JP2012239995A - Electret filter medium - Google Patents

Electret filter medium Download PDF

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JP2012239995A
JP2012239995A JP2011113432A JP2011113432A JP2012239995A JP 2012239995 A JP2012239995 A JP 2012239995A JP 2011113432 A JP2011113432 A JP 2011113432A JP 2011113432 A JP2011113432 A JP 2011113432A JP 2012239995 A JP2012239995 A JP 2012239995A
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filter medium
electret
web
filter
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Makoto Inoue
誠 井上
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Toyobo Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide an electret filter medium which develops stable collection efficiency while maintaining general filter properties such as pressure drops, filtering efficiency and strength of an air filter.SOLUTION: In the electret filter medium used for the pleat type filter unit that develops 50%-99% of the JIS 11 type colorimetry method collection efficiency at the initial stage among the performance evaluation methods defined by JIS B 9908:2001, it is characterized by bonding a sheet (A) which can be electretted with a web (B) that contains a short fiber which can be electretted. The portion (B layer)composing the short fiber that can be electretted after the heat pressure welding satisfies the following requirements (a)-(c): (a) the bulk density is 0.03-0.20 g/cmand the thickness is 1.5 mm or less, (b) the bending rebound property by the Gurley method is 100-500 mg and (c) the attachment amount of an oil agent is 0.1 wt.% or less.

Description

本発明は、エアフィルターユニット、主に空調用、エアコン用に使用可能なフィルターユニットに用いられるろ材に関するものであって、特にJIS B 9908:2001のうち形式2が適用されるやや微細な粉塵用フィルターユニットに使用されるろ材に関するものである。   TECHNICAL FIELD The present invention relates to an air filter unit, mainly for air conditioning, and a filter medium used for a filter unit that can be used for an air conditioner, and particularly for slightly fine dust to which type 2 of JIS B 9908: 2001 is applied. The present invention relates to a filter medium used for a filter unit.

エレクトレットろ材は、該ろ材を構成する繊維に半永久的に固定された電荷の静電気力によって空気中の微粒子を効果的に除去できるものであり、空調用、エアコン用、空気清浄機用フィルター、OA機器などの排気フィルターユニットに使用されている。こうした分野ではフィルターユニットの圧力損失を低く抑えつつ、大気中の微粒子を効率よく捕集する必要があるため、ろ材をジグザグに折り畳んでひだを構成したプリーツ状フィルターとして使用される。一方エレクトレットとして使用される繊維状不織布としてはメルトブロー不織布や薄物スパンボンド不織布、薄型スパンレース不織布があるが、剛性が低いためひだ折り加工しにくいという問題があった。こうした問題を解決する方法として、薄いポリプロピレンメルトブロー不織布と太繊度の芯鞘繊維で構成された繊維ウェブを積層、加熱して剛性の高い部分と荷電が可能な部分で構成される積層型のろ材が考案されている(特許文献1)。   The electret filter medium can effectively remove fine particles in the air by the electrostatic force of electric charges semi-permanently fixed to the fibers constituting the filter medium, and is used for air conditioning, air conditioning, air purifier filters, OA equipment. Used in exhaust filter units. In such fields, it is necessary to efficiently collect fine particles in the atmosphere while keeping the pressure loss of the filter unit low, so it is used as a pleated filter in which the filter medium is folded in a zigzag to form pleats. On the other hand, as the fibrous nonwoven fabric used as the electret, there are a melt blown nonwoven fabric, a thin spunbond nonwoven fabric, and a thin spunlace nonwoven fabric. As a method for solving such a problem, a laminated filter medium composed of a thin polypropylene melt blown nonwoven fabric and a fiber web composed of core-sheath fibers having a large fineness, and a heated portion that is highly rigid and a portion that can be charged is used. It has been devised (Patent Document 1).

また、機械的強度向上のためにエレクトレット化した不織布に合成繊維の網状物を熱接着させた積層型ろ材が考案されている(特許文献2)。こうした熱接着型の積層ろ材は、あらかじめエレクトレット化させた薄手の不織布と剛性のある基材と接合するため熱によって除電され、エレクトレットによる除塵効率が低下することがある。   In addition, a multilayer filter medium has been devised in which a synthetic fiber network is thermally bonded to an electret nonwoven fabric to improve mechanical strength (Patent Document 2). Such a heat-bonded laminated filter medium is bonded to a thin non-woven fabric that has been electretized beforehand and a rigid base material, so that it is neutralized by heat, and the dust removal efficiency by the electret may decrease.

また、エレクトレット可能な薄手の不織布と機械的強度のある部材をあらかじめ熱接着した後に荷電されることがあるが、部材に含まれる油剤などの有機成分がエレクトレット可能な不織布に作用してエレクトレット化を阻害する問題が生じていた。また、エレクトレットを疎外する油剤については加熱処理後の油剤付着量の減少率が60%以上であるポリオレフィン系熱融着繊維を用いたエレクトレット不織布の記載がある(特許文献3)。この文献では加熱により油剤が減少することでエレクトレット特性が得られて粉塵捕集効率が高いことが記載されているが、実際にフィルター用のろ材としての特性と具体的な大気中の捕集条件については何ら言及されていない   In addition, a thin non-woven fabric that can be electret and a member with mechanical strength may be charged after being thermally bonded in advance, but organic components such as oil agents contained in the member act on the non-woven fabric that can be electret. There was a problem to block. Moreover, about the oil agent which alienates an electret, there exists description of the electret nonwoven fabric using the polyolefin-type heat-fusion fiber whose reduction rate of the oil agent adhesion amount after heat processing is 60% or more (patent document 3). Although this document describes that electret characteristics are obtained by reducing the oil agent by heating and dust collection efficiency is high, the characteristics as filter media for filters and the specific collection conditions in the atmosphere There is no mention about

特開昭62−83017号公報JP-A-62-83017 特開平1−194912号公報JP-A-1-194912 特開2002−339256号公報JP 2002-339256 A

本発明はエアフィルターの圧力損失、粉塵捕集効率や強度といった一般的なフィルター特性を維持しつつ、安定した捕集効率を発現できるエレクトレットろ材を提供する。   The present invention provides an electret filter medium capable of expressing stable collection efficiency while maintaining general filter characteristics such as pressure loss, dust collection efficiency and strength of an air filter.

