JP2013132273A - Water-in-oil emulsified composition - Google Patents

Water-in-oil emulsified composition Download PDF

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JP2013132273A
JP2013132273A JP2011286333A JP2011286333A JP2013132273A JP 2013132273 A JP2013132273 A JP 2013132273A JP 2011286333 A JP2011286333 A JP 2011286333A JP 2011286333 A JP2011286333 A JP 2011286333A JP 2013132273 A JP2013132273 A JP 2013132273A
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oil
fatty acid
mass
water
fat
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Hidekazu Takahashi
秀和 高橋
Takaaki Tadokoro
敬章 田所
Katsuyuki Kosake
克之 小酒
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Kao Corp
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Kao Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a water-in-oil emulsified composition having a small amount of SFC, having foaming properties satisfactory as butter cream in spite of using oil and fat having a small ratio of a trans fatty acid in the constituent fatty acids, having stable shape retention, and suitable for the raw material of butter cream excellent in both of meltability in the mouth and flavor.SOLUTION: The water-in-oil emulsified composition contains the following components (a) and (b) in its oil phase: (a) oil and fat having 5-20% of SFC at 15°C and 15-30% of SFC at 5°C, and having ≤5.0 mass% of the trans fatty acid in its constituent fatty acids; (b) a polyglycerin fatty acid ester having ≤40 mass% of ≥22C fatty acid, 30-90 mass% of 14-20C saturated fatty acid and 10-70 mass% of ≤12C fatty acid in the whole of the constituent fatty acid, and having HLB of ≤4.0.

Description

本発明は、バタークリーム用として好適な油中水型乳化組成物に関する。   The present invention relates to a water-in-oil emulsion composition suitable for butter cream.

バタークリームとして、マーガリン、バター等の可塑性を有する油中水型乳化組成物と、糖類、水、風味素材等とを混合し、これをホイップして得られる含水系のバタークリームが知られている。含水系のバタークリームは、油中水型の乳化性状であることから、生クリームのような水中油型のクリームに比べて微生物が繁殖しにくく、保型性にも優れ、ベーカリー製品のフィリングやサンドをはじめとする調理用素材として広く用いられている。一方で含水系のバタークリームは、水中油型のクリームに比べて油っぽく、口溶けに劣る傾向があることから、食味に関するさらなる改善も求められている。   As a butter cream, a water-containing butter cream obtained by mixing a water-in-oil emulsion composition having plasticity such as margarine and butter with saccharides, water, and a flavor material and whipping the mixture is known. . The water-containing butter cream has a water-in-oil emulsifying property, so it is less prone to microorganisms to propagate than oil-in-water creams such as fresh cream. Widely used as a cooking material including sand. On the other hand, since the water-containing butter cream is more oily than the oil-in-water cream and has a tendency to be inferior in mouth melting, further improvement in taste is also demanded.

バタークリームに用いる油中水型乳化組成物には、広い温度範囲において可塑性を維持するためにほどよい硬さが必要とされる一方、起泡性及びクリーミー性も要求される。これを実現するため、一般的には、油相中に、天然の動植物油脂に加えて部分的水素添加油脂(部分硬化油脂)を配合する。しかし、部分硬化油脂には、通常、その構成脂肪酸中にトランス脂肪酸が10〜50質量%程度含まれる。トランス脂肪酸は、血液中のLDLコレステロールや中性脂肪の増加の原因となることが指摘されており、生活習慣病の発症に繋がることが懸念される。したがって、構成脂肪酸中のトランス脂肪酸含量をより抑えたバタークリーム用の油中水型乳化組成物の開発が望まれている。   The water-in-oil emulsion composition used for butter cream requires moderate hardness in order to maintain plasticity over a wide temperature range, and also requires foamability and creaminess. In order to achieve this, in general, a partially hydrogenated fat (partially hardened fat) is blended in the oil phase in addition to natural animal and vegetable fats. However, partially fatty oils and fats usually contain about 10 to 50% by mass of trans fatty acids in the constituent fatty acids. It has been pointed out that trans fatty acids cause an increase in LDL cholesterol and neutral fat in the blood, and there is concern that it may lead to the development of lifestyle-related diseases. Therefore, the development of a water-in-oil emulsion composition for butter cream that further suppresses the content of trans fatty acid in the constituent fatty acid is desired.

トランス脂肪酸を含む部分硬化油脂を油相に用いたバタークリーム用乳化組成物に代替する油脂組成物としては、パーム系油脂を用いた油脂組成物(特許文献1)、エステル交換油脂(特許文献2)、可塑性油脂に特定の油脂を添加した油脂組成物(特許文献3及び4)が開示されている。   As an oil and fat composition that replaces the emulsion composition for butter cream using partially hardened fat and oil containing trans fatty acid in the oil phase, an oil and fat composition using palm-based oil and fat (Patent Document 1), and transesterified oil and fat (Patent Document 2) ), And an oil / fat composition (Patent Documents 3 and 4) obtained by adding a specific oil / fat to a plastic oil / fat.

