JP2013517058A - Method for treating stained fabric - Google Patents

Abstract

  Method for treating a stained fabric The method comprises providing a contact substrate comprising a stain treatment fluid. The contact substrate includes microfibers having a diameter of less than about 5 micrometers. The stain treatment fluid can include a surfactant.

Description

  Processing of clothing stains.

  Many consumers experience stains on clothing when they leave the house, such as when eating out before a theatrical performance. Putting on clothes and getting in public can be embarrassing to the wearer. If such a stain occurs at home, the wearer may be able to choose another outfit, or the stain may be effectively processed by the stain processing system. Once you leave the house, your options will be limited.

  At present, there are stain treatment systems such as pens and wipes that discharge stain treatment fluid and can be used to scrub the stain. This pen is often shaped like a normal drawing marker, and because of its bulk, some consumers only carry such a pen when they have a wallet. However, if you do not carry your wallet, consumers are vulnerable to stains that occur without a stain processing system.

  When carrying a wipe to treat the stain, the consumer can grasp the wipe and scrub the stain. The wipe can include a blend of bleach and surfactant that does not fade. Some of these formulations may have malodors that consumers do not like. Due to the handling of the wipes, such malodors can migrate to the consumer's skin and collide with the fragrance used by the wearer. In addition, some consumers may not like the grip of a wet wipe that has a soapy feel.

  One method of stain processing is to consider the discrete characteristics of the stain and identify an effective treatment strategy for each element. For example, one method is to remove what is removable and bleach what is not removable. Removing stains, especially oily stains, from fabrics can be challenging. Applying a surfactant to the stain can aid in the treatment of oily stains. When the consumer applies pressure to the fiber web while scrubbing the stain, the surfactant stored in the interstitial space between the fibers of the fiber web can be delivered to the fabric. Alternatively, surfactant can be delivered to the fabric from a pen-type structure where the pen head is pushed into the pen to release the stain treatment fluid. To help detach the stain from the fabric, it can be removed using a scraper, fiber web, or brush. Developers of this method have sought to improve efficacy by optimizing the stain treatment fluid.

  With these constraints in mind, there is a continuing, yet unmet need for a processing tool that is compact, portable and convenient to carry.

  Furthermore, there is a continuing, yet unmet need for a stain treatment system that allows consumers to use stain treatment equipment without touching the stain treatment fluid.

  In addition, some of the means to assist in the delivery of the stain treatment fluid to the stain are ongoing, yet addressed, seeking a stain treatment system that can also help transfer the stain from the stain fabric to at least a portion of the stain treatment system. There are not needs.

  Providing a contact substrate comprising a microfiber having a diameter of less than about 5 micrometers, comprising a stain treatment fluid, for treating a blotted fabric; Contacting the fabric and transferring the stain treatment fluid to the stained fabric; and rubbing the stained fabric with the contact substrate. The stain treatment fluid may comprise from about 0.001% to about 99.99% surfactant by weight of the stain treatment fluid.

FIG. 2 is a cutaway perspective view of a package for processing a blotted fabric with the package in a first position. Fig. 2 is a schematic cross-sectional view of a package for processing a stained fabric as shown in Fig. 1. FIG. 2 is a bottom perspective schematic view of a package for processing a blotted fabric illustrated in FIG. 1 with a first side 40 shown in the viewer. FIG. 3 is a schematic diagram of a package for processing a blotted fabric with the package in a second position. FIG. 3 is a schematic diagram of a package for processing a blotted fabric with the package in a second position. FIG. 3 is a schematic side view of a package for processing a stained fabric. A package for processing a stained fabric, wherein the package is in a second position. A package for processing a stained fabric, wherein the package is in a second position. FIG. 3 is a schematic side view of a package for processing a stained fabric. FIG. 3 is a schematic side view of a package for processing a stained fabric. An embodiment of a package in which the package lacks a contact substrate. FIG. 6 is a cutaway perspective view of another embodiment of a package that provides a package capable of dispensing a first stain treatment fluid and a second stain treatment fluid. Schematic of the package coat | covered with the peeling type protective material. Schematic of another embodiment of a package covered with a peelable protective material. FIG. 4 is a diagram of a portion of a Hansen space spherical volume with a Hansen solubility parameter that is positive, with δ _H and δ _P shown in the viewer. FIG. 6 is a portion of a Hansen space spherical volume with a Hansen solubility parameter that is positive, with δ _D and δ _P shown in the viewer. Octopus grease absorption (g / g) vs. relative energy difference between each contact substrate under test and octopus grease under test. A graph showing the location of Hansen solubility parameters in Hansen space (δ _H and δ _P axes are shown) for the contact substrate under test. A graph illustrating the location of the Hansen solubility parameter in Hansen space (δ _D and δ _P axes are shown) relative to the contact substrate under test.

  As used herein, the term “coupled” means that the first member is attached or connected directly or indirectly to the second member, where the first member is the second member. Is attached to or connected to an intermediate member that is directly or indirectly attached to or connected to.

  FIG. 1 shows a cutaway view of a package 10 for treating fabric stains. Package 10 may have any generally planar shape, including a rectangle, square, circle, oval, triangle, pentagon, hexagon, trapezoid, or any other ergonomic shape. The planar shape of the package 10 can provide a package 10 that is convenient for storage and easy to hold firmly before and during use. The package 10 can have a length direction L and a width direction W in the plane of the support layer 20, and can have a Z direction perpendicular to the length direction L and the width direction W. The dimensions of the package 10 may be such that in the length direction L and the width direction W the package has a planar size that is smaller than or equal to a normal wallet size credit card or wallet size photo. it can.

  The package 10 can have a support layer 20. The support layer 20 can be made from any suitably rigid material including thin plastic materials such as polystyrene, polyethylene, polypropylene, or other polymeric materials. The support layer 20 can be sufficiently rigid to maintain the package 10 in a substantially flat shape during storage and transport. In some embodiments, the package 10 is sized and dimensioned to fit conveniently into a wallet, wallet, diaper bag, or pocket.

  The support layer 20 has a first surface 40 opposite to the second surface 30, and the first surface faces the bottom surface of the package 10. The support layer 20 has a line of weakness 130. The first surface 40 of the support layer 20 can have a line of weakness 130. The line of weakness 130 can allow the support layer 20 to break along the line of weakness 130 when the support layer 20 is subjected to a sufficient bending moment. The support layer 20 can have a first elastic limit.

  The line of weakness 130 can be any number of structures that result in controlled fracture in the support layer 20 when a sufficient bending moment is applied around the line of weakness 130. The line of weakness 130 may be selected from the group consisting of fold lines, fragile parts, punched holes, slits, apertures, and combinations thereof. When the package 10 is in a pre-use state, the structure of the support layer 20 can have structural integrity across the line of weakness 130. The fold line can be a scratch, a groove, a compressed portion, or other structure that structurally weakens the support layer 20. The fragile portion can be a series of scratched or compressed portions that structurally weaken the support layer 20 to create a line of weakness 130 that is controllably broken when strain is applied. The line of weakness 130 can be a punched hole or a series of punched holes in the support layer 20. By punching the support layer 20 to form a punched hole or a series of punched holes, a punched hole or a series of punched holes can be formed. The line of weakness 130 can be an aperture formed by selectively removing material from the support layer 20. The line of weakness 130 can be a slit formed by cutting the support layer 20. In use, when the support layer 20 is folded around the line of weakness 130, the line of weakness 130 can be ruptured.

  When such a structure is used, even if such a structure or another structure is used, the breakage of the weak line is caused by, for example, the depth of the folding line, the distance between the punched holes, the size of the aperture, and the size of the slit. It is possible to control the magnitude of the bending moment required for. If fold lines are used, the fold lines can penetrate into the support layer 20 by about 8% to about 10% of the thickness of the support layer 20 measured in the Z direction. When used, the fold line can penetrate into the support layer 20 by less than about 15% of the thickness of the support layer 20.

  The line of weakness 130 can extend between the edges of the support layer 20 as shown in FIG. The line of weakness 130 can extend partially between the edges of the support layer 20.

  Support layer 20 comprises hard styrene, foil, BAREX (available from BP Chemicals Inc. (Naperville, IL, USA)), polyethylene, nylon, polypropylene, and coextrudates and laminates of the above materials, as well as these A material selected from the group consisting of: The thickness of the support layer 20 can be less than about 2 mm, potentially less than about 1 mm, and potentially about 0.1 mm to about 0.5 mm. The support layer can have a length between about 3 cm and about 10 cm and a width between about 2 cm and about 6 cm. A larger support layer 20 may be used in the package 10 designed for home use. The support layer 20 is manufactured by Glenroy, Inc. (Menomonee Falls, WI, USA), a 0.381 mm thick layer of impact resistant styrene, a 0.019 mm thick layer of low density polyethylene and a coated polyester film of 0.0122 thickness. The coated polyester film is disposed toward the outer surface of the package 10.

  The package 10 can have a contact substrate 200 coupled to the first surface 40 of the support layer 20 proximate the line of weakness 130. When the package 10 is used, the contact substrate 200 can be forcibly brought into contact with the fabric to be processed. The bottom of the package 10 is considered to be the surface of the package 10 that is placed toward the fabric to be treated during use.

