JP2013230182A - Method of manufacturing bioelectrode - Google Patents

Method of manufacturing bioelectrode Download PDF

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JP2013230182A
JP2013230182A JP2012102367A JP2012102367A JP2013230182A JP 2013230182 A JP2013230182 A JP 2013230182A JP 2012102367 A JP2012102367 A JP 2012102367A JP 2012102367 A JP2012102367 A JP 2012102367A JP 2013230182 A JP2013230182 A JP 2013230182A
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insulator
bioelectrode
sponge
manufacturing
underlay
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Kazunobu Mishima
和宣 三嶋
Takao Kashiwagi
孝夫 柏木
Takayuki Kasuya
▲高▼之 粕谷
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TDK Corp
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TDK Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method of manufacturing bioelectrodes capable of forming a conductor serving as a shield integrally in a bioelectrode, and capable of efficiently manufacturing a number of bioelectrodes.SOLUTION: An insulator 4 and earth gel 5 are layered at different positions on the same layer on an underlay film 30. A base material 1 (with a conductor on one side) is layered astride over the two layers in such a way as to cover both the insulator 4 and the earth gel 5, and a nonwoven fabric 2 is further layered. The layered body on the underlay film 30 is cut into a plurality of pieces 51 in a prescribed shape leaving the underlay film 30, and one side of a slit 31 of the underlay film 30 is released. A receiver 6 is stuck to an exposed part of the insulator 4 in each piece 51, and a sponge 8 is stuck onto the receiver 6 with a double-sided adhesive tape 7 with one end of a cable 11 placed on the receiver 6. Aqueous gel 9 is injected into the sponge 8 and a cover 10 is stuck to the exposed part of the insulator 4.

Description

本発明は、生体信号の取得に用いられる生体電極の製造方法に関する。   The present invention relates to a method of manufacturing a biological electrode used for acquiring a biological signal.

衣類の摩擦による静電気などの雑音を防ぐために、生体電極の上部の少なくとも生体信号導出部位(導電ゲル)を覆う様に生体電極用シールドを固定することが従来から知られている(下記特許文献1)。この生体電極用シールドは、生体電極の導電ゲルを覆う様に導電層が形成された絶縁性のシート部材と、導電層に電気的接続状態で形成された粘着性導電ゲルとを有し、粘着性導電ゲルにより導電層は人体と同電位になり被測定部より生体電気を誘導する電極部分への外部の雑音の影響が減衰されるとしている。   In order to prevent noise such as static electricity due to clothing friction, it is conventionally known that a bioelectrode shield is fixed so as to cover at least a biosignal deriving portion (conductive gel) above the bioelectrode (Patent Document 1 below). ). This shield for bioelectrodes has an insulating sheet member in which a conductive layer is formed so as to cover the conductive gel of the bioelectrode, and an adhesive conductive gel formed in an electrically connected state to the conductive layer. The conductive layer has the same potential as the human body due to the conductive conductive gel, and the influence of external noise on the electrode part that induces bioelectricity from the measurement target part is attenuated.

登録実用新案第3020953号公報Registered Utility Model No. 3020953

特許文献1では、生体電極とシールドとが実質的に別部材で、多数個製造する場合にも1つ1つの生体電極に対して個別にシールド用シートやテープ等での固定作業が必要となり、手間とコストがかかるという問題がある。   In Patent Document 1, the living body electrode and the shield are substantially separate members, and even when a large number of pieces are manufactured, it is necessary to individually fix each living body electrode with a shielding sheet or tape, There is a problem that it takes time and cost.

本発明はこうした状況を認識してなされたものであり、その目的は、シールドとなる導電体を生体電極に一体に形成でき、かつ多数個を効率的に製造することの可能な、生体電極の製造方法を提供することにある。   The present invention has been made in view of such a situation, and an object of the present invention is to provide a bioelectrode capable of integrally forming a conductor as a shield on the bioelectrode and efficiently manufacturing a large number of them. It is to provide a manufacturing method.

本発明のある態様は、生体電極の製造方法である。この方法は、
下敷き材上に少なくとも絶縁体、導電体及び基材が順番に積層された積層体を、前記下敷き材を残して所定形状の複数の個片に切断する工程と、
前記下敷き材の一部を剥離して各々の個片の絶縁体の一部を露出させながら前記下敷き材の前記一部を除く他の部分により個片同士の連結を維持した状態で、前記絶縁体の前記一部に受信体を接着する工程と、
前記受信体にスポンジを接着し、かつ前記スポンジに含水ゲルを染み込ませ、その後、前記下敷き材の前記他の部分を剥離する工程とを有する。
One embodiment of the present invention is a method for producing a bioelectrode. This method
Cutting the laminate in which at least the insulator, the conductor, and the base material are sequentially laminated on the underlaying material into a plurality of pieces having a predetermined shape, leaving the underlaying material;
In the state where the connection between the pieces is maintained by the other part excluding the part of the underlay material while exfoliating a part of the underlay material and exposing a part of the insulator of each piece. Adhering a receiver to the part of the body;
Adhering a sponge to the receiver, and impregnating the sponge with a water-containing gel, and then peeling the other part of the underlaying material.

前記下敷き材には予めスリット又は切込みが形成されていて、前記下敷き材の前記一部と前記他の部分とが前記スリット又は前記切込みによって区画されていてもよい。   A slit or a cut may be formed in advance in the underlay material, and the part and the other portion of the underlay material may be partitioned by the slit or the cut.

前記スポンジに環状の両面接着テープを接着しておき、前記両面接着テープの接着力で前記受信体に前記スポンジを接着してもよい。   An annular double-sided adhesive tape may be bonded to the sponge, and the sponge may be bonded to the receiver by the adhesive force of the double-sided adhesive tape.

前記積層体を形成する工程では、ロール状の絶縁体を前記下敷き材上に繰り出しながら接着してもよい。   In the step of forming the laminated body, a roll-shaped insulator may be bonded while being fed onto the underlay material.

前記積層体を形成する工程では、ロール状の基材であって一方の面に導電体が設けられた基材を前記絶縁体上に繰り出しながら接着してもよい。   In the step of forming the laminated body, a base material that is a roll-shaped base material and a conductor is provided on one surface may be bonded to the insulator while being fed out.

