JP2012161921A - Method for manufacturing airtight electronic component, and airtight electronic component - Google Patents

Method for manufacturing airtight electronic component, and airtight electronic component Download PDF

Info

Publication number
JP2012161921A
JP2012161921A JP2011021473A JP2011021473A JP2012161921A JP 2012161921 A JP2012161921 A JP 2012161921A JP 2011021473 A JP2011021473 A JP 2011021473A JP 2011021473 A JP2011021473 A JP 2011021473A JP 2012161921 A JP2012161921 A JP 2012161921A
Authority
JP
Japan
Prior art keywords
molded product
airtight
electronic component
electronic substrate
electronic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2011021473A
Other languages
Japanese (ja)
Other versions
JP5748491B2 (en
Inventor
Akihiro Mochizuki
章弘 望月
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polyplastics Co Ltd
Original Assignee
Polyplastics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplastics Co Ltd filed Critical Polyplastics Co Ltd
Priority to JP2011021473A priority Critical patent/JP5748491B2/en
Publication of JP2012161921A publication Critical patent/JP2012161921A/en
Application granted granted Critical
Publication of JP5748491B2 publication Critical patent/JP5748491B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for manufacturing an airtight electronic component through a simple process while maintaining airtightness of the electronic component by maintaining compressive strain applied to a member for sealing an airtight part on an electronic substrate, and to provide the airtight electronic component manufactured by the method.SOLUTION: The electronic substrate with a first molded product arranged thereon is placed on an injection molding die after arranging the first molded product near an airtight region on the electronic substrate, and compressive strain is applied to the first molded product by mold clamping force. A second molded product for holding the compressive strain of the first molded product is then formed by injection molding. The airtight part for covering the airtight region on the electronic substrate is thereby formed to manufacture the airtight electronic component.

Description

本発明は、電子基板上に気密部が形成された気密電子部品の製造方法、及び気密電子部品に関する。   The present invention relates to a method for manufacturing an airtight electronic component in which an airtight portion is formed on an electronic substrate, and the airtight electronic component.

従来より、電子基板上に気密部が形成された気密電子部品が広く使用されている。これらの気密電子部品では、気密部が形成されるとともに、電気信号を取り出すために金属端子が設けられており、この金属端子の取り出し部の気密性がしばしば問題となる。   Conventionally, an airtight electronic component in which an airtight portion is formed on an electronic substrate has been widely used. In these airtight electronic components, an airtight portion is formed and a metal terminal is provided for taking out an electric signal, and the airtightness of the takeout portion of the metal terminal is often a problem.

例えば、屋外で使用される電子部品では、湿気にさらされるような場合、気密が不十分であると、内部の電子素子の動作不良が生じる場合がある。このため、電子基板を覆うケースが形成されたり、電子基板全体が樹脂により封止されたりする。   For example, in an electronic component used outdoors, when exposed to moisture, if the airtightness is insufficient, an internal electronic element may malfunction. For this reason, a case covering the electronic substrate is formed, or the entire electronic substrate is sealed with resin.

かかる電子部品上に気密部が設けられた気密電子部品の製造方法としては、例えば、電子基板上に配置された撮像素子の周囲を囲むOリング等の密着部材を電子基板上に配置し、撮像素子の外周を囲む筒状の押さえ部材を密着部材上に配置し、密着部材の開口部上に開口部を塞ぐように透光性部材を配置した後に、押さえ部材、及び密着部材に対して力を印加し、電子基板上の撮像素子を密封して気密部を形成する方法が知られている(特許文献1)。   As a method of manufacturing an airtight electronic component in which an airtight part is provided on such an electronic component, for example, an adhesion member such as an O-ring surrounding the periphery of an image sensor disposed on the electronic substrate is disposed on the electronic substrate, and imaging is performed. A cylindrical pressing member that surrounds the outer periphery of the element is disposed on the contact member, and after the translucent member is disposed on the opening portion of the contact member so as to close the opening, force is applied to the pressing member and the contact member. Is applied to form an airtight part by sealing an image pickup device on an electronic substrate (Patent Document 1).

特開2009−201079号公報JP 2009-201079 A

しかし、特許文献1に記載される方法では、基板上でOリングが移動しやすく、気密部を形成するための各部材の所定の位置への配置が難しく、気密電子部品を組み立て難い問題がある。また、Oリングに生じた圧縮歪を維持して気密性を維持するためには、押さえ部材と基板とを接着等の方法により固定するか、基板上に固定された部材により、押さえ部材の位置を固定する必要があり、これらの点からも気密電子部品の組立てが容易ではない。   However, in the method described in Patent Document 1, the O-ring is easy to move on the substrate, and it is difficult to arrange each member for forming the airtight portion at a predetermined position, and it is difficult to assemble the airtight electronic component. . Further, in order to maintain the compressive strain generated in the O-ring and maintain the airtightness, the pressing member and the substrate are fixed by a method such as adhesion or the position of the pressing member is fixed by a member fixed on the substrate. From these points, it is not easy to assemble the airtight electronic component.

本発明は、以上の課題を解決するためになされたものであり、その目的は、電子基板上の気密部を気密する部材に付与された圧縮歪を維持することによって電子部品の気密性を維持でき、且つ工程が簡易である気密電子部品の製造方法、及び、当該方法により製造される気密電子部品を提供することにある。   The present invention has been made to solve the above-described problems, and its object is to maintain the airtightness of electronic components by maintaining the compressive strain applied to the members that hermetically seal the airtight portions on the electronic substrate. An object of the present invention is to provide a method for manufacturing an airtight electronic component that can be manufactured and that has a simple process, and an airtight electronic component manufactured by the method.

本発明者らは、電子基板上の気密域の近傍に第一成形品を配置した後に、第一成形品が配置された電子基板を射出成形用の金型に載置し、型締力により第一成形品に圧縮歪を付与し、次いで、第一成形品の圧縮歪を保持する第二成形品を射出成形により形成することにより、電子基板上の気密域を覆う気密部を形成することによって、第一成形品に付与された圧縮歪により生じる電子基板と第一成形品との間の反発力によって気密部の気密性が維持され、簡易な工程で気密性に優れた気密電子部品を製造できることを見出し、本発明を完成するに至った。   The inventors have placed the first molded product in the vicinity of the hermetic zone on the electronic substrate, and then placed the electronic substrate on which the first molded product has been placed on a mold for injection molding. Forming an airtight part covering the airtight area on the electronic substrate by applying compression strain to the first molded product and then forming a second molded product that retains the compression strain of the first molded product by injection molding. The airtightness of the airtight part is maintained by the repulsive force between the electronic substrate and the first molded product caused by the compressive strain applied to the first molded product, and an airtight electronic component having excellent airtightness can be obtained by a simple process. The inventors have found that it can be manufactured, and have completed the present invention.

(1) 1)電子基板上の気密域の近傍に第一成形品を配置する工程、
2)前記第一成形品が配置された電子基板を射出成形用の金型に載置し、型締力により前記第一成形品に圧縮歪を付与する工程、及び、
3)前記第一成形品の圧縮歪を保持する第二成形品を射出成形により形成する工程、
の工程を含み、
電子基板上に形成され、前記気密域を覆って気密する気密部の少なくとも一部が、前記第一成形品、及び前記第二成形品からなる複合体である、
気密電子部品の製造方法。
(1) 1) A step of arranging a first molded product in the vicinity of an airtight region on an electronic substrate,
2) placing the electronic substrate on which the first molded product is disposed on a mold for injection molding, and applying compressive strain to the first molded product by a clamping force; and
3) forming a second molded product that retains the compression strain of the first molded product by injection molding;
Including the steps of
At least a part of an airtight part that is formed on the electronic substrate and covers the airtight region and is airtight is a composite made of the first molded product and the second molded product,
Manufacturing method for airtight electronic components.

(2) 前記第一成形品の材料が充填材を含有する熱可塑性樹脂であって、前記圧縮歪が、0.5%以上2.0%以下である、(1)記載の気密電子部品の製造方法。   (2) The airtight electronic component according to (1), wherein the material of the first molded article is a thermoplastic resin containing a filler, and the compressive strain is 0.5% or more and 2.0% or less. Production method.

(3) 前記第一成形品を前記電子基板上に射出成形する、(1)又は(2)記載の気密電子部品の製造方法。   (3) The method for manufacturing an airtight electronic component according to (1) or (2), wherein the first molded product is injection-molded on the electronic substrate.

(4) 前記第一成形品の材料が、ポリブチレンテレフタレート樹脂である、(1)か(3)何れか記載の気密電子部品の製造方法。   (4) The method for manufacturing an airtight electronic component according to any one of (1) and (3), wherein the material of the first molded article is a polybutylene terephthalate resin.

(5) (1)から(4)何れか記載の方法により製造される気密電子部品。   (5) An airtight electronic component manufactured by the method according to any one of (1) to (4).

