JP2012223940A - Method of manufacturing plant fiber foaming material - Google Patents

Method of manufacturing plant fiber foaming material Download PDF

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JP2012223940A
JP2012223940A JP2011092014A JP2011092014A JP2012223940A JP 2012223940 A JP2012223940 A JP 2012223940A JP 2011092014 A JP2011092014 A JP 2011092014A JP 2011092014 A JP2011092014 A JP 2011092014A JP 2012223940 A JP2012223940 A JP 2012223940A
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plant fiber
foaming
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Hsien-Cheng Liu
憲政 劉
Sen-Fang Hsieh
森芳 謝
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TRICAN CO Ltd
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PROBLEM TO BE SOLVED: To provide a method of manufacturing a plant fiber foaming material containing, in particular, natural plant fibers which can be naturally decomposed.SOLUTION: Plant fibers, a foaming agent, a thickening agent, a filler, and a combustion preventive agent are injected into a mixing and stirring tank, mixing processing is performed, and a mixture having uniform viscosity is formed. The uniform mixture is filled or injected in a molding container or a molding die. Pressurization processing is performed using a pressurizing device and a set pressure is applied. Heating processing is performed, and the temperature is raised to higher than a foaming temperature of the foaming agent to generate foaming action, and the plant fiber foaming material having a porous foaming structure is formed. The method of manufacturing the plant fiber foaming material can be easily achieved using an existing facility. The plant fiber foaming material has a function of naturally decomposing by natural plant fibers and can not only remarkably decrease a discharge amount of agricultural waste but also enhance an environment protection function.

Description

本発明は一種の発泡材の製造方法に係り、特に自然分解可能な天然植物繊維を包含する発泡材の製造方法に関する。   The present invention relates to a method for producing a kind of foam material, and more particularly to a method for producing a foam material including naturally-degradable natural plant fibers.

発泡材料は、軽量で防火及び衝突防止の機能を有するため、すでに大量に各種の領域、たとえば、包装材料、充填物、容器或いはケースに応用されている。一般に、発泡材料は基材及び発泡剤を利用して形成され、特に、加熱して発泡剤に大量の気体を発生させ、それと同時に基材を軟化或いは溶融させて必要な形状、たとえば平板状、波形板状、開口瓶状或いは密封形状に成形する。   Foamed materials are lightweight and have fire and collision prevention functions, so they have already been applied in large quantities to various areas such as packaging materials, fillers, containers or cases. In general, the foam material is formed using a base material and a foaming agent. In particular, the foam material is heated to generate a large amount of gas in the foaming agent, and at the same time, the base material is softened or melted to have a required shape, for example, a flat plate shape. It is molded into a corrugated plate shape, an open bottle shape or a sealed shape.

常用される基材は、各種の人造材料、たとえば熱可塑性プラスチック、熱硬化性プラスチック或いはゴムを包含する。このほか、非常に容易に既存の射出成形、押出成形、ロール成形或いはスプレーアップ成形などの加工工程に結合され、並びに適当な高温高圧蒸気、高周波、超音波或いは赤外線の加熱方式を組み合わせて実施される。   Commonly used substrates include various man-made materials such as thermoplastics, thermosetting plastics or rubber. In addition, it is very easily combined with existing injection molding, extrusion molding, roll molding or spray-up molding, and combined with a suitable high-temperature high-pressure steam, high-frequency, ultrasonic or infrared heating method. The

しかし、上述の周知の技術の欠点は、異なる材料に対しては、特定の発泡技術と適当な機械設備を選択使用する必要があり、このため製造実務上、自由度が低いことである。このほか、基材の原材料価格が高価でそれ自身が分解しにくく、使用後に大量の、簡単には処理できない廃棄物を発生し、相当にやっかいな環境保護問題を発生する。   However, a drawback of the above known techniques is that for different materials it is necessary to select and use a specific foaming technique and appropriate mechanical equipment, which is less flexible in manufacturing practice. In addition, the raw material price of the base material is expensive and difficult to decompose by itself, and a large amount of waste that cannot be easily treated is generated after use, resulting in considerable troublesome environmental protection problems.