前記積層体を形成する工程では、前記下敷き材上に前記絶縁体及びアースゲルを同じ層に積層し、前記絶縁体及び前記アースゲルの双方を覆うように両層上に跨って前記導電体と前記基材とを積層してもよい。   In the step of forming the laminate, the insulator and the earth gel are laminated on the underlay material in the same layer, and the conductor and the base are straddled over both layers so as to cover both the insulator and the earth gel. You may laminate | stack a material.

前記絶縁体及び前記アースゲルを前記下敷き材上にロール状から繰り出しながら接着し、両層上にロール状の基材であって一方の面に導電体が設けられた基材を繰り出しながら接着してもよい。   The insulator and the earth gel are bonded to the underlay material while being fed out from a roll, and the roll-shaped substrate on both layers is bonded to the base material provided with a conductor on one surface. Also good.

前記受信体に前記スポンジを接着する際に両者の間にリード線を挟んでもよい。   When the sponge is bonded to the receiver, a lead wire may be sandwiched between the two.

前記積層体を形成する工程では、前記下敷き材上の前記基材上に不織布を接着してもよい。   In the step of forming the laminate, a nonwoven fabric may be bonded onto the base material on the underlay material.

前記スポンジに前記含水ゲルを染み込ませた後、前記絶縁体の前記一部にカバーを接着して前記一部と前記スポンジとを前記カバーで覆い、前記下敷き材の前記他の部分を剥離しながら前記絶縁体の残りの部分に前記カバーを接着して前記絶縁体を全面的に前記カバーで覆ってもよい。   After the sponge is soaked with the water-containing gel, a cover is adhered to the part of the insulator, the part and the sponge are covered with the cover, and the other part of the underlaying material is peeled off The cover may be adhered to the remaining portion of the insulator so that the insulator is entirely covered with the cover.

なお、以上の構成要素の任意の組合せ、本発明の表現を物やシステムなどの間で変換したものもまた、本発明の態様として有効である。   It should be noted that any combination of the above-described constituent elements and a representation obtained by converting the expression of the present invention between objects and systems are also effective as an aspect of the present invention.

本発明によれば、シールドとなる導電体を生体電極に一体に形成でき、かつ多数個を効率的に製造することができる。   According to the present invention, a conductor serving as a shield can be formed integrally with a biological electrode, and a large number can be efficiently manufactured.

本発明の実施の形態に係る生体電極の製造方法の工程説明図(その1)。Process explanatory drawing (the 1) of the manufacturing method of the bioelectrode which concerns on embodiment of this invention. 同工程説明図(その2)。Process explanatory drawing (the 2). 同工程説明図(その3)。Process explanatory drawing (the 3). 同方法で製造した生体電極100の斜視図。The perspective view of the bioelectrode 100 manufactured by the same method. 生体電極100の分解斜視図。The disassembled perspective view of the bioelectrode 100. FIG. 生体電極100の両面接着テープ7の平面図。The top view of the double-sided adhesive tape 7 of the bioelectrode 100. FIG. 別の形態の生体電極の分解斜視図。The disassembled perspective view of the bioelectrode of another form. さらに別の形態の生体電極の一部分解上方斜視図。Furthermore, the partially exploded upper perspective view of the bioelectrode of another form. 同生体電極の一部分解下方斜視図。The partially exploded lower perspective view of the same bioelectrode. 同生体電極の一部分解側面図。The partially exploded side view of the bioelectrode. 図10の一部拡大図。FIG. 11 is a partially enlarged view of FIG. 10.

以下、図面を参照しながら本発明の好適な実施の形態を詳述する。なお、各図面に示される同一または同等の構成要素、部材等には同一の符号を付し、適宜重複した説明は省略する。また、実施の形態は発明を限定するものではなく例示であり、実施の形態に記述されるすべての特徴やその組み合わせは必ずしも発明の本質的なものであるとは限らない。   Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings. In addition, the same code | symbol is attached | subjected to the same or equivalent component, member, etc. which are shown by each drawing, and the overlapping description is abbreviate | omitted suitably. In addition, the embodiments do not limit the invention but are exemplifications, and all features and combinations thereof described in the embodiments are not necessarily essential to the invention.

図1〜図3は、本発明の実施の形態に係る生体電極の製造方法の工程説明図である。図4は、同方法で製造した生体電極100の斜視図である。図5は、生体電極100の分解斜視図である。まず、図4及び図5により完成状態の生体電極100の構成を説明し、その後、図1〜図3により本実施の形態の製法について説明する。   1-3 is process explanatory drawing of the manufacturing method of the bioelectrode which concerns on embodiment of this invention. FIG. 4 is a perspective view of the bioelectrode 100 manufactured by the same method. FIG. 5 is an exploded perspective view of the bioelectrode 100. First, the configuration of the completed biological electrode 100 will be described with reference to FIGS. 4 and 5, and then the manufacturing method of the present embodiment will be described with reference to FIGS. 1 to 3.

図4に示すように、生体電極100は、電極ユニット20と、未使用時に電極ユニット20の人体側を覆うカバー10と、電極ユニット20及び図示しない外部装置を相互に電気的に接続するケーブル11とを備える。ケーブル11の一端は電極ユニット20と接触し、他端には外部装置との接続用のコネクタ12が設けられている。   As shown in FIG. 4, the bioelectrode 100 includes an electrode unit 20, a cover 10 that covers the human body side of the electrode unit 20 when not in use, and a cable 11 that electrically connects the electrode unit 20 and an external device (not shown) to each other. With. One end of the cable 11 is in contact with the electrode unit 20, and the other end is provided with a connector 12 for connection to an external device.

図5に示すように、電極ユニット20は、基材1と、不織布2と、導電体3と、絶縁体4と、アースゲル5と、受信体6と、両面接着テープ7と、スポンジ8と、含水ゲル9とを備える。   As shown in FIG. 5, the electrode unit 20 includes a base material 1, a nonwoven fabric 2, a conductor 3, an insulator 4, an earth gel 5, a receiver 6, a double-sided adhesive tape 7, a sponge 8, A hydrogel 9.

