JP2014009177A - Hair detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair detergent composition giving a warm feeling to scalp, having a sufficient forming effect and detergency, and preventing entanglement of hair during rinsing.SOLUTION: The hair detergent composition contains (A) 50 to 80 mass% of polyethylene glycol having average molecular weight of 190 to 630, (B) an anionic surfactant, (C) cationic polymer having a sugar skelton, and (D) polyoxyalkylene methyl glucoside. The blend mass ratio of the component (D) to the component (C) expressed by (D)/(C) is 0.5 to 30.

Description

  The present invention relates to a hair cleansing composition that has a warming effect and gives smoothness to hair during rinsing.

  The function of shampoo includes removal of excess sebum, but warming the scalp is more effective for removing sebum. However, even when hot water is applied to the head during shampooing, the scalp temperature drops quickly, and the sebum in the clogged pores may not be sufficiently removed. Therefore, a shampoo that generates heat during hair washing and warms the scalp is required.

  So far, a thermal type conditioner using heat of hydration of high-concentration polyethylene glycol (PEG) has been proposed as an invasion product that generates heat. This is to thicken with cation surfactant and hydroxypropyl cellulose using PEG as a solvent.

However, warm-type hair cosmetics using PEG have the disadvantage that hair is entangled during rinsing and the usability is extremely poor. It is known to use a cationized polymer such as cationized cellulose as a method to prevent hair entanglement and squeaking during rinsing, but the cationized polymer is insoluble in PEG and the performance as a shampoo is sufficient. The current situation is that it has not been able to demonstrate.
In addition, the following are mentioned as prior art documents relevant to the present invention.

JP 2001-233743 A

  The present invention has been made in view of the above circumstances, and provides a hair cleansing composition that gives a warm feeling to the scalp, has sufficient foaming and detergency, and can prevent entanglement of hair during rinsing. The purpose is to do. Furthermore, an object of the present invention is to provide a hair cleansing composition having excellent low-temperature storage stability in addition to the above.

  The present inventors diligently studied to achieve the above object, and first tried to solubilize a (cellulose-based) cationic polymer having a sugar skeleton by mixing water with a hair cleansing composition containing PEG. However, although a cationic polymer having a sugar skeleton can be dissolved by mixing a large amount of water, PEG must be 50% by mass or more in order to obtain a warm feeling. It was found that the cationic polymer with a sugar skeleton disperses to some extent in the system, but quickly separates. The cationic polymer having a non-sugar skeleton is insoluble in a system having a PEG content of 50% by mass or more that provides a warm feeling.

Therefore, the present inventors further studied diligently, and investigated a solubility improver for cationic polymers in PEG. As a result, polyoxyalkylene methyl glucoside, in particular, polyoxyalkylene which is a POE adduct of methyl glucose (MGL). By blending ethylene methyl glucose, it was found that a cationic polymer having a sugar skeleton can be dissolved in PEG, and the present invention has been made.
In the present invention, the sense of warmness is a sense of temperature and sense of warmth, and refers to a case where the average score in the examples is 3.0 or more.

Accordingly, the present invention provides the following hair cleaning composition.
[1]
(A) Polyethylene glycol having an average molecular weight of 190 to 630: 50 to 80% by mass,
(B) an anionic surfactant,
(C) a cationic polymer having a sugar skeleton,
(D) Hair washing characterized by containing a polyoxyalkylene methyl glucoside and having a blending mass ratio of (C) and (D) components of 0.5 to 30 represented by (D) / (C) Agent composition.
[2]
(D) The hair cleaning composition according to [1], wherein the component is selected from POE (10) methyl glucoside, POE (20) methyl glucoside, POP (10) methyl glucoside, and POP (20) methyl glucoside.
[3]
(C) The hair cleaning composition according to [1] or [2], wherein the component is cationized cellulose.
[4]
The hair wash according to any one of [1] to [3], wherein the amount of component (C) is 0.04 to 1% by mass and the amount of component (D) is 0.3 to 10% by mass. Agent composition.
[5]
Furthermore, (E) The hair-cleaner composition in any one of [1]-[4] containing 1-30 mass% of polyhydric alcohols other than (A) component.
[6]
The hair cleansing composition according to any one of [1] to [5], which is a warm shampoo.