本発明はかかる問題点に鑑み、鋭意検討した結果得られたものである。すなわち、本発明は以下の通りである。
(1)エレクトレットろ材、特にJIS B 9908:2001で規定されている性能評価方法のうち、初期におけるJIS11種比色法捕集効率が50%から99%を発現するプリーツ型フィルターユニットに用いられるエレクトレットろ材において、エレクトレット可能なシート(A)とエレクトレット可能な短繊維ウェブ(B)とを加熱圧接により接合したエレクトレットろ材であり、かつ加熱圧接後における短繊維ウェブを構成する部位(B層)が以下の(ア)〜(ウ)の要件を満たすエレクトレットろ材。
(ア)ろ材の嵩密度が0.03〜0.20g/cmであり、かつ厚みが1.5mm以下であること。
(イ)ガーレ法における曲げ反発性が100〜500mgであること。
(ウ)油剤の付着量が0.1重量%以下であること。
(2)エレクトレット可能な短繊維を含むウェブにおいて、該ウェブを構成するエレクトレット可能な繊維はポリオレフィン系熱融着繊維であって、該熱融着繊維を60〜100重量%含む上記(1)に記載のエレクトレットろ材。
The present invention has been obtained as a result of intensive studies in view of such problems. That is, the present invention is as follows.
(1) Electret filter media, particularly electrets used in pleated filter units that exhibit 50% to 99% JIS11 colorimetric collection efficiency in the early stage of the performance evaluation method defined in JIS B 9908: 2001 In the filter medium, an electret filter medium in which the electret-capable sheet (A) and the electret-capable short fiber web (B) are joined by heat-pressure welding, and the portion (B layer) constituting the short-fiber web after heat-pressure welding is as follows: An electret filter medium that satisfies the requirements of (a) to (c).
(A) The bulk density of the filter medium is 0.03 to 0.20 g / cm 3 and the thickness is 1.5 mm or less.
(B) The bending resilience in the Gurley method is 100 to 500 mg.
(C) The amount of oil applied is 0.1% by weight or less.
(2) In the web containing short fibers that can be electret, the electret fibers constituting the web are polyolefin heat-sealing fibers, and the heat-sealing fibers are contained in 60 to 100% by weight in the above (1) The electret filter medium described.

本発明により、エアフィルターの圧力損失、粉塵捕集効率や強度といった一般的なフィルター特性を維持しつつ、フィルターの製造や使用時に必要である適度な強度を得ることが出来、かつ安定した捕集効率を得ることが出来る。   According to the present invention, while maintaining general filter characteristics such as pressure loss, dust collection efficiency and strength of an air filter, it is possible to obtain an appropriate strength necessary for manufacturing and using the filter, and stable collection. Efficiency can be obtained.

以下、本発明を詳細に説明する。
本発明はエレクトレットろ材、特にJIS B 9908:2001で規定されている性能評価方法のうち、初期におけるJIS11種比色法捕集効率が50%から99%を発現するプリーツ型フィルターユニットに用いられるエレクトレットろ材に適用される。該ろ材はエレクトレット可能なシート(A)とエレクトレット可能な短繊維を含むウェブ(B)とを加熱圧接により接合したエレクトレットろ材であることが特徴であり、具体的には加熱圧接後のエレクトレット可能な短繊維を構成する部位(B層)が以下の(ア)〜(ウ)の要件を満たなくてはならない。
(ア)嵩密度が0.03〜0.20g/cmであり、かつ厚みが1.5mm以下であること。
(イ)ガーレ法における曲げ反発特性が100〜500mgであること。
(ウ)油剤の付着量が0.1重量%以下であること。
また本発明を実現するには、ウェブを構成するエレクトレット可能な短繊維がポリオレフィン系熱融着繊維であり、ウェブは該熱融着繊維を60〜100重量%含むことが必要である。
Hereinafter, the present invention will be described in detail.
The present invention relates to an electret filter medium, particularly an electret used for a pleated filter unit in which the initial JIS11 colorimetric collection efficiency is 50% to 99% of the performance evaluation method defined in JIS B 9908: 2001. Applied to filter media. The filter medium is characterized in that it is an electret filter medium in which an electret-capable sheet (A) and a web (B) containing electret-capable short fibers are joined by heat-pressure welding. Specifically, the electret after heat-pressure welding is possible. The site | part (B layer) which comprises a short fiber must satisfy the requirements of the following (a)-(c).
(A) The bulk density is 0.03 to 0.20 g / cm 3 and the thickness is 1.5 mm or less.
(B) The bending repulsion characteristic in the Gurley method is 100 to 500 mg.
(C) The amount of oil applied is 0.1% by weight or less.
Moreover, in order to implement | achieve this invention, the electret short fiber which comprises a web is a polyolefin-type heat-fusion fiber, and a web needs to contain 60-100 weight% of this heat-fusion fiber.

