JP2013102757A - Powdered oil and fat for snack and daily dish, and snack and daily dish - Google Patents

Powdered oil and fat for snack and daily dish, and snack and daily dish Download PDF

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JP2013102757A
JP2013102757A JP2011251201A JP2011251201A JP2013102757A JP 2013102757 A JP2013102757 A JP 2013102757A JP 2011251201 A JP2011251201 A JP 2011251201A JP 2011251201 A JP2011251201 A JP 2011251201A JP 2013102757 A JP2013102757 A JP 2013102757A
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powdered
oils
oil
acid ester
snack
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JP5886007B2 (en
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Yuki Kono
友希 河野
Shinji Tsuda
信治 津田
Takashi Ito
隆史 伊藤
Hidetetsu Nishimura
英哲 西村
Eriko Yamada
絵梨子 山田
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Miyoshi Yushi KK
Miyoshi Oil and Fat Co Ltd
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Miyoshi Yushi KK
Miyoshi Oil and Fat Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a powdered oil and fat for snack and daily dish, capable of providing the snack and daily dish exhibiting good mold-releasability after dough has been baked, having excellent baked color and texture even when an egg is not contained in the dough, having excellent texture even when being re-heated after frozen storage, exhibiting excellent anti-aging effects, and hardly causing a decrease in the texture even after a long-term frozen storage by being added to the dough of the snack daily dish such as Takoyaki (grilled dumplings with bits of octopus) and Okonomiyaki (vegetable pancake).SOLUTION: The powdered oil and fat for the snack daily dish is obtained by drying and powdering an oil-in-water type emulsion containing a powderizing base material containing an edible oil and fat, a maltooligosaccharide having a polymerization degree of 2-4, and lactose, and lecithin and a fatty acid ester of glycerol as emulsifiers by drying, and contains 0.1-2 wt.% of the lecithin and 0.5-6.5 wt.% of the fatty acid ester of the glycerol.

Description

本発明は、たこ焼き、お好み焼き等のスナック惣菜類用粉末油脂及びスナック惣菜類に関する。   The present invention relates to powdered fats and oils for snacks such as takoyaki and okonomiyaki and snacks.

たこ焼きや、お好み焼きは、小麦粉に水、卵、具材、調味料等を添加混合して調製した生地を焼成して得られるものであり、たこ焼きでは外側がぱりっとし、中身がとろっとした食感を有するものが好まれ、お好み焼きではふんわりと柔らかく、口溶けが良く歯切れの良い食感のものが好まれており、優れた食感のたこ焼きやお好み焼きを得るための方法が、提案されている(特許文献1、特許文献2等)。また、たこ焼き、お好み焼きは、近年、冷蔵流通、冷凍流通が広く行われるようになり、店舗や家庭において解凍、再加熱して提供されることが多くなっており、焼き上げ直後の食感が優れるのみならず、解凍、再加熱した後の食感も優れていることが要求される。しかしながら冷蔵・冷凍保存されたたこ焼きやお好み焼きを解凍、再加熱すると、硬くなって食感が低下するため、電子レンジ等で再加熱した際の食感を改良する方法も提案されている(特許文献3、特許文献4等)。   Takoyaki and okonomiyaki are obtained by baking dough prepared by adding water, eggs, ingredients, seasonings, etc. to wheat flour. In takoyaki, the outside is crisp and the contents are crisp. Okonomiyaki is preferred because it has a soft texture, and it is soft and soft and has a mouthfeel and a crisp texture. A method for obtaining takoyaki and okonomiyaki with an excellent texture has been proposed ( Patent Document 1, Patent Document 2, etc.). In recent years, takoyaki and okonomiyaki have been widely used in refrigerated and frozen distribution, and are often provided by thawing and reheating at stores and homes, and the texture immediately after baking is excellent. In addition, the food texture after thawing and reheating is required to be excellent. However, thawing and re-heating refrigerated / frozen takoyaki and okonomiyaki becomes harder and lowers in texture, so a method for improving the texture when reheated in a microwave oven or the like has also been proposed (patent document) 3, Patent Document 4).

特開2002−125578号公報JP 2002-125578 A 特開2000−116311号公報Japanese Patent Laid-Open No. 2000-116311 特開2000−316504号公報JP 2000-316504 A 特開平7−298839号公報JP-A-7-29888

特許文献1にはお好み焼き類の生地に用いる澱粉のα化度を調整することで、滑らかで口溶けが良く、軽い食感が持続するお好み焼き類を製造する方法が、特許文献2記載には、水、エタノール、糖類、乳化剤を含む油脂組成物を、たこ焼きや、お好み焼き用バッターに練り込んで使用することで、しなやかな食感を有し、しっとりとして歯切れの良い食感のお好み焼きや、たこ焼きを得る方法が記載されている。また特許文献3には油脂、乳化剤、糖類等を含む水中油型乳化液を噴霧乾燥して得られ、水に乳化分散した時の粒度分布が5〜120μmとなる改質剤を、お好み焼き等の小麦加工食品に添加することで、食品を冷凍または冷蔵した後の食感低下を改善する方法が、特許文献4には起泡性粉末油脂を、たこ焼き等の電子レンジで加熱すると硬くなり易い食品に添加することで、電子レンジ加熱した時の食感低下を防ぐ方法が記載されている。   Patent Document 1 discloses a method for producing a okonomiyaki that has a smooth, good melt and a light texture by adjusting the degree of alpha conversion of starch used in the okonomiyaki dough. By using an oil and fat composition containing ethanol, saccharides, and emulsifiers in a takoyaki or okonomiyaki batter, the okonomiyaki and takoyaki have a supple texture and a crisp texture. A method is described. Patent Document 3 discloses a modifier that is obtained by spray-drying an oil-in-water emulsion containing fats and oils, emulsifiers, sugars, etc., and has a particle size distribution of 5 to 120 μm when emulsified and dispersed in water, such as okonomiyaki. A method for improving the decrease in texture after freezing or refrigeration of food by adding it to processed wheat food is disclosed in Patent Document 4 as a food that tends to become hard when foamed powdered oil is heated in a microwave oven such as takoyaki. A method for preventing a decrease in texture when heated in a microwave oven is described.