  According to the present invention, it is possible to provide a hair cleansing composition having a warming effect, sufficient foaming, good dirt removal, and improved hair smoothness during rinsing. In addition to the above, the present invention can provide a hair cleansing composition having excellent low-temperature storage stability.

The hair cleansing composition of the present invention comprises
(A) polyethylene glycol having an average molecular weight of 190 to 630,
(B) an anionic surfactant,
(C) a cationic polymer having a sugar skeleton,
(D) contains polyoxyalkylene methyl glucoside.

[(A) component: polyethylene glycol]
The component (A) of the present invention is polyethylene glycol having an average molecular weight of 190 to 630. When polyethylene glycol is blended, heat is generated due to heat of hydration during use, and heat can be given to the scalp during washing.
Polyethylene glycol is not particularly limited as long as it has an average molecular weight of 190 to 630, and can be used alone or in combination of two or more. Specific examples include polyethylene glycol 200 having an average molecular weight of 190 to 210, polyethylene glycol 300 having an average molecular weight of 280 to 320, polyethylene glycol 400 having an average molecular weight of 380 to 420, and polyethylene glycol 600 having an average molecular weight of 570 to 630. Depending on the product, for example, polyethylene glycol 200 may have a # between the polyethylene glycol and the numerical value, such as polyethylene glycol # 200.

  Among these, the average molecular weight is more preferably 280 to 420, more preferably polyethylene glycol 300 and polyethylene glycol 400, from the viewpoint of the solubility of the cationic polymer and the warmth during coating. By making the average molecular weight within the above range, a warmer sensation is obtained and the solubility of the cationic polymer is also improved.

  In the present invention, the polyethylene glycol 200 test method (p1378) listed in the Quasi-drug Raw Material Standard 2006 (Pharmaceutical Daily) is applied mutatis mutandis to the measurement of the average molecular weight of polyethylene glycol. That is, 42 g of phthalic anhydride is taken, added to a 1 L light-shielded stoppered bottle containing 300 mL of freshly distilled pyridine, and shaken vigorously to dissolve, then left for 16 hours or longer. 25 mL of this solution is accurately weighed and placed in an about 200 mL pressure-proof stopper bottle, and about 0.8 g of polyethylene glycol is precisely weighed, sealed, and placed in a water bath heated to 98 ° C. ± 2 ° C. After maintaining at 98 ° C. ± 2 ° C. for 30 minutes, remove the bottle from the water bath and leave it in the air until it reaches room temperature. Next, 50 mL of 0.5N sodium hydroxide solution is accurately added, and this solution is titrated with 0.5N sodium hydroxide solution. At this time, 5 drops of phenolphthalein / pyridine solution (1 → 100) is used as an indicator. However, the end point of the titration is when the liquid exhibits a light red color lasting 15 seconds. Perform a blank test in the same manner.

The obtained value is applied to the following formula, and the average molecular weight is calculated.
Average molecular weight = {sample amount (g) × 4000} / (ab)
However, a: consumption of 0.5N sodium hydroxide solution in the blank test (mL)
b: Consumption of 0.5N sodium hydroxide solution in the sample test (mL)

  (A) The compounding quantity of the polyethylene glycol of a component is 50-80 mass% in a hair-cleaner composition, Preferably it is 60-74 mass%. If it is less than 50% by mass, the temperature at the time of coating cannot be obtained, and if it exceeds 80% by mass, the solubility of the cationic polymer having a sugar skeleton of the component (C) described later is lowered, and the smoothness during rinsing is lowered. To do.

