JP2013030435A - Chemiluminescent device and its light-emitting method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a chemiluminescent device capable of emitting light for a long time by performing chemiluminescence by mixing two kinds of liquids simply and surely, and increasing the freedom of design on the shape of an outer container, and its light-emitting method.SOLUTION: The chemiluminescent device 1 is provided with an outer container 20 of hard resin having translucency, an inner container 30 having bursting performance with a first liquid agent filled, and an impact transmission member 40 which is arranged between the outer container 20 and the inner container 30 and formed in a spherical shape. A second liquid agent which makes chemiluminescence by mixing with the first liquid agent is sealed between the outer container 20 and the inner container 30. When an impact force is applied on a position of the outer container 20 corresponding to the impact transmission member 40, the inner container 30 is Hertz-destroyed and the first liquid agent flows into the outer container 20 and is mixed with the second liquid agent. Since it is not necessary to bend the outer container 20, the outer container 20 can be made into an arbitrary shape.

Description

  The present invention relates to a chemiluminescent device that emits chemiluminescence by mixing a first liquid agent stored in an inner container and a second liquid agent stored between an inner container and an outer container, and a method for emitting the same. It is.

  As a conventional chemiluminescent device, a first liquid agent is sealed in an inner container, a second liquid agent is inserted between the inner container and the outer container, and the inner container is broken by bending the elongated rod-shaped outer container. And what mix | blends a 1st liquid agent and a 2nd liquid agent and chemiluminescent is known. This conventional chemiluminescent tool is widely used as a toy for concerts and festivals, emergency lights, and fishing gear.

  Moreover, what was described in patent document 1 is known as another conventional chemiluminescent tool, for example. The light-emitting element based on the chemiluminescence method described in Patent Document 1 is a sealed sachet made of a thin film of aluminum foil for storing an oxalate solution, and is composed of a sachet provided with a polymer such as polyolefin inside. A first container, a second container enclosing the first container, containing an activating solution and composed of a sealed translucent polymer film, and manually operated by a user It is provided with a ball capable of making a hole in the inner sachet (first container).

Special table 2003-532253 gazette

  However, in the conventional chemiluminescent device in which the outer container is bent to break the inner container and the two liquids are mixed, it is not possible to easily emit light with a thickness that makes it difficult to bend the rod-shaped outer container. In addition, if the outer container is a disc shape, it is more difficult to bend if the thickness is a thin disc shape. Therefore, the volume of the liquid agent for increasing the thickness of the outer container and the inner container to increase the light emission, increasing the light emission time, and not only making the outer container shape a very thick rod, but also making it a thin disk shape Can not do it.

  Moreover, in the light emitting element based on the chemiluminescence method described in Patent Document 2, since the outer container and the inner container are made of a soft material, when the hole is opened in the inner pouch while pushing the sphere, The inner container is bent and difficult to operate. If too much pressure is applied, the internal liquid may leak from the sealed portion of the outer container.

  Therefore, the present invention provides a chemiluminescent device that can easily and reliably mix two liquids and cause chemiluminescence to emit light for a long time or to increase the degree of design freedom for the shape of the outer container. And it aims at providing the light-emission method.

  The chemiluminescent device of the present invention includes a breakable inner container in which a first liquid agent is sealed, and the second container that contains the inner container and chemiluminescent when mixed with the first liquid agent. An outer container made of translucent hard resin enclosed between the inner container and the impact container applied between the outer container and the inner container and applied to the outer container. And an impact transmission member for transmitting and destroying the inner container by Hertz.

  Further, the light emitting method of the chemiluminescent device of the present invention houses the breakable inner container in which the first liquid agent is enclosed, and the second liquid agent that chemiluminescents when mixed with the first liquid agent An outer container made of light-transmitting hard resin enclosed between the inner container and an impact on the position of the outer container corresponding to the impact transmission member disposed between the outer container and the inner container A step of transmitting the impact force to the outer container by the impact transmitting member to break the inner container, and a first liquid agent that has flowed out due to the breakage of the inner container. And chemiluminescence mixing with the second liquid agent sealed between the outer container and the outer container.