  The covering layer 50 is connected to the second surface 30 and can be opposed. The covering layer 50 is a polymer film and can have a second elastic limit. The second elastic limit may be greater than the first elastic limit. In other words, the strain that breaks the support layer 20 may be smaller than the strain that breaks the coating layer 50. The coating layer 50 can be a co-extruded film, one of which is a barrier layer such as an ethanol vinyl alcohol film facing outward from the support layer 20 and the other layer is a linear low density polyethylene film. . The covering layer 50 is a barrier layer such as a polyvinyl alcohol film (possibly an EVA film that is a copolymer of ethylene and vinyl acetate) with one layer facing the support layer 20, and the other layer is a line. It can be a coextruded film, which is a low-density polyethylene film. Coating layer 50, Glenroy, Inc. It can be a 0.0508 mm thick layer of high strength polyethylene film available from (Menomonee Falls, WI, USA). Coating layer 50, Glenroy, Inc. It may be a laminate of a 0.0508 mm thick layer of high strength polyethylene film and a 0.019 mm thick layer of medium density polyethylene film available from (Menomonee Falls, WI, USA). 50 is oriented so that the medium density polyethylene layer faces toward the support layer 20.

  The covering layer 50 can have a transmission portion 60. The transmission portion 60 can be substantially aligned with the line of weakness 130 in the support layer 20. The transmission portion 60 can be any number of structures that provide an opening that weighs from the covering layer 50 when using the package 20. The transmission portion 60 may be selected from the group consisting of fold lines, fragile portions, punched holes, slits, apertures, and combinations thereof. When the package 10 is in a pre-use state, the transmission portion 60 can be liquid impermeable. The fold line can be a scratch, a groove, or a compressed portion that structurally weakens the covering layer 50. The fragile portion can be a series of scratches or compression portions that structurally weaken the covering layer and cause the transmission portion 60 to break when strained. The transmission portion 60 can be a punched hole or a series of punched holes that puncture the covering layer 50 to create a punched hole or a series of punched holes. The transmission portion 60 can be an aperture formed by selectively removing material from the covering layer 50. The transmission portion 60 can be a slit formed by cutting or tearing the covering layer 50. The covering layer can have one or more transmission portions 60. For example, there can be at least one, at least two, at least three or more transmission portions 60 in the covering layer 50. The plurality of transfer portions 60 can be practical for distributing the stain treatment fluid 300 more widely to the contact substrate 200. The line of weakness 130 is on the first surface 40 of the support layer 20, on the second surface 30 of the support layer 20, on both the first surface 40 and the second surface 30 of the support layer 20. Can be provided. The line of weakness 130 can be a physical and / or chemical discontinuity within the structure of the support layer 20 or on the surface of the support layer 20.

  The peripheral edge of the covering layer 50 can be connected to the support layer 20. In that more than about 75% of the surface of the portion of the coating layer 50 opposite the second surface 30 of the support layer 20 is connected to the second surface 30 of the support layer 20, the coating layer 50 is The support layers 20 can be connected substantially continuously. The entire surface of the portion of the covering layer 50 that faces the second surface 30 of the support layer 20 may be coupled to the second surface of the support layer 20.

  The package 10 may include a pouch layer 70 connected to the covering layer 50 to form a pouch 80 therebetween, the pouch 80 having a closed volume between the pouch layer 70 and the covering layer 50. Defined. The pouch layer 70 can be directly connected to the support layer 20 to form a pouch therebetween. The pouch 80 can include a stain treatment fluid 300. The pouch layer 70 can be heat sealed to the coating layer 50. Using any known method for attaching two materials, including but not limited to adhesives, glues, ultrasonic bonding, chemical bonding, thermal bonding, and fusion bonding, the pouch layer 70 is coated. 50.

  The pouch layer 70 can be a blown film or a cast film. The pouch layer 70 can be liquid impervious and can be sufficiently durable to prevent penetration or breakage of the pouch layer 70. The pouch layer 70 and the covering layer 50 can also be chemically compatible with the stain treatment fluid 300 contained within the pouch 80. That is, the covering layer 50 and the pouch layer 70 are included in the stain for a long period of time providing chemical and mechanical stability from when the package is manufactured to when the package 10 is used for stain processing. It can be substantially inert to the processing fluid 300 and the external environment. The pouch 80 can include a volume of the stain treatment fluid 300.

  The pouch layer 70 can be a single layer or a multi-layer laminate. The pouch layer 70 can include a foil. The pouch layer 70 can be a layer of sheet material 12 μm thick, an adhesive layer, and a layer of linear low density polyethylene 0.06 mm thick. The pouch layer 70 can be white. A design, usage, or decorative appearance can be printed or otherwise affixed to the pouch layer 70. Pouch layer 70 can be transparent. The pouch layer 70 can be a 12 μm thick layer of metallized polyethylene terephthalate sheet material, an adhesive layer, and a layer of linear low density polyethylene. The pouch layer 70 can be a 12 μm thick silver or aluminum foil layer, an adhesive, a 0.009 mm thick silver or aluminum foil, and a 0.05 mm linear low density polyethylene sheet material. The pouch layer 70 is manufactured by Glenroy, Inc. 0.058 mm thick high strength polyethylene film layer, 0.0191 mm thick chemical resistant film (CRC-1), 0.007 mm thick foil available from (Menomonee Falls, WI, USA) The pouch 70 may be a laminate of a low density polyethylene film having a thickness of 0.0191 mm and a coated polyester having a thickness of 0.0122 mm. It is oriented so as to be directed away from.

  In one embodiment, the pouch layer 70 can be coupled to the support layer 20 and the pouch 80 can be formed therebetween. Using any known method for attaching two materials, including but not limited to adhesives, glues, ultrasonic bonding, chemical bonding, thermal bonding, and fusion bonding, the pouch layer 70 is a support. Can be coupled to layer 20.

  A cross section of the package 10 shown in FIG. 1 is shown in FIG. As shown in FIG. 2, the second surface 30 of the support layer 20 has a first planar region 22 and a second planar region 24 on the surface opposite to the line of weakness 130. As shown in FIG. 2, the transmission portion 60 can be substantially aligned with the line of weakness 130. When the support layer 20 is broken, the pouch 80 is in fluid communication with the contact substrate 200 and the stain treatment fluid 300 is removed from the fracture in the transfer portion 60 and the support layer 20 proximal to the line of weakness 130. It flows into 200. The covering layer 50 can have the same extent in the support layer 20 or in the periphery of the support layer 20. The covering layer 50 can have at least the same extent as the periphery of the support layer 20.

  It illustrates a bottom view of the package 10 in FIG. 3. As shown in FIG. 3, when the support layer 20 is broken, the stain treatment fluid 300 from within the pouch 80 can be transported from the cracks in the support layer 20 into the contact substrate 200. The line of weakness 130 can be at least partially spatially aligned with the contact substrate 200. As shown in FIG. 3, the line of weakness can extend partially between the edges of the support layer 20.

  The package 10 can have a first position in which the first planar region 22 and the second planar region 24 of the support layer 20 are substantially in-plane with each other. As shown in FIG. 4, the package 10 may be moved to a second position where the first planar region 22 and the second planar region 24 face each other in a substantially angled state. it can. The fact that the first planar region 22 and the second planar region 24 are opposed to each other in a substantially angled state means that the first planar region 22 on the second surface 30 of the support layer 20. Means that the inner angle β measured between the second planar region 24 and the second planar region 24 is less than about 90 degrees and they are arranged with respect to each other.

  In the first position, at least a portion of the first planar region 22 and the second planar region 24 can be integral with each other. The support layer 20 can be at least partially intact across the line of weakness 130. In the second position, at least a portion of the support layer 20 can be discontinuous across the line of weakness 130. In the second position, the support layer 20 can be broken proximal to or along the line of weakness 130 such that the pouch 80 is in fluid communication with the contact substrate 200.

  When the package 10 is in the first position, the package 10 can be conveniently carried in a pocket, a wallet pocket, a wallet pocket, or a glove compartment of a dashboard. The generally flat nature of the package 10 is not bulky and provides a shape that can be easily stored.

  As shown in FIG. 4, in the second position, the transmission portion 60 can be fluid permeable. The transmission portion 60 can be fluid permeable as a result of, for example, slitting in the covering layer 50. As shown in FIG. 4, the transmission portion 60 can be a slit that can be slightly stretched open. In the second position, the first planar region 22 and the second planar region 24 are arranged at an interior angle β of less than about 45 degrees as measured between the first planar region 22 and the second planar region 24. Set up. The transmission portion 60 can have various embodiments that provide fluid communication through the covering layer 50. In the second position, the first planar region 22 and the second planar region 24 are disposed with an interior angle β of less than about 10 degrees, an interior angle β of less than about 5 degrees, or an interior angle β of less than about 1 degree. be able to. In the second position, the first planar region 22 and the second planar region 24 can be disposed at an interior angle β between about 0 degrees and about 5 degrees.

  In the second position, the pouch 80 is foldable and the pressure applied from the first planar region 22 and the second planar region 24 pushes the stain treatment fluid 300 contained within the pouch 80. it can. If the first planar region 22 and the second planar region 24 are moved to an opposing relationship with closer angles, more of the stain treatment fluid 300 contained in the pouch 80 will be squeezed out? Or it can be extruded. When the user applies an effective squeezing force, the first planar region 22 and the second planar region 24 are pressurized against each other, and the stain treatment fluid 300 is transferred from the pouch 80 via the transmission portion 60 to the contact substrate 200. Extrude into. The folded support layer 20 provides a gripping structure that is convenient for a user of the package 10 to grip when the contact substrate 200 (if present) is rubbed back and forth over the fabric stain to be treated. Can be provided.