本発明によれば、電子基板上の気密部を気密する部材に付与された圧縮歪を維持することによって電子部品の気密性を維持でき、且つ工程が簡易である気密電子部品の製造方法、及び、当該方法により製造される気密電子部品を提供することが出来る。   According to the present invention, a method for manufacturing an airtight electronic component that can maintain the airtightness of the electronic component by maintaining the compressive strain applied to the member that hermetically seals the airtight portion on the electronic substrate, and the process is simple, and The airtight electronic component manufactured by the method can be provided.

本発明における、第一成形品及び第二成形品の断面を示す模式図である。It is a schematic diagram which shows the cross section of the 1st molded product and the 2nd molded product in this invention. 本発明の方法により形成される気密部の断面の模式図である。It is a schematic diagram of the cross section of the airtight part formed by the method of this invention. 本発明の方法により形成される気密部の断面の模式図である。It is a schematic diagram of the cross section of the airtight part formed by the method of this invention. 本発明の方法により形成される気密部の断面の模式図である。It is a schematic diagram of the cross section of the airtight part formed by the method of this invention. 端子付き電子基板を上面から見た模式図である。It is the schematic diagram which looked at the electronic substrate with a terminal from the upper surface. 表面に第一成形品が形成された端子付き電気基板を上面から見た模式図である。It is the schematic diagram which looked at the electric substrate with a terminal in which the 1st molded article was formed in the surface from the upper surface. 金型内に載置された、表面に第一成形品が形成された端子付き電子基板の、型締めされる前の断面の模式図である。It is a schematic diagram of the cross section before the mold clamping of the electronic substrate with a terminal in which the 1st molded product was formed in the surface mounted in the metal mold | die. 金型内に載置された、表面に第一成形品が形成された端子付き電子基板の、型締めされた状態の断面の模式図である。It is a schematic diagram of the cross section of the state clamped of the electronic substrate with a terminal in which the 1st molded article was formed in the surface mounted in the metal mold | die. 金型内に、第二成形品の材料が充填された状態の気密電子部品の断面の模式図である。It is a schematic diagram of the cross section of the airtight electronic component of the state with which the material of the 2nd molded product was filled in the metal mold | die. 第一成形品、及び第二成形品により封止された気密電子部品の斜視図である。It is a perspective view of the airtight electronic component sealed with the 1st molded product and the 2nd molded product.

以下、本発明の実施形態について説明する。なお、本発明の実施形態は、下記の実施形態に何ら限定されることなく、本発明の技術的範囲は、これに限定されるものではない。   Hereinafter, embodiments of the present invention will be described. In addition, embodiment of this invention is not limited to the following embodiment at all, and the technical scope of this invention is not limited to this.

なお、本願の発明の詳細な説明、及び特許請求の範囲において、電子基板上の「気密域」とは、電子基板上の気密状態が要求される領域である。気密域の具体例としては、自動車用部品等の腐食性ガス雰囲気下で使用される電子部品を構成する電子基板における、回路が形成されている領域や、ICチップや信号端子間の気密状態が要求される素子が配置されている領域が挙げられる。   In the detailed description of the invention of the present application and in the claims, the “airtight region” on the electronic substrate is a region where an airtight state on the electronic substrate is required. Specific examples of the hermetic zone include a region where a circuit is formed in an electronic substrate constituting an electronic component used in a corrosive gas atmosphere such as an automotive part, and an airtight state between an IC chip and a signal terminal. A region where the required element is arranged can be mentioned.

また、本願の発明の詳細な説明、及び特許請求の範囲において、電子基板上に形成される「気密部」とは、電子基板上に形成され、非接触又は接触の状態で、気密域を覆って、気密域を気密状態とする部材である。気密部は、少なくとも一部が、後述する第一成形品、及び第二成形品からなる複合体により構成される。   Further, in the detailed description of the invention of the present application and in the claims, the “airtight portion” formed on the electronic substrate is formed on the electronic substrate and covers the airtight region in a non-contact state or a contact state. Thus, it is a member that brings the airtight region into an airtight state. At least a part of the hermetic portion is composed of a composite made up of a first molded product and a second molded product described later.

本発明の、気密電子部品の製造方法は、以下の1)から3)の工程を含み、第一成形品、及び第二成形品からなる複合体を少なくとも一部に含む、気密域を覆って気密する気密部を電子基板上に形成する方法である。以下、1)から3)の工程、及び気密部の形成方法について順に説明する。   The manufacturing method of an airtight electronic component of the present invention includes the following steps 1) to 3), and covers an airtight region including at least a part of a composite formed of a first molded product and a second molded product. This is a method of forming an airtight part that is airtight on an electronic substrate. Hereinafter, the steps 1) to 3) and the method for forming the hermetic portion will be described in order.

1)電子基板上の気密域の近傍に第一成形品を配置する工程、
2)第一成形品が配置された電子基板を射出成形用の金型に載置し、型締力により第一成形品に圧縮歪を付与する工程、及び、
3)第一成形品の圧縮歪を保持する第二成形品を射出成形により形成する工程、
1) a step of arranging a first molded product in the vicinity of an airtight region on an electronic substrate;
2) placing the electronic substrate on which the first molded product is placed on a mold for injection molding, and applying compressive strain to the first molded product by a clamping force; and
3) forming a second molded product that retains the compression strain of the first molded product by injection molding;

〔工程1)〕
工程1)は、電子基板上の気密域の近傍に第一成形品を配置する工程である。
[Process 1)]
Step 1) is a step of placing the first molded product in the vicinity of the hermetic zone on the electronic substrate.

本発明において、気密電子部品の製造に用いる電子基板は、従来から電気・電子部品の製造に使用される電子基板であれば特に限定されず、単層基板であっても、多層基板であってもよい。電子基板の材料は、本発明の目的を阻害しない範囲で特に限定されず、従来電子基板の材料として使用されてきた、有機材料、無機材料、又はこれらの複合材料から適宜選択できる。   In the present invention, the electronic substrate used for manufacturing the airtight electronic component is not particularly limited as long as it is an electronic substrate conventionally used for manufacturing electrical / electronic components, and even a single layer substrate or a multilayer substrate may be used. Also good. The material of the electronic substrate is not particularly limited as long as the object of the present invention is not impaired, and can be appropriately selected from organic materials, inorganic materials, or composite materials thereof that have been conventionally used as materials for electronic substrates.

電子基板の好適な材料の具体例としては、エポキシ樹脂、ビスマレイミドトリアジン樹脂、シアネート樹脂、ポリパラフェニレンベンズビスオキサゾール樹脂、ポリアミド樹脂、ポリイミド樹脂、液晶性ポリマー、ポリエーテルエーテルケトン樹脂、ポリエーテルケトン樹脂、又はこれらの組合せ等の樹脂が挙げられる。電子基板の材料が樹脂である場合、これらの樹脂は、ガラス繊維、高弾性樹脂繊維、炭素繊維、又は金属繊維等の繊維を含むのが好ましい。かかる場合、繊維材料は織布、又は不織布の形態であるのが好ましい。   Specific examples of suitable materials for the electronic substrate include epoxy resin, bismaleimide triazine resin, cyanate resin, polyparaphenylene benzbisoxazole resin, polyamide resin, polyimide resin, liquid crystalline polymer, polyether ether ketone resin, polyether ketone. Examples thereof include resins such as resins and combinations thereof. When the material of the electronic substrate is a resin, these resins preferably include fibers such as glass fibers, high-elasticity resin fibers, carbon fibers, or metal fibers. In such a case, the fiber material is preferably in the form of a woven or non-woven fabric.

電子基板の形状は、気密部を形成可能であれば特に限定されず、平面状、曲面状、又はこれらの形状の組合せであってもよい。これらの形状の中では、第一成形品を所定の位置に固定しやすいことから、平面状が好ましい。   The shape of the electronic substrate is not particularly limited as long as the hermetic portion can be formed, and may be a planar shape, a curved surface shape, or a combination of these shapes. Among these shapes, a planar shape is preferable because the first molded product is easily fixed at a predetermined position.

第一成形品を電子基板上の気密域の近傍に配置する方法は特に限定されない。第一成形品を電子基板上の気密域の近傍の所定の場所に配置する具体的な方法としては、予め成形された第一成形品を電子基板上の所定の位置に載置する方法や、インサート射出成形により電子基板上の所定位置に第一成形品を形成する方法成形が挙げられる。インサート射出成形により第一成形品を形成する場合、電子基板の第一成形品を形成する箇所に予め凹部を設けることが好ましい。この場合、第一成形品がより強固に基板に固着される。第一成形品を電子基板上の所定の位置に載置する場合、第一成形品は、接着等の手段により電子基板上に固定されていてもよく、固定されていなくてもよい。   The method for arranging the first molded product in the vicinity of the hermetic zone on the electronic substrate is not particularly limited. As a specific method of placing the first molded product at a predetermined location in the vicinity of the hermetic zone on the electronic substrate, a method of placing the pre-formed first molded product at a predetermined position on the electronic substrate, There is a method of forming a first molded product at a predetermined position on an electronic substrate by insert injection molding. When forming a 1st molded product by insert injection molding, it is preferable to provide a recessed part previously in the location which forms the 1st molded product of an electronic substrate. In this case, the first molded product is more firmly fixed to the substrate. When the first molded product is placed at a predetermined position on the electronic substrate, the first molded product may or may not be fixed on the electronic substrate by means such as adhesion.