基材1は、PETフィルムやPPフィルム等の樹脂フィルムである(PET:ポリエチレンテレフタレート、PP:ポリプロピレン)。不織布2は、例えばPP不織布である。導電体3は、例えば導電性インクであって基材1に印刷等により塗布される。絶縁体4は、例えば生体粘着用(皮膚貼付用)両面粘着テープである。アースゲル5は、粘着性を有する導電ゲルである。受信体6は、PETフィルム等の樹脂フィルムの人体側に銀−塩化銀を塗布したものである。含水ゲル9は、水分含有量が80重量%で電気伝導のためにClイオンを含んでいる。含水ゲル9の水分含有量は、人体(肌)とのインピーダンス低減の観点から60重量%以上が望ましい。   The substrate 1 is a resin film such as a PET film or a PP film (PET: polyethylene terephthalate, PP: polypropylene). The nonwoven fabric 2 is, for example, a PP nonwoven fabric. The conductor 3 is, for example, conductive ink, and is applied to the substrate 1 by printing or the like. The insulator 4 is, for example, a bioadhesive (skin application) double-sided adhesive tape. The earth gel 5 is a conductive gel having adhesiveness. The receiver 6 is obtained by applying silver-silver chloride to the human body side of a resin film such as a PET film. The hydrogel 9 has a water content of 80% by weight and contains Cl ions for electrical conduction. The water content of the hydrogel 9 is preferably 60% by weight or more from the viewpoint of reducing impedance with the human body (skin).

基材1の反人体側の面に不織布2が設けられる(接着される)。不織布2は基材1の面垂直方向から見て基材1と略同形状である。基材1の人体側の面に導電体3が設けられる(全面的に塗布される)。導電体3の人体側の面に絶縁体4が設けられる(接着される)。絶縁体4は人体側の面にも粘着性を有する。受信体6は、絶縁体4の人体側の面に設けられる(絶縁体4の粘着力で接着される)。含水ゲル9は、単体では形が定まらないので、スポンジ8に染み込ませておく。含水ゲル9を染み込ませたスポンジ8は、受信体6の人体側に設けられる。スポンジ8と受信体6との接着は両面接着テープ7が行う。すなわち、両面接着テープ7は、スポンジ8の反人体側の面に接着されて当該面の中央部を囲む環状(ここではドーナツ状)であり、スポンジ8と受信体6とを接着する。両面接着テープ7は、好ましくはスポンジ8の反人体側の面の外周縁ないしその近傍を周回する。アースゲル5は、導電体3の人体側の面であって絶縁体4とは異なる位置に設けられる。なお、絶縁体4にアースゲル5が重なっても、アースゲル5が人体に接すれば機能的に良い。   A non-woven fabric 2 is provided (adhered) on the surface of the substrate 1 on the side opposite to the human body. The nonwoven fabric 2 has substantially the same shape as the base material 1 when viewed from the plane perpendicular to the base material 1. The conductor 3 is provided on the human body side surface of the substrate 1 (applied over the entire surface). An insulator 4 is provided (adhered) on the surface of the conductor 3 on the human body side. The insulator 4 also has adhesiveness on the surface on the human body side. The receiver 6 is provided on the human body side surface of the insulator 4 (adhered by the adhesive force of the insulator 4). The hydrated gel 9 is soaked in the sponge 8 because its shape is not fixed by itself. The sponge 8 soaked with the hydrous gel 9 is provided on the human body side of the receiver 6. Adhesion between the sponge 8 and the receiver 6 is performed by a double-sided adhesive tape 7. That is, the double-sided adhesive tape 7 has an annular shape (here, a donut shape) that is bonded to the surface of the sponge 8 on the side opposite to the human body and surrounds the center of the surface, and bonds the sponge 8 and the receiver 6 together. The double-sided adhesive tape 7 preferably circulates around the outer peripheral edge of the surface of the sponge 8 on the side opposite to the human body or the vicinity thereof. The earth gel 5 is provided on a human body side surface of the conductor 3 and at a position different from the insulator 4. In addition, even if the ground gel 5 overlaps the insulator 4, it is functionally good if the ground gel 5 is in contact with the human body.

カバー10は、平坦部10aと、平坦部10aから凹む凹部10bとを有する。平坦部10aは、電極ユニット20のうちスポンジ8を除く部分と対面する。凹部10bは、スポンジ8等を収容する。カバー10は、樹脂製であって、電極ユニット20との剥離性を良くするために電極ユニット20との接触部分(絶縁体4及びアースゲル5との接触面)にシリコーン又はフッ素(離型剤)がコーティングされている。また、カバー10と電極ユニット20との剥離作業性を良くするために、電極ユニット20のうちカバー10に対面する一部であってスポンジ8を除く一部に粘着性の無い部分を設けている。具体的には、アースゲル5の絶縁体4とは反対側の外周縁が、基材1と不織布2と導電体3との積層体の外周縁よりも内側にある。このため、前記積層体はアースゲル5の前記外周縁よりも外側に延在しており、使用者はこの延在した部分を手で持って電極ユニット20をカバー10から容易に剥離可能である。なお、粘着性の無い部分は、絶縁体4の外周縁を内側に寄せることによって設けてもよい。   The cover 10 includes a flat portion 10a and a concave portion 10b that is recessed from the flat portion 10a. The flat portion 10a faces a portion of the electrode unit 20 excluding the sponge 8. The recess 10b houses the sponge 8 and the like. The cover 10 is made of resin, and silicone or fluorine (release agent) is formed on a contact portion with the electrode unit 20 (contact surface with the insulator 4 and the earth gel 5) in order to improve releasability from the electrode unit 20. Is coated. Further, in order to improve the peeling workability between the cover 10 and the electrode unit 20, a part of the electrode unit 20 facing the cover 10 and a part having no adhesiveness is provided except for the sponge 8. . Specifically, the outer peripheral edge of the ground gel 5 opposite to the insulator 4 is inside the outer peripheral edge of the laminate of the base material 1, the nonwoven fabric 2, and the conductor 3. For this reason, the said laminated body is extended outside the said outer periphery of the earth gel 5, and the user can peel the electrode unit 20 from the cover 10 easily by holding this extended part. Note that the non-adhesive portion may be provided by bringing the outer peripheral edge of the insulator 4 to the inside.

ケーブル11は、カーボン線であり、端部が受信体6とスポンジ8との間に挟まれる。ケーブル11の保持は両面接着テープ7による。このため、図6に示すように、両面接着テープ7は、中央孔の形状を例えばD型にして周の一部を幅広部7aとし、幅広部7aでケーブル11を接着保持するとよい。   The cable 11 is a carbon wire, and its end is sandwiched between the receiver 6 and the sponge 8. The cable 11 is held by the double-sided adhesive tape 7. For this reason, as shown in FIG. 6, the double-sided adhesive tape 7 is preferably formed such that the center hole has a D shape, for example, and a part of the circumference is a wide part 7a, and the cable 11 is adhered and held by the wide part 7a.