  In the second position, the grip structure provided by the folded support layer 20 allows the consumer to effectively use the package 10 to treat the stain without touching the stain treatment fluid 300 or the contact substrate 200. Will be able to. Further, such a gripping structure can provide a solid structure that can be rubbed violently by the consumer, thereby causing the contact substrate 200 or broken if no contact substrate is present. The edge of the support layer 20 can be rubbed against the stain.

  The second elastic limit of the covering layer 50 can be larger than the first elastic limit of the support layer 20. Such a design provides a mechanical structure in which the support layer 20 can break before the cover layer 50 when the cover layer 50 and the support layer 20 connected together are distorted. be able to. Breaking the support layer 20 allows the covering layer 50 to maintain the structural integrity of the package 10 and allows the transmission portion 60 of the covering layer 50 to flow through the transmission portion 60 so that the stain treatment fluid 300 can flow from the transmission portion 60. Such a composition can be desirable because it can remain bonded by the covering layer 50. The transmission portion 60 can have a shape that provides a controlled fluid flow therein.

  Bending the support layer 20 around the line of weakness 130 moves the first planar region 22 and the second planar region 24 to a substantially opposing relationship, thereby causing a portion of the support layer to span the weakening line 130. By making it discontinuous, the package 10 can be used to treat a stained fabric. When the user presses the first planar region 22 and the second planar region 24 against each other, the stain treatment fluid 300 is dispensed into the contact substrate 200 from a portion of the support layer 20 that is discontinuous across the line of weakness 130. Is done. The support layer 20 is gripped in a manner similar to that shown in FIG. 5, for example, and the user rubs the stained fabric with the contact substrate 200.

  To bring more contact substrate 200 into contact with the stained fabric, the contact substrate 200 can be coupled to the support layer 20 by one or more hinges 100, as shown in FIG. By using a hinged structure, the contact substrate can be kept relatively flat even when the support layer 20 is bent or folded around the line of weakness 130. Each hinge 100 is formed from a flexible material, which allows a variable distance to be defined between the support layer 20 and the contact substrate 200. Each hinge 100 can be partially connected to the first surface 40 and partially connected to the contact substrate 200. When the support layer 20 is in a planar condition before being used for stain processing, each hinge 100 can be closed by a single bend or multiple folds with the associated hinge 100. When each hinge 100 is closed, the contact substrate 200 can be in a facing relationship with the support layer 20, resulting in a compact package 10. Each hinge 100 can be made from a folded piece of flexible material so that it has a substantially planar shape before the package is transitioned from the first position to the second position.

  As shown in FIG. 7, by breaking the support layer 20 and moving the first planar region 22 and the second planar region 24 to an opposing relationship in a substantially angled state, the package 10 is When the transition is made from this position to the second position, each hinge 100 can be opened so that a portion of the contact substrate 200 is spaced from the support layer. When the package is in the second position, each hinge 100 can have a generally “U” or “V” shape in cross-section as shown in FIG. Such a structure can provide a conduit that allows the stain treatment fluid 300 to flow from the pouch 80 to the contact substrate 200 while limiting the accumulation of the stain treatment fluid 300 in other components of the package 10. Each hinge 100 is considered to have two legs, one connected to the support layer 20 and one connected to the contact substrate 200. The leg of each hinge 100 connected to the contact substrate 200 is such that about 90% or more of the surface of the contact substrate 200 facing the support layer is connected to the hinge 100. Can have substantially the same extent. The leg of each hinge 100 is attached to the contact substrate using any known method for bonding two materials, including but not limited to adhesives, glue, ultrasonic bonding, thermal bonding, and fusion bonding. 200 or the support layer 20. In order to provide a more durable package 10, the method for connecting the hinges 100 can be chemically compatible with the stain treatment fluid 300. Each hinge 100 can be a polypropylene based tape, such as 3M 3560 available from 3M.

  Each hinge 100 is an integral extension of the contact substrate 200 and can comprise the same material of construction as the contact substrate 200 as shown in FIG. Such a structure can also facilitate manufacture by reducing the number of parts that need to be assembled to form the package 10.

  As shown in FIG. 9, the base layer 110 is such that the base layer 110 exists between the contact substrate 200 and the support layer 20, and the hinge 100 (if present) is coupled to the base layer 110. Can be coupled to the contact substrate 200 and the support layer 20. The base layer 110 can provide enhanced structural stability of the package 10 when the contact substrate 200 is rubbed vigorously against a stained fabric. The base layer 110 is, for example, a web of fluid permeable material, or has a substantially same extent as the contact substrate 200 in the length direction L and the width direction W, or in the transverse direction in the contact substrate 200. It may be a material that is selectively fluid permeable proximate the line of weakness 130 that has the same extent. The base layer 110 can be a web of fluid permeable material that has the same extent as the contact substrate 200 in the length direction L and the width direction W.

The base layer 110 is supported by each hinge 100 using any known method for bonding two materials including, but not limited to, adhesives, glue, ultrasonic bonding, thermal bonding, and fusion bonding. It can be connected to the layer 20. Similarly, the base layer 110 may be contacted with a contact substrate using any known method for bonding two materials, including but not limited to adhesives, glues, ultrasonic bonding, thermal bonding, and fusion bonding. 200 can be connected directly. The base layer 110 can be coupled to the contact substrate 200 by one or more intermediate layers. The base layer 110 can be a web of material selected from the group consisting of porous films, slit films, perforated films, nonwovens, wovens, and combinations thereof. The base layer 110 has a basis weight of 18 g / m ² available from DelStar Technologies, Inc., a high density polyethylene based substrate, such as DELNET AC 530-NAT-E with a thickness of 0.12 mm. It can be a material based on polyethylene.

In some embodiments, as shown in FIG. 10, the distribution layer 120 can be disposed, for example, in a relationship opposite the contact substrate 200 and between the support layer 20 and the contact substrate 200. The distribution layer 120 can widely distribute the stain treatment fluid 300 into and / or in the contact substrate 200 in the length direction L and the width direction W. To facilitate delivery of the stain treatment fluid 300 to the fabric to be treated, the distribution layer 120 can have a free absorption capacity that is smaller than the volume of the stain treatment fluid 300 contained in the pouch 80. The distribution layer 120 can include a fiber material based on hydrocarbons. The distribution layer 120 can include a fiber material selected from the group consisting of polyethylene, polypropylene, nylon, polyethylene terephthalate, rayon, and combinations thereof. The distribution layer 120 is coupled to the contact substrate 200 using any known method for bonding two materials including, but not limited to, adhesives, glue, ultrasonic bonding, thermal bonding, and fusion bonding. can do. Distribution layer 120 can be a needle punched fiber material. The distribution layer 120 can be a needle-punched nonwoven of polypropylene having a basis weight of 150 g / m ² . Basis weight can be quantified on a 1 cm × 1 cm sample using a 0.0001 g precision scale according to EDANA standard test WSP 130.1 (05), a standard test method for weight per unit area. Basis weight is determined based on integrating five samples and calculating the average from the integrated weight / area. The distribution layer 120 and the base layer 110 may be a composite material. DelStar Technologies, Inc. The composite substrate STRATEX 5.0NP5-E made by can provide a single product that includes both the distribution layer 120 and the base layer 110. This distribution layer 120 may be 1.5 mm thick. The thickness of the distribution layer can be quantified according to the EDANA recommended test method for nonwoven thickness (30.5-99).

  The free absorption capacity of the distribution layer 120 is measured as follows. The equipment required includes a nominal 2 mm mesh size stainless steel test sieve according to approximately 120 mm × 120 mm ISO 565 and a dish with fine wire mesh along with the test sample. The dish must be of sufficient volume to allow a test liquid depth of 20 mm. The test liquid is a 10% sodium dodecyl sulfate solution in distilled water. Using a suitable weighing glass and cover. A scale and stopwatch with an accuracy of plus or minus 0.01 g are also required.

The test is carried out in a laboratory at room temperature 25.0 ± 0.2 ° C. and relative humidity 50 ± 5%. All instruments and samples are allowed to equilibrate for 2 hours in the test environment. Cover the test dish to prevent excessive evaporation. A representative rectangular sample of distribution layer 120 weighing 1.00 ± 0.05 grams is cut from the distribution layer material, taking care not to compress the structure or otherwise disturb it. The length divided by the width of the sample must be less than 2 and the length is the longer side of the sample. If the individual distribution layers 120 are not of sufficient dimensions to make such a specimen, one or more distribution layers 120 from one or more packages 10 can be integrated to obtain the required weight and A stack of rectangular specimens of aspect ratio can be prepared. Each test specimen or stack of test specimens is weighed with a scale having an accuracy of 0.01 g. The specimen (or stack) is placed on a fine wire mesh and secured along the width edge by a suitable clip (ie within 1 mm of the material edge along the shorter dimension in the material plane). The wire mesh and attached sample are introduced into the test liquid at an oblique angle with the sample facing up. Once submerged, the fine mesh is placed horizontally 20 mm below the test liquid surface. This is conveniently done if the pan has a flat bottom and the test fluid is 20 mm deep. After 60 plus or minus 1 second, remove the fine wire mesh and test piece (or stack) from the test liquid, hang freely, and drain the liquid for 120 plus or minus 3 seconds. Orient the sample so that the clip is on the horizontal edge at the top of the sample during the draining process. After draining, the specimen (or stack) is separated from the fine wire mesh without squeezing fluid from the specimen or stack. The specimen (or stack) is then weighed within ± 0.1 grams. The difference between the weight of the specimen or stack before wetting and the weight of the specimen or stack after wetting is the free absorption capacity of the material in grams of fluid absorbed per gram of material. This is converted to the volume of fluid absorbed per gram of material by using 1 g / cm ³ as the test liquid density. Free absorption capacity is obtained as the average of five measurements made according to this procedure. Use freshly conditioned test fluid for each set of 5 measurements.