  According to the present invention, when an impact force is applied to the position of the outer container corresponding to the impact transmission member disposed between the outer container and the inner container, the impact force to the outer container is transmitted by the impact transmission member to the inner side. The container is broken by Hertz destruction. Due to the breakage of the inner container, the first liquid agent that has flowed out due to the breakage of the inner container is mixed with the second liquid agent sealed between the inner container and the outer container to cause chemiluminescence. Since Hertz breaks from the outer surface of the inner container to which an impact force is applied, it is not necessary to bend the outer container even if the outer container is made of a hard resin in order to break the inner container. Therefore, even if the outer container is not bent, the inner container can be broken only by applying an impact force to a part of the outer container, and the two liquids can be mixed. Can do. Moreover, since an inner container can be broken regardless of the shape of an outer container, an outer container can be made into arbitrary shapes.

  It is preferable that a convex portion is provided on the outer surface of the outer container so as to correspond to the position where the impact transmission member is disposed. When the impact force is applied to the outer surface of the outer container, the impact force is concentrated on the convex portion by applying the impact force to the convex portion, so that a larger impact force can be applied to the impact transmission member. The inner container can be broken. Moreover, the position which gives an impact force can be confirmed from an external appearance by providing the convex part.

It is desirable that a concave portion for restricting the movement of the impact transmission member is provided on the inner side surface of the outer container.
The recess provided on the inner surface of the outer container regulates the movement of the impact transmission member, so that the impact transmission member can move inside the outer container due to vibration or swinging, and the impact force can be transmitted to the inner container. It can be prevented from disappearing.

It is desirable that a concave portion for restricting movement of the end portion of the inner container is provided on the inner side surface of the outer container on the inner surface opposite to the position where the impact transmission member is disposed.
The concave portion provided on the inner side surface of the outer container regulates the movement of the end of the inner container, so that the inner container moves inside the inner container due to vibration or other factors, and the impact force of the impact transmitting member is reduced. It is possible to prevent the transmission to the inner container.

  If the body portion of the outer container is provided with an expansion / contraction portion formed in a bellows structure, even if the total length of the inner container and the impact transmission member is longer than the depth in the storage direction of the outer container, the expansion and contraction is performed. When the portion extends, the inner container and the impact transmission member can be accommodated in the outer container.

  The inner container is formed of a glass container in which a thread groove is formed in an opening filled with the first liquid agent, and a lid portion in which a screw thread that is screwed into the thread groove is formed and the opening is closed. It is desirable. By doing so, the commercial item with which the 1st liquid agent was enclosed as an inner side container can be used as it is.

  In the present invention, the inner container can be broken only by applying an impact force to a part of the outer container without bending the outer container, and the two liquids can be mixed. Therefore, the two liquids can be easily and reliably mixed to cause chemiluminescence to be emitted for a long period of time, and the design flexibility of the shape of the outer container can be expanded.

It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 1 of this invention. (A) And (B) is a figure for demonstrating the manufacturing method of the chemiluminescent tool shown in FIG. (A) And (B) is a figure for demonstrating the use condition of the chemiluminescent tool shown in FIG. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 2 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 3 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 6 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 7 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 8 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 9 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 10 of this invention. It is sectional drawing which shows the chemiluminescent tool which concerns on Embodiment 11 of this invention.

(Embodiment 1)
A chemiluminescent tool according to Embodiment 1 of the present invention will be described with reference to the drawings.
The chemiluminescent tool 10 shown in FIG. 1 emits chemiluminescence by mixing the first liquid L1 and the second liquid L2. The chemiluminescent device 10 shown in FIG. 1 includes an outer container 20, an inner container 30, and an impact transmission member 40.
The outer container 20 is a container made of a hard resin formed in a substantially cylindrical shape having watertightness by closing both ends. The outer container 20 can be formed of, for example, PE (polyethylene) or PP (polypropylene).

