having a rectangular cross section are used. For example, a glass tube material having a substantially circular or substantially rectangular cross section is a conventional glass processing material. It can be easily realized using technology. Also, a rectangular glass core material can be easily realized by using a conventional glass processing technique. Next, in the step of obtaining a fiber preform by inserting a rectangular glass core material so as to be in contact with the inner surface of the glass tube material at least at two or four locations, the glass tube material is heated by heating the outer periphery of the glass tube material. A rectangular glass core material can be fixed and held on the inner surface of the substrate. The fiber preform is heated and melted while being inserted into a high-temperature electric furnace at a predetermined speed, and the optical fiber is realized through a process of drawing the preform while drawing the tip of the preform at a predetermined speed. Can do. That is, a high-performance rectangular core fiber can be obtained by a simple process and an inexpensive method.

Further, the optical fiber includes a step of forming a SiO ₂ film to which F has been added in advance on the inner surface of the glass tube material, and inserting a glass core having a rectangular cross section so as to be in contact with the film surface at at least two locations. It can be realized by a step of obtaining a reform, a step of drawing the fiber preform while drawing and stretching the tip of the preform at a predetermined speed while being heated and melted while being inserted into a high-temperature electric furnace at a predetermined speed. it can. Here, a conventionally used gas phase chemical reaction method can be used as a method of forming a SiO ₂ film in which F is added in advance on the inner surface of the glass tube material. By forming a SiO ₂ film in which F is added in advance on the outer periphery of a rectangular glass core material by using a gas phase chemical reaction method, an optical fiber having a lower loss and a long-term reliability can be obtained. Can do.

The optical fiber which concerns on the 1st Example of this invention is shown, (a) is a cross-sectional view, (b) is an external view. The cross-sectional view which shows the optical fiber which concerns on the 2nd Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 3rd Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 4th Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 5th Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 6th Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 7th Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 8th Example of this invention. The cross-sectional view which shows the optical fiber which concerns on the 9th Example of this invention. The figure for demonstrating the manufacturing method of the optical fiber which concerns on one Example of this invention. The structure of the conventional optical fiber (rectangular core fiber) is shown, (a) is a cross-sectional view, (b) is an external view. The figure which shows the structure of another conventional rectangular core fiber. The figure which shows the manufacturing method of the conventional rectangular core fiber.

  Hereinafter, specific examples of the present invention will be described.

1A and 1B show an optical fiber 10 according to a first embodiment of the present invention, in which FIG. 1A is a cross-sectional view and FIG. 1B is an external view. The optical fiber 10 is composed of a glass tube 3 having a through hole having a circular cross section and a glass core 1 made of SiO ₂ glass having a rectangular cross section disposed in the through hole. The glass tube 3 is made of, for example, silicon dioxide glass to which boron (B) is added (hereinafter referred to as “high silicate glass”) or quartz glass. High silica glass is at least containing SiO ₂ 96%, a glass having a slightly lower refractive index than the refractive index of the SiO ₂ glass, high silica glass tubes are commercially available as trade name Vycor glass tube. An SiO ₂ film 2 to which fluorine (F) is added is formed on the inner surface of the glass tube 3 using a gas phase chemical reaction method, and the film 2 and four contact portions 5a, 5b, 5c, 5d are formed. A glass core 1 is formed in the glass tube 3 so as to be in contact therewith. With such a configuration, four gap portions 4 extending from one end side of the glass tube 3 to the other end side are formed between the glass tube 3 and the glass core 1. In the optical fiber configured as described above, the gap 4 functions as a cladding, and the optical signal propagates through the glass core 1.

  The glass core 1 is in contact with the membrane 2 at four contact portions 5a, 5b, 5c, and 5d. As will be described later, this contact portion melts while inserting the preform into the high-temperature electric furnace at a predetermined desired speed. The glass is melted and fixed when realizing the fiber while drawing the drawn glass at a predetermined desired speed. As described above, in the optical fiber according to the present embodiment, the rectangular glass core 1 is covered with the gaps 4 except for the four contact portions, so that the relative refractive index difference between the glass core 1 and its adjacent medium. Is a very large multimode fiber.

