JP2013057143A - Woven fabric base material and fiber-reinforced composite material - Google Patents

Woven fabric base material and fiber-reinforced composite material Download PDF

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JP2013057143A
JP2013057143A JP2011196328A JP2011196328A JP2013057143A JP 2013057143 A JP2013057143 A JP 2013057143A JP 2011196328 A JP2011196328 A JP 2011196328A JP 2011196328 A JP2011196328 A JP 2011196328A JP 2013057143 A JP2013057143 A JP 2013057143A
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reinforcing fiber
weft
warp
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fiber
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Fujio Hori
藤夫 堀
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Toyota Industries Corp
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PROBLEM TO BE SOLVED: To provide a woven fabric base material which is free from crimping of reinforcing fibers and excellent in shape retainability and shape formability so as to be suitable as a reinforcing fiber base material for a fiber-reinforced composite material.SOLUTION: A woven fabric base material 10 comprises: a plurality of reinforcing fiber warp yarns 11 which comprise fiber bundles and are arranged in parallel to each other; and a plurality of reinforcing fiber weft yarns 12 which comprise fiber bundles and are arranged in parallel to each other and in a direction intersecting the reinforcing fiber warp yarns 11. Auxiliary weft yarns 13, which comprise finer yarns than the reinforcing fiber weft yarns 12 and extend in the same direction as the reinforcing fiber weft yarns 12, are arranged on the side opposite to the reinforcing fiber weft yarns 12 with respect to the reinforcing fiber warp yarns 11. Auxiliary warp yarns 14a and 14b, which comprise finer yarns than the reinforcing fiber warp yarns 11, extend in the same direction as the reinforcing fiber warp yarns 11 and are each arranged between the reinforcing fiber warp yarns 11 in such a manner that turned-back portions in engagement with the reinforcing fiber weft yarns 12 are intermingled with turned-back portions in engagement with the auxiliary weft yarns 13.

Description

本発明は、織物基材及び繊維強化複合材料に関する。   The present invention relates to a textile substrate and a fiber reinforced composite material.

軽量、高強度の材料として繊維強化複合材料が使用されている。繊維強化複合材料は、強化繊維が樹脂や金属等のマトリックス中に複合化されることにより、マトリックス自体に比べて力学的特性(機械的特性)が向上するため、構造部品として好ましい。特にマトリックスとして樹脂を使用した繊維強化プラスチック(以下、FRPとも言う。)の場合はより軽量化が図れるため好ましい。   A fiber reinforced composite material is used as a lightweight, high-strength material. The fiber-reinforced composite material is preferable as a structural component because the mechanical properties (mechanical properties) are improved as compared with the matrix itself when the reinforcing fibers are compounded in a matrix of resin or metal. In particular, a fiber reinforced plastic (hereinafter, also referred to as FRP) using a resin as a matrix is preferable because the weight can be further reduced.

FRPに使用する織物基材として、平織、綾織、朱子織等で織られた織物がクロス材として使用されている。クロス材は、経糸と緯糸との交差部でクリンプ(屈曲状態)を形成しており、FRPにおいて一本の強化繊維について見た場合、強化繊維は他の強化繊維との交差部毎にクリンプが存在する状態でマトリックス中に配列された状態となる。その結果、強化繊維が本来発現すべき特性を十分に活用できず、強化繊維のクリンプによる強度、剛性の低下が指摘されている。   As a woven fabric base material used for FRP, a woven fabric woven with plain weave, twill weave, satin weave or the like is used as a cloth material. The cloth material forms a crimp (bent state) at the intersection between the warp and the weft. When viewed with respect to one reinforcing fiber in the FRP, the reinforcing fiber is crimped at each intersection with the other reinforcing fiber. It will be in the state arranged in the matrix in the state which exists. As a result, it is pointed out that the strength and rigidity of the reinforcing fiber cannot be fully utilized, and the strength and rigidity are reduced due to the crimping of the reinforcing fiber.

従来、クロス材の欠点である強化繊維のクリンプのない強化繊維基材として多軸成形材料(通称「多軸織物」)が提案されている(例えば、特許文献1参照)。特許文献1の多軸成形材料は、多数本の強化繊維糸条が並行に配列されたシートが、少なくとも2枚、該強化繊維糸条が交差するように積層されて積層体を構成し、該積層体がステッチ糸により一体化されている。即ち、多軸織物は、経糸、緯糸、斜方向糸の強化繊維が、互いに交わることが無く配列されて経糸層、緯糸層、斜方向糸層を構成し、さらに各層の強化繊維は、ステッチ糸により縫合されて一体化されている。   Conventionally, a multiaxial molding material (commonly referred to as “multiaxial woven fabric”) has been proposed as a reinforcing fiber base without crimping of reinforcing fibers, which is a drawback of cloth materials (see, for example, Patent Document 1). In the multiaxial molding material of Patent Document 1, at least two sheets in which a large number of reinforcing fiber yarns are arranged in parallel are laminated so that the reinforcing fiber yarns intersect to form a laminate, The laminate is integrated by stitch yarn. That is, in a multiaxial fabric, warp, weft, and oblique direction reinforcing fibers are arranged without crossing each other to form a warp layer, a weft layer, and an oblique direction yarn layer, and the reinforcing fibers in each layer are stitch yarns. And are integrated with each other.

また、強化繊維のクリンプのない強化繊維基材として、複合材料用布帛構造物も提案されている(特許文献2参照)。特許文献2の複合材料用布帛構造物は、図6に示すように、一方向にシート状に引き揃えた屈曲を有しない真っ直ぐな補強用繊維糸条51,52からなる2群の糸条群A,Bを有する。両糸条群A,Bはシート状の面が互いに対向し、かつ一方の糸条群Aの補強用繊維糸条51が他方の糸条群Bの補強用繊維糸条52に対して互いに交差した状態で補助繊維糸条53,54によって一体に保持されている。   Further, a fabric structure for composite materials has also been proposed as a reinforcing fiber base without crimping of reinforcing fibers (see Patent Document 2). As shown in FIG. 6, the fabric structure for a composite material of Patent Document 2 includes two groups of yarns composed of straight reinforcing fiber yarns 51 and 52 that are not bent in a sheet shape in one direction. A and B are included. The two yarn groups A and B have sheet-like surfaces facing each other, and the reinforcing fiber yarn 51 of one yarn group A intersects the reinforcing fiber yarn 52 of the other yarn group B. In this state, the auxiliary fiber yarns 53 and 54 are integrally held.

特開2007−182065公報JP 2007-182065 A 特開昭55−30974号公報Japanese Patent Laid-Open No. 55-30974

一般に、強化繊維基材は平板状のまま使用されることは少なく、所望の形状に賦形された状態で樹脂が含浸、硬化されて繊維強化複合材料が形成される。特許文献1に記載された多軸織物は、多数本の強化繊維糸条が並行に配列されたシートが複数積層されるとともにステッチ糸にて縫合されているため、強化繊維(強化繊維糸条)の動きが悪く(可撓性が悪く)クロス材と比べ賦形性に劣る。   In general, the reinforcing fiber base is rarely used in the form of a flat plate, and the resin is impregnated and cured in a state of being formed into a desired shape to form a fiber-reinforced composite material. In the multiaxial woven fabric described in Patent Document 1, a plurality of sheets in which a large number of reinforcing fiber yarns are arranged in parallel are laminated and stitched with stitch yarns, so that reinforcing fibers (reinforcing fiber yarns) The movement of the is poor (flexibility is poor) and inferior in formability compared to the cloth material.

