JP2012145669A - Fixing roller, fixing device, and image forming apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a fixing roller that fixes developer as desired with little remaining trace of a nip, and enables a fixing device to which the fixing roller is attached to expand the range of fixing temperature, as well as a fixing device and an image forming apparatus that fix developer as desired, and expand the range of fixing temperature.SOLUTION: A fixing roller 1 comprising a foam elastic layer 3 formed by the outer peripheral surface of a shaft body 2, and has the bound amount at normal temperature (cm) of 40 or more, which is measured by the following test method at normal temperature (23°C). A fixing device including the fixing roller and an image forming apparatus including the fixing device are also provided.

Description

  The present invention relates to a fixing roller, a fixing device, and an image forming apparatus. More specifically, it is possible to fix a developer in a desired manner and a fixing temperature in a mounted fixing device is widened. The present invention relates to a fixing roller that can contribute, a fixing device that can fix a developer as desired, and a wide range of fixing temperatures and an image forming apparatus.

  Various types of image forming apparatuses using an electrophotographic system are employed in laser printers, copiers, video printers, facsimiles, and complex machines of these. An image forming apparatus using an electrophotographic system includes a shaft body and an elastic layer formed on an outer peripheral surface thereof, for example, a cleaning roller, a charging roller, a developing roller, a transfer roller, a pressure roller, a paper feed conveyance roller, Various rollers such as a fixing roller are provided.

  Among these rollers, the fixing roller has a large nip width so that the fixing roller and the pressure roller come into contact with each other with a predetermined pressure in order to fix the developer on the recording medium and form a high quality image. It is required to be able to ensure. In order to secure a large nip width, it is effective to reduce the hardness of the elastic layer of the fixing roller. As a fixing roller with low hardness, for example, Patent Document 1 discloses that “addition reaction curable type having a rubber rebound resilience after curing (JIS K6301) of 30% or less on the outer peripheral surface of a columnar or cylindrical metal core. A low-hardness silicone rubber fixing roll characterized in that a silicone rubber obtained by curing a liquid silicone rubber composition is coated and an organic resin layer having a low surface energy is provided on the outer peripheral surface of the roll. Yes.

  As described above, when the nip width between the fixing roller and the pressure roller is increased, the elastic layer of the fixing roller is unlikely to return to the original shape at an early stage even if the contact of the fixing roller that has been in contact with the pressure roller is released. A nip trace may remain on the surface. Since the nip trace portion remaining in the elastic layer cannot fix the developer to the recording medium, a developer unfixed portion corresponding to the nip trace is generated in a streak pattern in the formed image.

  By the way, in recent years, since the image forming apparatus has been increased in speed or definition, and in order to cope with the diversification of the use environment, the fixing temperature in the fixing apparatus has been widened.

JP-A-11-194443

  An object of the present invention is to provide a fixing roller that can hardly fix a nip trace and can fix a developer as desired and can contribute to widening of a fixing temperature in a fixing device to be mounted.

  It is an object of the present invention to provide a fixing device and an image forming apparatus that can fix a developer as desired and enable a wide range of fixing temperatures.

As means for solving the problems,
Claim 1 is a fixing roller comprising a foamed elastic layer formed on the outer peripheral surface of the shaft body, and having a normal temperature rebound (cm) of 40 or more according to the following test method at normal temperature (23 ° C.). And
The second aspect of the present invention is characterized in that the room temperature repulsion amount (cm) and the heat repulsion amount (cm) by the test method when heated to 180 ° C. for 1 hour satisfy the following formula. Fixing roller,
According to a third aspect of the present invention, in the fixing roller according to the first or second aspect, the foamed elastic layer is formed by foaming and curing an addition reaction type foamed silicone rubber composition on the outer peripheral surface of the shaft body.
According to a fourth aspect of the present invention, the addition reaction type foamed silicone rubber composition contains a vinyl group-containing silicone raw rubber, a silica-based filler, a foaming agent, an addition reaction crosslinking agent, an addition reaction catalyst, and a reaction control agent. The fixing roller according to claim 3,
According to a fifth aspect of the present invention, the addition reaction crosslinking agent is contained in a proportion of more than 2 parts by mass and less than 8 parts by mass with respect to a total of 100 parts by mass of the vinyl group-containing silicone raw rubber and the silica filler. The fixing roller according to claim 4, wherein
A sixth aspect of the present invention is a fixing device comprising the fixing roller according to any one of the first to fifth aspects,
A seventh aspect of the present invention is an image forming apparatus comprising the fixing device according to the sixth aspect.

<Measurement method>
Height from the surface of the fixing roller when an iron ball (diameter: 11 mm, mass: 5.45 g) dropped vertically from a height of 100 cm bounces at a substantially central portion in the axial direction of the fixing roller fixed vertically cm) is measured 10 times, and the arithmetic average value of the measured values of the top five points is defined as the room temperature rebound amount (cm) of the fixing roller.

  Formula: (heat rebound amount (cm) −room temperature rebound amount (cm)) / room temperature rebound amount (cm) ≧ 0.20

  The fixing roller according to the present invention comprises a foamed elastic layer, and the room temperature repulsion amount (cm) by the test method is 40 or more, so that a large nip width can be secured, and the foamed elastic layer is made thinner. In addition to exhibiting high heat transfer properties, it is possible to quickly return to the original shape when contact with the pressure roller is released by rotation. Therefore, according to the present invention, it is possible to provide a fixing roller that can hardly fix the nip trace and can fix the developer as desired and can contribute to widening of the fixing temperature in the fixing device to be mounted.

  The fixing device according to the present invention includes the fixing roller according to the present invention, and the image forming apparatus according to the present invention includes the fixing device according to the present invention. It is possible to provide a fixing device and an image forming apparatus that can be fixed to each other and that enable a wide range of fixing temperatures.