[(B) component: anionic surfactant]
(B) component of this invention is an anionic surfactant, and can be used individually by 1 type or in combination of 2 or more types. The anionic surfactant removes excess sebum from the scalp and removes excess sebum dirt.

  (B) As an anionic surfactant, for example, polyoxyalkylene alkyl ether sulfate, alkyl sulfate, alkyl benzene sulfonate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, N-acyl glutamate, N-acylmethylalanine salts, alkyl ether carboxylates, acyl isethionates, alkyl sulfosuccinates, α-olefin sulfonates, fatty acid salts and the like can be mentioned.

  Among these, polyoxyalkylene alkyl ether sulfate is preferable from the viewpoint of good foaming and good soil removal. Examples of the alkyl group in the polyoxyalkylene alkyl ether sulfate include octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group and the like. And a dodecyl group, a tridecyl group or a tetradecyl group is preferred. Examples of the alkylene group moiety include a polyoxyethylene group and a polyoxypropylene group, and a polyoxyethylene group is particularly preferable. Moreover, the range of the total average addition mole number in preferable polyoxyethylene alkyl ether sulfate is 2-4. Examples of these counter ions include alkali metal salts such as sodium, alkaline earth metal salts, ammonium salts, alkanolamine salts, and the like. Among these, sodium is preferable.

  (B) The amount of the anionic surfactant is preferably 5 to 20% by mass, more preferably 8 to 15% by mass, from the viewpoint of good foaming and good stain removal in the hair cleaning composition. . By setting it within the above range, foaming and dirt removal are improved, and the solubility of the component (C) is also improved.

[Component (C): Cationic polymer having a sugar skeleton]
The component (C) is a cationic polymer having a sugar skeleton. (A) Since polyethylene glycol is a poor solvent, an ionic polymer is not normally dissolved in polyethylene glycol. However, in the present invention, it is significant that the component (C) insoluble in polyethylene glycol which is not originally dissolved can be dissolved by combining with the component (D).

  (C) A component can be used individually by 1 type or in combination of 2 or more types, Specifically, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose (cationized cellulose) ), O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum (cationized guar gum), cationized starch, cationized tamarind gum, cationized fenugreek gum, cationized tara gum, cationized locust bean gum, etc. Is mentioned.

Commercially available products can be used for these cationic polymers. For example, as the cationized cellulose, Leoguard series (GP, KGP, LP, MGP, MLP (manufactured by Lion Corporation)), Ucare polymer series (JR- 125, JR-400, JR-30M, LR-400, LR-30M (manufactured by Dow Chemical Co.), Katchinal series (HC-100, HC-200, LC-100, LC-200 (manufactured by Toho Chemical Industry Co., Ltd.) )) Etc. are preferred.
There are two types of cationized guar gum, one that dissolves transparently and the other that does not easily become transparent. The most transparent types are Laborum gum CG-M8M (Dainippon Sumitomo Pharma) and Jaguar Excel (Rhodia). Yes.
Examples of the cationized starch include Sensormer CI-50 (manufactured by Nalco Japan).
Cational CTM-200S (manufactured by Toho Chemical Co., Ltd.) as the cationized tamarind gum, Kachinal CF-100 as cationized fenugreek gum, Catinal CF-200 (manufactured by Toho Chemical Co., Ltd.), and Catinal CTR-100 as cationized tara gum Katchinal CTR-200 (manufactured by Toho Chemical Industry Co., Ltd.) and cationized locust bean gum include kachinal CL-200 (manufactured by Toho Chemical Industry Co., Ltd.).

  Among these, cationized cellulose is preferable from the viewpoint of smoothness at the time of rinsing and solubility of the cationic polymer. Specifically, Leogard GP (degree of cationization: 1.2 meq / g, weight average molecular weight) : Leogard MLP (cationization degree: 0.4 meq / g, weight average molecular weight: 1.2 million), kachinal HC-100 (cationization degree: 1.3 meq / g, weight average molecular weight: 400,000), kachinal HC-200 (cationization degree: 1.3 meq / g, weight average molecular weight: 1,000,000), kachinal LC-100 (cationization degree: 0.8 meq / g, weight average molecular weight: 400,000), kachinal LC-200 ( Cation degree: 1.0 meq / g, weight average molecular weight: 1,000,000) is preferable.