第一成形品を電子基板上の気密域の近傍の所定の位置に配置する方法としては、第一成形品の製造、及び電子基板上での位置決めが容易であり、電子基板上で第一成形品が移動し難いことから、インサート射出成形により電子基板上の所定位置に第一成形品を形成する方法がより好ましい。   As a method of arranging the first molded product at a predetermined position in the vicinity of the hermetic zone on the electronic substrate, the first molded product can be easily manufactured and positioned on the electronic substrate. Since the product is difficult to move, a method of forming the first molded product at a predetermined position on the electronic substrate by insert injection molding is more preferable.

予め成形された第一成形品を用いる場合の、第一成形品の製造方法は特に限定されない。かかる場合の第一成形品の製造方法としては、熱可塑性樹脂を用いる射出成形、押出成形等の溶融加工方法、切削加工方法、プレス加工方法等が挙げられる。   The method for producing the first molded product in the case of using the first molded product molded in advance is not particularly limited. Examples of the method for producing the first molded product in such a case include injection molding using a thermoplastic resin, melt processing methods such as extrusion molding, cutting processing methods, and press processing methods.

第一成形品の材料としては、後述する工程2)において、型締力により所望の圧縮歪を付与できる限り特に限定されず、熱可塑性樹脂、熱硬化性樹脂や光硬化性樹脂等の硬化性樹脂、ゴム等が挙げられる。前述する通り、第一成形品を電子基板上に配置する方法としてインサート射出成形がより好ましいことから、第一成形品の材料としては、熱可塑性樹脂がより好ましい。   The material of the first molded product is not particularly limited as long as a desired compressive strain can be imparted by the clamping force in the step 2) described below, and the curability of a thermoplastic resin, a thermosetting resin, a photocurable resin, or the like. Resin, rubber and the like can be mentioned. As described above, since insert injection molding is more preferable as a method of disposing the first molded product on the electronic substrate, a thermoplastic resin is more preferable as the material of the first molded product.

材料が熱可塑性樹脂である場合、射出成形可能であれば特に限定されず、結晶性樹脂及び非結晶性樹脂の何れも使用できる。好適な熱可塑性樹脂の具体例としては、ポリオレフィン(ポリエチレン(PE)、ポリプロピレン(PP)、ポリ4−メチル−ペンテン−1、ポリ環状オレフィン等)、ポリスチレン(PS)、AS樹脂、ABS樹脂、ポリ塩化ビニル(PVC)、ポリアクリロニトリル(PAN)、(メタ)アクリル樹脂、セルロース系樹脂、エラストマー等の汎用熱可塑性樹脂;脂肪族ポリアミド(ナイロン6、ナイロン6,6、ナイロン12、ナイロン6,12等)、芳香族ポリアミド(MXDナイロン等)、芳香族ポリエステル樹脂(ポリエチレンテレフタレート樹脂(PET)、ポリブチレンテレフタレート樹脂(PBT)、ポリエチレンナフタレート樹脂(PEN)等)、ポリカーボネート(PC)、ポリアセタール(POM)、ポリフェニレンエーテル樹脂(PPE)、ポリアリーレンサルファイド(PAS)(ポリフェニレンサルファイド樹脂(PPS)等)、ポリスルフォン(PSu)、ポリイミド(PI)、液晶性ポリマー(LCP)(液晶ポリエステル、液晶ポリエステルアミド、液晶ポリアミド等)のエンジニアリングプラスチック;脂肪族ジカルボン酸、脂肪族ジオール、及び、脂肪族ヒドロキシカルボン酸若しくはその環状化合物からなる群から選択される単量体を重縮合して得られる脂肪族ポリエステル、ジイソシアネート等により高分子量化された脂肪族ポリエステル等の生分解性樹脂が挙げられる。これらの熱可塑性樹脂は2種以上を組み合わせて用いることができる。   When the material is a thermoplastic resin, it is not particularly limited as long as it can be injection-molded, and either a crystalline resin or an amorphous resin can be used. Specific examples of suitable thermoplastic resins include polyolefin (polyethylene (PE), polypropylene (PP), poly-4-methyl-pentene-1, polycyclic olefin, etc.), polystyrene (PS), AS resin, ABS resin, poly General-purpose thermoplastic resins such as vinyl chloride (PVC), polyacrylonitrile (PAN), (meth) acrylic resin, cellulosic resin, elastomer; aliphatic polyamide (nylon 6, nylon 6,6, nylon 12, nylon 6,12, etc. ), Aromatic polyamide (MXD nylon, etc.), aromatic polyester resin (polyethylene terephthalate resin (PET), polybutylene terephthalate resin (PBT), polyethylene naphthalate resin (PEN), etc.), polycarbonate (PC), polyacetal (POM) , Polyphenylene Ether resin (PPE), polyarylene sulfide (PAS) (polyphenylene sulfide resin (PPS), etc.), polysulfone (PSu), polyimide (PI), liquid crystalline polymer (LCP) (liquid crystalline polyester, liquid crystalline polyester amide, liquid crystalline polyamide, etc. Engineering plastics; aliphatic dicarboxylic acids, aliphatic diols, and aliphatic polyesters obtained by polycondensation of monomers selected from the group consisting of aliphatic carboxylic acids or cyclic compounds thereof, diisocyanates, etc. Examples thereof include biodegradable resins such as molecular weight aliphatic polyesters. These thermoplastic resins can be used in combination of two or more.

これらの熱可塑性樹脂の中では、電気特性、耐熱性、及び耐久性のバランスに優れることからポリブチレンテレフタレート樹脂が特に好ましい。また、第一成形品に型締力を印加し圧縮歪を付与した際の、電子基板との密着性に優れ、気密性の良好な気密部を形成しやすいことから、第一成形品の材料として熱可塑性エラストマーも好ましい。   Among these thermoplastic resins, polybutylene terephthalate resin is particularly preferable because of its excellent balance of electrical properties, heat resistance, and durability. In addition, when applying a clamping force to the first molded product and applying compressive strain, the material of the first molded product is excellent in adhesion with the electronic substrate and easily forms an airtight part with good airtightness. A thermoplastic elastomer is also preferable.

本発明において、第一成形品の成形材料として熱可塑性樹脂を用いる場合、熱可塑性樹脂は、成形品の機械的特性の改良の目的等で充填材を配合できる。熱可塑性樹脂に配合される充填材の種類は、本発明の目的を阻害しない範囲で特に限定されず、従来から高分子材料の充填材として使用される種々の充填材を使用することができ、無機充填材及び有機充填材のいずれも使用できる。また、充填材の形状は、本発明の目的を阻害しない範囲で限定されず、繊維状充填材、粉粒状充填材、及び板状充填材のいずれも好適に使用できる。   In the present invention, when a thermoplastic resin is used as the molding material of the first molded product, the thermoplastic resin can be blended with a filler for the purpose of improving the mechanical properties of the molded product. The type of filler to be blended with the thermoplastic resin is not particularly limited as long as the object of the present invention is not impaired, and various fillers conventionally used as fillers for polymer materials can be used. Either inorganic fillers or organic fillers can be used. Further, the shape of the filler is not limited as long as the object of the present invention is not impaired, and any of a fibrous filler, a granular filler, and a plate-like filler can be suitably used.

好適な繊維状充填材として、例えば、ガラス繊維、アスベスト繊維、シリカ繊維、シリカ・アルミナ繊維、アルミナ繊維、ジルコニア繊維、窒化硼素繊維、窒化珪素繊維、硼素繊維、チタン酸カリウム繊維、さらにステンレス、アルミニウム、チタン、銅、真鍮等の金属の繊維状物等の無機質繊維状物質が挙げられる。   Suitable fibrous fillers include, for example, glass fibers, asbestos fibers, silica fibers, silica-alumina fibers, alumina fibers, zirconia fibers, boron nitride fibers, silicon nitride fibers, boron fibers, potassium titanate fibers, stainless steel, aluminum Inorganic fibrous materials such as metallic fibrous materials such as titanium, copper, and brass.

好適な粉粒状充填材としては、例えば、カーボンブラック、黒鉛、シリカ、石英粉末、ガラスビーズ、ミルドガラスファイバー、ガラスバルーン、ガラス粉、珪酸カルシウム、珪酸アルミニウム、カオリン、タルク、クレー、珪藻土、ウォラストナイトの如き珪酸塩、酸化鉄、酸化チタン、酸化亜鉛、三酸化アンチモン、アルミナの如き金属の酸化物、炭酸カルシウム、炭酸マグネシウムの如き金属の炭酸塩、硫酸カルシウム、硫酸バリウムの如き金属の硫酸塩、その他フェライト、炭化珪素、窒化珪素、窒化硼素、各種金属粉末等が挙げられる。また、好適な板状充填材としては、マイカ、ガラスフレーク、各種の金属箔等が挙げられる。   Suitable powdery fillers include, for example, carbon black, graphite, silica, quartz powder, glass beads, milled glass fiber, glass balloon, glass powder, calcium silicate, aluminum silicate, kaolin, talc, clay, diatomaceous earth, wollast. Silicate such as knight, iron oxide, titanium oxide, zinc oxide, antimony trioxide, metal oxide such as alumina, metal carbonate such as calcium carbonate and magnesium carbonate, metal sulfate such as calcium sulfate and barium sulfate Other examples include ferrite, silicon carbide, silicon nitride, boron nitride, and various metal powders. Suitable plate-like fillers include mica, glass flakes, various metal foils and the like.

