JP2012255221A - Gloves for work and method for producing gloves for work - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide gloves for work, which maintain an anti-adhesive property, even when used for a long period, and can improve the efficiency of the work even in work for handling an adhesive tape.SOLUTION: The glove 1 for work includes a fiber-made glove body 3 for covering the hand of a wearer and a coat layer 5 laminated to at least a palm region in the outer surface of the glove body having air permeability, wherein the coat layer 5 contains a urethane resin as a main component and contains a modified silicone oil. It is preferable to adopt a non-reactive modified silicone oil such as a polyether-modified silicone as the modified silicone oil.

Description

  The present invention relates to a working glove and a manufacturing method of the working glove.

  The work gloves are used, for example, when performing packing work. As this type of work glove, there is known a work glove body in which a resin coat layer having air permeability is attached to a fiber glove body for slip prevention. However, when the adhesive surface of the adhesive tape comes into contact with the coat layer while wearing such work gloves and handling the adhesive tape or the like, the coat layer adheres to the adhesive surface. The sticking of the coat layer to the adhesive surface not only lowers the work efficiency, but also part of the coat layer is peeled off from the glove body, thereby reducing the anti-slip effect of the coat layer.

  In view of the work of handling an adhesive substance or the like, for example, one disclosed in Japanese Patent Laid-Open No. 9-132804 has been proposed. The working glove described in Japanese Patent Laid-Open No. 9-132804 is constructed by forming a surface of a glove body or a part thereof with a material obtained by coating a fluorine fiber cloth with a chemical resistant resin such as urethane resin.

  However, the work glove described in the above publication is coated with a chemical resistant resin on the fluorine fiber fabric, and when the coat layer made of the chemical resistant resin is provided on the outer surface, The adhesion (hardness to stick) is not improved. That is, when the adhesive surface of the adhesive tape comes into contact with the work gloves, the coat layer comes into contact with the adhesive surface, and the coat layer sticks to the adhesive surface. Has the problem of peeling. In addition, the fluorine fiber is expensive, and thus the work gloves are also expensive.

  In addition, the thing of Unexamined-Japanese-Patent No. 2002-105721 is proposed as a glove for handling rice. The glove described in this publication is formed by infiltrating and impregnating silicone oil into a rubber latex layer provided on the outer surface of the glove body. However, since silicone oil is infiltrated and impregnated into the already formed rubber latex layer, the silicone oil easily bleeds. This bleed silicone oil is removed from the surface by washing or the like, and this causes a problem that the adhesion of the glove is lowered, so that the adhesion to the adhesive surface of the coat layer is likely to occur due to long-term use. In addition, the bleed silicone oil has a disadvantage that it is transferred (transferred) to the gripped handling object.

JP-A-9-132804 JP 2002-105721 A

  The present invention has been made in view of these disadvantages, and a work glove that can maintain its adhesion even when used for a long period of time and can improve work efficiency even when working with an adhesive tape and the like, and its manufacture The purpose is to provide a method.

The invention made to solve the above problems is
A fiber glove body covering the wearer's hand;
A coat layer having air permeability and laminated on at least the palm region of the outer surface of the glove body,
The coat layer is a working glove containing a urethane resin as a main component and a modified silicone oil.

  Since the work gloves are provided with adhesion resistance by the modified silicone contained in the coat layer, for example, when worn when handling an adhesive tape, the coat layer is in contact with the adhesive surface of the adhesive tape. Is difficult to stick to the adhesive surface, and therefore, the work can be performed efficiently, and the coating layer can be prevented from being peeled off by sticking to the adhesive surface. Further, the modified silicone oil has high compatibility with the urethane resin due to the modified group, and exists stably in the coat layer. Since the silicone oil is stably present in the coat layer in this manner, the modified silicone oil is difficult to bleed and the adhesion can be maintained even when the work gloves are used for a long period of time.

  In the work gloves, the modified silicone oil can be configured to be a non-reactive modified silicone oil, whereby the non-reactive modified silicone oil can be used by a polar interaction with a urethane resin or the like. In addition to being able to exist stably in the coat layer, it has the advantage that the adhesion resistance is effectively exhibited.

  As the non-reactive modified silicone oil, a polyether-modified silicone can be preferably used, and the modified silicone oil can be stably present in the coat layer due to the polar interaction between the polyether group and the urethane resin. .

