JP2014014317A - Oil composition for frying - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oil composition for frying, which restricts oil absorption of a fried material having a dough to be swollen and allows a fried food product with a non-fatty flavor to be produced.SOLUTION: In preparing a fried food product, an oil composition including one or two or more emulsifiers is used to provide a fried food product with less oil absorption, the emulsifiers being selected from the group consisting of sucrose stearate with an HLB value of 1, sucrose palmitate with an HLB value of 1, and sucrose behenate with an HLB value of 3.

Description

  The present invention relates to an oil composition for frying used for producing fried foods having a low oil absorption rate of fried seeds.

  Compared with cooking methods such as “baking” and “stir-fry”, fried foods are wrapped in edible oil at around 160 to 185 ° C., so that the amount of water in the ingredients evaporates much more, and the moisture content from the dough It is a feature of the taste that the oil evaporates and the oil is replaced and “lightly crisp”.

  However, in recent years, there has been an increasing need for reducing the calorie content of fried foods due to the health-consciousness of general consumers, and there has been a tendency to reduce oil content. In particular, confectionery such as yeast donuts and cake donuts, fritters using egg whites, puffed puffed snacks, rice crackers, instant fried noodles, etc. The oil content tends to increase.

  As a means to reduce the oil content of these frying foods, the raw materials and blending of the dough have been studied conventionally, but the development of frying oils and fat compositions that have a high oil absorption suppression effect with the frying oil used has not progressed sufficiently. .

  On the other hand, sucrose fatty acid ester is a compound in which a single or mixed fatty acid is bonded to one or more of eight hydroxyl groups of sucrose and substituted with an ester type, and depending on the type of fatty acid and the number of substituents, Hydrophilic lipophilic balance (HLB) value is different and widely used as a food additive in different applications depending on the HLB value.

  As an oil and fat composition containing sucrose fatty acid ester, triglyceride is the main component, the average substitution degree is 5 to 7, and the total of the polyesters of the triester or higher in the total sucrose fatty acid ester is 85% by mass or more, monoester Is an oil and fat composition containing 0.1 to 9.5% by mass of a sucrose fatty acid ester having an HLB value of 0 or more and less than 3 in a composition of 5% by mass or less and a diester of 10% by mass or less. And the absorption of fats and oils to a cooking target object is suppressed, As a result, the oil-fat composition for fried cooking which can be cooked by use of a small amount of fats and oils (for example, refer patent document 1), or [SME] <50 % By weight, [STE] ≧ 15% by weight ([SDE] + [STE] + [STeE]) / [SE]> 0.5 (where [SME], [SDE], [STE] and [STeE] ] Represents the content of mono-, di-, tri-, and tetra-esters of sucrose fatty acid in the sucrose fatty acid ester mixture, and [SE] represents the total amount of each ester constituting the sucrose fatty acid ester mixture.) Bake and fry A sucrose fatty acid ester mixture suitable for cooking such as (see, for example, Patent Document 2) has been reported.

JP 2005-218380 A JP 7-147902 A

  An object of the present invention is to provide an oil and fat composition for frying, which has a low oil absorption rate of fried seeds and can provide a light-flavored fried food.

  The present inventors diligently studied the composition of the oil composition for frying used in the preparation of fried food, and sucrose stearate having an HLB value of 1, sucrose palmitate having an HLB value of 1, and an HLB value of 3. When using a frying fat composition in which one or two or more emulsifiers selected from the group consisting of sucrose behenic acid esters are mixed with edible fats and oils, it is confirmed that a fried food with low oil absorption can be obtained. The invention has been completed.

  That is, the present invention provides [1] sucrose stearate having an HLB value of 0.5 to 1.5, sucrose palmitate having an HLB value of 0.5 to 1.5, and an HLB value of 2.5. Oil composition for frying characterized by containing one or more emulsifiers selected from the group consisting of sucrose behenate of ~ 3.5, and [2] an oil composition for frying The oil composition for frying according to [1] above, or [3] the frying according to [1] or [2] above, which is contained in an amount of 0.08 to 0.55% by mass relative to the total mass of the product. It is related with the manufacturing method of the fried food characterized by heat-cooking fried seeds in the oil-fat composition.

  According to the fat and oil composition for frying of the present invention, it is possible to reduce the oil absorption rate of fried seeds in the production of fried foods, provide a light-flavored fried food that is not oily, and reduce the amount of fats and oils to be used. Can also reduce costs. Such an effect is particularly effective in fried foods in which the dough expands, such as donuts, fritters using egg whites, puffed snacks, rice crackers, and instant fried noodles.