The cationization degree of the component (C) is preferably 0.4 to 1.3 meq / g, and more preferably 0.8 to 1.0 meq / g from the viewpoint of smoothness during rinsing and low temperature stability. If it is less than 0.4 meq / g and exceeds 1.3 meq / g, smoothness during rinsing and low-temperature stability may be deteriorated.
In the present invention, the degree of cationization of the cationic polymer was determined from the following formula. The unit of cationization degree meq / g indicates the number of milliequivalents of cationic groups per 1 g of sample.
Cation degree (meq / g)
= (Number of moles of cationized glucose unit in 1 g of polymer compound) x 1000
Number of moles of cationized glucose unit in 1 g of polymer compound = (nitrogen content in polymer compound) / (atomic weight of N)

  The degree of cationization of the cationic polymer can be easily calculated if the chemical structure is clear, but even if the structure such as the monomer ratio is unknown, the measured value of N content by the Kjeldahl method or the like. Can be calculated from The degree of cationization shown in the present invention was calculated based on the value measured by the second method of nitrogen determination method of the general test method of the cosmetic raw material standard which is the Kjeldahl method.

The weight average molecular weight of the component (C) is preferably in the range of 100,000 to 3,000,000, more preferably 300,000 to 2,000,000 in terms of solubility and smoothness during rinsing. By making it within the above range, the smoothness at the time of rinsing becomes better, the dry feel of the hair after drying can be further suppressed, the dissolution in the hair cleaning composition is also good, and the composition is stored. Stability is also good.
In the present invention, the weight average molecular weight is measured by static light scattering measurement. That is, the concentration-suggested refractive index curve using the suggested refractometer of the diluted polymer aqueous solution and the concentration-angle dependency of the scattering intensity using a scattering intensity measuring device are measured, and the concentration 0 and angle 0 of the Zimm plot are measured. The weight average molecular weight can be measured by extrapolating to.

  Although content of (C) component is not specifically limited, 0.04-1 mass% is preferable in a hair-cleaner composition, More preferably, it is 0.1-0.5 mass%. By setting it within the above range, smoothness and foaming during rinsing are improved, and the solubility of the component (C) is also improved.

[(D) component: polyoxyalkylene methyl glucoside]
As the polyoxyalkylene methyl glucoside of component (D), one kind can be used alone, or two or more kinds can be used in combination, but the alkylene group is preferably an ethylene group or a propylene group, and the average added mole number of the polyoxyalkylene group Is not particularly limited, but 10 to 20 is preferable from the viewpoint of the solubility of the cationic polymer of component (C). Specifically, polyoxyethylene (10-20) methyl glucoside, polyoxypropylene (10-20) methyl glucoside and the like can be exemplified. As a suitable component (D), polyoxyethylene (10 to 20) from the viewpoint of imparting a moist and moist feeling to the skin after washing and the solubility of the component (C) without adversely affecting the foam quality. It is preferable to use methyl glucoside.

A commercial item can be used for the said (D) component. Specifically, for example, polyoxyethylene (10) methyl glucoside: Macbiobride MG-10E, polyoxyethylene (20) methyl glucoside: Macbiobride MG-20E, polyoxypropylene (10) methyl glucoside: Macbio Examples include Bride MG-10P, polyoxypropylene (20) methyl glucoside: Macbiobride MG-20P (trade name, all manufactured by NOF Corporation) and the like. In addition, the numerical value in () shows the average added mole number of ethylene oxide or propylene oxide.
Among these, from the viewpoint of the solubility of the cationic polymer, polyoxyethylene (10) methyl glucoside: macbiobromide MG-10E and polyoxyethylene (20) methyl glucoside: macbiobromide MG-20E are preferable.

