JP6146896B2 - Developer conveying roller, developing device, and image forming apparatus - Google Patents

Description

  The present invention relates to a developer conveying roller, a developing device, and an image forming apparatus. More specifically, the present invention relates to a developer conveying roller, a developing device, and an image forming apparatus that are excellent in chargeability and abrasion resistance to the developer.

  Various printers such as laser printers and video printers, copiers, facsimiles, and multi-function machines of these types employ various image forming apparatuses using an electrophotographic system, for example.

  For example, an image forming apparatus 30 shown in FIG. 3 is a rotatable image carrier 31 on which an electrostatic latent image is formed, and is disposed around the image carrier 31. A charging unit 32, an exposing unit 33, a developing unit 40, a transfer unit 34, a cleaning unit 37, and a fixing unit 35 on the downstream side in the conveyance direction of the recording medium. Specifically, as shown in FIG. 3, the developing unit 40 includes a developer storage unit 41, a developer carrier 44 that supplies the developer 42 to the image carrier 31, and a developer carrier 44. A developer supply unit 43 that conveys and supplies the developer 42 to the developer carrier 44 and a developer regulating member 45 that charges the developer 42 are provided so as to be in pressure contact with each other. In the image forming apparatus 30, the developer 42 is supplied from the developer carrier 44 to the image carrier 31, and the electrostatic latent image formed on the surface of the image carrier 31 is developed. An image is formed on the recording medium by being transferred and fixed to the recording medium.

As such a developer supply means 43, an elastic roller having a silicone coat layer made of a silicone cured material such as silicone rubber is known.
For example, Patent Document 1 states that “a cured silicone layer having a hardness of 30 or less is formed on a roll shaft, and a cured silicone layer having a hardness higher than the hardness of the cured silicone product is formed thereon. "Characterized silicone coating roll" is described (claim 1 etc.).

  Patent Document 2 discloses that “on the surface of a developer carrying member, an electrically conductive powder is mainly dispersed in an inorganic coating liquid or a silicon varnish liquid and cured to form an inorganic conductive film. "Developing member to perform" (claim 1 etc.).

  Further, in Patent Document 3, “in a non-magnetic one-component developing roller that holds a non-magnetic one-component developer on a peripheral surface in a thin film and adheres the developer to a photosensitive member that holds an electrostatic latent image. A lower layer selected from the group consisting of urethane rubber, silicone rubber, natural rubber, and a copolymer containing ethylene and propylene, and an elastic rubber layer of 50 ° or less on the JISA scale, and an intermediate layer on this lower layer as necessary And a non-magnetic one-component developing roller characterized in that it has a multilayer structure comprising an upper layer made of an organosilicone polymer.

  By the way, in order to form a high quality image with the image forming apparatus when an elastic roller is employed as the developer supply means 43, the developer charged from the developer carrier 44 to the image carrier 31 to a predetermined charge amount. It is important to supply a predetermined amount of 42, and it is necessary to supply a predetermined amount of developer 42 charged to the developer carrier 44 from the developer supply means 43 to a predetermined amount of charge. There is. However, an elastic roller provided with a silicone coat layer made of a silicone cured body is not sufficient in the charge amount to the developer or its uniformity, and improvement has been desired.

  Further, since the developer supply means 43 is arranged so as to be in pressure contact with the developer carrier 44 and is driven to rotate together with the developer carrier 44, the silicone cured body is particularly easily worn and exhibits high wear resistance. It is requested.

JP 63-152711 A JP-A-8-6376 Japanese Patent Laid-Open No. 1-18681

  It is an object of the present invention to provide a developer transport roller, a developing device, and an image forming apparatus that are excellent in chargeability and abrasion resistance to the developer.

Means for solving the problems are as follows:
(1) A developer conveying roller comprising a foamed elastic layer, and a silicone coating layer disposed on an outer peripheral surface of the foamed elastic layer and including a methylphenyl silicone resin and an aminosilane coupling agent,
(2) The silicone coat layer is formed by curing a resin composition containing 100 parts by mass of a methylphenyl silicone resin and 1 to 10 parts by mass of an aminosilane coupling agent on the outer peripheral surface of the foamed elastic layer. The developer conveying roller according to (1),
(3) The silicone coat layer is the developer transport roller according to (1) or (2), which has a thickness of 9 μm or less.
(4) The developer conveying roller according to any one of (1) to (3), wherein Asker F hardness is 45 to 70,
(5) The aminosilane coupling agent is the developer transport roller according to any one of (1) to (4), wherein the aminosilane coupling agent is 3-aminopropyltriethoxysilane.
(6) The developer transport roller according to any one of (1) to (5), wherein the methylphenyl silicone resin has a JIS A hardness of 55 to 85 in a flat test piece having a thickness of 7 mm. Yes,
(7) The foamed elastic layer is the developer transport roller according to any one of (1) to (6), wherein Asker F hardness is 40 to 65,
(8) A developer carrier that carries the developer and supplies the developer to the image carrier, and the developer carrier that is disposed in pressure contact with the developer carrier and transports the developer to the developer carrier. (7) A developing device having the developer conveying roller according to any one of the above and a developer disposed around the developer conveying roller.
(9) An image forming apparatus including the developer conveying roller according to any one of (1) to (7).

  The developer carrying roller according to the present invention includes a foamed elastic layer and a silicone coating layer disposed on the outer peripheral surface of the foamed elastic layer and including a methylphenyl silicone resin and an aminosilane coupling agent. In addition to excellent abrasion to the body, the developer held on the outer peripheral surface can be charged to a desired charge amount. The developing device and the image forming apparatus according to the present invention include the developer transport roller according to the present invention. Therefore, according to the present invention, it is possible to provide a developer conveying roller, a developing device, and an image forming apparatus that are excellent in charging property and abrasion resistance to the developer.

FIG. 1 is a schematic perspective view showing a developer transport roller as an example of the developer transport roller according to the present invention. FIG. 2 is a schematic cross-sectional view showing a cross section when a developer transport roller as an example of the developer transport roller according to the present invention is cut along a cross section perpendicular to the axis. FIG. 3 is a schematic view showing an image forming apparatus as an example of the image forming apparatus according to the present invention, which includes the developing apparatus as an example of the developing apparatus according to the present invention.

  The developer transport roller according to the present invention includes a foamed elastic layer and a silicone coating layer disposed on the outer peripheral surface of the foamed elastic layer and including a methylphenyl silicone resin and an aminosilane coupling agent. This silicone coat layer can be formed, for example, by curing a resin composition containing a methylphenyl silicone resin and an aminosilane coupling agent on the outer peripheral surface of the foamed elastic layer.