  Embodiments of the package 10 where the package 10 lacks the contact substrate 200 as shown in FIG. 11 are also contemplated. When the package 10 is positioned in the second position by breaking the support layer 20 along the line of weakness 130, the stain treatment fluid 300 can flow from the discontinuities created in the support layer 20. In other words, in the second position, the pouch 80 can be in fluid communication with the first surface 40 of the support layer. In the second position, the stain treatment fluid 300 can be excluded from a portion of the support layer 20 that is discontinuous across the line of weakness 130. In such embodiments, the stain treatment fluid 300 is a gel and can provide improved control of the application of the stain treatment fluid 300. When the fluid is applied to the fabric to be treated or thereafter, the broken edge of the support layer 20 is rubbed back and forth to the fabric to be treated, thereby applying and distributing the stain treatment fluid 300 to the stain, and Potentially agglomerates / globules of the stain can be removed, the stain can be bleached, and / or the fabric can be whitened.

  Using the package 10 illustrated in FIG. 11, the support layer 20 is bent around the line of weakness 130 to move the first planar region 22 and the second planar region 24 into a substantially opposing relationship. Thus, by allowing a portion of the support layer to be discontinuous across the line of weakness 130, the stained fabric can be treated. As the user presses the first planar region 22 and the second planar region 24 against each other, the stain treatment fluid 300 is discontinuous across the line of weakness 130 from a portion of the support layer 20 to the first of the support layer 20. It is dispensed first surface 40 half. The user grasps the support layer 20 in a manner similar to that shown in FIG. 5, for example, and rubs the fabric stained with a portion of the support layer 20 that is discontinuous across the line of weakness 130.

  FIG. 12 is a cutaway perspective view of another embodiment of the package 10 that provides a package in which a first stain treatment fluid 301 and a second stain treatment fluid 302 can be dispensed. This structure can also be practical in that two materials can be dispensed that either interact favorably or provide a treatment effect for different types of stains. For example, the first stain treatment fluid 301 may provide an effective treatment of hydrophobic grease stains and the second stain treatment fluid 302 may provide an effective treatment of hydrophilic wine stains, for example by bleaching. The first stain treatment fluid 301 may be a detergent and the second stain treatment fluid 302 may be a bleach compound. Such a structure is advantageous for stain treatment fluid components that are not stable or lose efficacy when stored together for extended periods of time. Such a structure is advantageous for stain treatment fluid components that have optimal efficacy under different local conditions (eg, pH). The pouch layer 70 can be coupled to the support layer 20 or to the covering layer 50 (if present) to form a first pouch 81 and a second pouch 82. The first pouch 81 and the second pouch 82 can be separated by the separation portion 83. The separating portion 83 can be aligned parallel to the line of weakness 130, generally orthogonal to the line of weakness 130, or otherwise aligned generally with the line of weakness 130. The first pouch 81 can include a first stain treatment fluid 301 and the second pouch 82 can include a second stain treatment composition 302. A portion of the separation portion 83 can cross a portion of the line of weakness 130.

  For example, as shown in FIGS. 13 and 14, the package 10 can be covered with a peelable protective material 400. The first surface 40 of the support layer 20 can be at least partially covered with the peelable protective material 400. The peelable protective material 400 wraps around the support layer 20 and substantially covers the contact substrate 200, a slip backing material that at least partially wraps the package 10, an envelope that wraps the package 10, and a seal that wraps the package 10. And can be selected from the group consisting of strips connected to the support layer 20 so as to be peelable. The contact substrate 200 is substantially coated when about 75% or more of the surface of the contact substrate 200 facing away from the first surface 40 of the support layer 20 is coated. Conceivable. The protective material 400 can withstand any abrasion and tear that may occur prior to use with such protective material 400, including, for example, film, paper, fibrous nonwoven, foil, or package 10. It can be constructed from other suitable durable materials. The protective material 400 protects the package 10 from damage due to the package 10 being carried in a wallet, wallet, pocket, diaper bag, dashboard glove compartment, or other such location where the package 10 was placed prior to use. Can be limited. The protective material 400 may be connected to the first surface 40 of the support layer 20 so as to be peelable by an adhesive. Peel the protective material 400 to the support layer 20 using any known method for bonding two materials including, but not limited to, adhesives, glue, ultrasonic bonding, thermal bonding, and fusion bonding. it may be connected so as to be able to.

  Package 10 can be a dispensing package such as that disclosed in US Pat. No. 7,506,762 (B2). Package 10 can be a dispensing package such as that disclosed in US Application Publication No. 2009/0074502 (A1).

In one embodiment, the contact substrate 200 is from ES Fibervisions / Chisso, referred to as Code 020, having a fiber diameter of 2.2 denier, a fiber length of 51 mm, and a basis weight of 60 g / m ² . It can be a polypropylene / polyethylene 70/30 hollow 16 segmented pie microfiber. In one embodiment, the contact substrate can be selected from the group consisting of foam, fiber material, film, brush, and combinations thereof. Without being bound by theory, the contact substrate 200 that provides a rough surface to the fabric to be treated can improve the stain treatment because the rough surface can facilitate the removal of stains from the fabric. it is conceivable that. The contact substrate 200 is manufactured by Kinsei Seishi Co. , Ltd., Ltd. (Product ID: MF-60PEP available from Kochi-shi, Japan).

  Contact substrate 200 comprising microfibers can provide effective stain removal. While not being bound by theory, microfibers have the ability to hold oily materials more effectively than contact substrate 200, which consists of large fibers, between the fibers that make up the contact substrate, a smaller interstitial space It is thought to bring about. In one embodiment, the contact substrate 200 can include microfibers having a diameter between about 0.1 micrometers and about 5 micrometers. In one embodiment, the contact substrate 200 can include microfibers having a diameter of less than about 5 micrometers. The microfibers can be knurled pie microfibers with sharp fiber edges that occur during the formation of such microfibers. The microfiber can be a staple fiber or a continuous split fiber. The microfiber can be a split polypropylene-polyethylene microfiber.

  The contact substrate 200 can be selected from the group consisting of polyethylene, polypropylene, nylon, polyethylene terephthalate, rayon, and combinations thereof. Such a fiber type is thought to cause a stain lift, probably due to its molecular composition. The microfiber is practical as described above, and the contact substrate is selected from the group consisting of a nonwoven fabric containing microfiber, a woven fabric containing microfiber, a looped woven fabric containing microfiber, and a combination thereof. obtain.

Without being bound by theory, the Hansen solubility parameter of the contact substrate 200 for a fabric stain containing grease or oil indicates the ability of the contact substrate 200 to lift such a stain from the fabric under test. It is thought to be a thing. Title "Hansen Solubility Parameters A User's Handbook, Second Edition, 2007" (by Charles M. Hansen, CRC Press, Taylor & Francis Group L A paper on parameters. For a particular molecule, there are three Hansen solubility parameters: δ _D , δ _P , and δ _H. Where δ _D is the intermolecular interaction energy dispersion component per molar volume, δ _P is the polar component of the intermolecular interaction energy per molar volume, and δ _H is the intermolecular energy per molar volume. It is the binding energy component of the interaction energy. The three parameters can be thought of as the coordinates of a point in a three-dimensional space called Hansen space.

  In the context of stain treatment, the ability of contact substrate 200 to lift grease or oil stains from the fabric is believed to depend on the grease or oil stain to be removed from the fabric and the Hansen solubility parameter of contact substrate 200. . Blot lift is believed to occur when the Hansen solubility parameter of the contact substrate 200 is proximate to the Hansen solubility parameter of the grease or oil stain to be treated in the Hansen space. If the contact substrate 200 to be treated and the Hansen solubility parameter of the stain are in such a relationship, the stain and contact substrate 200 can transfer the stain from the stained fabric to the contact substrate 200. Are considered to be molecularly similar to each other sufficiently.

  The Hansen solubility parameter for the contact substrate 200 is as of January 7, 2010: http: // www. Hansen-Solubility. com / is available using HSPiP version 2.0 software. The Hansen solubility parameter for the polymer molecules of each component of the contact substrate 200 is determined using the polymer HSP prediction tool in HSPiP by specifying monomer units and attachment points using the improved SMILES notation. Repeat unit 1 is used. If any of the Hansen solubility parameters are predicted to be less than zero by HSPiP version 2.0, such parameters are determined to have a value of zero.