  As the fat and oil composition for frying of the present invention, a sucrose stearate having an HLB value of 0.5 to 1.5, a sucrose palmitate having an HLB value of 0.5 to 1.5, and an HLB value of 2.5 to If it is a composition consisting of edible fats and oils containing one or more emulsifiers selected from the group consisting of 3.5 sucrose behenic acid esters (hereinafter sometimes referred to as “the emulsifier”), there is no particular limitation. However, emulsifiers such as sucrose unsaturated fatty acid esters such as sucrose oleate other than the emulsifier can be used in combination. However, the proportion of the emulsifier in the total amount of the emulsifier is preferably 40% by mass or more, particularly 50 to 100% by mass. The HLB value is one of the indexes representing the effect of the surfactant. The higher the HLB value, the higher the hydrophilicity, the lower the HLB value, the higher the lipophilicity, and the HLB value is 0-3. If present, it hardly disperses in water. Although there are various formulas for calculating the HLB value, the HLB value in the present invention is based on the Griffin method which can be calculated by the following formula.

  As described above, the HLB value of the sucrose stearate is required to be 0.5 to 1.5, preferably 0.6 to 1.4, and preferably 0.7 to 1.3. More preferably, 0.8 to 1.2 is more preferable, and 0.9 to 1.1 is particularly preferable.

  Examples of the sucrose stearate having an HLB value of 0.5 to 1.5 include sucrose monostearate, sucrose distearate, sucrose tristearate, sucrose tetrastearate, sucrose pentastearate, and sucrose. 60% by mass or more, preferably 70% by mass or more, more preferably, based on one or a mixture of two or more selected from the group consisting of hexastearate, sucrose heptastearate, and sucrose octastearate Mention may be made of sucrose fatty acid esters and compositions thereof containing 80% by mass or more, more preferably 90% by mass or more, particularly preferably 95% by mass or more, and especially sucrose distearate without sucrose monostearate, Sucrose tristearate, sucrose tetrastearate, sucrose pentastearate, sucrose 60% by mass or more, preferably 70% by mass or more, more preferably, based on one or a mixture of two or more selected from the group consisting of xanthate, sucrose heptastearate, and sucrose octastearate A sucrose fatty acid ester or a composition thereof containing 80% by mass or more, more preferably 90% by mass or more, and particularly preferably 95% by mass or more can be suitably exemplified. Product name "F10" sucrose stearate (HLB value is about 1, stearic acid is about 70%, monoester is about 0%, di-tri-polyester is about 100%) and products from Mitsubishi Chemical Foods The name “S170” sucrose stearate (HLB value is about 1, sucrose stearate is about 70%, monoester is about 1%, Ester can be mentioned about 99%).

  As described above, the HLB value of the sucrose palmitate is required to be 0.5 to 1.5, preferably 0.6 to 1.4, and preferably 0.7 to 1.3. More preferably, 0.8 to 1.2 is more preferable, and 0.9 to 1.1 is particularly preferable.

  Examples of the sucrose palmitate having an HLB value of 0.5 to 1.5 include sucrose monopalmitate, sucrose dipalmitate, sucrose tripalmitate, sucrose tetrapalmitate, sucrose pentapalmitate, and sucrose. 60% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more, based on one or a mixture of two or more selected from hexapalmitate, sucrose hepta palmitate, and sucrose octapalmitate More preferably, sucrose fatty acid esters and compositions thereof containing 90% by mass or more, particularly preferably 95% by mass or more can be mentioned, and especially sucrose monopalmitate is not included, and sucrose dipalmitate, sucrose tripalmi is not included. Tate, sucrose tetrapalmitate, sucrose pentapalmitate, sucrose hexapalmitate 60% by mass or more, preferably 70% by mass or more, more preferably 80% by mass, based on one or a mixture selected from the group consisting of sucrose, sucrose hepta palmitate, and sucrose octapalmitate %, More preferably 90% by mass or more, and particularly preferably 95% by mass or more, sucrose fatty acid esters and compositions thereof can be suitably exemplified. Specifically, trade names “Mitsubishi Chemical Foods” P170 "sucrose palmitate (HLB value is about 1, sucrose palmitate is about 80%, monoester is about 1%, di-tri-polyester is about 99%).