しかしながら、特許文献1、特許文献2記載の方法では、焼成直後のたこ焼きやお好み焼きの食感をある程度向上することはできるものの、必ずしも十分とは言えないとともに、たこ焼きやお好み焼きを冷蔵、冷凍保存した後、電子レンジ等で解凍、再加熱した際の食感低下を改善することはできなかった。また特許文献3記載の方法で用いる改質剤は水に乳化分散したときの油脂粒子の粒度分布が大きいため、油脂粒子が合一し易く、電子レンジ加熱による食感低下は防止できても、製造直後の食感は悪くなり易い。更に起泡性粉末油脂を添加する特許文献4記載の方法は、生地に混合する際に空気を抱き込み易く、生地を焼成した際に抱き込んだ空気が膨張して製品に穴があき、商品価値低下を来し易いという問題があった。
本発明は上記従来技術の問題を解決すべくなされたもので、焼成直後の食感が優れているとともに、電子レンジ加熱しても食感が良好なたこ焼きやお好み焼き等のスナック惣菜類を提供することができるスナック惣菜類用粉末油脂及び、この粉末油脂を用いたスナック惣菜類を提供することを目的とする。
However, the methods described in Patent Document 1 and Patent Document 2 can improve the texture of takoyaki and okonomiyaki immediately after baking, but are not necessarily sufficient, and after refrigerated and frozen and preserved takoyaki and okonomiyaki. It was not possible to improve the decrease in texture when thawed and reheated with a microwave oven or the like. Moreover, since the modifier used in the method described in Patent Document 3 has a large particle size distribution of the fat particles when emulsified and dispersed in water, the fat particles are easy to coalesce, and even if the texture reduction due to microwave heating can be prevented, The texture immediately after production tends to deteriorate. Further, the method described in Patent Document 4 in which foaming powdery fats and oils are added is easy to embed air when mixed into the dough, and the air embraced when the dough is baked expands and has a hole in the product. There was a problem that it was easy to cause a decline in value.
The present invention has been made to solve the above-mentioned problems of the prior art, and provides snacks such as takoyaki and okonomiyaki that have excellent texture immediately after baking and have a good texture even when heated in a microwave oven. An object of the present invention is to provide powdered fats and oils for snacks that can be used, and snacks and vegetables using the powdered fats and oils.

即ち本発明は、
(1)食用油脂、粉末化基材、乳化剤としてレシチン及びグリセリン脂肪酸エステルを含む水中油型乳化物を乾燥粉末化した粉末油脂であって、粉末油脂中にレシチン0.1〜2重量%、グリセリン脂肪酸エステル0.5〜6.5重量%が含有されていることを特徴とするスナック惣菜類用粉末油脂、
(2)グリセリン脂肪酸エステルが、グリセリンモノ脂肪酸エステルとグリセリン有機酸脂肪酸エステルとの混合物である上記(1)のスナック惣菜類用粉末油脂、
(3)乳化剤として、レシチン、グリセリン脂肪酸エステルとともに、更にポリグリセリン縮合リシノレイン酸エステルを0.1〜10重量%含有する上記(1)又は(2)のスナック惣菜類用粉末油脂、
(4)粉末化基材が、重合度2〜4のマルトオリゴ糖及びラクトースを含有する上記(1)〜(3)のいずれかのスナック惣菜類用粉末油脂、
(5)水に分散させたときの油脂のメディアン径が0.3〜2μmとなる上記(1)〜(4)のいずれかのスナック惣菜類用粉末油脂、
(6)上記(1)〜(5)のいずれかのスナック惣菜類用粉末油脂を含有する生地を焼成して得たスナック惣菜類、
を要旨とする。
That is, the present invention
(1) Edible oil / fat, powdered base material, powdered oil / fat obtained by dry powderization of oil-in-water emulsion containing lecithin and glycerin fatty acid ester as emulsifier, 0.1 to 2% by weight of lecithin in powdered oil / fat, glycerin Powdered fats and oils for snacks, characterized by containing 0.5 to 6.5% by weight of a fatty acid ester,
(2) Powdered fats and oils for snacks and vegetables of the above (1), wherein the glycerin fatty acid ester is a mixture of a glycerin monofatty acid ester and a glycerin organic acid fatty acid ester,
(3) The powdered fats and oils for snacks of above-mentioned (1) or (2) containing 0.1 to 10% by weight of polyglycerin condensed ricinoleic acid ester together with lecithin and glycerin fatty acid ester as an emulsifier,
(4) Powdered fats and oils for snacks and vegetables according to any one of (1) to (3) above, wherein the powdered substrate contains malto-oligosaccharide having a polymerization degree of 2 to 4 and lactose,
(5) Powdered fats and oils for snacks and vegetables according to any one of (1) to (4) above, wherein the median diameter of the fats and oils when dispersed in water is 0.3 to 2 μm,
(6) Snack side dishes obtained by baking a dough containing the powdered fats and oils for snack side dishes in any of (1) to (5) above,
Is the gist.

