JP2012154463A - Rolling device - Google Patents

Rolling device Download PDF

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JP2012154463A
JP2012154463A JP2011016341A JP2011016341A JP2012154463A JP 2012154463 A JP2012154463 A JP 2012154463A JP 2011016341 A JP2011016341 A JP 2011016341A JP 2011016341 A JP2011016341 A JP 2011016341A JP 2012154463 A JP2012154463 A JP 2012154463A
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iron
rolling
mass
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projection material
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JP5485922B2 (en
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Hiroyuki Uchida
啓之 内田
Takenobu Inaba
武信 稲葉
Masaru Yanagimoto
勝 柳本
Yoshiaki Matsubara
慶明 松原
Takahisa Yamamoto
隆久 山本
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NSK Ltd
Sanyo Special Steel Co Ltd
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Sanyo Special Steel Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a rolling device that has superior lubricity and is long-lived, such as a rolling bearing, a liner guide device, a ball screw, and a linear motion bearing.SOLUTION: On raceway surfaces 1a, 2a and a rolling contact surface 3, shot peening treatment is applied which injects a mixed projection material including a hard injection material composed of iron-base ceramics powder and a soft projection material composed of at least either of soft metal powder and solid lubricant powder, and a composite structure layer 10 and a lubrication coating 12 stacked on the composite structure layer 10 are formed. The iron-base ceramics powder is composed of a FeB system iron-base boride of the area ratio of 50% to 90%, and an iron-base solid solution of the area ratio of 10% to 50%, having a body-centered space lattice structure and/or a face-centered space lattice structure, has a microstructure in which a FeB system iron-base boride is surrounded with an iron-base solid solution, or a microstructure in which a FeB system iron-base boride is surrounded with the eutectic of an iron-base solid solution and a FeB system iron-base boride, and contains a boride of 5 mass% to 8 mass% as element, and the rest is iron and inevitable impurities.

Description

本発明は、転がり軸受,リニアガイド装置,ボールねじ,直動ベアリング等のような転動装置に関する。   The present invention relates to a rolling device such as a rolling bearing, a linear guide device, a ball screw, a linear motion bearing and the like.

転がり軸受においては、軌道輪の軌道面や転動体の転動面に潤滑被膜を設けることにより、潤滑性を向上させて長寿命化する技術が知られている。例えば特許文献1には、クロム粉末又はニッケル粉末のショットピーニングにより潤滑被膜を設ける技術が開示されている。
また、転がり軸受の軌道輪の軌道面に圧縮残留応力を付与することにより、軌道面の損傷を抑制して長寿命化する技術が知られている。特許文献2には、略球状のセラミック粒子のショットピーニングにより圧縮残留応力を付与する技術が開示されている。
In rolling bearings, a technique is known in which a lubricating coating is provided on a raceway surface of a raceway ring or a rolling surface of a rolling element to improve lubricity and extend the life. For example, Patent Document 1 discloses a technique for providing a lubricating coating by shot peening of chromium powder or nickel powder.
In addition, a technique is known in which a compressive residual stress is applied to the raceway surface of the bearing ring of a rolling bearing to suppress damage to the raceway surface and extend the life. Patent Document 2 discloses a technique for applying compressive residual stress by shot peening of substantially spherical ceramic particles.

特開2007−146890号公報JP 2007-146890 A 特開2008−151235号公報JP 2008-151235 A 特開2008−51180号公報JP 2008-51180 A 特許第2949794号公報Japanese Patent No. 2949794 特開2008−138262号公報JP 2008-138262 A 特開2007−50766号公報Japanese Patent Laid-Open No. 2007-50766 特開2000−230544号公報JP 2000-230544 A 特開2006−329319号公報JP 2006-329319 A

しかしながら、特許文献1に開示の技術により形成された潤滑被膜は、母材の表面に対する密着性が十分ではないという問題があった。そのため、潤滑被膜が母材の表面から剥離して潤滑性が低下し、十分な長寿命化が達成されない場合があった。
また、特許文献2に開示の技術では、母材の表面に被膜が形成されて保護されるわけではないので、希薄潤滑環境下では転がり軸受に潤滑不良が生じるおそれがあるという問題があった。
そこで、本発明は上記のような従来技術が有する問題点を解決し、潤滑性に優れ長寿命な転動装置を提供することを課題とする。
However, the lubricating coating formed by the technique disclosed in Patent Document 1 has a problem that the adhesion to the surface of the base material is not sufficient. For this reason, the lubricating coating is peeled off from the surface of the base material, the lubricity is lowered, and there is a case where a sufficiently long life is not achieved.
Further, the technique disclosed in Patent Document 2 has a problem in that a rolling bearing may have a poor lubrication in a dilute lubrication environment because a coating is not formed on the surface of the base material to be protected.
SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to solve the above-described problems of the prior art and to provide a rolling device that is excellent in lubricity and has a long life.

前記課題を解決するため、本発明は次のような構成からなる。すなわち、本発明の一態様に係る転動装置は、互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素を含有し、残部が鉄及び不可避的不純物であることを特徴とする。 In order to solve the above problems, the present invention has the following configuration. That is, the rolling device according to one aspect of the present invention includes a first member and a second member having raceways arranged to face each other, a raceway surface of the first member, and a raceway surface of the second member. A rolling device arranged such that it can freely roll between, wherein one of the first member and the second member moves relative to the other through the rolling of the rolling member, At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element has a hard projecting material made of iron-based ceramic powder, soft metal powder, and solid lubricant powder. A shot peening process for injecting a mixed projection material including at least one soft projection material, and a composite tissue layer in which the soft projection material permeates a base material and the soft projection material. A lubricating coating laminated on the composite structure layer; Is formed, the iron-based ceramic powder has a Fe 2 B Keitetsumoto borides 50% to 90% in area ratio, a body-centered cubic lattice structure and / or face-centered cubic lattice structure, the area ratio in 10% to 50% of the iron-based solid solution, made from the Fe 2 B Keitetsumoto microstructure around the boride enclosed said iron-based solid solution, or, in the Fe 2 B Keitetsumoto borides In addition to having a microstructure surrounded by a eutectic of the iron-based solid solution and the Fe 2 B-based iron-based boride, the element contains 5% by mass to 8% by mass of boron, with the balance being iron And inevitable impurities.