しかし、特許文献1に記載されている油脂組成物を油相とした場合では、十分な可塑性がなく、特定の乳化剤を使用しなければホイップ性が得られない。更に、製造したバタークリームの口溶け感が劣るといった問題があった。
特許文献2に記載されているエステル交換油脂の使用では、油脂の可塑性と製造されるバタークリームの口溶けの良さを両立させることが難しく、開示される組成では可塑性が十分ではないとの問題があった。
特許文献3では、特定の添加油脂を製造し、これをマーガリン、ショートニングとして使用される汎用の可塑性油脂組成物に添加することで、ホイップ性、可塑性のある油脂組成物を製造することができる。この場合、特定の添加油脂を硬さの異なる可塑性油脂に添加することにより、1種の添加用油脂から様々な硬さのバタークリーム用油脂組成物を製造できるメリットがある。しかし、この組成物では、トランス脂肪酸を含む部分硬化油脂を用いた組成物と比較し、ホイップ性が劣るといった問題があった。また、特許文献4では、極度硬化油脂をエステル交換した油脂を添加油脂とし、可塑性油脂との混合により油脂組成物を得ているが、極度硬化油脂に由来する固体脂含量(油脂結晶量と同義、以下、SFCという。)の上昇から口溶けが劣るといった問題があった。
その他にも高HLBのグリセリン脂肪酸エステルを含有する方法(特許文献5)、パーム油を40%以上に限定し、特定のポリグリセリン脂肪酸エステルを含有する方法(特許文献6)、炭素数14〜22の脂肪酸からなるジグリセリン脂肪酸エステルとHLBが7〜16でラウリン酸を主成分とするポリグリセリン脂肪酸エステルを含有する方法(特許文献7)など乳化剤による改良が記載されているが、乳化状態の安定化により口溶けが低下するなどの問題もある。
However, when the oil and fat composition described in Patent Document 1 is used as an oil phase, there is no sufficient plasticity, and whipability cannot be obtained unless a specific emulsifier is used. Furthermore, there was a problem that the butter cream produced had a poor feeling of melting in the mouth.
The use of transesterified oils and fats described in Patent Document 2 makes it difficult to achieve both the plasticity of fats and oils and the good meltability of the butter cream produced, and the disclosed composition has a problem that the plasticity is not sufficient. It was.
In patent document 3, specific fats and oils can be manufactured, and this can be added to a general-purpose plastic fat and oil composition used as margarine and shortening, whereby a whip and plastic oil and fat composition can be manufactured. In this case, there is a merit that fat and oil compositions for butter cream having various hardnesses can be produced from one kind of fat and oil for addition by adding specific fats and oils to plastic fats and oils having different hardnesses. However, this composition has a problem that the whipping property is inferior to a composition using a partially hardened fat and oil containing a trans fatty acid. Moreover, in patent document 4, although the fats and oils which transesterified extremely hardened fats and oils were made into the addition fats and oils and fats and oils composition were obtained by mixing with plastic fats and oils, solid fat content derived from extremely hardened fats and oils (synonymous with fat crystal amount) , Hereinafter referred to as SFC)), there was a problem that the melting of the mouth was inferior.
In addition, a method (Patent Document 5) containing a high HLB glycerin fatty acid ester, a method of limiting palm oil to 40% or more and containing a specific polyglycerin fatty acid ester (Patent Document 6), and a carbon number of 14 to 22 Although the improvement by an emulsifier is described, such as the method (patent document 7) containing the diglycerol fatty acid ester which consists of the fatty acid of this, and the polyglyceryl fatty acid ester which HLB is 7-16 and which has lauric acid as a main component, stability of an emulsification state is described. There is also a problem that melting of the mouth decreases due to the conversion.

特開平8−47373号公報JP-A-8-47373 特開平9−165595号公報JP-A-9-165595 特開2005−60614号公報Japanese Patent Laid-Open No. 2005-60614 特開2009−90号公報JP 2009-90 A 特開平6−209706号公報JP-A-6-209706 特許第3397455号公報Japanese Patent No. 3397455 特開2006−273925号公報JP 2006-273925 A

以上のように、バタークリーム用乳化組成物には良好なホイップ性、バタークリームを製造した際の良好な口溶けが求められている。しかしながら、トランス脂肪酸を含まずに、これら全ての物性において、優れた性能を示すバタークリーム用乳化組成物は未だ提供されていない。   As described above, an emulsion composition for butter cream is required to have good whipping properties and good meltability when producing butter cream. However, an emulsified composition for butter cream that does not contain a trans fatty acid and exhibits excellent performance in all these physical properties has not yet been provided.

本発明は、SFCが少なく、かつ構成脂肪酸に占めるトランス脂肪酸の割合が少ない油脂を用いながらも、バタークリーム用として十分な起泡性を有する油中水型乳化組成物であって、安定した保型性を有し、口溶け及び風味のいずれにも優れるバタークリームの原料として好適な油中水型乳化組成物を提供することを目的とする。   The present invention is a water-in-oil emulsion composition having a sufficient foaming property for butter cream while using an oil and fat having a low SFC and a small proportion of trans fatty acids in the constituent fatty acids, and is a stable holding agent. An object of the present invention is to provide a water-in-oil emulsified composition suitable as a raw material for butter cream that has moldability and is excellent in both mouth melting and flavor.

本発明者等は上記課題に鑑み鋭意検討を行った結果、油中水型乳化組成物の油相にSFCの少なく、かつ構成脂肪酸に占めるトランス脂肪酸の割合が少ない油脂を用いた場合であっても、特定のポリグリセリン脂肪酸エステルを共存させることにより、これをバタークリーム用途に用いた場合に十分に起泡することを見い出した。また、この油中水型乳化組成物を用いてなるバタークリームは、型崩れしにくい一方で口溶けにも優れ、しかも良好な風味を有していた。本発明はこれらの知見に基づいて完成させたものである。   As a result of intensive studies in view of the above problems, the present inventors have found that the oil phase of the water-in-oil emulsion composition uses oils and fats with a low SFC and a small proportion of trans fatty acids in the constituent fatty acids. In addition, it has been found that when a specific polyglycerin fatty acid ester is allowed to coexist, it is sufficiently foamed when used for butter cream. Moreover, the butter cream using this water-in-oil emulsified composition was not easily lost in shape but also excellent in melting in the mouth, and had a good flavor. The present invention has been completed based on these findings.

本発明は、油相中に下記(a)成分及び(b)成分を含有する油中水型乳化組成物に関する:
(a)15℃におけるSFCが5〜20%、5℃におけるSFCが15〜30%であり、かつ構成脂肪酸中のトランス脂肪酸の割合が5.0質量%以下である油脂、及び
(b)全構成脂肪酸中、炭素数22以上の脂肪酸の割合が40質量%以下、炭素数14〜20の飽和脂肪酸の割合が30〜90質量%、炭素数12以下の脂肪酸の割合が10〜70質量%であり、HLBが4.0以下であるポリグリセリン脂肪酸エステル。
The present invention relates to a water-in-oil emulsion composition containing the following components (a) and (b) in an oil phase:
(A) SFC at 15 ° C. is 5 to 20%, SFC at 5 ° C. is 15 to 30%, and the proportion of trans fatty acid in the constituent fatty acid is 5.0% by mass or less, and (b) all In the constituent fatty acids, the proportion of fatty acids having 22 or more carbon atoms is 40% by mass or less, the proportion of saturated fatty acids having 14 to 20 carbon atoms is 30 to 90% by mass, and the proportion of fatty acids having 12 or less carbon atoms is 10 to 70% by mass. A polyglycerol fatty acid ester having an HLB of 4.0 or less.

本発明の油中水型乳化組成物は、油相にSFCの少ない柔らかな油脂を用いているため、口溶けに優れると同時に良好な風味を有し、しかも、起泡性及び保型性のいずれも良好なバタークリームを製造することができる。
また、本発明の油中水型乳化組成物では、使用する油脂の構成脂肪酸に占めるトランス脂肪酸の割合がより低い油脂を用いながらも、バタークリーム用として優れた性質を示す。
The water-in-oil emulsified composition of the present invention uses soft fats and oils with little SFC in the oil phase, so that it has excellent mouth melting and a good flavor, and it has both foamability and shape retention. Even good butter cream can be produced.
In addition, the water-in-oil emulsion composition of the present invention exhibits excellent properties for butter cream while using fats and oils with a lower proportion of trans fatty acids in the constituent fatty acids of the fats and oils used.