  In the working gloves, a configuration in which the modified silicone oil is a reactive modified silicone oil can be employed. Thereby, it can couple | bond with a urethane resin suitably by the reactive functional group which modified silicone oil has, and a modified silicone oil can exist more stably in a coat layer.

  As the reactive modified silicone oil, carbinol-modified silicone can be preferably used, and the hydroxyl group of the carbinol-modified silicone is suitably bonded to the urethane resin, so that the modified silicone oil is more stably present in the coat layer. be able to.

  Moreover, in the said work glove, it is preferable that the compounding quantity of modified | denatured silicone oil is 1 to 20 mass parts with respect to 100 mass parts of urethane resin components. If it is less than the above lower limit value, the adhesion to the adhesive surface of the adhesive tape may not be fully exhibited, and if it exceeds the above upper limit value, the tackiness between the work gloves (coat layers between This is because there is a possibility that the adhesiveness between the coat layers when they are overlapped may occur.

  Further, in the working glove, the coating layer is formed by depositing a resin composition containing a urethane resin, a modified silicone oil and a solvent on at least the palm region of the outer surface of the glove body, and depositing the resin composition. It is preferable to form by extracting a solvent from. Thereby, since a coat layer becomes porous, the air permeability of the said work glove is acquired, and it can wear easily that a hand is not easily stuffy. Further, since the modified silicone oil is contained in the resin composition forming the coating layer, the silicone oil is coated on the coating layer as compared with the case where the silicone latex is contained in the rubber latex layer already formed as in the prior art. It will exist more stably.

The present invention also provides:
A coat layer forming step of forming a coat layer on at least the palm region of the outer surface of the fiber glove body covering the wearer's hand;
The coat layer forming step
A resin composition deposition step of depositing a resin composition containing a main component urethane resin, a modified silicone oil and a solvent on the glove body;
It is a manufacturing method of the work glove which has the porous process which extracts a solvent from the deposited resin composition.

  In the working gloves manufactured by the manufacturing method, since the coat layer has air permeability, it is possible to prevent the hands from being damp even if worn for a long time, and the modified silicone oil is used as described above. Therefore, the anti-adhesion property is maintained for a long time.

  In the present invention, the “palm area” means an area (including a finger) on the inner surface when the object is grasped and extending from the wrist to the fingertip. “At least formed in the palm region” means that the coat layer is formed on the entire surface or a part of the palm region.

  As described above, in the work glove, the coating layer containing the modified silicone oil is difficult to adhere to the adhesive surface even if it comes into contact with the adhesive surface of the adhesive tape. Even when worn, the work efficiency is not lowered, the coat layer is hardly peeled off, and the modified silicone oil is stably present in the coat layer, so that the above effect is maintained for a long time.

It is explanatory drawing which looked at the wearing state of the work glove concerning one embodiment of the present invention from the front side (palm side). It is explanatory drawing which looked at the mounting state of the work glove of FIG. 1 from the back side (back side). It is the photograph of the state transferred to the transfer sheet in the transfer test.

  Hereinafter, embodiments of the present invention will be described in detail.

  A work glove 1 shown in FIGS. 1 and 2 includes a fiber glove body 3 that covers the wearer's hand, and a coat layer 5 that is laminated on the palm region of the outer surface of the glove body 3.

  The glove body 3 is knitted into a glove shape with fibers made of wooly nylon or the like, and has air permeability. In addition, the thickness of the cloth of the glove body 3 can be about 0.6 mm, and is preferably 0.2 mm or more and 1.0 mm or less, more preferably 0.4 mm or more and 0.8 mm or less at the center of the palm. This is because if it is thinner than the lower limit value, the strength of the glove body 3 is insufficient, and if it is larger than the upper limit value, workability at the time of wearing decreases. In addition, this thickness can be made into the average value of the result measured in arbitrary five places of the palm center, for example using brand name "Dial Cygness Gauge DS-1211 (made by Niigata Seiki Co., Ltd.)".

  In addition, the fiber which comprises the glove main body 3 is not limited to wooly nylon, A various fiber can be employ | adopted, for example, it can also comprise from polyester etc. In addition, as a means for forming a glove shape, for example, seamless knitting that can be knitted without a seam can be adopted.In addition, for example, a fabric that forms the upper part and a fabric that forms the palm part are sewn together into a glove shape It is also possible to provide it.