本発明のスナック惣菜類用粉末油脂を用いた生地を焼成して得られるたこ焼き、お好み焼き等のスナック惣菜類は、焼成時の離型性が良く、生地に卵を含まない場合でも、卵を用いた場合のような焼き色、食感を有し、焼成直後の食感に優れるのみならず、冷凍保存後に電子レンジ等で解凍、再加熱した場合でも優れた食感を有し、また優れた老化防止効果を有するため冷蔵保存した場合でも長時間食感低下を来す虞がない。またスナック惣菜類としてたこ焼きを製造する場合、外側がパリッとして中身がとろりとした優れた食感のたこ焼きを得ることができ、またたこ焼き形状に丸めやすいとともに、焼成時間が短くてすみ、ボリュームの大きいたこ焼きを得ることができる等の効果を奏する。   Snack side dishes such as takoyaki and okonomiyaki obtained by baking dough using the powdered fats and oils for snacks of the present invention have good releasability at the time of baking and use eggs even when dough does not contain eggs. It has a baked color and texture as if it were, not only excellent in texture immediately after baking, but also has an excellent texture even when thawed and reheated in a microwave oven etc. after frozen storage Since it has an effect of preventing aging, there is no possibility of causing a decrease in texture for a long time even when refrigerated. In addition, when manufacturing takoyaki as a snack side dish, it is possible to obtain a takoyaki with an excellent texture that is crunchy on the outside, easy to round into a takoyaki shape, short baking time, and large volume There are effects such as being able to obtain takoyaki.

本発明粉末油脂における食用油脂としては、液体、固体の動植物油脂、硬化した動植物油脂、動植物油脂のエステル交換油、分別した液体油又は固体脂等、食用に適するものであれば全て使用可能である。具体的には、ナタネ油、コーン油、大豆油、綿実油、サフラワー油、パーム油、ヤシ油、米糠油、ごま油、カカオ脂、オリーブ油、パーム核油等の植物性油脂、魚油、豚脂、牛脂、鶏脂、乳脂等の動物性油脂及び、これらの油脂の硬化油又はエステル交換油、或いはこれらの油脂を分別して得られる液体油、固体脂等が挙げられ、これらより選ばれた1種又は2種以上を用いることができる。   As edible fats and oils in the powdered fats and oils of the present invention, all liquids, solid animal and vegetable fats and oils, hardened animal and vegetable fats and oils, transesterified oils and fats of animal and vegetable fats, fractionated liquid oils and solid fats, and the like can be used. . Specifically, vegetable oils such as rapeseed oil, corn oil, soybean oil, cottonseed oil, safflower oil, palm oil, coconut oil, rice bran oil, sesame oil, cocoa butter, olive oil, palm kernel oil, fish oil, pork fat, Animal fats and oils such as beef tallow, chicken fat, milk fat and the like, and hardened oils or transesterified oils of these fats and oils, liquid oils obtained by separating these fats and oils, solid fats, etc. are mentioned, and one kind selected from these Or 2 or more types can be used.

本発明の粉末油脂における粉末化基材としては、乳蛋白、大豆蛋白、小麦蛋白、全脂粉乳、脱脂粉乳、小麦粉、デンプン、ゼラチン、ガム質、デキストリン、マルトオリゴ糖、ラクトースや、これら以外のグルコース、フルクトース、ガラクトース等の単糖類、ショ糖、水飴、トレハロース等の糖類を用いることができる。マルトオリゴ糖としては重合度2〜4のものが用いられ、重合度2〜4のマルトオリゴ糖は、グルコース同士がα−1,4グリコシド結合で2〜4重合した少糖類で、マルトース、マルトトリオース、マルトテトラオースが挙げられる。乳蛋白としては酸カゼイン、レンネットカゼイン、カゼインナトリウム、ホエー蛋白等が、デンプンとしては、オクテニルコハク酸デンプン、馬鈴薯デンプン、コーンスターチ、小麦デンプン、タピオカデンプン等が挙げられる。ガム質としてはキサンタンガム、アラビアガム、トラガントガム、ジェランガム、ローカストビーンガム、タマリンドシードガム、カラギーナン、寒天、LMペクチン、HMペクチン等が、デキストリンとしては、サイクロデキストリン、分岐サイクロデキストリン、マルトデキストリン等が挙げられる。粉末化基材は、重合度2〜4のマルトオリゴ糖及びラクトースを含有することが好ましく、粉末化基材中のマルトオリゴ糖とラクトースとの割合が50重量%以上あることが好ましく、より好ましくは64重量%以上、特に好ましくは68重量%以上である。上記マルトオリゴ糖とラクトースとを重量比で、マルトオリゴ糖:ラクトース=80:20〜20:80の割合で含有することが好ましいが、特にマルトオリゴ糖:ラクトース=70:30〜30:70の割合で含有することで、よりしっとりとした食感を得る事ができるなど保水効果がより発揮されるため好ましい。またマルトオリゴ糖が粉末油脂中に1重量%以上含有されることが望ましい。
マルトオリゴ糖及びラクトースとともに他の粉末化基材との混合物を粉末化基材として用いる場合、デキストリン及びカゼインナトリウムを、マルトオリゴ糖、ラクトースと併用すると、粉末油脂の油脂の染み出しや劣化が生じにくいという保存安定性、再溶解したときの分散性や乳化安定性がより高まるため好ましい。
The powdered base in the powdered fats and oils of the present invention includes milk protein, soybean protein, wheat protein, whole milk powder, skim milk powder, wheat flour, starch, gelatin, gum, dextrin, maltooligosaccharide, lactose, and other glucose Monosaccharides such as fructose and galactose, and sugars such as sucrose, starch syrup and trehalose can be used. Malto-oligosaccharides having a polymerization degree of 2 to 4 are used, and malto-oligosaccharides having a polymerization degree of 2 to 4 are oligosaccharides in which glucose is polymerized 2 to 4 by α-1,4 glycosidic bonds, and maltose and maltotriose. And maltotetraose. Examples of milk protein include acid casein, rennet casein, sodium caseinate, and whey protein. Examples of starch include octenyl succinate starch, potato starch, corn starch, wheat starch, and tapioca starch. Examples of gums include xanthan gum, gum arabic, tragacanth gum, gellan gum, locust bean gum, tamarind seed gum, carrageenan, agar, LM pectin, HM pectin, etc., and examples of dextrin include cyclodextrin, branched cyclodextrin, maltodextrin . The powdered substrate preferably contains malto-oligosaccharides and lactose having a degree of polymerization of 2 to 4, and the proportion of maltooligosaccharide and lactose in the powdered substrate is preferably 50% by weight or more, more preferably 64. % By weight or more, particularly preferably 68% by weight or more. The malto-oligosaccharide and lactose are preferably contained at a weight ratio of malto-oligosaccharide: lactose = 80: 20 to 20:80, but in particular, malto-oligosaccharide: lactose = 70: 30 to 30:70 By doing so, a moist texture can be obtained, and the water retention effect is more exhibited, which is preferable. In addition, it is desirable that malto-oligosaccharide is contained in the powdered oil / fat at 1% by weight or more.
When using a mixture of malto-oligosaccharide and lactose with another powdered substrate as a powdered substrate, if dextrin and sodium caseinate are used in combination with malto-oligosaccharide and lactose, exudation and deterioration of powdered fats and oils are difficult to occur. Storage stability, dispersibility when re-dissolved, and emulsion stability are further increased, which is preferable.