一方、特許文献2に記載された複合材料用布帛構造物はステッチ糸を使用せず、一般の織物の経糸の役割を果たす補助繊維糸条53と、緯糸の役割を果たす補助繊維糸条54とで織物組織の形態を保持する構成のため、ステッチ糸を使用した場合に比べて賦形性は良い。しかし、特許文献2の織物組織では、緯糸を構成する補強用繊維糸条52と補助繊維糸条54とが交互に配列される構成のため、補助繊維糸条53に張力が掛かると補強用繊維糸条52間が開き、補強用繊維糸条52間に隙間ができる。これはFRPにした場合、樹脂リッチ部が線状に存在することになり強度的に不利となる。   On the other hand, the fabric structure for composite material described in Patent Document 2 does not use a stitch yarn, and an auxiliary fiber yarn 53 that functions as a warp of a general fabric, and an auxiliary fiber yarn 54 that functions as a weft. Because of the configuration that maintains the shape of the fabric structure, the formability is better than when stitched yarn is used. However, in the woven fabric of Patent Document 2, the reinforcing fiber yarns 52 and the auxiliary fiber yarns 54 constituting the weft yarn are alternately arranged. Therefore, when the auxiliary fiber yarn 53 is tensioned, the reinforcing fibers The gaps between the yarns 52 are opened, and a gap is formed between the reinforcing fiber yarns 52. In the case of FRP, the resin-rich portion exists in a linear shape, which is disadvantageous in strength.

本発明は、前記の問題に鑑みてなされたものであって、その第1の目的は、強化繊維のクリンプが無く、しかも形態保持性及び賦形性が良く繊維強化複合材料の強化繊維基材に適した織物基材を提供することにある。また、第2の目的は強化繊維のクリンプが無く、しかも形態保持性及び賦形性が良い織物基材を強化繊維基材とした繊維強化複合材料を提供することにある。   The present invention has been made in view of the above-mentioned problems, and a first object thereof is a reinforcing fiber base material of a fiber-reinforced composite material that has no crimp of reinforcing fibers and has good shape retention and formability. It is in providing the textile base material suitable for. Another object of the present invention is to provide a fiber-reinforced composite material in which a reinforcing fiber substrate is used as a woven fabric substrate that does not have reinforcing fiber crimps and has good shape retention and formability.

前記第1の目的を達成するため、請求項1に記載の発明は、繊維束からなり互いに平行に配列された複数の強化繊維用経糸と、繊維束からなり互いに平行にかつ前記強化繊維用経糸と交差する方向に配列された複数の強化繊維用緯糸と、前記強化繊維用緯糸より細い糸条からなり、前記強化繊維用緯糸と同方向に延びかつ前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側に配列された補助緯糸と、前記強化繊維用経糸より細い糸条からなり、前記強化繊維用経糸と同方向に延びかつ前記強化繊維用経糸同士の間に配列され、前記強化繊維用緯糸に係合した状態での折り返し及び前記補助緯糸に係合した状態での折り返しが混在した状態で配列された補助経糸とを備えている。ここで、「強化繊維用経糸」とは、織物基材を複合材料の強化繊維基材として使用した際に、複合材料のマトリックスを強化する役割を担う経糸を意味し、「強化繊維用緯糸」とは、織物基材を複合材料の強化繊維基材として使用した際に、複合材料のマトリックスを強化する役割を担う緯糸を意味する。また、「補助経糸」及び「補助緯糸」とは、一般の織物の経糸及び緯糸と同様に、織組織を構成して織物(織物基材)の移送や取り扱いの際に、強化繊維の配列が乱れたり織物(織物基材)が変形したりするのを防止するための機能を有する糸条を意味し、「補助経糸」及び「補助緯糸」は、自身が複合材料の機械的強度に寄与する必要は必ずしもない。また、「補助経糸」及び「補助緯糸」は、複数本の繊維の束で構成されるものに限らず、1本のフィラメントのようなものをも含む。   In order to achieve the first object, the invention according to claim 1 is characterized in that a plurality of reinforcing fiber warps composed of fiber bundles and arranged in parallel to each other, and parallel to each other and the warp yarns for reinforcing fibers composed of fiber bundles. A plurality of reinforcing fiber wefts arranged in a direction intersecting with the reinforcing fiber, and a thread thinner than the reinforcing fiber weft, extending in the same direction as the reinforcing fiber weft and the reinforcing fiber with respect to the reinforcing fiber warp An auxiliary weft arranged on the opposite side of the weft for use, and a thread thinner than the warp for reinforcing fiber, extends in the same direction as the warp for reinforcing fiber and arranged between the warps for reinforcing fiber, and the reinforcing And auxiliary warps arranged in a mixed state of folding in a state of being engaged with a weft for fibers and folding in a state of being engaged with the auxiliary weft. Here, “warp yarn for reinforcing fiber” means a warp that plays a role of reinforcing a matrix of a composite material when a woven fabric base material is used as a reinforcing fiber substrate of the composite material. The term “weft” means a weft that plays a role of reinforcing the matrix of the composite material when the woven base material is used as the reinforcing fiber base material of the composite material. In addition, “auxiliary warp” and “auxiliary weft” are the same as the warp and weft of a general woven fabric. This means a yarn having a function to prevent turbulence and deformation of the woven fabric (textile base material). “Auxiliary warp” and “auxiliary weft” themselves contribute to the mechanical strength of the composite material. There is no necessity. Further, the “auxiliary warp” and “auxiliary weft” are not limited to those composed of a bundle of a plurality of fibers but also include one filament.

この発明の織物基材は、繊維強化複合材料を構成した場合に強化繊維として機能する強化繊維用経糸及び強化繊維用緯糸が交差部においてクリンプせずに配列されているため、強化繊維が本来発現すべき特性である強度、剛性を発現できる。また、織物組織を構成する補助経糸及び補助緯糸は、繊維強化複合材料を構成した場合に強化繊維として機能する必要が無いため、細い糸条を使用できる。そのため、ステッチ糸で縫合する構成に比べて強化繊維用経糸及び強化繊維用緯糸の拘束が緩く、動き易いため賦形性が良くなる。また、補助緯糸が強化繊維用経糸に対して強化繊維用緯糸の反対側に配列された構成のため、特許文献2の構成と異なり、補助経糸に張力が加わっても緯糸間が開くことが抑制されて緯糸間の隙間が拡がらず、繊維強化複合材料にした場合、樹脂リッチ部が線状に存在する状態にならず、強度低下を防止する。したがって、この発明は、強化繊維のクリンプが無く、しかも形態保持性及び賦形性が良く繊維強化複合材料の強化繊維基材に適した織物基材を提供することができる。   In the woven fabric base material of the present invention, when the fiber reinforced composite material is constituted, the warp yarns for reinforcing fibers and the weft yarns for reinforcing fibers that function as reinforcing fibers are arranged without crimping at the intersections. It is possible to develop strength and rigidity, which are characteristics that should be achieved. Further, since the auxiliary warp and auxiliary weft constituting the woven fabric structure do not need to function as reinforcing fibers when the fiber reinforced composite material is constituted, thin yarns can be used. For this reason, the warp for reinforcing fibers and the weft for reinforcing fibers are looser and easier to move than the configuration in which stitching is performed with stitch yarns, and the shapeability is improved. Further, since the auxiliary wefts are arranged on the opposite side of the reinforcing fiber warp with respect to the reinforcing fiber warp, unlike the configuration of Patent Document 2, it is possible to prevent the wefts from being opened even if tension is applied to the auxiliary warp. Thus, when the gap between the wefts is not expanded and the fiber reinforced composite material is used, the resin rich portion does not exist in a linear shape, and the strength reduction is prevented. Therefore, the present invention can provide a woven fabric base material that is free from crimping of reinforcing fibers, has good shape retention and formability, and is suitable as a reinforcing fiber base material for fiber-reinforced composite materials.

請求項2に記載の発明は、請求項1に記載の発明において、前記補助経糸は、隣接する前記強化繊維用経糸同士の間に複数配列され、かつ前記複数の補助経糸のうち少なくとも1本は他の少なくとも1本に対して前記強化繊維用緯糸あるいは前記補助緯糸に対する折り返し位置が互いに逆になるように配列されている。この発明の織物基材は、隣接する強化繊維用経糸の間に1本の補助経糸が配列された構成の織物基材に比べて組織が強固になり、織物基材の取り扱いが容易になる。   The invention according to claim 2 is the invention according to claim 1, wherein a plurality of the auxiliary warps are arranged between the adjacent warps for reinforcing fibers, and at least one of the plurality of auxiliary warps is The at least one other fiber is arranged so that the fold-back positions with respect to the reinforcing fiber weft or the auxiliary weft are opposite to each other. The fabric base material of the present invention has a stronger structure than the fabric base material having a configuration in which one auxiliary warp is arranged between adjacent warp yarns for reinforcing fibers, and the fabric base material can be easily handled.