  The developer conveying roller according to the present invention will be described together with the developer conveying roller 1 shown in FIGS. 1 and 2 as an example.

  The developer conveying roller 1 includes a shaft body 2, a foamed elastic layer 3 formed as an outermost layer on the outer peripheral surface of the shaft body 2, and a silicone coat layer 4 formed as an outermost layer on the outer peripheral surface of the foamed elastic layer 3. Is provided. The developer conveying roller 1 preferably has an Asker F hardness of 45 to 70. When the Asker F hardness is within the above range, the developer carrying member is uniformly pressed against the developer carrying member, and the nip width in the axial and circumferential directions. Becomes substantially uniform, and a predetermined amount of developer can be conveyed and supplied to the developer carrying member. The Asker F hardness is preferably 48 to 65, more preferably 50 to 60, in that the developer can be conveyed and supplied more uniformly in the axial direction and the circumferential direction. If the Asker F hardness of the developer conveying roller 1 is less than 45, it is necessary to increase the nip width due to insufficient surface pressure on the developing roller because of low hardness, and also because of low hardness. Since the cells of the elastic layer are liable to break, the hardness tends to decrease with long-term use. On the other hand, if the Asker F hardness of the developer conveying roller 1 exceeds 70, an excessive load may be applied to the torque of the drive motor, and the core becomes bent when trying to secure the nip width because the hardness is relatively high. Therefore, it may be impossible to uniformly transport the developer because a uniform nip width cannot be secured. In particular, when the hardness is high such as JIS A hardness, such a unique function of the developer conveying roller is not substantially exhibited, and it is difficult to use the high hardness roller as the developer conveying roller. The Asker F hardness is a value obtained by pressing the central portion of the presser of the hardness meter against the outer surface of the developer conveying roller according to the present invention and reading the scale at the moment when the reference surface contacts the outer surface. . Actually, it can be measured using “Asker rubber hardness meter F type” manufactured by Kobunshi Keiki Co., Ltd. In the present invention, it is preferable that the Asker F hardness of the developer transport roller according to the present invention is an arithmetic average value when measured in this manner a plurality of times. The Asker F hardness of the developer conveying roller can be appropriately adjusted depending on the hardness of the foamed elastic layer 3, the hardness and thickness of the silicone coat layer, and the like.

By the way, Patent Document 2 relating to “Non-magnetic one-component developing roller” describes that the lower layer is “not preferable because the upper layer is liable to crack because the upper layer is liable to crack” (page 2, lower left column, page 15). In the developer transport roller 1, the foamed elastic layer 3 has an Asker F hardness of 45 to 70 due to the average cell diameter of the foamed elastic layer 3 and the silicone coat layer 4. Even if the hardness is low, there is a remarkable effect that the silicone coat layer 4 is not cracked.
For example, when the developer conveying roller 1 is placed on a copper plate with a load of 200 to 600 g applied to the developer conveying roller, the conduction resistance between the silicone coating layer in contact with the copper plate and the shaft body is 1 × 10 ³ to 1. It has electrical characteristics of × 10 ⁶ Ω. When the developer conveying roller 1 has a conduction resistance in the above range, good printing characteristics can be obtained. For example, an electrical resistance meter (trade name: ULTRA HIGH RESISTANCE METER R8340A, manufactured by Advantest Co., Ltd.) is used for the conduction resistance, the developer transport roller 1 is placed horizontally, the thickness is 5 mm, the width is 30 mm, and the developer. A copper plate having a length on which the entire silicone coat layer 4 of the conveying roller 1 can be placed is used as an electrode, and a load of 100 to 300 g is supported on both ends of the shaft body 2 in the developer conveying roller 1. Measurement can be performed in accordance with a method in which DC 100 V is applied between the body 2 and the electrode, the value of an electric resistance meter after 1 second is read, and this value is used as a conduction resistance. If the total load applied to the developer conveying roller 1 (the load applied to each end is the same) is in the range of 200 to 600 g, the conduction resistance does not change depending on the load value, and 1 × 10 ³ to 1 It is in the range of × 10 ⁶ Ω.

  The shaft body 2 only needs to have good conductive properties, and is usually a so-called “core metal” composed of iron, aluminum, stainless steel, brass, or the like. Further, the shaft body 2 may be a shaft body that is made conductive by plating an insulating core body such as a thermoplastic resin or a thermosetting resin. Furthermore, the shaft body 2 may be a thermoplastic resin or a thermosetting resin. The shaft body may be formed of a conductive resin in which carbon black or metal powder is blended as a conductivity imparting agent. The shaft body 2 is adjusted to an appropriate diameter and axial length according to the image forming apparatus to be mounted.

  As shown in FIG. 1, the foamed elastic layer 3 is formed on the outer peripheral surface of the shaft body 2 so as to have a so-called straight shape having a single-layer structure with a thickness of 2 to 30 mm. The foamed elastic layer 3 is formed by curing a rubber composition described later on the outer peripheral surface of the shaft body 2. The foamed elastic layer 3 has a plurality of cells (not shown in FIG. 1) that are in an independent cell state, and has cells 6 that are open on the outer surface. A cell formed in the foamed elastic layer does not contact or communicate with other cells (referred to as an independent cell state), contacts with or communicates with other cells (communication cell state) Or the independent cell state and the communication cell state may coexist.

The average cell diameter of the cells 6 present in the foamed elastic layer 3 is preferably 150 to 400 μm, and particularly preferably 220 to 350 μm. When the average cell diameter is within the above range, the Asker F hardness within the above range can be achieved, and a sufficient and sufficient nip width with the developer carrying member 44 can be secured, and a sufficient amount of developer can be loaded. 44 can be conveyed. The average cell diameter of the cell 6 is determined by observing an area of about 20 mm ² with an electron microscope or the like on the surface of the foamed elastic layer 3 or a cut surface obtained by cutting an arbitrary surface. The maximum length of the part is measured, and the measured maximum length can be obtained as an average length obtained by arithmetic averaging. This average cell diameter can be adjusted by the foaming agent contained in the rubber composition to be described later forming the foamed elastic layer 3 or the curing conditions of the rubber composition.