また、本発明の別の態様に係る転動装置は、互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする。 Moreover, the rolling device according to another aspect of the present invention includes a first member and a second member having raceways arranged to face each other, a raceway surface of the first member, and a raceway surface of the second member. A rolling element that is arranged so as to be freely rollable between the rolling elements, wherein one of the first member and the second member moves relative to the other through the rolling of the rolling element. At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder A shot peening process for injecting a mixed projection material comprising at least one of the above, a composite tissue layer in which the soft projection material penetrates the base material, and the soft projection material And a lubricating coating laminated on the composite structure layer, It made which are, the iron-based ceramic powder has a Fe 2 B Keitetsumoto borides 90% more than 50% or less in area ratio, a body-centered cubic lattice structure and / or face-centered cubic lattice structure, the area ratio in 10% to 50% of the iron-based solid solution, made from the Fe 2 B Keitetsumoto microstructure around the boride enclosed said iron-based solid solution, or, in the Fe 2 B Keitetsumoto borides In addition to having a microstructure surrounded by a eutectic of the iron-based solid solution and the Fe 2 B-based iron-based boride, the element contains 5% by mass to 8% by mass of boron, and 10% by mass or less. It contains at least one of titanium and molybdenum of 10% by mass or less, and the balance is iron and inevitable impurities.

さらに、本発明のさらに別の態様に係る転動装置は、互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする。 Furthermore, the rolling device according to still another aspect of the present invention includes a first member and a second member having raceways arranged to face each other, a raceway surface of the first member, and a raceway surface of the second member. A rolling element that is arranged so as to be freely rotatable between the first member and the second member via the rolling of the rolling element. At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant A shot peening process for injecting a mixed projection material comprising at least one of powder, and a composite tissue layer in which the soft projection material permeates a base material, and the soft projection material A lubrication jacket constructed and laminated on the composite structure layer When has been formed, the iron-based ceramic powder has a Fe 2 B Keitetsumoto borides 90% more than 50% or less in area ratio, a body-centered cubic lattice structure and / or face-centered cubic lattice structure , the iron-based solid solution of 10% to 50% in area ratio, made, the Fe 2 B Keitetsumoto microstructure around the boride enclosed said iron-based solid solution, or the Fe 2 B Keitetsumoto While having a microstructure in which the eutectic of the iron-based solid solution and the Fe 2 B-based iron-based boride is surrounded around the boride, the element contains 5% by mass to 8% by mass of boron, and 25% by mass. % Or less of chromium and 10% by mass or less of nickel, and the balance is iron and inevitable impurities.

さらに、本発明のさらに別の態様に係る転動装置は、互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする転動装置。 Furthermore, the rolling device according to still another aspect of the present invention includes a first member and a second member having raceways arranged to face each other, a raceway surface of the first member, and a raceway surface of the second member. A rolling element that is arranged so as to be freely rotatable between the first member and the second member via the rolling of the rolling element. At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant A shot peening process for injecting a mixed projection material comprising at least one of powder, and a composite tissue layer in which the soft projection material permeates a base material, and the soft projection material A lubrication jacket constructed and laminated on the composite structure layer When has been formed, the iron-based ceramic powder has a Fe 2 B Keitetsumoto borides 90% more than 50% or less in area ratio, a body-centered cubic lattice structure and / or face-centered cubic lattice structure , the iron-based solid solution of 10% to 50% in area ratio, made, the Fe 2 B Keitetsumoto microstructure around the boride enclosed said iron-based solid solution, or the Fe 2 B Keitetsumoto While having a microstructure in which the eutectic of the iron-based solid solution and the Fe 2 B-based iron-based boride is surrounded around the boride, the element contains 5% by mass to 8% by mass of boron, and 10% by mass. % Of titanium and 10% by mass or less of molybdenum and 25% by mass or less of chromium and 10% by mass or less of nickel, and the balance being iron and inevitable impurities Rolling device

これらの各態様に係る転動装置においては、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち前記ショットピーニング処理が施された面は、表面における残留応力が−1500MPa以上−500MPa以下で、表面から10μm内側の深さ位置における残留応力が−200MPa以下であることが好ましい。
また、前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち前記ショットピーニング処理が施された面は、面積率で1%以上の部分に、前記潤滑被膜を備えていることが好ましい。
In the rolling device according to each of these aspects, the surface subjected to the shot peening treatment among the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element is a surface. It is preferable that the residual stress at −1500 MPa or more and −500 MPa or less and the residual stress at a depth position 10 μm inside from the surface is −200 MPa or less.
Further, the surface subjected to the shot peening treatment among the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element is an area ratio of 1% or more, A lubricating coating is preferably provided.

さらに、前記軟質金属粉末は、平均粒径が1μm以上70μm以下であり、錫,亜鉛,銅,ニッケル,クロム,及びチタンのうち少なくとも1種を含有するとともに、前記固体潤滑剤粉末は、平均粒径が1μm以上70μm以下であり、二硫化モリブデン,グラファイト,及びポリテトラフルオロエチレンのうち少なくとも1種を含有することが好ましい。
さらに、前記混合投射材のうちの前記硬質投射材の割合は30質量%以上90質量%以下であることが好ましい。
さらに、前記混合投射材の噴射圧力が0.2MPa以上0.8MPa以下で、噴射時間が5分以上30分以下であることが好ましい。
Further, the soft metal powder has an average particle size of 1 μm or more and 70 μm or less, and contains at least one of tin, zinc, copper, nickel, chromium, and titanium, and the solid lubricant powder has an average particle size of The diameter is preferably 1 μm or more and 70 μm or less, and preferably contains at least one of molybdenum disulfide, graphite, and polytetrafluoroethylene.
Furthermore, it is preferable that the ratio of the hard projection material in the mixed projection material is 30% by mass or more and 90% by mass or less.
Furthermore, it is preferable that the injection pressure of the mixed projection material is 0.2 MPa or more and 0.8 MPa or less and the injection time is 5 minutes or more and 30 minutes or less.

なお、本発明は種々の転動装置に適用することができる。例えば、転がり軸受,ボールねじ,リニアガイド装置,直動ベアリング等である。また、本発明における第一部材とは、転動装置が転がり軸受の場合には内輪、同じくボールねじの場合にはねじ軸、同じくリニアガイド装置の場合には案内レール、同じく直動ベアリングの場合には軸をそれぞれ意味する。また、第二部材とは、転動装置が転がり軸受の場合には外輪、同じくボールねじの場合にはナット、同じくリニアガイド装置の場合にはスライダ、同じく直動ベアリングの場合には外筒をそれぞれ意味する。   The present invention can be applied to various rolling devices. For example, a rolling bearing, a ball screw, a linear guide device, a linear motion bearing, and the like. The first member in the present invention is an inner ring when the rolling device is a rolling bearing, a screw shaft when it is a ball screw, a guide rail when it is a linear guide device, and a linear motion bearing. Means each axis. The second member is an outer ring when the rolling device is a rolling bearing, a nut when it is a ball screw, a slider when it is a linear guide device, and an outer cylinder when it is also a linear bearing. Each means.

