JP2012250353A5 - - Google Patents
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- JP2012250353A5 JP2012250353A5 JP2011122102A JP2011122102A JP2012250353A5 JP 2012250353 A5 JP2012250353 A5 JP 2012250353A5 JP 2011122102 A JP2011122102 A JP 2011122102A JP 2011122102 A JP2011122102 A JP 2011122102A JP 2012250353 A5 JP2012250353 A5 JP 2012250353A5
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- film
- curable composition
- meth
- acrylate
- active energy
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Description
本発明の要旨とするところは、四官能以上の（メタ）アクリレート（Ａ１）、パーフルオロポリエーテル（メタ）アクリレート（Ｂ１）、有機溶剤（Ｃ１）及び光重合開始剤（Ｄ１）を含有する紫外線硬化性組成物（１）をフィルム基材の上に塗布して、塗膜中の有機溶剤（Ｃ１）を揮発させた後に紫外線を照射することにより硬化させて得られる０．２〜１．５μｍの離型層がフィルム基材上に形成された離型フィルムを第１の発明とする。 The gist of the present invention is an ultraviolet ray containing a tetrafunctional or higher functional (meth) acrylate (A1), a perfluoropolyether (meth) acrylate (B1), an organic solvent (C1) and a photopolymerization initiator (D1). the curable composition (1) was applied onto the film substrate, that is obtained by curing by irradiation with ultraviolet rays was volatilized organic solvent in the coating film (C1) 0. A release film in which a release layer of 2 to 1.5 μm is formed on a film substrate is defined as a first invention.
また、本発明の要旨とするところは、下記（イ）〜（ハ）の工程を有する、樹脂基材の表面にパーフルオロポリエーテル（メタ）アクリレート（Ｂ２）を含む活性エネルギー線硬化性組成物（２）の硬化被膜が積層された樹脂積層体の製造方法を第２の発明とする。
（イ）四官能以上の（メタ）アクリレート（Ａ１）、パーフルオロポリエーテル（メタ）アクリレート（Ｂ１）、有機溶剤（Ｃ１）及び光重合開始剤（Ｄ１）を含有する紫外線硬化性組成物（１）をフィルム基材の上に塗布して、塗膜中の有機溶剤（Ｃ１）を揮発させた後に紫外線を照射することにより硬化させて得られる０．２〜１．５μｍの膜厚の離型層がフィルム基材上に形成された離型フィルムの離型層の面と樹脂基材とを、パーフルオロポリエーテル（メタ）アクリレート（Ｂ２）を含む活性エネルギー線硬化性組成物（２）の塗膜を介して、積層して得られる活性エネルギー線硬化性組成物（２）の塗膜含有積層体形成工程
（ロ）活性エネルギー線硬化性組成物（２）の塗膜含有積層体に活性エネルギー線を照射して活性エネルギー線硬化性組成物（２）の硬化被膜を形成させる活性エネルギー線硬化性組成物（２）の硬化被膜含有積層体形成工程
（ハ）活性エネルギー線硬化性組成物（２）の硬化被膜含有積層体から離型フィルムを剥離する剥離工程
Moreover, the gist of the present invention is that the active energy ray-curable composition containing perfluoropolyether (meth) acrylate (B2) on the surface of the resin base material, having the following steps (a) to (c). The manufacturing method of the resin laminated body in which the cured film of (2) was laminated | stacked is made into 2nd invention.
(A) An ultraviolet curable composition (1) containing a tetrafunctional or higher functional (meth) acrylate (A1), a perfluoropolyether (meth) acrylate (B1), an organic solvent (C1) and a photopolymerization initiator (D1). ) On a film substrate, volatilizes the organic solvent (C1) in the coating film, and then cured by irradiating with ultraviolet rays to obtain a mold release having a film thickness of 0.2 to 1.5 μm layer the surface and the resin base of the release layer material of the release film formed on the film substrate, a perfluoro polyether (meth) active energy ray-curable composition comprises an acrylate (B2) of (2) A coating-film-containing laminate forming step of the active energy ray-curable composition (2) obtained by laminating through the coating film (b) active in the coating-film-containing laminate of the active energy ray-curable composition (2) Irradiate energy rays to activate energy -A cured film-containing laminate forming step of the active energy ray-curable composition (2) for forming a cured film of the ray-curable composition (2) (c) A cured film containing the active energy ray-curable composition (2) Peeling process to peel the release film from the laminate
Claims (4)
（イ）四官能以上の（メタ）アクリレート（Ａ１）、パーフルオロポリエーテル（メタ）アクリレート（Ｂ１）、有機溶剤（Ｃ１）及び光重合開始剤（Ｄ１）を含有する紫外線硬化性組成物（１）をフィルム基材の上に塗布して、塗膜中の有機溶剤（Ｃ１）を揮発させた後に紫外線を照射することにより硬化させて得られる０．２〜１．５μｍの膜厚の離型層がフィルム基材上に形成された離型フィルムの離型層の面と樹脂基材とを、パーフルオロポリエーテル（メタ）アクリレート（Ｂ２）を含む活性エネルギー線硬化性組成物（２）の塗膜を介して、積層して得られる活性エネルギー線硬化性組成物（２）の塗膜含有積層体形成工程
（ロ）活性エネルギー線硬化性組成物（２）の塗膜含有積層体に活性エネルギー線を照射して活性エネルギー線硬化性組成物（２）の硬化被膜を形成させる活性エネルギー線硬化性組成物（２）の硬化被膜含有積層体形成工程
（ハ）活性エネルギー線硬化性組成物（２）の硬化被膜含有積層体から離型フィルムを剥離する剥離工程 The cured film of the active energy ray-curable composition (2) containing the perfluoropolyether (meth) acrylate (B-2) is laminated on the surface of the resin base material, which includes the following steps (a) to (c). A method for producing a resin laminate.