使用前には、生体電極100は、防湿袋に入れて保管される。使用の際には、生体電極100を防湿袋から取り出し、カバー10を取り外し、含水ゲル9の染み込んだスポンジ8を人体の所定部位に接触させ、絶縁体4とアースゲル5を人体に接着する。すると、生体信号は含水ゲル9を伝わって受信体6で受信され、ケーブル11を介して外部装置に送信される。一方、導電体3は、アースゲル5を介して人体と電気的に接続されて人体と近い電位になっている。このため、導電体3が外部の静電気等のノイズに対するシールドとなり、生体信号にノイズが入ることを防止できる。   Prior to use, the bioelectrode 100 is stored in a moisture-proof bag. In use, the bioelectrode 100 is taken out from the moisture-proof bag, the cover 10 is removed, the sponge 8 soaked with the hydrogel 9 is brought into contact with a predetermined part of the human body, and the insulator 4 and the earth gel 5 are bonded to the human body. Then, the biological signal is transmitted through the hydrogel 9 and received by the receiver 6 and transmitted to the external device via the cable 11. On the other hand, the conductor 3 is electrically connected to the human body via the earth gel 5 and has a potential close to that of the human body. For this reason, the conductor 3 becomes a shield against noises such as external static electricity, and noise can be prevented from entering the biological signal.

以下、図1〜図3を参照して本実施の形態の製法について説明する。   Hereinafter, the manufacturing method of the present embodiment will be described with reference to FIGS.

図1(A)に示すように、下敷き材としての下敷きフィルム30を準備する。下敷きフィルム30は、例えばPETフィルムからなる基材であり、製造工程で用いられて最終的には除去される。下敷きフィルム30には、スリット31と、位置決め孔32とが設けられる。スリット31は、下敷きフィルム30の中間部(好ましくは中央部)を横切るように形成されて下敷きフィルム30を厚さ方向に貫通する。位置決め孔32は、後述の各工程での位置合わせ用の基準孔として機能する。なお、下敷きフィルム30は好ましくはロール状から繰り出され、図1(A)に示される下敷きフィルム30は長尺に渡って並ぶ多数個の区画のうちの1つである(各区画にスリット31が設けられ、位置決め孔32は、スリット31の長さよりも中央側に設けられている)。   As shown in FIG. 1A, an underlay film 30 is prepared as an underlay material. The underlay film 30 is a base material made of, for example, a PET film, and is used in the manufacturing process and finally removed. The underlay film 30 is provided with slits 31 and positioning holes 32. The slit 31 is formed so as to cross an intermediate portion (preferably a central portion) of the underlay film 30 and penetrates the underlay film 30 in the thickness direction. The positioning hole 32 functions as a reference hole for alignment in each process described later. The underlay film 30 is preferably drawn out from a roll shape, and the underlay film 30 shown in FIG. 1 (A) is one of a number of compartments arranged in a long length (a slit 31 is provided in each compartment). The positioning hole 32 is provided on the center side with respect to the length of the slit 31).

下敷きフィルム30上に、位置決め孔32を基準にして、絶縁体4及びアースゲル5を同層かつ異なる位置に積層(接着)する。このとき、好ましくは絶縁体4及びアースゲル5をそれぞれロール状から繰り出し、下敷きフィルム30の多数個の区画に一括して接着する。絶縁体4の接着位置は、スリット31の両側に跨る位置とする。アースゲル5の接着位置は絶縁体4の近傍とする。   On the underlying film 30, the insulator 4 and the earth gel 5 are laminated (adhered) in the same layer and at different positions on the basis of the positioning holes 32. At this time, preferably, the insulator 4 and the earth gel 5 are each fed out from the roll shape and bonded together to a number of sections of the underlay film 30. The bonding position of the insulator 4 is a position straddling both sides of the slit 31. The bonding position of the earth gel 5 is in the vicinity of the insulator 4.

図1(B)に示すように、位置決め孔32を基準にして、絶縁体4及びアースゲル5の双方を覆うように両層上に跨って基材1を積層(接着)し、さらに不織布2を積層(接着)する。なお、基材1の片面には導電性インク(図5の導電体3)が印刷されており、導電性インクが絶縁体4及びアースゲル5側となるように基材1は積層される。このとき、好ましくは片面に導電性インクが塗布されたロール状の基材1を絶縁体4及びアースゲル5の上に繰り出しながら多数個の区画に一括して接着する。そして、好ましくはロール状の不織布2を基材1上に繰り出しながら多数個の区画に一括して接着する。   As shown in FIG. 1 (B), the base material 1 is laminated (adhered) over both layers so as to cover both the insulator 4 and the earth gel 5 with the positioning hole 32 as a reference, and the nonwoven fabric 2 is further bonded. Laminate (adhere). In addition, conductive ink (conductor 3 in FIG. 5) is printed on one surface of the substrate 1, and the substrate 1 is laminated so that the conductive ink is on the insulator 4 and the earth gel 5 side. At this time, the roll-shaped base material 1 preferably coated with conductive ink on one side is bonded to a large number of compartments while being fed onto the insulator 4 and the earth gel 5. And preferably, the roll-shaped nonwoven fabric 2 is bonded to a large number of compartments while being fed onto the substrate 1.

図1(C)に示すように、下敷きフィルム30上の積層体(第1層は絶縁体4及びアースゲル5、第2層は導電体3が設けられた基材1、第3層は不織布2)を、下敷きフィルム30を残して所定形状の複数の個片51に切断する(ハーフカットする)。ここでは、1区画につき6つの個片51に切断する。なお、以降説明する図2及び図3では、下敷きフィルム30及び個片51の厚みを図1と比較して小さく示している。図1(C)の工程後、下敷きフィルム30を区画ごとに分割し、全体を裏返して下敷きフィルム30を上側にする。なお、図1(D)は分割時の切断ラインの縮小説明図であり、本図において下敷きフィルム30以外の要素は省略している。   As shown in FIG. 1C, a laminate on the underlay film 30 (the first layer is an insulator 4 and an earth gel 5, the second layer is a substrate 1 provided with a conductor 3, and the third layer is a non-woven fabric 2). Is cut into a plurality of pieces 51 having a predetermined shape (half cut), leaving the underlay film 30. Here, it cuts into 6 pieces 51 per division. In FIGS. 2 and 3 to be described later, the thickness of the underlay film 30 and the piece 51 is shown smaller than that in FIG. After the process of FIG. 1C, the underlay film 30 is divided into sections, and the whole is turned over so that the underlay film 30 is on the upper side. Note that FIG. 1D is a diagram for explaining reduction of the cutting line at the time of division, and elements other than the underlay film 30 are omitted in this drawing.