請求項3に記載の発明は、請求項1又は請求項2に記載の発明において、前記強化繊維用緯糸は、前記強化繊維用経糸と90°の角度を成すように配列されている。この発明の織物基材を製織する場合、従来の織機の簡単な改造で対応することができる。また、この発明の織物基材を2枚使用して、一方の織物基材を他方の織物基材に対して強化繊維の配列方向が45°ずれる状態で積層して使用することにより、繊維配向角度が0°、90°、+45°、−45°で配列された強化繊維層を有する擬似等方性の繊維強化複合材料を容易に得ることができる。   The invention according to claim 3 is the invention according to claim 1 or 2, wherein the wefts for reinforcing fibers are arranged so as to form an angle of 90 ° with the warps for reinforcing fibers. When weaving the textile substrate of the present invention, it can be handled by a simple modification of a conventional loom. Further, by using two woven fabric substrates of the present invention and using one of the woven fabric substrates in a state where the arrangement direction of the reinforcing fibers is deviated by 45 ° with respect to the other woven fabric substrate, the fiber orientation A pseudo-isotropic fiber-reinforced composite material having reinforcing fiber layers arranged at angles of 0 °, 90 °, + 45 °, and −45 ° can be easily obtained.

請求項4に記載の発明は、請求項1〜請求項3のいずれか1項に記載の発明において、前記補助緯糸は、前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側において前記強化繊維用緯糸の幅内に配列されている。   The invention according to claim 4 is the invention according to any one of claims 1 to 3, wherein the auxiliary weft is the opposite side of the weft for reinforcing fiber to the warp for reinforcing fiber. They are arranged within the width of the reinforcing fiber weft.

請求項5に記載の発明は、請求項1〜請求項4のいずれか1項に記載の発明において、前記強化繊維用経糸及び前記強化繊維用緯糸は、太さが100〜1600テックスであり、前記補助経糸及び前記補助緯糸は、太さが前記強化繊維用経糸及び前記強化繊維用緯糸の1/10以下である。   The invention according to claim 5 is the invention according to any one of claims 1 to 4, wherein the warp for reinforcing fibers and the weft for reinforcing fibers have a thickness of 100 to 1600 tex, The auxiliary warp and the auxiliary weft have a thickness of 1/10 or less of the warp for reinforcing fiber and the weft for reinforcing fiber.

強化繊維用経糸及び強化繊維用緯糸の太さは要求性能に対応して設定される。例えば、繊維強化複合材料の強化繊維として使用される炭素繊維のうち、市販の長繊維(フィラメント)集合体のPAN系炭素繊維には、1K、3K、6K、12K、24Kがあり、東レ製T700は12Kで800テックスである。なお、1Kとは1000フィラメントを意味する。この発明では強化繊維用経糸及び強化繊維用緯糸の太さが前記範囲のため、例えば、強化繊維用経糸及び強化繊維用緯糸として炭素繊維を使用する場合、市販の炭素繊維を入手し易い。   The thicknesses of the reinforcing fiber warp and the reinforcing fiber weft are set in accordance with the required performance. For example, among carbon fibers used as reinforcing fibers for fiber reinforced composite materials, commercially available long-fiber (filament) aggregate PAN-based carbon fibers include 1K, 3K, 6K, 12K, and 24K. Is 800 tex at 12K. 1K means 1000 filaments. In this invention, since the thickness of the warp for reinforcing fiber and the weft for reinforcing fiber is in the above range, for example, when carbon fiber is used as the warp for reinforcing fiber and the weft for reinforcing fiber, it is easy to obtain commercially available carbon fiber.

前記第2の目的を達成するため、請求項6に記載の発明の繊維強化複合材料は、繊維束からなり互いに平行に真っ直ぐに配列された複数の強化繊維用経糸と、繊維束からなり互いに平行にかつ前記強化繊維用経糸と交差する方向に真っ直ぐに配列された複数の強化繊維用緯糸と、前記強化繊維用緯糸より細い糸条からなり、前記強化繊維用緯糸と同方向に延びかつ前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側に配列された補助緯糸と、前記強化繊維用経糸より細い糸条からなり、前記強化繊維用経糸と同方向に延びかつ前記強化繊維用経糸同士の間に配列され、前記強化繊維用緯糸に係合した状態での折り返し及び前記補助緯糸に係合した状態での折り返しが混在した状態で配列された補助経糸とを備えている織物基材に樹脂を含浸させてなる。   In order to achieve the second object, the fiber-reinforced composite material of the invention described in claim 6 is composed of a plurality of warp fibers for reinforcing fibers that are made of fiber bundles and arranged in parallel with each other, and fiber bundles that are parallel to each other. And a plurality of reinforcing fiber wefts arranged in a direction intersecting with the reinforcing fiber warp, and a thread thinner than the reinforcing fiber weft, extending in the same direction as the reinforcing fiber weft and reinforcing the reinforcing fiber The auxiliary warp arranged on the opposite side of the weft for reinforcing fiber with respect to the warp for fiber, and a thread thinner than the warp for reinforcing fiber, and extends in the same direction as the warp for reinforcing fiber and the warp for reinforcing fiber A woven fabric base material comprising an auxiliary warp arranged in a state of being mixed together and folded in a state of being engaged with the weft for reinforcing fiber and being folded in a state of being engaged with the auxiliary weft Resin Immersed was composed.

この発明の繊維強化複合材料は、強化繊維として機能する強化繊維用経糸及び強化繊維用緯糸が交差部においてクリンプせずに真っ直ぐな状態で配列されているため、強化繊維が本来発現すべき特性である強度、剛性を発現できる。強化繊維基材となる織物基材は、強化繊維用経糸及び強化繊維用緯糸をステッチ糸で縫合する構成に比べて強化繊維用経糸及び強化繊維用緯糸の拘束が緩く、動き易いため賦形性が良くなる。また、織物基材は、補助経糸に張力が加わっても緯糸間が開くことが抑制されて緯糸間の隙間が拡がらず、繊維強化複合材料にした場合、樹脂リッチ部が線状に存在する状態にならず、強度低下を防止する。したがって、繊維強化複合材料を製造する際の織物基材の取り扱いが容易になる。   In the fiber-reinforced composite material of the present invention, the warp for reinforcing fiber and the weft for reinforcing fiber functioning as the reinforcing fiber are arranged in a straight state without crimping at the intersection, so that the reinforcing fiber has a characteristic that should be originally expressed. A certain strength and rigidity can be expressed. The woven fabric base material used as the reinforcing fiber base is shaped by the warp for the reinforcing fiber and the weft for the reinforcing fiber is looser and easier to move than the configuration in which the warp for the reinforcing fiber and the weft for the reinforcing fiber are stitched with the stitch yarn. Will be better. Further, in the woven fabric base, even when tension is applied to the auxiliary warp, the opening between the wefts is suppressed, the gap between the wefts does not expand, and when the fiber reinforced composite material is used, the resin-rich portion exists linearly. It does not become a state and prevents strength reduction. Therefore, handling of the textile base material when manufacturing the fiber reinforced composite material becomes easy.

本発明によれば、強化繊維のクリンプが無く、しかも形態保持性及び賦形性が良く繊維強化複合材料の強化繊維基材に適した織物基材を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, there is no crimp of a reinforced fiber, Moreover, the form retention property and shapeability are good, and the textile base material suitable for the reinforced fiber base material of a fiber reinforced composite material can be provided.