FIG. 1 is a perspective view showing a fixing roller of an embodiment of the fixing roller according to the present invention. FIG. 2 is a schematic explanatory view showing an image forming apparatus according to the present invention provided with a fixing device according to the present invention. FIG. 3 is an explanatory view for explaining a measuring method for measuring the repulsion amount of the fixing roller according to the present invention, and FIG. 3A shows a measuring tool in the measuring method for measuring the repulsion amount of the fixing roller according to the present invention. FIG. 3B is a front view showing a state in which the measuring tool is arranged perpendicular to the fixing roller, and FIG. 3B is a side view showing a state in which the measuring tool is arranged perpendicular to the fixing roller in the measuring method for measuring the repulsion amount of the fixing roller according to the present invention. FIG. FIG. 4 is a schematic diagram showing a testing machine for carrying out the fixing roller test in the embodiment.

  The fixing roller according to the present invention includes a foamed elastic layer formed on the outer peripheral surface of the shaft body. Therefore, the fixing roller according to the present invention only needs to include the shaft body and the foamed elastic layer, and may include other layers or films in addition to these.

  The fixing roller according to the present invention is characterized in that a normal temperature repulsion amount (cm) according to the following test method at normal temperature (23 ° C.) is 40 or more. When the room temperature rebound amount (cm) of the fixing roller provided with the foamed elastic layer is less than 40, the rebound amount is too small and the contact with the pressure roller is caused even when the contact with the pressure roller is released. The recessed portion is difficult to return to the original shape at an early stage, and the recessed portion that does not return cannot melt and fix the developer, and a streaky developer unfixed portion may be generated in the image. Further, when the rebound amount (cm) of the fixing roller including the foamed elastic layer is less than 40, it is necessary to increase the thickness of the foamed elastic layer in order to secure a large nip width with the pressure roller. For this reason, the fixing roller itself must be heated to a temperature higher than the heating temperature at the time of fixing the developer, which cannot contribute to widening the fixing temperature. On the other hand, if the fixing roller having the foamed elastic layer has a room temperature rebound (cm) of 40 or more, a large nip width can be secured when mounted on the fixing device. The effective width of the nip width is increased, and the thickness, that is, the outer diameter of the foamed elastic layer for ensuring the necessary nip width can be reduced. As a result, the fixing roller according to the present invention can ensure a large nip width and exhibit high heat transfer properties by thinning the foamed elastic layer. Further, since this fixing roller has a room temperature repulsion amount (cm) of 40 or more, the rebound amount is large. For example, even if it is in contact with the pressure roller for a long period of time, the contact with the pressure roller is caused by rotation. When released, it can be restored to its original shape early. Therefore, the fixing roller according to the present invention can hardly fix the nip trace and can fix the developer as desired, and can contribute to the widening of the fixing temperature in the mounted fixing device.

  The room temperature repulsion amount (cm) is preferably 45 or more, and particularly preferably 48 or more, in that nip traces are less likely to remain and can contribute to further widening of the fixing temperature. The upper limit value of the room temperature rebound amount (cm) is not particularly limited, but if it is too large, the durability of the fixing roller itself may be affected. Therefore, considering sufficient durability, it is preferably 65 cm. Particularly preferred is 60 cm.

  The room temperature repulsion amount (cm) is that of the fixing roller when an iron ball (diameter 11 mm, mass 5.45 g) dropped vertically from a height of 100 cm rebounds at a substantially central portion in the axial direction of the fixing roller fixed vertically. The height (cm) from the surface is measured 10 times, and the arithmetic average value of the measured values at the top five points is taken as the room temperature rebound amount (cm) of the fixing roller. The height is the highest point of the spherical surface of the iron ball bounced off from the surface of the fixing roller, that is, the height of the portion that reaches the highest position (also referred to as the uppermost portion).

  In order to measure the room temperature rebound (cm), for example, a measuring tool 20 and an iron ball 21 are prepared. The iron ball 21 is an iron sphere having a diameter of 11 mm and a mass of 5.45 g. As shown in FIG. 3, the measuring tool 20 is a tubular body made of a transparent material having a small frictional force, such as an acrylic resin, and having both ends opened. The measuring tool 20 has an inner diameter of 12 mm larger than the outer diameter of the iron ball 21 and an axial length of 100 cm, and the outer diameter is 16 mm. A scale is attached to the outer peripheral surface of the measuring tool 20 so that the rebound height of the iron ball can be measured.

  In order to measure the room temperature repulsion amount (cm) of the fixing roller according to the present invention, for example, the fixing roller 1 described later, first, as shown in FIG. 3, the measurement environment is set to room temperature (23 ° C.), and the fixing roller 1 The measuring tool 20 and the iron ball 21 are left in this measurement environment for a while. Next, the fixing roller 1 is horizontally fixed by gripping or pinching the shaft body 2 with, for example, a fixing tool. Next, the measuring tool 20 is arranged vertically on the outer peripheral surface of the substantially fixing portion 1 in the axial direction of the fixed fixing roller 1. The iron ball 21 is naturally dropped from the opening of the free end 20 a of the measuring tool 20, and the height of the uppermost part of the iron ball 21 bounced back against the fixing roller 1 is determined with reference to the surface of the fixing roller 1. Measure visually. This measurement is performed ten times, and five points are selected from the largest of the measured values, and their arithmetic average is obtained. This arithmetic average value is defined as the room temperature rebound amount (cm) of the fixing roller 1. In this measurement method, the height is measured with a sensor or the like, although it is measured visually with a scale attached to the outer peripheral surface of the measuring tool 20.

  In the fixing roller according to the present invention, the amount of heat repulsion (cm) according to the test method when heated to 180 ° C. for 1 hour is preferably 54 or more, more preferably 57 or more, and 60 or more. It is particularly preferred. When the fixing roller according to the present invention including the foamed elastic layer has a heat repulsion amount (cm) within the above range, the effect that the nip trace is less likely to remain in the state when the fixing roller is mounted on the fixing device. Play.