式中、ｘは計算対象の特定のハンセン溶解度パラメーターに依存して、Ｄ、Ｐ、又はＨであり、ｉは構成成分分子の番号識別子であり、φは構成成分分子の重量分率である。２つ以上の異なる分子を含む接触基材の２００のハンセン溶解度パラメーターを求めるためのこのような方法は、コア／シース構造を有するファイバーの場合のように、浮き上がらせるべきしみに対する異なる分子の空間的な関係が、しみ除去にどのように影響を及ぼすかを要因として含めることができない。 For contact substrates 200 containing two or more different molecules, the Hansen solubility parameter is calculated on a weighted weight fraction basis of the component molecules as follows:

Where x is D, P, or H depending on the particular Hansen solubility parameter to be calculated, i is the number identifier of the component molecule, and φ is the weight fraction of the component molecule. Such a method for determining the 200 Hansen solubility parameter of a contact substrate containing two or more different molecules, such as in the case of a fiber with a core / sheath structure, is the spatial difference of the different molecules relative to the spots to be lifted. It is not possible to include as a factor how such a relationship affects stain removal.

  Hansen Solubility Parameters A User's Handbook, Second Edition, 2007, with lard and olive oil, or Hansen solubility parameters present in or near the same general area of Hansen space as octopus grease The contact substrate 200 can be used as the contact substrate 200. Such a contact substrate 200 may be capable of providing improved stain lift compared to a contact substrate 200 having a Hansen solubility parameter far from grease and oil in the Hansen space.

15 and 16 can be interpreted as providing a three-dimensional representation of the Hansen space of interest. The real arcs shown in FIGS. 16 and 17 represent a portion of the edge of the spherical volume of the Hansen space where δ _D , δ _P , and δ _H are positive. For example, FIG. 15 can be thought of as a side view of a Hansen space where δ _H and δ _P are shown in the viewer, and FIG. 16 is a top view of the Hansen space where δ _D and δ _P are shown in the viewer. Think of it as a figure. 15 and 16 can be interpreted as providing a three-dimensional representation of the Hansen space of interest. The real arcs shown in FIGS. 15 and 16 represent the edge portion of the Hansen space spherical volume where δ _D , δ _P , and δ _H are positive.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, contained within the Hansen space spherical volume of about 10000 MPa ^3/2, that is positive Hansen Fiber materials having solubility parameters can be included. As used herein, the Hansen space spherical volume is such that the Hansen space spherical volume extends outside of what is described as Hansen space in “Hansen Solubility Parameters A User's Handbook, Second Edition, 2007”. Are considered to include negative Hansen solubility parameters. That is, the Hansen space spherical volume includes negative values of δ _D , δ _P , or δ _H outside the Hansen space, which are limited to values of δ _D , δ _P , or δ _H that are positive. . As such, for example, a contact substrate 200 that is contained within a portion of the spherical volume of the Hansen space and has a positive δ _D , δ _P , or δ _H value can be targeted. It is understandable.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, contained within the Hansen space spherical volume of about 34000MPa ^3/2, that is positive Hansen It can be a fiber material having a solubility parameter.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, and [delta] _D between of about ^{15 MPa 1/2} to about ^{20 MPa 1/2} A fiber material having a Hansen solubility parameter that is contained within a certain Hansen space spherical volume of about 34000 MPa ^3/2 and that is positive can be included.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, are included in the Hansen space spherical volume of about 34000MPa ^3/2, about 10000 MPa ³ A fiber material having a Hansen solubility parameter that is positive and contained outside the Hansen space spherical volume of ^{/ 2} .

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, and [delta] _D between of about ^{15 MPa 1/2} to about ^{20 MPa 1/2} there, are included in the Hansen space spherical volume of about 34000MPa ^3/2, can include a fiber material having a Hansen solubility parameter it is, is positive contained outside the Hansen space spherical volume of about 10000 MPa ^3/2.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^½ , and the binding energy component of the interaction energy between molecules per molar volume δ _H about 3MPa ^1/2 , about 25000MPa ^3/2 , or about 20000MPa ^3/2 , or about 15000MPa ^3/2. Fiber material having a Hansen solubility parameter that is positive and contained within a Hansen space spherical volume.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, and [delta] _D between of about ^{15 MPa 1/2} to about ^{20 MPa 1/2} there, about 25,000 mPa ^3/2, or about 20000 MPa ^3/2, or included in the Hansen space spherical volume of about 15,000 MPa ^3/2, can include a fiber material having a Hansen solubility parameter is positive.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per mole volume, about 25,000 mPa ^3/2, about 20000 MPa ^3/2, or about 15,000 MPa ^3/2 A fiber material having a Hansen solubility parameter that is positive, contained within a Hansen space spherical volume, but outside a Hansen space spherical volume of about 10,000 MPa ^3/2 may be included.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per molar volume, and [delta] _D between of about ^{15 MPa 1/2} to about ^{20 MPa 1/2} there, about 25,000 mPa ^3/2, or about 20000 MPa ^3/2, or about but it is in 15000MPa Hansen space spherical volume of ^3/2, contained in the outside of the Hansen space spherical volume of about 10000 MPa ^3/2, a positive Fiber materials having certain Hansen solubility parameters can be included.

In one embodiment, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^½ , and the binding energy component of the interaction energy between molecules per molar volume δ _H is centered at about 3 MPa ^1/2 and δ _D is between about 15 MPa ^1/2 and about 20 MPa ^1/2 A fiber material having a Hansen solubility parameter that is positive and contained within a Hansen space spherical volume of about 10,000 MPa ^3/2 can be included.

In other embodiments, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per mole volume, about 9000 MPa ^3/2 or about 8500MPa ^3/2, or about 8000 MPa ^3/2, or about 6000 MPa ^3/2, or about 4000 MPa ^3/2, or contained in the Hansen space spherical volume of about 3000 MPa ^3/2, can include a fiber material having a Hansen solubility parameter is positive.

In other embodiments, the contact substrate 200 has a dispersion component δ _D of intermolecular interaction energy per molar volume δ _{D of} about 18 MPa ^1/2 , a polar component δ _P of intermolecular interaction energy per molar volume δ _{P of} about 1 MPa. ^1/2, and having a binding energy component [delta] _H about center 3 MPa ^1/2 of interaction energy between molecules per molar volume, and [delta] _D of about for each of these defined Hansen space spherical volume It is between 15 MPa ^1/2 to about ^{20 MPa 1/2,} about 9000 MPa ^3/2 or about 8500MPa ^3/2, or about 8000 MPa ^3/2, or about 6000 MPa ^3/2, or about 4000 MPa ^3/2,, alternatively from about 3000MPa included within the Hansen space spherical volume of ^3/2, that is positive Hansen parameters It can include a fiber material having over.

In other embodiments, the contact substrate 200 is positive and [(δ _D −18 MPa ^1/2 ) ² + (δ _P −1 MPa ^1/2 ) ² + (δ _H −3 MPa ^1/2 ) ² ]. ^1/2 is less than about ^{13 MPa 1/2,} Hansen solubility parameter [delta] _D, may comprise a fiber material having a [delta] _P, and [delta] _H. In another embodiment, the contact substrate 200 is positive and [(δ _D −18 MPa ^1/2 ) ² + (δ _P −1 MPa ^1/2 ) ² + (δ _H −3 MPa ^1/2 ) ² ]. ^1/2 less than about ^{11 MPa 1/2,} or about ^9MPa less than ^1/2, or ^{7 MPa 1/2,} alternatively less than about ^{5 MPa 1/2} less than the Hansen solubility parameter [delta] _D, fiber group having a [delta] _P, and [delta] _H Material can be included.

In another embodiment, contact substrate 200 is positive and δ _D is a dispersive component of intermolecular interaction energy per molar volume and δ _P is a polar component of intermolecular interaction energy per molar volume. And δ _H is the binding energy component of the interaction energy between molecules per molar volume, and [(δ _D −18 MPa ^1/2 ) ² + (δ _P −1 MPa ^1/2 ) ² + (δ _H -3MPa ^{1/2) 2] 1/2} are less than about ^{13 MPa 1/2,} and [delta] _D is between about ^{15 MPa 1/2} to about ^{20 MPa 1/2,} Hansen solubility parameter δ _D, δ _P , And δ _H can be included.

In other embodiments, the contact substrate 200 is positive and [(δ _D −18 MPa ^1/2 ) ² + (δ _P −1 MPa ^1/2 ) ² + (δ _H −3 MPa ^1/2 ) ² ]. ^1/2 less than about ^{11 MPa 1/2,} or less than about ^{9 MPa 1/2,} or ^7MPa less than ^1/2, or less than about ^{5 MPa 1/2,} and [delta] _D of about for each of these embodiments Fiber materials having Hansen solubility parameters δ _D , δ _P , and δ _H that are between 15 MPa ^1/2 and about 20 MPa ^1/2 can be included.

  While not being bound by theory, the contact substrate 200 described functions only to deliver the stain treatment fluid 300 to the soiled fabric and potentially capture the strain component accidentally. Rather, the contact substrate 200 itself is in a Hansen space proximal to the Hansen solubility parameter of the contact substrate 200 compared to the contact substrate 200 having a Hansen solubility parameter far from the stain to be treated. It is believed that it can also result in improved removal of blots with parameters.