  A convex portion 50 is provided on the outer surface of the outer container 20 so as to correspond to the position where the impact transmission member 40 is disposed. In the present embodiment, since the outer shape of the outer container 20 is formed in a substantially cylindrical shape, the impact transmission member 40 is arranged on one side of the outer container 20 and the inner container 30 is arranged on the other side. A convex portion 50 is provided on one end surface which is the bottom surface of the container 20. Since the projecting portion 50 is directly impacted, a hard body having high impact resistance is desirable, and for example, a ceramic or metal disk can be used. The convex portion 50 can be affixed with an adhesive or an adhesive tape having both surfaces as an adhesive surface after the outer container 20 is molded. However, when the outer container 20 made of hard resin is molded, It is also possible to integrally form the outer container 20 by embedding the portion.

The inner container 30 is a container formed in a substantially cylindrical shape having water tightness by being closed at both ends and having breakability. The inner container 30 can be formed of glass or the like, for example.
The impact transmission member 40 is a hard body disposed between the outer container 20 and the inner container 30. The impact transmission member 40 may be spherical, cylindrical, prismatic, conical, pyramidal or the like if it is rigid, or may have a different shape if the side in contact with the inner container 30 is sharp. it can. When the impact transmitting member 40 is conical or pyramidal, it is desirable that the top apex is directed toward the inner container 30 and the bottom surface is directed toward the outer container 20. Examples of the material of the impact transmission member 40 include glass, ceramic, and metal.

  Here, the positional relationship among the outer container 20, the inner container 30, and the impact transmission member 40 will be described. The depth length in the storage direction inside the outer container 20 is adjusted to the total length of the inner container 30 and the impact transmission member 40. Since the outer container 20, the inner container 30, and the impact transmission member 40 are formed in this way, the impact transmission member 40 is in a state where one side is in contact with or close to the inner side surface of the outer container 20, and the other The side is in contact with or close to the outer surface of the inner container 30.

  Here, the first liquid agent L1 and the second liquid agent L2 sealed in the chemiluminescent device 10 will be described in detail. In the chemiluminescent device 10, the first liquid agent L1 and the second liquid agent L2 are separately stored. The first liquid agent L1 is sealed in the inner container 30. The second liquid agent L <b> 2 is sealed between the outer container 20 and the inner container 30.

First, the first liquid agent L1 will be described. The first liquid agent L1 is an oxidizing agent containing hydrogen peroxide as an essential component. It is desirable that the solvent contained in the oxidizing solution is not a phthalic acid compound.
Specific examples of the solvent contained in the first solution (oxidizing solution) include triethyl citrate, tributyl acetyl citrate, benzyl benzoate, 3-methoxy-3-methylbutanol, hexylene glycol, propylene glycol, butyrolactone, Polyethylene glycol, triethylene glycol, triacetin, diethylene glycol diethyl ether, sebacic acid, diethylene glycol dimethyl ether or dipropylene glycol dimethyl ether.

These are easily soluble in hydrogen peroxide as an oxidizing agent and salicylate as a catalyst, and are excellent in compatibility with a fluorescent solution containing a fluorescent substance. These solvents are used by mixing at least two kinds.
Among these, the oxidizing solution is at least one solvent (solvent A) selected from triethyl citrate, tributyl acetyl citrate and benzyl benzoate, 3-methoxy-3-methylbutanol, hexylene glycol, propylene glycol, It is preferably a mixture with at least one solvent (solvent B) selected from butyrolactone, polyethylene glycol, triethylene glycol, triacetin, diethylene glycol diethyl ether, sebacic acid, diethylene glycol dimethyl ether and dipropylene glycol dimethyl ether.

  As the solvent A, triethyl citrate and benzyl benzoate are particularly preferable, and as the solvent B, triacetin, 3-methoxy-3-methylbutanol, and hexylene glycol are particularly preferably used.

When used alone, it is compatible with hydrogen peroxide as an oxidizing agent and salicylate as a catalyst, and compatible with a fluorescent solution containing a fluorescent substance, compared to conventional lower alcohols such as ethanol and butanol. It is difficult to make an oxidizing solution equivalent to or better than solubility.
In the combination of the above solvents, the solvent A such as triethyl citrate is a main solvent of the oxidizing solution, and the solvent B such as 3-methoxy-3-methylbutanol and hexylene glycol has a function as an auxiliary solvent. Together, both constitute an oxidizing solution with good luminous performance.