これにより、一種の植物繊維発泡材の製造方法が必要であり、自然分解可能な植物繊維を利用し、上述の周知の技術の問題を解決する。   Accordingly, a method for producing a kind of plant fiber foaming material is required, and the above-mentioned well-known technical problems are solved by utilizing naturally decomposable plant fibers.

本発明の目的は、一種の植物繊維発泡材の製造方法を提供することにある。   An object of the present invention is to provide a method for producing a kind of plant fiber foam material.

本発明の植物繊維発泡材の製造方法は、
植物繊維、発泡剤、増粘剤、充填剤及び燃焼防止剤を混合攪拌タンク中に入れ、混合処理し、並びに粘ちゅう状の均一な混和物を形成し、
均一な該混和物を成形容器或いは成形型中に充填或いは注入し、
加圧装置を利用して加圧処理して設定圧力を印加し、
加熱処理し、温度を発泡剤の発泡温度より高くして発泡作用を発生させ、これにより多孔状発泡構造を有する植物繊維発泡材を形成する。
The method for producing the plant fiber foam of the present invention comprises:
Plant fibers, foaming agents, thickeners, fillers and anti-burning agents are placed in a mixing and stirring tank, mixed and processed to form a viscous uniform mixture;
Fill or inject the uniform mixture into a molding container or mold,
Apply a set pressure by applying pressure using a pressurizing device,
Heat treatment is performed to raise the temperature above the foaming temperature of the foaming agent to generate a foaming action, thereby forming a plant fiber foam material having a porous foam structure.

上述の植物繊維は、稲茎、籾殻、麦茎、玉蜀黍葉、甘薯葉、椰子殻或いは牧草、或いはその組合せ物とされ、特に、それは植物繊維粒子(Fiber Particulate Composite;FPC)とされる。   The above-mentioned plant fiber is rice stalk, rice husk, wheat stalk, onion leaf, sweet potato leaf, coconut shell or pasture, or a combination thereof, in particular, it is a plant fiber composite (FPC).

増粘剤は澱粉を包含し、粘度を増加するのに用いられ、加工性を改善する。   Thickeners include starch and are used to increase viscosity and improve processability.

燃焼防止剤は、炭酸カルシウムを包含し、燃焼を阻止するか燃焼速度を遅くし、防火効果を改善する。   Combustion inhibitors include calcium carbonate to prevent combustion or slow down the combustion rate and improve the fire protection effect.

これにより、本発明の製造方法は自然分解可能な発泡剤を生成し、並びに農業廃棄物排出量を減らし、環境保護を促進する。   As a result, the production method of the present invention produces a naturally decomposable foaming agent, reduces agricultural waste emissions, and promotes environmental protection.

本発明の植物繊維発泡材の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the vegetable fiber foam material of this invention. 本発明の植物繊維発泡材の製造方法のもう一つの実施例のフローチャートである。It is a flowchart of another Example of the manufacturing method of the vegetable fiber foam material of this invention.

図1を参照されたい。本発明の植物繊維発泡材の製造方法のフローチャートである。図1に示されるように、本発明の製造方法は、順に実行される混合処理S10、注入処理S20、加圧処理S30、加熱処理S40を包含し、これにより、特定形状を有する植物繊維発泡材を製造する。   Please refer to FIG. It is a flowchart of the manufacturing method of the vegetable fiber foam material of this invention. As shown in FIG. 1, the manufacturing method of the present invention includes a mixing process S10, an injection process S20, a pressurizing process S30, and a heating process S40 that are executed in order, and thereby a plant fiber foam material having a specific shape. Manufacturing.

まず、混合処理S10から開始する。すなわち、植物繊維、発泡剤、増粘剤、充填剤及び燃焼防止剤を混合タンク中に入れ、攪拌方式で混合する。混合時間は少なくとも約3時間とし、並びに粘ちゅう状の均一な混和物を形成する。   First, the process starts from the mixing process S10. That is, plant fibers, foaming agents, thickeners, fillers and combustion inhibitors are put in a mixing tank and mixed by a stirring method. The mixing time should be at least about 3 hours, as well as forming a viscous uniform blend.