(A) An ultraviolet curable composition (1) containing a tetrafunctional or higher functional (meth) acrylate (A1), a perfluoropolyether (meth) acrylate (B1), an organic solvent (C1) and a photopolymerization initiator (D1). ) is applied on top of the film substrate, that obtained ultraviolet cured by irradiating the was volatilized organic solvent in the coating film (C1) 0. And a release layer surface and the resin base material of the release film a release layer is formed on a film substrate having a thickness of 2～1.5Myuemu, including perfluoropolyether (meth) acrylate (B2) Step of forming coating film-containing laminate of active energy ray curable composition (2) obtained by laminating through coating film of active energy ray curable composition (2) (b) Active energy ray curable composition Formation of cured film-containing laminate of active energy ray-curable composition (2) in which the coating film-containing laminate of (2) is irradiated with active energy rays to form a cured film of the active energy ray-curable composition (2) Step (c) Peeling step of peeling the release film from the cured film-containing laminate of the active energy ray curable composition (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011122102A JP5737573B2 (en) | 2011-05-31 | 2011-05-31 | Release film and method for producing resin laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011122102A JP5737573B2 (en) | 2011-05-31 | 2011-05-31 | Release film and method for producing resin laminate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012250353A JP2012250353A (en) | 2012-12-20 |
| JP2012250353A5 true JP2012250353A5 (en) | 2014-06-19 |
| JP5737573B2 JP5737573B2 (en) | 2015-06-17 |
Family
ID=47523648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011122102A Expired - Fee Related JP5737573B2 (en) | 2011-05-31 | 2011-05-31 | Release film and method for producing resin laminate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5737573B2 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014041940A1 (en) | 2012-09-14 | 2014-03-20 | 富士フイルム株式会社 | Curable composition and image-forming method |
| JP6122368B2 (en) * | 2013-09-24 | 2017-04-26 | リンテック株式会社 | Release sheet and adhesive sheet |
| KR101900742B1 (en) | 2014-05-30 | 2018-09-20 | 미쯔비시 케미컬 주식회사 | Resin product |
| JP2016124294A (en) * | 2014-12-26 | 2016-07-11 | 三菱化学株式会社 | Laminate and display body cover |
| WO2016175054A1 (en) * | 2015-04-28 | 2016-11-03 | デクセリアルズ株式会社 | Active energy ray-curable resin composition, antifogging antifouling laminate, article, method for producing same, and antifouling method |
| JP2017030347A (en) | 2015-04-28 | 2017-02-09 | デクセリアルズ株式会社 | Active-energy-ray curable resin composition, antifogging antifouling laminate, product and method for producing the same, and antifouling method |
| CN108431081A (en) * | 2015-12-22 | 2018-08-21 | 索尔维特殊聚合物意大利有限公司 | Purposes of certain (complete) perfluoroalkyl polyether polymer derivants as the additive in clear coating composition |
| JP6496066B1 (en) * | 2017-11-20 | 2019-04-03 | 日東電工株式会社 | Reinforcement film |
| JP7008277B2 (en) * | 2018-02-06 | 2022-01-25 | 大日本印刷株式会社 | A peeling sheet and a method for manufacturing a decorative board using the peeling sheet. |
| JP7248716B2 (en) * | 2021-02-09 | 2023-03-29 | 株式会社ネオス | Coating agent for release film, release film, article, and method for producing release film |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2952769B1 (en) * | 1998-03-30 | 1999-09-27 | 株式会社麗光 | Heat-resistant film with excellent dimensional stability and method for producing the same |
| JP4151370B2 (en) * | 2002-10-07 | 2008-09-17 | 東レ株式会社 | Release film |
| JP5144318B2 (en) * | 2008-03-13 | 2013-02-13 | 三菱レイヨン株式会社 | Manufacturing method of laminated resin plate |
-
2011
- 2011-05-31 JP JP2011122102A patent/JP5737573B2/en not_active Expired - Fee Related
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