  The heat repulsion amount (cm) is an arithmetic average value of the height (cm) when the iron ball 21 bounces, measured by the above method after heating the fixing roller 1 to 180 ° C. for 1 hour.

In the fixing roller according to the present invention, it is preferable that the room temperature repulsion amount (cm) and the heat repulsion amount (cm) satisfy the following formula. That is, it is preferable that the fixing roller according to the present invention has an increase amount calculated by the following formula of 0.20 or more. When the fixing roller according to the present invention comprising the foamed elastic layer satisfies the following formula, the heat transfer performance can be further enhanced, and the recessed portion caused by the contact with the pressure roller can be restored earlier, and this The object of the invention can be well achieved. From the standpoint of further superiority due to this effect, the increase amount [(heat repulsion amount (cm) −normal temperature repulsion amount (cm)) / normal temperature repulsion amount (cm)] is more preferably 0.23 or more, and 0.24. The above is particularly preferable.
Formula: (heat rebound amount (cm) −room temperature rebound amount (cm)) / room temperature rebound amount (cm) ≧ 0.20

  The room temperature rebound amount (cm) in the above formula is the arithmetic average value in the measurement method under a room temperature environment, and the heat repulsion amount (cm) is measured by the measurement method after heating the fixing roller 1 to 180 ° C. for 1 hour. Arithmetic mean value.

  The normal temperature repulsion amount (cm) can be adjusted by, for example, the value of the degree of crosslinking of the rubber forming the foamed elastic layer, the type or content of the crosslinking agent contained in the foamed rubber composition, and the like. For example, the room temperature rebound amount (cm) increases as the content of the crosslinking agent, such as an addition reaction crosslinking agent, contained in the foamed rubber composition forming the foamed elastic layer increases, and the degree of crosslinking of the rubber forming the foamed elastic layer. Is increased, and is increased when the content of the foaming agent or the hollow filler contained in the foamed rubber composition forming the foamed elastic layer is increased.

  The fixing roller according to the present invention preferably has an Asker C hardness of 25 to 55. When this fixing roller has the Asker C hardness in the above range, a large nip pressure and nip width can be secured over a long period of time when the fixing roller is mounted on the fixing device. The Asker C hardness of the fixing roller according to the present invention is preferably 25 to 50, and particularly preferably 25 to 45. Asker C hardness (1 kg load) can be measured in accordance with JIS K6253. The Asker C hardness of the fixing roller according to the present invention is selected, for example, by selecting the type of rubber, foaming agent and / or additive contained in the foamed rubber composition forming the foamed elastic layer, and / or blending thereof. It can be adjusted by changing the amount or the like, or by the molding conditions of the foamed elastic layer.

  The fixing roller according to the present invention includes a foamed elastic layer. This foamed elastic layer has cells on its inner and / or outer surface. When the foamed elastic layer has cells, the hardness of the foamed elastic layer can be reduced. Here, the cell which has in a foaming elastic layer says the hollow area | region produced by foaming or decomposition | disassembly of the foaming agent contained in the foamed rubber composition which forms a foaming elastic layer. A plurality of cells included in the foamed elastic layer are in a state where they do not contact or communicate with other cells (referred to as independent cell states), a state where they contact or communicate with other cells (a communication cell state) Or the independent cell state and the communication cell state may coexist. The foamed elastic layer preferably has such a hardness that the fixing roller has an Asker C hardness in the above range.

  The foamed elastic layer is preferably adjusted in terms of the average cell diameter of the cells formed in the foamed elastic layer, the foaming magnification of the foamed elastic layer, the density, etc., in that the effect of the present invention can be further enhanced. . For example, the average cell diameter of the foamed elastic layer is preferably 60 to 800 μm, particularly preferably 100 to 400 μm, and the expansion ratio of the foamed elastic layer is preferably 180 to 420%, 200 to 350% is particularly preferable. When the expansion ratio of the foamed elastic layer is within the above range, the effect of obtaining hardness and rebound resilience that enables a wide range of fixing temperatures can be obtained.

In the foamed elastic layer, the expansion ratio and the average cell diameter can be adjusted by the foaming agent contained in the foamed rubber composition forming the foamed elastic layer or the curing conditions of the foamed rubber composition. The foaming ratio can be calculated from the volume and mass of the foamed elastic layer measured by a conventional method. In addition, the average cell diameter of the cell is determined by observing an area of about 20 mm ² with an electron microscope or the like on the surface of the foamed elastic layer or a cut surface obtained by cutting an arbitrary surface. The maximum length of the part is measured, and the measured maximum length can be obtained as an average length obtained by arithmetic averaging.

The density of the foamed elastic layer is preferably 0.395~0.7 (g / cm ^3), particularly preferably from 0.42~0.6 (g / cm ^3). When the density is within the above range, the effect of the present invention can be further enhanced. The density of the foamed elastic layer can be measured with an electron density meter (water displacement method, water temperature 23 ° C.).

  The form of the foamed elastic layer is not particularly limited, and may be, for example, a so-called straight shape adjusted to have a uniform outer diameter along the axial direction, and the outer diameter at the center portion is larger than the outer diameters at both end portions. It may be a so-called crown shape that is adjusted to be the same, or it may be a so-called reverse crown shape that is adjusted so that the outer diameter at the center portion is smaller than the outer diameter at both ends thereof.

  The thickness of the foamed elastic layer is not particularly limited and can usually be adjusted to 2 to 20 mm. Since this fixing roller 1 has a room temperature rebound amount (cm) within the above range, a large nip width can be secured and the thickness can be reduced. For example, in order to ensure a large nip width, the foamed elastic layer can be formed in a thin shape that has been difficult until now, and can be adjusted to 10 mm or less, for example. In the present invention, the thickness of the foamed elastic layer is particularly preferably adjusted to 3 to 7 mm.