(a)は第1の実施形態の織物基材の模式斜視図、(b)は織物基材の模式断面図。(A) is a schematic perspective view of the textile base material of 1st Embodiment, (b) is a schematic cross section of a textile base material. 製織状態を示す模式側面図。The schematic side view which shows a weaving state. (a)は第2の実施形態の織物基材の模式斜視図、(b)は織物基材の模式断面図。(A) is a schematic perspective view of the textile base material of 2nd Embodiment, (b) is a schematic cross section of a textile base material. 第2の実施形態の織物基材の製織時におけるヘルドと強化繊維用経糸との関係を示す模式斜視図。The model perspective view which shows the relationship between the heald at the time of weaving of the textile base material of 2nd Embodiment, and the warp for reinforcement fibers. 別の実施形態の織物基材の模式斜視図。The schematic perspective view of the textile base material of another embodiment. 従来技術の複合材料用布帛構造物の概略斜視図。The schematic perspective view of the fabric structure for composite materials of a prior art.

(第1の実施形態)
以下、本発明を具体化した第1の実施形態を図1及び図2にしたがって説明する。
図1(a),(b)に示すように、織物基材10は、強化繊維としての複数の強化繊維用経糸11と、強化繊維としての複数の強化繊維用緯糸12と、補助緯糸13と、補助経糸14a,14bとを備えている。「強化繊維」とは、織物基材10を複合材料の強化繊維基材として使用した際に、複合材料のマトリックスを強化する役割を担う繊維束を意味する。複数の強化繊維用経糸11は、繊維束からなり互いに平行に真っ直ぐに配列され、複数の強化繊維用緯糸12も繊維束からなり互いに平行にかつ強化繊維用経糸11と交差する方向に真っ直ぐに配列されている。強化繊維用緯糸12は強化繊維用経糸11と90°の角度を成すように配列されている。
(First embodiment)
A first embodiment embodying the present invention will be described below with reference to FIGS.
As shown in FIGS. 1 (a) and 1 (b), a woven fabric base 10 includes a plurality of reinforcing fiber warps 11 as reinforcing fibers, a plurality of reinforcing fiber wefts 12 as reinforcing fibers, and auxiliary wefts 13; And auxiliary warp yarns 14a and 14b. The “reinforcing fiber” means a fiber bundle that plays a role of reinforcing the matrix of the composite material when the woven base material 10 is used as the reinforcing fiber base material of the composite material. The plurality of reinforcing fiber warps 11 are made of fiber bundles and arranged straight in parallel with each other, and the plurality of reinforcing fiber wefts 12 are also made of fiber bundles and arranged in parallel with each other and in a direction intersecting with the reinforcing fiber warps 11. Has been. The reinforcing fiber wefts 12 are arranged so as to form an angle of 90 ° with the reinforcing fiber warps 11.

強化繊維用経糸11及び強化繊維用緯糸12には炭素繊維が使用されている。炭素繊維は、複合材料の要求性能にもよるが、例えば、東レ製T700のフィラメント数が12000本で太さが800テックスのものを使用した。強化繊維用経糸11及び強化繊維用緯糸12は、炭素繊維が開繊された状態で織物基材10を構成している。「開繊された状態」とは、繊維束を構成する繊維間隔が拡げられて繊維束が扁平な状態になることを意味する。   Carbon fibers are used for the warp yarns 11 for reinforcing fibers and the weft yarns 12 for reinforcing fibers. Depending on the required performance of the composite material, for example, a carbon fiber with a T700 T700 filament count and a thickness of 800 tex was used. The reinforcing fiber warp 11 and the reinforcing fiber weft 12 constitute the woven fabric base 10 in a state where the carbon fiber is opened. The “opened state” means that the interval between fibers constituting the fiber bundle is widened and the fiber bundle becomes flat.

補助緯糸13は、強化繊維用緯糸より細い糸条でからなり、強化繊維用緯糸12と同方向に延びかつ強化繊維用経糸11に対して強化繊維用緯糸12の反対側に配列されている。強化繊維用緯糸12の反対側とは強化繊維用緯糸12の幅内に位置することを意味する。補助経糸14a,14bは、強化繊維用経糸11より細い糸条からなり、強化繊維用経糸11と同方向に延びかつ強化繊維用経糸11同士の間に配列され、強化繊維用緯糸12及び補助緯糸13と交差する状態でかつ強化繊維用緯糸12に係合した状態での折り返し及び補助緯糸13に係合した状態での折り返しが混在した状態で配列されている。この実施形態では、補助経糸14a,14bは隣り合う強化繊維用経糸11の間に交互に1本ずつ配列されている。補助緯糸13及び補助経糸14a,14bには太さが10テックス程度のナイロンやポリエステル製の糸が使用されている。   The auxiliary wefts 13 are made of threads that are thinner than the wefts for reinforcing fibers, extend in the same direction as the wefts 12 for reinforcing fibers, and are arranged on the opposite side of the wefts 12 for reinforcing fibers with respect to the warp yarns 11 for reinforcing fibers. The opposite side of the reinforcing fiber weft 12 means being positioned within the width of the reinforcing fiber weft 12. The auxiliary warps 14a and 14b are made of a thread thinner than the reinforcing fiber warp 11, extend in the same direction as the reinforcing fiber warp 11, and are arranged between the reinforcing fiber warps 11, and include the reinforcing fiber weft 12 and the auxiliary weft. 13 are arranged in a state where the folding in the state intersecting with the weft 12 for reinforcing fibers and the folding in the state engaged with the auxiliary weft 13 are mixed. In this embodiment, the auxiliary warps 14 a and 14 b are alternately arranged one by one between the adjacent reinforcing fiber warps 11. For the auxiliary weft 13 and the auxiliary warps 14a and 14b, nylon or polyester yarn having a thickness of about 10 tex is used.

次に前記のように構成された織物基材10の製造方法を説明する。織物基材10の製織は、例えば、補助経糸14a,14bの開口を行う2枚のヘルドフレーム(綜絖枠)を備えた従来の平織織機の簡単な改造で対応することができる。具体的には、補助経糸14a,14bの同じ開口に強化繊維用緯糸12及び補助緯糸13を緯入れする構成にする。   Next, the manufacturing method of the textile base material 10 comprised as mentioned above is demonstrated. The weaving of the woven base material 10 can be performed by a simple modification of a conventional plain weaving machine having two heald frames (rib frames) for opening the auxiliary warps 14a and 14b, for example. Specifically, the reinforcing fiber weft 12 and the auxiliary weft 13 are inserted into the same opening of the auxiliary warps 14a and 14b.

図2に示すように、織機は、強化繊維用経糸11を供給する強化繊維用経糸ビーム21と、補助経糸14aを供給する補助経糸ビーム22と、補助経糸14bを供給する補助経糸ビーム23とが上下に3段に配置されている。強化繊維用経糸ビーム21からは強化繊維用経糸11が水平に送り出され、一方の補助経糸ビーム22から送り出される補助経糸14aは一方のヘルドフレームのヘルド24により開口動作が行われ、他方の補助経糸ビーム23から送り出される補助経糸14bは他方のヘルドフレームのヘルド25により開口動作が行われるようになっている。なお、ヘルド24,25の目は図において黒丸で示されている。筬30はヘルド24と織り前31との間に配置されている。   As shown in FIG. 2, the loom has a reinforcing fiber warp beam 21 for supplying the reinforcing fiber warp 11, an auxiliary warp beam 22 for supplying the auxiliary warp 14a, and an auxiliary warp beam 23 for supplying the auxiliary warp 14b. It is arranged in three stages up and down. The reinforcing fiber warp 11 is horizontally fed out from the reinforcing fiber warp beam 21, and the auxiliary warp 14a fed out from one auxiliary warp beam 22 is opened by the heald 24 of one heald frame, while the other auxiliary warp. The auxiliary warp 14b delivered from the beam 23 is opened by the heald 25 of the other heald frame. The eyes of healds 24 and 25 are indicated by black circles in the figure. The heel 30 is disposed between the heald 24 and the weave 31.

強化繊維用緯糸12は補助経糸14a,14bの開口に対して強化繊維用経糸11の上側に緯入れ機構(図示せず)により緯入れされ、補助緯糸13は補助経糸14a,14bの開口に対して強化繊維用経糸11の下側に緯入れ機構(図示せず)により緯入れされるようになっている。   Reinforcing fiber weft 12 is weft-inserted by a weft insertion mechanism (not shown) above reinforcing fiber warp 11 with respect to the openings of auxiliary warps 14a, 14b, and auxiliary weft 13 is against the openings of auxiliary warps 14a, 14b. Thus, the weft insertion mechanism (not shown) is inserted below the reinforcing fiber warp 11.