本発明におけるエレクトレットろ材においては、エレクトレット可能なシート(A層)とエレクトレット可能な短繊維ウェブ(B層)とを加熱圧接により接合したことを特徴とするエレクトレットろ材である。この場合、エレクトレット可能なシート(A層)とはポリピロピレン、ポリエチレン、ポリ−3−メチル−1−ブテン、ポリ−4−メチル−1−ペンテン、ポリフッ化ビニリデン、ポリカーボネートを成分とする繊維を糸状にして織布や編地にしたものやスパンボンド、メルトブロー不織布、バインダーと共に抄紙した湿式紙状物などがあげられるが、プリーツ型フィルターとしての加工性や荷電特性、通気性などを考慮するとポリオレフィン系、例えばポリプロピレン繊維、ポリエチレン/ポリプロピレンの熱融着繊維をもとにしたスパンボンド不織布、ポリプロピレンのメルトブロー不織布が好適に用いられる。   In the electret filter medium in the present invention, the electret filter medium is characterized in that an electret-capable sheet (A layer) and an electret-capable short fiber web (B layer) are joined by heat-pressure welding. In this case, the electret-capable sheet (A layer) is a fiber made of polypropylene, polyethylene, poly-3-methyl-1-butene, poly-4-methyl-1-pentene, polyvinylidene fluoride, and polycarbonate. Woven fabrics and knitted fabrics, spunbonds, melt blown nonwoven fabrics, wet papers made with binders, etc. For example, polypropylene fibers, spunbonded nonwoven fabrics based on polyethylene / polypropylene heat-bonded fibers, and polypropylene meltblown nonwoven fabrics are preferably used.

また、もう一方のエレクトレット可能な短繊維を含むウェブ(B)とは上述のエレクトレット可能な繊維を原綿として公知の方法で解繊し、カードにかけてレイヤーにしたものである。この場合のエレクトレット可能な繊維はポリオレフィン系熱融着繊維であり、該熱融着繊維を含んだウェブ(B)とエレクトレット可能なシート(A)を積層し、加熱により圧接することによって得られる。この場合、加熱圧接後における短繊維ウェブを構成する部位(B層)については、嵩密度がろ材の持つ粉塵捕集効率と通気抵抗のバランスおよびろ材の加工性を考慮した場合、0.03〜0.20g/cm、好ましく0.04〜0.18g/cmである。嵩密度が0.03g/mより小さい場合、繊維の量が少ない為エレクトレット後の粉塵捕集効率が低下し、0.20g/cmより高い場合、ろ材の空気抵抗が高くフィルターユニットにした場合の圧力損失が高くなり、かつ粉塵保持量が小さくなり、いずれも好ましくない。 Further, the other web (B) containing short fibers that can be electret is obtained by defibrating the above-mentioned electret fibers as a raw cotton by a known method and putting it on a card to form a layer. The electretable fiber in this case is a polyolefin-based heat-sealing fiber, and is obtained by laminating the web (B) containing the heat-sealing fiber and the electretable sheet (A) and pressing them by heating. In this case, about the site | part (B layer) which comprises the short fiber web after heat press-contacting, when considering the balance of the dust collection efficiency and ventilation resistance which a bulk density has, and the workability of a filter medium, 0.03- 0.20 g / cm 3, preferably 0.04~0.18g / cm 3. When the bulk density is smaller than 0.03 g / m 3 , the amount of fibers is small, so the dust collection efficiency after electret is lowered. When the bulk density is higher than 0.20 g / cm 3 , the air resistance of the filter medium is high and the filter unit is made. In some cases, the pressure loss increases, and the dust holding amount decreases, which is not preferable.

厚みについてはプリーツ後のフィルターユニットの圧力損失に大きく影響するため、1.5mm以下、好ましく1.4mm以下に調整される。厚みが1.5mmより大きい場合、プリーツ後のフィルターユニットにおける通気時の構造抵抗が増加するため圧力損失が大きくなり、好ましくない。さらに、本発明における加熱圧接後の部位のガーレ法における曲げ反発特性が100〜500mg、好ましくは120〜480mgであることが適度なプリーツ加工性を維持する上で必要である。曲げ反発特性が100mgより低い場合、ろ材の曲げ強度が低下するのでプリーツ加工時にきれいな山状のプリーツが形成されず、いびつな形状を形成する。反対に500mgより大きい場合、強度が高いためプリーツ加工時に折り曲げることが出来ず、頂点がいびつな形状に形成されるため、いずれも好ましくない。   Since the thickness greatly affects the pressure loss of the filter unit after pleating, it is adjusted to 1.5 mm or less, preferably 1.4 mm or less. When the thickness is larger than 1.5 mm, the structural resistance at the time of ventilation in the filter unit after pleating increases, so that the pressure loss increases, which is not preferable. Furthermore, it is necessary for maintaining the appropriate pleating processability that the bending repulsion characteristics in the Gurley method of the portion after heating and pressure welding in the present invention is 100 to 500 mg, preferably 120 to 480 mg. When the bending resilience characteristic is lower than 100 mg, the bending strength of the filter medium is lowered, so that a beautiful mountain-shaped pleat is not formed at the time of pleating, and an irregular shape is formed. On the other hand, if it is larger than 500 mg, the strength is high and it cannot be bent during pleating, and the apex is formed in an irregular shape.