The foamed rubber composition for forming the foamed elastic layer may be a composition containing rubber, a foaming agent or a hollow filler, and various additives as required. For example, a cell in an independent cell state is formed. Preferred examples include foamed silicone rubber-based compositions and foamed urethane rubber-based compositions. In particular, the foamed silicone rubber-based composition capable of forming a cell in an independent cell state is excellent in heat resistance, durability, resistance to residual strain, etc., and is suitable for a high-speed operation of an image forming apparatus. It is. As such a foamed silicone rubber composition, an addition reaction type foamed silicone rubber composition is particularly preferred. As a hollow filler, what is necessary is just a filler which can form a cell, for example after hardening | curing a rubber composition, For example, polyorganosiloxane type spherical powder is mentioned. The polyorganosiloxane spherical powder may be a spherical powder made of polyorganosiloxane, and examples thereof include silicone powder. More specifically, a silicone rubber powder having a structure in which linear dimethylpolysiloxane is crosslinked (also referred to as silicone rubber powder), a three-dimensional structure in which a siloxane bond is represented by (CH ₃ SiO _3/2 ) _n. Examples thereof include a powder of silicone resin such as so-called polymethylsilsesquioxane having a network-crosslinked structure, and a powder of coated silicone rubber in which the surface of the silicone rubber is coated with silicone resin or the like.

  The fixing roller according to the present invention will be specifically described. A fixing roller 1 as an embodiment of the fixing roller according to the present invention comprises a shaft body 2 and a foamed elastic layer 3 formed on the outer peripheral surface of the shaft body 2 as shown in FIG. The fixing roller 1 has the room temperature rebound amount (cm) of 40 or more, the heat repulsion amount (cm) of 54 or more, and the increase amount of 0.20 or more.

  The shaft body 2 only needs to have good conductive properties, and is usually a so-called “core metal” composed of iron, aluminum, stainless steel, brass, or the like. Further, the shaft body 2 may be a shaft body that is made conductive by plating an insulating core body such as a thermoplastic resin or a thermosetting resin. Furthermore, the shaft body 2 may be a thermoplastic resin or a thermosetting resin. The shaft body may be formed of a conductive resin in which carbon black or metal powder is blended as a conductivity imparting agent.

  The foamed elastic layer 3 is formed on the outer peripheral surface of the shaft body 2 so as to have a thickness within the above range with a foamed rubber composition to be described later. As shown in FIG. 1, the foamed elastic layer 3 has the straight shape, and has a cell in an independent cell state on the inside and / or outer surface thereof (in FIG. 1, the outer peripheral surface and the end surface of the foamed elastic layer 3). The cell opened in (not shown) has an average cell diameter, expansion ratio and density within the above range. Since this foamed elastic layer 3 is the outermost layer of the fixing roller 1, it has the same Asker C hardness as the Asker C hardness of the fixing roller 1.

  The foamed silicone rubber composition forming the foamed elastic layer 3 may be a composition containing silicone rubber, a foaming agent or a hollow filler, and various additives as required, preferably containing a vinyl group An addition reaction type foamed silicone rubber composition containing a silicone raw rubber, a silica-based filler, a foaming agent, an addition reaction crosslinking agent, an addition reaction catalyst, and a reaction control agent. The addition reaction type foamed silicone rubber composition may further contain an organic peroxide crosslinking agent, a heat resistance improver, and various additives as desired.

  Examples of the vinyl group-containing silicone raw rubber include millable silicone rubber and heat-crosslinked silicone rubber (HTV: High Temperature Vulcanizing). These vinyl group-containing silicone raw rubbers have the property that a foaming agent and an addition reaction cross-linking agent can be easily kneaded with a roll mill or the like in a later step, and are used alone or in combination of two or more. Can be used. Examples of the vinyl group-containing silicone raw rubber include trade name “KE-77VBS” manufactured by Shin-Etsu Chemical Co., Ltd.

Examples of the silica-based filler include a fumed silica or a precipitated silica having a reinforcing property, and a surface having a high reinforcing effect that is surface-treated with a silane coupling agent represented by a general formula RSi (OR ′) _3. A treated silica-based filler is preferred. Here, R in the general formula is a glycidyl group, vinyl group, aminopropyl group, methacryloxy group, N-phenylaminopropyl group, mercapto group or the like, and R ′ in the general formula is a methyl group or an ethyl group. . Examples of the silane coupling agent represented by the above general formula include trade names “KBM1003” and “KBE402” manufactured by Shin-Etsu Chemical Co., Ltd., and trade names “Celite Super Floss” manufactured by Toshin Kasei Co., Ltd. It can be easily obtained. Such a silica-based filler surface-treated with a silane coupling agent can be obtained by treating the surface of the silica-based filler according to a conventional method. The compounding quantity of a silica type filler is 40-100 mass parts with respect to 100 mass parts of said vinyl group containing silicone raw rubbers, It is preferable that it is 45-70 mass parts, and it is 50-60 mass parts. Particularly preferred. A silica type filler can be used individually by 1 type or in mixture of 2 or more types.

  The foaming agent may be any foaming agent conventionally used for foamed rubber. Examples of the inorganic foaming agent include sodium bicarbonate and ammonium carbonate. Examples of the organic foaming agent include diazoamino derivatives, azonitrile derivatives, azo And organic azo compounds such as dicarboxylic acid derivatives. Usually, an inorganic foaming agent is used when forming open cells in rubber, and an organic foaming agent is used when forming closed cells. In the present invention, the foaming agent is preferably an organic foaming agent because the foamed elastic layer 3 can be easily formed. Specifically, for example, azodicarboxylic acid amide, azobis-iso An azo compound such as butyronitrile is preferably used. In particular, dimethyl-1,1'-azobis (1-cyclohexanecarboxylate) can be preferably used. The blending amount of the foaming agent may be, for example, 0.1 to 10 parts by mass, particularly 0.5 to 5 parts by mass with respect to 100 parts by mass of the vinyl group-containing silicone raw rubber. A foaming agent can be used individually by 1 type or in mixture of 2 or more types.