これらの充填材の中では、コストと得られる第一成形品の物性とのバランスに優れることからガラス繊維を用いるのが特に好ましい。   Among these fillers, it is particularly preferable to use glass fibers because of excellent balance between cost and physical properties of the obtained first molded product.

ガラス繊維としては、公知のガラス繊維がいずれも好ましく用いられ、ガラス繊維径や、円筒、繭形断面、長円断面等の断面形状、あるいはチョップドストランドやロービング等の製造に用いる際の長さやガラスカットの方法にはよらない。本発明において、ガラス繊維の原料となるガラスの種類は特に限定されないが、品質上、Eガラスや、組成中にジルコニウム元素を含む耐腐食ガラスが好ましく用いられる。   As the glass fiber, any known glass fiber is preferably used, and the glass fiber diameter, the cross-sectional shape such as a cylinder, a bowl-shaped cross section, an oval cross section, or the length or glass used for manufacturing chopped strands, rovings, etc. It does not depend on the cutting method. In the present invention, the type of glass used as a raw material for the glass fiber is not particularly limited, but E glass or corrosion resistant glass containing a zirconium element in the composition is preferably used in terms of quality.

また、熱可塑性樹脂のマトリックスと充填材との界面特性を向上させる目的で、シラン化合物やエポキシ化合物等の有機処理剤で表面処理された充填材が好ましく用いられる。かかる充填材に用いられるシラン化合物やエポキシ化合物としては公知のものがいずれも好ましく用いることができ、本発明で充填材の表面処理に用いられるシラン化合物、エポキシ化合物の種類には依存しない。   Further, for the purpose of improving the interface characteristics between the matrix of the thermoplastic resin and the filler, a filler whose surface is treated with an organic treating agent such as a silane compound or an epoxy compound is preferably used. As the silane compound and epoxy compound used for such a filler, any known one can be preferably used, and does not depend on the type of silane compound or epoxy compound used for the surface treatment of the filler in the present invention.

充填材の使用量は、本発明の目的を阻害しない範囲で限定されないが、典型的には、熱可塑性樹脂100質量部に対して、5質量部以上120質量部以下が好ましく、10質量部以上100質量部以下がより好ましく、15質量部以上80質量部以下が特に好ましい。   The amount of the filler used is not limited as long as the object of the present invention is not impaired, but typically, 5 parts by mass or more and 120 parts by mass or less are preferable with respect to 100 parts by mass of the thermoplastic resin, and 10 parts by mass or more. 100 mass parts or less are more preferable, and 15 mass parts or more and 80 mass parts or less are especially preferable.

また、第一成形品の材料として熱可塑性樹脂を用いる場合、必要に応じて、酸化防止剤、耐熱安定剤、紫外線吸収剤、帯電防止剤、染料、顔料、潤滑剤、離型剤、結晶化促進剤、結晶核剤等をさらに添加して使用できる。   In addition, when using a thermoplastic resin as the material of the first molded product, an antioxidant, a heat stabilizer, an ultraviolet absorber, an antistatic agent, a dye, a pigment, a lubricant, a release agent, crystallization as necessary. Accelerators, crystal nucleating agents and the like can be further added and used.

第一成形品として、電子基板との接触面に気密が保たれるとともに、第二成形品の材料との接合性に優れるものを選択することで、接着剤を塗布する等の加工を施すことなく気密電子部品を得ることが出来る。また、第一成形品の材料として、例えば、エラストマー等の表面硬度の低い材料を用いる場合、第一成形品に型締力を印加し圧縮歪を付与する際に電子基板と第一成形品との間で高い密着性を得られるため、気密性の良好な気密部を形成しやすい。   As the first molded product, while maintaining airtightness on the contact surface with the electronic substrate, processing such as applying an adhesive is performed by selecting a material that has excellent bonding properties with the material of the second molded product. Airtight electronic components can be obtained without any problems. In addition, when using a material having a low surface hardness such as an elastomer as the material of the first molded product, when applying a clamping force to the first molded product and applying compressive strain, the electronic substrate and the first molded product Therefore, it is easy to form an airtight part with good airtightness.

第一成形品の形状は、後述する工程2)において型締力により圧縮歪を付与可能であり、第二成形品により圧縮歪を保持できる形状であれば特に限定されない。図1は、第一成形品の断面形状の具体例を示すである。以下、図1(a)〜図1(h)により、第一成形品の好適な断面形状について説明する。   The shape of the first molded product is not particularly limited as long as it allows compression strain to be imparted by the clamping force in step 2) to be described later and the compression strain can be retained by the second molded product. FIG. 1 shows a specific example of the cross-sectional shape of the first molded product. Hereinafter, a suitable cross-sectional shape of the first molded product will be described with reference to FIGS. 1 (a) to 1 (h).

第一成形品12の好適な断面形状は、電子基板11の面方向に対して垂直方向であって、第二成形品13から電子基板11への方向に作用する力によって、工程2)で第一成形品12に付与される圧縮歪が保持される形状である。第一成形品12の断面形状の好適な例としては、四角形(図1(a)、(b)、及び(c))、三角形(図(d))、半円形(図(e)、及び図(f))等の突起を有する形状が挙げられる。第一成形品12の断面形状がかかる突起を有する形状である場合、第二成形品13と電子基板11との間に生じる密着力によって、第一成形品12の突起が電子基板11の方向に押さえつけられ、第一成形品12の圧縮歪が保持される。   A suitable cross-sectional shape of the first molded article 12 is a direction perpendicular to the surface direction of the electronic substrate 11, and is the first in step 2) by the force acting in the direction from the second molded article 13 to the electronic substrate 11. This is a shape in which the compressive strain applied to one molded article 12 is maintained. Suitable examples of the cross-sectional shape of the first molded article 12 include a quadrilateral (FIGS. 1A, 1B, and 1C), a triangle (FIG. 4D), a semicircular shape (FIG. 2E), and A shape having protrusions such as FIG. When the cross-sectional shape of the first molded product 12 is a shape having such a protrusion, the protrusion of the first molded product 12 is directed in the direction of the electronic substrate 11 due to the adhesion force generated between the second molded product 13 and the electronic substrate 11. The compression strain of the first molded product 12 is maintained by being pressed.

第一成形品12の材料と第二成形品13の材料とが密着性に優れる組合せである場合には、第一成形品12と第二成形品13との界面に生じる密着力により第一成形品の圧縮歪を保持することもできる。かかる場合、第一成形品12の断面形状は、図1(g)に示すような長方形であってもよく、図1(h)に示すような台形であってもよい。   When the material of the first molded product 12 and the material of the second molded product 13 are a combination having excellent adhesion, the first molding is performed by the adhesive force generated at the interface between the first molded product 12 and the second molded product 13. The compression strain of the product can also be maintained. In such a case, the cross-sectional shape of the first molded product 12 may be a rectangle as shown in FIG. 1G or a trapezoid as shown in FIG.

これらの第一成形品の断面形状の中では、圧縮歪により生じる第一成形品12と電子基板11との間の反発力を広範囲にわたって作用させることができ、気密性に優れる気密電子部品を製造しやすいことから、図1(a)に示されるL字型の断面形状がより好ましい。   Among these cross-sectional shapes of the first molded product, a repulsive force between the first molded product 12 and the electronic substrate 11 caused by compressive strain can be applied over a wide range, and an airtight electronic component having excellent airtightness is manufactured. Since it is easy to do, the L-shaped cross-sectional shape shown by Fig.1 (a) is more preferable.

〔工程2)〕
工程2)は、第一成形品が配置された電子基板を射出成形用の金型に載置し、型締力により前期第一成形品に圧縮歪を付与する工程である。
[Step 2)]
Step 2) is a step of placing the electronic substrate on which the first molded product is disposed on a mold for injection molding, and applying compressive strain to the first molded product in the previous period by a clamping force.

工程2)で使用される金型は、第一成形品が所定の位置に配置された電子基板上に、後述する工程3)において第二成形品を成形可能であって、型締力によって第一成形品に所望の圧縮歪を付与できるものであれば特に限定されない。また、工程2)で使用される金型のキャビティの形状は、型締力により、第一成形品に所定の圧縮歪を付与でき、第一成形品に付加された圧縮歪を保持できる形状の第二成形品を形成できるものであれば特に限定されず、最終的に製造される気密電子部品の形状に応じて種々の形状を選択できる。なお、金型のキャビティ面の第一成形品に当接する箇所の形状は、型締後に、第一成形品に所望の圧縮歪が付与されるように設計される。   The mold used in step 2) can mold the second molded product in step 3) to be described later on the electronic substrate on which the first molded product is arranged at a predetermined position. There is no particular limitation as long as a desired compression strain can be imparted to one molded article. Further, the shape of the cavity of the mold used in step 2) is such that a predetermined compressive strain can be applied to the first molded product and the compressive strain applied to the first molded product can be retained by the clamping force. It will not specifically limit if a 2nd molded article can be formed, According to the shape of the airtight electronic component finally manufactured, various shapes can be selected. It should be noted that the shape of the portion of the cavity surface of the mold that comes into contact with the first molded product is designed so that a desired compressive strain is applied to the first molded product after clamping.

