JP2013049867A5 - Cellulose acetate - Google Patents

Cellulose acetate Download PDF

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Publication number
JP2013049867A5
JP2013049867A5 JP2012259798A JP2012259798A JP2013049867A5 JP 2013049867 A5 JP2013049867 A5 JP 2013049867A5 JP 2012259798 A JP2012259798 A JP 2012259798A JP 2012259798 A JP2012259798 A JP 2012259798A JP 2013049867 A5 JP2013049867 A5 JP 2013049867A5
Authority
JP
Japan
Prior art keywords
cellulose acetate
substitution
glucose unit
ppm
average degree
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2012259798A
Other languages
Japanese (ja)
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JP5570580B2 (en
JP2013049867A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2012259798A priority Critical patent/JP5570580B2/en
Priority claimed from JP2012259798A external-priority patent/JP5570580B2/en
Publication of JP2013049867A publication Critical patent/JP2013049867A/en
Publication of JP2013049867A5 publication Critical patent/JP2013049867A5/en
Application granted granted Critical
Publication of JP5570580B2 publication Critical patent/JP5570580B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Claims (5)

グルコース単位の6−位のアシル基平均置換度が0.91〜1.0であり、残存硫酸量が
10〜150ppmであり、かつ粘度平均重合度が230〜380であるセルロースアセ
テート。
A cellulose acetate having a degree of acyl substitution at the 6-position of glucose unit of 0.91 to 1.0, a residual sulfuric acid content of 10 to 150 ppm, and a viscosity average degree of polymerization of 230 to 380.
グルコース単位の2−位、3−位及び6−位のアシル基平均置換度が下記式(I)及び(I
I)を満足し、残存硫酸量が20〜130ppmである請求項1記載のセルロースアセテ
ート。
DS2+DS3≧1.95 (I)
DS6≧0.91 (II)
(式中、DS2はグルコース単位の2−位のアシル基平均置換度、DS3はグルコース単
位の3−位のアシル基平均置換度、DS6はグルコース単位の6−位のアシル基平均置換
度を示す)
The average degree of substitution of acyl groups at 2-position, 3-position and 6-position of glucose unit is represented by the following formulas (I) and (I)
The cellulose acetate according to claim 1, which satisfies I) and has a residual sulfuric acid content of 20 to 130 ppm.
DS2 + DS3 1.9 1.95 (I)
DS6 0.9 0.91 (II)
(Wherein, DS2 represents the average degree of substitution of acyl groups at 2-position of glucose unit, DS3 represents the degree of average substitution of acyl groups at 3-position of glucose unit, and DS6 represents the average degree of substitution of acyl groups at 6-position of glucose unit )
カルシウム含量10〜110ppm、残存硫酸量25〜110ppm、残存硫酸に対す
るカルシウムの化学当量比0.5〜3.0、および平均酢化度58〜62.5%のセルロ
ーストリアセテートである請求項2記載のセルロースアセテート。
Cellulose triacetate having a calcium content of 10 to 110 ppm, a residual sulfuric acid content of 25 to 110 ppm, a chemical equivalent ratio of calcium to residual sulfuric acid of 0.5 to 3.0, and an average degree of acetylation of 58 to 62.5%. Cellulose acetate.
請求項1〜3のいずれかに記載のセルロースアセテートで構成されているセルロースアセテートフィルム。   The cellulose acetate film comprised with the cellulose acetate in any one of Claims 1-3. 液晶表示装置用光学補償フィルム又は偏光板の保護フィルムである請求項4記載のセル
ロースアセテートフィルム。
The cellulose acetate film according to claim 4, which is a protective film for an optical compensation film for a liquid crystal display device or a polarizing plate.
JP2012259798A 2012-11-28 2012-11-28 Cellulose acetate Expired - Lifetime JP5570580B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012259798A JP5570580B2 (en) 2012-11-28 2012-11-28 Cellulose acetate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012259798A JP5570580B2 (en) 2012-11-28 2012-11-28 Cellulose acetate

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2004275758A Division JP5465368B2 (en) 2004-09-22 2004-09-22 Cellulose ester and method for producing the same

Publications (3)

Publication Number Publication Date
JP2013049867A JP2013049867A (en) 2013-03-14
JP2013049867A5 true JP2013049867A5 (en) 2014-02-27
JP5570580B2 JP5570580B2 (en) 2014-08-13

Family

ID=48012136

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2012259798A Expired - Lifetime JP5570580B2 (en) 2012-11-28 2012-11-28 Cellulose acetate

Country Status (1)

Country Link
JP (1) JP5570580B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6820858B2 (en) * 2015-10-08 2021-01-27 株式会社ダイセル Cellulose Acetate, Cellulose Acetate Manufacturing Method and Equipment
JP6160751B1 (en) * 2016-08-12 2017-07-12 富士ゼロックス株式会社 Method for producing cellulose acylate
JP7162292B2 (en) * 2018-06-12 2022-10-28 国立大学法人北海道大学 Cellulose acetate, cellulose acetate fiber, cellulose acetate composition, method for producing cellulose acetate, and method for producing cellulose acetate composition

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57207601A (en) * 1981-06-15 1982-12-20 Daicel Chem Ind Ltd Aging method of cellulose acetate
JPS6017441B2 (en) * 1981-07-10 1985-05-02 ダイセル化学工業株式会社 New method for producing cellulose acetate
JPH0632801A (en) * 1992-05-26 1994-02-08 Eastman Kodak Co Preparation of cellulose ester
JPH09255701A (en) * 1996-03-22 1997-09-30 Daicel Chem Ind Ltd Production of cellulose ester
JP3895801B2 (en) * 1996-04-19 2007-03-22 ダイセル化学工業株式会社 Cellulose ester with excellent solubility
JP4136054B2 (en) * 1997-03-19 2008-08-20 ダイセル化学工業株式会社 Cellulose acetate and dope containing the same
JP3727755B2 (en) * 1997-06-17 2005-12-14 富士写真フイルム株式会社 Cellulose acetate film, method for producing the same, and polarizing plate protective film
JP4016565B2 (en) * 1999-03-03 2007-12-05 コニカミノルタホールディングス株式会社 Optical film made of cellulose ester film, polarizing plate
JP4207379B2 (en) * 2000-10-20 2009-01-14 コニカミノルタホールディングス株式会社 Polarizing plate protective film, method for producing the same, polarizing plate and liquid crystal display device
JP2003055466A (en) * 2001-08-15 2003-02-26 Fuji Photo Film Co Ltd Method for producing cellulose acylate solution and cellulose acylate film
KR101057509B1 (en) * 2003-02-25 2011-08-17 다이셀 가가꾸 고교 가부시끼가이샤 Cellulose esters with improved wet heat stability
JP5465368B2 (en) * 2004-09-22 2014-04-09 株式会社ダイセル Cellulose ester and method for producing the same

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