  Suitable examples of the addition reaction crosslinking agent include known organohydrogenpolysiloxanes as addition reaction type crosslinking agents having two or more SiH groups (SiH bonds) in one molecule. An addition reaction crosslinking agent can be used individually by 1 type or in mixture of 2 or more types. The compounding amount of the addition reaction crosslinking agent is more than 2.0 parts by mass and less than 8.0 parts by mass relative to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and the silica-based filler. ) And the like can be adjusted within the above range. The addition amount of the addition reaction crosslinking agent is more preferably 2.1 to 7.9 parts by mass, and particularly preferably 2.5 to 7.5 parts by mass with respect to 100 parts by mass in total.

  The addition reaction catalyst may be any catalyst that is usually used in addition reactions of silicone raw rubber, and examples thereof include simple metals of Group 9 or 10 of the periodic table and compounds thereof. The addition amount of the addition reaction catalyst is sufficient as the catalyst amount, and is usually 1 to 1 with respect to the addition reaction type foamed silicone rubber composition in terms of the metal amount of Group 9 or Group 10 of the periodic table. 000 ppm. An addition reaction catalyst can be used individually by 1 type or in mixture of 2 or more types.

  As the reaction control agent, a known reaction control agent can be used without particular limitation, and examples thereof include methylvinylcyclotetrasiloxane, acetylene alcohols, siloxane-modified acetylene alcohol, and hydroperoxide. The compounding amount of the reaction control agent is preferably 0.1 to 2 parts by mass with respect to 100 parts by mass of the vinyl group-containing silicone raw rubber. The reaction control agents can be used alone or in combination of two or more.

  The organic peroxide cross-linking agent can be used alone to cross-link vinyl group-containing silicone raw rubber, but if used in combination as an auxiliary cross-linking agent for an addition reaction cross-linking agent, the physical properties of the silicone rubber, such as strength and strain, can be improved. improves. Examples of the organic peroxide crosslinking agent include benzoyl peroxide, bis-2,4-dichlorobenzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, and 2,5-dimethyl-2,5-bis. (T-butylperoxy) hexane and the like. The compounding amount of the organic peroxide crosslinking agent is preferably 0.3 to 10 parts by mass with respect to 100 parts by mass of the vinyl group-containing silicone raw rubber. An organic peroxide crosslinking agent can be used individually by 1 type or in mixture of 2 or more types.

  The heat resistance improver may be any compound that improves the heat resistance of the foamed elastic layer 3, and examples thereof include carbon black, iron oxide (also referred to as bengara), cerium oxide, and cerium hydroxide. These can be used individually by 1 type or in mixture of 2 or more types.

  The various additives can be used singly or in combination of two or more without particularly limiting the additives such as conductivity imparting agents such as carbon black.

  As the silicone rubber composition containing the vinyl group-containing silicone raw rubber, the silica filler, and the various additives, for example, trade names “KE series” and “KEG series” manufactured by Shin-Etsu Chemical Co., Ltd. can be easily used. It can be obtained. In particular, as a silicone rubber composition containing a silica-based filler in the above range, for example, trade names “KE-904FU”, “KE-151KU”, “KE-9510U” and “KE-” manufactured by Shin-Etsu Chemical Co., Ltd. 981U "and the like.

  The foamed silicone rubber composition is preferably mixed for several minutes to several hours until it is uniformly mixed using a rubber kneader such as a two-roll, three-roll, roll mill, Banbury mixer, or dough mixer (kneader). Is obtained by kneading at room temperature or under heating for 5 minutes to 1 hour.

  The fixing roller according to the present invention can be manufactured by a manufacturing method including a step of forming a foamed elastic layer by foaming and curing a foamed rubber composition disposed on the outer peripheral surface of the shaft body. For example, as one method for adjusting the room temperature rebound amount (cm) and the like within the above range, an addition reaction type foamed silicone rubber composition containing an addition reaction crosslinking agent in a content within the above range is used for the shaft body 2. The method of foam-curing on an outer peripheral surface is mentioned.

  Specifically, the fixing roller according to the present invention can be manufactured as follows. First, an adhesive or primer is applied to the outer peripheral surface of the shaft body 2 made of the material as necessary to form an adhesive layer or primer layer. Next, a foamed rubber composition for forming the foamed elastic layer 3 is disposed on the outer peripheral surface of the shaft body 2. As the method, for example, the shaft body 2 and the foamed rubber composition are integrally extracted by an extruder or the like, and the foamed rubber composition is disposed on the outer peripheral surface of the shaft body 2. Examples thereof include a method of injecting a foamed rubber composition into a mold to be disposed and arranging the foamed rubber composition on the outer peripheral surface of the shaft body 2. Among these, the method of integrally dispensing the shaft body 2 and the foamed rubber composition with an extruder or the like is preferable in terms of easy work and continuous operation. After disposing the foamed rubber composition on the outer peripheral surface of the shaft body 2 in this manner, the foamed rubber composition is heated together with the shaft body 2 while maintaining this state. The foamed rubber composition may be heated under conditions sufficient for the rubber contained in the foamed rubber composition, for example, vinyl group-containing silicone raw rubber to crosslink and the foaming agent to decompose or foam. For example, a foamed silicone rubber composition such as an addition reaction type foamed silicone rubber composition is usually about 170 to 500 ° C., particularly 200 to 200 ° C., depending on a heating furnace such as an infrared heating furnace or a hot air furnace, a heating machine such as a dryer. It is heated to 400 ° C. and heated for several minutes to 1 hour, particularly 5 to 30 minutes. The foamed silicone rubber composition may be further subjected to secondary heating if desired. The physical properties of the foamed elastic layer 3 are stabilized by the secondary heating. In the secondary heating, for example, the foamed silicone rubber composition crosslinked under the above-described conditions is further extruded, for example, at 180 to 250 ° C, preferably 190 to 230 ° C, and 1 to 24. Over a period of time, preferably 3 to 10 hours, or using a mold, for example, 130 to 200 ° C., preferably 150 to 180 ° C., for 5 minutes to 24 hours, preferably 10 minutes to 10 hours, This is done by heating again. The foamed elastic layer 3 thus molded is subjected to a grinding process, a polishing process and / or a cutting process, etc., which are adjusted to a desired size and shape as a finishing process, if desired. Manufactured.