  The expansion ratio of the foamed elastic layer is preferably 300 to 450%, particularly preferably 330 to 410%. When the expansion ratio of the foamed elastic layer is within the above range, the foamed elastic layer 3 and thus the Asker F of the developer conveying roller 1 can be adjusted within a predetermined range. As a result, the hardness of the developer conveying roller 1 is reduced. Is less likely to occur, and the developer can be transported uniformly. In the foamed elastic layer, the expansion ratio and the average cell diameter can be adjusted by the foaming agent contained in the foamed rubber composition forming the foamed elastic layer or the curing conditions of the foamed rubber composition. The foaming ratio can be calculated from the volume and mass of the foamed elastic layer measured by a conventional method.

The density of the foamed elastic layer is preferably 0.08~0.20 (g / cm ^3), particularly preferably from 0.11~0.17 (g / cm ^3). When the density is within the above range, the effect of the present invention can be further enhanced. The density of the foamed elastic layer can be measured with an electron density meter (water displacement method, water temperature 23 ° C.).
The foamed elastic layer 3 preferably has an Asker F hardness of 40 to 65, more preferably 45 to 65, and particularly preferably 47 to 60. When the Asker F hardness of the foamed elastic layer 3 is in the above range, the Asker F hardness of the developer conveying roller 1 can be set in the above range. The agent can be transported uniformly. The Asker F hardness of the foamed elastic layer 3 can be measured basically in the same manner as the developer conveying roller 1.
As described above, the foamed elastic layer 3 is a single-layered tubular body formed of a so-called “sponge-like” rubber composition on the outer peripheral surface of the shaft body 2 and contains a conductivity-imparting agent.
The conductivity imparting agent is basically the same as the conductivity imparting agent contained in the composition to be described later, and the content of the conductivity imparting agent in the foamed elastic layer 3 is the vinyl group-containing silicone raw rubber and the silica-based filler. It is preferable that it is 10-50 mass parts with respect to a total of 100 mass parts, and it is especially preferable that it is 15-50 mass parts. When the content of the conductivity imparting agent is within the above range, a charging characteristic is exhibited that charges the developer with a charge amount necessary for the developer when a voltage is applied to the image forming apparatus.

The thickness of the foamed elastic layer 3 is adjusted to an appropriate thickness according to the function required for the developer conveying roller 1, and is usually preferably 2 to 30 mm, more preferably 3 to 20 mm. Even more preferred.
The rubber composition forming the foamed elastic layer 3 contains rubber or raw rubber, a foaming agent, a conductivity imparting agent, and various additives as desired. The rubber is not particularly limited, and examples thereof include silicone or silicone-modified rubber, urethane rubber, fluororubber, and the like. Silicone or silicone-modified rubber is preferable in terms of excellent heat resistance and charging characteristics. The foaming agent may be any foaming agent conventionally used for foamed rubber. Examples of the inorganic foaming agent include sodium bicarbonate and ammonium carbonate. Examples of the organic foaming agent include diazoamino derivatives, azonitrile derivatives, and azodicarboxylic acids. Examples thereof include organic azo compounds such as derivatives. An inorganic foaming agent is used when forming continuous cells in the foamed elastic layer 3, and an organic foaming agent is used when forming independent cells. This rubber composition may contain a hollow filler in addition to or instead of the foaming agent. As a hollow filler, what is necessary is just a filler which can form a cell, for example after hardening | curing a rubber composition, For example, polyorganosiloxane type spherical powder is mentioned. The polyorganosiloxane spherical powder may be a spherical powder made of polyorganosiloxane, and examples thereof include silicone powder. More specifically, a silicone rubber powder having a structure in which linear dimethylpolysiloxane is crosslinked (also referred to as silicone rubber powder), a three-dimensional structure in which a siloxane bond is represented by (CH ₃ SiO _3/2 ) _n. Examples thereof include a powder of silicone resin such as so-called polymethylsilsesquioxane having a network-crosslinked structure, and a powder of coated silicone rubber in which the surface of the silicone rubber is coated with silicone resin or the like. The conductivity-imparting agent only needs to be a compound that can impart conductivity, and examples thereof include conductive powder and ion conductive materials. More specifically, examples of the conductive powder include conductive carbons such as ketjen black and acetylene black, carbons for rubber, metals, conductive polymers, and the like. Include sodium perchlorate, lithium perchlorate, calcium perchlorate, and lithium chloride. Examples of the various additives include fillers, colorants, flame retardant improvers, thermal conductivity improvers, mold release agents, dispersants, pulverized quartz, and non-reinforcing silica. These various additives are blended in a desired blending amount.
The rubber composition is preferably a foamed conductive silicone rubber composition or a foamed conductive urethane rubber composition that can form a cell in an independent cell state. In particular, the foamed conductive silicone rubber composition capable of forming a cell in an independent cell state is excellent in heat resistance, durability, resistance to residual strain, etc., and suitable rubber that can withstand high-speed operation of an image forming apparatus. It is a composition. As such a foamed conductive silicone rubber composition, an addition reaction type foamed conductive silicone rubber composition is particularly preferable.
The addition reaction type foamed conductive silicone rubber composition includes a vinyl group-containing silicone raw rubber, a silica-based filler, a foaming agent, an addition reaction crosslinking agent, an addition reaction catalyst, a reaction control agent, and a conductivity imparting agent. If desired, it further contains an organic peroxide crosslinking agent, a heat resistance improver (excluding those that function as the conductivity-imparting agent), and various additives.
Examples of the vinyl group-containing silicone raw rubber include millable silicone rubber and heat-crosslinked silicone rubber (HTV: High Temperature Vulcanizing). These vinyl group-containing silicone raw rubbers have the property that a foaming agent and an addition reaction cross-linking agent can be easily kneaded with a roll mill or the like in a later step, and are used singly or in combination of two or more. be able to. Examples of the vinyl group-containing silicone raw rubber include trade name “KE-77VBS” manufactured by Shin-Etsu Chemical Co., Ltd.
Examples of the silica-based filler include reinforcing fumed silica or precipitated silica, and surface treatment with a silane coupling agent represented by the general formula RSi (OR ′) _3, which has a high reinforcing effect. Silica-based fillers are preferred. Here, R in the general formula is a glycidyl group, vinyl group, aminopropyl group, methacryloxy group, N-phenylaminopropyl group, mercapto group or the like, and R ′ in the general formula is a methyl group or an ethyl group. . Examples of the silane coupling agent represented by the above general formula include trade names “KBM1003” and “KBE402” manufactured by Shin-Etsu Chemical Co., Ltd., and trade names “Celite Super Floss” manufactured by Toshin Kasei Co., Ltd. It can be easily obtained. Such a silica-based filler surface-treated with a silane coupling agent can be obtained by treating the surface of the silica-based filler according to a conventional method. The compounding amount of the silica-based filler is preferably 40 to 100 parts by mass, more preferably 45 to 70 parts by mass, with respect to 100 parts by mass of the vinyl group-containing silicone raw rubber, and 50 to 60 parts by mass. Part is particularly preferred. A silica type filler can be used individually by 1 type or in mixture of 2 or more types.
The foaming agent may be a foaming agent conventionally used for foamed rubber, and examples thereof include the inorganic foaming agent and the organic foaming agent. In the present invention, the foaming agent is preferably an organic foaming agent because the foamed elastic layer 3 can be easily formed. Specifically, for example, azodicarboxylic acid amide, azobis-isobutyro An azo compound such as nitrile is preferably used. In particular, dimethyl-1,1′-azobis (1-cyclohexanecarboxylate) can be preferably used. The blending amount of the foaming agent is, for example, 0.1 to 10 parts by mass, particularly 0.5 to 8 parts by mass with respect to a total of 100 parts by mass of the vinyl group-containing silicone raw rubber and the silica filler. Is good. A foaming agent can be used individually by 1 type or in mixture of 2 or more types.
Suitable examples of the addition reaction crosslinking agent include known organohydrogenpolysiloxanes as addition reaction type crosslinking agents having two or more SiH groups (SiH bonds) in one molecule. An addition reaction crosslinking agent can be used individually by 1 type or in mixture of 2 or more types. The compounding amount of the addition reaction crosslinking agent is preferably 0.01 to 20 parts by mass with respect to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and the silica filler.
The addition reaction catalyst may be any catalyst that is usually used for the addition reaction of silicone raw rubber, and examples thereof include simple metals of 9th group or 10th group and compounds thereof. The amount of addition reaction catalyst affects the hardness of the foamed elastic layer 3 and is 0.40 to 0.7 parts by mass with respect to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and the silica-based filler. If it exists, the Asker F hardness of the foaming elastic layer 3 and its hardness ratio can be adjusted in the said range. An addition reaction catalyst can be used individually by 1 type or in mixture of 2 or more types.
As the reaction control agent, a known reaction control agent can be used without particular limitation, and examples thereof include methylvinylcyclotetrasiloxane, acetylene alcohols, siloxane-modified acetylene alcohol, and hydroperoxide. The compounding amount of the reaction control agent is preferably 0.1 to 2 parts by mass with respect to a total of 100 parts by mass of the vinyl group-containing silicone raw rubber and the silica filler. The reaction control agents can be used alone or in combination of two or more.
The conductivity imparting agent is as described above, and can be used alone or in combination of two or more. The blending amount of the conductivity-imparting agent is preferably 5 to 50 parts by mass with respect to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and the silica filler.
The organic peroxide cross-linking agent can be used to cross-link vinyl group-containing silicone raw rubber alone, but when used as an auxiliary cross-linking agent for addition reaction cross-linking agents, the physical properties of silicone rubber, such as strength and strain, are improved. To do. Examples of the organic peroxide crosslinking agent include benzoyl peroxide, bis-2,4-dichlorobenzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, and 2,5-dimethyl-2,5-bis. (T-butylperoxy) hexane and the like. The compounding amount of the organic peroxide crosslinking agent may be 0.3 to 10 parts by mass with respect to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and the silica-based filler. An organic peroxide crosslinking agent can be used individually by 1 type or in mixture of 2 or more types.
The heat resistance improver may be a compound that improves the heat resistance of the foamed elastic layer 3 other than the conductivity imparting agent, and examples thereof include iron oxide (also referred to as bengara), cerium oxide, and cerium hydroxide. . These can be used individually by 1 type or in mixture of 2 or more types.
As the silicone rubber composition containing the vinyl group-containing silicone raw rubber, the silica filler, and the various additives, for example, trade names “KE series” and “KEG series” manufactured by Shin-Etsu Chemical Co., Ltd. can be easily used. It can be obtained.
The rubber composition is, for example, several minutes to several hours, preferably 5 until it is uniformly mixed using a rubber kneader such as a two-roll, three-roll, roll mill, Banbury mixer, dough mixer (kneader) or the like. It can be obtained by kneading at room temperature or under heating for at least 1 minute and at most 1 hour.

