JP2013051092A5 - - Google Patents

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JP2013051092A5
JP2013051092A5 JP2011187887A JP2011187887A JP2013051092A5 JP 2013051092 A5 JP2013051092 A5 JP 2013051092A5 JP 2011187887 A JP2011187887 A JP 2011187887A JP 2011187887 A JP2011187887 A JP 2011187887A JP 2013051092 A5 JP2013051092 A5 JP 2013051092A5
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Japan
Prior art keywords
positive electrode
metal
oxygen
binder
storage material
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JP2011187887A
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Japanese (ja)
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JP5373869B2 (en
JP2013051092A (en
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Priority claimed from JP2011187887A external-priority patent/JP5373869B2/en
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Publication of JP2013051092A5 publication Critical patent/JP2013051092A5/ja
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Claims (6)

酸素貯蔵材料、導電助剤、及び結着剤を含む混合物からなるとともに酸素を活物質とする正極と、金属リチウムを活物質とする負極と、該正極及び該負極に挟持された電解質層と、前記正極内で前記酸素貯蔵材料及び前記導電助剤とともに三相界面を形成する電解液とを備える金属酸素電池において、
前記結着剤は、伸縮性を有するとともに該電解液に浸透可能な高分子からなり、
前記正極は、前記結着剤に前記導電助剤が分散された高分子複合体からなるとともに前記酸素貯蔵材料の表面を被覆する被覆膜を備えることを特徴とする金属酸素電池。
A positive electrode comprising an oxygen storage material, a conductive additive, and a binder and oxygen as an active material; a negative electrode comprising metal lithium as an active material; and an electrolyte layer sandwiched between the positive electrode and the negative electrode; In a metal oxygen battery comprising an electrolyte that forms a three-phase interface with the oxygen storage material and the conductive additive in the positive electrode,
The binder is made of a polymer having elasticity and penetrating into the electrolyte solution,
The metal positive electrode is characterized in that the positive electrode includes a coating film that is made of a polymer composite in which the conductive additive is dispersed in the binder and covers the surface of the oxygen storage material.
請求項1記載の金属酸素電池において、
前記正極に対する前記酸素貯蔵材料の含有量は、40〜98質量%の範囲であることを特徴とする金属酸素電池。
In the metal oxygen battery of claim 1 Symbol placement,
Content of the said oxygen storage material with respect to the said positive electrode is the range of 40-98 mass%, The metal oxygen battery characterized by the above-mentioned.
請求項1又は請求項2記載の金属酸素電池において、
前記酸素貯蔵材料は、YMnOで表される複合金属酸化物であることを特徴とする金属酸素電池。
The metal oxygen battery according to claim 1 or 2 ,
The metal oxygen battery, wherein the oxygen storage material is a composite metal oxide represented by YMnO 3 .
請求項1乃至請求項のいずれか1項記載の金属酸素電池において、
前記結着剤は、カルボキシメチルセルロースであることを特徴とする金属酸素電池。
The metal oxygen battery according to any one of claims 1 to 3 ,
The metal oxygen battery, wherein the binder is carboxymethyl cellulose.
酸素貯蔵材料、導電助剤、及び結着剤を含む混合物からなるとともに酸素を活物質とする正極と、金属リチウムを活物質とする負極と、該正極及び該負極に挟持された電解質層と、前記正極内で前記酸素貯蔵材料及び前記導電助剤とともに三相界面を形成する電解液とを備える金属酸素電池の製造方法において、
前記結着剤として、伸縮性を有するとともに前記電解液に浸透可能な高分子を用い、該結着剤と該導電助剤と水とを混合し、スラリー状高分子複合体を得る工程と、
該スラリー状高分子複合体と前記酸素貯蔵材料とを混合し、前記混合物を得る工程と、
該混合物を基板に塗布する工程と、
該基板に塗布された混合物を乾燥して前記正極を形成する工程と
を備えることを特徴とする金属酸素電池の製造方法。
A positive electrode comprising an oxygen storage material, a conductive additive, and a binder and oxygen as an active material; a negative electrode comprising metal lithium as an active material; and an electrolyte layer sandwiched between the positive electrode and the negative electrode; In a method for producing a metal oxygen battery comprising an electrolyte solution that forms a three-phase interface with the oxygen storage material and the conductive additive in the positive electrode,
Using the polymer having elasticity and penetrating into the electrolytic solution as the binder, mixing the binder, the conductive auxiliary agent and water to obtain a slurry polymer composite;
Mixing the slurry-like polymer composite and the oxygen storage material to obtain the mixture;
Applying the mixture to a substrate;
And a step of drying the mixture applied to the substrate to form the positive electrode.
請求項記載の金属酸素電池の製造方法において、
前記スラリー状高分子複合体の粘度は、0.01〜100Pa・sの範囲であることを特徴とする金属酸素電池の製造方法。
In the manufacturing method of the metal oxygen battery of Claim 5 ,
The slurry-like polymer composite has a viscosity in the range of 0.01 to 100 Pa · s.
JP2011187887A 2011-08-30 2011-08-30 Metal oxygen battery Expired - Fee Related JP5373869B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2011187887A JP5373869B2 (en) 2011-08-30 2011-08-30 Metal oxygen battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2011187887A JP5373869B2 (en) 2011-08-30 2011-08-30 Metal oxygen battery

Publications (3)

Publication Number Publication Date
JP2013051092A JP2013051092A (en) 2013-03-14
JP2013051092A5 true JP2013051092A5 (en) 2013-05-16
JP5373869B2 JP5373869B2 (en) 2013-12-18

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Family Applications (1)

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JP2011187887A Expired - Fee Related JP5373869B2 (en) 2011-08-30 2011-08-30 Metal oxygen battery

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JP (1) JP5373869B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5276203B2 (en) * 2011-09-07 2013-08-28 本田技研工業株式会社 Metal oxygen battery
JP5393748B2 (en) * 2011-09-14 2014-01-22 本田技研工業株式会社 Metal oxygen battery

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007157445A (en) * 2005-12-02 2007-06-21 Toshiba Battery Co Ltd Air cell
JP5023936B2 (en) * 2006-10-06 2012-09-12 株式会社豊田中央研究所 Cathode catalyst and lithium-air secondary battery
US9209503B2 (en) * 2010-07-01 2015-12-08 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials
US8658319B2 (en) * 2010-07-01 2014-02-25 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials

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