  Since the fixing roller according to the present invention has the high-temperature repulsion amount (cm), durability and high repulsion force, which have been conventionally difficult, can be achieved at a high level. In addition, since the fixing roller according to the present invention has the above-described characteristics, the recording medium conveyed to the nip portion can be conveyed with a strong narrow pressure, and the recording medium can be prevented from being clogged in the fixing device. it can. Furthermore, since the nip trace hardly remains in the fixing roller according to the present invention, the intended purpose can be sufficiently achieved even when the fixing roller is mounted on a high-speed image forming apparatus in which the fixing roller is rotated at high speed. Further, as described above, the diameter can be reduced and the size can be reduced, which is effective for energy saving. In particular, in addition to the room temperature rebound amount (cm), if the heat rebound amount (cm) and further satisfy the above formula, the object of the present invention can be well achieved.

  The fixing roller according to the present invention is not limited to the above-described embodiment, and various modifications can be made within a range in which the object of the present invention can be achieved. For example, although the foamed elastic layer 3 has a single layer structure, in the present invention, it may have a multilayer structure of two or more layers.

  The fixing roller 1 includes a shaft body 2 and a foamed elastic layer 3. The fixing roller according to the present invention includes a shaft body, a foamed elastic layer formed on the outer peripheral surface thereof, and an outer periphery of the foamed elastic layer. And a tube layer formed on the surface. If the tube layer is formed on the outer surface of the foamed elastic layer, the releasability of the developer can be improved. The tube layer may have a single layer structure or a stacked structure in which two or more layers are stacked. The tube layer is formed to a thickness of 1 to 100 μm, for example. The material for forming the tube layer is not particularly limited. However, the elastic roller is preferably in contact with or pressed against the contacted body, and thus is preferably a material that is not easily permanently deformed. For example, alkyd resin, phenol Modified alkyd resin such as modified / silicone modified, oil-free alkyd resin, acrylic resin, silicone resin, epoxy resin, fluororesin, phenol resin, polyamide resin, urethane resin, polyamideimide resin, and mixtures thereof. The tube layer may be a metal sleeve, and examples of the metal forming the sleeve include a metal material having high thermal conductivity such as iron, stainless steel, and nickel. The tube layer can be formed on the outer surface of the foamed elastic layer by inserting the foamed elastic layer into a tubular body previously formed into a cylindrical shape having the same inner diameter as that of the foamed elastic layer. When the tube layer is formed in this way, the tube layer having a smooth surface can be formed without being greatly affected by the uneven shape present on the surface of the foamed elastic layer. The tube layer may be formed by applying the material to the outer peripheral surface of the foamed elastic layer according to, for example, a dip method or a spray method, and then curing and / or crosslinking.

  The fixing roller 1 may include a heating element such as an electric heater or a heating coil in the shaft body 2 and / or between the shaft body 2 and the foamed elastic layer 3 depending on the application. For example, when the fixing roller 1 is used as a fixing roller of a heat roller fixing device, a heating body is provided in the shaft body 2.

  Next, a fixing device including the fixing roller according to the present invention (hereinafter sometimes referred to as a fixing device according to the present invention) and an image forming apparatus including the fixing device (hereinafter referred to as an image according to the present invention). An example of a forming apparatus will be described with reference to FIG.

  As shown in FIG. 2, an image forming apparatus 30 according to the present invention is arranged around a rotatable image carrier 31 on which an electrostatic latent image is formed, for example, a photosensitive member, and the image carrier 31. The charging unit 32 includes a charging roller, an exposure unit 33, a developing unit 40, a transfer unit 34 such as a transfer roller and a cleaning unit 37, and a fixing unit 35 on the downstream side in the conveyance direction of the recording medium. The developing means 40 is formed basically in the same manner as the conventional developing means. Specifically, as shown in FIG. 2, the developer containing portion 41 and the development for supplying the developer 42 to the image carrier 31 are developed. A developer carrier 44, a developer supply unit 43 that supplies the developer 42 to the developer carrier 44, and a developer regulating member 45 that charges the developer 42 are provided.

  The fixing unit 35 is a fixing device including a heating unit 57 and an endless belt 55. That is, the fixing device 35 has a fixing roller 53 and an endless arrangement disposed in the vicinity of the fixing roller 53 in a casing 50 having an opening 52 through which the recording medium 36 passes, as shown in a cross section in FIG. A belt support roller 54, an endless belt 55 wound around the fixing roller 53 and the endless belt support roller 54, a pressure roller 56 that presses the fixing roller 53 via the endless belt 55, and a contactless contact with the endless belt 55. And a heating unit 57 that heats the fixing roller 53 from the outside via the endless belt 55, so that the fixing roller 53 and the pressure roller 56 are in contact with or pressed against each other via the endless belt 55. It is a pressure heat fixing device which is supported in a freely rotatable manner. The endless belt support roller 54 may be a roller that is usually used in an image forming apparatus. For example, an elastic roller or the like is used. For example, the endless belt 55 may be an endless belt formed of a resin such as polyamide or polyamideimide, and the thickness of the endless belt 55 may be appropriately adjusted to match the fixing unit 35. The fixing roller 53 and the pressure roller 56 are pivotally supported, and the pressure roller 56 is pressed against the fixing roller 53 via an endless belt 55 by an urging means (not shown) such as a spring. In the fixing device 35, the fixing roller according to the present invention is mounted as the fixing roller 53. As the heating means 57, a radiant heating method using a halogen heater, a reflector, or the like, a direct contact heating method in which a heater or the like is directly contacted and heated, an induction heating method, or the like is adopted. The heating means 57 is a member having substantially the same length as that of the fixing roller 53 in the axial direction, and may be disposed in any of the fixing devices 35. However, as shown in FIG. It is preferable that the fixing roller 53 be arranged substantially in parallel with a predetermined interval. In the induction heating method, a heating coil is used, and this heating coil is usually a ferromagnetic material such as ferrite, and is a typical shape used for a switching power source. It is formed into a mold or the like, and is formed by winding a conducting wire. By passing the recording medium 36 between the endless belt 55 and the pressure roller 56, the recording medium 36 is heated simultaneously with the pressurization, and the developer 42 (electrostatic latent image) transferred to the recording medium 36 is fixed. be able to.