  The silicone coat layer 4 is disposed on the outer peripheral surface of the foamed elastic layer, and preferably is disposed on the cell wall existing between the open cells opened on the outer peripheral surface of the foamed elastic layer 3 as shown in FIG. , Disposed on all or part of the inner surface of the open cell. Since the foamed elastic layer 3 is in the form of a three-dimensional mesh-like sponge even when arranged on the cell wall in this way, the silicone coat layer 4 has an integral film shape, and the outer peripheral surface of the foamed elastic layer 3 That is, it is firmly attached on the cell wall. In particular, when the foamed elastic layer 3 is formed of silicone rubber, the adhesion becomes stronger due to the interaction.

  The silicone coat layer 4 has a thickness of 9 μm or less. When the thickness exceeds 9 μm, the cell of the foamed elastic layer 3 in the vicinity of the silicone coat layer 4 is broken and damaged by the stress acting on the developer transport roller when mounted on the image forming apparatus, Further, cracks extending in the axial direction may occur on the surface of the silicone coat layer 4, and the silicone coat layer 4 may be peeled off from the foamed elastic layer 3, thereby reducing the durability of the developer transport roller 1. There is. The thickness of the silicone coat layer 4 is 9 μm or less, preferably 1 to 8 μm, more preferably 1 to 6 μm, and particularly preferably, in that the developer conveying roller 1 exhibits even higher durability. 1-5 μm. Here, as shown in FIG. 2, the thickness of the silicone coat layer 4 is the thickness T of the silicone coat layer 4 laminated on the cell wall or porous skeleton constituting the outer peripheral surface of the foamed elastic layer 3. And by observing the cross section of the foamed elastic layer 3. Therefore, the thickness of the silicone coat layer 4 does not consider the thickness of the silicone coat layer 4 entering the cell 6.

The silicone coat layer 4 is usually formed by curing a resin composition containing a methylphenyl silicone resin and an aminosilane coupling agent. Therefore, the silicone coat layer 4 can be referred to as a coat layer formed by curing a resin composition containing a methylphenyl silicone resin and an aminosilane coupling agent.
When the silicone coat layer 4 is formed using a methylphenyl silicone resin, the charging characteristics required for the developer conveying roller 1 can be effectively exhibited.