本発明の転動装置は、第一部材の軌道面,第二部材の軌道面,及び転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、軟質投射材が母材に浸透してなる複合組織層と、軟質投射材で構成され複合組織層の上に積層された潤滑被膜と、が形成されているので、潤滑性に優れ長寿命である。   The rolling device according to the present invention includes a hard projection material made of iron-based ceramic powder and a soft metal powder on at least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element. And a soft projection material composed of at least one of solid lubricant powder, and a shot peening process for injecting a mixed projection material including the composite structure layer in which the soft projection material penetrates the base material, and the soft projection Since the lubricating film made of the material and laminated on the composite structure layer is formed, it has excellent lubricity and has a long life.

本発明に係る転動装置の一実施形態である深溝玉軸受の構造を示す部分縦断面図である。It is a fragmentary longitudinal cross-section which shows the structure of the deep groove ball bearing which is one Embodiment of the rolling device which concerns on this invention. ショットピーニング処理を説明する工程図である。It is process drawing explaining a shot peening process. 残留応力の測定結果を示すグラフである。It is a graph which shows the measurement result of residual stress.

本発明に係る転動装置の実施の形態を、図面を参照しつつ詳細に説明する。図1は、本発明に係る転動装置の一実施形態である深溝玉軸受の構造を示す部分縦断面図である。
図1の深溝玉軸受は、外周面に軌道面1aを有する内輪1(第一部材)と、内輪1の軌道面1aに対向する軌道面2aを内周面に有する外輪2(第二部材)と、両軌道面1a,2a間に転動自在に配された複数の転動体(玉)3と、内輪1及び外輪2の間に転動体3を保持する保持器4と、内輪1及び外輪2の間の隙間の開口を覆う密封装置5,5(例えば接触又は非接触ゴムシールやシールド)と、を備えており、転動体3の転動を介して内輪1及び外輪2の一方が他方に対して相対回転運動可能となっている。
DESCRIPTION OF EMBODIMENTS Embodiments of a rolling device according to the present invention will be described in detail with reference to the drawings. FIG. 1 is a partial longitudinal sectional view showing a structure of a deep groove ball bearing which is an embodiment of a rolling device according to the present invention.
The deep groove ball bearing of FIG. 1 includes an inner ring 1 (first member) having a raceway surface 1a on an outer peripheral surface and an outer ring 2 (second member) having a raceway surface 2a facing the raceway surface 1a of the inner ring 1 on the inner peripheral surface. A plurality of rolling elements (balls) 3 that are arranged to freely roll between the raceway surfaces 1a and 2a, a cage 4 that holds the rolling elements 3 between the inner ring 1 and the outer ring 2, and an inner ring 1 and an outer ring. Sealing devices 5 and 5 (for example, contact or non-contact rubber seals or shields) covering the opening of the gap between the two, and one of the inner ring 1 and the outer ring 2 is switched to the other through the rolling of the rolling element 3. On the other hand, relative rotation is possible.

そして、内輪1と外輪2と密封装置5,5とで囲まれた軸受内部空間内には、両軌道面1a,2aと転動体3の転動面3aとの潤滑を行う潤滑剤G(例えば潤滑油,グリース)が配されていて、密封装置5,5により軸受内部空間内に密封されている。なお、保持器4,密封装置5,潤滑剤Gは備えていなくてもよい。
内輪1の軌道面1a、外輪2の軌道面2a、及び転動体3の転動面3aのうち少なくとも一つには、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されている。
In the bearing inner space surrounded by the inner ring 1, the outer ring 2, and the sealing devices 5, 5, a lubricant G (for example, a lubricant G that lubricates both the raceway surfaces 1 a, 2 a and the rolling surface 3 a of the rolling element 3). (Lubricating oil, grease) is disposed and sealed in the bearing internal space by the sealing devices 5 and 5. Note that the cage 4, the sealing device 5, and the lubricant G may not be provided.
At least one of the raceway surface 1a of the inner ring 1, the raceway surface 2a of the outer ring 2, and the rolling surface 3a of the rolling element 3 has a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder. A shot peening process for injecting a mixed projection material including at least one of the soft projection materials is performed.

内輪1,外輪2,及び転動体3は、軸受鋼等の金属材料(母材)で構成されているが、前記ショットピーニング処理の結果、ショットピーニング処理が施された被処理面には、複合組織層10と、複合組織層10の上に積層された潤滑被膜12と、が形成されている(図2を参照)。
複合組織層10は、硬質投射材が噴射されることにより塑性流動している母材に、軟質投射材が浸透して(入り込んで)なる層である。また、潤滑被膜12は、複合組織層10上に軟質投射材が付着して形成された被膜である。
The inner ring 1, the outer ring 2, and the rolling element 3 are made of a metal material (base material) such as bearing steel. As a result of the shot peening process, the processed surface subjected to the shot peening process is complex. A tissue layer 10 and a lubricating film 12 laminated on the composite tissue layer 10 are formed (see FIG. 2).
The composite structure layer 10 is a layer in which a soft projection material penetrates (enters) a base material that is plastically flowed by injection of a hard projection material. The lubricating coating 12 is a coating formed by attaching a soft projection material on the composite tissue layer 10.

軌道面1a,2aや転動面3aが潤滑被膜12で覆われているので、本実施形態の深溝玉軸受は潤滑性に優れており、特に、希薄潤滑環境下においても潤滑不良を起こすことなく、ピーリング等の表面損傷が生じにくくなっている。また、母材と潤滑被膜12との間に、折り畳み効果によって形成された複合組織層10が中間層として介在しているので、母材に対する潤滑被膜12の密着性が優れている。よって、母材からの潤滑被膜12の剥離が生じにくいので、潤滑性の低下が生じにくい。このようなことから、本実施形態の深溝玉軸受は、潤滑性に優れ長寿命である。   Since the raceway surfaces 1a and 2a and the rolling surface 3a are covered with the lubricating film 12, the deep groove ball bearing of this embodiment has excellent lubricity, and in particular, does not cause poor lubrication even in a lean lubrication environment. Surface damage such as peeling is less likely to occur. Moreover, since the composite structure layer 10 formed by the folding effect is interposed as an intermediate layer between the base material and the lubricating coating 12, the adhesion of the lubricating coating 12 to the base material is excellent. Therefore, since the lubricating coating 12 is hardly peeled off from the base material, the lubricity is hardly lowered. For these reasons, the deep groove ball bearing of this embodiment has excellent lubricity and a long life.