  The quantity ratio between hydrogen peroxide and the solvent (total amount) in the oxidizing solution can be appropriately selected depending on the purpose of use, but usually the concentration of hydrogen peroxide is 0.5 to 10% by weight, preferably 3 To 6% by weight.

  In the first liquid agent (oxidizing liquid), for example, a small amount (usually 0.001) of salicylic acid and its derivatives such as lithium salicylate, lithium t-butylsalicylate, sodium salicylate, tetraalkylammonium salicylate, etc. To 0.1% by weight).

  Next, the second liquid agent L2 will be described. The second liquid agent L2 contains an oxalate ester, a fluorescent substance, and a solvent.

  As the oxalic acid ester (oxalate) used as the second liquid agent (fluorescent liquid), oxalic acid derivatives such as oxalic acid halide, oxalic acid ester, and oxalic acid oxamide can be used. (2,4,5-trichloro-6-carbobutoxyphenyl oxalate), bis (2,4,5-trichloro-6-carbopentoxyphenyl oxalate) and the like.

  The fluorescent substance is not particularly limited as long as it is a fluorescent compound having spectral emission at 300 to 1200 nm and at least partially soluble in a solvent. These fluorescent compounds include conjugated polycyclic aromatics having condensed rings such as anthracene, substituted anthracene, benzoanthracene, phenanthrene, substituted phenanthrene, naphthacene, substituted naphthacene, pentacene, substituted pentacene, perylene, substituted perylene, violanthrone, substituted violanthrone, etc. Examples are compounds. The substituent of the above compound is not particularly limited as long as it does not hinder the luminescence reaction, and examples thereof include a phenyl group, a lower alkyl group, a chloro group, a bromo group, a cyano group, an alkoxy group, and a phenylnaphthyl group.

  Specific fluorescent materials include 2-chloro-9,10-bis (4-methylethynyl) anthracene, 9,10-bis (phenylethynyl) anthracene, 1-methoxy-9,10-bis (phenylethynyl) anthracene. Perylene, 1,5-dichloro-9,10-bis (phenylethynyl) anthracene, 1,8-dichloro-9,10-bis (phenylethynyl) anthracene, monochloro and dichloro substituted 9,10-bis (phenylethynyl) Anthracene, 5,12-bis (phenylethynyl) tetracene, 9,10-diphenylanthracene, 16,17-dihexyloxyviolanthrone, 2-methyl-9,10-bis- (phenylethynyl) anthracene, 9,10- Bis- (4-methoxyphenyl) -2-chloroanthracene, 9,10-bis- (4-ethoxyphenyl) -2-chloroanthracene, 5,12-bis- (phenylethynyl) naphthacene, 5,6,11,12-tetraphenylnaphthacene (rubrene) and mixtures thereof Illustrated.

  Examples of products of these fluorescent substances include Lumogen Red (LUMOGEN RED, perylene dicarboxyimide fluorescent agent that emits red, BASF, trade name), Lumogen Yellow (LUMOGEN YELLOW, perylene dicarboxyimide fluorescent that emits yellow) Agent, BASF, trade name), Lumogen Orange (LUMOGEN ORANGE, perylene dicarboxyimide fluorescent agent that emits orange, BASF, trade name) is preferably used.

In the second liquid agent (fluorescent solution), as the solvent, acetyl tributyl citrate (ATBC), benzyl benzoate (BeB), dipropylene glycol dimethyl ether (DMM) or the like is generally used alone or in combination.
In the present invention, phthalic acid esters such as dimethyl phthalate and dibutyl phthalate are not used not only as a solvent for an oxidizing solution but also as a solvent for a fluorescent solution.

  The composition ratio of each component in the fluorescent solution can be arbitrarily selected according to the purpose to be used. In general, the amount ratio (molar ratio) between the oxalate ester and the fluorescent substance is sufficient to cause chemiluminescence, but is preferably 20: 1 to 40: 1. The amount ratio of the solvent to the oxalate can also be appropriately selected depending on the purpose of use, but the concentration of the oxalate is usually 0.01 to 0.5 mol / liter, preferably 0.05 to 0.3. An amount of solvent that will be in moles / liter is used.