The methylphenyl silicone resin in this resin composition may be a methylphenyl silicone resin containing a methyl group and a phenyl group as organic groups bonded to the silicon atom, and the methyl group and the phenyl group are bonded to the same silicon atom. Examples thereof include methylphenyl silicone resin. The methylphenyl silicone resin may be produced as appropriate or a commercially available product may be obtained. For example, as the methylphenyl silicone resin, trade names “KR-271” and “KR-282” manufactured by Shin-Etsu Chemical Co., Ltd., trade name “SILRES H62C” manufactured by Asahi Kasei Wacker Silicone Co., Ltd., and the like can be given.
The methylphenyl silicone resin preferably has a JIS A hardness of 55 to 85, more preferably 60 to 70, when a flat test piece having a thickness of 7 mm is used. When the JIS A hardness of the methylphenyl-based silicone resin is within the above range, even if the foamed elastic layer 3 is formed on the outer peripheral surface of the low hardness, damage to the cells of the foamed elastic layer 3, occurrence of cracked cracks, and Separation from the foamed elastic layer 3 can be effectively prevented. The JIS A hardness can be measured in accordance with JIS K6253 using the flat plate test piece. In the present invention, the JIS A hardness of the methylphenyl silicone resin is almost the same value even if it contains a conductivity-imparting agent.

The aminosilane coupling agent in this resin composition is also referred to as an amino group-containing silane coupling agent, and may have at least one hydrolyzable silyl group and amino group in the molecule. R ¹ —SiR ² _m R ³ _(3-m) (wherein R ¹ is an amino group-containing group, R ² is an organic group, R ³ is a hydrolyzable group, and m is 0) And an aminosilane coupling agent represented by (2).

The amino group-containing group R ¹ may be a group containing an amino group, and examples thereof include an aminoalkyl group and an aminoaryl group. The number of carbon atoms of the amino group-containing group R ¹ is not particularly limited, For example, it is preferably about 1 to 20. The amino group contained in the amino group-containing group R ¹ may be any of a primary amino group, a secondary amino group (including an imino group), a tertiary amino group, and a quaternary amino group, but has excellent charging characteristics. And preferably a primary amino group, a secondary amino group, or a tertiary amino group. The amino group-containing group R ¹ may contain two or more amino groups. Examples of the aminoalkyl group include aminomethyl group, aminoethyl group, aminopropyl group, N-2- (aminoethyl) -3-aminopropyl group, N, N-dimethylaminopropyl group, and alkyl or aryl thereof. Examples of the aminoaryl group include an aminophenyl group, an aminobenzyl group, and alkyl or aryl substituents thereof.

Examples of the organic group R ² include alkyl groups and aryl groups having about 1 to 30 carbon atoms, and specific examples include a methyl group, an ethyl group, and a propyl group.

The hydrolyzable group R ³ may be any group that can easily hydrolyze the Si—R ³ bond in the presence of moisture, such as a halogen atom, an alkoxy group, a (meth) acryloyl group, a mercapto group, and the like. Examples include hydrolyzable substituents. Among these, an alkoxy group is preferable because it is easily available. Examples of the alkoxy group include a methoxy group, an ethoxy group, and a propoxy group.

  M is an integer of 0 to 2, and is preferably 0 or 1 and particularly preferably 0 in that the curing rate of the aminosilane coupling agent is high and desired properties can be exhibited. .

  Examples of the aminosilane coupling agent represented by the above formula include 3-aminopropyltrimethoxysilane, 3-aminopropylmethyldimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropylethyldiethoxysilane, 3- Aminopropyldimethylethoxysilane, 3-aminopropylmethyldiethoxysilane, N-2- (aminoethyl) -3-aminopropyltrimethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane N-2- (aminoethyl) -3-aminopropyltriethoxysilane, N, N-dimethylaminopropyltrimethoxysilane, N, N-diethylaminopropyltrimethoxysilane, N, N-dipropylaminopropyltrimethoxysilane , N, N-di Tylaminopropyltrimethoxysilane, N-monobutylaminopropyltrimethoxysilane, N, N-dioctylaminopropyltrimethoxysilane, N, N-dibutylaminopropylmethyldimethoxysilane, N, N-dibutylaminopropyldimethylmonomethoxysilane 3-triethoxysilyl-N- (1,3-dimethyl-butylidene) propylamine, N, N-dimethylaminophenyltrimethoxysilane, trimethoxysilyl-3-propylphenylamine, trimethoxysilyl-3-propylbenzyl Examples include amine, trimethoxysilyl-3-propylpiperidine, trimethoxysilyl-3-propylmorpholine, trimethoxysilyl-3-propylimidazole and the like.

  The content of the aminosilane coupling agent in this resin composition is preferably 1 to 10 parts by mass, particularly preferably 1 to 3 parts by mass with respect to 100 parts by mass of the methylphenyl silicone resin. If the content of the aminosilane coupling agent is less than 1 part by mass, the effect of containing the aminosilane coupling agent cannot be sufficiently exhibited, and the chargeability and wear resistance may not be improved. On the other hand, when the content of the aminosilane coupling agent exceeds 10 parts by mass, tackiness is generated on the roller surface, and the releasability of the developer on the roller surface may be lowered.

The conductivity imparting agent is basically the same as the conductivity imparting agent of the foamed elastic layer 3, and carbon black is preferable. The content of the conductivity-imparting agent in the silicone coat layer 4 is preferably 2 to 10 parts by mass, and particularly preferably 3 to 7 parts by mass with respect to 100 parts by mass of the methylphenyl silicone resin. When the content of the conductivity-imparting agent is within the above range, the silicone coating layer 4 itself can be used without impairing the charging characteristics exhibited by the foamed elastic layer 3 when a voltage is applied to the image forming apparatus. In addition, it exhibits a charging characteristic that charges the developer with a charge amount necessary for the developer, and exhibits an excellent charging characteristic as the developer conveying roller 1.
The conductivity imparting agent may be contained alone in the silicone coat layer 4 or may be contained as a complex with other substances.