本発明の油中水系乳化組成物(以下、単に、本発明の乳化組成物という。)について以下に詳細に説明する。   The water-in-oil emulsion composition of the present invention (hereinafter simply referred to as the emulsion composition of the present invention) will be described in detail below.

本発明の乳化組成物は、油相中に、特定の油脂((a)成分)と、特定のポリグリセリン脂肪酸エステル((b)成分)とを含有する。
本発明に用いる上記(a)成分の油脂は、口溶けと保型性の観点より15℃におけるSFCが5〜20%であるが、15℃におけるSFCが10〜17%であることが好ましい。また、上記(a)成分の油脂は、5℃におけるSFCが15〜30%であるが、5℃におけるSFCが20〜28%であることが好ましい。上記SFCは、油脂中の固体油脂含量、すなわち、結晶量を表す指標であり、日本油化学協会制定の基準油脂分析試験法の2.2.9固体脂含量(NMR法)に記載の方法に従い測定した値である。
The emulsified composition of the present invention contains a specific fat ((a) component) and a specific polyglycerin fatty acid ester ((b) component) in the oil phase.
The fats and oils of the component (a) used in the present invention have an SFC of 5 to 20% at 15 ° C. from the viewpoint of mouth melting and shape retention, but preferably an SFC at 15 ° C. of 10 to 17%. Moreover, although the fats and oils of the said (a) component are 15-30% of SFC in 5 degreeC, it is preferable that SFC in 5 degreeC is 20-28%. The SFC is an index representing the solid fat content in the fat, that is, the amount of crystals. According to the method described in 2.2.9 solid fat content (NMR method) of the standard fat analysis method established by the Japan Oil Chemical Association. It is a measured value.

また、本発明に用いる上記(a)成分の油脂は、その構成脂肪酸に占めるトランス脂肪酸の割合が5.0質量%以下である。さらに、当該トランス脂肪酸の割合は0.0〜4.5質量%であることが好ましく、0.0〜4.0質量%であることがより好ましい。
油脂を構成する脂肪酸組成は、日本油化学会編「基準油脂分析試験法」中の「脂肪酸メチルエステルの01調製法(2.4.1.−1996)」に従って脂肪酸メチルエステルを調製し、得られたサンプルを、American Oil Chemists. Society Official Method Ce 1f−96(GLC法)に付すことで測定することができる。
従来、バタークリーム用に好適な所望の性状の乳化組成物を得るには、構成脂肪酸にトランス脂肪酸を多く含む部分硬化油脂をある程度用いる必要があった。しかし、本発明の乳化組成物では、部分硬化油脂をより少量で用いても、又は用いなくても、バタークリーム用として好適な性状の乳化組成物を得ることができる。
なお、本明細書において「バタークリーム」とは、原料油脂にバターを用いて製造されるものの他、マーガリンのようなバター以外の植物性油脂や動物性油脂を原料として製造されるものをも含む概念である。
Moreover, the fat of the said (a) component used for this invention is 5.0 mass% or less in the ratio of the trans fatty acid to the constituent fatty acid. Furthermore, it is preferable that the ratio of the said trans fatty acid is 0.0-4.5 mass%, and it is more preferable that it is 0.0-4.0 mass%.
The fatty acid composition constituting the fats and oils was obtained by preparing fatty acid methyl esters according to “01 Preparation Method of Fatty Acid Methyl Esters (2.4.1.-1996)” in “Standard Fat and Fat Analysis Test Method” edited by Japan Oil Chemists' Society. Samples were obtained from American Oil Chemists. It can be measured by attaching to Society Official Method Ce 1f-96 (GLC method).
Conventionally, in order to obtain an emulsified composition having a desired property suitable for butter cream, it has been necessary to use partially hardened fats and oils containing a large amount of trans fatty acids as constituent fatty acids. However, the emulsified composition of the present invention can provide an emulsified composition having suitable properties for butter cream even when a partially cured oil or fat is used in a smaller amount or not.
In addition, in this specification, "butter cream" includes not only those produced using butter as raw material fats and oils, but also those produced using vegetable oils and animal fats other than butter such as margarine as raw materials. It is a concept.

上記(a)成分として用いうる油脂は、上記の性状を示す限り特に制限はなく、1種類の油脂であっても良いし、2種以上の油脂からなる混合油脂であってもよい。上記(a)成分として用いうる油脂として、例えば、大豆油、ナタネ油、米油、コーン油、綿実油、ゴマ油、サフラワー油、ひまわり油、オリーブ油、マカデミアナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、エゴマ油、カラシ油、米糠油、小麦麦芽油、ひまわり油等もしくはこれらの混合油脂からなる低融点の油脂と、パーム油、ヤシ油又はパーム核油との混合油脂を用いることができる。また、前記各油脂の硬化油やそのエステル交換油、分別油を混合してもよい。さらに、本発明に用いる油脂には、ラード、乳脂、牛脂、鶏脂、魚油等又はこれらの硬化油、分別油等が含まれていてもよい。また、上記(a)成分には、精製又は部分精製されたモノアシルグリセロール(モノグリセリド)、ジアシルグリセロール(ジグリセリド)又はトリアシルグリセロール(トリグリセリド)が含まれていてもよい。   The fats and oils that can be used as the component (a) are not particularly limited as long as they exhibit the above properties, and may be one kind of fat or oil, or may be a mixed fat or oil composed of two or more kinds of fats and oils. Examples of the fats and oils that can be used as the component (a) include soybean oil, rapeseed oil, rice oil, corn oil, cottonseed oil, sesame oil, safflower oil, sunflower oil, olive oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, and walnut oil. Oils of low melting point consisting of coconut oil, tea seed oil, sesame oil, mustard oil, rice bran oil, wheat germ oil, sunflower oil, etc., or mixed oils thereof, and palm oil, coconut oil or palm kernel oil Can be used. Moreover, you may mix the hardened oil of each said fats and oils, its transesterification oil, and fractionated oil. Furthermore, the fats and oils used in the present invention may contain lard, milk fat, beef tallow, chicken fat, fish oil or the like, or hardened oil, fractionated oil, or the like thereof. The component (a) may contain purified or partially purified monoacylglycerol (monoglyceride), diacylglycerol (diglyceride), or triacylglycerol (triglyceride).