  Although content of (D) component is not specifically limited, From a viewpoint of providing a moist and moist feeling, 0.3-10 mass% is preferable in a hair-cleaner composition, More preferably, the point of the good foaming From 0.5 to 5% by mass, particularly from 1 to 5% by mass. By setting it within the above range, the solubility of the cationic polymer is better, the smoothness at the time of rinsing becomes better, and foaming and dirt removal can be improved.

  Here, the blending ratio of (C) a cationic polymer having a sugar skeleton and (D) polyoxyalkylene methyl glucoside is (D) / from the viewpoint of solubility and stabilization of component (C) and good foaming. (C) = 0.5-30, more preferably 1-20. If it is less than 0.5, sufficient cationic polymer solubility cannot be obtained, and the smoothness at the time of rinsing is lowered. If it exceeds 30, the foaming is good and the smoothness at the time of rinsing is deteriorated.

[Component (E): Polyhydric alcohol other than component (A)]
In addition to the above components, the hair cleansing composition of the present invention may further contain a polyhydric alcohol other than the components (E) and (A). By blending the component (E), the solubility and warmth of the component (D) can be further improved, and good low-temperature stability can be obtained. Examples of the polyhydric alcohol other than the component (A) include ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyglycerin, sorbitol, xylitol, and trehalose. In the present invention, one of these components can be blended alone or in appropriate combination of two or more, but in particular, the warmth during application, the solubility of the component (C), and the low temperature stability, Glycerin, diglycerin, and propylene glycol are preferred, and glycerin is particularly preferred from the viewpoints of low temperature stability and warmth.

  Although content of (E) component is not specifically limited, 1-30 mass% is preferable in a hair cleaning composition from the warmth at the time of application | coating, and the solubility point of (C) component, and 10-20 mass%. Is more preferable, and 10-15 mass% is still more preferable from the point of the warmth at the time of application | coating. If it is the said range, a cationic polymer can fully melt | dissolve and the smoothness at the time of a rinse can be provided, and a warming effect can also be acquired.

[Other ingredients]
Moreover, the component used for a normal hair cleaning composition other than the said component can be used for the hair cleaning composition of this invention in the range which does not impair the effect of this invention. For example, it is preferable to use a carboxybetaine-type amphoteric active agent in the hair cleanser composition in an amount of 1 to 10% by mass, particularly 2 to 5% by mass in terms of smoothness and foaming during rinsing. In addition, as solubilizers, lower alcohols such as ethanol and isopropanol, cationic surfactants, nonionic surfactants such as polyglyceryl laurate other than component (D), thickening of oils, carboxymethylcellulose, hydroxyethylcellulose, etc. , Chelating agents such as citric acid and EDTA, clouding agents such as ethylene glycol diisostearate and fish scales and mica pieces, fungicides such as isopropylmethylphenol and triclosan, pigments, antiseptic / antifungal agents, refreshing agents, fragrances and fragrance compositions A thing etc. can be mix | blended suitably as needed.

  In the present invention, in order to sufficiently obtain a warm feeling with polyethylene glycol and further improve the solubility of the cationic polymer, the water content is 33% by mass or less, particularly 23% by mass in the hair cleansing composition. The following is preferable. The lower limit is not particularly limited and may not be contained, but is preferably 2.5% by mass or more from the viewpoint of the solubility of the cationic polymer.

  The pH of the hair cleansing composition of the present invention at 25 ° C. (diluted 10-fold with purified water) is preferably 6 to 9, and more preferably 6.5 to 8. In the present invention, the pH can be measured using a pH meter HM-30V (manufactured by Toa DKK Co., Ltd.), and the pH can be adjusted with a pH adjusting agent such as citric acid or potassium hydroxide. Can be used.