乳化剤として用いるレシチンとしては、大豆レシチン、卵黄レシチン、酵素分解レシチン等が挙げられる。またグリセリン脂肪酸エステルとしては、グリセリンモノ脂肪酸エステル、グリセリンジ脂肪酸エステル、グリセリン有機酸脂肪酸エステル等が挙げられ、これらグリセリン脂肪酸エステルは1種又は2種以上を混合して用いることができるが、グリセリンモノ脂肪酸エステルとグリセリン有機酸脂肪酸エステルを併用することが好ましい。グリセリンモノ脂肪酸エステルは、グリセリン1分子に1分子の脂肪酸がエステル化した化合物であり、グリセリンモノ脂肪酸エスエルとしては、脂肪酸が飽和であることが好ましく、さらにステアリン酸であることが好ましい。グリセリン有機酸脂肪酸エステルは、グリセリンに脂肪酸と有機酸の両方がそれぞれ1個から2個エステル結合した構造の化合物で、グリセリンモノ脂肪酸エステルと有機酸との反応、油脂と有機酸とのエステル交換、又はグリセリンと有機酸と脂肪酸との反応などにより得ることができる。有機酸として例えば、酢酸、乳酸、コハク酸、ジアセチル酒石酸、クエン酸等が挙げられる。グリセリン有機酸脂肪酸エステルの構成脂肪酸は、飽和脂肪酸、不飽和脂肪酸のいずれでも良い。グリセリン有機酸脂肪酸エステルは、有機酸や脂肪酸の種類の異なるものを混合して用いることもできる。本発明において用いるグリセリン有機酸脂肪酸エステルは、有機酸がコハク酸、ジアセチル酒石酸であるものが食感、風味等の点から好ましく、特に有機酸がジアセチル酒石酸であると口溶け感が向上し更に好ましい。グリセリン有機酸脂肪酸エステルを構成する脂肪酸は、特にステアリン酸等の飽和脂肪酸であることが好ましい。グリセリンモノ脂肪酸エステルとグリセリン有機酸脂肪酸エステルは、重量比で10:1〜1:1の割合で混合して用いることが好ましい。7:1〜3:1の割合がより好ましい。本発明のスナック惣菜類用粉末油脂は、粉末油脂中にレシチンを0.1〜2重量%、グリセリンエステルを0.5〜6.5重量%含有するが、レシチンを0.5〜1重量%、グリセリンエステル3〜6重量%が好ましい。粉末油脂中のレシチンの割合が0.1重量%未満であると粉末化する前の水中油型(O/W型)乳化物の安定性が悪くなり、2重量%を超えると、粉末化に際して水分が飛散し難く、粉末油脂の流動性が悪くなり、いずれの場合も粉末油脂の状態が悪くなる。またグリセリンエステルの割合が0.5重量%未満であるとO/W型乳化物の安定性が悪くなり、6.5重量%を超えるとたこ焼きやお好み焼きの風味が低下する。   Examples of lecithin used as an emulsifier include soybean lecithin, egg yolk lecithin, and enzymatically decomposed lecithin. Examples of the glycerin fatty acid ester include glycerin mono-fatty acid ester, glycerin di-fatty acid ester, and glycerin organic acid fatty acid ester. These glycerin fatty acid esters can be used alone or in combination of two or more. It is preferable to use a fatty acid ester and a glycerin organic acid fatty acid ester in combination. The glycerin monofatty acid ester is a compound in which one molecule of fatty acid is esterified to one molecule of glycerin. As the glycerin monofatty acid ester, the fatty acid is preferably saturated, and more preferably stearic acid. Glycerin organic acid fatty acid ester is a compound having a structure in which one to two fatty acids and organic acids are ester-bonded to glycerin, respectively, reaction of glycerin monofatty acid ester and organic acid, transesterification of fat and organic acid, Or it can obtain by reaction of glycerin, an organic acid, and a fatty acid. Examples of the organic acid include acetic acid, lactic acid, succinic acid, diacetyltartaric acid, and citric acid. The constituent fatty acid of the glycerin organic acid fatty acid ester may be either a saturated fatty acid or an unsaturated fatty acid. As the glycerin organic acid fatty acid ester, different kinds of organic acids and fatty acids can be mixed and used. As the glycerin organic acid fatty acid ester used in the present invention, those in which the organic acid is succinic acid and diacetyltartaric acid are preferable from the viewpoints of texture and flavor, and in particular, the organic acid is diacetyltartaric acid, which is more preferable because of improved mouth-feel. The fatty acid constituting the glycerin organic acid fatty acid ester is particularly preferably a saturated fatty acid such as stearic acid. The glycerin mono fatty acid ester and the glycerin organic acid fatty acid ester are preferably mixed and used in a weight ratio of 10: 1 to 1: 1. A ratio of 7: 1 to 3: 1 is more preferred. The powdered fats and oils for snacks of the present invention contain 0.1 to 2% by weight of lecithin and 0.5 to 6.5% by weight of glycerin ester in the powdered fat and oil, but 0.5 to 1% by weight of lecithin. The glycerin ester is preferably 3 to 6% by weight. When the proportion of lecithin in the powdered oil is less than 0.1% by weight, the stability of the oil-in-water (O / W type) emulsion before pulverization becomes poor. It is difficult for water to scatter and the fluidity of the powdered fats and oils deteriorates. On the other hand, when the proportion of glycerin ester is less than 0.5% by weight, the stability of the O / W emulsion is deteriorated, and when it exceeds 6.5% by weight, the flavor of takoyaki or okonomiyaki is lowered.

