JP2014006339A5 - - Google Patents

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JP2014006339A5
JP2014006339A5 JP2012141023A JP2012141023A JP2014006339A5 JP 2014006339 A5 JP2014006339 A5 JP 2014006339A5 JP 2012141023 A JP2012141023 A JP 2012141023A JP 2012141023 A JP2012141023 A JP 2012141023A JP 2014006339 A5 JP2014006339 A5 JP 2014006339A5
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polyester resin
toner
domain
resin
major axis
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JP2012141023A
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JP2014006339A (en
JP5984528B2 (en
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Description

本発明は、ポリエステル樹脂A、ポリエステル樹脂B、及び着色剤を含有するトナーにおいて、
(1)該ポリエステル樹脂Aは、結晶構造をとりうる部位を有する樹脂であり、
(2)該ポリエステル樹脂Bは、結晶構造をとりうる部位を有さない樹脂であり、
(3)透過型電子顕微鏡(TEM)を用いた該トナーの断面観察において、該トナーの断面に該ポリエステル樹脂A由来のドメインを有し、該ドメインの中で長径が最大のドメインの長径が3.0μm以上であり、
(4)該ドメインのアスペクト比(長径/短径)の平均が4.0以上20.0以下であり、
(5)該ポリエステル樹脂Aの融点Taと該ポリエステル樹脂Bの軟化点Tbが下記式1を満足することを特徴とするトナーを提供する。
Ta<Tb ・・・式1
The present invention relates to a toner containing polyester resin A, polyester resin B, and a colorant.
(1) The polyester resin A is a resin having a portion capable of taking a crystal structure,
(2) The polyester resin B is a resin that does not have a portion capable of taking a crystal structure,
(3) In the transmission electron microscope (TEM) cross-section observation of the toner with, the cross-section of the toner has a domain from the polyester resin A, the major diameter of the largest domain diameter in the domain Is 3.0 μm or more,
(4) The average aspect ratio (major axis / minor axis) of the domain is 4.0 or more and 20.0 or less,
(5) A toner is provided in which the melting point Ta of the polyester resin A and the softening point Tb of the polyester resin B satisfy the following formula 1.
Ta <Tb Formula 1

なお、本発明におけるポリエステル樹脂Aドメインの最大長径及び平均アスペクト比は、透過型電子顕微鏡(TEM)を用いたトナーの断面観察を行うことにより測定することができる。測定方法は限定されるものではなく、ポリエステル樹脂Aのドメインの断面観察ができればよい。
The maximum diameter and average aspect ratio of the polyester resin A domain in the present invention can be determined by performing cross section observation of the toner using a transmission electron microscope (TEM). The measuring method is not limited, and it is only necessary to observe the cross section of the domain of the polyester resin A.

Claims (4)