本発明においては加熱圧接後における短繊維ウェブを構成する部位(B層)に含まれる油剤の付着量が0.1重量%以下であることがプリーツ型フィルターユニット用におけるエレクトレットろ材において必要な捕集性能を得る上で重要である。短繊維不織布に使用される原綿にはカード時に発生する静電気を抑制してウェブ形成性を安定化するために有機成分が主である油剤が含有されている。こうした油剤はウェブの形成を安定化する反面、シート化後に荷電処理を行いエレクトレット化した場合においても抑制する効果を有する。したがって本発明における油剤の付着量は部位(B層)の全重量に対して0.1重量%以下であることが必要な荷電効果を得る上で重要である。油剤の付着量が0.1重量%より多い場合、仮に荷電されても電荷が安定せず、必要な粉塵捕集効率を得ることが出来なくなり、好ましくない。   In the present invention, it is necessary for the electret filter medium for the pleated filter unit that the amount of the oil agent contained in the portion (B layer) constituting the short fiber web after heating and pressure welding is 0.1% by weight or less. It is important in obtaining performance. The raw cotton used for the short fiber nonwoven fabric contains an oil mainly composed of organic components in order to stabilize the web-forming property by suppressing static electricity generated during carding. While such an oil agent stabilizes the formation of the web, it has an effect of suppressing even when electretized by performing a charging process after forming into a sheet. Therefore, the adhesion amount of the oil agent in the present invention is important for obtaining a charging effect that is required to be 0.1% by weight or less with respect to the total weight of the part (B layer). When the amount of the oil agent adhered is more than 0.1% by weight, the charge is not stable even if it is charged, and the required dust collection efficiency cannot be obtained, which is not preferable.

なお、こうしたエレクトレットろ材を得るためにはエレクトレットが可能な素材、特にポリオレフィン系の成分でポリオレフィン系熱融着繊維を60〜100重量%含む熱融着された不織布であることが必要である。ポリオレフィン系の熱融着繊維の含有率が60重量%より低い場合、必要な荷電効果が得られず、かつシートとして必要な強度が得られないため好ましくない。   In order to obtain such an electret filter medium, it is necessary to be a non-woven fabric that can be electretized, particularly a heat-bonded non-woven fabric containing 60 to 100% by weight of a polyolefin-based heat-bonding fiber with a polyolefin-based component. When the content of the polyolefin-based heat-fusible fiber is lower than 60% by weight, a necessary charging effect cannot be obtained, and a necessary strength as a sheet cannot be obtained.

本発明を実現するための具体的な製造方法について説明する。本発明、特にエレクトレット可能な短繊維を含むウェブ(B)については、ポリプロピレンを芯にポリエチレンを鞘に構成される芯鞘繊維を用い、公知の方法でウェブ化することが融着特性と工程の合理性の観点から好適に用いられる。該芯鞘繊維はシートの強度と圧力損失を考慮した場合、2.2〜22dtexの繊維を用いることが好ましく、それより繊度の大きいものである場合、難燃剤が含有した場合の融着強度が低下するためシートの強度が弱くなる。また2.2dtex未満である場合、繊維直径が細くなるためにシートにした場合の圧力損失が高くなり、好ましくない。主成分のポリプロピレン繊維と接着成分としてのポリエチレンとの比率は配合の方法により様々であるが充分な接着性を得るためにはポリプロピレン(PP)繊維とポリエチレン(PE)が重量比で1:4〜4:1に調整されることが好ましい。こうしたポリオレフィン系の芯鞘繊維と他の繊維を混綿して公知の方法でカード機にかけweb状にした後、公知の方によって得られたエレクトレット可能なシート(A)とを積層し、加熱圧接を行ってろ材を製造する。特にエレクトレット可能な短繊維を含むウェブ(B)については、ポリオレフィン系の芯鞘繊維と混綿する他の繊維はシートに要求される機能に応じて選択される。例えば、抗菌、高カビ性や難燃性を付与したい場合はこうした機能を持つ公知の添加剤が添加された繊維をエレクトレット性が損なわない程度に混ぜてもよい。   A specific manufacturing method for realizing the present invention will be described. In the present invention, in particular, the web (B) containing short fibers that can be electreted, a core-sheath fiber composed of polypropylene as a core and polyethylene as a sheath is used to form a web by a known method. It is preferably used from the viewpoint of rationality. When considering the strength and pressure loss of the sheet, the core-sheath fiber is preferably a fiber of 2.2 to 22 dtex, and if the fiber has a fineness greater than that, the fusion strength when the flame retardant is contained is The strength of the sheet is weakened due to the decrease. Moreover, when it is less than 2.2 dtex, since the fiber diameter becomes thin, the pressure loss at the time of making it into a sheet becomes high, and it is not preferable. The ratio of the main component polypropylene fiber to polyethylene as an adhesive component varies depending on the blending method, but in order to obtain sufficient adhesion, polypropylene (PP) fiber and polyethylene (PE) are in a weight ratio of 1: 4 to It is preferably adjusted to 4: 1. After blending these polyolefin-based core-sheath fibers and other fibers into a web using a known method, laminating the electret-capable sheet (A) obtained by a known method, and applying heat-pressure welding Go to produce filter media. Particularly for the web (B) containing short fibers that can be electreted, other fibers mixed with the polyolefin-based core-sheath fibers are selected according to the function required of the sheet. For example, in order to impart antibacterial properties, high moldability and flame retardancy, fibers to which known additives having such functions are added may be mixed to such an extent that electret properties are not impaired.