  The optical fiber 10 according to the present embodiment transmits a laser beam into the optical fiber 10 to irradiate a processed material, patterning of a line shape with higher dimensional accuracy, surface modification of the material surface, material annealing, material It is used to perform scribe processing. Therefore, the shape and size of the glass core 1 may be set depending on the processing size of the workpiece, and specifically, a range of about 2 μm square to 500 μm square is preferable. Since the optical fiber 10 according to the present embodiment is not a communication fiber, the diameter of the optical fiber is preferably in the range of 50 μm to 700 μm in consideration of the handleable range, the drawable range, the bendability, and the like. In particular, in the optical fiber of the present embodiment, the rectangular glass core 1 is covered with a gap, that is, an air layer, except for four places in contact with the film 2, so that there is a relative refractive index difference between the glass core 1 and the adjacent medium. Become very large. Therefore, the optical signal propagates in the rectangular glass core 1 in a state of almost total reflection, and the optical power distribution in the glass core 1 forms a substantially rectangular flat top beam profile. Therefore, even if the optical fiber is bent with a small bending radius, the increase in light loss is small, and the light distribution in the rectangular glass core 1 is not easily changed. In addition, since there is a gap with a large cross-sectional area, the mechanical strength by bending is strong, so that an optical fiber having a larger diameter can be realized.

When the optical fiber 10 according to this embodiment is actually manufactured and used, the outer peripheral surface is coated with a polymer material, a metal material, or the like like a communication fiber.
For example, when this fiber 10 is used by propagating a laser beam in the ultraviolet region with a short wavelength, the rectangular glass core 1 is made of a material that has been subjected to chlorine treatment so that the content of OH groups is extremely reduced ( The OH group content is preferably 100 ppb or less.
When, for example, SiO ₂ glass added with boron (B) is used as the material of the glass tube 3, the SiO ₂ film 2 added with fluorine (F) may be omitted.

With respect to the following prototype of the optical fiber 10 of the present example, the loss was measured using laser beams with wavelengths of 350 nm and 632.8 nm, and as a result, values of 42 dB / km and 7 dB / km could be obtained. Even when this fiber was bent to a bending radius of 5 mm, there was almost no increase in optical loss. Furthermore, it was found that the fluctuation of the optical power distribution in the rectangular glass core 1 was very small.
(Prototype example)
・ Glass core 1 size: 50μm square ・ Contents of OH groups in glass core 1 components: approx. 50ppb
-The thickness of the SiO ₂ film 2 to which F is added: about 8 μm
・ Diameter of optical fiber: 150μm

  FIG. 2 shows a cross-sectional view of an optical fiber 10 according to a second embodiment of the present invention. This optical fiber is different from the structure of the first embodiment in that the rectangular glass core 1 has a rectangular cross section. The optical fiber having such a structure is effective for performing wide patterning, surface modification of the material surface, material annealing, material scribing, and the like. Therefore, in the second embodiment, the rectangular size of the glass core 1 is preferably a width of about 5 μm to about 500 μm and a height of about 2 μm to about 300 μm.

FIG. 3 shows a cross section of an optical fiber 10 according to a third embodiment of the present invention. This optical fiber is different from the first embodiment in that the cross section of the through hole of the glass tube 3 is rectangular. Also in the third embodiment, the SiO ₂ film 2 to which the inner peripheral surface F of the glass tube 3 is added is formed, and the rectangular shape so as to contact the film 2 at the four contact portions 5a, 5b, 5c, and 5d. A glass core 1 having a shape is held. As a simple method of processing the cross-section of the through hole of the glass tube 3 into a rectangular shape, the inner surface of the glass rod is cut and then cleaned, and is cleaned in an electric furnace that can be heat-treated in a chlorine atmosphere at a temperature of 1200 ° C. Although there is a method of performing a time chlorine atmosphere treatment, a method of polishing the inner surface of the glass rod may be used. Or you may implement | achieve by cutting the inner surface of a glass rod.

FIG. 4 shows a cross section of an optical fiber 10 according to a fourth embodiment of the present invention. The optical fiber 10 is different from the structure of the first embodiment in that the SiO ₂ film 2 to which F is added is formed on the outer peripheral surface of the glass core 1 instead of the inner peripheral surface of the glass tube 3. In the optical fiber according to the fourth embodiment, the glass core 1 is in contact with the inner peripheral surface of the glass tube 3 through four contact portions 5a, 5b, 5c, and 5d through the SiO ₂ film 2 to which F is added. Is arranged. Accordingly, the glass core 1 is adjacent to the gap 4 (air layer) except for the contact portion, and the optical signal propagates through the rectangular glass core 1.

In this optical fiber 10 as well, an optical signal can be transmitted more tightly confined in the rectangular glass core 1. Further, since the outer peripheral surface of the glass core 1 is covered with the SiO ₂ film 2 to which F is added, it is possible to prevent moisture contained in the air in the gap from diffusing and mixing into the rectangular glass core 1 for a long time. be able to. Moreover, it can suppress that the impurity in air adheres to the surface of the rectangular glass core 1, and increases optical loss.
In this embodiment, the glass tube 3 is made of quartz glass because the SiO ₂ film 2 to which F is added in advance is formed on the outer peripheral surface of the rectangular glass core 1. This is because an optical fiber with lower loss can be realized by using quartz glass.