The developer conveying roller 1 can be manufactured by a manufacturing method including a step of forming a foamed elastic layer 3 by foaming and curing the rubber composition on the outer peripheral surface of the shaft body 2. Specifically, it can be produced as follows. First, an adhesive or primer is applied to the outer peripheral surface of the shaft body 2 made of the material as necessary to form an adhesive layer or primer layer. Next, a rubber composition for forming the foamed elastic layer 3 is disposed on the outer peripheral surface of the shaft body 2. As the method, for example, the shaft body 2 and the rubber composition are integrally extracted by an extruder or the like, and the rubber composition is disposed on the outer peripheral surface of the shaft body 2, or a mold for housing the shaft body 2 is used. And a method of injecting the rubber composition into the outer peripheral surface of the shaft body 2 and the like. Among these, the method of dispensing the shaft body 2 and the rubber composition integrally with an extruder or the like is preferable because the operation is easy and the operation can be performed continuously. After arranging the rubber composition on the outer peripheral surface of the shaft body 2 in this way, the rubber composition is heated together with the shaft body 2 while maintaining this state. The heating of the rubber composition may be performed under conditions sufficient for the rubber contained in the rubber composition, for example, vinyl group-containing silicone raw rubber to crosslink and the foaming agent to decompose or foam. For example, the rubber composition is usually heated to about 170 to 500 ° C., particularly 200 to 400 ° C. by a heating furnace such as an infrared heating furnace or a hot air oven, a heating machine such as a dryer, and the like. In particular, it is heated for 5 to 30 minutes. The rubber composition may be further subjected to secondary heating as desired. The physical properties of the foamed elastic layer 3 are stabilized by the secondary heating. In the secondary heating, for example, the rubber composition cross-linked under the above-described conditions is further in an extruded state, for example, 180 to 250 ° C, preferably 190 to 230 ° C, for 1 to 24 hours. Heating again for 3 to 10 hours or using a mold, for example, at 130 to 200 ° C., preferably 150 to 180 ° C. for 5 minutes to 24 hours, preferably 10 minutes to 10 hours or less Is done. The foamed elastic layer 3 thus molded is subjected to a grinding step, a polishing step and / or a cutting step, etc., which are adjusted to a desired size and shape as a finishing step, if desired.
Next, the resin composition applied to the outer peripheral surface of the foamed elastic layer 3 can be manufactured by a manufacturing method including a step of forming the cured silicone coat layer 4 on the outer peripheral surface. When the resin composition is thus cured, the methylphenyl silicone resin and the aminosilane coupling agent react on the outer peripheral surface of the foamed elastic layer 3 to form the silicone coat layer 4.
In this production method, for example, when the platinum catalyst content in the rubber composition and / or the heating temperature (curing temperature) at the time of primary curing are adjusted, as described above, the Asker F before the rotation test on the developer conveying roller 1 is performed. The hardness can be adjusted to the above range.

  Since the developer conveying roller 1 has the above-described configuration, it is difficult to be worn even if it is rotationally driven together with the developer carrier and has excellent wear resistance, and the developer held on the silicone coat layer 4 can be charged to a desired level. Can be charged to an amount.

Next, a developing device (hereinafter sometimes referred to as a developing device according to the present invention) provided with a developer conveying roller according to the present invention and an image forming device (hereinafter referred to as an image forming device according to the present invention). An example) will be described with reference to FIG.
An image forming apparatus 30 as an example of the image forming apparatus according to the present invention includes a rotatable image carrier 31 on which an electrostatic latent image is formed, for example, a photosensitive member, and a charging unit 32 disposed around the image carrier 31. For example, a charging roller, an exposure unit 33, a developing unit 40, a transfer unit 34, such as a transfer roller and a cleaning unit 37, and a fixing unit 35, for example, a fixing device for an image forming apparatus, are arranged on the downstream side in the conveyance direction of the recording medium. . Here, the image carrier 31, the charging unit 32, the exposure unit 33, the transfer unit 34, and the fixing unit 35 are the same as those conventionally known.
The developing means 40 is an example of a developing device according to the present invention. Specifically, as shown in FIG. 2, as shown in FIG. 2, a developer container 41 and a developer carrying member that supplies the developer 42 to the image carrier 31. A developer supply means 43 for supplying the developer 42 to the developer carrying member 44, for example, a developer supply roller, and a developer regulating member 45 for charging the developer 42. In the developing means 40, the developer conveying roller according to the present invention as the developer supplying means 43 is pushed in the thickness direction of the foamed elastic layer 3 as the nip width with the developer carrier 44 as the pressure contact body ( It is mounted so that the amount of depression is 1 mm. The developing means 40 is basically the same as the conventional developing means except that the developer feeding roller according to the present invention is mounted as the developer supplying means 43. The developer 42 may be a dry developer or a wet developer as long as it is a one-component developer, and may be a non-magnetic developer or a magnetic developer. Good.
The fixing unit 35 only needs to fix the developer 42 (electrostatic latent image) transferred to the recording medium 36. For example, a heating roller fixing device including a fixing roller capable of generating heat, an oven fixing device, or the like is used. A fixing device, a pressure fixing device including a fixing roller capable of being pressed, and the like can be used. These fixing devices may be fixing devices having endless belts. The fixing device 35 has a fixing roller 53 and an endless belt supported in the vicinity of the fixing roller 53 in a housing 50 having an opening 52 through which the recording medium 36 passes, as shown in a cross section in FIG. A roller 54, an endless belt 55 wound around the fixing roller 53 and the endless belt support roller 54, and a pressure roller 56 disposed opposite to the fixing roller 53. The pressure heat fixing device is configured to be rotatably supported so that the pressure roller 56 is in contact with or in pressure contact with each other. The endless belt support roller 54 may be a roller that is normally used in an image forming apparatus. For example, an elastic roller or the like is used. For example, the endless belt 55 may be an endless belt formed of a resin such as polyamide or polyamideimide, and the thickness of the endless belt 55 may be appropriately adjusted to match the fixing unit 35. Each of the fixing roller 53, the endless belt support roller 54, and the pressure roller 56 includes a heating body (not shown), and the pressure roller 56 causes the endless belt 55 to be moved by a biasing means (not shown) such as a spring. Via the fixing roller 53. By passing the recording medium 36 between the endless belt 55 and the pressure roller 56, the recording medium 36 is heated simultaneously with the pressurization, and the developer 42 (electrostatic latent image) transferred to the recording medium 36 is fixed. be able to.
The image forming apparatus 30 according to the present invention operates as follows. First, in the image forming apparatus 30, the image carrier 31 is uniformly charged by the charging unit 32, and an electrostatic latent image is formed on the surface of the image carrier 31 by the exposure unit 33. Next, the developer 42 is supplied from the developing means 40 to the image carrier 31 to develop the electrostatic latent image. Here, the developer transport roller according to the present invention as the developer supply means 43 supplies the developer to the developer carrier 44 without changing the supply amount over time, that is, substantially the same amount over a long period of time. The developer carrier 44 can supply substantially the same amount of developer to the image carrier 31 over a long period of time. Next, the developer image is transferred onto a recording body 36 conveyed between the image carrier 31 and the transfer means 34. The recording body 36 is conveyed to the fixing unit 35, and the developer image is fixed on the recording body 36 as a permanent image. In this manner, the image forming apparatus 30 can stably form a high quality image having a desired print density on the recording body 36 over a long period of time.
The developing means 40 as an example of the developing apparatus according to the present invention and the image forming apparatus 30 as an example of the image forming apparatus according to the present invention include the developer transport roller according to the present invention as the developer supplying means 43. The developing unit 40 can contribute to forming an image having a desired print density stably over a long period of time, and the image forming apparatus 30 can form an image having a desired print density stably over a long period of time.
The image forming apparatus 30 is an image forming apparatus that forms an image at a conventional printing speed (for example, a printing speed of 21 to 30 sheets / min), and a high speed at which the developer conveying roller according to the present invention is preferably employed. The printing type image forming apparatus is basically configured in the same manner as the image forming apparatus 30, for example, which forms an image at a conventional printing speed except that the image forming speed is as high as 31 to 40 sheets / min. Therefore, the high-speed printing type image forming apparatus employing the developer conveying roller according to the present invention can form an image having a desired print density stably over a long period of time, similar to the image forming apparatus 30. The developing means employing the developer conveying roller can contribute to forming an image having a desired print density stably over a long period of time, like the developing means 40.
The developer conveying roller, the developing device, and the image forming apparatus according to the present invention are not limited to the above-described examples, and various modifications can be made as long as the object of the present invention can be achieved. For example, the developer transport roller 1 includes the foamed elastic layer 3 having a single layer structure. However, in the present invention, the developer transport roller may include a foamed elastic layer having two or more layers.
Although the developer conveying roller 1 includes the shaft body 2 and the foamed elastic layer 3, in this invention, the developer conveying roller may include a surface layer on the outer peripheral surface of the foamed elastic layer.
In the developer conveying roller 1, the foamed elastic layer 3 is formed on the outer peripheral surface of the shaft body 2 without any other layer. In the present invention, the adhesion between the shaft body and the elastic layer, It is also possible to provide a primer layer, an adhesive layer or the like that improves followability.
The image forming apparatus 30 is an electrophotographic image forming apparatus. However, in the present invention, the image forming apparatus is not limited to the electrophotographic system, and may be, for example, an electrostatic image forming apparatus. Good.
Further, the image forming apparatus 30 is a monochrome image forming apparatus in which the developing unit 40 contains only a single color developer 42. However, in this invention, the image forming apparatus is not limited to a monochrome image forming apparatus. It may be an image forming apparatus. Examples of the color image forming apparatus include a four-cycle color image forming apparatus that sequentially repeats primary transfer of a developer image carried on an image carrier to an intermediate transfer body, and a plurality of image carriers provided with developing means for each color. Examples thereof include a tandem type color image forming apparatus in which a body is arranged in series on an intermediate transfer body or a transfer conveyance belt. The image forming apparatus 30 is an image forming apparatus such as a copying machine, a facsimile machine, or a printer.
In the image forming apparatus 30, a one-component developer is advantageously used as the developer 42, but a two-component developer including a toner and a carrier such as iron or nickel can also be used.
In the present invention, the developing device includes a developing unit that is detachable from the image forming apparatus.