エレクトレット可能な短繊維を含むウェブ(B)を製造する方法は公知の方法でよいが取扱性を向上させるため、例えばカードwebをニードルパンチにかける方法、カードwebを水流によって交絡させラフなシートを構成したのち(A)と積層して加熱圧着する方法を用いても良い。しかしながら必要な強度を得るためには積層した各層を、熱融着繊維の鞘成分の融点以上の温度で十分に熱が行き渡る時間、具体的には10〜60秒間ヒートスルーオーブンで加熱して鞘部を融解させて繊維間接着をする必要がある。この場合、必要とされる厚みにするためにはwebを交絡した不織布を所定のギャップに調整したネットに挟み込んで加熱圧接することで可能となる。また、webを交絡した不織布をオーブンで加熱させた後所定のギャップに調整したプレスローラー中を通過させることによってでも可能である。プリーツろ材として必要な曲げ反発特性を得るにはB層の熱融着繊維成分が加熱された状態でA層と接合され、所定の厚みに調整して冷却させることが必要で、このような状態で厚みを調整する方法であれば特に限定されるものではない。   A known method may be used to produce the web (B) containing short fibers that can be electret. However, in order to improve handling, for example, a method in which the card web is subjected to a needle punch, a card sheet is entangled by a water flow, and a rough sheet After the configuration, a method of laminating with (A) and thermocompression bonding may be used. However, in order to obtain the required strength, the laminated layers are heated in a heat-through oven for a time during which heat is sufficiently distributed at a temperature equal to or higher than the melting point of the sheath component of the heat-sealing fiber, specifically, for 10 to 60 seconds. It is necessary to melt the part and bond between the fibers. In this case, in order to obtain the required thickness, the nonwoven fabric entangled with the web is sandwiched between the nets adjusted to a predetermined gap and heated and pressed. It is also possible to heat a nonwoven fabric entangled with a web through a press roller adjusted to a predetermined gap after heating in an oven. In order to obtain the required bending resilience characteristics as a pleated filter medium, it is necessary that the heat-bonding fiber component of the B layer is joined to the A layer in a heated state, adjusted to a predetermined thickness and cooled. If it is the method of adjusting thickness by, it will not specifically limit.

必要なエレクトレット性を得る上で必要な油剤の除去方法について説明する。油剤はシート形成後50〜80℃程度の温浴に数分間含浸して脱水することによって得られる。また連続的には未加熱のB層を温浴に通した後所定の温度で乾燥し、A層と融点以上の温度に加熱圧接して得ることも可能である。また、加熱によって油剤成分が減少する繊維(特許文献3)を用いてもよい。油剤が除去されたシートは荷電処理によって荷電され、エレクトレットフィルターろ材になる。荷電方法特に限定されるものではないがコロナ放電による方法や水などの液体を通過させて得られる方法、シートを摩擦によって静電気を発生させる方法など公知の方法でよい。   A method for removing the oil necessary for obtaining the required electret properties will be described. The oil agent is obtained by impregnating a hot bath at about 50 to 80 ° C. for several minutes after the formation of the sheet and dehydrating it. It is also possible to continuously obtain an unheated B layer by passing it through a warm bath, drying it at a predetermined temperature, and heating and pressing the A layer to a temperature not lower than the melting point. Moreover, you may use the fiber (patent document 3) from which an oil agent component reduces by heating. The sheet from which the oil agent has been removed is charged by the charging process and becomes an electret filter medium. The charging method is not particularly limited, and may be a known method such as a method using corona discharge, a method obtained by passing a liquid such as water, or a method of generating static electricity by rubbing the sheet.

次に実施例、比較例を用いて本発明を具体的に説明するが、本発明は実施例のみに限定されるものではない。なお、測定方法は下記の方法で実施した。
加熱圧着後のB層の物性評価については加熱圧着後、A層を剥し、以下に記載する(1)〜(5)の評価を行った。
(1)目付(g/m):200mm角の寸法で切り出し、秤量して寸法で除した。
(2)厚み(mm):荷重0.7kPaの厚みを読み取った。
(3)嵩密度(g/cm):目付を厚みで除した値を採用した。
(4)曲げ反発性:JIS L 1096(1990)6.20.1 A法に準拠。
(5)油剤付着量:試料2gを採取し、エタノール/メタノール:重量混合比2/1の抽出液50ccに含浸させて油剤を抽出した。抽出前後の重量を測定して単位重量あたりの抽出量(重量%)を算出した。
(6)フィルターユニットの特性
ろ材605mm巾×20m長を製造し、山高さ58mmにてひだ折りして山ピッチ6mmになる様に公知の方法でビード樹脂を25mm間隔で流し込んで成型し、プリーツを形成した。610mm角のアルミ枠材にプリーツを装填してろ材のB層が上流側になる様に測定装置に設置して圧力損失とJIS11種の初期捕集効率、粉塵保持量を測定した。測定装置はJIS B 9908(2001)の形式2に基づく装置を用いた。風量は56m/minで実施し、粉塵負荷は294Paで終了した。
Next, the present invention will be specifically described using examples and comparative examples, but the present invention is not limited to the examples. In addition, the measuring method was implemented with the following method.
Regarding the physical property evaluation of the B layer after thermocompression bonding, the A layer was peeled off after thermocompression bonding, and the following (1) to (5) were evaluated.
(1) Weight per unit area (g / m 2 ): Cut out with a size of 200 mm square, weighed and divided by the size.
(2) Thickness (mm): The thickness at a load of 0.7 kPa was read.
(3) Bulk density (g / cm 3 ): A value obtained by dividing the basis weight by the thickness was adopted.
(4) Bending resilience: Conforms to JIS L 1096 (1990) 6.20.1 A method.
(5) Oil agent adhesion amount: 2 g of a sample was collected and impregnated in 50 cc of an extract of ethanol / methanol: weight mixing ratio 2/1 to extract the oil agent. The weight before and after extraction was measured to calculate the amount of extraction (% by weight) per unit weight.
(6) Characteristics of the filter unit A filter medium of 605 mm width × 20 m length is manufactured, and bead resin is poured at a 25 mm interval and molded so as to be folded at a peak height of 58 mm to a peak pitch of 6 mm. Formed. A 610 mm square aluminum frame member was loaded with pleats and installed in a measuring apparatus so that the B layer of the filter medium was on the upstream side, and pressure loss, initial collection efficiency of JIS 11 species, and dust holding amount were measured. As the measuring apparatus, an apparatus based on type 2 of JIS B 9908 (2001) was used. The air flow was 56 m 3 / min, and the dust load was finished at 294 Pa.