  Stain treatment fluid 300 compositions are known in the art for stain treatment, such as compositions containing chelating agents, radical scavengers and preferably bleaching agents, as disclosed in US Pat. No. 6,846,332. May be known.

  The composition of the stain treatment fluid 300 can be aqueous or non-aqueous. In one embodiment, the composition comprises from 0% to about 99.99%, alternatively from about 70% to about 99.99%, alternatively from about 90% to about 99.9%, alternatively from about 94.0%. Contains ~ 99.0 weight of water and can therefore be an aqueous solution.

  The composition of the stain treatment fluid 300 can include additional components such as bleaching agents, surfactants, solvents, chelating agents, radical scavengers, and mixtures thereof.

  The composition of the stain treatment fluid 300 is about 0.001% to about 99.99%, alternatively about 0% to about 15%, alternatively about 0.001% to about 7% by weight of the composition. it can contain a bleaching agent. In one embodiment, the bleaching agent can be selected from the group consisting of peroxide bleaching agents (such as N, N-phthaloylaminoperoxycaproic acid or other peroxyacids), hydrogen peroxide, and mixtures thereof. In one embodiment, the stain treatment fluid 300 composition may comprise about 0.5% to about 3% hydrogen peroxide by weight of the composition. Peroxide sources other than hydrogen peroxide can be used in the present invention. Comparative peracids, persalts, perbleaching agents, metal catalysts, etc., known in the detergent art can be used.

  The stain treatment fluid 300 composition has a surface activity of from about 0.001% to about 99.99% by weight of the composition, alternatively from about 0.05% to about 5%, from about 0.05% to about 2%. An agent can be included. The surfactant may be selected from the group consisting of nonionic, anionic, cationic, amphoteric surfactants and mixtures thereof. Specific examples include ethoxylated alcohols or propoxylated, ethoxylated alcohols and their sulfates, or alkylphenols, alkyl carboxylates, alkyl sulfates, alkyl sulfonates, NaAES, NH4AES, alkyl quaternary ammonium salts, amine oxides, and mixtures thereof.

  Nonionic surfactants such as ethoxylated C10-C16 alcohols such as NEODOL 23-6.5, low molecular weight alkyl / arylamines, alkyl / arylpolyamines, or combinations thereof may be used in the composition. . Alkyl sulfate surfactants that can be used herein as cleaners and for stabilizing aqueous compositions are of the formula CH3 (CH2) x (CHOSO3-M +) CH3 and CH3 (CH2) y (CHOSO3-M +) CH2CH3. C8-C18 primary (“AS”), wherein x and (y + 1) are integers of at least 7, preferably at least 9, and M is a water-solubilizing cation, especially sodium, potassium, and magnesium. Preferably C10-C14, sodium salts), and unsaturated sulfates such as branched and random C10-C20 alkyl sulfates, and C10-C18 second aryl (2,3) alkyl sulfates and oleoyl sulfates. is there. The alkyl ethoxy sulfate (AES) surfactant used herein is of the formula R (EO) xSO3Z, where R is C10-C16 alkyl, EO is -CH2CH2-O-, and x is 1-10, including, for example, (EO) 2.5, (EO) 6.5, etc., which are conveniently expressed as an average, and Z is sodium, ammonium, potassium, or magnesium (It is a cation such as (MgAES)). In addition, surfactants such as quaternary alkylammonium compounds that can include, but are not limited to, hydrochloride and alkyl sulfates. C8-C16 alkylamine oxide surfactants can also be used.

  The stain treatment fluid 300 composition may comprise from 0% to about 99.99% by weight of the composition, alternatively from about 0% to about 20%, alternatively from 0% to about 10% by weight of a non-aqueous solvent. Solvents useful herein include butoxypropoxypropanol (BPP), benzyl alcohol, cyclohexane dimethylamine, glycol ethers such as diethylene glycol, dipropylene glycol and propylene glycol phenyl ether, or other described herein. A solvent is mentioned. In one embodiment, the solvent is an organic solvent. In one embodiment, the composition comprises about 1% to about 4% BPP, available in commercial quantities as a mixture of about equal amounts of isomers.

  Other useful solvents are hydrotropes such as sodium toluene sulfonate and sodium cumene sulfonate, short chain alcohols such as ethanol and isopropanol, and the like. These can be present in the composition as simple solvents or in combination with other solvents.

  The solvent: surfactant weight ratio can range from about 10: 1 to about 1: 1. In one embodiment, the composition comprises a mixture of 2% glycol ether and diethylene glycol solvent and 0.3% sodium lauryl sulfate.

  The composition of the stain treatment fluid 300 may include a chelating agent. The composition can include up to about 5% by weight of the chelating agent, or mixtures thereof, of the total composition. In one embodiment, the composition is about 0.001% to about 1.5%, alternatively about 0.001% to about 0.5%, alternatively about 0.001% to about 5% of the stain treatment fluid. % by weight of the total composition of a chelating agent.

  Chelating agents can include any known in the art, including phosphonate chelating agents, aminocarboxylate chelating agents, other carboxylate chelating agents, ethylenediamine N, N′-disuccinic acid, Multifunctional substituted aromatic chelating agents, citric acid, and mixtures thereof.

  In one embodiment, the chelating agent is aminoaminotri (methylenephosphonic acid), di-ethylene-triamino-pentaacetic acid, diethylenetriaminepentamethylenephosphonate, 1,2-dihydroxy-3,5-benzenedisulfonic acid, 1- Hydroxyethane diphosphonate, ethylenediamine N, N′-disuccinic acid, and mixtures thereof.

  The compositions herein may also include organic stabilizers to improve the chemical stability of the composition, if such materials are compatible or suitably formulated. . When incorporated, organic stabilizers can be used at levels of from about 0.001% to about 5.0% by weight of the composition, alternatively from about 0.001% to about 0.5%.

  The composition of the stain treatment fluid 300 may include a radical scavenger or a mixture thereof. The radical scavenger can be present in the composition in an amount ranging up to about 10% by weight of the composition. In one embodiment, the composition comprises about 0.001% to about 0.5% by weight of the composition of a radical scavenger.

  Radical scavengers useful herein include the well-known substituted mono- and dihydroxybenzenes, and analogs thereof, alkyl and aryl carboxylates, and mixtures thereof. Specific examples include 3,4,5-trimethoxybenzoic acid (TMBA) and tetrabutylethylidene bisphenol.

  The stain treatment fluid 300 composition may contain small amounts of various optional ingredients including enzymes, preservatives, antistatic agents, antioxidants / stabilizers, fragrance perfumes, malodor absorbing components (such as cyclodextrins). ), Bleach activators, builders, polymer-type soil release agents, dispersible polymers, oil-absorbing polymers; antifogging and / or corrosion inhibitors, dyes, fillers, bactericides, hydrotropes, sorbotropic agents , Enzyme stabilizers, solubilizers, clay soil removers / anti-redeposition agents, fabric softeners, dye transfer inhibitors, brighteners, bleach catalysts, electrostatic control agents, thickeners and the like. When used, such optional ingredients can comprise 0.0001% to 10%, alternatively 0.01% to 2% by weight of the composition.

  The pH of this formulation can be selected to maximize the cleaning efficacy of a particular formulation. If hydrogen peroxide is present in the formulation, the pH must be maintained between 3 and 6. In the absence of hydrogen peroxide, the pH can be increased. Buffering agents such as citric acid may be used to maintain the desired pH.

  In one embodiment, after treating such a stain on the fabric surface, the stain treatment fluid 300 composition can be formulated so that only a small amount of visible residue remains on the fabric surface. Thus, the stain treatment fluid 300 composition comprises various polyacrylate-based emulsifiers, polymeric antistatic agents, inorganic builder salts and other residue-forming materials at about 0.1% by weight of the composition. May be substantially free except at low levels of about 0.3% by weight, preferably 0% of such materials (% is 100% active weight% as used herein). Represents). Similarly, the water used in the composition of the stain treatment fluid 300 can be free of residue-forming material by distillation, deionization, or other methods.

  In one embodiment, the stain treatment fluid 300 composition may be formulated as a liquid fabric treatment composition. In one alternative embodiment, these may be provided as gels.

Theoretical Example of the Composition of Stain Treatment Fluid 300 Stain Treatment Fluid 300—Example 1

Stain treatment fluid 300-Example 2

Stain treatment fluid 300-Examples 3 & 4

Blotting fluid 300-Example 5

Stain treatment fluid 300-Examples 6-12

  In one embodiment, the stain treatment fluid 300 comprises 95.05% by weight distilled water, 0.34% by weight sodium lauryl sulfate, 1.68% by weight amine oxide, 1.5% by weight glycol ether PPh, 0.2 wt% EDDS, 0.21 wt% citric acid, 1.00 wt% hydrogen peroxide, 0.02 wt perfume. In one embodiment, the stain treatment fluid 300 comprises 96.04750% by weight distilled water, 0.90% by weight sodium lauryl sulfate, 0.15% by weight magnesium sulfate solution, 0.30% by weight amine oxide, It may contain 1.5 wt% glycol ether PPh, 0.0025 wt% EDDS, 0.08 wt% citric acid, 1.00 wt% hydrogen peroxide, 0.02 wt% perfume.