また、混合投射材を噴射することにより、複合組織層10と潤滑被膜12が形成されるので、硬質投射材を噴射した後に軟質投射材を噴射する方法と比べると、工程数を削減することができる。また、硬質投射材と軟質投射材を別々に噴射する前記方法では、複合組織層が形成されないので、潤滑被膜が母材から剥離しやすいが、本実施形態のショットピーニング処理によれば複合組織層10が形成されるため、潤滑被膜12が母材から剥離しにくい。
深溝玉軸受の潤滑性を十分に高めて長寿命とするためには、被処理面(軌道面1a,2aや転動面3a)のうち潤滑被膜を備えている部分は、面積率で1%以上とすることが好ましい。
Moreover, since the composite structure layer 10 and the lubricating coating 12 are formed by injecting the mixed projection material, the number of steps can be reduced as compared with the method of injecting the soft projection material after injecting the hard projection material. it can. Further, in the above-described method of spraying the hard projection material and the soft projection material separately, since the composite structure layer is not formed, the lubricating coating is easily peeled off from the base material, but according to the shot peening process of this embodiment, the composite structure layer 10 is formed, the lubricating coating 12 is difficult to peel off from the base material.
In order to sufficiently enhance the lubricity of the deep groove ball bearing and to have a long service life, the portion of the surface to be treated (the raceway surfaces 1a and 2a and the rolling surface 3a) having a lubricating coating is 1% in area ratio. The above is preferable.

また、硬質投射材が噴射されることにより、被処理面には高い圧縮残留応力が付与されている。これにより、軌道面1a,2aや転動面3aの疲労強度が向上するため、本実施形態の深溝玉軸受は長寿命である。疲労強度を十分に向上させるためには、被処理面の表面における残留応力は、−1500MPa以上−500MPa以下とすることが好ましく、表面から10μm内側の深さ位置における残留応力は、−200MPa以下とすることが好ましい。   Moreover, high compressive residual stress is provided to the to-be-processed surface by injecting a hard projection material. Thereby, since the fatigue strength of the raceway surfaces 1a and 2a and the rolling surface 3a is improved, the deep groove ball bearing of this embodiment has a long life. In order to sufficiently improve the fatigue strength, the residual stress on the surface of the processing surface is preferably −1500 MPa or more and −500 MPa or less, and the residual stress at a depth position 10 μm inside from the surface is −200 MPa or less. It is preferable to do.

さらに、硬質投射材は再利用することが可能であるため、噴射後の硬質投射材を回収することにより、繰り返しショットピーニング処理に供することができる。その結果、ショットピーニング処理のコストを低減することができる。なお、混合投射材のうちの硬質投射材の割合は、30質量%以上90質量%以下であることが好ましい。30質量%未満であると、残留応力を十分に付与できないおそれがある。一方、90質量%超過であると、潤滑被膜12が形成されにくくなるおそれがある。   Furthermore, since the hard projection material can be reused, it is possible to repeatedly perform shot peening treatment by collecting the hard projection material after injection. As a result, the cost of the shot peening process can be reduced. In addition, it is preferable that the ratio of the hard projection material among mixed projection materials is 30 mass% or more and 90 mass% or less. If it is less than 30% by mass, the residual stress may not be sufficiently applied. On the other hand, if it exceeds 90% by mass, the lubricating coating 12 may be difficult to be formed.

さらに、ショットピーニング処理においては、混合投射材の噴射圧力は0.2MPa以上0.8MPa以下とすることが好ましく、噴射時間は5分以上30分以下とすることが好ましい。噴射時間が5分未満であると、ショットピーニング処理が十分に施されないおそれがある。一方、30分を超えて行っても、それ以上の効果が期待できないばかりか、コストが高くなる。
ここで、鉄基セラミックス粉末について詳細に説明する。鉄基セラミックス粉末は、元素としては鉄(Fe)を主成分とし、ホウ素(B)を5質量%以上8質量%以下含有する鉄基セラミックスの粉末である。すなわち、元素としては5質量%以上8質量%以下のホウ素を含有し、残部が鉄及び不可避的不純物である。
Furthermore, in the shot peening treatment, the spray pressure of the mixed projection material is preferably 0.2 MPa or more and 0.8 MPa or less, and the spray time is preferably 5 minutes or more and 30 minutes or less. If the injection time is less than 5 minutes, the shot peening process may not be sufficiently performed. On the other hand, even if it goes beyond 30 minutes, not only the effect cannot be expected, but the cost becomes high.
Here, the iron-based ceramic powder will be described in detail. The iron-based ceramic powder is an iron-based ceramic powder containing iron (Fe) as a main component and boron (B) in an amount of 5% by mass to 8% by mass. That is, the element contains 5% by mass or more and 8% by mass or less of boron, with the balance being iron and inevitable impurities.

このような組成により、この鉄基セラミックスは、Fe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する鉄基固溶体と、からなり、Fe2 B系鉄基ホウ化物の相と、体心立方格子構造及び/又は面心立方格子構造を有する鉄基固溶体の相との過共晶組織を有する。Fe2 B系鉄基ホウ化物と鉄基固溶体との比率は、面積率で、Fe2 B系鉄基ホウ化物:鉄基固溶体=50%:50%〜90%:10%である。なお、この面積率は、鉄基セラミックス粉末を樹脂埋めした試料の反射電子像を画像解析することにより求めることができる。 With such a composition, this iron-based ceramic is composed of an Fe 2 B-based iron-based boride and an iron-based solid solution having a body-centered cubic lattice structure and / or a face-centered cubic lattice structure, and Fe 2 B-based iron It has a hypereutectic structure of a phase of a base boride and a phase of an iron-based solid solution having a body-centered cubic lattice structure and / or a face-centered cubic lattice structure. Fe 2 B Keitetsumoto boride and the ratio of the iron-based solid solution, an area ratio, Fe 2 B Keitetsumoto borides: iron solid solution = 50%: 50% to 90%: 10%. The area ratio can be obtained by image analysis of a backscattered electron image of a sample in which iron-based ceramic powder is filled with resin.