以下実施例中および比較例で用いたシートの荷電方法を以下に示した。
(a)荷電装置
アース側:アルミ板に厚さ2mmのシリコンシートを敷設した。
電極側:針間隔10mmの針電極
電極−アース間距離:針先端からシリコンシートまで10mm
(b)荷電方法
印加電圧:20kV
荷電時間:30秒
The sheet charging method used in the examples and comparative examples is shown below.
(A) Charging device Ground side: A silicon sheet having a thickness of 2 mm was laid on an aluminum plate.
Electrode side: Needle electrode with 10 mm needle spacing Electrode-earth distance: 10 mm from needle tip to silicon sheet
(B) Charging method Applied voltage: 20 kV
Charging time: 30 seconds

[実施例1]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtexの短繊維、および6.6dtexの短繊維(いずれも宇部日東化成株式会社製耐熱脱油繊維HR−LE)を8:2の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層し、ニードルパンチをかけてB層とした。A、B層を積層させて上下をステンレスメッシで挟み、上下メッシュの間隔を1.0mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付107g/m、厚み1.0mmの積層ろ材を得た。該不織布を荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作しユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Example 1]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. As the A layer side, a polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared. 2.2 dtex short fibers composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio of 1: 1) and 6.6 dtex short fibers (both manufactured by Ube Nitto Kasei Co., Ltd.) Heat-resistant deoiling fiber HR-LE) was mixed at a ratio of 8: 2 and applied to a card machine to make a web. The web was continuously laminated with a cross layer, and needle punching was applied to make a B layer. Layers A and B are stacked, sandwiched between upper and lower stainless steel meshes, transported in a state where the distance between the upper and lower meshes is set to 1.0 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 107 g / A laminated filter medium with m 2 and a thickness of 1.0 mm was obtained. The nonwoven fabric was charged through a charging device to obtain an electret filter medium. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

[実施例2]
JIS B 9908:2001の形式2に準じた効率95%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付30g/m、厚み0.30m、平均繊維直径2μmのポリプロピレンのメルトブロー不織布を用意した。かたやB層としては実施1で製造したものを使用した。A、B層を積層させてステンレスメッシで挟み、上下メッシュの間隔を1.0mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付115g/m、厚み1.1mmの積層ろ材を得た。該不織布を荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作しユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Example 2]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 95% filter according to JIS B 9908: 2001 type 2. As the layer A side, a polypropylene melt-blown nonwoven fabric having a basis weight of 30 g / m 2 , a thickness of 0.30 m, and an average fiber diameter of 2 μm was prepared. As the B layer, the layer manufactured in Example 1 was used. Layers A and B are laminated and sandwiched between stainless meshes, transported in a state where the distance between the upper and lower meshes is set to 1.0 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 115 g / m 2. A laminated filter medium having a thickness of 1.1 mm was obtained. The nonwoven fabric was charged through a charging device to obtain an electret filter medium. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

[実施例3]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtexの短繊維(宇部日東化成株式会社製耐熱脱油繊維HR−LE)、および6.6dtexのポリエステル短繊維(東レ株式会社製T201)を8:2の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層し、ニードルパンチをかけてB層とした。A、B層を積層してステンレスメッシで挟み、上下メッシュの間隔を1.0mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付117g/m、厚み1.2mmの積層ろ材を得た。該不織布を荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作しユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Example 3]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. As the A layer side, a polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared. 2.2 dtex short fiber (heat-resistant deoiled fiber HR-LE made by Ube Nitto Kasei Co., Ltd.) composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio is 1: 1), and A 6.6 dtex polyester short fiber (T201 manufactured by Toray Industries, Inc.) is mixed at a ratio of 8: 2 and applied to a card machine to make a web. The web is continuously laminated with a cross layer, and a needle punch is applied to form a B layer. did. Layers A and B are laminated and sandwiched between stainless meshes, conveyed in a state where the distance between the upper and lower meshes is set to 1.0 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 117 g / m 2. A laminated filter medium having a thickness of 1.2 mm was obtained. The nonwoven fabric was charged through a charging device to obtain an electret filter medium. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