上記の織機で織物基材10を製織する場合、強化繊維用経糸ビーム21から引き出された強化繊維用経糸11及び補助経糸ビーム22,23から引き出された補助経糸14a,14bの端部が巻き取りロール(図示せず)に固定された状態から製織が開始される。2枚のヘルドフレームが交互に上下方向に移動されることにより、一方のヘルドフレームに支持された各ヘルド24と、他方のヘルドフレームに支持された各ヘルド25とが逆方向に移動される。そして、補助経糸14a,14bは隣接するもの同士で交互に上下に開き、その都度形成される経糸開口16に対して、強化繊維用緯糸12及び補助緯糸13が緯入れされる。   When weaving the textile substrate 10 with the above-mentioned loom, the ends of the auxiliary warp yarns 14a and 14b drawn out from the reinforcing fiber warp yarn 11 and the auxiliary warp yarns 22 and 23 are wound up. Weaving is started from a state of being fixed to a roll (not shown). By moving the two heald frames alternately in the vertical direction, each heald 24 supported by one heald frame and each heald 25 supported by the other heald frame are moved in opposite directions. The auxiliary warps 14a and 14b are alternately opened up and down alternately, and the reinforcing fiber weft 12 and the auxiliary weft 13 are inserted into the warp opening 16 formed each time.

強化繊維用緯糸12は、経糸開口16の強化繊維用経糸11より上側に緯入れされ、補助緯糸13は、経糸開口16の強化繊維用経糸11より下側に緯入れされる。強化繊維用緯糸12及び補助緯糸13が緯入れされて、筬30の筬打ち動作が行われた後、ヘルド24,25が逆方向に移動されて開口状態が変更されて、次の緯入れ動作が行われる。これらの動作が繰り返されて織物基材10が製織され、巻き取りロールに巻き取られる。   The reinforcing fiber weft 12 is inserted above the reinforcing fiber warp 11 in the warp opening 16, and the auxiliary weft 13 is inserted below the reinforcing fiber warp 11 in the warp opening 16. After the weft 12 for reinforcing fiber and the auxiliary weft 13 are inserted and the hammer 30 is hammered, the healds 24 and 25 are moved in the opposite direction to change the opening state, and the next weft insertion operation Is done. These operations are repeated to weave the woven base material 10 and wind it up on a winding roll.

織物基材10は、複数枚積層された状態で賦形されてプリフォームに形成された後、例えば、RTM法で硬化前の液状の熱硬化性樹脂が含浸硬化されて繊維強化複合材料が形成される。擬似等方性の繊維強化複合材料を製造する場合は、擬似等方性の繊維基材を賦形してプリフォームを形成する必要がある。織物基材10は強化繊維用経糸11と強化繊維用緯糸12とが90°の角度で交差しており、2枚の織物基材10を強化繊維用経糸11が45°の角度で交差する状態で積層することにより、強化繊維が0°、90°、+45°、−45°で配列された擬似等方性の強化繊維基材を構成できる。また、繊維束の配向角が45°の一方向織物2枚と、1枚の織物基材10とを積層することによっても、強化繊維が0°、90°、+45°、−45°で配列された擬似等方性の強化繊維基材を構成できる。   After the fabric base material 10 is formed in a state of being laminated in a plurality of layers and formed into a preform, for example, a liquid thermosetting resin before curing is impregnated and cured by an RTM method to form a fiber-reinforced composite material. Is done. When producing a quasi-isotropic fiber reinforced composite material, it is necessary to form a quasi-isotropic fiber substrate to form a preform. In the woven fabric base 10, the reinforcing fiber warp 11 and the reinforcing fiber weft 12 intersect at an angle of 90 °, and the two woven fabric substrates 10 intersect the reinforcing fiber warp 11 at an angle of 45 °. By laminating with, a pseudo-isotropic reinforcing fiber substrate in which reinforcing fibers are arranged at 0 °, 90 °, + 45 °, and −45 ° can be configured. Further, by laminating two unidirectional woven fabrics having a fiber bundle orientation angle of 45 ° and one woven fabric base material 10, the reinforcing fibers are arranged at 0 °, 90 °, + 45 °, and −45 °. A pseudo-isotropic reinforcing fiber substrate can be formed.

この実施形態によれば、以下に示す効果を得ることができる。
(1)織物基材10は、繊維束からなり互いに平行に配列された複数の強化繊維用経糸11と、繊維束からなり互いに平行にかつ強化繊維用経糸11と交差する方向に配列された複数の強化繊維用緯糸12とを備えている。したがって、織物基材10を繊維強化複合材料の強化繊維基材に用いた場合、強化繊維が本来発現すべき特性である強度、剛性を発現できる。
According to this embodiment, the following effects can be obtained.
(1) The woven fabric base 10 is composed of a plurality of reinforcing fiber warps 11 made of fiber bundles and arranged in parallel to each other, and a plurality of fibers made of fiber bundles arranged in parallel to each other and intersecting the reinforcing fiber warps 11. And a weft 12 for reinforcing fibers. Therefore, when the woven fabric substrate 10 is used as a reinforcing fiber substrate of a fiber reinforced composite material, strength and rigidity, which are characteristics that the reinforcing fiber should originally express, can be expressed.

(2)織物基材10は、強化繊維用緯糸12より細い糸条からなり、強化繊維用緯糸12と同方向に延びる補助緯糸13と、強化繊維用経糸11より細い糸条からなり、強化繊維用経糸11と同方向に延びる補助経糸14a,14bとを備えている。補助緯糸13は、強化繊維用経糸11に対して強化繊維用緯糸12の反対側に配列され、補助経糸14a,14bは、強化繊維用経糸11同士の間に配列され、かつ強化繊維用緯糸12に係合した状態での折り返し及び補助緯糸13に係合した状態での折り返しが混在した状態で配列されている。織物組織を構成する補助経糸14a,14b及び補助緯糸13は、繊維強化複合材料を構成した場合に強化繊維として機能する必要が無いため、細い糸条を使用できる。そのため、ステッチ糸で縫合する構成に比べて強化繊維用経糸11及び強化繊維用緯糸12の拘束が緩く、動き易いため賦形性が良くなる。また、補助緯糸13が強化繊維用経糸11に対して強化繊維用緯糸12の反対側に配列された構成のため、補助経糸14a,14bに張力が加わっても緯糸間が開くことが抑制されて緯糸間の隙間が拡がらず、繊維強化複合材料にした場合、樹脂リッチ部が線状に存在する状態にならず、強度低下が防止される。したがって、織物基材10は、強化繊維のクリンプが無く、しかも形態保持性及び賦形性が良く繊維強化複合材料の強化繊維基材に適した織物基材10となる。   (2) The woven fabric base 10 is made of a thread thinner than the reinforcing fiber weft 12, is made of an auxiliary weft 13 extending in the same direction as the reinforcing fiber weft 12, and a thread thinner than the reinforcing fiber warp 11, and is made of reinforcing fiber. Auxiliary warps 14a and 14b extending in the same direction as the warp 11 are provided. The auxiliary wefts 13 are arranged on the side opposite to the reinforcing fiber wefts 12 with respect to the reinforcing fiber warps 11, the auxiliary warps 14 a and 14 b are arranged between the reinforcing fiber warps 11, and the reinforcing fiber wefts 12. Are arranged in a mixed state of folding in the engaged state with the auxiliary weft 13 and folding in the engaged state with the auxiliary weft 13. Since the auxiliary warp yarns 14a and 14b and the auxiliary weft yarn 13 constituting the woven fabric structure do not need to function as reinforcing fibers when the fiber reinforced composite material is constituted, thin yarns can be used. For this reason, the warp 11 for reinforcing fibers and the weft 12 for reinforcing fibers are looser and easier to move than the configuration in which stitching is performed with stitch yarns, and the shapeability is improved. In addition, since the auxiliary weft 13 is arranged on the opposite side of the reinforcing fiber weft 12 with respect to the reinforcing fiber warp 11, it is possible to prevent the weft from being opened even if tension is applied to the auxiliary warps 14a and 14b. When the gap between the wefts does not widen and a fiber reinforced composite material is used, the resin-rich portion does not exist in a linear shape, and strength reduction is prevented. Therefore, the fabric base material 10 is a fabric base material 10 that is free from crimping of reinforcing fibers, has good shape retention and shapeability, and is suitable as a reinforcing fiber base material for fiber-reinforced composite materials.