  The contact substrate 200 can have at least one surface that is lightly colored. The lightly colored contact base material 200 can effectively lift the stain to be processed from the fabric to be processed and can function as an indicator of the transition to the contact base material 200. When the contact substrate 200 captures the stain, the color of the contact substrate tends to darken. For patterned fabric-based stains that may be difficult to see in darkly lit places such as restaurants where stains may occur, having a lightly colored contact substrate 200 that darkens in use is a contact Substrate users can help monitor the spots to be removed.

Contact substrate 200 may have an L ^* value greater than about 80. Contact substrate 200 may have an L ^* value greater than about 85. Contact substrate 200 may have an L ^* value greater than about 90. Contact substrate 200 may have an L ^* value greater than about 95. Contact substrate 200 can have an L ^* value greater than about 90, an a ^* value between about −5 and about 5, and a b ^* value between about −5 and about 5.

The color of the contact substrate 200 is measured with a reflectance spectrophotometer according to the color L ^* , a ^* , and b ^* values. When the contact substrate 200 is connected to the support layer 20, the L ^* , a ^* , and b ^* values of the contact substrate 200 are directed away from the support layer 20. Measure on the surface.

  Reflection color is measured using a Hunter Lab LabScan XE reflection spectrophotometer obtained from Hunter Associates Laboratory (Reston, Va.). Contact substrate 200 is tested at an ambient temperature between 18 ° C. and 24 ° C. (65 ° F. and 75 ° F.) and a relative humidity between 50% and 80%.

  Set spectrophotometer to CIELab color scale and use D65 illumination. The observer is set to 10 ° and the mode is set to 45/0 °. The area view is set to 0.318 cm (0.125 ") and the port size is set to 0.51 cm (0.20"). After calibrating the spectrophotometer, the sample is analyzed using black glass and white reference tiles supplied with the instrument from the supplier. Calibration is performed according to the manufacturer's instructions as described in the LabScan XE User's Manual, Manual Version 1.1 (August 2001, A60-1010-862). If reference tiles or samples need to be cleaned, only embossed, lotion or brightener-free tissue (eg, Puffs tissue) is used. Any sample point on the contact substrate 200 facing away from the first surface 40 of the support layer 20 can be selected.

  A contact substrate 200 is placed over the sample port of the spectrophotometer and a white clamp disc is placed behind the contact substrate 200. The contact substrate is substantially flat and free from wrinkles.

Remove and reposition the contact substrate and read the color of the contact substrate at least three times. Each reading is performed in different regions of the contact substrate so that the two sample points do not overlap. The readings are averaged to obtain reported values for L ^* , a ^* , and b ^* .

  Package 10 as described herein can be used in a method for treating a stained fabric. The method steps include bending the support layer 20 about the line of weakness 130 to move the first planar region 22 and the second planar region 24 into a substantially opposing relationship, thereby providing a support layer 20 Including making the portion discontinuous across the line of weakness 130. The stain treatment fluid 300 can be dispensed from the portion of the support layer 20 that is discontinuous across the line of weakness 130 to the first surface 40 of the support layer 20. The user then grasps the support layer 20 and rubs the stained fabric with a portion of the support layer 20 that is discontinuous across the line of weakness 130. As part of this method, if the contact substrate 200 is part of the package 10, the stain treatment fluid 300 is coupled to the first surface 40 of the support layer 20 proximal to the line of weakness 130. permeability to Note contact substrate 200 binary. If the distribution layer 120 is present, the stain treatment fluid 300 can be transported from the distribution layer 120 to the contact substrate 200.

  The stained fabric is a step of providing a contact substrate 200 comprising a stain treatment fluid 300, the contact substrate 200 comprising microfibers having a diameter of less than about 5 micrometers; Contacting the stain 200 with the stain fabric and transferring the stain treatment fluid 300 to the stain fabric; and rubbing the stain fabric with the contact substrate 200; 300 can be processed by a method for treating a stained fabric comprising from about 0.001% to about 99.99% by weight of surfactant of the stain treatment fluid 300. Contact substrate 200 can be any of the embodiments of contact substrate 200 described herein. A method in which the contact substrate 200 is connected to the support layer 20 can be carried out using a stain wiping tool. The support layer 20 can provide a grip for the user when the user wipes the stain with the contact substrate 200. The process of rubbing the stained fabric with the contact substrate can be assisted by the support layer 20 connected to the contact substrate 200. The stain wiping tool can be the support layer 20. The stain wiping tool can be a rigid body sized and dimensioned to be operably engaged with the contact substrate 200 and grasped by a human hand.

  This method can be performed on the costume when the user of the package 10 is wearing the costume. The stained fabric can be a fibrous woven or non-woven web. For example, a stained fabric can be part of a costume. In one embodiment, this method can be used to treat grease or oil stains on the fabric.

Tests were conducted to measure octopus grease stain removal for the various contact substrates shown in Table 1.

A. The basis weight calculated on the basis of the weight of a single 10 cm square sample. The stain removal test was conducted using a 6-position Nu-Martindale abrasion tester. The stained fabrics tested were from Testfabrics, Inc. A 140 mm diameter sample of bleached, mercerized, combed cotton broad, available from (West Pittiston, PA, USA). 3.1 g sodium dodecyl sulfate (SLS) solution and 0.94 g amine oxide (AO) solution are added to 96.37 g deionized water, 0.9% AO for the purpose of stain removal testing, A stain treatment fluid was prepared by using a 0.3% SLS solution, and the contact substrate was wetted by the stain treatment fluid. The contact substrate tested had a diameter of 38 mm.

  The tested contact substrate and cotton broad cloth samples were equilibrated at constant temperature (21 ± 1 ° C. (70 ± 2 ° F.)) and humidity (65% ± 2% relative humidity) (CTCH) for at least 8 hours prior to testing. Turned into. After the equilibration period, the initial weight of each contact substrate tested was measured.

  Standard octopus grease obtained from the Empirical Manufacturing Company (Cincinnati, OH, USA), heated in a water bath to between 45 ° C. and 50 ° C. (113 ° F. to 122 ° F.), and aspirated into a pipette The cotton broad sample was applied using a pipette in. Then, using a pipette, 1 milliliter of standard octopus grease was applied to each contact substrate. The weight of the octopus grease applied to each cotton broad sample was 0.2850 +/- 0.0250 g. After the octopus grease was applied to the cotton broad sample, the cotton broad sample spotted with octopus grease was cooled for 10 minutes.

  Cotton broad samples and contact substrates were fixed at individual wear positions on a Nu-Martindale wear tester. Each position of the Nu-Martindale wear tester results in wear by a single contact substrate of a single cotton broad sample. A normal force (perpendicular to the treated surface) was applied to the substrate that was stressed during wear using a 12 kPa (1.4 lb) weight. The number of wear cycles used in the test was 500.

  After abrasion, the cotton broad sample and contact substrate were removed from the abrasion tester and allowed to equilibrate in the CTCH chamber for at least 8 hours. After the equilibration period, the weight of the cotton broad sample and the contact substrate was measured individually. The weight of the octopus grease collected by the contact substrate was determined by subtracting the initial weight of the contact substrate from the final weight of the contact substrate after abrasion. Equilibration period after wear test and wear test due to the low weight of non-aqueous components in the stain treatment fluid and possibly transfer of some of the stain treatment fluid initially applied to the contact substrate to the cotton broad sample It was assumed that the weight of any component of the stain treatment fluid remaining on the contact substrate after is negligible. The stain throughput of the contact substrate was quantified in the form of octopus grease absorption, defined as the weight of acquired octopus grease per weight of contact substrate.

“Solvability Parameters A User's Handbook, Second Edition, 2007” (by Charles M. Hansen, Hansen, CRC Press, Taylor & Francis Group LLC, published by BocaR, LLC) The Hansen solubility parameter of octopus grease was measured using a multi-solvent method based in part. The Hansen solubility parameters for octopus grease were determined to be δ _D = 17.62 MPa ^1/2 , δ _P = 1.06 MPa ^1/2 , δ _H = 3.06 MPa ^1/2 . The radius R of the sphere with respect to the octopus grease in the Hansen space was determined to be R = 5.9 MPa ^1/2 .

  The degree of macroscopic dissolution of octopus grease was scored by adding 5 mL of a given solvent to 0.5 g of octopus grease in a test tube with a glass pipette and forming a vortex for 10 seconds. A score of 1 was given for the results described as clear-no separation-all dissolved. A score of 2 was given for the results described as turbid-no separation. A score of 3 was given for the results described as turbid-separated. A score of 4 was given to the results described as slightly turbid-separated. A score of 5 was given for the results described as slightly haze-separated. A score of 6 was assigned to the results described as transparent-separated. These characterizations are described in Appendix A, Table A.1, “Solubility Parameters A User's Handbook, Second Edition”. 3 was chosen to generally correspond to the scale described for different solvent-solute systems.

Table 2 is a list of observed octopus grease dissolution ratings for the solvent acting on the octopus grease.

  A rating of 1 was considered to indicate that the octopus grease is soluble in the rated solvent. A rating of 2-6 was considered to indicate that the octopus grease was insoluble in the rated solvent. The Hansen solubility parameter of the solvent used was entered into the HSPiP software.