[実施例4]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtex短繊維(宇部日東化成株式会社製HR−CK)、および6.6dtexのポリエステル短繊維(東レ株式会社製T201)を8:2の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層しにドールパンチをかけてB層とした。A、B層を積層し、ステンレスメッシュで上下から挟み、上下メッシュの間隔を1.0mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付112g/m、厚み1.0mmの積層ろ材を得た。該シートを70℃に設定された温浴中に5分間含浸させよく揉んで水分が不織布中に行き渡るように洗浄し、その後脱水して油剤を除去した。油剤の除去を2回繰り返した後、乾燥させて荷電装置に通して荷電し、エレクトレットろ材を得た。
このろ材をひだ折りしてフィルターユニットを製作してユニット特性を評価したB層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Example 4]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. A polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared as the A layer side. 2.2 dtex short fibers (HR-CK manufactured by Ube Nitto Kasei Co., Ltd.) composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio is 1: 1), and 6.6 dtex polyester Short fibers (T201 manufactured by Toray Industries, Inc.) were mixed at a ratio of 8: 2 and applied to a card machine to make a web. The web was continuously laminated with a cross layer, and a doll punch was applied to form a B layer. Layers A and B are laminated, sandwiched from above and below with stainless steel mesh, transported in a state where the distance between the top and bottom mesh is set to 1.0 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 112 g / A laminated filter medium with m 2 and a thickness of 1.0 mm was obtained. The sheet was impregnated in a warm bath set at 70 ° C. for 5 minutes, thoroughly rinsed and washed so that moisture spread throughout the nonwoven fabric, and then dehydrated to remove the oil agent. After removing the oil agent twice, it was dried and charged through a charging device to obtain an electret filter medium.
The filter unit was manufactured by folding the filter medium and the unit characteristics were evaluated. Unit weight on the B layer side, thickness, bulk density, amount of oil adhesion, filter unit pressure loss, dust retention, initial JIS 11 species collection efficiency Is shown in Table 1.

[比較例1]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtexの短繊維、および6.6dtexの短繊維(いずれも宇部日東化成株式会社製耐熱脱油繊維HR−LE)を8:2の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層し、ニードルパンチをかけてB層とした。A、B層を積層させて上下をステンレスメッシで挟み、上下メッシュの間隔を2.5mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付107g/m、厚み2.5mmの積層ろ材を得た。該不織布を荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作しユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Comparative Example 1]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. As the A layer side, a polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared. 2.2 dtex short fibers composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio of 1: 1) and 6.6 dtex short fibers (both manufactured by Ube Nitto Kasei Co., Ltd.) Heat-resistant deoiling fiber HR-LE) was mixed at a ratio of 8: 2 and applied to a card machine to make a web. The web was continuously laminated with a cross layer, and needle punching was applied to make a B layer. Layers A and B are laminated and sandwiched between upper and lower stainless steel meshes, transported in a state where the distance between the upper and lower meshes is set to 2.5 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 107 g / A laminated filter medium with m 2 and a thickness of 2.5 mm was obtained. The nonwoven fabric was charged through a charging device to obtain an electret filter medium. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

[比較例2]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtexの短繊維、および6.6dtexの短繊維(いずれも宇部日東化成株式会社製耐熱脱油繊維HR−LE)を8:2の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層し、ニードルパンチをかけてB層とした。A、B層を積層させて上下をステンレスメッシで挟み、上下メッシュの間隔を0.7mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付67g/m、厚み0.8mmの積層ろ材を得た。該不織布を荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折り加工を実施したがろ材の剛性が低いためうまく加工出来なかった。
B層側の目付、厚み、嵩密度、油剤付着量を表1に示す。
[Comparative Example 2]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. As the A layer side, a polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared. 2.2 dtex short fibers composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio of 1: 1) and 6.6 dtex short fibers (both manufactured by Ube Nitto Kasei Co., Ltd.) Heat-resistant deoiling fiber HR-LE) was mixed at a ratio of 8: 2 and applied to a card machine to make a web. The web was continuously laminated with a cross layer, and needle punching was applied to make a B layer. Layers A and B are stacked and sandwiched between upper and lower stainless steel meshes, transported in a state where the distance between the upper and lower meshes is set to 0.7 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 67 g / A laminated filter medium with m 2 and a thickness of 0.8 mm was obtained. The nonwoven fabric was charged through a charging device to obtain an electret filter medium. Although this filter medium was fold-folded, it could not be processed well due to the low rigidity of the filter medium.
Table 1 shows the weight per unit area, thickness, bulk density, and oil adhesion amount.

[比較例3]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。実施例4と同じ条件で積層ろ材を得た後、洗浄せず荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作してユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Comparative Example 3]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. After obtaining a laminated filter medium under the same conditions as in Example 4, it was charged through a charging device without washing, and an electret filter medium was obtained. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

[比較例4]
JIS B 9908:2001の形式2に準じた効率90%フィルター向けのろ材として以下に記載する方法でエレクトレットろ材を製造した。A層側として目付22g/m、厚み0.23m、平均繊維直径3.5μmのポリプロピレンのメルトブロー不織布を用意した。かたやポリプロピレン(芯成分)/ポリエチレン(鞘成分)(ポリプロピレン:ポリエチレン重量比は1:1)で構成される2.2dtex短繊維(宇部日東化成株式会社製HR−CK)、および6.6dtexのポリエステル短繊維(東レ株式会社製T201)を1:1の割合で混繊してカード機にかけてwebとし、webをクロスレイヤーで連続的に積層しにドールパンチをかけてB層とした。A、B層を積層し、ステンレスメッシュで上下から挟み、上下メッシュの間隔を1.0mmに設定した状態で搬送してエアスルーオーブンに通し、温度150℃、1分間加熱融着させ、目付172g/m、厚み1.2mmの積層ろ材を得た。該シートを70℃に設定された温浴中に5分間含浸させよく揉んで水分が不織布中に行き渡るように洗浄し、その後脱水して油剤を除去した。油剤の除去を2回繰り返した後、乾燥させて荷電装置に通して荷電し、エレクトレットろ材を得た。このろ材をひだ折りしてフィルターユニットを製作してユニット特性を評価した。
B層側の目付、厚み、嵩密度、油剤付着量、フィルターユニットの圧力損失、粉塵保持量、初期におけるJIS11種捕集効率を表1に示す。
[Comparative Example 4]
An electret filter medium was manufactured by the method described below as a filter medium for an efficiency 90% filter according to JIS B 9908: 2001 format 2. As the A layer side, a polypropylene melt-blown nonwoven fabric having a basis weight of 22 g / m 2 , a thickness of 0.23 m, and an average fiber diameter of 3.5 μm was prepared. 2.2 dtex short fibers (HR-CK manufactured by Ube Nitto Kasei Co., Ltd.) composed of polypropylene (core component) / polyethylene (sheath component) (polypropylene: polyethylene weight ratio is 1: 1), and 6.6 dtex polyester Short fibers (T201 manufactured by Toray Industries, Inc.) were mixed at a ratio of 1: 1 and applied to a card machine to make a web. The web was continuously laminated with a cross layer, and a doll punch was applied to form a B layer. Layers A and B are stacked, sandwiched from above and below with stainless steel mesh, transported in a state where the distance between the top and bottom mesh is set to 1.0 mm, passed through an air-through oven, heated and fused at a temperature of 150 ° C. for 1 minute, and a basis weight of 172 g / A laminated filter medium with m 2 and a thickness of 1.2 mm was obtained. The sheet was impregnated in a warm bath set at 70 ° C. for 5 minutes, thoroughly rinsed and washed so that moisture spread throughout the nonwoven fabric, and then dehydrated to remove the oil agent. After removing the oil agent twice, it was dried and charged through a charging device to obtain an electret filter medium. This filter medium was folded and a filter unit was manufactured to evaluate the unit characteristics.
Table 1 shows the basis weight, thickness, bulk density, oil agent adhesion amount, filter unit pressure loss, dust holding amount, and initial JIS 11 species collection efficiency on the B layer side.