  As described above, the HLB value of the sucrose behenate is required to be 2.5 to 3.5, preferably 2.6 to 3.4, and preferably 2.7 to 3.3. More preferably, 2.8 to 3.2 is more preferable, and 2.9 to 3.1 is particularly preferable.

  Examples of the sucrose behenate having an HLB value of 2.5 to 3.5 include sucrose monobehenate, sucrose dibehenate, sucrose tribehenate, sucrose tetrabehenate, sucrose pentabehenate, sucrose hexabehenate, sucrose heptabehenate, and sucrose. 60% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more, still more preferably 90% by mass or more, particularly preferably 95%, based on one or more mixtures selected from sugar octabehenate as a main component. The sucrose fatty acid ester and its composition containing not less than mass% can be mentioned, and in particular, sucrose monobehenate is not included, sucrose dibehenate, sucrose tribehenate, sucrose tetrabehenate, sucrose pentabehenate, sucrose hexabehenate, sucrose heptabehenate And a mixture of one or two or more selected from the group consisting of sucrose octabehenate as a main component, 60% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more, and further preferably 90% by mass or more. Particularly preferred examples include sucrose fatty acid esters containing 95% by mass or more, and compositions thereof. Specific examples include sucrose behenate esters of trade name “B30” of Daiichi Kogyo Seiyaku Co., Ltd. , Sucrose behenate of the trade name “B370” of Mitsubishi Chemical Foods, Inc. (HLB value is about 3, sucrose behenate is about 70%, monoester is about 20%, di-tri-polyester is about 80% ).

  The emulsifier and the emulsifier containing the emulsifier (hereinafter, these may be collectively referred to as “the emulsifier and the like”) may be 0.08 to 0.000 based on the total mass of the frying oil / fat composition of the present invention. It is preferably contained 55% by mass, more preferably 0.1-0.5% by mass, more preferably 0.15-0.45% by mass, and 0.2-0.4% by mass. More preferably, if it is less than 0.08% by mass, the effect of the oil composition having a low oil absorption rate of the present invention may be insufficient, and if it exceeds 0.55% by mass, it is advantageous in terms of cost. The effect of the present invention may not be sufficient. As long as the effects of the present invention are exhibited, as described above, in addition to sucrose oleate, sorbitan fatty acid ester, propylene glycol fatty acid ester, polyglycerol fatty acid ester, polyglycerol condensed ricinoleate, glycerol fatty acid ester, and their Other emulsifiers such as derivatives may be used in combination with the emulsifier.

  As a method for preparing the oil composition for frying of the present invention, a method of adding the above-mentioned emulsifier and the like to edible oil and fat and uniformly dissolving or dispersing the oil and fat in a known method can be exemplified.

  The above edible oils include rapeseed oil, safflower oil, safflower oil, cottonseed oil, corn oil, rice bran oil, soybean oil, palm oil and other vegetable oils; lard, beef tallow and other animal oils; and their hydrogenated oils, transesterification The 1 type (s) or 2 or more types selected from the group which consists of oil can be mentioned. In addition, fats and oils having nutritional characteristics such as health and healthy, for example, oils and fats containing medium chain fatty acids can be used.

  The oil and fat composition used for the production of the fried food of the present invention is generally used for flavoring agents such as natural flavors, synthetic flavors, animal and plant extracts, seasoning oils, and edible fats and oils as long as the effects of the present invention are exhibited. Additives to be added to, for example, tocopherol and silicone resin can be appropriately added.

  As a manufacturing method of fried food in the present invention, fried food is manufactured by heating the frying fat composition of the present invention and heating the fried seed in the oil composition adjusted to a predetermined temperature. It is not particularly limited as long as it is a method. For example, a method for producing a fried food in which a fried seed is immersed in the oil and fat composition of the present invention or heated in a floating state can be preferably mentioned. "Does not include heat treatment. Specifically, 1 to 5 kg or more of the oil composition for frying of the present invention is adjusted to 160 to 200 ° C, preferably 170 to 190 ° C, more preferably 175 to 185 ° C, and further preferably 178 to 182 ° C. The step of heating and adding the frying seed and heating for 60 to 180 seconds, preferably 90 to 150 seconds, more preferably 110 to 130 seconds can be mentioned. A step of inverting 1 to 3 times or more may be included.