ポリエステル樹脂A、ポリエステル樹脂B、及び着色剤を含有するトナーにおいて、
(1)該ポリエステル樹脂Aは、結晶構造をとりうる部位を有する樹脂であり、
(2)該ポリエステル樹脂Bは、結晶構造をとりうる部位を有さない樹脂であり、
(3)透過型電子顕微鏡(TEM)を用いた該トナーの断面観察において、該トナーはトナー断面に該ポリエステル樹脂A由来のドメインを有し、該ドメインの中で長径が最大のドメインの長径が3.0μm以上であり、
(4)該ドメインのアスペクト比(長径/短径)の平均が4.0以上20.0以下であり、
(5)該ポリエステル樹脂Aの融点Taと該ポリエステル樹脂Bの軟化点Tbが下記式1を満足することを特徴とするトナー。
Ta<Tb ・・・式1
In a toner containing polyester resin A, polyester resin B, and a colorant,
(1) The polyester resin A is a resin having a portion capable of taking a crystal structure,
(2) The polyester resin B is a resin that does not have a portion capable of taking a crystal structure,
(3) In the transmission electron microscope (TEM) the toner of cross section observation using, the toner having the polyester resin A from the domain toner section, major axis in the domain of the largest domain The major axis is 3.0 μm or more,
(4) The average aspect ratio (major axis / minor axis) of the domain is 4.0 or more and 20.0 or less,
(5) A toner wherein the melting point Ta of the polyester resin A and the softening point Tb of the polyester resin B satisfy the following formula 1.
Ta <Tb Formula 1
該ポリエステル樹脂Aと該ポリエステル樹脂Bの質量比率が、5:95〜40:60であることを特徴とする請求項1に記載のトナー。   The toner according to claim 1, wherein a mass ratio of the polyester resin A and the polyester resin B is 5:95 to 40:60. 該ポリエステル樹脂Aが、炭素数6以上12以下の脂肪族ジオールを全アルコール成分に対して85モル%以上含有するアルコール成分と、炭素数6以上12以下の脂肪族カルボン酸を全カルボン酸成分に対して85モル%以上含有するカルボン酸成分とを重縮合して得られたポリエステル樹脂であることを特徴とする請求項1又は2に記載のトナー。 The polyester resin A, the alcohol component and the total carboxylic acid component and an aliphatic dicarboxylic acid having 6 to 12 carbon atoms which contains at least 85 mol% 6 or more carbon atoms 12 The following aliphatic diols, relative to the total alcohol component the toner according to claim 1 or 2, characterized in that a 85 mol% or more containing to Luke carboxylic acid component is a polycondensation polyester resin obtained against. 該トナーが、熱球形化処理を経て製造されたトナーであることを特徴とする請求項1乃至3のいずれか一項に記載のトナー。   The toner according to any one of claims 1 to 3, wherein the toner is a toner produced through a thermal spheronization treatment.
JP2012141023A 2012-06-22 2012-06-22 toner Active JP5984528B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012141023A JP5984528B2 (en) 2012-06-22 2012-06-22 toner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012141023A JP5984528B2 (en) 2012-06-22 2012-06-22 toner

Publications (3)

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JP2014006339A JP2014006339A (en) 2014-01-16
JP2014006339A5 true JP2014006339A5 (en) 2015-07-23
JP5984528B2 JP5984528B2 (en) 2016-09-06

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JP6541471B2 (en) * 2015-06-30 2019-07-10 キヤノン株式会社 TONER AND METHOD FOR MANUFACTURING TONER
JP6632317B2 (en) * 2015-10-16 2020-01-22 キヤノン株式会社 toner
JP6582910B2 (en) * 2015-11-17 2019-10-02 コニカミノルタ株式会社 Toner for developing electrostatic latent image and method for producing the same
JP6589589B2 (en) * 2015-11-17 2019-10-16 コニカミノルタ株式会社 Method for producing toner for developing electrostatic latent image
JP6597319B2 (en) * 2016-01-07 2019-10-30 コニカミノルタ株式会社 Toner for developing electrostatic latent image and method for producing the same
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JP2018031987A (en) 2016-08-26 2018-03-01 富士ゼロックス株式会社 Toner for electrostatic charge image development, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
US9989872B2 (en) 2016-08-26 2018-06-05 Fuji Xerox Co., Ltd. Electrostatic charge image developing toner, electrostatic charge image developer, and toner cartridge
JP2018060067A (en) * 2016-10-05 2018-04-12 富士ゼロックス株式会社 Toner for electrostatic charge image development, electrostatic charge image developer, toner cartridge, image forming apparatus, and image forming method
JP6686941B2 (en) * 2017-03-09 2020-04-22 京セラドキュメントソリューションズ株式会社 Toner for developing electrostatic latent image and manufacturing method thereof
JP7306008B2 (en) 2019-03-26 2023-07-11 富士フイルムビジネスイノベーション株式会社 Electrostatic charge image developing toner, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
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JP2022052629A (en) * 2020-09-23 2022-04-04 富士フイルムビジネスイノベーション株式会社 Electrical static charge image development toner, electrical static charge image developer, toner cartridge, process cartridge, image formation device, and method for forming image
JP2022052625A (en) * 2020-09-23 2022-04-04 富士フイルムビジネスイノベーション株式会社 Toner for electrostatic charge image development, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
JP2022052624A (en) * 2020-09-23 2022-04-04 富士フイルムビジネスイノベーション株式会社 Electrical static charge image development toner, electrical static charge image developer, toner cartridge, process cartridge, image formation device, and method for forming image
WO2022202135A1 (en) * 2021-03-24 2022-09-29 Ricoh Company, Ltd. Resin particles, toner, method for producing resin particles, method for producing toner, developer, toner storage unit, and image forming apparatus

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