本発明において乳化剤として、上記レシチン及びグリセリン脂肪酸エステルとともに、更にポリグリセリン縮合リシノール酸エステルを含有しているとたこ焼きやお好み焼きのソフトさが向上するとともに、たこ焼きではボリュームのあるものが得られるという効果がある。ポリグリセリン縮合リシノール酸エステルは、リシノール酸同士が縮合したエステルと、ポリグリセリンとがエステル化したものであり、ポリグリセリン縮合リシノール酸エステルを構成するポリグリセリンとしては、重合度4〜10量体が好ましい。また縮合リシノール酸としては3〜6量体がエステル結合しているものが好ましい。ポリグリセリン縮合リシノール酸エステルを併用する場合、ポリグリセリン縮合リシノール酸エステルはレシチン、グリセリン脂肪酸エステルの合計重量の0.1〜10重量%用いることが好ましく0.5〜3重量%がより好ましい。   In the present invention, as an emulsifier, when containing the above-mentioned lecithin and glycerin fatty acid ester, and further containing a polyglycerin condensed ricinoleic acid ester, takoyaki and okonomiyaki softness is improved, and takoyaki has an effect that a large volume is obtained. is there. The polyglycerin condensed ricinoleic acid ester is obtained by esterifying an ester obtained by condensing ricinoleic acid with polyglycerin, and the polyglycerin constituting the polyglycerin condensed ricinoleic acid ester has a degree of polymerization of 4 to 10 monomers. preferable. The condensed ricinoleic acid is preferably one in which a 3-6 mer is ester-bonded. When the polyglycerin condensed ricinoleic acid ester is used in combination, the polyglycerin condensed ricinoleic acid ester is preferably used in an amount of 0.1 to 10% by weight of the total weight of lecithin and glycerin fatty acid ester, and more preferably 0.5 to 3% by weight.

本発明のスナック惣菜類用粉末油脂は、水に分散させたときの油脂のメディアン径が0.3〜2μmとなるものは、粉末油脂の保存安定性が良好であり、スナック惣菜類の生地中に微細に油脂が分散するため、食感が向上し、澱粉の老化防止効果があるため好ましい。   In the case of the powdered fats and oils for snacks and vegetables of the present invention, the oils and fats having a median diameter of 0.3 to 2 μm when dispersed in water have good storage stability of the powdered oils and fats, Since the fats and oils are finely dispersed, the texture is improved and the starch has an anti-aging effect, which is preferable.

本発明の粉末油脂は、食用油脂、粉末化基材、乳化剤、乳化剤を含むO/W型乳化物を乾燥粉末化して得られる。O/W型乳化物は、まず、水相に油相を添加し、ホモミキサー等で攪拌後、ホモゲナイザー等を使用し、均質化して得ることができる。O/W型乳化物を調製する際に、乳化剤は水相、油相の両方、またはいずれか一方に含有されていれば良い。また、粉末化基材は水相に添加して用いることができる。O/W型乳化物を調製するに際し、粉末化基材は10〜60重量%配合することが好ましい。O/W型乳化物を乾燥粉末化する方法としては、一般的に知られている噴霧乾燥法、真空凍結乾燥法、真空乾燥法等用いることができる。得られた粉末油脂を水に分散させたときの油脂のメディアン径が0.3〜2μmとなる粉末油脂は、均質化時の圧力を10〜150kgf/cmに調整することにより得ることが出来る本発明の粉末油脂を得る際に、O/W型乳化物中に必要に応じて香料や酸化防止剤等を配合し、粉末油脂中に香料、酸化防止剤を含有させても良い。 The powdered fats and oils of this invention are obtained by dry-powdering edible fats and oils, a pulverization base material, an emulsifier, and the O / W type emulsion containing an emulsifier. The O / W emulsion can be obtained by first adding an oil phase to an aqueous phase, stirring with a homomixer or the like, and then homogenizing using a homogenizer or the like. When preparing the O / W type emulsion, the emulsifier may be contained in either or both of the aqueous phase and the oil phase. The powdered substrate can be used by adding to the aqueous phase. In preparing the O / W emulsion, the powdered substrate is preferably blended in an amount of 10 to 60% by weight. As a method for dry-pulverizing the O / W emulsion, generally known spray-drying methods, vacuum freeze-drying methods, vacuum-drying methods and the like can be used. The powdered fats and oils having a median diameter of 0.3 to 2 μm when the obtained powdered fats and oils are dispersed in water can be obtained by adjusting the pressure during homogenization to 10 to 150 kgf / cm 2. When obtaining the powdered fats and oils of the present invention, a fragrance, an antioxidant and the like may be blended in the O / W emulsion as necessary, and the fragrances and antioxidants may be contained in the powdered fats and oils.