本発明の乳化組成物の油相中において、(a)成分である油脂の含有量は、保型性、口溶け、風味の点から、80.0質量%以上であることが好ましく、85.0〜99.9質量%であることがより好ましく、90.0〜99.8質量%であることがさらに好ましく、95.0〜99.7質量%であることがさらに好ましい。   In the oil phase of the emulsified composition of the present invention, the content of the fat (a) as component (a) is preferably 80.0% by mass or more from the viewpoint of shape retention, melting in the mouth, and flavor, and 85.0 More preferably, it is -99.9 mass%, It is further more preferable that it is 90.0-99.8 mass%, It is further more preferable that it is 95.0-99.7 mass%.

本発明に用いる上記(b)成分のポリグリセリン脂肪酸エステルは、グリセリン重合体と脂肪酸とがエステル結合した化合物である。
当該ポリグリセリン脂肪酸エステルは、経時変化抑制の観点よりその構成脂肪酸中、炭素数22以上の脂肪酸(飽和脂肪酸と不飽和脂肪酸の合計を意味する。以下同様。)の割合が40質量%以下であり、0〜20質量%であることが好ましく、0〜10質量%であることがより好ましい。当該炭素数22以上の脂肪酸は、好ましくは炭素数22〜24の脂肪酸である。また、上記構成脂肪酸中、炭素数14〜20の飽和脂肪酸の割合は30〜90質量%であり、35〜90質量%であることが好ましく、40〜83質量%であることがより好ましく、60〜80質量%であることが更に好ましい。当該炭素数14〜20の飽和脂肪酸は、好ましくは炭素数14〜18の飽和脂肪酸である。さらに、上記構成脂肪酸中、炭素数12以下の脂肪酸の割合は10〜70質量%であり、20〜65質量%であることが好ましく、18〜40質量%であることがさらに好ましい。当該炭素数12以下の脂肪酸は、好ましくは炭素数8〜12の脂肪酸である。構成脂肪酸組成が上記範囲のポリグリセリン脂肪酸エステルを用いることで、本発明の乳化組成物の性状を安定なバタークリーム用乳化物とすることができる。
本発明に用いるポリグリセリン脂肪酸エステルの構成脂肪酸中、炭素数22以上の脂肪酸、炭素数14〜20の飽和脂肪酸、及び炭素数12以下の脂肪酸の総量は実質的に100質量%であることが好ましい。
ポリグリセリン脂肪酸エステルを構成する脂肪酸組成は、日本油化学会編「基準油脂分析試験法」中の「脂肪酸メチルエステルの01調製法(2.4.1.−1996)」に従って脂肪酸メチルエステルを調製し、得られたサンプルを、American Oil Chemists. Society Official Method Ce 1f−96(GLC法)に付すことで測定することができる。
The polyglycerin fatty acid ester of the component (b) used in the present invention is a compound in which a glycerin polymer and a fatty acid are ester-bonded.
In the polyglycerin fatty acid ester, the proportion of fatty acids having 22 or more carbon atoms (meaning the sum of saturated fatty acids and unsaturated fatty acids, the same applies hereinafter) in the constituent fatty acids is 40% by mass or less from the viewpoint of suppressing change over time. 0 to 20% by mass is preferable, and 0 to 10% by mass is more preferable. The fatty acid having 22 or more carbon atoms is preferably a fatty acid having 22 to 24 carbon atoms. Moreover, the ratio of C14-C20 saturated fatty acid is 30-90 mass% in the said structural fatty acid, It is preferable that it is 35-90 mass%, It is more preferable that it is 40-83 mass%, 60 More preferably, it is -80 mass%. The C 14-20 saturated fatty acid is preferably a C 14-18 saturated fatty acid. Furthermore, in the constituent fatty acids, the proportion of fatty acids having 12 or less carbon atoms is 10 to 70% by mass, preferably 20 to 65% by mass, and more preferably 18 to 40% by mass. The fatty acid having 12 or less carbon atoms is preferably a fatty acid having 8 to 12 carbon atoms. By using a polyglycerin fatty acid ester having a constituent fatty acid composition in the above range, the properties of the emulsion composition of the present invention can be made into a stable emulsion for butter cream.
It is preferable that the total amount of fatty acids having 22 or more carbon atoms, saturated fatty acids having 14 to 20 carbon atoms, and fatty acids having 12 or less carbon atoms is substantially 100% by mass in the constituent fatty acids of the polyglycerol fatty acid ester used in the present invention. .
The fatty acid composition of the polyglycerin fatty acid ester was prepared according to “01 Preparation Method of Fatty Acid Methyl Ester (2.4.1.-1996)” in “Standard Oil Analysis Test Method” edited by Japan Oil Chemists' Society. The obtained sample was then obtained from American Oil Chemists. It can be measured by attaching to Society Official Method Ce 1f-96 (GLC method).

さらに、本発明に用いる(b)成分のポリグリセリン脂肪酸エステルは、親疎水性バランスであるHLBが4.0以下であるが、乳化及び油脂結晶の安定性向上の点からHLBが1.5〜3.5であることが好ましい。本発明において、HLBは下記の数式で表されるGriffin法(W.C.Griffin,J.Soc.Cosmetic.Chemists.,1,311(1949))により計算した値である。

HLB=20×(親水基部分の分子量)/(ポリグリセリン脂肪酸エステルの分子量)
Furthermore, the polyglycerin fatty acid ester of the component (b) used in the present invention has an HLB of 4.0 or less, which is a hydrophilic / hydrophobic balance, but the HLB is 1.5 to 3 from the viewpoint of emulsification and stability improvement of the oil crystal. .5 is preferable. In the present invention, HLB is a value calculated by the Griffin method (WCGriffin, J. Soc. Cosmetic. Chemists., 1, 311 (1949)) represented by the following mathematical formula.

HLB = 20 × (molecular weight of hydrophilic group part) / (molecular weight of polyglycerol fatty acid ester)

本発明に用いる(b)成分のポリグリセリン脂肪酸エステルを構成するグリセリン重合体は、そのグリセリン単位の数に特に制限はないが、上記のHLBとするために、グリセリン重合度(平均重合度)を2〜15とすることが好ましく、4〜10とすることがより好ましい。   The glycerin polymer constituting the polyglycerin fatty acid ester of component (b) used in the present invention is not particularly limited in the number of glycerin units, but in order to obtain the above HLB, the glycerin polymerization degree (average polymerization degree) is 2 to 15 is preferable, and 4 to 10 is more preferable.