図2(A)に示すように、下敷きフィルム30の一部を剥離して各々の個片51の絶縁体4の一部を露出させながら、下敷きフィルム30の残りの部分により個片51同士の連結を維持した状態とする。具体的には、下敷きフィルム30のうちスリット31の一方側(アースゲル5の存在しない側)を剥離する。この際、スリット31があることにより、下敷きフィルム30の両端部を切断する(例えば区画ごとへの分割時に図1(D)のようにスリット31の端部と繋がる切断ラインで切断しておく)ことで容易に下敷きフィルム30の一部を剥離することができる。   As shown in FIG. 2 (A), a part of the underlay film 30 is peeled off to expose a part of the insulator 4 of each piece 51, and the remaining pieces of the underlay film 30 make the pieces 51 to each other. The connection is maintained. Specifically, one side (the side where the earth gel 5 does not exist) of the slit 31 is peeled from the underlying film 30. At this time, both ends of the underlay film 30 are cut due to the presence of the slits 31 (for example, cut at a cutting line connected to the ends of the slits 31 as shown in FIG. 1D when divided into sections). Thus, a part of the underlay film 30 can be easily peeled off.

図2(B)に示すように、各々の個片51の絶縁体4の露出部分に、受信体6を接着する。次に、図2(C)に示すように各々の受信体6にケーブル11(リード線アセンブリ)の一端(コネクタ12と反対側の端部)を載置した状態で、図2(D)に示すように受信体6上にスポンジ8を両面接着テープ7で接着する。このとき、両面接着テープ7の幅広部7aでケーブル11の一端を接着保持する。   As shown in FIG. 2B, the receiver 6 is bonded to the exposed portion of the insulator 4 of each piece 51. Next, as shown in FIG. 2 (C), with one end (the end opposite to the connector 12) of the cable 11 (lead wire assembly) placed on each receiver 6, FIG. As shown, a sponge 8 is bonded to the receiver 6 with a double-sided adhesive tape 7. At this time, one end of the cable 11 is bonded and held by the wide portion 7 a of the double-sided adhesive tape 7.

図3(A)に示すように、各々のスポンジ8に、所定量の含水ゲル9を注入する(染み込ませる)。その後、図3(B)に示すように、絶縁体4の露出部分にカバー10を接着して絶縁体4の露出部分とスポンジ8とをカバー10で覆い、下敷きフィルム30の残りの部分を剥離しながら絶縁体4の残りの部分にカバー10を接着して絶縁体4を全面的にカバー10で覆う(カバー10の平坦部10aで絶縁体4を覆い、凹部10bでスポンジ8を覆う)。そして、1区画(6つの個片51)単位で不図示の防湿袋に入れ、必要に応じて箱詰めする。   As shown in FIG. 3 (A), a predetermined amount of water-containing gel 9 is injected (soaked) into each sponge 8. Thereafter, as shown in FIG. 3B, the cover 10 is adhered to the exposed portion of the insulator 4 to cover the exposed portion of the insulator 4 and the sponge 8 with the cover 10, and the remaining portion of the underlay film 30 is peeled off. Then, the cover 10 is adhered to the remaining portion of the insulator 4, and the insulator 4 is entirely covered with the cover 10 (the insulator 4 is covered with the flat portion 10a of the cover 10 and the sponge 8 is covered with the recess 10b). And it puts into a moisture-proof bag not shown in the unit of 1 section (six pieces 51), and packs up as needed.

本実施の形態によれば、下記の効果を奏することができる。   According to the present embodiment, the following effects can be achieved.

(1) ノイズに対するシールドとなる導電体を生体電極に一体に形成できるため、従来と異なり、1つ1つの生体電極に対して個別にシールド用シートやテープ等での固定作業をする必要がない。したがって、従来と比較してシールド固定の手間がなく、製造容易かつコスト安である。 (1) Since the conductor that serves as a shield against noise can be formed integrally with the biological electrode, unlike the conventional case, it is not necessary to individually fix each biological electrode with a shielding sheet or tape. . Therefore, there is no need to fix the shield as compared with the conventional case, and the manufacturing is easy and the cost is low.

(2) 下敷きフィルム30上の積層体を複数の個片51に分割するとき、下敷きフィルム30の一部を剥離して各々の個片51の絶縁体4の一部を露出させながら、下敷きフィルム30の残りの部分により個片51同士の連結を維持した状態とするので、以降の作業において同一区画の個片51がばらばらにならず、作業性が良い。また、下敷きフィルム30のスリット31を利用することで下敷きフィルム30の前記一部の剥離は容易である。 (2) When the laminated body on the underlay film 30 is divided into a plurality of pieces 51, the underlay film 30 is peeled off while exposing a part of the insulator 4 of each piece 51. Since the connection between the pieces 51 is maintained by the remaining 30 parts, the pieces 51 in the same section are not separated in the subsequent work, and the workability is good. Further, the part of the underlying film 30 can be easily peeled off by using the slit 31 of the underlying film 30.

(3) 下敷きフィルム30上に、絶縁体4、アースゲル5、基材1(片面に導電体あり)、及び不織布2をロール状から繰り出して積層することで、多数個分の積層体を一括して作製でき、製造効率が良い。 (3) On the underlay film 30, the insulator 4, the earth gel 5, the base material 1 (with a conductor on one side), and the non-woven fabric 2 are rolled out and laminated, so that a large number of laminated bodies are collected at once. Manufacturing efficiency and good manufacturing efficiency.

(4) 受信体6に対するスポンジ8の接着は両面接着テープ7で行っているため、ホットメルトを使用する場合と異なり、高温に保つディスペンサーや恒温槽での加熱保持が不要となる。 (4) Since the sponge 8 is bonded to the receiver 6 with the double-sided adhesive tape 7, unlike the case of using hot melt, it is not necessary to heat and hold the dispenser at a high temperature or a thermostatic bath.