  The image forming apparatus 30 according to the present invention operates as follows. First, in the image forming apparatus 30, the image carrier 31 is uniformly charged by the charging unit 32, and an electrostatic latent image is formed on the surface of the image carrier 31 by the exposure unit 33. Next, the developer 42 is supplied from the developing unit 40 to the image carrier 31 to develop the electrostatic latent image, and the developer image is conveyed between the image carrier 31 and the transfer unit 34 on the recording member 36. Is transcribed. The recording body 36 is conveyed to the fixing unit 35, and the developer image is fixed on the recording body 36 as a permanent image. In this way, an image can be formed on the recording body 36.

  The fixing device 35 and the image forming apparatus 30 according to the present invention employ the elastic roller according to the present invention as the fixing roller 53, so that the developer can be fixed as desired and a wide range of fixing temperatures is possible. To.

  The image forming apparatus 30 is an electrophotographic image forming apparatus. However, in the present invention, the image forming apparatus is not limited to the electrophotographic system, and may be, for example, an electrostatic image forming apparatus. Further, the image forming apparatus 30 is a monochrome image forming apparatus in which the developing unit 40 contains only the single color developer 42. However, in the present invention, the image forming apparatus is not limited to the monochrome image forming apparatus, and color image formation is performed. It may be a device. Examples of the color image forming apparatus include a four-cycle color image forming apparatus that sequentially repeats primary transfer of a developer image carried on an image carrier to an intermediate transfer body, and a plurality of image carriers provided with developing means for each color. Examples thereof include a tandem type color image forming apparatus in which a body is arranged in series on an intermediate transfer body or a transfer conveyance belt. The image forming apparatus 30 is an image forming apparatus such as a copying machine, a facsimile machine, or a printer.

  In the image forming apparatus 30, a one-component developer is advantageously used as the developer 42, but a two-component developer including a toner and a carrier such as iron or nickel can also be used.

Example 1
A shaft body (diameter 20 mm × length 350 mm, SUM22) subjected to electroless nickel plating was washed with toluene, and a primer “No. 101A / B” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) was applied. The primer-treated shaft was baked at 180 ° C. for 30 minutes using a gear oven, and then cooled at room temperature for 30 minutes or more to form a primer layer.

  Next, 100 parts by mass of a mixture of a vinyl group-containing silicone raw rubber and a silica-based filler (silicone rubber composition “KE-904FU” manufactured by Shin-Etsu Chemical Co., Ltd.) and an addition reaction crosslinking agent “C-153A” (Shin-Etsu Chemical) Manufactured by Kogyo Co., Ltd .: trade name) 5 parts by mass, 2.5 parts by mass of the blowing agent azobis-isobutyronitrile, an appropriate amount of platinum catalyst as an addition reaction catalyst, and a reaction control agent “R-153A” (Shin-Etsu Chemical Co., Ltd.) Product name: 0.5 parts by mass, organic peroxide crosslinking agent “C-3” (manufactured by Shin-Etsu Chemical Co., Ltd .: product name), and heat resistance improver “KEP-12” (Shin-Etsu) Chemical Industry Co., Ltd. product name) 1.0 part by mass was sufficiently kneaded with two rolls to prepare an addition reaction type foamed silicone rubber composition.

  Next, the shaft body 2 on which the primer layer is formed and the addition reaction type foamed silicone rubber composition are integrally extracted by an extruder, and the addition reaction type foamed silicone rubber composition is 250 by using an infrared heating furnace (IR furnace). It was heated at 0 ° C. for 10 minutes for foam crosslinking. After that, the addition reaction type foamed silicone rubber composition after foaming and crosslinking is further heated at 200 ° C. for 7 hours using a gear oven, left at room temperature for 1 hour or more, and then outer diameter is measured by a cylindrical grinder. A fixing roller of Example 1 having a so-called straight-shaped foamed elastic layer 3 ground to 30 mm was produced.

(Examples 2 and 3)
Example 1 except that the content of the addition reaction crosslinking agent was changed to 2.5 parts by mass and 7.5 parts by mass with respect to 100 parts by mass of the mixture of the vinyl group-containing silicone raw rubber and the silica-based filler, respectively. The fixing rollers of Examples 2 and 3 were manufactured basically in the same manner as described above.

(Comparative Example 1)
Basically the same as in Example 1 except that the content of the addition reaction crosslinking agent was changed to 1.5 parts by mass with respect to 100 parts by mass of the mixture of the vinyl group-containing silicone raw rubber and the silica-based filler. A fixing roller of Comparative Example 1 was produced.

(Comparative Example 2)
When the content of the addition reaction crosslinking agent was changed to 8.0 parts by mass with respect to 100 parts by mass of the mixture of the vinyl group-containing silicone raw rubber and the silica-based filler, a foamed elastic layer could not be formed.

  The normal temperature repulsion amount (cm), the heat repulsion amount (cm), the increase amount, the Asker C hardness, the average cell diameter (μm), and the expansion ratio (%) in each fixing roller manufactured in this manner. The results measured according to the above method are shown in Table 1.