  Moreover, the sleeve part 3a of the glove body 3 has elasticity in the circumferential direction, and is thereby provided so as to be able to expand and contract in the radial direction. Further, the part of the glove body 3 closer to the fingertip than the sleeve 3a is also stretchable in the circumferential direction and provided so as to be expandable and contractable in the radial direction. Here, the sleeve part 3a has larger elasticity than the other part (the part on the fingertip side from the sleeve part 3a), and is provided so that the contraction state is smaller than the assumed wearer's wrist. Is preferable, and a higher fit can be obtained when worn.

  The coat layer 5 is formed in the palm region of the outer surface of the glove body 3. The coat layer 5 is impregnated in the glove body 3, and specifically, a liquid resin composition (coat layer forming material) that forms the coat layer 5 over the entire palm region of the glove body 3 is applied, This material is formed by solidifying. In the illustrated example, not only on the palm region of the glove body 3 but also on the outer periphery of the back region (the region on the outer surface when the object is grasped and extending from the wrist to the fingertip) that is the back side of the palm region. 2 is formed as shown in FIG. 2, but the coat layer 5 is provided in a so-called spine shape that is not formed in the central portion of the upper region. The coat layer 5 is preferably not formed on the sleeve portion 3a, but even if the coat layer 5 is formed on the upper sleeve portion 3a in the manufacturing process, it is within the range intended by the present invention.

  The coat layer 5 is mainly composed of a urethane resin and contains a modified silicone oil. The coat layer 5 is provided in a porous state and has air permeability. Here, it is preferable to employ a wet processing polyurethane solution as a material constituting the coat layer 5. As this wet processing polyurethane resin, for example, the product name Crisbon 8006HVLD (manufactured by DIC Corporation) can be used. . Thus, by using the polyurethane solution for wet processing, since this polyurethane solution for wet processing has a low viscosity, the coat layer 5 can be formed in a relatively thin layer, and the flexibility of the working glove 1 is increased. Is not disturbed. The coat layer 5 is formed by applying a coat layer forming material containing a polyurethane solution, a modified silicone oil and a solvent to the glove body, and extracting the solvent from the applied coat layer forming material. As the solvent, for example, DMF (N, N-dimethylformamide) can be used, and a solution obtained by dissolving a polyurethane resin for wet processing and a modified silicone oil in DMF can be used as a coating layer forming material.

In addition, the work gloves 1 preferably have a moisture permeability of 1000 g / m ² · 24 h to 15000 g / m ² · 24 h, more preferably 4000 g / m between the outer surface and the inner surface on the palm side. ² · 24h to 12000g / m ² · 24h or less. This is because if it is smaller than the above lower limit value, there is a possibility that the palm will be steamed if the wearer wears it for a long time. Moreover, when it provides more than the said upper limit, it is because there exists a possibility that the thickness, area, etc. of the coat layer 5 may become inadequate and sufficient grip force by the coat layer 5 may not be obtained. In addition, the said moisture permeability is a numerical value measured by JIS-L-1099A method (The moisture permeability test method of a textile product).

  As the modified silicone oil contained in the coat layer 5, a non-reactive modified silicone oil can be used, and this has the advantage that the adhesion resistance is more excellent. Although this is not always clear, the non-reactive modified silicone oil can exist stably in the coat layer due to polar interaction with the urethane resin, that is, regardless of the unreacted isocyanate group of the polyurethane resin. Since it can exist stably in the coating layer (without reacting), it is possible to make the number of isocyanate groups of the urethane resin relatively small. As a result, it is considered that the adhesion resistance is excellent.

  Non-reactive modified silicone oils include polyether modified silicone oil, methylstyryl modified silicone oil, alkyl modified silicone oil, higher fatty acid ester modified silicone oil, hydrophilic special modified silicone oil, higher fatty acid-containing silicone oil, fluorine modified Although silicone oil can be used, it is particularly preferable to use polyether-modified silicone oil. By using the polyether-modified silicone in this way, the modified silicone oil can be stably present in the coat layer due to the polar interaction between the polyether group and the urethane resin. As this polyether-modified silicone oil, for example, “DOW CORNING TORAY 8211 ADDITIVE (manufactured by Toray Dow Corning Co., Ltd.)” can be used.