そのうち、植物繊維の重量%は10%−90%とし、且つ植物繊維は、植物繊維粒子(FPC)、或いは天然植物の茎部、葉、果殻、果皮及び根部の少なくとも一つより選択する。   Among them, the weight percent of the plant fiber is 10% -90%, and the plant fiber is selected from plant fiber particles (FPC) or at least one of stem, leaf, fruit shell, pericarp and root of a natural plant.

たとえば、植物繊維は、稲茎、稲殻、麦茎、玉蜀黍葉、甘薯葉、亜麻葉、竹葉、甜菜葉、牧草、椰子殻、パイナップル皮及び牛蒡の少なくとも一つとする。   For example, the plant fiber is at least one of rice stalk, rice husk, wheat stalk, onion leaf, sweet potato leaf, flax leaf, bamboo leaf, sugar beet leaf, pasture grass, coconut shell, pineapple skin, and cow pod.

発泡剤は、エチレンビニルアセテートコポリマー(EVA)、発泡ポリエチレン(EPE)、ポリ乳酸(Poly Lactic Acid;PLA)とすることができ、且つ発泡剤は発泡温度を有し、たとえば、発泡温度が摂氏200度であると、温度がそれより高く、たとえば摂氏220度であると、大量の化学慣性を有するガス、たとえば二酸化炭素を発生し、これにより多孔状の開いた或いは閉じた孔を形成する。   The blowing agent can be ethylene vinyl acetate copolymer (EVA), expanded polyethylene (EPE), polylactic acid (PLA), and the blowing agent has a foaming temperature, for example, a foaming temperature of 200 degrees Celsius. If the temperature is higher, for example, 220 degrees Celsius, a large amount of gas having a chemical inertia, such as carbon dioxide, is generated, thereby forming a porous open or closed pore.

充填剤は、石粉を包含し得て、増粘剤は澱粉を包含し得て、粘度を増加して、加工性を改善するのに用いる。   Fillers can include stone flour and thickeners can include starch, which is used to increase viscosity and improve processability.

燃焼防止剤は炭酸カルシウムとすることができ、燃焼阻止するか或いは燃焼速度を遅くして防火効果を改善する。このほか、燃焼防止剤はエポキシ基粘ちゅう剤或いは活性炭燃焼防止剤とされる。そのうち、活性炭燃焼防止剤は、活性炭効果を有する燃焼防止剤であり、火災発生時に、燃焼阻止の特性を有するほか、優れた煙吸着効果を有し、火災現場の濃い煙を減らす特性を有し、現在世界で最も知られた環境保護効果と安全性を有する燃焼防止剤である。活性炭燃焼防止剤は一般に、天然炭素鉱を特殊処理して製造し、その特性は、常温から摂氏200度の時には安定して不変形の状態であり、加熱されて温度が摂氏200度より高くなると、その厚さが急激に膨張し、数十から数百倍となり、ばらばらの蛆虫状粉末となり、燃焼表面に隔離炭層を形成し、一方で熱を隔離し、もう一方で空気の流動を減らし、防火の目的を達成する。   The combustion inhibitor can be calcium carbonate, which inhibits combustion or slows the combustion rate to improve the fire protection effect. In addition, the flame retardant is an epoxy-based viscosity agent or an activated carbon flame retardant. Among them, the activated carbon combustion inhibitor is a combustion inhibitor having an activated carbon effect. In addition to having a property of preventing combustion in the event of a fire, it has an excellent smoke adsorption effect and has a property of reducing dense smoke at the fire site. It is the world's most known combustion inhibitor with environmental protection and safety. The activated carbon combustion inhibitor is generally manufactured by specially processing natural carbon ore, and its characteristics are stable and undeformed when the temperature is from room temperature to 200 degrees Celsius, and when heated, the temperature becomes higher than 200 degrees Celsius. , Its thickness expands abruptly, tens to hundreds of times, becomes a loose wormlike powder, forms a sequestration coal layer on the combustion surface, isolates heat on the one hand, reduces air flow on the other, Achieve fire protection objectives.