  The developer conveying roller, the developing device, and the image forming apparatus according to the present invention are not limited to the above-described embodiments, and various modifications can be made within a range in which the object of the present invention can be achieved.

Example 1
An addition reaction type foamed conductive silicone rubber composition was prepared as a rubber composition for forming a foamed elastic layer. That is, a silicone foam rubber composition “KE-904FU” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) 70 containing a vinyl group-containing silicone raw rubber and a silica-based filler within the above range and no conductivity-imparting agent. 42.8 parts by weight and 30 parts by weight of a conductivity imparting agent “KE-87C40PU” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) (100 parts by weight in total of vinyl group-containing silicone raw rubber and silica filler) Part by mass) and 2 parts by mass of an addition reaction crosslinking agent “C-153A” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) (100 parts by mass in total of vinyl group-containing silicone raw rubber and silica-based filler). 9 parts by mass), 5 parts by mass of the blowing agent azobis-isobutyronitrile (7.1 parts by mass with respect to a total of 100 parts by mass of the vinyl group-containing silicone raw rubber and the silica-based filler), 0.45 parts by mass of platinum catalyst as an addition reaction catalyst (0.64 parts by mass with respect to 100 parts by mass in total of vinyl group-containing silicone raw rubber and silica filler), and reaction control agent “R-153A” (Shin-Etsu) Chemical Industry Co., Ltd .: Trade name) 0.5 parts by mass (0.71 parts by mass with respect to 100 parts by mass in total of the vinyl group-containing silicone raw rubber and silica-based filler) and the organic peroxide crosslinking agent “C -3 ”(manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) was adequately kneaded with two rolls to prepare an addition reaction type foamed conductive silicone rubber composition.
A shaft body (diameter 6 mm × length 370 mm, SUM22) subjected to electroless nickel plating was washed with toluene, and a primer “No. 101A / B” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) was applied. The primer-treated shaft was fired at a temperature of 150 ° C. for 30 minutes using a gear oven, and then cooled at room temperature for 30 minutes or more to form a primer layer.
Next, the shaft body 2 on which the primer layer is formed and the prepared addition reaction type foamed conductive silicone rubber composition are integrally dispensed by an extruder, and then at 260 ° C. using an infrared heating furnace (IR furnace). It was heated for 10 minutes to effect foam crosslinking (primary curing). Thereafter, the addition reaction type foamed conductive silicone rubber composition after foaming and crosslinking was further heated at 200 ° C. for 4 hours using a gear oven, and left at room temperature for 1 hour. Next, the addition reaction type foamed conductive silicone rubber composition that has been foam-cured is polished with a cylindrical grinder to form a so-called straight-shaped foamed elastic layer 3 having an outer diameter of 15 mm and constant in the axial direction, thereby producing a roller. did. In this roller, the length of the foamed elastic layer 3 in the axial direction was 330 mm.

  Next, 100 parts by mass of a methylphenyl silicone resin “KR-271” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) and an aminosilane coupling agent “3-aminopropyltriethoxysilane” (trade name “KBE-903”, 5 parts by mass of Shin-Etsu Chemical Co., Ltd.), 5 parts by mass of carbon black “ECP600JD” (manufactured by Lion Corporation: product name) as a conductivity imparting agent, and a curing agent “CAT-AC” (manufactured by Shin-Etsu Chemical Co., Ltd.) : Product name) 1 mass part and diluent “KF96” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) 100 parts by mass of a resin composition prepared by mixing, the outer surface of the foamed elastic layer 3 in the roller A silicone coating layer 4 was formed by applying the film by dipping so that the thickness after curing was 9 μm, followed by heat curing at 150 ° C. for 3 hours. In this way, the developer conveying roller 1 was manufactured.