  A reactive silicone oil oil can be used as the modified silicone oil. When the reactive modified silicone oil is employed, the modified silicone oil can be stably present in the coat layer by suitably bonding with the isocyanate group of the urethane resin by the reactive modifying group of the modified silicone oil. As the reactive silicone oil, amino-modified silicone oil, epoxy-modified silicone oil, carboxy-modified silicone oil, carbinol-modified silicone oil, methacryl-modified silicone oil, phenol-modified silicone oil, and different functional group-modified silicone oil can be used. In particular, it is preferable to use carbinol-modified silicone oil. Accordingly, the hydroxyl group of the carbinol-modified silicone oil is suitably bonded to the isocyanate group of the urethane resin, so that the modified silicone oil can be stably present in the coat layer.

  The modified silicone oil having a solubility parameter (SP value) of about 10 can be used, and the modified silicone oil having a solubility parameter of 9 to 11 can be suitably used. The urethane resin having a solubility parameter of about 11 is used, and the urethane resin having a solubility parameter of 10 to 12 is preferably used. Here, the solubility parameter is calculated by the method proposed by Fedors et al. In “POLYMER ENGINEERING AND SCIENCE, FEBRUARY, 1974, Vol. 14, No. 2, ROBERT F. FEDORS. It is.

  Furthermore, the blending amount of the modified silicone oil is preferably 1 part by mass or more and 20 parts by mass or less, and more preferably 5 parts by mass or more and 10 parts by mass or less with respect to 100 parts by mass of the urethane resin component. This is because if it is less than the lower limit, the adhesion to the adhesive surface of the adhesive tape may not be fully exhibited. On the other hand, when the above upper limit is exceeded, there is a possibility that tackiness between the work gloves (adhesiveness between the coat layers when the coat layers are overlapped) may occur. When the product is stored in a packaging bag, this product (a pair of working gloves) is purchased, and the purchaser opens the packaging bag, the pair of left and right working gloves are attached to each other. This may cause discomfort to the purchaser.

  In the working glove 1 having the above-described configuration, the coat layer 5 is provided on the outer surface of the glove body 3, and the fibers of the glove body 3 are not exposed. The force can be exerted and the object to be grasped can be securely grasped. In addition, since the work glove 1 is provided with adhesion resistance by the modified silicone contained in the coat layer 5, when the work glove 1 is worn when performing an operation for handling the adhesive tape, it comes into contact with the adhesive surface of the adhesive tape. Also, the coat layer 5 is difficult to stick to the adhesive surface, so that the work can be performed efficiently. Moreover, since the coat layer 5 is excellent in adhesion resistance, peeling of the coat layer 5 due to sticking to the adhesive surface can be prevented. In particular, the modified silicone oil has high compatibility with the urethane resin due to the modified group, and exists more stably in the coat layer 5. Furthermore, since the modified silicone oil is contained in the coating layer forming material, the silicone oil is more stable in the coating layer 5 than in the case where the silicone oil is permeated and contained in the coating layer already formed as in the past. Exists. As described above, the silicone oil is stably present in the coat layer 5, so that the silicone oil is difficult to bleed. For this reason, even if the said working glove 1 is washed, silicone oil is hard to be removed, and even if the said working glove 1 is used for a long period of time, adhesion prevention is maintained. Further, since the silicone oil is difficult to bleed as described above, it is difficult for the silicone oil to transfer (transfer) to an object handled by wearing the work glove 1.

  Further, in the work glove 1, the coat layer 5 is made porous and has air permeability, so that it is hard to get stuffy and comfortable to wear.

  Next, although the manufacturing method of the working gloves 1 of the present embodiment having the above-described configuration will be outlined, the manufacturing method of the present invention is not limited to this. Moreover, in the following description of the manufacturing method, when it overlaps with the description of the work gloves, the description may be omitted.

  The manufacturing method of the present embodiment includes a glove forming step of forming a fiber glove body 3 covering a wearer's hand, and a coat layer forming step of forming a coat layer 5 in the palm region of the formed glove body 3. Have.

  The glove forming step is a step of forming the glove body 3 by knitting into a glove shape with fibers made of woolly nylon or the like.

  Further, the coat layer forming step was applied to the glove body 3, and a coat layer material applying step for applying a coat layer forming material containing a main component urethane resin, a modified silicone oil and a solvent, to the glove body. And a porous process for extracting the solvent of the coating layer forming material.