  Moreover, the viscosity at 25 ° C. of the hair cleansing composition of the present invention is preferably 0.2 to 7 Pa · s, particularly preferably 0.5 to 6 Pa · s. In the present invention, the viscosity can be measured with a BM viscometer (rotor No. 3, 30 rotations / 20 seconds).

  The hair cleansing composition of the present invention can be widely used in shampoos, rinse-in shampoos, conditioning shampoos, treatment-in shampoos, etc., and has a warming effect, and in particular, warming-type shampoo, warming-type rinse-in shampoo, warming-type conditioning. It can be used as a shampoo or a warm-type treatment-in-shampoo. A warm-type shampoo is preferred because it improves the cleaning power by warming the scalp and can also suppress squeaking during rinsing. These are prepared according to conventional methods. be able to.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example. In the following examples, unless otherwise specified, “%” in the composition indicates mass%, the ratio indicates the mass ratio, and the amount of each component in the table is an amount converted into a pure component.

[Examples 1-41 and Comparative Examples 1-19]
The hair cleaning composition (shampoo) shown in the following table was prepared as follows. (A), (B), (D) component, and common components other than a fragrance | flavor were heated and melt | dissolved at 80 degreeC. After dissolution, component (C) was added with stirring, and after cooling, a fragrance was added. The following evaluation was performed about the obtained hair cleaning composition. The results are also shown in the table.

Solubility of cationic polymer having sugar skeleton <Evaluation method>
A hard transparent glass bottle (capacity 55 mL) having a height of 8 cm and a diameter of 3 cm was filled with 50 mL of the hair cleaning composition and allowed to stand at 25 ° C., and then the appearance was visually evaluated.
<Evaluation criteria>
◎: Transparent ◎ to ○: Almost transparent ○: Slightly clouded △: Cloudy ×: Precipitates

Evaluation of feeling of use “Warmness during application”, “Good foaming”, “Good dirt removal” and “Smoothness during rinsing” were performed by 10 subjects using the hair cleansing compositions shown in the table below. evaluated. Fill the pump container (inner volume 500 mL, discharge volume 3 mL) with the hair cleanser composition, pre-wash the hair with tap water at 42 ° C. at a flow rate of 7 L / min for 30 seconds, and then put the sample on the palm wet with water About 6 mL was taken and extended to the hair with both hands and foamed to evaluate “warmth during application” and “good foaming”. Further, the sample was rinsed with tap water at 42 ° C. and 7 L / min, and “good dirt removal” and “smoothness during rinsing” were evaluated.
Evaluation was carried out in accordance with the following judgment criteria by assigning a 5-level score based on the evaluation criteria shown below and taking the average value of the scores of each sample.

"Warmness during application"
<Evaluation criteria>
5 points: very warm feeling 4 points: warm feeling 3 points: slightly warm feeling 2 points: not feeling warm feeling 1 point: not feeling warm feeling

"Good foaming"
<Evaluation criteria>
5 points: Very good 4 points: Good 3 points: Slightly good 2 points: Slightly bad 1 point: Bad

"Good dirt removal"
<Evaluation criteria>
5 points: Very good 4 points: Good 3 points: Slightly good 2 points: Slightly bad 1 point: Bad

"Smoothness when rinsing"
<Evaluation criteria>
5 points: very smooth 4 points: smooth 3 points: slightly smooth 2 points: slightly not smooth 1 point: not smooth

<Judgment standard for average score>
◎: 4.5 to 5 points ◎ to ○: 4.0 points to less than 4.5 points ○: 3.0 points to less than 4.0 points Δ: 2.0 points to less than 3.0 points ×: 2 Less than 0 points

Low temperature stability (-5 ° C)
A hard transparent glass bottle (capacity 55 mL) having a height of 8 cm and a diameter of 3 cm was filled with 50 mL of the hair cleaning composition and stored at −5 ° C. for 1 month, and then the appearance was visually evaluated.
<Evaluation criteria>
◎: Transparent ◎ to ○: Almost transparent ○: Slightly cloudy but no precipitate Δ: Cloudy but no precipitate x: Precipitate