(5) 生体信号取得用に水分を60重量%以上含む含水ゲル9を染み込ませたスポンジ8を用いているため、従来のように粘着性の導電ゲルを用いる場合と異なり、導電性クリームなどを塗らなくても人体とのインピーダンスを小さくすることができる。したがって、導電性クリームやそれを塗る作業が不要で、従来と比較して手間とコストが低減される。 (5) Since the sponge 8 impregnated with the water-containing gel 9 containing 60% by weight or more of moisture is used for biosignal acquisition, a conductive cream or the like is used unlike a case where an adhesive conductive gel is used. The impedance with the human body can be reduced without painting. Therefore, the conductive cream and the work of applying it are unnecessary, and labor and cost are reduced as compared with the conventional case.

(6) 基材1が樹脂フィルムのため、導電体3としての導電性インクを均一に塗布でき、シールド効果が高い。 (6) Since the substrate 1 is a resin film, the conductive ink as the conductor 3 can be uniformly applied, and the shielding effect is high.

(7) 基材1の反人体側の面に不織布2を設けているため、不織布2が無い場合と比較して静電気の発生が小さくなり、ノイズが少なくなる。特に、医者や患者が着る手術服の材質はPPであることが多いため、不織布2をPP不織布とすれば、静電気発生の防止効果が高い。 (7) Since the nonwoven fabric 2 is provided on the surface of the substrate 1 on the side opposite to the human body, the generation of static electricity is reduced and noise is reduced as compared with the case where the nonwoven fabric 2 is not provided. In particular, since the material of surgical clothes worn by doctors and patients is often PP, if the nonwoven fabric 2 is a PP nonwoven fabric, the effect of preventing the generation of static electricity is high.

(8) スポンジ8と受信体6とを接着する両面接着テープ7をドーナツ状としているため、接着作業性がよく、またドーナツ状の内側の広い面積でスポンジ8と受信体6とが接触することになり生体信号の受信感度が高い。さらに、両面接着テープ7の幅広部7aでケーブル11を接着保持するため、ケーブル11の保持強度が高い。 (8) Since the double-sided adhesive tape 7 for bonding the sponge 8 and the receiver 6 has a donut shape, the bonding workability is good, and the sponge 8 and the receiver 6 are in contact with each other over a wide area inside the donut shape. The reception sensitivity of biological signals is high. Furthermore, since the cable 11 is bonded and held by the wide portion 7a of the double-sided adhesive tape 7, the holding strength of the cable 11 is high.

(9) カバー10は樹脂製であって絶縁体4及びアースゲル5との接触面にシリコーンが塗布されているため、使用時にカバー10を剥離しやすく(取り外しやすく)、カバー10の剥離時における電極ユニットの変形が少なくなる。また、基材1と不織布2と導電体3との積層体がアースゲル5の絶縁体4とは反対側の外周縁よりも外側に延在しているため、使用者はこの延在した部分を手で持って電極ユニット20をカバー10から容易に剥離可能である。 (9) Since the cover 10 is made of resin and silicone is applied to the contact surface with the insulator 4 and the earth gel 5, the cover 10 can be easily peeled off (easy to remove) during use, and the electrode when the cover 10 is peeled off Unit deformation is reduced. Moreover, since the laminated body of the base material 1, the nonwoven fabric 2, and the conductor 3 extends outside the outer peripheral edge on the side opposite to the insulator 4 of the earth gel 5, the user can use this extended portion. The electrode unit 20 can be easily peeled from the cover 10 by hand.

(10) 電極ユニット20は全てX線を透過する材料で構成され、かつ受信体6と外部装置とを接続するケーブル11にカーボン線を使用しているため、生体電極100はX線透過型となり、X線を透過しながら治療する用途にも適合する。 (10) Since the electrode unit 20 is all made of a material that transmits X-rays and uses a carbon wire for the cable 11 that connects the receiver 6 and the external device, the biological electrode 100 becomes an X-ray transmission type. It is also suitable for use in treatment while transmitting X-rays.

図7は、図4及び図5に示したものとは別の形態の生体電極の分解斜視図である。この生体電極は、図4及び図5に示したものと比較して、絶縁体4が小さくなり、それにより空いたスペースにアースゲル5’が設けられている(アースゲルが複数設けられて絶縁体4を挟む配置である)点で相違し、その他の点は同様である。アースゲル5’は、受信体6の反人体側の面に延在している。この形態によれば、アースゲル5,5’が相互に異なる位置で人体と接触して導電体3を確実かつ安定的に人体と同電位にするため、図4及び図5の形態と比較して、更なるノイズ低減効果を奏することができる。製造にあたっては、絶縁体4及びアースゲル5と共にアースゲル5’も併せて下敷きフィルム30上に同層かつ異なる位置に積層(接着)する。また、受信体6の接着位置は、絶縁体4の露出部分とアースゲル5’の露出部分とに跨る。製法におけるその他の点は図1〜図3で説明した実施の形態のものと同じである。   FIG. 7 is an exploded perspective view of a bioelectrode having a form different from that shown in FIGS. 4 and 5. In this bioelectrode, the insulator 4 is smaller than those shown in FIGS. 4 and 5, and thereby an earth gel 5 ′ is provided in the vacant space (a plurality of earth gels are provided and the insulator 4 is provided). The other points are the same. The earth gel 5 ′ extends on the surface of the receiver 6 on the side opposite to the human body. According to this embodiment, the earth gels 5 and 5 'come into contact with the human body at different positions so that the conductor 3 is reliably and stably at the same potential as the human body. Further noise reduction effects can be achieved. In manufacturing, the ground gel 5 ′ together with the insulator 4 and the ground gel 5 are laminated (adhered) on the underlying film 30 in the same layer and at different positions. The bonding position of the receiver 6 extends over the exposed portion of the insulator 4 and the exposed portion of the earth gel 5 '. Other points in the manufacturing method are the same as those of the embodiment described with reference to FIGS.