また、この鉄基セラミックスは、Fe2 B系鉄基ホウ化物の周りを鉄基固溶体が囲んだミクロ組織、又は、Fe2 B系鉄基ホウ化物の周りを、鉄基固溶体とFe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有する。
このような鉄基セラミックスは、アトマイズ法又は急冷リボン粉砕法により製造することができる。これらの方法で製造することにより、初晶となる高硬度なFe2 B系鉄基ホウ化物を、高靱性な鉄基固溶体もしくは該鉄基固溶体とFe2 B系鉄基ホウ化物の共晶物が取り囲むミクロ組織とすることができるので、HV1000超過という高硬度と一般的なセラミックス以上の高靱性とが両立されるとともに、安価である。
Further, the iron-based ceramics, Fe 2 B Keitetsumoto microstructure surrounded the iron-based solid solution around the boride, or around the Fe 2 B Keitetsumoto boride, iron solid solution and Fe 2 B system It has a microstructure surrounded by eutectic with iron-based borides.
Such an iron-based ceramic can be produced by an atomizing method or a quenching ribbon crushing method. By producing by these methods, a high-hardness Fe 2 B-based iron-based boride that becomes primary crystals is converted into a tough iron-based solid solution or an eutectic of the iron-based solid solution and Fe 2 B-based iron-based boride. Therefore, it is possible to achieve both a high hardness exceeding HV1000 and a high toughness higher than that of general ceramics, and at a low cost.

Fe2 B系鉄基ホウ化物は、Fe2 Bの融点が比較的低温(約1400℃)であるため、アトマイズ法や急冷リボン粉砕法による製造が可能であるとととに、高硬度(HV1400程度)であり、さらに安価な原材料を用いて製造できる。Fe2 B系鉄基ホウ化物の比率が面積率で50%未満であると、十分な硬度が得られにくく、90%超過であると、十分な靱性が得られにくい。 Fe 2 B iron-based boride has a relatively low melting point of Fe 2 B (about 1400 ° C.) and can be produced by an atomizing method or a rapid ribbon pulverization method. It can be manufactured using cheaper raw materials. If the ratio of the Fe 2 B iron-based boride is less than 50% in terms of area ratio, it is difficult to obtain sufficient hardness, and if it exceeds 90%, it is difficult to obtain sufficient toughness.

また、鉄基固溶体は、硬質相としてFe2 B系鉄基ホウ化物を利用していることから、最終凝固部位は高靱性な鉄基固溶体又は鉄基固溶体とFe2 B系鉄基ホウ化物との共晶物となる。また、この鉄基固溶体の構成相は、固溶元素や冷却速度,熱処理などにより、体心立方格子構造及び/又は面心立方格子構造となり得るが、両相ともに十分な靱性を有しているため、いずれか一方でも両方でも差し支えない。鉄基固溶体の比率が面積率で10%未満であると、十分な靱性が得られにくく、50%超過であると、十分な硬度が得られにくい。 Further, since the iron-based solid solution uses Fe 2 B-based iron-based boride as the hard phase, the final solidification site is a tough iron-based solid solution or iron-based solid solution and Fe 2 B-based iron-based boride. Eutectic. In addition, the constituent phase of the iron-based solid solution can have a body-centered cubic lattice structure and / or a face-centered cubic lattice structure depending on the solid solution element, cooling rate, heat treatment, etc., but both phases have sufficient toughness. Therefore, either one or both can be used. When the ratio of the iron-based solid solution is less than 10% in terms of area ratio, it is difficult to obtain sufficient toughness, and when it exceeds 50%, it is difficult to obtain sufficient hardness.

さらに、鉄基セラミックス中のホウ素の含有量が5質量%未満であると、Fe2 Bが少なくなって十分な硬度が得られにくい。一方、8質量%を超えると、Fe2 Bが多すぎるため、十分な靱性が得られにくい。
さらに、鉄基セラミックスが、Fe2 B系鉄基ホウ化物の周りを鉄基固溶体が囲んだミクロ組織、又は、Fe2 B系鉄基ホウ化物の周りを、鉄基固溶体とFe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有することにより、高硬度相を高靱性相が取り囲むこととなるので、高硬度と高靱性を両立することができる。
Furthermore, if the boron content in the iron-based ceramic is less than 5% by mass, Fe 2 B is reduced and it is difficult to obtain sufficient hardness. On the other hand, if it exceeds 8 mass%, since Fe 2 B is too large, sufficient toughness is difficult to obtain.
Further, the iron-based ceramics, Fe 2 B Keitetsumoto microstructure surrounded the iron-based solid solution around the boride, or around the Fe 2 B Keitetsumoto boride, iron solid solution and Fe 2 B-type iron By having a microstructure surrounded by the eutectic with the base boride, the high toughness phase surrounds the high hardness phase, so that both high hardness and high toughness can be achieved.

ただし、元素として、5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物である鉄基セラミックスを用いることもできる。また、元素として、5質量%以上8質量%以下のホウ素と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物である鉄基セラミックスを用いることもできる。さらに、元素として、5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物である鉄基セラミックスを用いることもできる。   However, as an element, an iron group containing 5% by mass or more and 8% by mass or less of boron, 10% by mass or less of titanium, and 10% by mass or less of molybdenum, with the balance being iron and inevitable impurities. Ceramics can also be used. Further, an iron group containing 5% by mass or more and 8% by mass or less of boron as an element and at least one of 25% by mass or less of chromium and 10% by mass or less of nickel, with the balance being iron and inevitable impurities Ceramics can also be used. Furthermore, as an element, at least one of 5% by mass to 8% by mass of boron, 10% by mass of titanium and 10% by mass of molybdenum, 25% by mass of chromium and 10% by mass of nickel at least On the other hand, iron-based ceramics containing iron and the balance being iron and inevitable impurities can also be used.

投射材は大気中で保管されることが多いが、保管時又は使用時に発錆しないことが好ましい。クロム及びニッケルは耐食性を改善する作用を有しているため、クロムの場合は25質量%以下、ニッケルの場合は10質量%以下の範囲内で添加することが好ましい。ただし、これらの上限値を超えると融点が上昇し、アトマイズ法や急冷リボン粉砕法による製造が困難となる。
また、チタン及びモリブデンは、いずれも硬度を向上させる目的で添加される。ただし、10質量%を超えると融点が上昇し、アトマイズ法や急冷リボン粉砕法による鉄基セラミックスの製造が困難となる。
The projection material is often stored in the atmosphere, but it is preferable that the projection material does not rust during storage or use. Since chromium and nickel have the effect of improving the corrosion resistance, it is preferable to add them in the range of 25% by mass or less in the case of chromium and 10% by mass or less in the case of nickel. However, when these upper limit values are exceeded, the melting point rises, making it difficult to produce by the atomizing method or the quenching ribbon crushing method.
Titanium and molybdenum are both added for the purpose of improving the hardness. However, if it exceeds 10% by mass, the melting point rises, making it difficult to produce iron-based ceramics by the atomizing method or the quenching ribbon pulverization method.