本発明の粉末油脂は、たこ焼きやお好み焼き等のスナック惣菜類の生地における穀粉類100重量部に対し、1〜50重量部配合することが好ましく、5〜30重量部配合することが好ましい。穀粉類としては、小麦粉、澱粉、米粉等が用いられる。   The powdered fats and oils of the present invention are preferably blended in an amount of 1 to 50 parts by weight, preferably 5 to 30 parts by weight, based on 100 parts by weight of flour in a snack side dish such as takoyaki or okonomiyaki. As the flour, wheat flour, starch, rice flour and the like are used.

以下、実施例、比較例を挙げて本発明を更に詳細に説明する。
実施例1〜13、比較例1〜4、参考例
油脂を70℃に調温後、表1に示す乳化剤を添加し油相を調製した。水相は、水を60℃に調温し、表1に示す粉末化基材を添加し調製した。油相を70℃、水相を60℃で保持し、水相をホモミキサーで攪拌しながら油相の全量を添加し、O/W型に乳化させた後、ホモジナイザーで150kg/cmの圧力をかけて均質化し(実施例13は、30kg/cm)、均質化後、スプレードライヤーにより粉末化して粉末油脂を得た。得られた粉末油脂の状態を表1に併せて示した。
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.
Examples 1 to 13, Comparative Examples 1 to 4 and Reference Example After adjusting the temperature of oil to 70 ° C., the emulsifiers shown in Table 1 were added to prepare an oil phase. The aqueous phase was prepared by adjusting the temperature of water to 60 ° C. and adding the powdered substrate shown in Table 1. While maintaining the oil phase at 70 ° C. and the aqueous phase at 60 ° C., adding the total amount of the oil phase while stirring the aqueous phase with a homomixer and emulsifying it into an O / W type, the pressure at 150 kg / cm 2 with the homogenizer (Example 13 is 30 kg / cm 2 ), and after homogenization, it was pulverized with a spray dryer to obtain a powdered fat. The state of the obtained powdered fats and oils is shown together in Table 1.

Figure 2013102757
Figure 2013102757

※1:エマルジーMS(理研ビタミン製)
※2:ポエムW−10(理研ビタミン製)
※3:ポエムB−10(理研ビタミン製)
※4:SYグリスターCR−ED(阪本薬品工業製)
※5:レシチンM(昭和産業製)
* 1: Emergy MS (made by Riken Vitamin)
* 2: Poem W-10 (Riken Vitamin)
* 3: Poem B-10 (Riken Vitamin)
* 4: SY Grister CR-ED (manufactured by Sakamoto Pharmaceutical)
* 5: Lecithin M (made by Showa Sangyo)

※6:粉末油脂の状態
目視により状態を確認して以下の基準で評価した。
○:乾燥状態が良好で油脂の染み出しもなく、流動性も良い。
△:乾燥状態は良好だが、わずかに油脂の染み出しがあり、流動性が若干悪い。
×:乾燥が不十分であるか油脂の染み出しがあり、流動性が悪い。
* 6: State of powdered oil and fat The state was visually confirmed and evaluated according to the following criteria.
○: The dry state is good, the oil and fat does not ooze out, and the fluidity is good.
Δ: The dry state is good, but there is a slight exudation of fats and oils, and the fluidity is slightly poor.
X: Insufficient drying or exudation of fats and oils and poor fluidity.

※7:粒径(メディアン径)
粉末油脂の10重量%水溶液のメディアン径を、島津製作所製:SALD−2100湿式レーザー回折装置により測定して求めた。
* 7: Particle size (median diameter)
The median diameter of a 10% by weight aqueous solution of powdered fats and oils was determined by measurement with a Shimadzu SALD-2100 wet laser diffractometer.

表1に示す粉末油脂を用い、下記配合に基づき、まず食塩及び調味料、全卵、水をミキサーボールに入れて混合した後、これに、薄力粉、ベーキングパウダー、粉末油脂を混合したものを添加、混合して調製したたこ焼き生地を、下記の条件で焼成してたこ焼きを製造し、評価を行った。結果を表2に示した。尚、参考例は、粉末油脂を添加しないことを除いて他の成分は実施例、比較例と同様に配合した生地を用いて焼成した。   Using powdered fats and oils shown in Table 1, based on the following formulation, salt and seasoning, whole eggs, and water are first mixed in a mixer bowl, and then mixed with soft flour, baking powder, and powdered fats and oils. The takoyaki dough prepared by mixing was baked under the following conditions to produce takoyaki and evaluated. The results are shown in Table 2. In addition, the reference example baked using the dough which mix | blended other components similarly to the Example and the comparative example except not adding powder fats and oils.

たこ焼き生地配合
薄力粉 100重量部
全卵 20重量部
ベーキングパウダー 1重量部
粉末油脂 6重量部
食塩及び調味料 4重量部
水 415重量部
Takoyaki dough combination Soft flour 100 parts by weight Whole egg 20 parts by weight Baking powder 1 part by weight Powdered fat 6 parts by weight Salt and seasoning 4 parts by weight Water 415 parts by weight

たこ焼き生地の焼成条件
予め油脂を均一に塗布した焼き型に生地を流し込んで焼成し、生地がまとまったところで反転し、均一な焼き色が付くまで焼成を行った。
Firing conditions for the takoyaki dough The dough was poured into a baking mold in which oils and fats were uniformly applied in advance and baked. When the dough was gathered, it was inverted and baked until a uniform baked color was obtained.

Figure 2013102757
Figure 2013102757

※8:焼成時間
表面に均一な焼き色がつくまでの焼成時間を測定し、
◎:17分未満
○:17分以上、18分未満
△:18分以上、19分未満
×:19分以上
と評価した。
* 8: Baking time Measure the baking time until the surface has a uniform baking color.
◎: Less than 17 minutes ○: 17 minutes or more, less than 18 minutes Δ: 18 minutes or more, less than 19 minutes ×: Evaluated as 19 minutes or more.