  The coating layer material application step is a step of covering the glove body 3 in a three-dimensional shape and immersing the palm region of the glove body 3 in the coating layer forming material. As this coating layer forming material, for example, a polyurethane resin for wet processing such as trade name Crisbon 8006HVLD (manufactured by DIC Corporation) is dissolved in a solvent such as DMF and a modified silicone oil is added thereto. .

  In the porous forming step, the glove body 3 is bathed in a hot water for a predetermined time or more to replace the solvent in the coat layer forming material immersed in the glove body 3 with water, and then dried to make the coat layer 5 porous. It is a process to convert.

  According to the said method, the said working glove 1 which has the said advantage can be manufactured.

  In addition, this invention can be implemented in the aspect which gave various change and improvement other than the said aspect.

  That is, in the above-described embodiment, the coating layer is formed over the entire palm region of the glove body 3, but it is also possible to provide the coating layer only on a part of the palm region. It is also possible to provide the above-mentioned coat layer only on the fingertip portion. More specifically, for example, a coat layer may be provided on the palm region and the instep region of the fingertip portion of the glove body 3 to form a so-called finger-sack-like coat layer. it can. In addition, it is possible to change the design as appropriate to form a coat over a wide area or the entire area of the upper area as well as the palm area.

  EXAMPLES Hereinafter, although this invention is demonstrated concretely based on an Example, this invention is not limited to these Examples.

[Example 1]
A polyurethane resin solution was prepared by mixing 100 parts by mass of wet processing polyurethane resin (“Crisbon 8006HVLD” manufactured by DIC Corporation) and 200 parts by mass of N, N-dimethylformamide (DMF). Further, a polyether-modified silicone oil ("DOW CORNING TORAY 8211 ADDIIVE" manufactured by Toray Dow Corning Co., Ltd.) as a modified silicone oil is added to 100 parts by mass of the polyurethane resin component so that the active ingredient is 5 parts by mass. Was formed as a coating layer forming material.

  A glove body was prepared by knitting 280 denier wooly nylon using a 13 gauge glove knitting machine (“trade name N-SFG” manufactured by Shima Seiki Co., Ltd.).

  The glove body thus created was placed on a dipping hand mold and dipped in a coating layer forming material. The glove body infiltrated with the coating layer forming material was immersed in a hot water bath at 50 ° C. for 60 minutes, then dried at 120 ° C. for 20 minutes, and the gloves of Example 1 were produced by removing the gloves from the hand mold.

[Example 2]
As a modified silicone oil for the coating layer forming material, a reactive carbinol-modified silicone oil ("DOW CORNING TORAY SF8427" manufactured by Toray Dow Corning Co., Ltd.) added to the active ingredient so as to be 5 parts by mass is used. Obtained a glove of Example 2 in the same manner as Example 1.

[Comparative Example 1]
A glove of Comparative Example 1 was obtained in the same manner as in Example 1 except that the coating layer forming material not containing silicone oil was used.

[Comparative Example 2]
Example 1 except that a straight silicone oil ("DOW CORNING TORAY SH200" manufactured by Toray Dow Corning Co., Ltd.) was added as an active ingredient so as to be 5 parts by mass instead of the modified silicone oil of the coating layer forming material. In the same manner as described above, a glove of Comparative Example 2 was obtained.

<Evaluation>
The following evaluation was performed on the manufactured gloves (Example 1, Example 2, Comparative Example 1 and Comparative Example 2).

(Adhesion performance)
In the adhesion prevention performance test, an adhesive tape was pressure-bonded to an 80 × 25 mm portion of a test piece cut out from the produced glove for 1 hour with a force of 0.01 kg / cm ² , and then peeled off by 70 mm at a tensile speed of 300 mm / min. The average stress at the time was measured. The evaluation of the anti-adhesion performance of the measurement results was judged as follows from the correlation with the workability when the adhesive tape was actually attached to the hand and handled.
A: Adhesion performance (average stress less than 1.8 (N))
B: Slight adhesion performance (average stress 1.8 (N) or more and less than 2.0 (N))
C: No adhesion prevention performance (average stress of 2.0 (N) or more)

  As shown in Table 1, the gloves of Examples 1 and 2 have a smaller average stress value than Comparative Examples 1 and 2, and exhibit excellent adhesion performance.