  An additive such as a surfactant can be added to the oxidizing solution and the fluorescent solution as necessary. Further, the oxidizing solution and the fluorescent solution can be used by being supported on a light-emitting base material such as nonwoven fabric, work cloth, glass or plastic.

  Next, the manufacturing method of the chemiluminescent tool 10 shown in FIG. 1 will be described based on FIG. As shown in FIG. 2 (A), the convex portion 50 is provided, and the outer container 20 opened on the opposite side of the convex portion 50 is arranged in the first container in consideration of the volume of the inner container 30 and the impact transmission member 40. A solution containing a predetermined amount of the second liquid L2 is prepared. Next, after putting the impact transmission member 40 in the outer container 20 containing the second liquid agent L2, the inner container 30 enclosing the first liquid agent L1 is put. Then, as shown in FIG. 2B, a lid is thermally welded to the opening of the outer container 20 and sealed. By doing so, the inner container 30 enclosing the first liquid agent L1 and the impact transmission member 40 can be disposed in the outer container 20, and the second liquid agent L2 can be enclosed in the outer container 20. .

Next, a method of using the chemiluminescent tool 10 according to Embodiment 1 will be described based on the drawings.
As shown in FIG. 3A, first, the chemiluminescent tool 10 is held with one hand with the convex portion 50 facing down. Since the outer container 20 is provided with the convex portion 50, the position to which the impact force is applied can be confirmed from the appearance, so that the direction in which the chemiluminescent tool 10 is gripped can be easily determined.

  Next, the user strikes the convex portion 50 against the hard object K vigorously. The hard object K may be a table or a wall if the user is in the room, or may be a guardrail or a road surface if the user is on the road.

  As shown in FIG. 3B, the convex portion 50 to which the impact force is applied elastically deforms the end surface of the outer container 20 by this impact. Pressure is applied to the impact transmission member 40 because the end surface of the outer container 20 is elastically deformed. The pressure is transmitted to the inner container 30 by applying a pressure due to the elastic deformation of the outer container 20 to the impact transmitting member 40. When a large pressure is momentarily applied to the inner container 30, the end surface of the inner container 30 is cracked. In particular, since the contact area between the impact transmission member 40 and the end surface of the inner container 30 is small, the pressure from the impact transmission member 40 becomes a concentrated pressure on the end surface of the inner container 30. By applying this concentrated pressure to the end surface of the inner container 30, a conical fracture surface is generated from the outer surface on the end surface of the inner container 30. This is called a Hertzian fracture, and is a fracture phenomenon that occurs when, for example, a pistol bullet is shot into glass, unlike a phenomenon in which a crack is generated from the inner surface due to a tensile stress caused by bending.

  When the inner container 30 breaks due to Hertzian destruction, the first liquid L1 enclosed in the inner container 30 flows out and mixes with the second liquid L2 between the inner container 30 and the outer container 20. Chemiluminescence starts when the first liquid L1 and the second liquid L2 are mixed.

Thus, since the chemiluminescent tool 10 is broken from the outer surface of the inner container 30 using Hertzian destruction, there is no need to bend the outer container 20 made of hard resin in order to break the inner container 30. Only the chemiluminescent tool 10 can be held and chemiluminescent can be performed. Therefore, the inner container 30 can be broken only by applying an impact force to a part of the outer container 20 without bending the outer container 20, and the two liquids can be mixed, so that both hands cannot be used. Even so, chemiluminescence can be reliably produced by a simple operation.
In addition, since the outer container does not have to be bent, the outer container can have various shapes. Therefore, by increasing the inner volume of the outer container and the inner container, the outer container can emit light for a long period of time. The degree of freedom in designing the shape can be expanded.

(Embodiment 2)
A chemiluminescent device according to Embodiment 2 will be described with reference to FIG. In FIG. 4, the same components as those in FIG.
The outer container 21 of the chemiluminescent device 11 shown in FIG. 4 is formed in a truncated cone shape in which the cross section gradually decreases from the bottom surface side where the convex portion 50 is provided toward the tip.
A recess 21 a for restricting the movement of the impact transmission member 40 is provided on the inner surface of the outer container 21. The concave portion 21 a is provided on the side where the convex portion 50 on the inner side surface of the outer container 21 is provided. Moreover, the impact transmission member 40 is arrange | positioned in the recessed part 21a.