本発明における(b)成分の性状は、本発明の乳化組成物の油相中に存在する全ポリグリセリン脂肪酸エステルを均質に混合した場合における性状を表す。
本発明の乳化組成物の油相中において、(b)成分であるポリグリセリン脂肪酸エステルの含有量は、油脂結晶の安定化及び風味の点から、0.1〜5.0質量%であることが好ましく、0.1〜1.5質量%であることがより好ましく、0.1〜1.0質量%であることがより好ましい。
本発明に用いるポリグリセリン脂肪酸エステルは通常の方法で合成することができる。また、SYグリスターTHL−17、THL−15(商品名、いずれも阪本薬品工業株式会社)や、サンソフトQMP−1(商品名、太陽化学株式会社)などの市販品を用いてもよい。
The property of (b) component in this invention represents the property in the case of mixing all the polyglycerol fatty acid ester which exists in the oil phase of the emulsion composition of this invention homogeneously.
In the oil phase of the emulsified composition of the present invention, the content of the polyglycerin fatty acid ester as the component (b) is 0.1 to 5.0% by mass from the viewpoint of stabilization of the fat crystal and flavor. Is preferable, it is more preferable that it is 0.1-1.5 mass%, and it is more preferable that it is 0.1-1.0 mass%.
The polyglycerol fatty acid ester used in the present invention can be synthesized by an ordinary method. Commercially available products such as SY Grister THL-17 and THL-15 (trade names, both of which are Sakamoto Pharmaceutical Co., Ltd.) and Sunsoft QMP-1 (trade name, Taiyo Kagaku Co., Ltd.) may be used.

本発明の乳化組成物の油相は、上記(a)成分及び(b)成分のみから構成されていてもよい。また、油相中において上記(a)成分及び(b)成分の合計が100質量%に満たなくてもよいが、その場合には、乳化剤、風味成分、香料、着色料等の、通常、バタークリーム用の乳化組成物に含まれうる他の成分が残部を構成する。当該乳化剤としては、例えば、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン有機酸脂肪酸エステル、レシチン等が挙げられる。なお、上記他の成分には、油脂及びポリグリセリン脂肪酸エステルは含まれない。   The oil phase of the emulsified composition of the present invention may be composed of only the component (a) and the component (b). Further, the sum of the components (a) and (b) in the oil phase may not be less than 100% by mass. In that case, however, the emulsifier, the flavor component, the fragrance, the colorant, etc. Other ingredients that can be included in the emulsified composition for cream constitute the balance. Examples of the emulsifier include sucrose fatty acid ester, sorbitan fatty acid ester, glycerin organic acid fatty acid ester, and lecithin. The other components do not include fats and oils and polyglycerin fatty acid esters.

本発明の乳化組成物における水相は、水又は水を基質とする水溶液から構成される。本発明の乳化組成物の水相に用いうる水としては、水道水、精製水、イオン交換水、ミネラルウォーター等が挙げられる。本発明の乳化組成物における水相は、風味成分、乳タンパク、デンプン、増粘多糖類、ゼラチン、無機塩類等が含まれてもよい。   The aqueous phase in the emulsified composition of the present invention is composed of water or an aqueous solution containing water as a substrate. Examples of water that can be used in the aqueous phase of the emulsified composition of the present invention include tap water, purified water, ion-exchanged water, and mineral water. The aqueous phase in the emulsified composition of the present invention may contain a flavor component, milk protein, starch, thickening polysaccharide, gelatin, inorganic salts and the like.

本発明の乳化組成物は常法により調製することができる。例えば、ほどよい可塑性が得られるマーガリン様の乳化組成物を得る場合には、上述の本発明の乳化組成物の油相と同じ成分組成の油脂組成物を50〜80℃程度の温度で加熱攪拌し、これに50〜80℃程度に加熱した上記の水又は水を基質とする水溶液を除々に添加しながらホモミキサーで攪拌乳化後、急冷捏和処理し、必要により熟成(テンパリング)させることで得ることができる。本発明の乳化組成物において、上記油脂組成物に由来する油相と上記の水又は水を基質とする水溶液に由来する水相の質量比(油相/水相)は、保型性、耐菌性の観点より、100/40〜100/1であることが好ましく、100/30〜100/2であることがより好ましく、100/25〜100/3であることがさらに好ましく、100/20〜100/5であることがさらに好ましく、100/15〜100/10であることがさらに好ましい。   The emulsified composition of the present invention can be prepared by a conventional method. For example, when obtaining a margarine-like emulsified composition capable of obtaining moderate plasticity, the oil and fat composition having the same component composition as the oil phase of the above-described emulsified composition of the present invention is heated and stirred at a temperature of about 50 to 80 ° C. In addition, the above water heated to about 50 to 80 ° C. or an aqueous solution containing water as a substrate is gradually added and stirred and emulsified with a homomixer, followed by quenching and kneading and aging (tempering) if necessary. Can be obtained. In the emulsified composition of the present invention, the mass ratio (oil phase / water phase) of the oil phase derived from the oil and fat composition and the water phase derived from the above water or an aqueous solution containing water as a substrate is determined as the shape retention and resistance. From the viewpoint of fungi, it is preferably 100/40 to 100/1, more preferably 100/30 to 100/2, still more preferably 100/25 to 100/3, and 100/20. More preferably, it is-100/5, and it is further more preferable that it is 100/15-100/10.

乳化組成物の劣化を抑えるために、本発明の乳化組成物には、抗酸化剤が含まれてもよい。抗酸化剤としては、アスコルビン酸エステル、トコフェロール、茶、ローズマリー等のハーブ、桃の茶や根塊から抽出した天然抗酸化成分等が挙げられる。これらの成分は、その水溶性により、適宜に油相中又は水相中に含有させることができる。   In order to suppress deterioration of the emulsion composition, the emulsion composition of the present invention may contain an antioxidant. Examples of the antioxidant include herbs such as ascorbic acid ester, tocopherol, tea and rosemary, natural antioxidant components extracted from peach tea and root mass, and the like. These components can be appropriately contained in the oil phase or the water phase depending on their water solubility.