FIG. 5 shows a cross section of an optical fiber 10 according to a fifth embodiment of the present invention. The optical fiber 10 is different from the structure of the first embodiment in that the outer shape of the cross section of the glass tube 3 is substantially rectangular. Also in this optical fiber, the SiO ₂ film 2 to which F is added is formed on the inner peripheral surface of the glass tube 3, and the four contact portions 5a, 5b, 5c, 5d on the inner surface of the film 2 are in contact with each other. A rectangular glass core 1 is held in the glass tube 3.

Here, the glass tube 3 having a substantially rectangular outer cross-section was prepared by preparing a quartz glass tube having a circular outer cross-section and grinding the four outer surfaces of the glass tube. Then, by drawing a fiber preform obtained from the glass tube material into a fiber, an optical fiber having a structure with four rounded corners can be obtained.
When the optical fiber of the present invention is used for various processing, it is attached to an ultra-high-precision processing apparatus that requires processing of extremely high dimensional accuracy and high-definition patterns on the order of microns. For this reason, it is necessary to fix the optical fiber firmly in a narrow area so as not to cause position fluctuations, and to hold the optical fiber with an ultra-small tool. When the outer shape of the cross section of the optical fiber has a substantially rectangular structure as in this embodiment, it is difficult to shake in the radial direction and the axial direction, and it is easy to hold the optical fiber with an ultra-small tool. Suitable for processing.

FIG. 6 shows a cross-sectional view of an optical fiber 10 according to a sixth embodiment of the present invention. The optical fiber 10 has a fifth point in that a glass tube 3 having a through-hole having a rectangular cross section is used, and a SiO ₂ film 2 to which F is added is formed on the inner surface of the glass tube 3. This is different from the structure of the embodiment. Also in this optical fiber, the rectangular glass core 1 is held in the glass tube 3 so as to be in contact with the film 2 at the four contact portions 5a, 5b, 5c, and 5d.

FIG. 7 shows a cross-sectional view of an optical fiber 10 according to a seventh embodiment of the present invention. This optical fiber 10 is different from the sixth embodiment in that an SiO ₂ glass tube (trade name: Vycor glass tube) to which B (boron) is added is used as the material of the glass tube 3. The other configuration is the same as that of the sixth embodiment.

FIG. 8 shows a cross-sectional view of an optical fiber 10 according to an eighth embodiment of the present invention. This optical fiber 10 is an embodiment using a glass tube 3 (a trade name: Vycor glass tube, which is a SiO ₂ glass tube to which B is added) having a substantially circular outer cross section. A through hole having a substantially rectangular cross section is formed inside the glass tube 3. A rectangular glass core 1 is disposed in the glass tube 3 so as to be in contact with the inner surface of the glass tube 3 at four contact portions 5a, 5b, 5c, and 5d. In the optical fiber of this example, the SiO ₂ film added with F is not formed on either the inner peripheral surface of the glass tube 3 or the outer peripheral surface of the glass core 1.

  FIG. 9 shows a cross-sectional view of an optical fiber 10 according to a ninth embodiment of the present invention. This optical fiber 10 is different from the eighth embodiment in that the cross section of the through hole of the glass tube 3 is rectangular and the cross section of the glass core 1 is square. With such a configuration, the glass core 1 is disposed in the glass tube 3 so as to be in contact with the inner peripheral surface of the glass tube 3 at the two contact portions 5a and 5b.

  FIG. 10 shows an embodiment of the optical fiber manufacturing method of the present invention. This manufacturing method is roughly divided into four steps. First, (a) is a step of creating a glass core 1 having a rectangular cross section. The glass core material 1A, which is the material, is obtained by grinding a quartz glass rod with a diameter of 12 mm, which is made by the VAD (Vapor Phase Axial Deposition) method and de-OH group treatment at a high temperature of 1200 ° C in a chlorine atmosphere. And processed into a shape of about 8 mm square.

Next, as shown in (b), a SiO ₂ glass film (wavelength 0.63) in which F is added using a conventional MCVD (Modified Chemical Vapor Deposition) method in a quartz glass tube 3A having a diameter of 12 mm and a wall thickness of 1.5 mm. A refractive index of 1.445) at about 50 μm was formed.

After that, as shown in (c), it was prepared in (a) so as to come into contact with the film on the inner surface of the quartz glass tube 3A formed with SiO ₂ glass film added with F as shown in (b) at four locations. A rectangular glass core material 1A was inserted. And the fiber preform 6 was implement | achieved by heating the outer periphery of this glass-tube material 3A, and fixing the part which the said 4 places contact to a film surface.