続いて注入処理S20を実行する。すなわち、注入或いは押出方式で、粘ちゅう状の均一な混和物を特定形状の成形容器或いは成形型に充填或いは注入する。   Subsequently, an injection process S20 is executed. That is, a viscous uniform mixture is filled or injected into a specific shape molding container or mold by injection or extrusion.

さらに加圧処理S30を実行し、緻密性を強化し、たとえば、加圧装置を利用して圧力を印加する。加圧装置は油圧機或いは高圧空気シリンダとする。   Further, a pressurizing process S30 is executed to enhance the density, and for example, pressure is applied using a pressurizing device. The pressurizing device is a hydraulic machine or a high-pressure air cylinder.

最後に加熱処理S40を実行する。それは加熱装置を利用し、成形容器或いは成形型中の均一な混和物の温度を発泡剤の発泡温度より高く、たとえば摂氏220度とし、且つ10〜60秒その温度を維持して、発泡剤に発泡作用を発生させ並びに均一な混和物を多孔状発泡構造の植物繊維発泡材に変化させる。加熱装置は高圧高温蒸気、高周波、超音波或いは赤外線の加熱方式を使用可能である。   Finally, heat treatment S40 is performed. It uses a heating device to make the temperature of the uniform mixture in the molding container or mold higher than the foaming temperature of the foaming agent, for example, 220 degrees Celsius, and maintain that temperature for 10 to 60 seconds. A foaming action is generated and the uniform admixture is changed to a plant fiber foam having a porous foam structure. The heating device can use a high-pressure high-temperature steam, high-frequency, ultrasonic or infrared heating system.

これにより、製造する植物繊維発泡材は成形容器或いは成形型により特定の形状を有し得て、直接特定商品の包装に用いて、湿気防止、防火或いは衝撃防止の保護機能を提供できる。   Thereby, the plant fiber foam to be manufactured can have a specific shape by a molding container or a mold, and can be used directly for packaging of a specific product to provide a protection function of moisture prevention, fire prevention or impact prevention.

図2を参照されたい。図2は本発明のもう一つの実施例の植物繊維発泡材の製造方法のフローチャートである。そのうち、本発明のもう一つの実施例の製造方法は、順に実行される混合処理S10、カレンダ処理S22、加熱処理S40及び裁断処理S50を包含し、これにより平板状の植物繊維発泡材を製造し、混合処理S10及び加熱処理S40は図1の実施例に述べたものと同じであるため、重複した説明は行わない。   Please refer to FIG. FIG. 2 is a flowchart of a method for producing a plant fiber foam material according to another embodiment of the present invention. Among them, the manufacturing method of another embodiment of the present invention includes a mixing process S10, a calendar process S22, a heating process S40, and a cutting process S50, which are executed in order, thereby manufacturing a plate-like vegetable fiber foam material. The mixing process S10 and the heating process S40 are the same as those described in the embodiment of FIG.

カレンダ処理S22では、カレンダ装置を利用し、粘ちゅう状の均一な混和物をカレンダ処理して所定厚さの予成形の平板を形成する。   In the calendering process S22, a calender device is used to calender the viscous uniform mixture to form a pre-formed flat plate having a predetermined thickness.

続いて、加熱処理S40し、発泡剤に発泡作用を形成させて、これにより、予成形の平板を平板状の植物繊維発泡材に変換する。   Subsequently, heat treatment S40 is performed to cause the foaming agent to form a foaming action, whereby the pre-formed flat plate is converted into a flat vegetable fiber foam material.

このほか、加熱処理S40は同時に加圧処理を実行でき、たとえば、熱圧機を利用し、これにより加圧加熱処理を実現し、植物繊維発泡材の緻密度を増加する。   In addition, the heat treatment S40 can perform the pressure treatment at the same time. For example, a heat press is used to realize the pressure heat treatment, thereby increasing the density of the plant fiber foam material.

最後に、裁断処理S50を実行し、裁断装置を利用して、植物繊維発泡材を適当なサイズと形状に裁断する。   Finally, the cutting process S50 is executed, and the plant fiber foam is cut into an appropriate size and shape using a cutting device.

本発明の製造方法の特徴は、既存の機械設備を用いて発泡を実行し、実現でき、余分の加工器具に交換或いは増加する必要がなく、各種の植物繊維発泡材の発泡成形に多元的に応用でき、且つ使用する材料は、実際の要求によって調整でき、コストを下げることができ、特に、その製造工程の可塑性は高く、必要材料と発泡剤の選択をカスタマイズできる。これにより、全体の製造工程が簡単便利で、成形が容易である。   The feature of the manufacturing method of the present invention is that foaming can be performed by using existing machinery and equipment, and it is not necessary to replace or increase with extra processing tools, and it is multi-factory for foam molding of various plant fiber foam materials. The materials that can be applied and used can be adjusted according to actual requirements and can reduce the cost. In particular, the plasticity of the manufacturing process is high and the selection of necessary materials and blowing agents can be customized. Thereby, the whole manufacturing process is simple and convenient, and molding is easy.

本発明の製造方法のもう一つの特徴は、植物繊維発泡材に必要な植物繊維が自然分解可能で且つ取得が容易であり、たとえば、農業生産加工中に発生或いは残留する廃棄物とされ、これにより、環境保護に貢献し、農業廃棄物の排出量を減らす。   Another feature of the production method of the present invention is that the plant fiber necessary for the plant fiber foam is naturally degradable and easy to obtain, for example, waste generated or remaining during agricultural production processing. To contribute to environmental protection and reduce agricultural waste emissions.

以上述べたことは、本発明の実施例にすぎず、本発明の実施の範囲を限定するものではなく、本発明の特許請求の範囲に基づきなし得る同等の変化と修飾は、いずれも本発明の権利のカバーする範囲内に属するものとする。   The above description is only an example of the present invention, and does not limit the scope of the present invention. Any equivalent changes and modifications that can be made based on the scope of the claims of the present invention are all described in the present invention. Shall belong to the scope covered by the rights.

S10 混合処理
S20 注入処理
S22 カレンダ処理
S30 加圧処理
S40 加熱処理
S50 裁断処理
S10 Mixing process S20 Injection process S22 Calendar process S30 Pressurizing process S40 Heating process S50 Cutting process

Claims (6)

植物繊維発泡材の製造方法において、
混合処理ステップにおいて、植物繊維、発泡温度を有する発泡剤、増粘剤、充填剤及び燃焼防止剤を混合攪拌タンク中に入れ、混合及び攪拌し、均一な混和物を形成し、
注入処理ステップにおいて、該均一な該混和物を成形容器或いは成形型中に充填或いは注入し、
加圧処理ステップにおいて、加圧装置を利用して設定圧力を印加し、
加熱処理ステップにおいて、加熱装置を利用して該発泡剤の発泡温度より高い温度まで加熱し、該発泡剤に発泡作用を発生させ、大量の気体を発生させ、並びに該均一な混和物を多孔状発泡構造を有する植物繊維発泡材に変化させ、
以上のステップを包含することを特徴とする、植物繊維発泡材の製造方法。
In the method for producing a plant fiber foam material,
In the mixing process step, plant fiber, foaming agent with foaming temperature, thickener, filler and anti-burning agent are placed in a mixing and stirring tank, mixed and stirred to form a uniform blend,
In the injection processing step, the uniform mixture is filled or injected into a molding container or mold,
In the pressure treatment step, a set pressure is applied using a pressure device,
In the heat treatment step, a heating device is used to heat the foaming agent to a temperature higher than the foaming temperature of the foaming agent, causing the foaming agent to produce a foaming action, to generate a large amount of gas, and to form the uniform mixture in a porous state. Change to a plant fiber foam with a foam structure,
The manufacturing method of a vegetable fiber foaming material characterized by including the above step.
植物繊維発泡材の製造方法において、
混合処理ステップにおいて、植物繊維、発泡温度を有する発泡剤、増粘剤、充填剤及び燃焼防止剤を混合攪拌タンク中に入れ、混合及び攪拌し、均一な混和物を形成し、
カレンダ処理ステップにおいて、カレンダ装置で該均一な混和物を処理し、所定厚さを有する予成形の平板を形成し、
加熱処理ステップにおいて、加熱装置を利用して該予成形の平板を該発泡剤の発泡温度より高い温度まで加熱し、該発泡剤に発泡作用を発生させ、大量の気体を発生させ、並びに該予成形の平板を多孔状発泡構造を有する平板状の植物繊維発泡材に変化させ、
裁断処理ステップにおいて、裁断装置を利用し、該植物繊維発泡材を適当なサイズ及び形状に裁断し、
以上のステップを包含することを特徴とする、植物繊維発泡材の製造方法。
In the method for producing a plant fiber foam material,
In the mixing process step, plant fiber, foaming agent with foaming temperature, thickener, filler and anti-burning agent are placed in a mixing and stirring tank, mixed and stirred to form a uniform blend,
In the calendar processing step, the uniform admixture is processed by a calendar device to form a pre-formed flat plate having a predetermined thickness,
In the heat treatment step, the preformed flat plate is heated to a temperature higher than the foaming temperature of the foaming agent by using a heating device to generate a foaming action in the foaming agent, to generate a large amount of gas, and to perform the preforming. Change the molded flat plate into a flat vegetable fiber foam material having a porous foam structure,
In the cutting process step, using a cutting device, cutting the plant fiber foam into an appropriate size and shape,
The manufacturing method of a vegetable fiber foaming material characterized by including the above step.
請求項2記載の植物繊維発泡材の製造方法において、該加熱処理ステップでは、加圧処理も同時に行うことを特徴とする、植物繊維発泡材の製造方法。   The method for producing a plant fiber foamed material according to claim 2, wherein in the heat treatment step, a pressure treatment is also performed simultaneously. 請求項1又は2記載の植物繊維発泡材の製造方法において、該植物繊維の重量%は10%−90%とし、且つ植物繊維は、植物繊維粒子(FPC)、或いは天然植物の茎部、葉、果殻、果皮及び根部の少なくとも一つより選択し、該植物繊維は、稲茎、稲殻、麦茎、玉蜀黍葉、甘薯葉、亜麻葉、竹葉、甜菜葉、牧草、椰子殻、パイナップル皮及び牛蒡の少なくとも一つとすることを特徴とする、植物繊維発泡材の製造方法。   The method for producing a plant fiber foamed material according to claim 1 or 2, wherein the weight percent of the plant fiber is 10% -90%, and the plant fiber is plant fiber particles (FPC), or a stem or leaf of a natural plant. Selected from at least one of fruit shell, pericarp and root, and the plant fiber is rice stalk, rice husk, wheat stalk, onion leaf, sweet potato leaf, flax leaf, bamboo leaf, sugar beet leaf, grass, coconut shell, pineapple A method for producing a plant fiber foam material, characterized by comprising at least one of leather and beef bowl. 請求項1又は2記載の植物繊維発泡材の製造方法において、該発泡剤は、エチレンビニルアセテートコポリマー(EVA)、発泡ポリエチレン(EPE)、ポリ乳酸(Poly Lactic Acid;PLA)を包含し、該充填剤は、少なくとも石粉を包含し、該増粘剤は少なくとも澱粉を包含し、粘度を増加して、加工性を改善するのに用いられ、該燃焼防止剤は少なくとも炭酸カルシウムを包含し、燃焼阻止するか或いは燃焼速度を遅くするのに用いられることを特徴とする、植物繊維発泡材の製造方法。   3. The method for producing a plant fiber foamed material according to claim 1, wherein the foaming agent includes ethylene vinyl acetate copolymer (EVA), expanded polyethylene (EPE), polylactic acid (PLA), and the filling. The agent includes at least stone powder, the thickener includes at least starch, is used to increase viscosity and improve processability, the combustion inhibitor includes at least calcium carbonate, and inhibits combustion. Or a method for producing a plant fiber foam material, characterized in that the method is used to reduce the burning rate. 請求項1又は2記載の植物繊維発泡材の製造方法において、該加熱装置は高圧高温蒸気、高周波、超音波或いは赤外線の加熱方式のいずれかを使用することを特徴とする、植物繊維発泡材の製造方法。   3. The method for producing a plant fiber foam according to claim 1 or 2, wherein the heating device uses any one of a heating system of high-pressure and high-temperature steam, high-frequency, ultrasonic or infrared. Production method.
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