本発明の乳化組成物は、バタークリームの原料として好適に用いられる。本発明の乳化組成物と、糖類と、必要により、水、無機塩類、乳製品(粉乳、練乳、牛乳等)、カカオ類(チョコレート、ココアパウダー等)、卵黄及び/又は卵白(鶏卵、ダチョウ卵、アヒル卵等)、呈味成分、果肉ジャム類、果汁類、チーズ類、ナッツ類(ピーナッツペースト等)等とを混合し、常法により撹拌して起泡させることで、本発明のバタークリームを得ることができる。   The emulsified composition of the present invention is suitably used as a raw material for butter cream. The emulsified composition of the present invention, saccharides, and water, inorganic salts, dairy products (milk powder, condensed milk, milk, etc.), cacao (chocolate, cocoa powder, etc.), egg yolk and / or egg white (chicken eggs, ostrich eggs, if necessary) , Duck eggs, etc.), flavoring ingredients, pulp jams, fruit juices, cheeses, nuts (peanut paste, etc.), etc. Can be obtained.

本発明のバタークリームは、本発明の乳化組成物を用いて製造される。風味の観点から、本発明の乳化組成物の油相100質量部に対して、上記糖類を10〜200質量部含有することが好ましく、20〜160質量部含有することがより好ましい。上記糖類に特に制限はなく、例えば、グルコース、マルトース、フルクトース、シュークロース、ラクトース、トレハロース、マルトトリオース、マルトテトラオース、ソルビトール、キシリトール、エリスリトール、マルチトール等の単糖類、二糖類、三糖類、四糖類、五糖類、六糖類や澱粉加水分解物、又はこれらを還元した糖アルコール、水飴、シロップ等が挙げられる。また、上記糖類の全部又は一部は、アセスルファムカリウム、スクラロース、アスパルテーム等の甘味料であってもよい。本発明において、「糖類」は、糖類及び甘味料を包含する概念として用いる。   The butter cream of the present invention is produced using the emulsion composition of the present invention. From a flavor viewpoint, it is preferable to contain 10-200 mass parts of the said saccharide with respect to 100 mass parts of oil phases of the emulsion composition of this invention, and it is more preferable to contain 20-160 mass parts. The saccharide is not particularly limited, and examples thereof include monosaccharides such as glucose, maltose, fructose, sucrose, lactose, trehalose, maltotriose, maltotetraose, sorbitol, xylitol, erythritol, maltitol, disaccharides, trisaccharides, Examples include tetrasaccharides, pentasaccharides, hexasaccharides and starch hydrolysates, or sugar alcohols, starch syrups, and syrups obtained by reducing these. In addition, all or part of the saccharide may be a sweetener such as acesulfame potassium, sucralose, aspartame. In the present invention, “saccharide” is used as a concept including saccharide and sweetener.

本発明のバタークリーム中の上記乳製品の含有量は、風味のバランスの観点から、本発明の乳化組成物の油相100質量部に対して0〜100質量部であることが好ましく、0〜50質量部であることがより好ましい。
また、本発明のバタークリーム中のカカオ類の含有量は、本発明の乳化組成物の油相100質量部に対して0〜100質量部であることが好ましく、0〜50質量部であることがより好ましい。
The content of the dairy product in the butter cream of the present invention is preferably 0 to 100 parts by mass with respect to 100 parts by mass of the oil phase of the emulsified composition of the present invention, from the viewpoint of balance of flavor. More preferably, it is 50 mass parts.
Moreover, it is preferable that it is 0-100 mass parts with respect to 100 mass parts of oil phases of the emulsion composition of this invention, and content of cacao in the butter cream of this invention is 0-50 mass parts. Is more preferable.

本発明のバタークリームは、例えば、ケーキ、パン、ビスケット、クッキー等の種々のベーカリー製品のナッペ、フィリング等、通常のバタークリームの用途に用いることができる。   The butter cream of the present invention can be used for normal butter cream applications such as nappe and filling of various bakery products such as cakes, breads, biscuits and cookies.

以下、本発明を実施例に基づき詳細に説明するが、本発明はこれらに限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited to these.

[分析方法]
構成脂肪酸組成:
日本油化学会編「基準油脂分析試験法」中の「脂肪酸メチルエステルの01調製法(2.4.1.−1996)」に従って脂肪酸メチルエステルを調製し、得られたサンプルを、American Oil Chemists. Society Official Method Ce 1f−96(GLC法)により測定した。
[Analysis method]
Composition fatty acid composition:
The fatty acid methyl ester was prepared according to “01 Preparation Method of Fatty Acid Methyl Ester (2.4.1.-1996)” in “Standard Analysis Method for Fats and Oils” edited by the Japan Oil Chemists' Society, and the obtained sample was obtained from American Oil Chemists. . It was measured by Society Official Method Ce 1f-96 (GLC method).

固体脂含量(SFC):
日本油化学協会制定の基準油脂分析試験法の2.2.9固体脂含量(NMR法)に記載の方法に従い測定した。
Solid fat content (SFC):
It was measured according to the method described in 2.2.9 solid fat content (NMR method) of the standard oil analysis test method established by the Japan Oil Chemical Association.

[調製例1] 油脂A〜Dの調製
菜種油(昭和産業株式会社製)、菜種硬化油(ヨウ素価=80、花王株式会社製)パーム油(花王株式会社製)、パーム分別油(ヨウ素価=63、日清オイリオグループ株式会社製)、魚油硬化油(ヨウ素価=83、花王株式会社製)、及び、パーム油とヤシ油とのエステル交換油(花王株式会社製)を用意し、これらの油脂を混合し、下記表1に記載の構成脂肪酸組成(単位:全構成脂肪酸量を100質量%としたときの質量%)の油脂A〜Dを調製した。各油脂のSFC(%)も表1に示す。
[Preparation Example 1] Preparation of fats and oils A to D Rapeseed oil (manufactured by Showa Sangyo Co., Ltd.), rapeseed hardened oil (iodine number = 80, manufactured by Kao Corporation) palm oil (manufactured by Kao Corporation), palm fractionated oil (iodine number = 63, Nissin Oilio Group Co., Ltd.), fish oil hardened oil (iodine value = 83, Kao Co., Ltd.), and transesterified oil of palm oil and coconut oil (Kao Co., Ltd.) are prepared. Fats and oils were mixed to prepare fats and oils A to D having the constituent fatty acid composition described in Table 1 below (unit: mass% when the total constituent fatty acid amount was 100% by mass). Table 1 also shows the SFC (%) of each fat.

Figure 2013132273
Figure 2013132273

[調製例2] ポリグリセリン脂肪酸エステルE〜Pの調製
下記表2に示すグリセリン平均重合度、構成脂肪酸組成(単位:全構成脂肪酸量を100質量%としたときの質量%)、及びHLBを示すポリグリセリン脂肪酸エステルを常法により得た。
[Preparation Example 2] Preparation of polyglycerin fatty acid esters E to P The glycerin average polymerization degree, the constituent fatty acid composition (unit: mass% when the total constituent fatty acid amount is 100% by mass) shown in Table 2 below, and HLB are shown. Polyglycerin fatty acid ester was obtained by a conventional method.