(3)強化繊維用経糸11及び強化繊維用緯糸12は、炭素繊維で構成され、市販の炭素繊維より容易に太さを選定して入手できる。
(4)強化繊維用緯糸12は、強化繊維用経糸11と90°の角度を成すように配列されている。したがって、織物基材10を製織する場合、従来の織機の簡単な改造で対応することができる。また、織物基材10を2枚使用して、一方の織物基材10を他方の織物基材10に対して強化繊維の配列方向が45°ずれる状態で積層して使用することにより、繊維配向角度が0°、90°、+45°、−45°で配列された強化繊維層を有する擬似等方性の繊維強化複合材料を容易に得ることができる。
(3) The warp yarns 11 for reinforcing fibers and the weft yarns 12 for reinforcing fibers are made of carbon fibers, and can be easily obtained by selecting the thickness from commercially available carbon fibers.
(4) The reinforcing fiber wefts 12 are arranged so as to form an angle of 90 ° with the reinforcing fiber warps 11. Therefore, when weaving the woven base material 10, it can be handled by a simple modification of a conventional loom. Further, by using two woven fabric base materials 10 and laminating and using one woven fabric base material 10 in a state where the arrangement direction of the reinforcing fibers is shifted by 45 ° with respect to the other woven fabric base material 10, A pseudo-isotropic fiber-reinforced composite material having reinforcing fiber layers arranged at angles of 0 °, 90 °, + 45 °, and −45 ° can be easily obtained.

(5)補助経糸14a,14bは、隣り合う強化繊維用経糸11の間に交互に1本ずつ配列されている。したがって、織物基材10を製織する織機の経糸開口装置として、2枚のヘルドフレームで隣り合う経糸を交互に上下動させる一般の平織織機の装置を使用することができる。   (5) The auxiliary warps 14a and 14b are alternately arranged one by one between the adjacent reinforcing fiber warps 11. Therefore, as a warp opening device of a loom for weaving the woven base material 10, a general plain loom device that alternately moves up and down adjacent warps with two heald frames can be used.

(第2の実施形態)
次に第2の実施形態を図3及び図4にしたがって説明する。この実施形態の織物基材10は、補助経糸14a,14bの配列状態が前記第1の実施形態と異なっており、その他の構成は第1の実施形態と同様であり、第1の実施形態と同様の部分は同一符号を付して詳しい説明を省略する。
(Second Embodiment)
Next, a second embodiment will be described with reference to FIGS. The fabric base material 10 of this embodiment is different from the first embodiment in the arrangement state of the auxiliary warps 14a and 14b, and the other configurations are the same as those of the first embodiment. Similar parts are denoted by the same reference numerals, and detailed description thereof is omitted.

第1の実施形態では、隣接する強化繊維用経糸11の間に補助経糸14aと補助経糸14bとが交互に配列されていた。この実施形態では、図3(a),(b)に示すように、織物基材10を構成する補助経糸14a,14bは、隣接する強化繊維用経糸11の間に2本の補助経糸14a,14bが、強化繊維用緯糸12あるいは補助緯糸13に対する折り返し位置が互いに逆になるように配列されている。即ち、強化繊維用緯糸12及び補助緯糸13は、隣り合う強化繊維用経糸11間において強化繊維用緯糸12の配列面及び補助緯糸13の配列面と直交する平面内に位置する2本の補助経糸14a,14bにより保持される構成となる。   In the first embodiment, the auxiliary warps 14a and the auxiliary warps 14b are alternately arranged between the adjacent reinforcing fiber warps 11. In this embodiment, as shown in FIGS. 3A and 3B, the auxiliary warps 14 a and 14 b constituting the woven fabric base 10 are composed of two auxiliary warps 14 a and 14 b between the adjacent reinforcing fiber warps 11. 14b are arranged so that the folding positions with respect to the reinforcing fiber weft 12 or the auxiliary weft 13 are opposite to each other. That is, the reinforcing fiber weft 12 and the auxiliary weft 13 are two auxiliary warps located in a plane perpendicular to the arrangement surface of the reinforcing fiber weft 12 and the auxiliary weft 13 between the adjacent reinforcing fiber warps 11. It becomes the structure hold | maintained by 14a, 14b.

織物基材10を製織する織機は、従来の平織織機と同様に補助経糸14a,14bの開口を行う2枚のヘルドフレーム(綜絖枠)を備えている。しかし、各ヘルドフレームのヘルド24,25は、図4に示すように、補助経糸14a及び補助経糸14bがそれぞれ同じ隣り合う強化繊維用経糸11の間において経糸開口を形成するように、隣り合う強化繊維用経糸11間の一平面内で上下動するように構成されている。したがって、強化繊維用経糸11の本数が同じ場合補助経糸14a,14bの本数は第1の実施形態の2倍になる。   The loom for weaving the woven base material 10 includes two heald frames (rib frames) for opening the auxiliary warp yarns 14a and 14b as in the conventional plain weaving loom. However, as shown in FIG. 4, the healds 24 and 25 of each heald frame are adjacent to each other so that the auxiliary warps 14 a and the auxiliary warps 14 b form warp openings between the same adjacent reinforcing fiber warps 11. It is comprised so that it may move up and down within one plane between the warp yarns 11 for fibers. Therefore, when the number of reinforcing fiber warps 11 is the same, the number of auxiliary warps 14a and 14b is twice that of the first embodiment.

この第2の実施形態によれば、第1の実施形態の(1)〜(4)と同様な効果に加えて以下の効果を得ることができる。
(6)織物基材10を構成する補助経糸14a,14bは、隣接する強化繊維用経糸11の間に2本の補助経糸14a,14bが、強化繊維用緯糸12あるいは補助緯糸13に対する折り返し位置が互いに逆になるように配列されている。そのため、隣接する強化繊維用経糸11の間に1本の補助経糸が配列された構成の織物基材10に比べて組織が強固になり、織物基材10をプリフォームを形成するための成形型内に収容したり、マトリックス用の樹脂を含浸、硬化するための型内に収容したりするなどの取り扱いが容易になる。
According to this 2nd Embodiment, in addition to the effect similar to (1)-(4) of 1st Embodiment, the following effects can be acquired.
(6) The auxiliary warp yarns 14a and 14b constituting the woven fabric substrate 10 have two auxiliary warp yarns 14a and 14b between the adjacent reinforcing fiber warp yarns 11, and the return position relative to the reinforcing fiber weft yarn 12 or the auxiliary weft yarn 13 is They are arranged so that they are opposite to each other. Therefore, the structure becomes stronger than the fabric base 10 having a configuration in which one auxiliary warp is arranged between adjacent warp yarns 11 for reinforcing fibers, and a molding die for forming the fabric base 10 into a preform. It becomes easy to handle such as housing in a mold or housing in a mold for impregnating and curing a matrix resin.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
○ 織物基材10は、隣り合う強化繊維用経糸11の間に補助経糸14a,14bの少なくとも一方が配列されている必要はなく、例えば、図5に示すように、補助経糸14aが配列された箇所と、補助経糸14a,14bが配列されていない箇所と、補助経糸14bが配列された箇所とが繰り返される構成としてもよい。
The embodiment is not limited to the above, and may be embodied as follows, for example.
○ In the woven fabric base material 10, it is not necessary that at least one of the auxiliary warps 14a and 14b be arranged between the adjacent reinforcing fiber warps 11, for example, the auxiliary warps 14a are arranged as shown in FIG. A location, a location where the auxiliary warps 14a and 14b are not arranged, and a location where the auxiliary warps 14b are arranged may be repeated.