  Using the best fit method of HSPiP software, the Hansen solubility parameter solution for octopus grease was identified so that the solvent in which the octopus grease is soluble separates from the solvent in which the octopus grease is insoluble. The solution is a sphere that contains a solvent in which the octopus grease is soluble in the Hansen space and does not contain a solvent in which the octopus grease is insoluble. There are potentially a myriad of spheres that can meet the constraints of partitioning the solvent based on whether the octopus grease is soluble or insoluble, and the software uses a random method to solve it. The best fitting method does not give a unique solution. Multiple runs of the best fit method were performed to identify the potential minimum radius for the octopus grease sphere in Hansen space.

  Then, the potential minimum radius of the sphere after multiple runs of the best fit method is selected as a starting estimate for the radius to include the solvent in which the octopus grease is soluble and the solvent in which the octopus grease is insoluble Better definition of the radius of a sphere in Hansen space, not including

  The start estimate for the radius was then repeated to determine the minimum radius that can be solved for the Hansen solubility parameter that still allows separation of the solvent in which the octopus grease is soluble from the solvent in which the grease is insoluble. Five runs of the iterative process starting from the start estimate for the radius were performed to determine the minimum radius. The radius obtained from the iteration starting from the Hansen solubility parameter and the starting estimate for the radius was recorded as the smallest radius that contains the solvent in which the octopus grease is soluble.

  The best-fit process described above was repeated for conditions where the octopus grease insoluble and insoluble octopus grease was closest to the solvent in which the octopus grease was soluble. Such an analysis identified the largest sphere containing a solvent in which the octopus grease is insoluble and closest to the solvent in which the octopus grease is soluble in addition to the solvent in which the octopus grease is soluble. These Hansen solubility parameters and radii were recorded as being the maximum radius containing the solvent in which the octopus grease is soluble.

  The Hansen solubility parameters for the smallest and largest spheres were averaged and these averaged parameters were recorded as describing the Hansen solubility parameter for octopus grease. The Hansen solubility parameters and radii determined by this method describe a sphere that has a perimeter that is above the mean sphere of the smallest sphere and within the mean of the largest sphere.

式中、１７．６２、１．０６、及び３．０６の値は、それぞれ、実験的に求められたｄδ_Ｄ ＭＰａ^１／２、δ_Ｐ ＭＰａ^１／２、及びδ_Ｈ ＭＰａ^１／２である。相対的なエネルギー差が、試験したタコグリースに対してδ_Ｄ、δ_Ｐ、及びδ_Ｈのみを基準に計算されるように、１ＭＰａ^１／２の値を有するようにＲを設定した。

The Hansen solubility parameters shown in Table 2 were determined for the tested contact substrates using the HSPiP version 2.0 software described above. “Hansen Solubility Parameters A User's Handbook, Second Edition, 2007” (by Charles M. Hansen, Published by CRC, Taylor & France) The relative energy difference between each tested contact substrate and octopus grease was calculated using a typical energy difference equation:

In the formula, the values of 17.62, 1.06, and 3.06 are respectively experimentally determined dδ _D MPa ^1/2 , δ _P MPa ^1/2 , and δ _H MPa ^1/2 . . R was set to have a value of 1 MPa ^1/2 so that the relative energy difference was calculated on the basis of only δ _D , δ _P , and δ _H for the tested octopus grease.

A. Number of Specimens Tested A graph, RED, of octopus grease absorption versus relative energy difference between each contact substrate tested and octopus grease is shown in FIG. As shown in FIG. 17, the octopus grease absorption tends to absorb as the relative energy difference between the contact substrate and the octopus grease decreases. The error bars in FIG. 17 represent the standard deviation plus or minus 1 of the measured value of grease absorption. This is because the basic behavior with respect to solubility, where similar materials dissolve similar materials, is at least partly described by the affinity for the molecules that make up the stain for the fibers that make up the contact substrate. A response is expected to occur. A contact substrate having a relatively high octopus grease absorption is effective in transferring grease or oil stains from the fabric to the contact substrate.

18 and 19 show the location in Hansen of the Hansen solubility parameter for the contact substrate shown in Table 2 and the locations of δ _D , δ _P , and δ _H for the octopus grease tested (TGs in FIGS. 18 and 19). (Label) is illustrated. 18 and 19 provide a three-dimensional illustration of a portion of the Hansen space that may be of interest. 18 is a side view of the Hansen space where δ _H and δ _P are shown in the viewer, and FIG. 19 is a top view of the Hansen space where δ _D and δ _P are shown in the viewer. The actual arcs shown in each of FIGS. 18 and 19 have positive δ _D , δ _P , and δ _H as shown, and the center of the Hansen space spherical volume is 18 MPa ^1/2 . One of the edges of the Hansen space spherical volume located at δ _D , 1 MPa ^1/2 δ _P , and 3 MPa ^1/2 δ _H and the Hansen space spherical volume is 10000 MPa ^3/2 or 34000 MPa ^3/2. Part. As illustrated in FIGS. 18 and 19, the tested contact substrate (δ _D = 17.62 MPa ¹⁾ having a relative energy difference of less than 13 between the contact substrate and the Hansen solubility parameter for the tested octopus grease. ^{_{/ 2, δ P = 1.08MPa 1/2}} , (δ H = 3.06MPa 1/2) R is set equal to ^{1 MPa 1/2),} as shown in FIGS. 18 and 19, 18 MPa ^{1 / It is in} a Hansen space spherical volume of 10000 MPa ^3/2 centered at ² δ _D , 1 MPa ^1/2 δ _P , and 3 MPa ^1/2 δ _H. Further, as illustrated in FIGS. 18 and 19, the tested contact substrate having a relative energy difference of less than 20 (R is 1 MPa 1/1 ^/) between the contact substrate and the Hansen solubility parameter for the tested octopus grease. set equal to ^2), as shown in FIGS. 18 and 19, having a central [delta] _D, ^{1 MPa 1/2} of [delta] _P of ^{18 MPa 1/2,} and ^{3 MPa 1/2} of δ _H, 34000MPa ^{3 / 2 in} the Hansen space spherical volume.

  Unless otherwise indicated, all percentages and ratios used herein are based on the weight of the total composition and all measurements are made at 25 ° C. One angle is a plane unit of an angle index having a size equal to 1/360 of full rotation.

  While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. Accordingly, all such changes and modifications that fall within the scope of the invention are intended to be covered by the appended claims.

  All documents cited are hereby incorporated by reference in their relevant parts, but the citation of any document should not be construed as an admission that it is prior art related to the present invention.

Claims (15)

A method for processing a stained fabric,
Providing a contact substrate (200) comprising a stain treatment fluid (300), the contact substrate comprising microfibers having a diameter of less than about 5 micrometers;
Contacting the contact substrate with the blotted fabric and transferring the stain treatment fluid to the blotted fabric; and
Rubbing the stained fabric with the contact substrate,
The method wherein the stain treatment fluid comprises from 0.001% to about 99.99% surfactant by weight of the stain treatment fluid.   The method of claim 1, wherein the contact substrate comprises a fiber selected from the group consisting of polyethylene, polypropylene, nylon, polyethylene terephthalate, rayon, and combinations thereof.   The method according to claim 1 or 2, wherein the contact substrate is selected from the group consisting of a nonwoven fabric containing microfibers, a woven fabric containing microfibers, a looped woven fabric containing microfibers, and combinations thereof. .   The method according to claim 1, wherein the microfiber is a scored pie microfiber.   The method according to claim 1, wherein the microfiber is a staple microfiber or a continuous split fiber.   The method according to claim 1, wherein the microfiber is a split polypropylene-polyethylene fiber. The contact substrate interaction variance components [delta] _D of about ^{18 MPa 1/2} energy, interaction polar component [delta] _P of about ^{1 MPa 1/2} of energy between molecules per molar volume between molecules per molar volume, and moles with binding energy component [delta] _H about center ^{3 MPa 1/2} of interaction energy between molecules per volume, contained within the Hansen space spherical volume 34000MPa ^3/2, a fiber material having a Hansen solubility parameter is positive There is a way. The method according to claim 1, wherein the contact substrate is a fiber material having a Hansen solubility parameter contained within a Hansen space spherical volume of 10,000 MPa ^3/2 . The method of claim 7, wherein the contact substrate is a fiber material having a Hansen solubility parameter outside a Hansen space spherical volume of 10,000 MPa ^3/2 . The dispersion component [delta] _D of the interaction energy between molecules per molar volume, is between about ^{15 MPa 1/2} and ^{20 MPa 1/2,} the method according to any one of claims 7-9.   11. A method according to any one of the preceding claims, wherein the step of rubbing the stained fabric with the contact substrate is assisted by a support layer (20) connected to the contact substrate. . 12. A method according to any one of the preceding claims, wherein the contact substrate has an L ^* value greater than 80 as measured by a reflectometer.   13. A method according to any one of the preceding claims, wherein the stain treatment fluid comprises 0.05% to 5% by weight of the surfactant of the stain treatment fluid.   14. A method according to any one of the preceding claims, wherein the stain treatment fluid comprises from 0.001% to 7% bleach of the stain treatment fluid. The stain treatment fluid is
a) 0.05% to 5% by weight of the surfactant of the stain treatment fluid;
b) 0.001% to 7% by weight of a bleaching agent of the stain treatment fluid;
15. A package according to any one of the preceding claims comprising c) 0.001% to 5% by weight chelating agent of the stain treatment fluid, and d) perfume.

Images