Figure 2013132273
Figure 2013132273

なお、上記表1及び2において、例えば、「C8:0」は、炭素数8の脂肪酸であって不飽和結合を有さない飽和脂肪酸を表し、「C18:1」は炭素数18で2重結合を1つ有する不飽和脂肪酸を表し、「C18:3」は炭素数18で2重結合を3つ有する不飽和脂肪酸を表す。   In Tables 1 and 2, for example, “C8: 0” represents a saturated fatty acid having 8 carbon atoms and no unsaturated bond, and “C18: 1” is 18 carbon atoms and doubled. An unsaturated fatty acid having one bond is represented, and “C18: 3” represents an unsaturated fatty acid having 18 carbon atoms and three double bonds.

[調製例3] 油中水系乳化組成物の調製
上記調製例1で得られた各油脂と、上記調製例2で得られた各ポリグリセリン脂肪酸エステルと、モノアシルグリセロール(商品名:エキセルO−95R、花王株式会社製)と、ショ糖脂肪酸エステル(商品名:リョートーシュガーエステルS−1170、三菱化学フーズ株式会社製)と、フレーバー(ミルクフレーバー、協和香料興産株式会社製)とを、下記表3に示す割合(単位:油相と水相の合計を100質量%としたときの質量%)で混合し、60℃に加熱して攪拌溶解することで油相成分を調製した。
上記油相成分に、下記表3に示す割合(単位:油相と水相の合計を100質量%としたときの質量%)で、60℃に加熱した水道水を徐々に添加しながらホモミキサー(特殊機化工業社製)で攪拌乳化を行い(7000rpm、10分間)、その後、急冷捏和処理して油中水型乳化組成物(本発明品1〜7、比較品1〜10)を得た。
[Preparation Example 3] Preparation of water-in-oil emulsion composition Each fat obtained in Preparation Example 1, each polyglycerin fatty acid ester obtained in Preparation Example 2, and monoacylglycerol (trade name: Excel O- 95R, manufactured by Kao Corporation, sucrose fatty acid ester (trade name: Ryoto Sugar Ester S-1170, manufactured by Mitsubishi Chemical Foods Co., Ltd.), and flavor (milk flavor, manufactured by Kyowa Fragrance Co., Ltd.) The oil phase component was prepared by mixing at a ratio shown in Table 3 (unit: mass% when the total of the oil phase and the aqueous phase was 100 mass%), heating to 60 ° C., and dissolving with stirring.
Homomixer while gradually adding tap water heated to 60 ° C. to the oil phase component at the ratio shown in Table 3 below (unit: mass% when the sum of the oil phase and water phase is 100 mass%) Stir emulsification (made by Tokushu Kika Kogyo Co., Ltd.) (7000 rpm, 10 minutes), then quench quenching treatment to give a water-in-oil emulsion composition (present products 1-7, comparative products 1-10). Obtained.

[調製例4] バタークリームの調製
上記調製例3で得られた油中水型乳化組成物100質量部、シロップ(Brix70)120質量部、水30質量部、加糖練乳10質量部、洋酒10質量部を混合し、ホバートミキサー(N−50、ホバートジャパン社製)にて比重0.70までホイップすることでバタークリームを調製した。
[Preparation Example 4] Preparation of butter cream 100 parts by mass of the water-in-oil emulsion composition obtained in Preparation Example 3, 120 parts by mass of syrup (Brix70), 30 parts by mass of water, 10 parts by mass of sweetened condensed milk, 10 parts by mass of sake The butter cream was prepared by whipping to a specific gravity of 0.70 with a Hobart mixer (N-50, manufactured by Hobart Japan).

[試験例] 油中水型乳化組成物及びバタークリームの評価
上記調製例3で得られた各油中水型乳化組成物について、起泡性を下記評価基準に従って評価した。また、上記調製例4で得られた各バタークリームについて、外観(保型性)、口溶け、風味及び食感を下記評価基準に従って評価した。評価結果を下記表3に示す。
[Test Example] Evaluation of water-in-oil emulsion composition and butter cream The water-in-oil emulsion composition obtained in Preparation Example 3 was evaluated for foamability according to the following evaluation criteria. Moreover, about each butter cream obtained by the said preparation example 4, the external appearance (shape retention), mouth melt, flavor, and food texture were evaluated in accordance with the following evaluation criteria. The evaluation results are shown in Table 3 below.

−起泡性の評価基準−
調製例3で得られた油中水型乳化組成物を20℃にて48時間テンパリングした後、15℃にて1日及び、21日静置した。それぞれの日数静置後の油中水型乳化組成物300gを20℃に調温し、ホバートミキサーを用いて、ホイッパーを使用して2速にて40分間撹拌し、起泡させた。これを内容量110cmのプラスチック容器を用いて重量を計測して比容積(cm/g)を求めた。1日後に対する21日後の比容積の変化を「経時変化」として表3に示した。
-Evaluation criteria for foamability-
The water-in-oil emulsion composition obtained in Preparation Example 3 was tempered at 20 ° C. for 48 hours, and then allowed to stand at 15 ° C. for 1 day and 21 days. 300 g of the water-in-oil emulsified composition after standing for each number of days was adjusted to 20 ° C. and stirred for 40 minutes at 2nd speed using a whipper using a Hobart mixer to cause foaming. This was determined by measuring the weight by using the plastic container having an inner volume of 110 cm 3 and the specific volume (cm 3 / g). The change in specific volume after 21 days with respect to 1 day later is shown in Table 3 as “Change over time”.

−外観、口溶け、風味及び食感の評価基準−
外観、口溶け、風味及び食感は、5名の専門パネルの各々が、後述の点数基準に従って点数を付け、その合計点に基づき評価した。
-Evaluation criteria for appearance, melting in mouth, flavor and texture-
Appearance, melting in the mouth, flavor and texture were evaluated by each of the five specialized panels according to the score criteria described below and based on the total score.

外観、口溶け、風味及び食感に関する上記の評価基準の基とした点数基準を以下に示す。   The score criteria based on the above evaluation criteria for appearance, melting in mouth, flavor and texture are shown below.