次に、軟質金属粉末及び固体潤滑剤粉末について説明する。軟質金属粉末の種類は特に限定されるものではないが、錫,亜鉛,銅,ニッケル,クロム,及びチタンの粉末が好ましい。また、これらの金属の粉末のうち2種以上を混合した混合粉末でもよい。軟質金属粉末の平均粒径は、1μm以上70μm以下であることが好ましい。
また、固体潤滑剤粉末の種類は特に限定されるものではないが、二硫化モリブデン,グラファイト,及びポリテトラフルオロエチレンの粉末が好ましい。また、これらの固体潤滑剤の粉末のうち2種以上を混合した混合粉末でもよい。固体潤滑剤粉末の平均粒径は、1μm以上70μm以下であることが好ましい。
軟質金属粉末及び固体潤滑剤粉末の平均粒径が1μm未満であると、ショットピーニング処理の際に粉末が舞って飛散しやすいため、処理が困難となるおそれがある。一方、70μm超過であると、被処理面の表面粗さが粗くなるため、軌道面や転動面として不適となるおそれがある。
Next, the soft metal powder and the solid lubricant powder will be described. The kind of soft metal powder is not particularly limited, but powders of tin, zinc, copper, nickel, chromium, and titanium are preferable. Moreover, the mixed powder which mixed 2 or more types of these metal powders may be sufficient. The average particle size of the soft metal powder is preferably 1 μm or more and 70 μm or less.
The type of solid lubricant powder is not particularly limited, but molybdenum disulfide, graphite, and polytetrafluoroethylene powders are preferred. Also, a mixed powder obtained by mixing two or more of these solid lubricant powders may be used. The average particle size of the solid lubricant powder is preferably 1 μm or more and 70 μm or less.
If the average particle size of the soft metal powder and the solid lubricant powder is less than 1 μm, the powder tends to fly and scatter during the shot peening process, which may make the process difficult. On the other hand, if it exceeds 70 μm, the surface roughness of the surface to be processed becomes rough, which may be inappropriate as a raceway surface or a rolling surface.

なお、本実施形態は本発明の一例を示したものであって、本発明は本実施形態に限定されるものではない。例えば、内輪1,外輪2,及び転動体3を構成する金属材料(母材)として、SUJ2,SUJ3に代表される軸受用の高炭素クロム鋼を用いてもよいし、SCM420,SCr420等の浸炭鋼やステンレス鋼を用いてもよい。さらに、内輪1,外輪2,及び転動体3は、同一種の金属材料で構成する必要はなく、例えば、転動体3と内輪1,外輪2とを異なる鋼種としてもよい。   In addition, this embodiment shows an example of this invention and this invention is not limited to this embodiment. For example, as the metal material (base material) constituting the inner ring 1, the outer ring 2, and the rolling element 3, high-carbon chromium steel for bearings represented by SUJ2 and SUJ3 may be used, and carburizing such as SCM420 and SCr420. Steel or stainless steel may be used. Furthermore, the inner ring 1, the outer ring 2, and the rolling element 3 do not need to be made of the same type of metal material. For example, the rolling element 3, the inner ring 1, and the outer ring 2 may be different steel types.

また、本実施形態においては、転動装置の例として深溝玉軸受をあげて説明したが、転がり軸受の種類は深溝玉軸受に限定されるものではなく、本発明は様々な種類の転がり軸受に対して適用することができる。例えば、アンギュラ玉軸受,自動調心玉軸受,自動調心ころ軸受,針状ころ軸受,円すいころ軸受,円筒ころ軸受等のラジアル形の転がり軸受や、スラスト玉軸受,スラストころ軸受等のスラスト形の転がり軸受である。さらに、本発明は、転がり軸受に限らず、他の種類の様々な転動装置に対して適用することができる。例えば、ボールねじ,リニアガイド装置,直動ベアリング等である。   Further, in the present embodiment, the deep groove ball bearing has been described as an example of the rolling device, but the type of the rolling bearing is not limited to the deep groove ball bearing, and the present invention is applicable to various types of rolling bearings. It can be applied to. For example, radial rolling bearings such as angular contact ball bearings, self-aligning ball bearings, self-aligning roller bearings, needle roller bearings, tapered roller bearings, cylindrical roller bearings, and thrust types such as thrust ball bearings and thrust roller bearings This is a rolling bearing. Furthermore, the present invention can be applied not only to rolling bearings but also to various types of various rolling devices. For example, a ball screw, a linear guide device, a linear motion bearing, or the like.

〔実施例〕
以下に、実施例を示して、本発明をさらに具体的に説明する。まず、スラストころ軸受の転動体であるころに、ショットピーニング処理を施して、被処理面の残留応力を測定した結果について説明する。
ガスアトマイズ法により製造した平均粒径44μmのFeCrBセラミックス粉末と、平均粒径38μmの錫粉末と、これら両粉末の混合粉末(FeCrBセラミックス粉末:錫粉末=3質量部:1質量部)と、を用意して、投射材とした。
〔Example〕
Hereinafter, the present invention will be described more specifically with reference to examples. First, a description will be given of a result of performing shot peening treatment on a roller that is a rolling element of a thrust roller bearing and measuring a residual stress on the surface to be treated.
An FeCrB ceramic powder having an average particle size of 44 μm manufactured by a gas atomization method, a tin powder having an average particle size of 38 μm, and a mixed powder of these two powders (FeCrB ceramic powder: tin powder = 3 parts by mass: 1 part by mass) are prepared. And it was set as the projection material.

直径3mm、長さ6mmのころの円筒面に各投射材をそれぞれ噴射して(噴射圧力は0.4MPa、噴射時間は20分)、ショットピーニング処理を施した。混合粉末を用いてショットピーニング処理を施したころを実施例1、錫粉末を用いてショットピーニング処理を施したころを比較例1、FeCrBセラミックス粉末を用いてショットピーニング処理を施したころを比較例2とする。なお、錫粉末を用いてショットピーニング処理を施したころに関しては、前処理として、FeCrBセラミックス粉末を用いたショットピーニング処理を行い、その後に錫粉末を用いたショットピーニング処理を行っている。   Each blasting material was sprayed onto a cylindrical surface of a roller having a diameter of 3 mm and a length of 6 mm (spray pressure was 0.4 MPa, spray time was 20 minutes), and a shot peening treatment was performed. Example 1 shows a roller subjected to shot peening treatment using mixed powder, Comparative Example 1 shows a roller subjected to shot peening treatment using tin powder, and Comparative Example shows a roller subjected to shot peening treatment using FeCrB ceramic powder. 2. In addition, about the roller which performed the shot peening process using the tin powder, the shot peening process using the FeCrB ceramic powder is performed as the pretreatment, and the shot peening process using the tin powder is performed thereafter.