Figure 2012239995
Figure 2012239995

本発明のエレクトレットろ材は強度を保持する為のカバー層に荷電保持性を有することによってろ材の全体的な電荷保持性が安定し、従来にくらべて高い粉塵捕集効率を得ることが出来る。   Since the electret filter medium of the present invention has charge retention in the cover layer for maintaining strength, the overall charge retention of the filter medium is stabilized, and a higher dust collection efficiency can be obtained than in the past.

Claims (2)

JIS B 9908:2001で規定されている性能評価方法のうち、初期におけるJIS11種比色法捕集効率が50%から99%を発現するプリーツ型フィルターユニットに用いられるエレクトレットろ材において、該ろ材はエレクトレット可能なシート(A)とエレクトレット可能な短繊維を含むウェブ(B)とを加熱圧接により接合したことを特徴とするエレクトレットろ材であり、加熱圧接後のエレクトレット可能な短繊維を構成する部位(B層)が以下の(ア)〜(ウ)の要件を満たす。
(ア)嵩密度が0.03〜0.20g/cmであり、かつ厚みが1.5mm以下であること。
(イ)ガーレ法における曲げ反発特性が100〜500mgであること。
(ウ)油剤の付着量が0.1重量%以下であること。
Among the performance evaluation methods defined in JIS B 9908: 2001, in an electret filter medium used in a pleated filter unit that exhibits 50% to 99% JIS11 species colorimetric collection efficiency in the initial stage, the filter medium is an electret This is an electret filter medium characterized in that a sheet (A) capable of being electret and a web (B) containing short fibers capable of electret are joined by heat pressure welding, and a portion (B Layer) satisfies the following requirements (a) to (c).
(A) The bulk density is 0.03 to 0.20 g / cm 3 and the thickness is 1.5 mm or less.
(B) The bending repulsion characteristic in the Gurley method is 100 to 500 mg.
(C) The amount of oil applied is 0.1% by weight or less.
ウェブを構成するエレクトレット可能な短繊維はポリオレフィン系熱融着繊維であり、ウェブは該融着繊維を60〜100重量%含む請求項1に記載のエレクトレットろ材。   2. The electret filter medium according to claim 1, wherein the electret short fibers constituting the web are polyolefin heat-sealing fibers, and the web contains 60 to 100% by weight of the fusion fibers.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014117668A (en) * 2012-12-18 2014-06-30 Toyobo Co Ltd Electret filter medium
JP2014208318A (en) * 2013-04-16 2014-11-06 東洋紡株式会社 Antibacterial electret filter medium
JP2015000378A (en) * 2013-06-17 2015-01-05 倉敷繊維加工株式会社 Air filter medium, its manufacturing method, and air filter
CN105854419A (en) * 2016-05-11 2016-08-17 安徽元琛环保科技股份有限公司 Production method of electret compound filter material
WO2018105546A1 (en) * 2016-12-08 2018-06-14 東レ株式会社 Electret fiber sheet

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014117668A (en) * 2012-12-18 2014-06-30 Toyobo Co Ltd Electret filter medium
JP2014208318A (en) * 2013-04-16 2014-11-06 東洋紡株式会社 Antibacterial electret filter medium
JP2015000378A (en) * 2013-06-17 2015-01-05 倉敷繊維加工株式会社 Air filter medium, its manufacturing method, and air filter
CN105854419A (en) * 2016-05-11 2016-08-17 安徽元琛环保科技股份有限公司 Production method of electret compound filter material
CN105854419B (en) * 2016-05-11 2018-03-23 安徽元琛环保科技股份有限公司 A kind of production method of electret composite filtering material
WO2018105546A1 (en) * 2016-12-08 2018-06-14 東レ株式会社 Electret fiber sheet
JP2018095973A (en) * 2016-12-08 2018-06-21 東レ株式会社 Melt-blown nonwoven fabric
CN110036148A (en) * 2016-12-08 2019-07-19 东丽株式会社 Electret fiber sheet material
US11154803B2 (en) 2016-12-08 2021-10-26 Toray Industries, Inc. Electret fiber sheet

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