○ 第2の実施形態のように隣り合う強化繊維用経糸11の間に2本の補助経糸14a,14bが配列された構成においても、2本の補助経糸14a,14bが配列された箇所と、補助経糸14a,14bが配列されていない箇所とが交互に繰り返される構成としてもよい。また、補助経糸14a,14bが配列されていない箇所と2本の補助経糸14a,14bが配列された箇所とがランダムに存在する構成としてもよい。これらの場合、補助経糸14a,14bの合計本数が第1の実施形態と同じでも、第1の実施形態に比べて補助経糸14a,14bによる織物基材10の形態保持効果が高くなる。   ○ In the configuration in which two auxiliary warps 14a and 14b are arranged between adjacent reinforcing fiber warps 11 as in the second embodiment, a place where the two auxiliary warps 14a and 14b are arranged; It is good also as a structure by which the place where the auxiliary warp yarns 14a and 14b are not arranged is repeated alternately. Moreover, it is good also as a structure where the location where the auxiliary warps 14a and 14b are not arranged and the location where the two auxiliary warps 14a and 14b are arranged exist at random. In these cases, even if the total number of the auxiliary warps 14a and 14b is the same as that in the first embodiment, the effect of maintaining the shape of the fabric base 10 by the auxiliary warps 14a and 14b is higher than that in the first embodiment.

○ 織物基材10は、隣り合う強化繊維用経糸11の間に配列された補助経糸14a,14bの本数が1本の箇所と、2本の箇所が存在する構成であってもよい。
○ 補助経糸14a,14bは、隣接する強化繊維用経糸11同士の間に複数配列され、かつ複数の補助経糸14a,14bのうち少なくとも1本は他の少なくとも1本に対して強化繊維用緯糸12あるいは補助緯糸13に対する折り返し位置が互いに逆になるように配列されていればよく、補助経糸14a,14bの本数が3本以上であってもよい。
The fabric base 10 may have a configuration in which the number of auxiliary warps 14a and 14b arranged between adjacent reinforcing fiber warps 11 is one and two locations.
A plurality of auxiliary warp yarns 14a and 14b are arranged between adjacent reinforcing fiber warp yarns 11, and at least one of the plurality of auxiliary warp yarns 14a and 14b is a reinforcing fiber weft yarn 12 with respect to at least one other. Alternatively, the auxiliary wefts 13 may be arranged so that the folding positions with respect to the auxiliary wefts 13 are opposite to each other, and the number of auxiliary warps 14a and 14b may be three or more.

○ 織物基材10は、強化繊維用緯糸12が強化繊維用経糸11と成す角度は90°に限らず、他の角度であってもよい。例えば、強化繊維用緯糸12が強化繊維用経糸11と成す角度を45°としてもよい。   In the woven fabric base 10, the angle formed by the reinforcing fiber weft 12 and the reinforcing fiber warp 11 is not limited to 90 °, and may be another angle. For example, the angle formed by the reinforcing fiber weft 12 and the reinforcing fiber warp 11 may be 45 °.

○ 強化繊維用経糸11及び強化繊維用緯糸12を構成する繊維束は炭素繊維に限らず、繊維強化複合材料に要求される物性に対応して、アラミド繊維、ポリ−p−フェニレンベンゾビスオキサゾール繊維、超高分子量ポリエチレン繊維等の高強度の有機繊維、ガラス繊維やセラミック繊維等の無機繊維を使用してもよい。例えば、ガラス繊維を使用した場合は、ガラス繊維が炭素繊維に比べて安価なため、コスト低減となる。   ○ The fiber bundles constituting the warp yarn 11 for reinforcing fibers and the weft yarn 12 for reinforcing fibers are not limited to carbon fibers, and aramid fibers, poly-p-phenylenebenzobisoxazole fibers corresponding to the physical properties required for fiber reinforced composite materials Further, high-strength organic fibers such as ultrahigh molecular weight polyethylene fibers, and inorganic fibers such as glass fibers and ceramic fibers may be used. For example, when glass fiber is used, the cost is reduced because the glass fiber is less expensive than the carbon fiber.

○ 強化繊維用経糸11及び強化繊維用緯糸12は、太さが600テックス程度に限らない。繊維強化複合材料に対する要求性能にもよるが、炭素繊維の場合3K〜24Kの本数のものが使用され、炭素繊維の種類にもよるが太さはおおよそ100〜1600テックスとなる。なお、炭素繊維のフィラメントの密度は1〜2割程度の範囲でばらつきが有り、直径は5割程度の範囲でばらつきが有るため、同じ本数の炭素繊維であってもテックスで表す太さもバラツキが有る。   The warp yarn 11 for reinforcing fibers and the weft yarn 12 for reinforcing fibers are not limited to about 600 tex in thickness. Depending on the required performance of the fiber reinforced composite material, the number of carbon fibers of 3K to 24K is used, and the thickness is approximately 100 to 1600 tex depending on the type of carbon fiber. Note that the density of carbon fiber filaments varies within a range of about 10 to 20%, and the diameter varies within a range of about 50%, so even the same number of carbon fibers can vary in thickness expressed by tex. Yes.

○ 補助緯糸13及び補助経糸14a,14bはナイロンやポリエステル製の糸に限らず、炭素繊維やガラス繊維の繊維束であってもよい。
○ 補助緯糸13及び補助経糸14a,14bとしてナイロンやポリエステル製の糸を使用した場合その太さは数十デニールから1500デニール程度であり、テックスに換算すると数テックスから160テックス程度となる。即ち、補助緯糸13及び補助経糸14a,14b及びの太さは強化繊維用経糸11及び強化繊維用緯糸12の1/10以下になる。補助緯糸13及び補助経糸14a,14bは、織物基材10が繊維強化複合材料を構成した状態で強化繊維として機能する必要が無いため、織物基材10の状態において織物基材10の形態を保持できる太さであれば、細い方が好ましい。
The auxiliary weft 13 and the auxiliary warps 14a and 14b are not limited to nylon or polyester yarns, and may be fiber bundles of carbon fibers or glass fibers.
When nylon or polyester yarn is used as the auxiliary weft 13 and the auxiliary warp yarns 14a and 14b, the thickness is about tens of deniers to about 1500 deniers. When converted to texes, the thickness is about several texes to about 160 texes. That is, the thickness of the auxiliary weft 13 and the auxiliary warps 14a and 14b is 1/10 or less of the warp 11 for reinforcing fibers and the weft 12 for reinforcing fibers. The auxiliary weft 13 and the auxiliary warps 14a and 14b do not need to function as reinforcing fibers in a state in which the fabric base 10 constitutes a fiber reinforced composite material, and thus the shape of the fabric base 10 is maintained in the state of the fabric base 10. The thinner one is preferable as long as it is possible.

○ 織物基材10を繊維強化複合材料の強化繊維基材として使用する場合、マトリックス樹脂の種類や繊維強化複合材料の製造方法に、特に規制はない。
○ 織物基材10にRTM法で樹脂を含浸硬化する場合、織物基材10を予めプリフォームに賦形した後、樹脂の含浸硬化用の金型内に配置するのではなく、複数の織物基材10を金型内に配置しつつ賦形してもよい。
O When using the textile base material 10 as a reinforced fiber base material of a fiber reinforced composite material, there is no restriction | limiting in particular in the kind of matrix resin, or the manufacturing method of a fiber reinforced composite material.
○ In the case where a resin is impregnated and cured by the RTM method on the woven base material 10, after the woven base material 10 is pre-shaped into a preform, it is not arranged in a mold for impregnating and hardening the resin, The material 10 may be shaped while being placed in the mold.