得られた上記3種のころ及び未処理のころについて、表面(円筒面)における残留応力と、表面から所定深さ内側の深さ位置における残留応力とを測定した。結果を図3のグラフに示す。図3のグラフから分かるように、混合粉末を用いてショットピーニング処理を施した場合は、未処理品と比べて、表面における圧縮残留応力が約1.2倍高かった。また、表面から10μm内側の深さ位置においても、表面と同等の圧縮残留応力が付与されていた。
さらに、表面分析により、表面に付着した錫の量を測定した結果、実施例1については面積率で10%、比較例1については面積率で40%であった。
With respect to the obtained three types of rollers and untreated rollers, the residual stress on the surface (cylindrical surface) and the residual stress at the depth position inside the predetermined depth from the surface were measured. The results are shown in the graph of FIG. As can be seen from the graph of FIG. 3, when the shot peening treatment was performed using the mixed powder, the compressive residual stress on the surface was about 1.2 times higher than that of the untreated product. In addition, a compressive residual stress equivalent to the surface was applied even at a depth position 10 μm inside from the surface.
Furthermore, as a result of measuring the amount of tin adhering to the surface by surface analysis, the area ratio for Example 1 was 10%, and the area ratio for Comparative Example 1 was 40%.

次に、ころ軸受の寿命試験を行った。鏡面処理を施したSUJ2製のフラットワッシャーを内外輪とし、これと上記のころ14個及び保持器を組み立てて、ころ軸受を得た。このころ軸受に、6370Nのスラスト荷重を印加し、室温下で回転速度1000min-1で回転させた。なお、粘度10cStの鉱油を潤滑剤として用いて、ころ軸受の潤滑を行った。 Next, a life test of the roller bearing was performed. A flat washer made of SUJ2 subjected to mirror surface treatment was used as an inner and outer ring, and this was assembled with 14 rollers and a cage to obtain a roller bearing. A thrust load of 6370 N was applied to the roller bearing, and the roller bearing was rotated at a rotation speed of 1000 min −1 at room temperature. The roller bearing was lubricated using mineral oil having a viscosity of 10 cSt as a lubricant.

1種のころ軸受につき5個の軸受の寿命試験を行って、その平均値をそのころ軸受の寿命とした。未処理のころを組み込んだころ軸受の寿命を1とした場合の相対値で、各ころ軸受の寿命を表すと、実施例1のころを組み込んだころ軸受の寿命は20、比較例1のころを組み込んだころ軸受の寿命12は、比較例2のころを組み込んだころ軸受の寿命は5であった。このように、実施例1のころを組み込んだころ軸受の寿命は、従来品である比較例1のころを組み込んだころ軸受と比べて、寿命が約1.5倍であった。   A life test was performed on five bearings per one type of roller bearing, and the average value was defined as the life of the roller bearing. When the life of each roller bearing is expressed as a relative value when the life of the roller bearing incorporating the untreated roller is 1, the life of the roller bearing incorporating the roller of Example 1 is 20, and the roller of Comparative Example 1 The life 12 of the roller bearing incorporating the roller was 5. The life of the roller bearing incorporating the roller of Comparative Example 2 was 5. Thus, the life of the roller bearing incorporating the roller of Example 1 was about 1.5 times that of the conventional roller bearing incorporating the roller of Comparative Example 1.

1 内輪
1a 軌道面
2 外輪
2a 軌道面
3 転動体
3a 転動面
10 複合組織層
12 潤滑被膜
DESCRIPTION OF SYMBOLS 1 Inner ring 1a Raceway surface 2 Outer ring 2a Raceway surface 3 Rolling element 3a Rolling surface 10 Composite structure layer 12 Lubrication coating

Claims (9)