  Finally, the fiber preform 6 is inserted at 10 mm / min into the core tube 8 in the high-temperature electric furnace 7 heated to a maximum temperature of 1980 ° C., and melted in the core tube 8 of the high-temperature electric furnace. An optical fiber (rectangular core fiber) 10 could be realized by winding the tip of the reformer around the drum 9 while drawing the fiber at 50 m / min.

In addition, this invention is not limited to the said Example. The size of the glass core (rectangular core) of the optical fiber and the diameter of the entire optical fiber are not limited to the above embodiments. The outer periphery of the optical fiber may be covered with a protective film made of a polymer material or a metal material.
In the above description, air is present in the gap 4. However, when an optical fiber is actually used, an inert gas may flow from the laser incident side into the optical fiber (in the gap). A thin quartz glass thin film may be attached to both end faces of the fiber.

  In the above embodiment, a rectangular core having a square or rectangular cross section is disposed in the glass tube so as to be in contact with the glass tube at at least two contact portions, but a square other than a square or a rectangle (such as a trapezoid or a rhombus). Alternatively, a glass core having a cross-sectional shape such as a polygon other than a quadrangle (triangle, pentagon, etc.) may be arranged in the glass tube. In short, the entire inner peripheral surface of the glass tube, the entire outer peripheral surface of the glass core, and the entire inner peripheral surface of the glass tube are not in contact with each other, but the glass core is fixed and held in the glass tube with at least two points in line contact. As a result, it is sufficient that a gap is formed between the inner peripheral surface of the glass tube and the outer peripheral surface of the glass core.

Further, the present invention mainly aims to provide an optical fiber useful for processing, annealing, and surface modification by propagating laser light from the ultraviolet region to the near infrared region. Although the SiO ₂ glass is used as the material, the optical fiber of the present invention can be applied to other uses, and in that case, it is possible to use not only the glass core but also a resin core. Further, if the core can be fixed and held while forming the gap, it is possible to use a resin thin tube instead of the glass tube.

1 ... glass core 1A ... glass core material 2 ... F SiO was added ₂ film 3 ... glass tube 3A ... glass tubing 4 ... void portion 5a, 5b, 5c, 5d ... contact portions 6 fiber preform 7 ... electric furnace 8 ... Core tube 9 ... Drum 10 ... Optical fiber

Claims (6)

A glass tube having a through-hole having a square cross section and a square outer shape of the cross section ;
A glass core having a rectangular cross section disposed in the through hole of the glass tube;
Wherein the inner peripheral surface of the glass tube is a low refractive index than said glass core, F are formed SiO ₂ film is added, the glass core and the SiO ₂ film in which the F is added 4 contact with the contact portion of the point, characterized in that the air gap cross-section extending in the longitudinal direction of the triangular shape between the SiO2 film where the said glass core other than the contact portion F is added is four formed And optical fiber. A glass tube having a through-hole having a square cross section and a square outer shape of the cross section ;
A glass core having a rectangular cross section disposed in the through hole of the glass tube;
On the outer peripheral surface of the glass core, a SiO ₂ film added with F, which has a lower refractive index than the glass core, is formed, and the glass core passes through the SiO ₂ film added with F. the contact with the contact portion of the glass tube and at four, the gap portion cross-section extending in the longitudinal direction of the right-angled triangle between the SiO2 film where the said glass tube other than the contact portion F is added four forms An optical fiber characterized by being made . The optical fiber according to claim 1 or 2 ,
The glass tube is made of glass containing at least 96% SiO ₂ , and the rectangular glass core is made of SiO ₂ glass. Step cross section extending from one end to the other end have a square-shaped through hole, the outer shape of the cross-section to form a SiO ₂ film F is added to the inner peripheral surface of the glass tubing is square,
A step of obtaining a fiber preform by inserting a glass core material having a rectangular cross section so as to come into contact with the SiO ₂ film to which the F is added in four places in the glass tube material,
A method of manufacturing an optical fiber, comprising: heating and melting the tip of the fiber preform, and drawing the optical fiber while drawing the tip of the preform at a predetermined speed. Forming a SiO ₂ film in which F is added to the outer periphery of a glass core material having a rectangular cross section;
Cross-section extending to the other end have a square-shaped through-hole from one side, in the transverse plane glass tubing outer shape is square, so as to contact the inner circumferential surface and four places of the glass tubing, the A step of obtaining a fiber preform by inserting a glass core material having a square cross section formed on the outer periphery of a SiO ₂ film to which F is added;
A method of manufacturing an optical fiber, comprising: heating and melting the tip of the fiber preform, and drawing the optical fiber while drawing the tip of the preform at a predetermined speed. In the manufacturing method of the optical fiber according to claim 4 or 5 ,
The glass tube material is formed of glass containing at least 96% SiO ₂ , and the rectangular glass core is made of SiO ₂ glass.

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