JP2013156381A5 - - Google Patents

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JP2013156381A5
JP2013156381A5 JP2012015880A JP2012015880A JP2013156381A5 JP 2013156381 A5 JP2013156381 A5 JP 2013156381A5 JP 2012015880 A JP2012015880 A JP 2012015880A JP 2012015880 A JP2012015880 A JP 2012015880A JP 2013156381 A5 JP2013156381 A5 JP 2013156381A5
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Japan
Prior art keywords
electrophoretic
coupling agent
silane coupling
particle
initiating group
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JP2012015880A
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JP2013156381A (en
JP5927938B2 (en
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Claims (13)

母粒子と、
前記母粒子の少なくとも一部を覆う被覆層とを有し、
前記被覆層は、重合開始基を有するシランカップリング剤と、前記重合開始基に、モノマーがリビングラジカル重合した重合部とを備えるポリマーを含んでおり、
前記ポリマーは、前記母粒子の表面への結合度が0.01chain/nm以上、0.1chain/nm以下であることを特徴とする電気泳動粒子。
Mother particles,
A coating layer covering at least a part of the mother particles,
The coating layer includes a silane coupling agent having an Polymerization initiating group, the polymerization initiation group, monomer includes a polymer and a living radical polymerization combined polymerization unit,
The electrophoretic particle, wherein the polymer has a binding degree to the surface of the mother particle of 0.01 chain / nm 2 or more and 0.1 chain / nm 2 or less.
前記モノマーは、非イオン性モノマーを含む請求項1に記載の電気泳動粒子。   The electrophoretic particle according to claim 1, wherein the monomer includes a nonionic monomer. 前記モノマーは、陽イオン性モノマーを含む請求項1または2に記載の電気泳動粒子。   The electrophoretic particle according to claim 1, wherein the monomer includes a cationic monomer. 前記モノマーは、陰イオン性モノマーを含む請求項1または2に記載の電気泳動粒子。   The electrophoretic particle according to claim 1, wherein the monomer includes an anionic monomer. 前記シランカップリング剤は、前記重合開始基として、原子移動ラジカル重合により重合するものを備える請求項1ないし4のいずれかに記載の電気泳動粒子。   The electrophoretic particle according to any one of claims 1 to 4, wherein the silane coupling agent includes a polymer that is polymerized by atom transfer radical polymerization as the polymerization initiating group. 母粒子と、前記母粒子の少なくとも一部を覆う被覆層とを含む電気泳動粒子の製造方法であって、
前記母粒子を用意し、前記母粒子の表面に、重合開始基を有するシランカップリング剤を、その結合度が0.01chain/nm以上、0.1chain/nm以下となるように結合させる第1の工程と、
前記重合開始基に、モノマーをリビングラジカル重合させて重合部を形成してポリマーを得ることにより、前記ポリマーの前記母粒子の表面への結合度を0.01chain/nm以上、0.1chain/nm以下に設定する第2の工程とを有することを特徴とする電気泳動粒子の製造方法。
A method for producing electrophoretic particles comprising mother particles and a coating layer covering at least a part of the mother particles,
Prepare the mother particles, the surface of the mother particle, a silane coupling agent having a polymerization initiating group, the degree of coupling 0.01chain / nm 2 or more, is coupled such that 0.1chain / nm 2 or less A first step;
Wherein the polymerization initiation group, by obtaining a polymer to form a polymerized unit a monomer living radical causes heavy engaged to, the degree of coupling to the surface of the mother particle of the polymer 0.01chain / nm 2 or more, 0. And a second step of setting it to 1 chain / nm 2 or less.
前記第1の工程において、前記重合開始基を有するシランカップリング剤を含む溶液を、前記重合開始基を有するシランカップリング剤の含有量が低くなるように調製し、前記母粒子の表面に前記溶液を接触させる請求項6に記載の電気泳動粒子の製造方法。   In the first step, a solution containing the silane coupling agent having the polymerization initiating group is prepared so that the content of the silane coupling agent having the polymerization initiating group is low, and the surface of the base particle is The method for producing electrophoretic particles according to claim 6, wherein the solution is contacted. 前記第1の工程において、前記重合開始基を有するシランカップリング剤と、重合開始基を有しないシランカップリング剤とを含む溶液を調製し、前記母粒子の表面に前記溶液を接触させる請求項6に記載の電気泳動粒子の製造方法。   In the first step, a solution containing a silane coupling agent having a polymerization initiating group and a silane coupling agent not having a polymerization initiating group is prepared, and the solution is brought into contact with the surface of the mother particle. 6. A method for producing an electrophoretic particle according to 6. 前記第1の工程において、重合開始基を有するシランカップリング剤を含む溶液を母粒子の表面に接触させて、前記重合開始基を有するシランカップリング剤を母粒子の表面に結合させた後、結合した前記重合開始基を有するシランカップリング剤の前記重合開始基の一部を失活させる請求項6に記載の電気泳動粒子の製造方法。   In the first step, after bringing the solution containing the silane coupling agent having a polymerization initiating group into contact with the surface of the base particle, and binding the silane coupling agent having the polymerization initiating group to the surface of the base particle, The method for producing electrophoretic particles according to claim 6, wherein a part of the polymerization initiating group of the silane coupling agent having the bonded polymerization initiating group is deactivated. 請求項1ないし4のいずれかに記載の電気泳動粒子または請求項5ないし9のいずれかに記載の電気泳動粒子の製造方法により製造された電気泳動粒子を含有することを特徴とする電気泳動分散液。   An electrophoretic dispersion comprising the electrophoretic particles according to any one of claims 1 to 4 or the electrophoretic particles produced by the method for producing electrophoretic particles according to any one of claims 5 to 9. liquid. 基板と、
請求項10に記載の電気泳動分散液を収納する複数の構造体とを含むことを特徴とする電気泳動シート。
A substrate,
An electrophoretic sheet comprising: a plurality of structures containing the electrophoretic dispersion liquid according to claim 10.
請求項11に記載の電気泳動シートを備えることを特徴とする電気泳動装置。   An electrophoretic apparatus comprising the electrophoretic sheet according to claim 11. 請求項12に記載の電気泳動装置を備えることを特徴とする電子機器。   An electronic apparatus comprising the electrophoresis apparatus according to claim 12.
JP2012015880A 2012-01-27 2012-01-27 Electrophoretic particles, method for producing electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus Active JP5927938B2 (en)