※9:ボリューム
焼成して得たたこ焼きの幅、高さをノギスで測定し、その平均値を直径とする真球とみなして下記式より体積を算出し、30個のボリュームの平均値により、
◎:ボリュームの平均値が26〜28cm
○:ボリュームの平均値が24〜26cm未満
△:ボリュームの平均値が22〜24cm未満
×:ボリュームの平均値が22cm未満
と評価した。
(数1)
たこ焼きの体積=4πr/3(r:球の半径)
* 9: Volume Measure the width and height of the takoyaki obtained by firing with calipers, calculate the volume from the following formula, assuming that the average value is a true sphere, and calculate the average value of 30 volumes.
A: The average value of the volume is 26 to 28 cm 3
○: less than the average value of the volume 24~26cm 3 △: average volumes 22~24Cm 3 below ×: average value of volume is evaluated as less than 22 cm 3.
(Equation 1)
Takoyaki volume = 4πr 3/3 (r: radius of the sphere)

※10:離型性
たこ焼き30個分の焼き型に生地を流し込み、焼成時に反転する際の型への付着度により、
◎:30個全てが型に付着することなく容易に反転できた。
○:一部型への付着はあるが、容易に反転できた。
△:生地がややまとまりにくく、30個全てを反転するのに時間がかかる。
×:生地が型にべたつき、かなり火が通ってからでないと反転が困難。
と評価した。
* 10: Releasability Depending on the degree of adhesion to the mold when the dough is poured into a baking mold for 30 pieces of takoyaki and reversed during firing,
A: All 30 pieces could be easily reversed without adhering to the mold.
○: Although there was adhesion to some molds, it could be easily reversed.
(Triangle | delta): It is hard to unite dough somewhat and it takes time to invert all 30 pieces.
X: The dough is sticky to the mold, and it is difficult to reverse it until after a considerable amount of fire.
It was evaluated.

※11:食感
焼成直後のたこ焼きの食感と、焼成後、24時間冷凍保存し、電子レンジで解凍した後のたこ焼きの食感10名のパネラーが試食し、たこ焼きの内側(中身部分)と外側(皮部分)の食感を下記の5段階で評価し、10名のパネラーの評価の平均値を示した。
(1)内側の食感の評価
5:非常にトロトロしている。
4:トロトロしている。
3:若干トロトロしている。
2:殆どトロミがないが、生地が柔らかい。
1:全くトロミがなく、中の生地に硬さがある。
(2)外側の食感の評価
5:かなりパリパリしており、皮の存在感がある。
4:パリパリ感がある。
3:若干パリパリ感がある。
2:かなり柔らかい。
1:大変柔らかい。
* 11: Texture The texture of takoyaki immediately after baking and the texture of takoyaki after freezing for 24 hours after baked and thawed in a microwave oven. The texture of the outer side (skin part) was evaluated in the following 5 levels, and the average value of the evaluation of 10 panelists was shown.
(1) Evaluation of inner texture 5: Extremely trotting.
4: It is trotting.
3: Slightly trotting.
2: There is almost no tromi, but the dough is soft.
1: There is no trolley at all, and the inside fabric is hard.
(2) Evaluation of outer texture 5: It is quite crispy and has a skin presence.
4: There is a crisp feeling.
3: Slightly crispy.
2: Pretty soft.
1: Very soft.

※12:耐老化性
焼成直後のたこ焼き内側の食感評価値と、電子レンジで解凍した冷凍保存たこ焼きの内側の食感評価値の差により、
◎:評価値の差が0。
○:評価値の差が0超、0.5以下。
△:評価値の差が0.5超、1以下。
×:評価値の差が1超。
と評価した。
* 12: Aging resistance Due to the difference between the texture evaluation value inside the takoyaki immediately after baking and the texture evaluation value inside the frozen takoyaki thawed in the microwave oven,
A: Evaluation value difference is zero.
○: The difference in evaluation values is more than 0 and 0.5 or less.
Δ: Evaluation value difference is more than 0.5 and 1 or less.
X: The difference of evaluation value is more than 1.
It was evaluated.

全卵を無添加の下記配合のたこ焼き生地によりたこ焼きを焼成したところ、全卵を添加した生地を用いた場合と遜色ない焼き色のたこ焼きを得ることが出来た。   When takoyaki was baked with a takoyaki dough of the following composition with no addition of whole eggs, a takoyaki with a color that was inferior to the case of using the dough with the addition of whole eggs could be obtained.

全卵無添加のたこ焼き生地配合
薄力粉 100重量部
ベーキングパウダー 1重量部
粉末油脂 6重量部
食塩及び調味料 4重量部
水 415重量部
Takoyaki dough with no egg added Soft flour 100 parts by weight Baking powder 1 part by weight Powdered oil 6 parts by weight Salt and seasoning 4 parts by weight Water 415 parts by weight

表1に示す粉末油脂を用い、下記配合に基づいて、薄力粉、ベーキングパウダー、粉末油脂を混合し、これを、食塩及び調味料、全卵、水を混合したものと合わせてミキシングして得た生地を下記条件で焼成してお好み焼きを得た。   Using the powdered fats and oils shown in Table 1, based on the following formulation, mixed flour, baking powder and powdered fats and oils were mixed and mixed with a mixture of salt, seasoning, whole egg and water. The dough was baked under the following conditions to obtain okonomiyaki.