○ 強化繊維用経糸11及び強化繊維用緯糸12は、織物基材10の状態ではそれぞれ真っ直ぐに配列されずに湾曲した状態に配列されていてもよい。織物基材10を製造した段階では強化繊維用経糸11及び強化繊維用緯糸12が湾曲した状態であっても、強化繊維用経糸11及び強化繊維用緯糸12が真っ直ぐに配列された状態でマトリックスとなる樹脂を含浸、硬化させることで繊維強化複合材料の状態では強化繊維用経糸11及び強化繊維用緯糸12が真っ直ぐに配列された状態にできる。   The warp yarns 11 for reinforcing fibers and the weft yarns 12 for reinforcing fibers may be arranged in a curved state instead of being arranged straight in the state of the woven fabric substrate 10. Even when the reinforcing fiber warp yarn 11 and the reinforcing fiber weft yarn 12 are curved at the stage of manufacturing the woven fabric base material 10, the reinforcing fiber warp yarn 11 and the reinforcing fiber weft yarn 12 are arranged in a straight line. By impregnating and curing the resulting resin, in the state of the fiber-reinforced composite material, the warp yarns 11 for reinforcing fibers and the weft yarns 12 for reinforcing fibers can be arranged in a straight line.

以下の技術的思想(発明)は前記実施形態から把握できる。
(1)隣り合う前記強化繊維用経糸の間には、前記補助経糸が配置された箇所と前記補助経糸が配置されていない箇所とが交互に存在する請求項1〜請求項5のいずれか1項に記載の織物基材。
The following technical idea (invention) can be understood from the embodiment.
(1) Between the adjacent warps for reinforcing fibers, there are alternately places where the auxiliary warps are arranged and places where the auxiliary warps are not arranged. Item 10. A textile substrate according to item.

(2)請求項1〜請求項5及び前記技術的思想(1)のいずれか一項に記載の織物基材からなるプリフォーム。
(3)請求項1〜請求項5及び前記技術的思想(1),(2)のいずれか一項に記載の織物基材を強化繊維基材として含む繊維強化複合材料。
(2) A preform comprising the textile substrate according to any one of claims 1 to 5 and the technical idea (1).
(3) A fiber-reinforced composite material comprising the woven fabric substrate according to any one of claims 1 to 5 and the technical ideas (1) and (2) as a reinforced fiber substrate.

10…織物基材、11…強化繊維用経糸、12…強化繊維用緯糸、13…補助緯糸、14a,14b…補助経糸。   DESCRIPTION OF SYMBOLS 10 ... Textile base material, 11 ... Warp for reinforcement fiber, 12 ... Weft for reinforcement fiber, 13 ... Auxiliary weft, 14a, 14b ... Auxiliary warp

Claims (6)

繊維束からなり互いに平行に配列された複数の強化繊維用経糸と、
繊維束からなり互いに平行にかつ前記強化繊維用経糸と交差する方向に配列された複数の強化繊維用緯糸と、
前記強化繊維用緯糸より細い糸条からなり、前記強化繊維用緯糸と同方向に延びかつ前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側に配列された補助緯糸と、
前記強化繊維用経糸より細い糸条からなり、前記強化繊維用経糸と同方向に延びかつ前記強化繊維用経糸同士の間に配列され、前記強化繊維用緯糸に係合した状態での折り返し及び前記補助緯糸に係合した状態での折り返しが混在した状態で配列された補助経糸と
を備えている織物基材。
A plurality of warp yarns for reinforcing fibers made of fiber bundles and arranged in parallel with each other;
A plurality of weft yarns for reinforcing fibers which are made of fiber bundles and arranged in parallel to each other and in a direction intersecting with the warp yarns for reinforcing fibers;
An auxiliary weft consisting of a thread thinner than the reinforcing fiber weft, extending in the same direction as the reinforcing fiber weft and arranged on the opposite side of the reinforcing fiber weft with respect to the reinforcing fiber warp;
The reinforcing fiber warp is made of a thread that is thinner than the reinforcing fiber warp, extends in the same direction as the reinforcing fiber warp, and is arranged between the reinforcing fiber warps. A woven fabric base material comprising auxiliary warp yarns arranged in a mixed state of folding when engaged with auxiliary weft yarns.
前記補助経糸は、隣接する前記強化繊維用経糸同士の間に複数配列され、かつ前記複数の補助経糸のうち少なくとも1本は他の少なくとも1本に対して前記強化繊維用緯糸あるいは前記補助緯糸に対する折り返し位置が互いに逆になるように配列されている請求項1に記載の織物基材。   A plurality of the auxiliary warp yarns are arranged between the adjacent warp yarns for reinforcing fibers, and at least one of the plurality of auxiliary warp yarns is relative to at least one of the reinforcing fiber weft yarns or the auxiliary weft yarns. The textile base material according to claim 1, wherein the folding positions are arranged so as to be opposite to each other. 前記強化繊維用緯糸は、前記強化繊維用経糸と90°の角度を成すように配列されている請求項1又は請求項2に記載の織物基材。   The fabric substrate according to claim 1 or 2, wherein the reinforcing fiber wefts are arranged so as to form an angle of 90 ° with the reinforcing fiber warps. 前記補助緯糸は、前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側において前記強化繊維用緯糸の幅内に配列されている請求項1〜請求項3のいずれか1項に記載の織物基材。   4. The auxiliary weft according to claim 1, wherein the auxiliary weft is arranged within the width of the reinforcing fiber weft on the side opposite to the reinforcing fiber weft with respect to the reinforcing fiber warp. 5. Woven textile substrate. 前記強化繊維用経糸及び前記強化繊維用緯糸は、太さが100〜1600テックスであり、前記補助経糸及び前記補助緯糸は、太さが前記強化繊維用経糸及び前記強化繊維用緯糸の1/10以下である請求項1〜請求項4のいずれか1項に記載の織物基材。   The warp for reinforcing fiber and the weft for reinforcing fiber have a thickness of 100 to 1600 tex, and the auxiliary warp and the auxiliary weft have a thickness of 1/10 of the warp for reinforcing fiber and the weft for reinforcing fiber. It is the following, The textile base material given in any 1 paragraph of Claims 1-4. 繊維束からなり互いに平行に真っ直ぐに配列された複数の強化繊維用経糸と、
繊維束からなり互いに平行にかつ前記強化繊維用経糸と交差する方向に真っ直ぐに配列された複数の強化繊維用緯糸と、
前記強化繊維用緯糸より細い糸条からなり、前記強化繊維用緯糸と同方向に延びかつ前記強化繊維用経糸に対して前記強化繊維用緯糸の反対側に配列された補助緯糸と、
前記強化繊維用経糸より細い糸条からなり、前記強化繊維用経糸と同方向に延びかつ前記強化繊維用経糸同士の間に配列され、前記強化繊維用緯糸に係合した状態での折り返し及び前記補助緯糸に係合した状態での折り返しが混在した状態で配列された補助経糸と
を備えている織物基材に樹脂を含浸させてなる繊維強化複合材料。
A plurality of warp yarns for reinforcing fibers which are made of fiber bundles and arranged straight in parallel with each other;
A plurality of weft yarns for reinforcing fibers which are made of fiber bundles and arranged in parallel to each other and straight in the direction intersecting with the warp yarns for reinforcing fibers;
An auxiliary weft consisting of a thread thinner than the reinforcing fiber weft, extending in the same direction as the reinforcing fiber weft and arranged on the opposite side of the reinforcing fiber weft with respect to the reinforcing fiber warp;
The reinforcing fiber warp is made of a thread that is thinner than the reinforcing fiber warp, extends in the same direction as the reinforcing fiber warp, and is arranged between the reinforcing fiber warps. A fiber-reinforced composite material obtained by impregnating a fabric base material with an auxiliary warp arranged in a mixed state of folding in a state of being engaged with auxiliary wefts.
JP2011196328A 2011-09-08 2011-09-08 Woven fabric base material and fiber-reinforced composite material Withdrawn JP2013057143A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103753828A (en) * 2013-12-30 2014-04-30 广东生益科技股份有限公司 Electronic-grade glass fiber cloth and copper-clad plate taking electronic-grade glass fiber cloth as reinforcing material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103753828A (en) * 2013-12-30 2014-04-30 广东生益科技股份有限公司 Electronic-grade glass fiber cloth and copper-clad plate taking electronic-grade glass fiber cloth as reinforcing material

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