図8は、図4、図5及び図7に示したものとは別の形態の生体電極の一部分解上方斜視図である。図9は、同生体電極の一部分解下方斜視図である。図10は、同生体電極の一部分解側面図である。図11は、図10の一部拡大図である。なお、これらの図においては、受信体6の樹脂フィルム61(PETフィルム等)及びそれに塗布された銀−塩化銀62を別々に示している。この生体電極は、図4及び図5に示したものと異なり、図示しない外部装置との接続をクリップ等で行う構成としている。以下、相違点を中心に説明し、一致点についての説明は適宜省略する。   FIG. 8 is a partially exploded upper perspective view of a bioelectrode having a different form from that shown in FIGS. 4, 5, and 7. FIG. 9 is a partially exploded lower perspective view of the bioelectrode. FIG. 10 is a partially exploded side view of the bioelectrode. FIG. 11 is a partially enlarged view of FIG. In these figures, the resin film 61 (PET film or the like) of the receiver 6 and the silver-silver chloride 62 applied thereto are separately shown. Unlike the one shown in FIGS. 4 and 5, this bioelectrode is configured to be connected to an external device (not shown) with a clip or the like. Hereinafter, the description will focus on the differences, and the description on the points of coincidence will be omitted as appropriate.

受信体6を成す樹脂フィルム61及び銀−塩化銀62はそれぞれ、スポンジ8の外側に同形状で延在した延在部61a,62aを有する。基材1及び導電体3はそれぞれ、折返し部1a,3aを有する。折返し部1a,3aは、基材1及び導電体3の主面部より幅狭で当該主面部から外側に延び、反人体側に折り返されている。導電体3の折返し部3aは、反人体側の表面に露出する。樹脂フィルム61及び銀−塩化銀62の延在部61a,62aと、基材1及び導電体3の折返し部1a,3aとは、間に絶縁体4の延在部4aを挟み、また基材1の面垂直方向から見て互いに略同一位置にあって基材1の主面部の外側において略同一形状であり、これらをクリップで挟み込むことで、銀−塩化銀62の延在部62aを外部装置の信号取得端子に接続し、導電体3の折返し部3aを外部装置のアース端子に接続できる。なお、導電体3を外部装置のアース端子に接続するため、図5に示すアースゲル5は用いず、その分だけ絶縁体4を大きなものとしている。カバー10との剥離性を考えて絶縁体4の外周縁を基材1、不織布2及び導電体3の外周縁よりも内側としてもよい。この形態によれば、クリップ接続のためX線透過型にならない点を除き、図4及び図5の形態と同様の作用効果を奏することができる。   Each of the resin film 61 and the silver-silver chloride 62 constituting the receiver 6 has extending portions 61 a and 62 a extending in the same shape on the outside of the sponge 8. The base material 1 and the conductor 3 respectively have folded portions 1a and 3a. The folded portions 1 a and 3 a are narrower than the main surface portions of the base material 1 and the conductor 3, extend outward from the main surface portions, and are folded back to the anti-human body side. The folded portion 3a of the conductor 3 is exposed on the surface on the anti-human body side. The extending portions 61a and 62a of the resin film 61 and the silver-silver chloride 62, and the folded portions 1a and 3a of the base material 1 and the conductor 3 sandwich the extending portion 4a of the insulator 4 between them. 1 are substantially in the same position as viewed from the direction perpendicular to the surface of the substrate 1 and have substantially the same shape on the outside of the main surface portion of the substrate 1, and by sandwiching them with clips, the extended portion 62a of the silver-silver chloride 62 can be Connected to the signal acquisition terminal of the device, the folded portion 3a of the conductor 3 can be connected to the ground terminal of the external device. Since the conductor 3 is connected to the ground terminal of the external device, the ground gel 5 shown in FIG. 5 is not used, and the insulator 4 is made larger correspondingly. Considering the peelability from the cover 10, the outer peripheral edge of the insulator 4 may be set inside the outer peripheral edges of the substrate 1, the nonwoven fabric 2 and the conductor 3. According to this embodiment, the same effects as those of the embodiments of FIGS. 4 and 5 can be obtained except that the X-ray transmission type is not achieved due to the clip connection.

製造にあたっては、基材1、導電体3(基材1に塗布済み)、及び絶縁体4には予め折返し部1a,3a及び延在部4aに相当する部分を積層前の(ロール状の)段階から形成しておく。アースゲル5は下敷きフィルム30上に積層しない。基材1、導電体3(基材1に塗布済み)を絶縁体4上に積層後、折返し部1a,3aを不織布2の手前まで折り返す(不織布2には重ねない)。また、受信体6を成す樹脂フィルム61及び銀−塩化銀62は、延在部61a,62aが予め設けられたものを用い、絶縁体4上の所定位置に接着する。外部との接続はクリップによるため、ケーブル11は取り付けない。製法におけるその他の点は図1〜図3で説明した実施の形態のものと同じである。   In the production, the base material 1, the conductor 3 (already applied to the base material 1), and the insulator 4 are pre-stacked (roll-shaped) portions corresponding to the folded portions 1a, 3a and the extending portion 4a. Form from the stage. The earth gel 5 is not laminated on the underlying film 30. After the base material 1 and the conductor 3 (already applied to the base material 1) are laminated on the insulator 4, the folded portions 1a and 3a are folded back to the front of the non-woven fabric 2 (not overlapped with the non-woven fabric 2). In addition, the resin film 61 and the silver-silver chloride 62 constituting the receiver 6 are provided with extension portions 61 a and 62 a in advance, and are adhered to predetermined positions on the insulator 4. Since the connection with the outside is by a clip, the cable 11 is not attached. Other points in the manufacturing method are the same as those of the embodiment described with reference to FIGS.

以上、実施の形態を例に本発明を説明したが、実施の形態の各構成要素や各処理プロセスには請求項に記載の範囲で種々の変形が可能であることは当業者に理解されるところである。以下、変形例について触れる。   The present invention has been described above by taking the embodiment as an example. However, it is understood by those skilled in the art that various modifications can be made to each component and each processing process of the embodiment within the scope of the claims. By the way. Hereinafter, modifications will be described.

用途によっては不織布は無くてもかまわない。   Depending on the application, there may be no non-woven fabric.

下敷き材はフィルム状に限らず、例えばシート状であってもよい。   The underlay material is not limited to a film shape, and may be a sheet shape, for example.

スリット31に代えて、幅の無い切込みを設けてもよい。   Instead of the slit 31, a cut having no width may be provided.

基材1は、樹脂フィルムに限らず、PP不織布等の不織布、又は布であってもよい。この場合、基材1の反人体側には不織布は設けない。導電体3としての導電性インクの塗布均一性に関しては基材1は樹脂フィルムであるほうが良いものの、その他の点では本変形例も実施の形態と同様の効果を得られる。   The substrate 1 is not limited to a resin film, and may be a nonwoven fabric such as a PP nonwoven fabric or a cloth. In this case, a non-woven fabric is not provided on the anti-human body side of the substrate 1. Regarding the application uniformity of the conductive ink as the conductor 3, the base material 1 is preferably a resin film, but in other respects, this modification can also obtain the same effects as those of the embodiment.

1 基材
2 不織布
3 導電体
4 絶縁体
5 アースゲル
6 受信体
61 樹脂フィルム
62 銀−塩化銀
7 両面テープ
7a 幅広部
8 スポンジ
9 含水ゲル
10 カバー
10a 平坦部
10b 凹部
11 ケーブル
12 コネクタ
20 電極ユニット
30 下敷きフィルム
31 スリット
32 位置決め孔
100 生体電極
DESCRIPTION OF SYMBOLS 1 Base material 2 Nonwoven fabric 3 Conductor 4 Insulator 5 Ground gel 6 Receiver 61 Resin film 62 Silver-silver chloride 7 Double-sided tape 7a Wide part 8 Sponge 9 Hydrous gel 10 Cover 10a Flat part 10b Recess 11 Cable 12 Connector 20 Electrode unit 30 Underlay film 31 Slit 32 Positioning hole 100 Bioelectrode

Claims (10)

下敷き材上に少なくとも絶縁体、導電体及び基材が順番に積層された積層体を、前記下敷き材を残して所定形状の複数の個片に切断する工程と、
前記下敷き材の一部を剥離して各々の個片の絶縁体の一部を露出させながら前記下敷き材の前記一部を除く他の部分により個片同士の連結を維持した状態で、前記絶縁体の前記一部に受信体を接着する工程と、
前記受信体にスポンジを接着し、かつ前記スポンジに含水ゲルを染み込ませ、その後、前記下敷き材の前記他の部分を剥離する工程とを有する、生体電極の製造方法。
Cutting the laminate in which at least the insulator, the conductor, and the base material are sequentially laminated on the underlaying material into a plurality of pieces having a predetermined shape, leaving the underlaying material;
In the state where the connection between the pieces is maintained by the other part excluding the part of the underlay material while exfoliating a part of the underlay material and exposing a part of the insulator of each piece. Adhering a receiver to the part of the body;
A method of manufacturing a bioelectrode, comprising: adhering a sponge to the receiver and impregnating the sponge with a water-containing gel, and then peeling the other part of the underlay material.
前記下敷き材には予めスリット又は切込みが形成されていて、前記下敷き材の前記一部と前記他の部分とが前記スリット又は前記切込みによって区画されている、請求項1に記載の生体電極の製造方法。   2. The bioelectrode production according to claim 1, wherein a slit or a cut is formed in advance in the underlay material, and the part and the other portion of the underlay material are partitioned by the slit or the cut. Method. 前記スポンジに環状の両面接着テープを接着しておき、前記両面接着テープの接着力で前記受信体に前記スポンジを接着する、請求項1又は2に記載の生体電極の製造方法。   The bioelectrode manufacturing method according to claim 1, wherein an annular double-sided adhesive tape is bonded to the sponge, and the sponge is bonded to the receiver by an adhesive force of the double-sided adhesive tape. 前記積層体を形成する工程では、ロール状の絶縁体を前記下敷き材上に繰り出しながら接着する、請求項1から3のいずれか一項に記載の生体電極の製造方法。   The method for producing a bioelectrode according to any one of claims 1 to 3, wherein in the step of forming the laminated body, a roll-shaped insulator is adhered while being fed onto the underlaying material. 前記積層体を形成する工程では、ロール状の基材であって一方の面に導電体が設けられた基材を前記絶縁体上に繰り出しながら接着する、請求項1から4のいずれか一項に記載の生体電極の製造方法。   5. The step of forming the laminated body includes a roll-shaped base material, and a base material provided with a conductor on one surface is bonded to the insulator while being fed out. The manufacturing method of the bioelectrode as described in any one of. 前記積層体を形成する工程では、前記下敷き材上に前記絶縁体及びアースゲルを同じ層に積層し、前記絶縁体及び前記アースゲルの双方を覆うように両層上に跨って前記導電体と前記基材とを積層する、請求項1から3のいずれか一項に記載の生体電極の製造方法。   In the step of forming the laminate, the insulator and the earth gel are laminated on the underlay material in the same layer, and the conductor and the base are straddled over both layers so as to cover both the insulator and the earth gel. The manufacturing method of the bioelectrode as described in any one of Claim 1 to 3 which laminates | stacks a material. 前記絶縁体及び前記アースゲルを前記下敷き材上にロール状から繰り出しながら接着し、両層上にロール状の基材であって一方の面に導電体が設けられた基材を繰り出しながら接着する、請求項6に記載の生体電極の製造方法。   The insulator and the earth gel are adhered while being fed out from the roll on the underlaying material, and are adhered while being fed out a base material that is a roll-shaped base material on one surface and a conductor is provided on one surface. The manufacturing method of the bioelectrode of Claim 6. 前記受信体に前記スポンジを接着する際に両者の間にリード線を挟む請求項6又は7に記載の生体電極の製造方法。   The bioelectrode manufacturing method according to claim 6 or 7, wherein a lead wire is sandwiched between the two when the sponge is bonded to the receiver. 前記積層体を形成する工程では、前記下敷き材上の前記基材上に不織布を接着する、請求項1から8のいずれか一項に記載の生体電極の製造方法。   The method for producing a bioelectrode according to any one of claims 1 to 8, wherein in the step of forming the laminate, a non-woven fabric is bonded onto the base material on the underlay material. 前記スポンジに前記含水ゲルを染み込ませた後、前記絶縁体の前記一部にカバーを接着して前記一部と前記スポンジとを前記カバーで覆い、前記下敷き材の前記他の部分を剥離しながら前記絶縁体の残りの部分に前記カバーを接着して前記絶縁体を全面的に前記カバーで覆う、請求項1から9のいずれか一項に記載の生体電極の製造方法。   After the sponge is soaked with the water-containing gel, a cover is adhered to the part of the insulator, the part and the sponge are covered with the cover, and the other part of the underlaying material is peeled off The bioelectrode manufacturing method according to any one of claims 1 to 9, wherein the cover is bonded to the remaining portion of the insulator and the insulator is entirely covered with the cover.
JP2012102367A 2012-04-27 2012-04-27 Method of manufacturing bioelectrode Pending JP2013230182A (en)

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