  As described above, the outer container 21 has a truncated conical shape and the bottom surface side is formed wide so that the impact transmission member 40 is moved by the vibration or swinging when the chemiluminescent tool 11 is moved. The movement of the impact transmission member 40 is restricted by the recess 21a even when the outer container 21 is easily moved along the width direction of the outer container 21, so that the impact transmission member 40 is detached from the end surface of the inner container 30. Can be prevented. Accordingly, since the positional relationship between the inner container 30 and the impact transmission member 40 in the outer container 21 can be maintained, the impact transmission member 40 is in contact with the inner surface of the outer container 21 and the outer surface of the inner container 30. Or in close proximity.

  Even if the outer container 21 is formed in a truncated conical shape and the outer container 21 is difficult to bend, the impact force applied to the outer container 21 is transmitted to the inner container 30 via the impact transmission member 40, Since the two liquids (the first liquid agent and the second liquid agent) can be mixed by destroying the hertz of the container 30, the two liquids can be mixed reliably.

  In addition, although the surface which the impact-transmission member 40 contacts is formed in the circular arc surface, the recessed part 21a may be a plane as long as it does not remove | deviate from the end surface of the inner side container 30, and may be a V-shaped inclined surface.

(Embodiment 3)
A chemiluminescent device according to Embodiment 3 will be described with reference to FIG. In FIG. 5, the same components as those in FIGS. 1 and 4 are denoted by the same reference numerals, and description thereof is omitted.
The outer container 22 of the chemiluminescent device 12 shown in FIG. 5 is formed in a truncated cone shape whose cross section gradually increases from the bottom surface side where the convex portion 50 is provided toward the tip.
By forming the outer container 22 into a truncated conical shape whose cross section gradually increases from the bottom surface side toward the tip, even if the outer container 22 has a shape that is difficult to bend, the outer container 22 is interposed via the impact transmission member 40. Since the impact force applied to 21 is transmitted to the inner container 30 and the inner container 30 is broken by Hertz, two liquids (the first liquid agent and the second liquid agent) can be mixed. Can be mixed.

(Embodiment 4)
A chemiluminescent tool according to Embodiment 4 will be described with reference to FIG. In FIG. 6, the same components as those in FIGS. 1 and 4 are denoted by the same reference numerals, and description thereof is omitted.
In the chemiluminescent tool 13 shown in FIG. 6, the outer container 23 is formed in a substantially disk shape whose length in the width direction is shorter than the length in the axial direction. Therefore, the inner container 31 encloses the material constituting the inner container 31 and the first liquid agent except that the axial direction is shorter and the diameter is larger than the inner container 30 of the first to third embodiments. The same as the inner container 30.

Since the outer container 23 is formed in a substantially disk shape having a thickness, it is difficult to further break the outer container 23 and break the inner container 31. However, the impact force applied to the outer container 23 is transmitted to the inner container 30 via the impact transmission member 40, and the inner container 30 is broken by Hertz, so that two liquids (first liquid agent and second liquid agent) are obtained. Since it can be made to mix, two liquids can be mixed reliably.
In the fourth embodiment, the outer container 23 is formed in a disc shape. However, the outer container 23 may have a plate shape that is polygonal in plan view. Moreover, you may provide the recessed part 21a in the inner surface of the outer side container 23 like the chemiluminescent tool 1 which concerns on Embodiment 1 shown in FIG.

(Embodiment 5)
A chemiluminescent tool according to Embodiment 5 will be described with reference to FIG. In FIG. 7, the same components as those in FIGS. 1 and 4 are denoted by the same reference numerals, and description thereof is omitted.
In the chemiluminescent device 14 shown in FIG. 7, an expansion / contraction part 24 a is provided on the body part of the outer container 24. The stretchable part 24a is formed in a bellows structure.