(Examples 2 and 3: change in blending amount)
A developer transport roller was produced basically in the same manner as in Example 1 except that the content of the aminosilane coupling agent was changed to 1 part by mass or 10 parts by mass.

(Example 4: Aminosilane coupling agent change)
Example 1 except that the aminosilane coupling agent was changed to “N-2- (aminoethyl) -3-aminopropyltriethoxysilane” (trade name “KBM-603”, manufactured by Shin-Etsu Chemical Co., Ltd.). A developer conveying roller was produced basically in the same manner as described above.

(Example 5: Change of methylphenyl silicone resin)
A developer conveying roller was produced basically in the same manner as in Example 1, except that the methylphenyl silicone resin was changed to “SILRES H62C” (manufactured by Asahi Kasei Wacker Silicone Co., Ltd .: trade name).

(Example 6)
A developer conveying roller was produced in basically the same manner as in Example 1 except that the thickness of the silicone coat layer was changed to 1 μm.

(Comparative Example 1)
A developer conveying roller was produced basically in the same manner as in Example 1 except that the silicone coat layer 4 was not provided.

(Comparative Example 2)
A developer conveying roller was produced basically in the same manner as in Example 1 except that the methylphenyl silicone resin was changed to methyl silicone resin “KR-251” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name). .

(Measurement of Asker F hardness)
The Alker F hardness of each manufactured developer transport roller and the Asker F hardness of the foamed elastic layer 3 before forming the silicone coat layer 4 were measured as described above. The Asker F hardness is measured at three locations on the developer conveying roller and the foamed elastic layer (measurement points are on the same line on the outer peripheral surface of the foamed elastic layer, and 2 mm of 25 mm from both ends of the foamed elastic layer toward the center). It is an arithmetic average value when the measurement point is one place in the place and the central part). Table 1 shows the measured Asker F hardness of the developer conveying roller and the foamed elastic layer 3.

(Measurement of JIS A hardness)
A flat test piece having a thickness of 7 mm was produced using only the various silicone resins used in the examples and comparative examples. The JIS A hardness of the produced flat test piece was measured as described above, and the measured value was defined as the JIS A hardness of various silicone resins contained in the silicone coat layer 4. The results are shown in Table 1.

(Measurement of average cell diameter and expansion ratio)
Table 1 shows the results of measuring the average cell diameter and the expansion ratio of the foamed elastic layer 3 of each of the manufactured developer conveying rollers according to the measurement method.

(Abrasion resistance test)
The durability test of the silicone coat layer 4 was carried out by measuring the amount of decrease in the thickness of the silicone coat layer 4 by carrying out a durability test as follows using the manufactured developer conveying roller (excluding Comparative Example 1). Evaluated. Specifically, a metal shaft (outer diameter: 16 mm) obtained by blasting (# 200) and electroless nickel on the SUM material and the manufactured developer conveying roller are pressed against each other so that the nip width is 0.5 mm. Both the developer conveying roller and the metal shaft were rotated in the same direction at 500 rpm for 3 hours. The amount of decrease in the outer diameter of the developer conveying roller before and after the wear test was calculated. Evaluation is “◎” when the outer diameter reduction is less than 0.05 mm, “◯” when 0.05 mm or more and less than 0.10 mm, and 0.10 mm or more and less than 0.15 mm. Was “×”, and the case of 0.15 mm or more was “XX”. The results are shown in Table 1.

(Black solid printing evaluation)
The manufactured developer transport roller is mounted on a developing device of an image forming apparatus (trade name “MICROLINE 1032PS”, manufactured by Oki Data Corporation), and is operated in an environment of a temperature of 20 ° C. and a relative humidity of 50%. 6,000 sheets of solid printing were printed. Thereafter, black solid-halftone dot-5% duty-white background printing was repeated twice, and the Macbeth density of the black solid print portion printed at the second time was measured using a Macbeth densitometer. The case where the Macbeth density of the black solid printing portion is 1.3 to 1.5 is “◎”, the case where the Macbeth density is 1.2 or more and less than 1.3 is “◯”, and the Macbeth density is 1 When it was less than 2 or more than 1.5, it was judged as a printing failure, and “x” was assigned. The results are shown in Table 1.

DESCRIPTION OF SYMBOLS 1 Developer conveyance roller 2 Shaft body 3 Foam elastic layer 4 Silicone coat layer 6 Cell 30 Image forming apparatus 31 Image carrier 32 Charging means 33 Exposure means 34 Transfer means 35 Fixing apparatus 36 Recording body 37 Cleaning means 40 Developing means 41 Developer Storage unit 42 Developer 43 Developer supply means 44 Developer carrier 45 Developer regulating member 50 Housing 52 Opening

53 Fixing Roller 54 Endless Belt Support Roller 55 Endless Belt 56 Pressure Roller

Claims (9)

  A developer conveying roller comprising: a foamed elastic layer; and a silicone coating layer disposed on an outer peripheral surface of the foamed elastic layer and including a methylphenyl silicone resin and an aminosilane coupling agent.   The silicone coat layer is formed by curing a resin composition containing 100 parts by mass of a methylphenyl silicone resin and 1 to 10 parts by mass of an aminosilane coupling agent on the outer peripheral surface of the foamed elastic layer. The developer conveying roller according to the description.   The developer transport roller according to claim 1, wherein the silicone coat layer has a thickness of 9 μm or less. The developer conveying roller according to claim 1, wherein the developer conveying roller has an Asker F hardness of 45 to 70. 5.   The developer transport roller according to claim 1, wherein the aminosilane coupling agent is 3-aminopropyltriethoxysilane.   The developer conveying roller according to any one of claims 1 to 5, wherein the methylphenyl silicone resin has a JIS A hardness of 55 to 85 in a flat test piece having a thickness of 7 mm.   The developer conveying roller according to any one of claims 1 to 6, wherein the foamed elastic layer has an Asker F hardness of 40 to 65.   8. A developer carrier that carries the developer and supplies the developer to the image carrier, and is placed in pressure contact with the developer carrier, and conveys the developer to the developer carrier. A developing device comprising: the developer conveying roller according to item 1; and a developer disposed around the developer conveying roller.   An image forming apparatus comprising the developer conveying roller according to claim 1.

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