<外観>
上記調製例4で得られたバタークリームを20℃に調温後、絞り袋に入れ菊型口金でシャーレに花型に絞り、蓋をし、20℃で3日間保存した。保存後の外観を目視観察し、下記基準に従い点数を付けた。外観は、保型性を示す尺度である。
2点:型崩れが観察されない。
1点:若干の型崩れが認められ、表面に荒れやひび割れも観察される。
0点:型崩れと共に油染み(オイルオフ)も生じている。
<Appearance>
The butter cream obtained in Preparation Example 4 was adjusted to 20 ° C., placed in a squeeze bag, squeezed into a petri dish with a chrysanthemum die, covered, and stored at 20 ° C. for 3 days. The appearance after storage was visually observed and scored according to the following criteria. Appearance is a measure of shape retention.
2 points: No deformation is observed.
1 point: Some shape loss is observed, and surface roughness and cracks are also observed.
0 point: An oil stain (oil-off) occurs along with the shape loss.

<口溶け>
上記調製例4で得られたバタークリームを20℃で1日間保存後に食し、下記基準に従い点数を付けた。
2点:溶け残り感がない。
1点:若干溶け残り感がある。
0点:溶け残り感がある。
<Melting mouth>
The butter cream obtained in Preparation Example 4 was eaten after storage at 20 ° C. for 1 day, and scored according to the following criteria.
2 points: There is no feeling of unmelted residue.
1 point: Some undissolved feeling.
0 points: There is a feeling of unmelted.

<風味>
上記調製例4で得られたバタークリームを20℃で1日間保存後に食し、下記基準に従い点数を付けた。
2点:風味の出が早い。
1点:風味の出がやや遅い。
0点:風味の出が遅い。
<Flavor>
The butter cream obtained in Preparation Example 4 was eaten after storage at 20 ° C. for 1 day, and scored according to the following criteria.
2 points: The flavor comes out quickly.
1 point: The appearance of flavor is slightly slow.
0 point: Slow flavor.

<食感>
上記調製例4で得られたバタークリームを20℃で1日間保存後に食し、下記基準に従い点数を付けた。
2点:バタークリームとして丁度良い硬さである。
1点:バタークリームとして食感がやや硬い、又はやや軟らかい。
0点:バタークリームとして食感が硬すぎる、又は軟らかすぎる。
<Food texture>
The butter cream obtained in Preparation Example 4 was eaten after storage at 20 ° C. for 1 day, and scored according to the following criteria.
2 points: Hardness just as butter cream.
1 point: The texture is slightly hard or slightly soft as a butter cream.
0 point: The texture of the butter cream is too hard or too soft.

Figure 2013132273
Figure 2013132273

表3の結果から、比較品1〜10のうち、比較品1及び3〜10では、SFCが本発明で規定する範囲内の油脂を用いているが、いずれも起泡性に劣るものであった。油脂のSFCを上げると、起泡性は改善するが、バタークリームの口溶けと風味に劣る結果となった(比較品2)。
これに対し、SFCが本発明で規定する範囲内の油脂を用いた場合であっても、本発明で規定するポリグリセリン脂肪酸エステルを併用した乳化組成物は、起泡性に優れ、これを用いたバタークリームは、外観(保型性)、口溶け、風味及び食感のいずれも良好であった(本発明品1〜7)。
From the results in Table 3, among the comparative products 1 to 10, the comparative products 1 and 3 to 10 use fats and oils within the range specified by the SFC in the present invention, but all of them are inferior in foaming properties. It was. Increasing the SFC of the fats and oils improved the foaming properties, but resulted in poor butter cream melting and flavor (Comparative Product 2).
On the other hand, even when the fats and oils within the range specified by the SFC in the present invention are used, the emulsion composition using the polyglycerin fatty acid ester specified in the present invention is excellent in foaming properties and uses this. The butter cream had good appearance (shape retention), melting in the mouth, flavor and texture (present products 1 to 7).

Claims (4)

油相中に下記(a)成分及び(b)成分を含有する油中水型乳化組成物:
(a)15℃におけるSFCが5〜20%、5℃におけるSFCが15〜30%であり、かつ構成脂肪酸中のトランス脂肪酸の割合が5.0質量%以下である油脂、及び
(b)全構成脂肪酸中、炭素数22以上の脂肪酸の割合が40質量%以下、炭素数14〜20の飽和脂肪酸の割合が30〜90質量%、炭素数12以下の脂肪酸の割合が10〜70質量%であり、HLBが4.0以下であるポリグリセリン脂肪酸エステル。
Water-in-oil emulsion composition containing the following component (a) and component (b) in the oil phase:
(A) SFC at 15 ° C. is 5 to 20%, SFC at 5 ° C. is 15 to 30%, and the proportion of trans fatty acid in the constituent fatty acid is 5.0% by mass or less, and (b) all In the constituent fatty acids, the proportion of fatty acids having 22 or more carbon atoms is 40% by mass or less, the proportion of saturated fatty acids having 14 to 20 carbon atoms is 30 to 90% by mass, and the proportion of fatty acids having 12 or less carbon atoms is 10 to 70% by mass. A polyglycerol fatty acid ester having an HLB of 4.0 or less.
油相中における(b)成分の含有量が0.1〜5.0質量%である、請求項1に記載の油中水型乳化組成物。   The water-in-oil emulsion composition according to claim 1, wherein the content of the component (b) in the oil phase is 0.1 to 5.0% by mass. 油相/水相(質量比)が100/40〜100/1である、請求項1又は2に記載の油中水型乳化組成物。   The water-in-oil emulsion composition according to claim 1 or 2, wherein the oil phase / water phase (mass ratio) is 100/40 to 100/1. 請求項1〜3のいずれか1項に記載の油中水型乳化組成物を用いてなるバタークリーム。   The butter cream which uses the water-in-oil type emulsion composition of any one of Claims 1-3.
JP2011286333A 2011-12-27 2011-12-27 Water-in-oil emulsified composition Pending JP2013132273A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018113961A (en) * 2017-01-16 2018-07-26 月島食品工業株式会社 Water-in-oil-type emulsified oil and fat composition for filling
JP6966610B1 (en) * 2020-09-11 2021-11-17 キユーピー株式会社 Plastic fat and oil compositions, O / W / O emulsified compositions and foods

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018113961A (en) * 2017-01-16 2018-07-26 月島食品工業株式会社 Water-in-oil-type emulsified oil and fat composition for filling
JP7129779B2 (en) 2017-01-16 2022-09-02 月島食品工業株式会社 Water-in-oil emulsified fat composition for filling
JP6966610B1 (en) * 2020-09-11 2021-11-17 キユーピー株式会社 Plastic fat and oil compositions, O / W / O emulsified compositions and foods
JP2022047330A (en) * 2020-09-11 2022-03-24 キユーピー株式会社 Plastic oil-and-fat composition, o/w/o emulsion composition and food

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