(Nip trace evaluation)
The fixing rollers of Examples 1 to 3 and Comparative Example 1 were evaluated under severe conditions by using a testing machine 70 shown in FIG. As shown in FIG. 4, the testing machine 70 is fixed to the lower surface inside the housing and is provided on both sides of the heating roller 71 having an internal heater 72 along the axial direction of the heating roller 71. A test roller mounting part 74 provided on the upper surface inside the housing so as to be movable up and down so as to face the heat insulating material 73 and the heating roller 71, and a pressing force adjusting means capable of moving the test roller mounting part 74 up and down. 75, for example, a pressure adjusting micrometer. The heating roller 71 includes a metal (stainless steel, SUS304) roller having a diameter of 30 mm. The fixing rollers of Examples 1 to 3 and Comparative Example 1 are mounted on the bearings of the test roller mounting portion 74 as elastic rollers 76, the heating roller 71 is fixed so as not to rotate, and the heat insulating material 73 and the internal heater 72 are started. The surface temperature of the heating roller 71 was adjusted to 180 ° C. After the surface temperature of the heating roller 71 reached 180 ° C., the pressing force adjusting means 75 was cured and the elastic roller 76 was brought into pressure contact with the heating roller 71 by 4.2 mm in the center direction. That is, the elastic roller 76 is pressed against the heating roller 71 so that the distance between the axis of the elastic roller 76 and the axis of the heating roller 71 is 4.2 mm shorter than the sum of the radius of the elastic roller 76 and the radius of the heating roller 71. I let you. After leaving the elastic roller 76 in pressure contact for 5 minutes in this way, the pressure contact was released, removed from the testing machine, and left at 23 ° C. for 24 hours. The evaluation was made by observing the pressed portion of the elastic roller 76, and “◎” when there was no dent, “◯” when there was a dent mark but the circumferential width was less than 5 mm, and the circumferential width was When it was 5 mm or more, it was set as "x". The evaluation results are shown in Table 1.

(Evaluation of fixing range)
Using the fixing rollers of Examples 1 to 3 and Comparative Example 1 and the testing machine 70, the fixing width of each fixing roller on the paper was evaluated under severe conditions. Specifically, the elastic roller 76 was brought into pressure contact with the heating roller 71 at the same time as the heating roller 71 and elastic roller 76 were brought into pressure contact under the same condition setting as in the nip trace evaluation. Next, an OHP film “CG3700 (A4 size (297 mm long, 210 mm wide, JIS), thickness 0.125 mm, made of polyethylene terephthalate resin)” manufactured by Sumitomo 3M Limited is applied to the pressure contact portion between the elastic roller 76 and the heating roller 71 in the vertical direction. After maintaining the pressure contact state in which the substantially central portion in the vertical direction of the OHP film was pressed in the pressure contact portion along the horizontal direction for 30 seconds, the OHP film was detached from the pressure contact portion. The surface of the detached OHP film was allowed to stand until it reached 23 ° C., and the length in the vertical direction of the area where the pressure contact portion, that is, the sandwiched portion of the OHP film was discolored (clouded) was measured. In this fixing range evaluation, the “fixing range” of the OHP film was measured by measuring the length in the vertical direction of a total of three locations, the center portion in the lateral direction and the two end portions 50 mm inside from both ends of the pressure contact portion of the OHP film. These were arithmetic averages. In the evaluation, a case where the width was 14 mm or more was “◎”, a case where the width was 12 mm or more and less than 14 mm was “◯”, and a case where the width was less than 12 mm was “x”. The measurement results and the evaluation results are shown in Table 1.

DESCRIPTION OF SYMBOLS 1 Fixing roller 2 Shaft body 3 Foam elastic layer 20 Measuring tool 20a Free end 21 Iron ball 30 Image forming apparatus 31 Image carrier 32 Charging means 33 Exposure means 34 Transfer means 35 Fixing means 36 Recording body 37 Cleaning means 40 Developing means 41 Developing Agent storage section 42 Developer 43 Developer supply means 44 Developer carrier 45 Developer regulating member 50 Housing 52 Opening 53 Fixing roller 54 Endless belt support roller 55 Endless belt 56 Pressure roller 57 Heating means 70 Durability test device 71 Heating Roller 72 Internal heater 73 External heater 74 Test roller mounting portion 75 Pressure adjusting means 76 Elastic roller

Claims (7)

A fixing roller comprising a foamed elastic layer formed on an outer peripheral surface of a shaft body, and having a normal temperature repulsion amount (cm) of 40 or more according to the following test method at normal temperature (23 ° C.).
<Measurement method>
Height from the surface of the fixing roller when an iron ball (diameter: 11 mm, mass: 5.45 g) dropped vertically from a height of 100 cm bounces at a substantially central portion in the axial direction of the fixing roller fixed vertically cm) is measured 10 times, and the arithmetic average value of the measured values of the top five points is defined as the room temperature rebound amount (cm) of the fixing roller. 2. The fixing roller according to claim 1, wherein the normal temperature repulsion amount (cm) and the heat repulsion amount (cm) according to the test method when heated to 180 ° C. for 1 hour satisfy the following formula.
Formula: (heat rebound amount (cm) −room temperature rebound amount (cm)) / room temperature rebound amount (cm) ≧ 0.20   The fixing roller according to claim 1, wherein the foamed elastic layer is formed by foaming and curing an addition reaction type foamed silicone rubber composition on an outer peripheral surface of the shaft body.   The addition reaction type foamed silicone rubber composition comprises a vinyl group-containing silicone raw rubber, a silica-based filler, a foaming agent, an addition reaction crosslinking agent, an addition reaction catalyst, and a reaction control agent. The fixing roller according to claim 3.   The addition reaction crosslinking agent is contained in a proportion of more than 2 parts by mass and less than 8 parts by mass with respect to 100 parts by mass of the total mass of the vinyl group-containing silicone raw rubber and the silica filler. Item 5. The fixing roller according to Item 4.   A fixing device comprising the fixing roller according to claim 1.   An image forming apparatus comprising the fixing device according to claim 6.

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