互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、
前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、
前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素を含有し、残部が鉄及び不可避的不純物であることを特徴とする転動装置。
A first member and a second member having raceway surfaces arranged opposite to each other, and rolling elements arranged to roll between the raceway surface of the first member and the raceway surface of the second member, A rolling device in which one of the first member and the second member moves relative to the other through the rolling of the rolling element,
At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder A shot peening process for injecting a mixed projection material comprising at least one of the above, a composite tissue layer in which the soft projection material penetrates the base material, and the soft projection material And a lubricating film laminated on the composite structure layer is formed,
The iron-based ceramic powder has an area ratio of 50% to 90% Fe 2 B iron-based boride, a body-centered cubic lattice structure and / or a face-centered cubic lattice structure, and an area ratio of 10% to 50%. % or less and iron-based solid solution, made from the Fe 2 B Keitetsumoto said about the boride iron solid solution enclosed microstructure, or the around the Fe 2 B Keitetsumoto borides iron It has a microstructure surrounded by a eutectic of a solid solution and the Fe 2 B-based iron-based boride, and contains 5% by mass or more and 8% by mass or less of boron as an element, with the balance being iron and inevitable impurities. A rolling device characterized by being.
互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、
前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、
前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする転動装置。
A first member and a second member having raceway surfaces arranged opposite to each other, and rolling elements arranged to roll between the raceway surface of the first member and the raceway surface of the second member, A rolling device in which one of the first member and the second member moves relative to the other through the rolling of the rolling element,
At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder A shot peening process for injecting a mixed projection material comprising at least one of the above, a composite tissue layer in which the soft projection material penetrates the base material, and the soft projection material And a lubricating film laminated on the composite structure layer is formed,
The iron-based ceramic powder has an area ratio of 50% to 90% Fe 2 B iron-based boride, a body-centered cubic lattice structure and / or a face-centered cubic lattice structure, and an area ratio of 10% to 50%. % or less and iron-based solid solution, made from the Fe 2 B Keitetsumoto said about the boride iron solid solution enclosed microstructure, or the around the Fe 2 B Keitetsumoto borides iron While having a microstructure surrounded by a eutectic of a solid solution and the Fe 2 B-based iron-based boride, the elements include boron of 5% by mass to 8% by mass, titanium of 10% by mass and less, and 10% by mass. A rolling device comprising at least one of the following molybdenum, the balance being iron and inevitable impurities.
互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、
前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、
前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする転動装置。
A first member and a second member having raceway surfaces arranged opposite to each other, and rolling elements arranged to roll between the raceway surface of the first member and the raceway surface of the second member, A rolling device in which one of the first member and the second member moves relative to the other through the rolling of the rolling element,
At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder A shot peening process for injecting a mixed projection material comprising at least one of the above, a composite tissue layer in which the soft projection material penetrates the base material, and the soft projection material And a lubricating film laminated on the composite structure layer is formed,
The iron-based ceramic powder has an area ratio of 50% to 90% Fe 2 B iron-based boride, a body-centered cubic lattice structure and / or a face-centered cubic lattice structure, and an area ratio of 10% to 50%. % or less and iron-based solid solution, made from the Fe 2 B Keitetsumoto said about the boride iron solid solution enclosed microstructure, or the around the Fe 2 B Keitetsumoto borides iron While having a microstructure surrounded by a eutectic of a solid solution and the Fe 2 B-based iron-based boride, the elements include boron of 5% by mass to 8% by mass, chromium of 25% by mass or less, and 10% by mass. A rolling device comprising at least one of the following nickel, the balance being iron and inevitable impurities.
互いに対向配置される軌道面を備えた第一部材及び第二部材と、前記第一部材の軌道面と前記第二部材の軌道面との間に転動自在に配された転動体と、を備え、前記転動体の転動を介して前記第一部材及び前記第二部材の一方が他方に対して相対運動する転動装置において、
前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち少なくとも一つに、鉄基セラミックス粉末からなる硬質投射材と、軟質金属粉末及び固体潤滑剤粉末の少なくとも一方からなる軟質投射材と、を含む混合投射材を噴射するショットピーニング処理が施されていて、前記軟質投射材が母材に浸透してなる複合組織層と、前記軟質投射材で構成され前記複合組織層の上に積層された潤滑被膜と、が形成されており、
前記鉄基セラミックス粉末は、面積率で50%以上90%以下のFe2 B系鉄基ホウ化物と、体心立方格子構造及び/又は面心立方格子構造を有する、面積率で10%以上50%以下の鉄基固溶体と、からなり、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体が囲んだミクロ組織、又は、前記Fe2 B系鉄基ホウ化物の周りを前記鉄基固溶体と前記Fe2 B系鉄基ホウ化物との共晶物が囲んだミクロ組織を有するとともに、元素としては5質量%以上8質量%以下のホウ素と、10質量%以下のチタン及び10質量%以下のモリブデンの少なくとも一方と、25質量%以下のクロム及び10質量%以下のニッケルの少なくとも一方と、を含有し、残部が鉄及び不可避的不純物であることを特徴とする転動装置。
A first member and a second member having raceway surfaces arranged opposite to each other, and rolling elements arranged to roll between the raceway surface of the first member and the raceway surface of the second member, A rolling device in which one of the first member and the second member moves relative to the other through the rolling of the rolling element,
At least one of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, a hard projection material made of iron-based ceramic powder, a soft metal powder, and a solid lubricant powder A shot peening process for injecting a mixed projection material comprising at least one of the above, a composite tissue layer in which the soft projection material penetrates the base material, and the soft projection material And a lubricating film laminated on the composite structure layer is formed,
The iron-based ceramic powder has an area ratio of 50% to 90% Fe 2 B iron-based boride, a body-centered cubic lattice structure and / or a face-centered cubic lattice structure, and an area ratio of 10% to 50%. % or less and iron-based solid solution, made from the Fe 2 B Keitetsumoto said about the boride iron solid solution enclosed microstructure, or the around the Fe 2 B Keitetsumoto borides iron While having a microstructure surrounded by a eutectic of a solid solution and the Fe 2 B-based iron-based boride, the elements include boron of 5% by mass to 8% by mass, titanium of 10% by mass and less, and 10% by mass. A rolling device comprising at least one of the following molybdenum and at least one of 25 mass% or less of chromium and 10 mass% or less of nickel, the balance being iron and inevitable impurities.
前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち前記ショットピーニング処理が施された面は、表面における残留応力が−1500MPa以上−500MPa以下で、表面から10μm内側の深さ位置における残留応力が−200MPa以下であることを特徴とする請求項1〜4のいずれか一項に記載の転動装置。   Of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, the surface subjected to the shot peening treatment has a residual stress on the surface of −1500 MPa to −500 MPa, The rolling device according to any one of claims 1 to 4, wherein a residual stress at a depth position on the inner side of 10 µm from the surface is -200 MPa or less. 前記第一部材の軌道面,前記第二部材の軌道面,及び前記転動体の転動面のうち前記ショットピーニング処理が施された面は、面積率で1%以上の部分に、前記潤滑被膜を備えていることを特徴とする請求項1〜5のいずれか一項に記載の転動装置。   Of the raceway surface of the first member, the raceway surface of the second member, and the rolling surface of the rolling element, the surface subjected to the shot peening treatment has an area ratio of 1% or more, and the lubricating coating The rolling device according to claim 1, wherein the rolling device is provided. 前記軟質金属粉末は、平均粒径が1μm以上70μm以下であり、錫,亜鉛,銅,ニッケル,クロム,及びチタンのうち少なくとも1種を含有するとともに、前記固体潤滑剤粉末は、平均粒径が1μm以上70μm以下であり、二硫化モリブデン,グラファイト,及びポリテトラフルオロエチレンのうち少なくとも1種を含有することを特徴とする請求項1〜6のいずれか一項に記載の転動装置。   The soft metal powder has an average particle size of 1 μm or more and 70 μm or less and contains at least one of tin, zinc, copper, nickel, chromium, and titanium, and the solid lubricant powder has an average particle size of It is 1 micrometer or more and 70 micrometers or less, and contains at least 1 sort (s) among molybdenum disulfide, graphite, and polytetrafluoroethylene, The rolling device as described in any one of Claims 1-6 characterized by the above-mentioned. 前記混合投射材のうちの前記硬質投射材の割合は30質量%以上90質量%以下であることを特徴とする請求項1〜7のいずれか一項に記載の転動装置。   The rolling device according to claim 1, wherein a ratio of the hard projecting material in the mixed projecting material is 30% by mass or more and 90% by mass or less. 前記混合投射材の噴射圧力が0.2MPa以上0.8MPa以下で、噴射時間が5分以上30分以下であることを特徴とする請求項1〜8のいずれか一項に記載の転動装置。   9. The rolling device according to claim 1, wherein an injection pressure of the mixed projection material is 0.2 MPa or more and 0.8 MPa or less, and an injection time is 5 minutes or more and 30 minutes or less. .
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