工程2)において、第一成形品に印加される型締力は、本発明の目的を阻害しない範囲で特に限定されず、第一成形品の材料の種類や形状を考慮して適宜選択される。第一成形品の材料としては、得られる気密電子部品が、機械的特性、電気的特性、耐久性、加工性、及び気密性が総合的に優れることから、充填材を含む熱可塑性樹脂が好ましいが、かかる場合、工程2)において第一成形品に付与される圧縮歪は0.5%以上2.0%以下が好ましい。圧縮歪が過小であったり、過大であったりする場合、所望の気密性を有する気密電子部品を得にくくなる場合がある。   In step 2), the clamping force applied to the first molded product is not particularly limited as long as the object of the present invention is not impaired, and is appropriately selected in consideration of the type and shape of the material of the first molded product. . As the material of the first molded product, a thermoplastic resin containing a filler is preferable because the obtained airtight electronic component is generally excellent in mechanical properties, electrical properties, durability, workability, and airtightness. In such a case, however, the compressive strain applied to the first molded product in step 2) is preferably 0.5% or more and 2.0% or less. When the compressive strain is too small or too large, it may be difficult to obtain an airtight electronic component having desired airtightness.

〔工程3)〕
工程3)は、工程2)において付加された第一成形品の圧縮歪を保持する第二成形品を射出成形により形成する工程である。
[Step 3)]
Step 3) is a step of forming a second molded product that retains the compression strain of the first molded product added in step 2) by injection molding.

工程3)では、工程1)について説明したように、工程2)で第一成形品に付加された圧縮歪を保持できるような形状の第二成形品を、射出成形により形成する。射出成形に使用される材料は熱可塑性樹脂であり、結晶性樹脂及び非結晶性樹脂の何れも使用できる。好適な熱可塑性樹脂の具体例としては、ポリオレフィン(ポリエチレン(PE)、ポリプロピレン(PP)、ポリ4−メチル−ペンテン−1、ポリ環状オレフィン等)、ポリスチレン(PS)、AS樹脂、ABS樹脂、ポリ塩化ビニル(PVC)、ポリアクリロニトリル(PAN)、(メタ)アクリル樹脂、セルロース系樹脂、エラストマー等の汎用熱可塑性樹脂;脂肪族ポリアミド(ナイロン6、ナイロン6,6、ナイロン12、ナイロン6,12等)、芳香族ポリアミド(MXDナイロン等)、芳香族ポリエステル樹脂(ポリエチレンテレフタレート樹脂(PET)、ポリブチレンテレフタレート樹脂(PBT)、ポリエチレンナフタレート樹脂(PEN)等)、ポリカーボネート(PC)、ポリアセタール(POM)、ポリフェニレンエーテル樹脂(PPE)、ポリアリーレンサルファイド(PAS)(ポリフェニレンサルファイド樹脂(PPS)等)、ポリスルフォン(PSu)、ポリイミド(PI)、液晶性ポリマー(LCP)(液晶ポリエステル、液晶ポリエステルアミド、液晶ポリアミド等)のエンジニアリングプラスチック;脂肪族ジカルボン酸、脂肪族ジオール、及び、脂肪族ヒドロキシカルボン酸若しくはその環状化合物からなる群から選択される単量体を重縮合して得られる脂肪族ポリエステル、ジイソシアネート等により高分子量化された脂肪族ポリエステル等の生分解性樹脂が挙げられる。これらの熱可塑性樹脂は2種以上を組み合わせて用いることができる。   In step 3), as described for step 1), a second molded product having a shape capable of holding the compression strain added to the first molded product in step 2) is formed by injection molding. The material used for injection molding is a thermoplastic resin, and both a crystalline resin and an amorphous resin can be used. Specific examples of suitable thermoplastic resins include polyolefin (polyethylene (PE), polypropylene (PP), poly-4-methyl-pentene-1, polycyclic olefin, etc.), polystyrene (PS), AS resin, ABS resin, poly General-purpose thermoplastic resins such as vinyl chloride (PVC), polyacrylonitrile (PAN), (meth) acrylic resin, cellulosic resin, elastomer; aliphatic polyamide (nylon 6, nylon 6,6, nylon 12, nylon 6,12, etc. ), Aromatic polyamide (MXD nylon, etc.), aromatic polyester resin (polyethylene terephthalate resin (PET), polybutylene terephthalate resin (PBT), polyethylene naphthalate resin (PEN), etc.), polycarbonate (PC), polyacetal (POM) , Polyphenylene Ether resin (PPE), polyarylene sulfide (PAS) (polyphenylene sulfide resin (PPS), etc.), polysulfone (PSu), polyimide (PI), liquid crystalline polymer (LCP) (liquid crystalline polyester, liquid crystalline polyester amide, liquid crystalline polyamide, etc. Engineering plastics; aliphatic dicarboxylic acids, aliphatic diols, and aliphatic polyesters obtained by polycondensation of monomers selected from the group consisting of aliphatic carboxylic acids or cyclic compounds thereof, diisocyanates, etc. Examples thereof include biodegradable resins such as molecular weight aliphatic polyesters. These thermoplastic resins can be used in combination of two or more.

第一成形品及び第二成形品の材料の組合せは、本発明の目的を阻害しない範囲で特に限定されないが、第二成形品の材料は、第一成形品の材料との密着性を考慮して選定されるのが好ましい。第一成形品及び第二成形品の材料の組み合わせとしては、両者が芳香族ポリエステルであるのが好ましく、両者がポリブチレンテレフタレート樹脂であるのがより好ましい。第一成形品及び第二成形品の材料がポリブチレンテレフタレートである場合、ポリブチレンテレフタレートが電気特性、耐熱性、及び耐久性のバランスに優れることから、良好な気密性を長期に保持でき、性能に優れる気密電子部品を得やすい。   The combination of the material of the first molded product and the material of the second molded product is not particularly limited as long as the object of the present invention is not hindered, but the material of the second molded product is in consideration of the adhesion with the material of the first molded product. Are preferably selected. As a combination of materials of the first molded product and the second molded product, both are preferably aromatic polyesters, and more preferably both are polybutylene terephthalate resins. When the material of the first molded product and the second molded product is polybutylene terephthalate, the polybutylene terephthalate has a good balance of electrical properties, heat resistance, and durability. It is easy to obtain airtight electronic components that excel in

第二成形品の材料である熱可塑性樹脂は、第一成形品の材料として熱可塑性樹脂を用いる場合と同様に、必要に応じて、充填材、酸化防止剤、耐熱安定剤、紫外線吸収剤、帯電防止剤、染料、顔料、潤滑剤、離型剤、結晶化促進剤、結晶核剤等をさらに添加して使用できる。   The thermoplastic resin that is the material of the second molded product, as in the case of using the thermoplastic resin as the material of the first molded product, is optionally filled with a filler, an antioxidant, a heat stabilizer, an ultraviolet absorber, Antistatic agents, dyes, pigments, lubricants, mold release agents, crystallization accelerators, crystal nucleating agents and the like can be further added and used.

〔気密部の形成方法〕
本発明において、気密域を覆って気密状態とする気密部は、以上説明した工程1)から3)により形成される第一成形品、及び第二成形品からなる複合体を少なくとも一部に含む。以下、本発明における気密部の形成方法の具体例について、気密部の電子基板と垂直方向の断面の模式図である、図2から図4を参照して説明する。また、気密部の形成方法の具体例として、一部に端子が露出した気密電子部品の形成方法について、図5〜図10を参照して説明する。
[Method of forming hermetic portion]
In the present invention, the hermetic portion that covers the hermetic zone and is in an airtight state includes at least a part of the composite formed of the first molded product and the second molded product formed by the above-described steps 1) to 3). . Hereinafter, a specific example of the method for forming an airtight portion in the present invention will be described with reference to FIGS. 2 to 4 which are schematic views of a cross section in a direction perpendicular to the electronic substrate of the airtight portion. In addition, as a specific example of the method for forming the hermetic portion, a method for forming a hermetic electronic component in which terminals are partially exposed will be described with reference to FIGS.