  Examples of the above-mentioned fried seeds include fried seeds with dough that expands during frying, for example, flours mainly made from flour, yeast, salt, sugar, water, milk, Yeast donuts prepared by fermenting, forming, proofing, and frying the dough mixed with other auxiliary materials; instead of using yeast, the dough added with baking powder is shaped and fried without fermentation. Cake donuts prepared by the above; donuts such as rice donuts, cream donuts, piloshiki etc. with ingredients in the above-mentioned yeast donuts and cake donuts; egg yolks, water, milk and edible oils Fritters that wrap the ingredients in a mix of whipped egg white with salt and salt; fry to fry; puffed snacks; rice confectionery; The noodles can be mentioned. Specifically, for 80 to 120 parts of flour mainly composed of wheat flour, 5 to 20 parts of whole egg and 20 to 50 parts of cold water have a mass per piece of 20 to 35 g. You can list the raw donut dough.

  When the oil absorption rate of fried food when fried using only edible fats and oils is 100%, the relative value of the oil absorption rate of fried food when fried using the oil and fat composition of the present invention is Less than 100%, preferably less than 99.8%, more preferably less than 97.4%, even more preferably less than 95%, even more preferably less than 91.7%, and particularly preferably less than 89.6%.

  EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, the technical scope of this invention is not limited to these illustrations.

  Semi-solid fat mixed with refined palm oil and rapeseed salad oil in a ratio of 75:25 was used as an edible fat. As the emulsifier, emulsifiers shown in Table 1 below were used.

なお、上記のＨＬＢ値は製造者の表示値である。

In addition, said HLB value is a display value of a manufacturer.

  The emulsifiers of Examples 1 to 7 shown in Table 2 below were added to 1.5 kg of the above edible fats and oils so as to have a predetermined addition ratio to prepare seven types of frying fats and oil compositions. Moreover, the edible oil and fat which does not add an emulsifier was made into control oil and fat.

  10 parts of pasteurized egg whole egg adjusted to 5 ° C, 35 parts of cold water adjusted to 11 ° C are added to 100 parts of commercial cake donut mix powder (C10, manufactured by Nippon Flour Mills), and after mixing, After taking the floor time for 10 minutes, the dough was divided into about 27 g by a donut cutter to prepare a pre-fried donut, and the mass of each pre-fried donut was measured. The oil and fat composition was carried into a frying container and the temperature was adjusted to 180 ° C., and 4 raw donuts before frying were added at a time. The frying process was performed by inverting twice every 40 seconds after charging the raw donut, and the frying process was completed after 120 seconds. Frying was performed 8 times for each oil and fat composition, and 32 fried donuts were prepared using 7 types of oil and fat compositions. Control donuts fried using control fats and oils were similarly prepared.

  The amount of oil and fat composition in the container for frying before frying and the amount of oil and fat composition in the container for frying after frying were measured, and the oil absorption when each oil and fat composition was fried was calculated using the following formula.

  Next, an oil absorption rate relative value (oil absorption rate) was calculated by the following equation, assuming that the oil absorption amount of the control was 100%.

  The results are shown in Table 2 below.

(result)
As apparent from Table 2 above, it was confirmed that when the frying process was performed by adding the emulsifier of the present invention to edible fats and oils, the oil absorption of the fried food was lower than when no emulsifier was added.

[Comparative example]
As the emulsifier, the emulsifiers shown in Table 3 below were used.

なお、上記のＨＬＢ値は各製造者の表示値である。

In addition, said HLB value is a display value of each manufacturer.

    It carried out like Example 1 except having used the emulsifier of Comparative Examples 1-12 as follows. The oil absorption relative value was calculated with the oil absorption of the donut and the oil absorption of the control as 100%. The results are shown in Table 4 below.

(result)
As is clear from Table 4 above, it was confirmed that the oil composition was not an oil composition having the effect of the present invention, that is, an oil composition having a large oil absorption amount and a low oil absorption rate as compared with the control oil.

Claims (3)

Sucrose stearate having an HLB value of 0.5 to 1.5, sucrose palmitate having an HLB value of 0.5 to 1.5, and sucrose behenic acid having an HLB value of 2.5 to 3.5 A frying oil composition comprising one or more emulsifiers selected from the group consisting of esters. The fat and oil composition for frying according to claim 1, wherein the emulsifier is contained in an amount of 0.08 to 0.55 mass% with respect to the total mass of the fat and oil composition for frying. A method for producing a fried food, characterized in that fried seeds are cooked in the oil composition for frying according to claim 1 or 2.