お好み焼き生地配合
薄力粉 100重量部
粉末油脂 6重量部
全卵 30重量部
ベーキングパウダー 1重量部
食塩及び調味料 4重量部
水 110重量部
Okonomiyaki dough blended flour 100 parts by weight powdered oil 6 parts by weight whole egg 30 parts by weight baking powder 1 part by weight salt and seasoning 4 parts by weight water 110 parts by weight

お好み焼き生地の焼成条件
生地250gと粗微塵にしたキャベツを合わせた後、200℃に加熱したプレート上に流し入れ、端を押さえて成型し、生地表面が沸騰して来たら裏返して表面側を焼成し、焦げ目がついたら再度裏返して2分焼成して加熱終了した。
Baking conditions for okonomiyaki dough After combining 250 g of dough and cabbage made into coarse and fine dust, pour it onto a plate heated to 200 ° C, press down on the edge, mold it, and when the dough surface boils, turn it over and bake the surface side When burnt, the plate was turned over again and baked for 2 minutes to complete the heating.

生地を焼成する際の焼成時間及び好み焼きの食感、老化性を評価した結果を表3に示した。尚、参考例は、粉末油脂を添加しないことを除いて他の成分は実施例、比較例と同様に配合した生地を用いて焼成した。   Table 3 shows the results of evaluating the baking time when baking the dough, the texture of okonomiyaki, and aging properties. In addition, the reference example baked using the dough which mix | blended other components similarly to the Example and the comparative example except not adding powder fats and oils.

Figure 2013102757
Figure 2013102757

※13:焼成時間は、内部まで火が通り、表皮に均一な焼き色がつくまでの時間を測定し、
◎:14分未満
○:14分以上、15分未満
△:15分以上、16分未満
×:16分以上
として評価した。
* 13: The baking time is the time it takes for the fire to reach the inside and the skin to become evenly colored.
◎: Less than 14 minutes ○: 14 minutes or more, less than 15 minutes Δ: 15 minutes or more, less than 16 minutes ×: Evaluation was made as 16 minutes or more.

※14:食感
焼成直後のお好み焼きの食感と、焼成後、24時間冷凍保存し、電子レンジで解凍した後のお好み焼きの食感を、10名のパネラーが試食してソフトさを下記の5段階で評価し、10名のパネラーの評価の平均値を示した。
ソフトさの評価
5:非常にソフトな食感。
4:ソフトな食感。
3:ややソフトな食感。
2:やや硬い食感。
1:硬い食感。
* 14: Texture The taste of okonomiyaki immediately after baking and the texture of okonomiyaki after freezing for 24 hours after baked and thawed in a microwave oven were sampled by 10 panelists and the softness of the following 5 The evaluation was performed in stages, and the average value of the evaluation of 10 panelists was shown.
Evaluation of softness 5: Very soft texture.
4: Soft texture.
3: Slightly soft texture.
2: A slightly hard texture.
1: Hard texture.

※15:耐老化性
焼成直後のお好み焼きの食感評価値と、電子レンジで解凍した冷凍保存お好み焼きの食感評価値の差により、
◎:評価値の差が0。
○:評価値の差が0超、0.5以下。
△:評価値の差が0.5超、1以下。
×:評価値の差が1超。
と評価した。
* 15: Aging resistance Due to the difference between the texture evaluation value of okonomiyaki immediately after baking and the texture evaluation value of okonomiyaki frozen and thawed in a microwave oven,
A: Evaluation value difference is zero.
○: The difference in evaluation values is more than 0 and 0.5 or less.
Δ: Evaluation value difference is more than 0.5 and 1 or less.
X: The difference of evaluation value is more than 1.
It was evaluated.

Claims (6)

食用油脂、粉末化基材、乳化剤としてレシチン及びグリセリン脂肪酸エステルを含む水中油型乳化物を乾燥粉末化した粉末油脂であって、粉末油脂中にレシチン0.1〜2重量%、グリセリン脂肪酸エステル0.5〜6.5重量%が含有されていることを特徴とするスナック惣菜類用粉末油脂。   An oil-in-water emulsion containing an edible oil and fat, a powdered base material, and an oil-in-water emulsion containing lecithin and glycerin fatty acid ester as an emulsifier, wherein 0.1 to 2% by weight of lecithin and glycerin fatty acid ester 0 in the powdered oil and fat Powder oil and fat for snacks and vegetables, characterized by containing 0.5 to 6.5% by weight. グリセリン脂肪酸エステルが、グリセリンモノ脂肪酸エステルとグリセリン有機酸脂肪酸エステルとの混合物である請求項1記載のスナック惣菜類用粉末油脂。   The powdered oil for snacks and vegetables according to claim 1, wherein the glycerin fatty acid ester is a mixture of glycerin mono-fatty acid ester and glycerin organic acid fatty acid ester. 乳化剤として、レシチン、グリセリン脂肪酸エステルとともに、更にポリグリセリン縮合リシノレイン酸エステルを0.1〜10重量%含有する請求項1又は2記載のスナック惣菜類用粉末油脂。   The powdered fats and oils for snacks of Claim 1 or 2 which contain 0.1-10 weight% of polyglycerin condensed ricinoleic acid ester as an emulsifier with lecithin and glycerol fatty acid ester further. 粉末化基材が、重合度2〜4のマルトオリゴ糖及びラクトースを含有する請求項1〜3のいずれかに記載のスナック惣菜類用粉末油脂。   The powdered fats and oils for snack beet according to any one of claims 1 to 3, wherein the powdered substrate contains malto-oligosaccharide having a polymerization degree of 2 to 4 and lactose. 水に分散させたときの油脂のメディアン径が0.3〜2μmとなる請求項1〜4のいずれかに記載のスナック惣菜類用粉末油脂。   The powdered fats and oils for snacks and vegetables according to any one of claims 1 to 4, wherein the median diameter of the fats and oils when dispersed in water is 0.3 to 2 µm. 請求項1〜5のいずれかのスナック惣菜類用粉末油脂を含有する生地を焼成して得たスナック惣菜類。   Snack side dishes obtained by baking the dough containing the powdered fats and oils for snack side dishes according to any one of claims 1 to 5.
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