気密部1を形成する方法の具体例としては、図2に示されるように、電子基板11上に配置された各種の電子素子等の被気密部材14の周囲を囲うように第一成形品12と第二成形品13とからなる筒状の複合体を形成し、上部の開口部を、例えば、接着、溶着等の方法により蓋材15により閉じて気密部1を形成する方法が挙げられる。かかる方法は、被気密部材14が表面弾性波素子等の気体中で使用される素子である場合に好適である。   As a specific example of the method of forming the hermetic portion 1, as shown in FIG. 2, the first molded product 12 is enclosed so as to surround the airtight member 14 such as various electronic elements arranged on the electronic substrate 11. And the second molded product 13 is formed, and the upper opening is closed by the lid member 15 by, for example, a method such as adhesion or welding to form the airtight portion 1. Such a method is suitable when the airtight member 14 is an element used in a gas such as a surface acoustic wave element.

気密部1を形成する方法の他の具体例としては、図3に示されるように、電子基板11上に配置された各種の電子素子等の被気密部材14の周囲を囲うように筒状に第一成形品12を形成した後に、筒状の第一成形品12の内部に、被気密部材14に接触して被覆するように第二成形品13を形成して、第一成形品12と第二成形品13とからなる複合体を形成して、かかる複合体を気密部1とする方法が挙げられる。かかる態様は、被気密部材14が気体中で使用される必要がない場合、簡易な工程で気密電子部品を製造できるために好適である。   As another specific example of the method of forming the hermetic portion 1, as shown in FIG. 3, a cylindrical shape is formed so as to surround the airtight member 14 such as various electronic elements arranged on the electronic substrate 11. After forming the first molded product 12, the second molded product 13 is formed inside the cylindrical first molded product 12 so as to be in contact with and covered with the airtight member 14. There is a method in which a composite formed of the second molded product 13 is formed and the composite is used as the airtight portion 1. Such an embodiment is preferable because the airtight electronic component can be manufactured by a simple process when the airtight member 14 does not need to be used in a gas.

また、被気密部材14の周囲に十分なスペースがある場合、図4に示されるように、電子基板11上に形成された被気密部材14に隣接する箇所に第一成形品12を形成した後に、被気密部材14に接触して被覆し、且つ、被気密部材14への気体の浸入を十分に防げる程度の、電子基板11の面方向に広がりを有する第二成形品13を成形して、第一成形品12と第二成形品13とからなる複合体を形成して、かかる複合対を気密部1とする方法も好適である。   Further, when there is a sufficient space around the airtight member 14, as shown in FIG. 4, after forming the first molded product 12 at a location adjacent to the airtight member 14 formed on the electronic substrate 11. Then, the second molded product 13 having a spread in the surface direction of the electronic substrate 11 is formed so as to contact and cover the hermetic member 14 and sufficiently prevent the gas from entering the hermetic member 14. A method of forming a composite body including the first molded product 12 and the second molded product 13 and using the composite pair as the airtight portion 1 is also suitable.

次いで、気密部の形成方法の具体例として、好適な電子部品の一つである、一部に端子が露出した気密電子部品の製造方法について、図5〜図10を参照して説明する。一部に端子が露出した気密電子部品2を製造する際には、図5に示される表面に複数の端子22が形成された端子付き電子基板21を用いる。   Next, as a specific example of the method for forming the hermetic portion, a method for manufacturing a hermetic electronic component with a terminal exposed in part, which is one of suitable electronic components, will be described with reference to FIGS. When manufacturing the airtight electronic component 2 in which the terminals are partially exposed, the electronic substrate with terminals 21 having a plurality of terminals 22 formed on the surface shown in FIG. 5 is used.

工程1)について、図6、及び図7を参照して説明する。図6は、第一成形品23が形成された端子付き電子基板21を上面から見た図であり、図7は、上型24と下型25とからなる金型内に載置された、第一成形品23が形成された端子付き電子基板21の、図5に示されるA−A’断面における断面図である。   Step 1) will be described with reference to FIG. 6 and FIG. FIG. 6 is a view of the electronic substrate with terminal 21 on which the first molded product 23 is formed as viewed from above, and FIG. 7 is placed in a mold composed of an upper mold 24 and a lower mold 25. It is sectional drawing in the AA 'cross section shown by FIG. 5 of the electronic substrate 21 with a terminal in which the 1st molded article 23 was formed.

工程1)では、図6、及び図7に示されるように、気密成形品において外部に露出する端子22を囲うように、端子付き電子基板21の面方向に対して垂直方向の断面がL字型の形状の第一成形品23を、端子付き電子基板21の前面、及び後面に形成する。第一成形品23の材料は、前述の種々の材料を用いることができるが、機械的特性、電気的特性、耐久性、加工性、及び得られる気密電子部品2の気密性が総合的に優れることから、ガラス繊維を充填されたポリブチレンテレフタレート樹脂であるのがより好ましい。   In step 1), as shown in FIGS. 6 and 7, the cross section in the direction perpendicular to the surface direction of the electronic substrate 21 with terminals is L-shaped so as to surround the terminals 22 exposed to the outside in the airtight molded product. The first molded product 23 in the shape of a mold is formed on the front surface and the rear surface of the terminal-equipped electronic substrate 21. As the material of the first molded product 23, the above-described various materials can be used, but mechanical properties, electrical properties, durability, workability, and airtightness of the obtained airtight electronic component 2 are comprehensively excellent. Therefore, polybutylene terephthalate resin filled with glass fibers is more preferable.

工程2)について、図7、及び図8を参照して説明する。図8は、型締力により第一成形品23に圧縮歪が付与された状態の、端子付き電子基板21の、図5に示されるA−A’断面における断面図である。   Step 2) will be described with reference to FIGS. FIG. 8 is a cross-sectional view of the terminal-attached electronic board 21 taken along the line A-A ′ shown in FIG. 5 in a state where compressive strain is applied to the first molded product 23 by the clamping force.

工程2)では、前面、及び後面に第一成形品23を形成された、端子付き電子基板21は、上型24と下型25とからなる金型内に載置された後、図7、及び図8に示されるように、上型24と下型25とを合わせ、型締めすることにより、第一成形品23に所定の圧縮歪が付与される。型締めする際の型締め力は、圧縮歪量、及び第一成形品の23の材料の機械的性質に応じて、適宜設定される。第一成形品23の材料としてガラス繊維が充填されたポリブチレンテレフタレート樹脂を用いる場合、第一成形品23に付与される圧縮歪の量は0.5%以上2.0%以下が好ましい。   In step 2), the terminal-attached electronic substrate 21 having the first molded product 23 formed on the front surface and the rear surface is placed in a mold composed of an upper mold 24 and a lower mold 25, and then FIG. And as FIG. 8 shows, a predetermined | prescribed compressive strain is provided to the 1st molded article 23 by match | combining the upper mold | type 24 and the lower mold | type 25, and clamping. The clamping force at the time of clamping is appropriately set according to the amount of compressive strain and the mechanical properties of the material 23 of the first molded product. When a polybutylene terephthalate resin filled with glass fibers is used as the material of the first molded product 23, the amount of compressive strain applied to the first molded product 23 is preferably 0.5% or more and 2.0% or less.

工程3)について、図8、図9、図10を参照して説明する。図9は、金型内のキャビティに26に、第二成形品27を形成する溶融状態の成形材料が注入された状態の、図5に示されるA−A’断面における断面図である。また、図10は、第一成形品23、及び第二成形品27によって封止された気密電子部品2の、図5に示されるA−A’断面における断面図である。   Step 3) will be described with reference to FIG. 8, FIG. 9, and FIG. FIG. 9 is a cross-sectional view taken along the line A-A ′ shown in FIG. 5, in which a molten molding material for forming the second molded product 27 is injected into the cavity 26 in the mold. FIG. 10 is a cross-sectional view of the airtight electronic component 2 sealed by the first molded product 23 and the second molded product 27 in the A-A ′ cross section shown in FIG. 5.

図9に示されるように、工程3)では、射出成形機等の成形機によって、金型が備えるゲート(不図示)から、金型内のキャビティ26に、溶融状態の第二成形品27の成形材料が注入され、端子付き電子基板21の前面、後面、及び側面を被覆するように、第二成形品27が形成される。第一成形品23の断面形状がL字型であるため、端子付き電子基板21の表面に形成された第二成形品27によって、端子付き電子基板21の面方向に対して垂直な方向に第一成形品23が押さえつけられ、第一成形品23に付与された圧縮歪が保持され、気密部の気密性を実現できる。   As shown in FIG. 9, in step 3), the molten second molded product 27 is transferred from the gate (not shown) provided in the mold to the cavity 26 in the mold by a molding machine such as an injection molding machine. The molding material is injected, and the second molded product 27 is formed so as to cover the front surface, the rear surface, and the side surface of the terminal-equipped electronic substrate 21. Since the cross-sectional shape of the first molded product 23 is L-shaped, the second molded product 27 formed on the surface of the terminal-equipped electronic substrate 21 is arranged in a direction perpendicular to the surface direction of the terminal-equipped electronic substrate 21. The one molded product 23 is pressed down, the compressive strain applied to the first molded product 23 is maintained, and the airtightness of the hermetic portion can be realized.