(Durability of adhesion prevention performance)
The glove 1 was washed with water 30 (mass ratio) for 30 minutes and then dried. For the gloves thus washed and dried, the same test as the above-mentioned adhesion performance test was performed. That is, an adhesive tape was pressure-bonded to an 80 × 25 mm portion of a test piece cut out from a glove, and an average stress when the adhesive tape was peeled off by 70 mm at a tensile speed of 300 mm / min was measured. The evaluation of the adhesion performance (sustainability of adhesion performance) of this measurement result was also based on the same evaluation criteria as the above adhesion performance test.

  As shown in Table 2, the gloves of Example 1 and Example 2 have smaller average stress values than Comparative Examples 1 and 2, and excellent adhesion performance is maintained.

(Transferability)
In the transferability test, the forefinger was pressed against the transfer sheet in a state where the produced glove was attached to the hand, and the presence or absence of transfer to the pressed portion was visually confirmed. The transfer sheet is used to check the presence / absence of bleed according to the presence / absence of transfer, and when transferred, the transfer can be visually observed (see FIG. 3). Transferability was evaluated visually.

  As shown in Table 3, Example 1 and Example 2 did not cause transfer unlike Comparative Example 2 containing silicone oil.

[Examples 1-1 to 1-4]
Gloves of Examples 1-1 to 1-4 were obtained in the same manner as in Example 1 except that the content of the polyether-modified silicone oil was changed. For 100 parts by mass of the polyurethane resin component, polyether-modified silicone oil is an active ingredient, 0.5 parts by mass for Example 1-1, 1 part by mass for Example 1-2, and Example 1-3. Was formed as a coating layer forming material by adding 20 parts by mass, and for Examples 1-4, the added solution was 30 parts by mass.

<Evaluation>
The following evaluation was performed together with Example 1 for the manufactured gloves (Examples 1-1 to 1-4).

(Protection performance and tackiness)
For the adhesion performance, a test similar to the above-described adhesion performance test was performed. In addition, the tackiness was determined by determining whether or not the finished gloves were overlapped so that the coat layers were in contact with each other, and there was adhesiveness that would cause the gloves to stick together.
Adhesion property A: Adhesion performance (average stress less than 1.8 (N))
B: Slight adhesion performance (average stress 1.8 (N) or more and less than 2.0 (N))
C: No adhesion prevention performance (average stress of 2.0 (N) or more)
Tackiness A: No tackiness B: Some tackiness C: Some tackiness

  As shown in Table 4, it is clear that Examples 1-2 to 1-4 and Example 1 are excellent in adhesion prevention, and Examples 1-1 to 1-3 and Example 1 are excellent in tackiness. became.

  As described above, the work gloves of the present invention can be worn and used by an operator in, for example, a factory.

1 Work Gloves 3 Glove Body 3a Sleeve 5 Coat Layer

Claims (8)

A fiber glove body covering the wearer's hand;
A coat layer having air permeability and laminated on at least the palm region of the outer surface of the glove body,
A work glove in which the coat layer contains a urethane resin as a main component and a modified silicone oil.   The work glove according to claim 1, wherein the modified silicone oil is a non-reactive modified silicone oil.   The work glove according to claim 2, wherein the non-reactive modified silicone oil contains a polyether-modified silicone.   The work glove according to claim 1, wherein the modified silicone oil is a reactive modified silicone oil.   The work glove according to claim 4, wherein the reactive modified silicone oil contains carbinol-modified silicone.   The work glove according to any one of claims 1 to 5, wherein a blending amount of the modified silicone oil is 1 part by mass or more and 20 parts by mass or less with respect to 100 parts by mass of the urethane resin component.   The coat layer is formed by applying a resin composition containing a urethane resin, a modified silicone oil and a solvent to at least the palm region of the outer surface of the glove body, and extracting the solvent from the applied resin composition. The work glove according to any one of claims 1 to 6. A coat layer forming step of forming a coat layer on at least the palm region of the outer surface of the fiber glove body covering the wearer's hand;
The coat layer forming step
A resin composition deposition step of depositing a resin composition containing a main component urethane resin, a modified silicone oil and a solvent on the glove body;
The manufacturing method of the work glove which has the porous process which extracts a solvent from the deposited resin composition.