The raw materials used in Examples and Comparative Examples are shown below.
* 1: PEG # 300K (Lion Corporation)
* 2: PEG # 200K (Lion Corporation)
* 3: PEG # 600K (Lion Corporation)
* 4: Sinoline SPE-1250 (Shin Nihon Rika Co., Ltd.)
* 5: Sinoline SPE-1250 was taken in a stainless steel vat and dried with a vacuum dryer (50 ° C.), and the pure content was concentrated to 80%.
* 6: Scope A-225B (Toho Chemical Co., Ltd.) was placed in a stainless steel vat and dried with a vacuum dryer (50 ° C.) to concentrate the pure content to 70%.
* 7: Amilite GCK-11 (Ajinomoto Co., Inc.)
* 8: Alanon ALA (Kawaken Fine Chemical Co., Ltd.)
* 9: Leo Guard GP (Lion Corporation)
* 10: Sensormer CI-50 (Nalco Japan Co., Ltd.)
* 11: Lapole Gum CG-M (DSP Gokyo Food & Chemical Co., Ltd.)
* 12: Marcote 2001 (Nalco Japan Co., Ltd.)
* 13: Marcote 2003 (Nalco Japan Co., Ltd.)
* 14: Marcote 100 (Nalco Japan Co., Ltd.)
* 15: Marcote 550 (Nalco Japan Co., Ltd.)
* 16: Marcote 280 (Nalco Japan Co., Ltd.)
* 17: Marcote Plus 3330 (Nalco Japan Co., Ltd.)
* 18: Macbiobride MG-10E (NOF Corporation)
* 19: Macbiobride MG-20E (NOF Corporation)
* 20: Macbiobride MG-10P (NOF Corporation)
* 21: Macbiobride MG-20P (NOF Corporation)
* 22: Willbride S-753 (NOF Corporation)
* 23: Unilube DGP-700 (NOF Corporation)
* 24: UNIOR HS-1600D (NOF Corporation)
* 25: PLANTACARE 2000UP (Cognis Japan Co., Ltd.)
* 26: Enagicol L-30B (Lion Corporation)
* 27: Enagicol L-30B was taken in a stainless steel vat and dried with a vacuum dryer (50 ° C.) to concentrate the pure content to 90%.
* 28: HPC-H (Nippon Soda Co., Ltd.)
* 29: Leoguard MLP (Lion Corporation)
* 30: Kachinar LC-100 (Toho Chemical Co., Ltd.)
* 31: Concentrated glycerin (Sakamoto Pharmaceutical Co., Ltd.)
* 32: Diglycerin (Sakamoto Pharmaceutical Co., Ltd.)
* 33: Propylene glycol for cosmetics (Adeka Co., Ltd.)

Claims (6)

(A) Polyethylene glycol having an average molecular weight of 190 to 630: 50 to 80% by mass,
(B) an anionic surfactant,
(C) a cationic polymer having a sugar skeleton,
(D) Hair washing characterized by containing a polyoxyalkylene methyl glucoside and having a blending mass ratio of (C) and (D) components of 0.5 to 30 represented by (D) / (C) Agent composition.   The hair cleansing composition according to claim 1, wherein the component (D) is selected from POE (10) methyl glucoside, POE (20) methyl glucoside, POP (10) methyl glucoside, and POP (20) methyl glucoside.   The hair cleansing composition according to claim 1 or 2, wherein the component (C) is cationized cellulose.   The amount of the component (C) is 0.04 to 1% by mass, and the amount of the component (D) is 0.3 to 10% by mass. The hair cleanser according to any one of claims 1 to 3. Composition.   Furthermore, the hair-cleaner composition of any one of Claims 1-4 which contains 1-30 mass% of polyhydric alcohols other than (E) (A) component.   The hair cleansing composition according to any one of claims 1 to 5, which is a warm shampoo.