以上、説明した工程1)〜工程3)により製造された、第一成形品23、及び第二成形品27により封止された気密電子部品は、第二部品により被覆された気密部が良好に気密されるため、長期にわたり良好な性能を保持できる。また、以上説明した、端子付き電子基板21を封止した気密電子部品2は、一部、端子が露出しているため、露出した端子と他の電子部品と結線され、好適に利用される。   As described above, the airtight electronic parts sealed by the first molded product 23 and the second molded product 27 manufactured by the steps 1) to 3) described above have good airtight portions covered by the second parts. Since it is airtight, good performance can be maintained over a long period of time. Further, since the airtight electronic component 2 encapsulating the terminal-equipped electronic substrate 21 described above is partially exposed, the exposed terminal is connected to another electronic component and is preferably used.

以上説明した方法により、電子基板上に気密部を形成した後、所望により、筐体やその他の電子部品を、気密部又は気密部内の被気密部材と組み合わせて、気密電子部品が製造される。   After the airtight part is formed on the electronic substrate by the method described above, the airtight electronic part is manufactured by combining the case and other electronic parts with the airtight part or the airtight member in the airtight part as desired.

本発明の気密電子部品の製造方法によれば、射出成形により容易に製造可能であるため、安価に、十分な気密性を有する気密電子部品を製造できる。本発明の方法により製造される気密電子部品の具体例としては、車載用ICチップモジュール等が挙げられる。   According to the method for manufacturing a hermetic electronic component of the present invention, since it can be easily manufactured by injection molding, a hermetic electronic component having sufficient hermeticity can be manufactured at low cost. Specific examples of the airtight electronic component manufactured by the method of the present invention include an in-vehicle IC chip module.

以下、実施例により本発明を具体的に説明するが、本発明はこれに限定されるものではない。   EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.

第一成形品の材料として、以下の1)、及び2)の材料を用いた。
1)ジュラネックス303RA(ポリブチレンテレフタレート樹脂組成物、ガラス繊維15質量%配合、ウィンテックポリマー株式会社製)
2)ハイトレル5557(ポリエステルエラストマー、東レ・デュポン株式会社製)
The following materials 1) and 2) were used as the material of the first molded product.
1) DURANEX 303RA (polybutylene terephthalate resin composition, 15% by mass of glass fiber, manufactured by Wintech Polymer Co., Ltd.)
2) Hytrel 5557 (polyester elastomer, manufactured by Toray DuPont Co., Ltd.)

また、第二成形品の材料として、ジュラネックス305RA(ポリブチレンテレフタレート樹脂組成物、ガラス繊維15質量%配合、ウィンテックポリマー株式会社製)を用いた。   Further, Duranex 305RA (polybutylene terephthalate resin composition, blended with 15% by mass of glass fiber, manufactured by Wintech Polymer Co., Ltd.) was used as the material of the second molded product.

電子基板として、厚さ1.6mm、縦横各45mmの形状の、ガラスエポキシ基板を用いた。   A glass epoxy substrate having a thickness of 1.6 mm and a length and width of 45 mm was used as the electronic substrate.

〔参考例〕
(第一成形品の作成)
気密電子部品における、圧縮された第一成形品の高さ(電子基板の面方向に対して垂直方向の、電子基板の表面から第一成形品の表面までの距離)に対して、高さが3.0%高い形状の未圧縮の第一成形品(実施例3で使用)を、ジュラネックス303RAを使用し射出成形により製造した。第一成形品の断面形状は、図1(a)に示されるL字型の形状であった。
[Reference example]
(Creation of the first molded product)
The height of the compressed first molded article in the airtight electronic component (the distance from the surface of the electronic board to the surface of the first molded article in the direction perpendicular to the surface direction of the electronic board) A 3.0% higher shaped uncompressed first molded product (used in Example 3) was produced by injection molding using Duranex 303RA. The cross-sectional shape of the first molded product was an L-shape shown in FIG.

気密電子部品における圧縮された第一成形品の高さに対して、高さが3.0%高い形状の未圧縮の第一成形品を、切削して、気密電子部品における圧縮された第一成形品の高さに対して、高さが0.5%高い第一成形品(実施例1で使用)、高さが2.0%高い第一成形品(実施例2で使用)、及び高さが同じである第一成形品(比較例1で使用)を作成した。   The uncompressed first molded product having a height 3.0% higher than the height of the compressed first molded product in the hermetic electronic component is cut, and the compressed first molded product in the hermetic electronic component is cut. A first molded product whose height is 0.5% higher than that of the molded product (used in Example 1), a first molded product whose height is 2.0% higher (used in Example 2), and A first molded product (used in Comparative Example 1) having the same height was prepared.

また、材料をハイトレル5557に変えることの他は、実施例3で使用する形状と同じ形状の第一成形品(実施例4で使用)を作成した。   A first molded product (used in Example 4) having the same shape as that used in Example 3 was prepared except that the material was changed to Hytrel 5557.

〔実施例1〜3〕
型締め時に0.5〜3.0%の所定の圧縮歪が生じるように形状を調整された第一成形品を、電子基板の前面、及び後面に対称的になるように配置した。次いで、第一成形品が配置された電子基板を金型に載置し、型締めして、第一成形品に所定の圧縮歪を付与した。その後、ジュラネックス305RAを使用して、射出成形により、電子基板の、前面、後面、及び側面を被覆するように、第二成形品を形成して気密電子部品を得た。なお、気密電子部品における、第二成形品の高さ(電子基板の面方向に対して垂直方向の、電子基板の表面から第一成形品の表面までの距離)は、第一成形品の同じ高さである。得られた気密電子部品について、気密電子部品5個を用いて、下記の方法に従いインク浸入試験を行い、第二成形品で被覆された気密部の気密性を確認した。実施例1〜3で得た気密電子部品について、気密電子部品5個中の、気密性が不十分であった気密電子部品の数を、表1に示す。
Examples 1 to 3
The first molded product whose shape was adjusted so that a predetermined compressive strain of 0.5 to 3.0% was generated at the time of mold clamping was disposed so as to be symmetrical on the front surface and the rear surface of the electronic substrate. Next, the electronic substrate on which the first molded product was placed was placed on a mold and clamped to give a predetermined compressive strain to the first molded product. Thereafter, a second molded product was formed by using Duranex 305RA so as to cover the front surface, the rear surface, and the side surface of the electronic substrate by injection molding to obtain an airtight electronic component. In the airtight electronic component, the height of the second molded product (distance from the surface of the electronic substrate to the surface of the first molded product in the direction perpendicular to the surface direction of the electronic substrate) is the same as that of the first molded product. It is height. About the obtained airtight electronic component, the ink penetration test was performed according to the following method using 5 airtight electronic components, and the airtightness of the airtight part coat | covered with the 2nd molded article was confirmed. Regarding the airtight electronic components obtained in Examples 1 to 3, Table 1 shows the number of airtight electronic components with insufficient airtightness in 5 airtight electronic components.

<インク浸入試験>
得られた封止電子部品を、赤インクに浸漬し、23℃で1時間放置し、次いで、封止電子部品表面に付着したインクを拭き取り、第一成形品、及び第二成形品を、工具を用いて電子基板から剥離し、気密部へのインクの浸入の有無を目視にて確認する。
<Ink penetration test>
The obtained encapsulated electronic component is immersed in red ink and left at 23 ° C. for 1 hour, and then the ink adhering to the surface of the encapsulated electronic component is wiped off, and the first molded product and the second molded product are used as a tool. Is peeled off from the electronic substrate, and the presence or absence of ink intrusion into the airtight portion is visually confirmed.

〔実施例4〕
ハイトレル5557で作成された、型締めに時に3.0%の圧縮歪が生じる形状の第一成形品を用いることの他は、実施例1と同様にして気密電子部品を得た。実施例4で得た気密電子部品のインク浸入試験の結果を表1に示す。
Example 4
An airtight electronic component was obtained in the same manner as in Example 1 except that the first molded product having a shape that produced 3.0% compressive strain at the time of clamping was produced by using Hytrel 5557. Table 1 shows the result of the ink penetration test of the airtight electronic component obtained in Example 4.

〔比較例1〕
型締め時に圧縮歪の生じない第一成形品を用いる他は、実施例1と同様にして気密成形品を得た。比較例1で得た気密電子部品のインク浸入試験の結果を表1に示す。
[Comparative Example 1]
An airtight molded product was obtained in the same manner as in Example 1 except that the first molded product that did not cause compressive strain during mold clamping was used. Table 1 shows the results of the ink penetration test of the airtight electronic component obtained in Comparative Example 1.