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JP2012015880A JP5927938B2 (en) 2012-01-27 2012-01-27 Electrophoretic particles, method for producing electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus

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JP2012015880A JP5927938B2 (en) 2012-01-27 2012-01-27 Electrophoretic particles, method for producing electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus

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JP2013156381A JP2013156381A (en) 2013-08-15
JP2013156381A5 true JP2013156381A5 (en) 2015-03-12
JP5927938B2 JP5927938B2 (en) 2016-06-01

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JP6303577B2 (en) 2014-02-18 2018-04-04 セイコーエプソン株式会社 Method for producing electrophoretic particles, electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic apparatus and electronic apparatus
JP6264100B2 (en) * 2014-03-05 2018-01-24 セイコーエプソン株式会社 Electrophoretic particles, dispersion, electrophoretic display device and electronic device
JP2016090897A (en) 2014-11-07 2016-05-23 セイコーエプソン株式会社 Production method of electrophoretic particle, electrophoretic particle, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic equipment
TWI551615B (en) * 2014-12-31 2016-10-01 奇美實業股份有限公司 Conjugated diene-vinyl aromatic hydrocarbon copolymer
JP2016170222A (en) 2015-03-11 2016-09-23 セイコーエプソン株式会社 Electrophoretic particle, production method of electrophoretic particle, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus
JP6463651B2 (en) 2015-03-27 2019-02-06 イー インク コーポレイション Electrophoretic particles, method for producing electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus
JP6629551B2 (en) 2015-09-18 2020-01-15 イー インク コーポレイション Electrophoretic particles, method for producing electrophoretic particles, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic equipment

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EP1393122B1 (en) * 2001-05-15 2018-03-28 E Ink Corporation Electrophoretic particles
JP4708741B2 (en) * 2004-06-09 2011-06-22 キヤノン株式会社 Electrophoretic particles and method for producing the same
JP4534998B2 (en) * 2006-02-21 2010-09-01 セイコーエプソン株式会社 Method for producing charged particle, charged particle, electrophoretic dispersion, electrophoretic sheet, electrophoretic apparatus and electronic apparatus

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