  In order to destroy the inner container 30 with Hertz, it is important to maintain the impact transmission member 40 in a state where it is in contact with or close to the inner surface of the outer container 21 and the outer surface of the inner container 30. However, there is a possibility that the outer container becomes long due to a manufacturing error when molding the outer container. If it does so, a clearance gap may arise between the impact transmission member 40 and the inner side surface of an outer side container, or between the impact transmission member 40 and the outer side surface of the inner side container 30, and there exists a possibility that the impact force from an outer side container cannot be transmitted to the inner side container 30. There is.

  By providing the expansion / contraction part 24a on the body part of the outer container 24, even if a slight error occurs in the length of the outer container 24 when the outer container 24 is molded, the expansion / contraction part 24a expands, so that the outer container 24 is expanded. Therefore, the inner container 30 and the impact transmission member 40 can be accommodated in the outer container 24.

(Embodiment 6)
A chemiluminescent tool according to Embodiment 6 will be described with reference to FIG. In FIG. 8, the same components as those in FIGS. 1 and 4 are denoted by the same reference numerals, and description thereof is omitted.
The chemiluminescent tool 15 shown in FIG. 8 is formed in a concave shape in which the end surface 25a of the outer container 25 (the end surface opposite to the side on which the convex portion 50 is provided) faces outward, and the concave portion 25b is provided on the inner side surface. ing. The recess 25b is formed by a circular wall surface.

  Since the end surface 25a of the outer container 25 is formed in a concave shape facing outward, even if a slight error occurs in the length of the outer container 25 when the outer container 25 is molded, the concave end surface 25a of the outer container 25 is formed. Presses the end surface of the inner container 30 by the biasing force. Accordingly, the gap between the impact transmission member 40 and the inner side surface of the outer container 25 or between the impact transmission member 40 and the outer side surface of the inner container 30 can be eliminated, so that the impact force from the outer container 25 can be reliably ensured. It can be transmitted to the inner container 30 via the impact transmission member 40.

  Further, the inner container 30 is likely to be displaced from the end surface 25a due to the biasing force of the concave end surface 25a of the outer container 25. However, since the inner surface of the end surface 25a is provided with the recess 25b, the movement of the inner container 30 is performed. Is regulated. Accordingly, since the positional relationship between the inner container 30 and the impact transmission member 40 in the outer container 25 can be maintained, the impact transmission member 40 is in contact with the inner surface of the outer container 25 and the outer surface of the inner container 30. Can be maintained.

  In the sixth embodiment, the recess 25b is formed by a circular wall surface, but may be a recess 21a formed by an arc surface as shown in FIG.

(Embodiment 7)
A chemiluminescent tool according to Embodiment 7 will be described with reference to FIG. In FIG. 9, the same components as those in FIGS. 1, 4 and 8 are denoted by the same reference numerals and description thereof is omitted.
The chemiluminescent tool 16 shown in FIG. 9 is formed in a concave shape in which the end surface 26a of the outer container 26 (the end surface on the side where the convex portion 50 is provided) faces outward, and the concave portion 25b is provided on the inner side surface.
Moreover, since the end surface 26a of the outer container 26 that transmits the impact force from the convex portion 51 is formed in a concave shape and is recessed, the convex portion 51 has a thickness that protrudes outward from the recess.
By forming the outer container 26 in this way, the same effect as in the sixth embodiment can be obtained.
In other words, a concave portion facing outward is provided on one end face of the outer container, and the inner container 30 or the impact transmission member 40 is brought into close contact with the outer container by pressing the inner container 30 or the impact transmission member 40. be able to.

(Embodiment 8)
A chemiluminescent device according to Embodiment 8 will be described with reference to FIG. In FIG. 10, the same components as those in FIG.
The chemiluminescent tool 16 shown in FIG. 10 is provided with a recess 32 a on the end surface of the inner container 32 (the end surface on the side in contact with the impact transmission member 40).
By providing the recess 32 a in the inner container 32, the impact transmitting member 40 is moved along the inner surface of the outer container 20 in the width direction of the outer container 20 due to vibration or swing when the chemiluminescent tool 16 is moved. Even if it tries to move, since the movement of the impact transmission member 40 is restricted by the recess 32 a, the impact transmission member 40 can be prevented from being detached from the end face of the inner container 32. Further, since the inner container 32 has a wide area in contact with the impact transmission member 40, it is not easily displaced.

  Therefore, since the positional relationship between the inner container 32 and the impact transmission member 40 in the outer container 20 can be maintained, the impact transmission member 40 is in contact with the inner surface of the outer container 20 and the outer surface of the inner container 32. Can be maintained.

(Embodiment 9)
A chemiluminescent tool according to Embodiment 9 will be described with reference to FIG. In FIG. 11, the same components as those in FIG.
The chemiluminescent device 17 shown in FIG. 11 uses the inner container 33 as a container with a lid.
The inner container 33 is formed of a glass container 33a in which a screw groove is formed in an opening filled with the first liquid agent L1, and a lid 33b in which a screw thread that is screwed into the screw groove is formed and the opening is closed. ing. By doing so, since a bottle with a screw mouth such as a commercially available vial can be used as it is as the inner container 33, the heat sealing step of the inner container filled with the first liquid agent can be omitted.

Although the chemiluminescent tool according to the embodiment of the present invention has been described above, the present invention is not limited to the above embodiment. For example, the concave portion 21a for restricting the displacement of the impact transmission member, the concave portion 25b or the concave portion 32a for regulating the displacement of the inner container, the expansion / contraction portion 24a for increasing the manufacturing tolerance of the outer container 24, and the concave shape for pressing the inner container or the impact transmission member. The formed end surfaces 25a and 26b can be applied to the chemiluminescent devices 10 to 17 according to the first to ninth embodiments.
In the present embodiment, the oxidizing liquid is described as the first liquid L1, and the fluorescent liquid is described as the second liquid L2. However, the fluorescent liquid is referred to as the first liquid L1, and the oxidizing liquid is referred to as the second liquid L2. Also good.

  Since the chemiluminescent tool according to the present invention does not need to be bent and can be formed into a free shape, it can be widely used as a concert or festival toy, an emergency light, or a fishing tool.

10-17 Chemiluminescence tool 20-26 Outer container 21a Concave part 24a Extendable part 25a End surface 25b Concave part 30-33 Inner container 40 Shock transmitting member 50, 51 Convex part

Claims (7)

An inner container having a fracture property in which the first liquid agent is enclosed;
An outer container made of a hard resin having translucency, containing the inner container and encapsulating a second liquid agent that chemiluminescents when mixed with the first liquid agent, and the inner container;
An impact transmission member is disposed between the outer container and the inner container and transmits an impact force applied to the outer container to the inner container to destroy the inner container by Hertz. Chemiluminescent tool.   The chemiluminescent device according to claim 1, wherein a convex portion is provided on an outer surface of the outer container so as to correspond to a position where the impact transmission member is disposed.   The chemiluminescent device according to claim 1 or 2, wherein a concave portion for restricting movement of the impact transmission member is provided on an inner surface of the outer container.   The inner surface of the outer container, which is the inner surface opposite to the position where the impact transmission member is disposed, is provided with a recess for restricting the movement of the end of the inner container. The chemiluminescent device according to any one of the above.   The chemiluminescent tool according to any one of claims 1 to 4, wherein the body portion of the outer container is provided with a stretchable portion formed in a bellows structure.   The inner container is formed of a glass container in which a thread groove is formed in an opening filled with the first liquid agent, and a lid portion in which a screw thread that is screwed into the thread groove is formed and the opening is closed. The chemiluminescent tool according to any one of claims 1 to 5. A translucent container in which a second liquid agent that chemiluminescence is mixed with the inner container is contained between the inner container and the inner container having a fracture property in which the first liquid agent is encapsulated and mixed with the first liquid agent. An outer container made of a hard resin having a step of applying an impact force to the position of the outer container corresponding to an impact transmission member disposed between the outer container and the inner container;
Transmitting the impact force to the outer container by the impact transmitting member and breaking the inner container by Hertzian destruction;
And a step of mixing chemiluminescence by mixing the first liquid agent that has flowed out due to the breakage of the inner container with the second liquid agent sealed between the inner container and the outer container. The light emitting method of the light emitting tool.

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