Figure 2012161921
Figure 2012161921

表1から、実施例1〜4と、比較例1との比較により、第一成形品に型締力により圧縮歪を与えた後に、第二成形品を形成して気密電子部品を製造する場合、気密電子部品における気密不良の発生を抑制できることが分かる。また、実施例1、及び2と、実施例3との比較により、第一成形品の材料が、充填材を含む熱可塑性樹脂(ポリブチレンテレフタレート樹脂)である場合、圧縮歪の量を0.5%以上2.0%以下とすることにより、気密不良の発生が効果的に抑制されることが分かる。一方、実施例4によれば、第一成形品の材料が熱可塑性エラストマーである場合、圧縮歪みの量が2.0%を超えていても、極めて優れる気密不良の発生の抑制効果が得られることが分かる。   From Table 1, by comparing Examples 1 to 4 and Comparative Example 1, after applying compressive strain to the first molded product by the clamping force, forming a second molded product to manufacture an airtight electronic component It can be seen that the occurrence of airtight defects in the airtight electronic component can be suppressed. In addition, when Examples 1 and 2 and Example 3 are compared, when the material of the first molded product is a thermoplastic resin (polybutylene terephthalate resin) containing a filler, the amount of compressive strain is set to 0.00. It turns out that generation | occurrence | production of an airtight defect is suppressed effectively by setting it as 5% or more and 2.0% or less. On the other hand, according to Example 4, when the material of the first molded article is a thermoplastic elastomer, even if the amount of compressive strain exceeds 2.0%, an extremely excellent effect of suppressing the occurrence of airtight defects can be obtained. I understand that.

比較例1で得られた気密成形品についてインク浸入試験を行った結果、試験した5個の気密電子部品全てにおいて、第二成形品部分へのインクの侵入が確認された。つまり、第一成形品に圧縮歪を付与しない場合、第一成形品と電子基板との間に微小な隙間が生じるため、気密電子部品の気密性が不十分となることが分かる。   As a result of conducting an ink penetration test on the airtight molded product obtained in Comparative Example 1, intrusion of ink into the second molded product portion was confirmed in all of the 5 airtight electronic components tested. That is, when compressive strain is not applied to the first molded product, a minute gap is generated between the first molded product and the electronic substrate, and thus it is understood that the airtightness of the hermetic electronic component is insufficient.

1 気密部
11 電子基板
12 第一成形品
13 第二成形品
14 被気密部材
15 蓋材
21 端子付き電子基板
22 端子
23 第一成形品
24 上型
25 下型
26 キャビティ
27 第二成形品
DESCRIPTION OF SYMBOLS 1 Airtight part 11 Electronic substrate 12 1st molded product 13 2nd molded product 14 Airtight member 15 Lid material 21 Electronic substrate with a terminal 22 Terminal 23 1st molded product 24 Upper mold | type 25 Lower mold | type 26 Cavity 27 2nd molded product

Claims (5)

1)電子基板上の気密域の近傍に第一成形品を配置する工程、
2)前記第一成形品が配置された電子基板を射出成形用の金型に載置し、型締力により前記第一成形品に圧縮歪を付与する工程、及び、
3)前記第一成形品の圧縮歪を保持する第二成形品を射出成形により形成する工程、
の工程を含み、
電子基板上に形成され、前記気密域を覆って気密する気密部の少なくとも一部が、前記第一成形品、及び前記第二成形品からなる複合体である、
気密電子部品の製造方法。
1) a step of arranging a first molded product in the vicinity of an airtight region on an electronic substrate;
2) placing the electronic substrate on which the first molded product is disposed on a mold for injection molding, and applying compressive strain to the first molded product by a clamping force; and
3) forming a second molded product that retains the compression strain of the first molded product by injection molding;
Including the steps of
At least a part of an airtight part that is formed on the electronic substrate and covers the airtight region and is airtight is a composite made of the first molded product and the second molded product,
Manufacturing method for airtight electronic components.
前記第一成形品の材料が充填材を含有する熱可塑性樹脂であって、前記圧縮歪が、0.5%以上2.0%以下である、請求項1記載の気密電子部品の製造方法。   The method for manufacturing an airtight electronic component according to claim 1, wherein the material of the first molded article is a thermoplastic resin containing a filler, and the compression strain is 0.5% or more and 2.0% or less. 前記第一成形品を前記電子基板上に射出成形する、請求項1又は2記載の気密電子部品の製造方法。   The manufacturing method of the airtight electronic component of Claim 1 or 2 which injection-molds said 1st molded article on the said electronic substrate. 前記第一成形品の材料が、ポリブチレンテレフタレート樹脂である、請求項1から3何れか記載の気密電子部品の製造方法。   The manufacturing method of the airtight electronic component in any one of Claim 1 to 3 whose material of said 1st molded article is polybutylene terephthalate resin. 請求項1から4何れか記載の方法により製造される気密電子部品。   An airtight electronic component manufactured by the method according to claim 1.
JP2011021473A 2011-02-03 2011-02-03 Method for manufacturing airtight electronic component and airtight electronic component Expired - Fee Related JP5748491B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2011021473A JP5748491B2 (en) 2011-02-03 2011-02-03 Method for manufacturing airtight electronic component and airtight electronic component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2011021473A JP5748491B2 (en) 2011-02-03 2011-02-03 Method for manufacturing airtight electronic component and airtight electronic component

Publications (2)

Publication Number Publication Date
JP2012161921A true JP2012161921A (en) 2012-08-30
JP5748491B2 JP5748491B2 (en) 2015-07-15

Family

ID=46841844

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011021473A Expired - Fee Related JP5748491B2 (en) 2011-02-03 2011-02-03 Method for manufacturing airtight electronic component and airtight electronic component

Country Status (1)

Country Link
JP (1) JP5748491B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017065218A (en) * 2015-10-02 2017-04-06 トヨタ自動車株式会社 Manufacturing method of composite material
JP2020193926A (en) * 2019-05-30 2020-12-03 株式会社ニチリン Gas type inspection device and gas type inspection method of eye joint ferrule-equipped hose

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6750962B2 (en) * 2016-05-09 2020-09-02 ポリプラスチックス株式会社 Insert molded body and electrical connector for fuel pump
MX2020005263A (en) * 2017-12-06 2020-08-24 Sipa Progettazione Automaz Injection-compression molding device.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11202145A (en) * 1998-01-08 1999-07-30 Nippon Telegr & Teleph Corp <Ntt> Optical module and its manufacture
JPH11254477A (en) * 1998-03-13 1999-09-21 Mitsubishi Eng Plast Corp Production of resin-sealed molded product of electric/ electronic part
JP2006130714A (en) * 2004-11-04 2006-05-25 Enomoto Co Ltd Injection molding machine, led device and led device manufactured using injection molding machine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11202145A (en) * 1998-01-08 1999-07-30 Nippon Telegr & Teleph Corp <Ntt> Optical module and its manufacture
JPH11254477A (en) * 1998-03-13 1999-09-21 Mitsubishi Eng Plast Corp Production of resin-sealed molded product of electric/ electronic part
JP2006130714A (en) * 2004-11-04 2006-05-25 Enomoto Co Ltd Injection molding machine, led device and led device manufactured using injection molding machine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017065218A (en) * 2015-10-02 2017-04-06 トヨタ自動車株式会社 Manufacturing method of composite material
JP2020193926A (en) * 2019-05-30 2020-12-03 株式会社ニチリン Gas type inspection device and gas type inspection method of eye joint ferrule-equipped hose
JP7394435B2 (en) 2019-05-30 2023-12-08 株式会社ニチリン Gas inspection method for hoses with eye joint fittings

Also Published As

Publication number Publication date
JP5748491B2 (en) 2015-07-15

Similar Documents

Publication Publication Date Title
JP4396702B2 (en) Composite mold product
JP5748491B2 (en) Method for manufacturing airtight electronic component and airtight electronic component
US7989079B2 (en) Insert-molded cover and method for manufacturing same
JP5378992B2 (en) Resin composition for electronic tag sealing, resin-encapsulated electronic tag, and method for producing the same
TWI638010B (en) Resin composition for insert molding, metal-resin composite formed body using the same, and manufacturing method thereof
US20090280316A1 (en) Joining structure and insert-molded cover using same
CN107109058B (en) Polyarylene sulfide resin composition and insert molded article
WO2016117711A1 (en) Composite of metal member and resin mold, and metal member for forming composite with resin mold
EP2204403A1 (en) Resin composition
JP2017055044A (en) Lead frame
CN105829452A (en) Thermosetting resin composition and metal-resin composite
JP6341508B2 (en) Waterproof connector and method for manufacturing waterproof connector
JP2012245665A (en) Molding method
WO2015129236A1 (en) Resin molded body and manufacturing method therefor
WO2018124807A1 (en) Thermoplastic resin composition for laser direct structuring process and molded article produced therefrom
CN111740281B (en) Box with connector, wire harness with connector and engine control unit
JP2015066846A (en) Method for producing structure and method for producing battery lid
KR102076961B1 (en) Encapsulated Electrical Device and Manufacturing Method
WO2020016788A1 (en) Metal-plastic hybrid structures and methods of making the same
CN111725653A (en) Box with connector, wire harness with connector and engine control unit
JP6413951B2 (en) Resin molded body and manufacturing method thereof
KR20070063858A (en) Method for manufacturing anti-moisture pcb using thermoplastic resin
JP2012176601A (en) Molding die, method of manufacturing thermoplastic resin sealed electronic substrate by injection molding, and thermoplastic resin sealed electronic substrate
WO2022075192A1 (en) Injection molded article and method for producing same
JP2017170806A (en) Composite body of metallic member and resin mold

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20140116

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20141110

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20141118

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20141121

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20150428

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20150512

R150 Certificate of patent or registration of utility model

Ref document number: 5748491

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees