JP2012121948A - Solvent composition for cleaning - Google Patents
Solvent composition for cleaning Download PDFInfo
- Publication number
- JP2012121948A JP2012121948A JP2010271709A JP2010271709A JP2012121948A JP 2012121948 A JP2012121948 A JP 2012121948A JP 2010271709 A JP2010271709 A JP 2010271709A JP 2010271709 A JP2010271709 A JP 2010271709A JP 2012121948 A JP2012121948 A JP 2012121948A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- solvent composition
- cleaning
- parts
- cleaned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000002904 solvent Substances 0.000 title claims abstract description 58
- 238000004140 cleaning Methods 0.000 title claims abstract description 43
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 31
- 229930195733 hydrocarbon Natural products 0.000 claims description 30
- 229910052731 fluorine Inorganic materials 0.000 claims description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- 239000003921 oil Substances 0.000 description 53
- 239000002480 mineral oil Substances 0.000 description 18
- 235000010446 mineral oil Nutrition 0.000 description 16
- 239000011737 fluorine Substances 0.000 description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 239000012459 cleaning agent Substances 0.000 description 10
- -1 glycol ethers Chemical class 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- DJXNLVJQMJNEMN-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane Chemical compound COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F DJXNLVJQMJNEMN-UHFFFAOYSA-N 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 4
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 4
- FNUBKINEQIEODM-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropentanal Chemical compound FC(F)(F)C(F)(F)C(F)(F)CC=O FNUBKINEQIEODM-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 229940104873 methyl perfluorobutyl ether Drugs 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229940104872 methyl perfluoroisobutyl ether Drugs 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- WBRFDUJXCLCKPX-UHFFFAOYSA-N 2,3-dimethylheptane Chemical compound CCCCC(C)C(C)C WBRFDUJXCLCKPX-UHFFFAOYSA-N 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N 2-Methylheptane Chemical compound CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- HHPDFYDITNAMAM-UHFFFAOYSA-N 2-[cyclohexyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)C1CCCCC1 HHPDFYDITNAMAM-UHFFFAOYSA-N 0.000 description 2
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 2
- HGEMCUOAMCILCP-UHFFFAOYSA-N 2-methyldodecane Chemical compound CCCCCCCCCCC(C)C HGEMCUOAMCILCP-UHFFFAOYSA-N 0.000 description 2
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
- CJBFZKZYIPBBTO-UHFFFAOYSA-N 2-methyltridecane Chemical compound CCCCCCCCCCCC(C)C CJBFZKZYIPBBTO-UHFFFAOYSA-N 0.000 description 2
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- GGBJHURWWWLEQH-UHFFFAOYSA-N butylcyclohexane Chemical compound CCCCC1CCCCC1 GGBJHURWWWLEQH-UHFFFAOYSA-N 0.000 description 2
- 239000010730 cutting oil Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- HMSWAIKSFDFLKN-UHFFFAOYSA-N hexacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC HMSWAIKSFDFLKN-UHFFFAOYSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 231100001231 less toxic Toxicity 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 125000004971 nitroalkyl group Chemical group 0.000 description 2
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- DEDZSLCZHWTGOR-UHFFFAOYSA-N propylcyclohexane Chemical compound CCCC1CCCCC1 DEDZSLCZHWTGOR-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- POOSGDOYLQNASK-UHFFFAOYSA-N tetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC POOSGDOYLQNASK-UHFFFAOYSA-N 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- OMMLUKLXGSRPHK-UHFFFAOYSA-N tetramethylbutane Chemical compound CC(C)(C)C(C)(C)C OMMLUKLXGSRPHK-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- QKAGYSDHEJITFV-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)pentane Chemical compound FC(F)(F)C(F)(F)C(F)(OC)C(F)(C(F)(F)F)C(F)(F)F QKAGYSDHEJITFV-UHFFFAOYSA-N 0.000 description 1
- TZMQCOROQZMJIS-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)pentane Chemical compound FC(F)(F)C(F)C(F)(F)C(C)OC(F)(F)C(F)C(F)(F)F TZMQCOROQZMJIS-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical compound C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- COJYJGCWESKHMR-UHFFFAOYSA-N 1-cyclohexyltetradecylcyclohexane Chemical compound C1CCCCC1C(CCCCCCCCCCCCC)C1CCCCC1 COJYJGCWESKHMR-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- RHISRDQWNQEBBY-UHFFFAOYSA-N 1-phenyltetradecylbenzene Chemical compound C=1C=CC=CC=1C(CCCCCCCCCCCCC)C1=CC=CC=C1 RHISRDQWNQEBBY-UHFFFAOYSA-N 0.000 description 1
- IIYGOARYARWJBO-UHFFFAOYSA-N 2,2,4-trimethylheptane Chemical compound CCCC(C)CC(C)(C)C IIYGOARYARWJBO-UHFFFAOYSA-N 0.000 description 1
- YFHGNGNLIWGTTR-UHFFFAOYSA-N 2,3,4-trimethyldecane Chemical compound CCCCCCC(C)C(C)C(C)C YFHGNGNLIWGTTR-UHFFFAOYSA-N 0.000 description 1
- QSSUTSOGIQHRIU-UHFFFAOYSA-N 2,3-dimethylundecane Chemical compound CCCCCCCCC(C)C(C)C QSSUTSOGIQHRIU-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- IBLVSWYGUFGDMF-UHFFFAOYSA-N 2-cyclohexylethylcyclohexane Chemical compound C1CCCCC1CCC1CCCCC1 IBLVSWYGUFGDMF-UHFFFAOYSA-N 0.000 description 1
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 1
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- NKMJCVVUYDKHAV-UHFFFAOYSA-N 3-ethyl-2-methylheptane Chemical compound CCCCC(CC)C(C)C NKMJCVVUYDKHAV-UHFFFAOYSA-N 0.000 description 1
- JORZBSFPMKMFMU-UHFFFAOYSA-N 9-dodecylanthracene Chemical compound C1=CC=C2C(CCCCCCCCCCCC)=C(C=CC=C3)C3=CC2=C1 JORZBSFPMKMFMU-UHFFFAOYSA-N 0.000 description 1
- QBNLPAPGLLSKBN-UHFFFAOYSA-N 9-dodecylphenanthrene Chemical compound C1=CC=C2C(CCCCCCCCCCCC)=CC3=CC=CC=C3C2=C1 QBNLPAPGLLSKBN-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- QQUZVPOZCFYGDY-UHFFFAOYSA-N heptadecan-9-ylcyclohexane Chemical compound CCCCCCCCC(CCCCCCCC)C1CCCCC1 QQUZVPOZCFYGDY-UHFFFAOYSA-N 0.000 description 1
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- PLZDDPSCZHRBOY-UHFFFAOYSA-N inaktives 3-Methyl-nonan Natural products CCCCCCC(C)CC PLZDDPSCZHRBOY-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- HOWGUJZVBDQJKV-UHFFFAOYSA-N n-propyl-nonadecane Natural products CCCCCCCCCCCCCCCCCCCCCC HOWGUJZVBDQJKV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- IRKYBYIUHWZQGP-UHFFFAOYSA-N octan-2-ylcyclohexane Chemical compound CCCCCCC(C)C1CCCCC1 IRKYBYIUHWZQGP-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- GRJUENNHVNYCHD-UHFFFAOYSA-N ξ-3-methyldodecane Chemical compound CCCCCCCCCC(C)CC GRJUENNHVNYCHD-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
本発明は、洗浄用溶剤組成物に関し、更に詳しくは、油が付着した被洗浄物を洗浄するための溶剤組成物に関する。 The present invention relates to a cleaning solvent composition, and more particularly to a solvent composition for cleaning an object to be cleaned to which oil adheres.
電気・電子部品、光学部品、自動車部品、及び機械部品の加工及び製造において、各種部品には、種々の油類、例えば、切削油、プレス油、引抜き油、熱処理油、防錆油、及び潤滑油等が付着するため、これらが付着した各種部品の洗浄工程が必要である。 In the processing and manufacturing of electrical / electronic parts, optical parts, automobile parts, and machine parts, various parts include various oils such as cutting oil, press oil, drawing oil, heat treatment oil, rust prevention oil, and lubrication. Since oil or the like adheres, a cleaning process of various parts to which these adhere is necessary.
特許文献１には、（ａ）メチルパーフルオロブチルエーテル、メチルパーフルオロイソブチルエーテルおよびこれらの混合物から選ばれる少なくとも一種以上の化合物と（ｂ）特定のグリコールエーテル類から選ばれる少なくとも一種以上の化合物を含有することを特徴とする不燃性洗浄剤が記載されている。
特許文献２には、１，１，１，３，３−ペンタフルオロブタン（３６５ｍｆｃ、化学式Ｃ４Ｈ５Ｆ５）と、プロピレングリコール系溶剤とを含有し、引火性がないことを特徴とする洗浄用溶剤組成物が、洗浄能力、特に脱脂洗浄能力の大幅なアップが図れ、各種洗浄剤としては、十分な性能を発揮させることができることが記載されている。
いずれの文献においても、鉱物油に対する洗浄剤が開示されているが、様々な種類の油に対して優れた洗浄効果を発揮する溶剤組成物は開示されておらず、様々な種類の油のいずれに対しても優れた洗浄効果を有する洗浄剤としては、ＨＣＦＣ２２５（３，３−ジクロロ−１，１，１，２，２−ペンタフルオロプロパンと１，３−ジクロロ−１，１，２，２，３−ペンタフルオロプロパンの混合物）などの塩素系溶剤が用いられているが、オゾン破壊係数が高く、規制の対象となっている。
Patent Document 1 contains (a) at least one compound selected from methyl perfluorobutyl ether, methyl perfluoroisobutyl ether and mixtures thereof, and (b) at least one compound selected from specific glycol ethers. Non-flammable cleaning agents are described which are characterized by
Patent Document 2 contains 1,1,1,3,3-pentafluorobutane (365 mfc, chemical formula C 4 H 5 F 5 ) and a propylene glycol solvent, and is not flammable. It is described that the cleaning solvent composition can greatly improve the cleaning capability, particularly the degreasing cleaning capability, and can exhibit sufficient performance as various cleaning agents.
In any document, a cleaning agent for mineral oil is disclosed, but a solvent composition that exhibits an excellent cleaning effect for various types of oil is not disclosed, and any of various types of oil is not disclosed. As a cleaning agent having an excellent cleaning effect against HCFC225 (3,3-dichloro-1,1,1,2,2-pentafluoropropane and 1,3-dichloro-1,1,2,2) , 3-pentafluoropropane mixture) is used, but it has a high ozone depletion coefficient and is subject to regulation.
本発明は、様々な種類の油による汚れに対して優れた洗浄力を発揮する洗浄用溶剤組成物を提供するものである。 The present invention provides a cleaning solvent composition that exhibits an excellent detergency against dirt caused by various types of oil.
本発明者らは、前記の課題を解決するべく鋭意研究を重ねた結果、１，１，１，３，３−ペンタフルオロブタン（３６５ｍｆｃ）、及び１種以上の特定のハイドロフルオロエーテル化合物を主成分とする溶剤組成物が、油が付着した被洗浄物に対して優れた洗浄効果を有することを見出し本発明に至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have mainly used 1,1,1,3,3-pentafluorobutane (365mfc) and one or more specific hydrofluoroether compounds. The present inventors have found that the solvent composition as a component has an excellent cleaning effect for an object to be cleaned to which oil adheres, and have reached the present invention.
すなわち、本発明は、（ａ）１，１，１，３，３−ペンタフルオロブタン１００重量部に対して、（ｂ）１種以上の、一般式（１）：
Ｒ１−Ｏ−Ｒ２ （１）
（式中、
Ｒ１は、少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基であり、
Ｒ２は、炭素原子数１〜４のアルキル基、又は少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基である）
で示される、ハイドロフルオロエーテル化合物を４０〜４５０重量部含むことを特徴とする、油が付着した被洗浄物を洗浄するための溶剤組成物に関する。
また、本発明は、さらに、（ａ）成分及び（ｂ）成分の合計１００重量部に対して、（ｃ）炭化水素系溶剤を０．１重量部〜５０重量部含む、前記に記載の溶剤組成物に関する。
That is, the present invention relates to (a) 100 parts by weight of 1,1,1,3,3-pentafluorobutane (b) one or more general formulas (1):
R 1 —O—R 2 (1)
(Where
R 1 is an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom,
R 2 is an alkyl group having 1 to 4 carbon atoms, or an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom)
It is related with the solvent composition for wash | cleaning the to-be-washed | cleaned material to which oil adhere | attached characterized by including 40-450 weight part of hydrofluoroether compounds shown by these.
In addition, the present invention further includes (c) a hydrocarbon solvent in an amount of 0.1 to 50 parts by weight with respect to 100 parts by weight of the total of component (a) and component (b). Relates to the composition.
本発明の溶剤組成物は、油が付着した被洗浄物に対して良好な洗浄効果を奏する。また、本発明の溶剤組成物は、乾燥性に優れるため本発明の溶剤組成物を用いて洗浄した被洗浄物には洗浄しみが存在せず、さらに毒性も少なく、安全性の面からも非常に優れている。 The solvent composition of the present invention has a good cleaning effect on an object to be cleaned to which oil adheres. In addition, since the solvent composition of the present invention is excellent in drying properties, the object to be cleaned that has been cleaned using the solvent composition of the present invention does not have a stain, is less toxic, and is extremely safe from the viewpoint of safety. Is excellent.
本発明の溶剤組成物は、（ａ）１，１，１，３，３−ペンタフルオロブタン１００重量部に対して、（ｂ）１種以上の、一般式（１）：
Ｒ１−Ｏ−Ｒ２ （１）
（式中、
Ｒ１は、少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基であり、
Ｒ２は、炭素原子数１〜４のアルキル基、又は少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基である）
で示される、ハイドロフルオロエーテル化合物を４０〜４５０重量部含む。
The solvent composition of the present invention comprises (b) one or more general formulas (1) with respect to 100 parts by weight of 1,1,1,3,3-pentafluorobutane:
R 1 —O—R 2 (1)
(Where
R 1 is an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom,
R 2 is an alkyl group having 1 to 4 carbon atoms, or an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom)
40 to 450 parts by weight of a hydrofluoroether compound represented by the formula:
本発明において、少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基は、直鎖状又は分岐鎖状であってよく、好ましくは、下記式（２）：
ＣｎＨｍＦ（２ｎ−ｍ＋１）− （２）
（式中、
ｎは、３〜６の整数であり、
ｍは、０又は１〜６の整数であり、そして
ｍ≦ｎである）
で示される基であり、特に好ましくは、下記式（３）：
ＣｎＦ（２ｎ＋１）− （３）
（式中、ｎは、３〜６の整数である）
で示されるペルフルオロアルキル基である。
In the present invention, the alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom may be linear or branched, and preferably has the following formula (2):
C n H m F (2n−m + 1) − (2)
(Where
n is an integer of 3 to 6,
m is 0 or an integer from 1 to 6, and m ≦ n.
And particularly preferably the following formula (3):
C n F (2n + 1) − (3)
(In the formula, n is an integer of 3 to 6)
The perfluoroalkyl group shown by these.
このような少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基の具体例は、−Ｃ３Ｆ６Ｈ、−Ｃ３Ｆ４Ｈ３、−ＣＨ（ＣＨ３）ＣＦ２ＣＨＦＣＦ３、及び−ＣＦ２ＣＨＦＣＦ３などのハイドロフルオロアルキル基、並びに−Ｃ３Ｆ７、−ＣＦ（ＣＦ３）ＣＦ３、−Ｃ４Ｆ９、−ＣＦ（ＣＦ３）ＣＦ２ＣＦ３、及び−ＣＦ（Ｃ２Ｆ５）ＣＦ（ＣＦ３）ＣＦ３などのペルフルオロアルキル基が挙げられる。 Specific examples of such at least one alkyl group having a carbon number of 3-6, which is substituted by fluorine atoms, -C 3 F 6 H, -C 3 F 4 H 3, -CH (CH 3) CF 2 CHFCF 3, and hydro fluoroalkyl groups such as -CF 2 CHFCF 3 and -C 3 F 7,, -CF ( CF 3) CF 3, -C 4 F 9, -CF (CF 3) CF 2 CF 3 and - Examples include perfluoroalkyl groups such as CF (C 2 F 5 ) CF (CF 3 ) CF 3 .
炭素原子数１〜４のアルキル基としては、メチル基、エチル基、ｎ−プロピル基、イソプロピル基、ｎ−ブチル基、イソブチル基、ｔ−ブチル基が挙げられ、好ましくはメチル基及びエチル基である。 Examples of the alkyl group having 1 to 4 carbon atoms include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, and a t-butyl group, preferably a methyl group and an ethyl group. is there.
よって、一般式（１）で示されるハイドロフルオロエーテルとしては、メチルパーフルオロエーテル、メチルノナフルオロブチルエーテル、メチルノナフルオロイソブチルエーテル、エチルノナフルオロブチルエーテル、エチルノナフルオロイソブチルエーテル、１,１,１，２，２，３，４，５，５，５−デカフルオロ−３−メトキシ−４−（トリフルオロメチル）ペンタン、１，１，１，２，３，３−ヘキサフルオロ−４−（１，１，２，３，３，３−ヘキサフルオロプロポキシ）−ペンタンが挙げられ、メチルノナフルオロブチルエーテル、メチルノナフルオロイソブチルエーテル、エチルノナフルオロブチルエーテル、エチルノナフルオロイソブチルエーテルが好ましい。 Accordingly, the hydrofluoroether represented by the general formula (1) includes methyl perfluoroether, methyl nonafluorobutyl ether, methyl nonafluoroisobutyl ether, ethyl nonafluorobutyl ether, ethyl nonafluoroisobutyl ether, 1,1,1,2 , 2,3,4,5,5,5-decafluoro-3-methoxy-4- (trifluoromethyl) pentane, 1,1,1,2,3,3-hexafluoro-4- (1,1 , 2,3,3,3-hexafluoropropoxy) -pentane, and methyl nonafluorobutyl ether, methyl nonafluoroisobutyl ether, ethyl nonafluorobutyl ether, and ethyl nonafluoroisobutyl ether are preferable.
以上より、（ｂ）成分として、メチルノナフルオロブチルエーテル、メチルノナイソブチルエーテル、エチルノナフルオロブチルエーテル、エチルノナイソブチルエーテル、メチルノナフルオロブチルエーテル及びメチルノナイソブチルエーテルの混合物、並びにエチルノナフルオロブチルエーテル及びエチルノナイソブチルエーテルの混合物が好ましい。 From the above, as component (b), methyl nonafluorobutyl ether, methyl nonaisobutyl ether, ethyl nonafluorobutyl ether, ethyl nonaisobutyl ether, a mixture of methyl nonafluorobutyl ether and methyl nonaisobutyl ether, and ethyl nonafluorobutyl ether and ethyl nonaiso A mixture of butyl ether is preferred.
（ｂ）成分において、２以上のハイドロフルオロエーテル化合物の混合物を用いる場合、これらの成分の含有量の比は任意であってよい。例えば、（ｂ）成分として、メチルパーフルオロブチルエーテル及びメチルパーフルオロイソブチルエーテルの混合物を用いる場合、メチルパーフルオロブチルエーテル及びメチルパーフルオロイソブチルエーテルの混合物の重量に対して、メチルパーフルオロブチルエーテルは５〜９５重量％が好ましく、５０〜８０重量％がより好ましい。このようなハイドロフルオロエーテルは、市販品として、住友スリーエム社より、ＨＦＥ７０００、ＨＦＥ７１００、ＨＦＥ７２００、ＨＦＥ７３００、ＨＦＥ７６００などのノベックＨＦＥシリーズが挙げられる。 In the component (b), when a mixture of two or more hydrofluoroether compounds is used, the ratio of the contents of these components may be arbitrary. For example, when a mixture of methyl perfluorobutyl ether and methyl perfluoroisobutyl ether is used as component (b), methyl perfluorobutyl ether is 5 to 95 based on the weight of the mixture of methyl perfluorobutyl ether and methyl perfluoroisobutyl ether. % By weight is preferable, and 50 to 80% by weight is more preferable. As such a hydrofluoroether, Novec HFE series such as HFE7000, HFE7100, HFE7200, HFE7300, and HFE7600 are available from Sumitomo 3M as a commercial product.
本発明において、（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物が４０重量部未満であると、特にフッ素オイルを被洗浄物から効率よく洗浄除去することが難しく、４５０重量部を超えると、特に鉱物油などに対する洗浄効果が劣るので好ましくない。本発明の溶剤組成物は、（ａ）１，１，１，３，３−ペンタフルオロブタン１００重量部に対して、（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテルを５０〜４００重量部含むのが好ましく、７０〜３５０重量部含むのがより好ましい。 In the present invention, when (b) the hydrofluoroether compound represented by one or more general formulas (1) is less than 40 parts by weight, it is particularly difficult to efficiently wash and remove fluorine oil from an object to be cleaned. Exceeding parts by weight is not preferable because the cleaning effect on mineral oil and the like is particularly poor. The solvent composition of the present invention comprises (a) 100 parts by weight of 1,1,1,3,3-pentafluorobutane, (b) one or more hydrofluoroethers represented by the general formula (1). It is preferable to contain 50 to 400 parts by weight, and more preferably 70 to 350 parts by weight.
また、本発明の溶剤組成物は、例えばフッ素オイルが付着した被洗浄物を洗浄するために、（ａ）１，１，１，３，３−ペンタフルオロブタン１００重量部に対して、（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物を１００〜４５０重量部含むのが好ましく、１５０〜４５０重量部含むのがより好ましい。さらに、本発明の溶剤組成物は、鉱物油が付着した被洗浄物を洗浄するために、（ａ）１，１，１，３，３−ペンタフルオロブタン１００重量部に対して、（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物を４０〜１００重量部含むのが好ましく、４０〜７０重量部含むのがより好ましい。このような範囲であれば、油が付着した被洗浄物に対する浸透力が高くなり、洗浄時間が短くなる点で良好である。また、洗浄後に被洗浄物に洗浄しみが残らず、かつ被洗浄物に対する乾燥性が優れ、洗浄時間が短くなり、さらなるすすぎ工程を必要としない点で良好である。また、本発明において、（ａ）１，１，１，３，３−ペンタフルオロブタン及び（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物は、全溶剤に対して１０重量％〜１００重量％の含有量で含まれる。 In addition, the solvent composition of the present invention, for example, in order to clean an object to be cleaned to which fluorine oil adheres, (b) 100 parts by weight of 1,1,1,3,3-pentafluorobutane (b) ) It is preferable to contain 100 to 450 parts by weight, more preferably 150 to 450 parts by weight of the hydrofluoroether compound represented by one or more general formulas (1). Furthermore, the solvent composition of the present invention comprises (b) 100 parts by weight of (a) 1,1,1,3,3-pentafluorobutane in order to wash the object to which the mineral oil is adhered. It is preferable that 40-100 weight part of hydrofluoroether compounds shown by 1 or more types of General formula (1) are included, and it is more preferable that 40-70 weight part is included. If it is such a range, it is favorable at the point which the osmotic power with respect to the to-be-cleaned object to which oil adhered becomes high, and cleaning time becomes short. Further, it is favorable in that no stains remain on the object to be cleaned after cleaning, the drying property for the object to be cleaned is excellent, the cleaning time is shortened, and no further rinsing step is required. In the present invention, (a) 1,1,1,3,3-pentafluorobutane and (b) one or more hydrofluoroether compounds represented by the general formula (1) It is contained at a content of from wt% to 100 wt%.
本発明の溶剤組成物は、更なる洗浄力の向上のために（ｃ）炭化水素系溶剤を添加することができる。炭化水素系溶剤として、パラフィン系炭化水素、イソパラフィン系炭化水素、ナフテン系炭化水素、芳香族系炭化水素、並びにパラフィン系炭化水素、イソパラフィン系炭化水素、ナフテン系炭化水素及び芳香族系炭化水素からなる群より選択される２以上の炭化水素の混合物が挙げられる。 To the solvent composition of the present invention, (c) a hydrocarbon solvent can be added for further improvement of detergency. Hydrocarbon solvents include paraffinic hydrocarbons, isoparaffinic hydrocarbons, naphthenic hydrocarbons, aromatic hydrocarbons, and paraffinic hydrocarbons, isoparaffinic hydrocarbons, naphthenic hydrocarbons, and aromatic hydrocarbons. And a mixture of two or more hydrocarbons selected from the group.
パラフィン系炭化水素は、直鎖状の脂肪族炭化水素であり、例えば、ｎ−ヘキサン、ｎ−ヘプタン、ｎ−オクタン、ｎ−ノナン、ｎ−デカン、ｎ−ウンデカン、ｎ−テトラデカン、ｎ−ヘキサデカン、ｎ−エイコサン、ｎ−テトラコサン、及びｎ−ヘキサコサン等が挙げられる。 Paraffin hydrocarbons are linear aliphatic hydrocarbons such as n-hexane, n-heptane, n-octane, n-nonane, n-decane, n-undecane, n-tetradecane, and n-hexadecane. , N-eicosane, n-tetracosane, n-hexacosane and the like.
イソパラフィン系炭化水素は、分岐状の脂肪族炭化水素であり、例えば、ヘキサメチルエタン、２−メチルヘプタン、３−メチルヘプタン、２，２，４−トリメチルヘプタン、２，３−ジメチルヘプタン、２−メチルノナン、２−メチル−３−エチルヘプタン、２−メチルデカン、２，３，４−トリメチルデカン、２，３−ジメチルウンデカン、２−メチルドデカン、２−メチルプロピル−３−ドデカン、２−エチルウンデカン、及び２−メチルトリデカン等が挙げられる。 Isoparaffinic hydrocarbons are branched aliphatic hydrocarbons such as hexamethylethane, 2-methylheptane, 3-methylheptane, 2,2,4-trimethylheptane, 2,3-dimethylheptane, 2- Methylnonane, 2-methyl-3-ethylheptane, 2-methyldecane, 2,3,4-trimethyldecane, 2,3-dimethylundecane, 2-methyldodecane, 2-methylpropyl-3-dodecane, 2-ethylundecane, And 2-methyltridecane.
ナフテン系炭化水素は、炭化水素基を置換基として有していてもよい環状構造有する脂肪族飽和炭化水素であり、例えば、シクロヘキサン、メチルシクロヘキサン、エチルシクロヘキサン、プロピルシクロヘキサン、ブチルシクロヘキサン、２−メチルプロピルシクロヘキサン、２−シクロヘキシルオクタン、９−シクロヘキシルヘプタデカン、１，２−ジシクロヘキシルエタン、及び１，１−ジシクロヘキシルテトラデカン等が挙げられる。
芳香族系炭化水素としては、例えば、１，２−ジフェニルエタン、１，１−ジフェニルテトラデカン、９−ｎ−ドデシルフェナントレン、及び９−ｎ−ドデシルアントラセン等が挙げられる。
Naphthenic hydrocarbons are aliphatic saturated hydrocarbons having a cyclic structure which may have a hydrocarbon group as a substituent, such as cyclohexane, methylcyclohexane, ethylcyclohexane, propylcyclohexane, butylcyclohexane, 2-methylpropyl. Examples include cyclohexane, 2-cyclohexyloctane, 9-cyclohexylheptadecane, 1,2-dicyclohexylethane, and 1,1-dicyclohexyltetradecane.
Examples of the aromatic hydrocarbon include 1,2-diphenylethane, 1,1-diphenyltetradecane, 9-n-dodecylphenanthrene, 9-n-dodecylanthracene, and the like.
本発明において、（ｃ）炭化水素系溶剤の含有量は、（ａ）成分及び（ｂ）成分の合計１００重量部に対して、好ましくは０．１重量部〜５０重量部であり、より好ましくは０．１〜３０重量部である。 In the present invention, the content of the (c) hydrocarbon solvent is preferably 0.1 to 50 parts by weight, more preferably 100 parts by weight in total for the components (a) and (b). Is 0.1 to 30 parts by weight.
本発明の溶剤組成物は、さらに、安定剤、アルコール、及びグリコールエーテルモノアルキルエーテルから選択される１以上の（ｄ）添加剤を含むことができる。 The solvent composition of the present invention may further contain one or more (d) additives selected from stabilizers, alcohols, and glycol ether monoalkyl ethers.
安定剤として、ニトロアルカン系安定剤、エポキシド系安定剤、及びエーテル系安定剤が挙げられる。ニトロアルカン系安定剤としては、例えばニトロメタン、ニトロエタン、１−ニトロプロパン及び２−ニトロプロパンが挙げられ、毒性が少ないことからニトロメタン及びニトロエタンが好ましい。エポキシド系安定剤としては、１，２−ブチレンオキシド、プロピレンオキシド及びグリシドール等が挙げられる。エーテル系安定剤としては、１，３−ジオキソラン等が挙げられる。 Examples of stabilizers include nitroalkane stabilizers, epoxide stabilizers, and ether stabilizers. Examples of the nitroalkane stabilizer include nitromethane, nitroethane, 1-nitropropane and 2-nitropropane, and nitromethane and nitroethane are preferred because of their low toxicity. Examples of the epoxide stabilizer include 1,2-butylene oxide, propylene oxide, and glycidol. Examples of ether stabilizers include 1,3-dioxolane.
アルコールとしては、メタノール、エタノール、ｎ−プロパノール及びイソプロパノール等が挙げられ、エタノール及びイソプロパノールが好ましい。 Examples of the alcohol include methanol, ethanol, n-propanol, and isopropanol, and ethanol and isopropanol are preferable.
グリコールエーテルモノアルキルエーテルとして、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル及びジプロピレングリコールモノメチルエーテル等が挙げられ、プロピレングリコールモノメチルエーテルが好ましい。 Examples of the glycol ether monoalkyl ether include diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, and dipropylene glycol monomethyl ether, with propylene glycol monomethyl ether being preferred.
本発明において、（ｄ）添加剤の含有量の合計量は、（ａ）成分及び（ｂ）成分の合計１００重量部に対して、好ましくは０．１重量部〜１０重量部であり、より好ましくは１〜５重量部である。 In the present invention, the total content of the (d) additive is preferably 0.1 to 10 parts by weight with respect to 100 parts by weight of the total of the component (a) and the component (b). Preferably it is 1-5 weight part.
本発明の溶剤組成物は、本発明の目的を損なわない範囲内において、さらに防錆剤、界面活性剤、紫外線吸収剤及び酸化防止剤を含むことができる。これらは１種のみを用いてもよく、２種以上を用いてもよい。これらそれぞれの成分の含有量は、（ａ）成分及び（ｂ）成分の合計１００重量部に対して、０．１重量部〜５重量部含むことが好ましく、０．１重量部〜３重量部含むことがより好ましい。 The solvent composition of the present invention can further contain a rust inhibitor, a surfactant, an ultraviolet absorber and an antioxidant within the range not impairing the object of the present invention. These may use only 1 type and may use 2 or more types. The content of each of these components is preferably 0.1 to 5 parts by weight, preferably 0.1 to 3 parts by weight, based on 100 parts by weight of the total of component (a) and component (b). More preferably.
防錆剤としては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モノイソプロパノールアミン、ジイソプロパノールアミン、トリイソプロパノールアミン、アミノメチルプロパノールアミン、アミノエチルエタノールアミン、シクロヘキシルアミン、ジシクロヘキシルアミン及びＮ，Ｎ−ビス（２−ヒドロキシエチル）−Ｎ−シクロヘキシルアミンが挙げられ、Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−Ｎ−シクロヘキシルアミンが特に好ましい。 Examples of rust preventives include monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, aminomethylpropanolamine, aminoethylethanolamine, cyclohexylamine, dicyclohexylamine and N, N-bis ( 2-hydroxyethyl) -N-cyclohexylamine is exemplified, and N, N-bis (2-hydroxyethyl) -N-cyclohexylamine is particularly preferable.
本発明の溶剤組成物は、フッ素オイル及び鉱物油に対する溶解速度の向上のために、界面活性剤を含有することができる。界面活性剤としては、非イオン性界面活性剤が好ましく、例えば高級アルコールエチレンオキサイド付加物、アルキルフェノールエチレンオキサイド付加物、脂肪酸エチレンオキサイド付加物、高級アルキルアミンエチレンオキサイド付加物、ソルビトール及びソルビタンの脂肪酸エステル、ショ糖脂肪酸エステル、シリコーン系界面活性剤、及びフッ素系界面活性剤等が挙げられる。 The solvent composition of the present invention can contain a surfactant in order to improve the dissolution rate in fluorine oil and mineral oil. As the surfactant, a nonionic surfactant is preferable, for example, higher alcohol ethylene oxide adduct, alkylphenol ethylene oxide adduct, fatty acid ethylene oxide adduct, higher alkylamine ethylene oxide adduct, sorbitol and fatty acid esters of sorbitan, Examples thereof include sucrose fatty acid esters, silicone surfactants, and fluorine surfactants.
本発明の溶剤組成物は、洗浄液の長期保存等における安定性の向上のために、紫外線吸収剤及び酸化防止剤を含有することができる。紫外線吸収剤は、本発明の溶剤組成物に溶解するものであればいずれも使用することができ、ベンゾトリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、及びヒンダードアミン系紫外線吸収剤が挙げられる。酸化防止剤は、本発明の溶剤組成物に溶解するものであればいずれも使用することができ、フェノール系酸化防止剤、アミン系酸化防止剤、硫黄系酸化防止剤、及びリン系等酸化防止剤が挙げられる。 The solvent composition of the present invention can contain an ultraviolet absorber and an antioxidant in order to improve the stability of the cleaning liquid during long-term storage. Any ultraviolet absorber can be used as long as it is soluble in the solvent composition of the present invention, and examples thereof include benzotriazole ultraviolet absorbers, benzophenone ultraviolet absorbers, and hindered amine ultraviolet absorbers. Any antioxidant can be used as long as it is soluble in the solvent composition of the present invention, such as phenolic antioxidants, amine-based antioxidants, sulfur-based antioxidants, and phosphorus-based antioxidants. Agents.
本発明の溶剤組成物は、原料成分である（ａ）１，１，１，３，３−ペンタフルオロブタン、（ｂ）１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物、並びに場合により更に含まれる成分、例えば（ｃ）炭素水素系溶剤、（ｄ）添加剤、防錆剤、界面活性剤、及び紫外線吸収剤及び酸化防止剤を混合することにより製造することができる。 The solvent composition of the present invention comprises (a) 1,1,1,3,3-pentafluorobutane as raw material components, (b) one or more hydrofluoroether compounds represented by the general formula (1), and It may be produced by mixing optional components, for example, (c) a hydrocarbon solvent, (d) an additive, a rust inhibitor, a surfactant, and an ultraviolet absorber and an antioxidant.
本発明の溶剤組成物は、油が付着した被洗浄物を洗浄するための組成物として用いることができる。本発明において、洗浄とは、油が付着した被洗浄物から、油を除去することをいう。本発明において、油としては、常温、例えば２０℃において液体であり、水に溶解せず、粘性を感じるものであれば特に限定されないが、例えばフッ素オイル、鉱物油、及びシリコーンオイルが挙げられる。よって、本発明の溶剤組成物の用途として、例えば、油により汚染された被洗浄物用の洗浄剤、例えば切削油、プレス油、引抜き油、熱処理油、防錆油、及び潤滑油により汚染された被洗浄物用の洗浄剤が挙げられる。また本発明の溶剤組成物が、（ａ）成分及び（ｂ）成分からなる場合は、各種洗浄剤により洗浄された被洗浄物のためのリンス洗浄剤や仕上げ洗浄剤として使用することもできる。 The solvent composition of the present invention can be used as a composition for cleaning an object to be cleaned to which oil has adhered. In the present invention, “cleaning” refers to removing oil from an object to be cleaned to which oil has adhered. In the present invention, the oil is not particularly limited as long as it is liquid at normal temperature, for example, 20 ° C., does not dissolve in water, and feels viscous, and examples thereof include fluorine oil, mineral oil, and silicone oil. Therefore, as a use of the solvent composition of the present invention, for example, a cleaning agent for an object to be cleaned contaminated with oil, such as cutting oil, press oil, drawing oil, heat treatment oil, rust preventive oil, and lubricating oil, may be contaminated. And cleaning agents for the objects to be cleaned. Moreover, when the solvent composition of this invention consists of (a) component and (b) component, it can also be used as a rinse cleaning agent and a finishing cleaning agent for the to-be-cleaned object wash | cleaned with various cleaning agents.
本発明において、フッ素オイルとは、ポリアルキルエーテル化合物における水素原子の一部又は全部をフッ素で置換した物質であり、塩素及び臭素等のハロゲン、リン、硫黄、及び窒素などの更なる原子を含んでいてもよい。フッ素オイルは、常温で液状又はグリース状である。本発明において、フッ素オイルは、例えば一般式（４）：
ＣＦ3ＣＦ2ＣＦ2Ｏ−（ＣＦ（ＣＦ3）ＣＦ2Ｏ）ｘ−ＣＦ2ＣＦ3 （４）
（式中、ｘは、１以上の整数である）、
一般式（５）：
ＨＯＣＨ2ＣＦ2Ｏ−（ＣＦ2ＣＦ2Ｏ）p−（ＣＦ2Ｏ）q−ＣＦ2ＣＨ2ＯＨ （５）
（式中、ｐ及びｑは、互いに独立して、１以上の整数である）、
又は、一般式（６）：
Ｆ−（ＣＦ2ＣＦ2ＣＦ2Ｏ）ｙ−ＣＦ2ＣＦ2Ｏ−ＣＨ2ＯＨ （６）
（式中、ｙは、１以上の整数である）
で示される構造を有する。
In the present invention, the fluorine oil is a substance in which part or all of the hydrogen atoms in the polyalkyl ether compound are substituted with fluorine, and includes further atoms such as halogen such as chlorine and bromine, phosphorus, sulfur, and nitrogen. You may go out. Fluorine oil is liquid or grease-like at normal temperature. In the present invention, the fluorine oil is, for example, the general formula (4):
CF 3 CF 2 CF 2 O- ( CF (CF 3) CF 2 O) x -CF 2 CF 3 (4)
(Wherein x is an integer of 1 or more),
General formula (5):
HOCH 2 CF 2 O- (CF 2 CF 2 O) p - (CF 2 O) q -CF 2 CH 2 OH (5)
(Wherein p and q are each independently an integer of 1 or more),
Or, general formula (6):
F- (CF 2 CF 2 CF 2 O) y -CF 2 CF 2 O-CH 2 OH (6)
(Wherein y is an integer of 1 or more)
It has the structure shown by.
上記のフッ素オイルは、市販品として、例えばソルベイソレクシス社製のフォンブリン Ｙ−ＬＶＡＣ、Ｙ−ＨＶＡＣ、Ｙ０４、及びＹＲ；ＮＯＫクリューバー社製のバリエルタ（ＢＡＲＲＩＥＲＴＡ）Ｊ１００フルード、バリエルタＪ２５フルード、バリエルタＪ４００フルード、バリエルタＪ２５Ｖ、バリエルタＳＪ０７、バリエルタＳＪ１５、及びバリエルタＳＪ３０；デュポン株式会社製のクライトックス１５０６、クライトックス１５１４、及びクライトックス１５２５；ダイキン工業株式会社製のデムナムＳ−２０等が挙げられる。本発明の溶剤組成物は、フッ素オイルのなかで、一般式（４）及び（５）で示されるパーフルオロアルキルエーテルオイルに対して特に優れた洗浄効果を有する。 The above-mentioned fluoro oils are commercially available products such as Fomblin Y-LVAC, Y-HVAC, Y04, and YR manufactured by Solvay Solexis; BARRIRETA J100 fluid, Barrierta J25 fluid, Barrierta manufactured by NOK Kluber. Examples include J400 fluid, Barrierta J25V, Barrierta SJ07, Barrierta SJ15, and Barrierta SJ30; Krytox 1506, Krytox 1514, Krytox 1525 manufactured by DuPont, and Demnum S-20 manufactured by Daikin Industries, Ltd. The solvent composition of the present invention has a particularly excellent cleaning effect on perfluoroalkyl ether oils represented by the general formulas (4) and (5) among fluorine oils.
鉱物油とは、天然の石油由来の油分で、精製蒸留されて得られる液状及びグリース状の化学物質である。鉱物油に含まれる成分として、例えばパラフィン系炭化水素、イソパラフィン系炭化水素、ナフテン系炭化水素、芳香族系炭化水素、並びにパラフィン系炭化水素、イソパラフィン系炭化水素、ナフテン系炭化水素及び芳香族系炭化水素からなる群より選択される２以上の炭化水素の混合物が挙げられる。これら炭化水素の具体例は上記の炭化水素系溶剤の具体例として挙げられた炭化水素が挙げられる。このような鉱物油は、市販品として、出光興産株式会社製のアリソールエース、アイソールソフト、及びアイソール；ジャパンエナジー社製のニッコーホワイトＮ−１０；エクソン化学社製エクソンＤ−４０、及びエクソンナフサＮｏ−５等が挙げられる。本発明において、鉱物油が付着した被洗浄物を洗浄するための溶剤組成物として、（ｃ）成分を含まない溶剤組成物が好ましい。また、本発明の溶剤組成物は、鉱物油のなかで、パラフィン系炭化水素油及びナフテン系炭化水素系油の混合物に対して特に優れた洗浄効果を有する。 Mineral oil is an oil component derived from natural petroleum and is a liquid and grease-like chemical substance obtained by refining and distilling. Examples of components contained in mineral oil include paraffinic hydrocarbons, isoparaffinic hydrocarbons, naphthenic hydrocarbons, aromatic hydrocarbons, and paraffinic hydrocarbons, isoparaffinic hydrocarbons, naphthenic hydrocarbons, and aromatic hydrocarbons. And a mixture of two or more hydrocarbons selected from the group consisting of hydrogen. Specific examples of these hydrocarbons include the hydrocarbons listed as specific examples of the above hydrocarbon solvents. Such mineral oils are commercially available from Idemitsu Kosan Co., Ltd. Arisol Ace, Isole Soft, and Isole; Japan Energy Nikko White N-10; Exxon Chemical Exxon D-40, and Exon Naphtha No-5 etc. are mentioned. In the present invention, a solvent composition containing no component (c) is preferable as the solvent composition for cleaning the object to be cleaned to which mineral oil is adhered. The solvent composition of the present invention has a particularly excellent cleaning effect on a mixture of paraffinic hydrocarbon oil and naphthenic hydrocarbon oil among mineral oils.
本発明において、シリコーンオイルとは、シロキサン結合からなる直鎖状ポリマーであるシリコーンオイルであり、主にジメチルシリコーンオイルやメチルフェニルシリコーンオイルの側鎖又は末端に、カルボキシル基、アミノ基、又はエポキシ基などの他の有機基を導入したものであってもよい。このようなシリコーンオイルの具体例としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ポリオキシエチレン−メチルポリシロキサンなどが挙げられる。このようなシリコーンオイルとしては、市販品として、信越化学社製ＫＦ−９６Ｌ−２ＣＳが挙げられる。 In the present invention, the silicone oil is a silicone oil that is a linear polymer composed of a siloxane bond, and is mainly a carboxyl group, an amino group, or an epoxy group at the side chain or terminal of dimethyl silicone oil or methylphenyl silicone oil. Other organic groups may be introduced. Specific examples of such silicone oil include dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, polyoxyethylene-methylpolysiloxane, and the like. As such a silicone oil, Shin-Etsu Chemical Co., Ltd. KF-96L-2CS is mentioned as a commercial item.
本発明の溶剤組成物を用いて洗浄される被洗浄物は、油が付着した、すなわち油により汚染された各種部品が挙げられる。このような部品として、電気・電子部品、光学部品、自動車部品、及び機械部品等が挙げられる。なお、本発明の被洗浄物は、日常的なメンテナンス用、１日に１回〜２回洗浄される被洗浄物であるか、オーバーホール用、例えば６か月〜１年に１回洗浄される被洗浄物であってもよい。 Examples of objects to be cleaned using the solvent composition of the present invention include various parts to which oil is attached, that is, contaminated with oil. Examples of such parts include electric / electronic parts, optical parts, automobile parts, and machine parts. The object to be cleaned of the present invention is an object to be cleaned for daily maintenance or once or twice a day, or for overhaul, for example, 6 months to 1 year. It may be an object to be cleaned.
電気・電子部品としては、プリント配線基板、及びセラミック配線基板などの配線基板が挙げられる。
光学部品としては、カメラ用のレンズ及びカメラ筐体が挙げられる。
自動車部品としては、自動車用のシャフトやフレーム部品、外装部品等に用いられる金属製部品が挙げられる。
機械部品としては、真空ポンプ、半導体製造装置、洗浄装置、モーター、ファンなどの軸受、時計などの精密機械用部品などの軸受などの部品が挙げられる。
これらの部品は、金属製又は樹脂製であり、その形状は板状部材に限らず、断面円形状や矩形状のパイプ状部材や長尺部材であったり、その他、複雑な形状を有する部材であったりする。なお、本発明の溶剤組成物は、洗浄後の乾燥性に優れるため、プリント基板や各種樹脂製部品に付着した塵や埃もあわせて除去することができる。
Examples of the electric / electronic components include printed wiring boards and wiring boards such as ceramic wiring boards.
Examples of the optical component include a camera lens and a camera housing.
Examples of the automobile parts include metal parts used for automobile shafts, frame parts, exterior parts, and the like.
Examples of the mechanical parts include parts such as vacuum pumps, semiconductor manufacturing apparatuses, cleaning apparatuses, bearings such as motors and fans, and bearings such as precision machine parts such as watches.
These parts are made of metal or resin, and the shape thereof is not limited to a plate-like member, but is a pipe-like member or a long member having a circular cross section or a rectangular shape, or other members having a complicated shape. There is. In addition, since the solvent composition of this invention is excellent in the drying property after washing | cleaning, it can also remove dust and dust adhering to a printed circuit board and various resin components.
本発明において、被洗浄物を洗浄する方法は、本発明の溶剤組成物を、油が付着した被洗浄物と接触させる工程を含む。本発明の溶剤組成物と、油が付着した被洗浄物とを接触させるための方法としては、特に制限はなく、溶剤組成物への前記被洗浄物の浸漬、溶剤組成物を含浸したスポンジによる前記被洗浄物の拭き取り、及び前記被洗浄物に対する溶剤組成物のスプレー等が好ましく、浸漬による方法がより好ましい。浸漬による方法において、洗浄効果を高めるために、浸漬と同時に、攪拌、揺動、超音波振動、又はエアバブリング等による手段を組み合わせることが好ましく、超音波振動による手段を組み合わせることがより好ましい。超音波振動は、発振周波数が２０〜１００ｋＨｚであり、発振出力が１０〜５００Ｗであるのが好ましい。エアバブリングでは、微細な気泡を、ガス及び溶剤組成物の体積比が１：１〜５：１となるように通気することが好ましい。 In the present invention, the method for cleaning an object to be cleaned includes a step of bringing the solvent composition of the present invention into contact with the object to be cleaned to which oil has adhered. The method for bringing the solvent composition of the present invention into contact with the object to be cleaned is not particularly limited, and it is immersed in the object to be cleaned in the solvent composition, using a sponge impregnated with the solvent composition. Wiping of the object to be cleaned and spraying of the solvent composition to the object to be cleaned are preferable, and a method by immersion is more preferable. In the immersion method, in order to enhance the cleaning effect, it is preferable to combine means by stirring, shaking, ultrasonic vibration, air bubbling or the like at the same time as immersion, and more preferable to combine means by ultrasonic vibration. The ultrasonic vibration preferably has an oscillation frequency of 20 to 100 kHz and an oscillation output of 10 to 500 W. In air bubbling, it is preferable to vent fine bubbles so that the volume ratio of the gas and the solvent composition is 1: 1 to 5: 1.
本発明において、溶剤組成物及び被洗浄物の接触時間に相当する洗浄時間は、被洗浄物に付着した油を洗浄除去できる時間であれば特に制限されない。例えば、超音波振動を組み合わせた浸漬による方法における、油が付着した被洗浄物を洗浄するための洗浄時間は、好ましくは５秒間〜５分間、特に好ましくは１０秒間〜１分間であり、浸漬による方法における、油が付着した被洗浄物を洗浄するための洗浄時間は、好ましくは１０分〜５時間、特に好ましくは３０分〜２時間である。上記洗浄時間未満である場合は洗浄が不十分で、付着した油を被洗浄物から十分に除去できない場合があり、一方、上記洗浄時間を超えた場合は、洗浄効果が格別向上しない。 In the present invention, the cleaning time corresponding to the contact time between the solvent composition and the object to be cleaned is not particularly limited as long as the oil adhering to the object to be cleaned can be cleaned and removed. For example, in the method using immersion combined with ultrasonic vibration, the cleaning time for cleaning the object to which the oil adheres is preferably 5 seconds to 5 minutes, particularly preferably 10 seconds to 1 minute. In the method, the washing time for washing the object to which the oil adheres is preferably 10 minutes to 5 hours, particularly preferably 30 minutes to 2 hours. When the cleaning time is shorter than the above cleaning time, the cleaning may be insufficient and the adhered oil may not be sufficiently removed from the object to be cleaned. On the other hand, when the cleaning time is exceeded, the cleaning effect is not particularly improved.
本発明において洗浄温度は、好ましくは２０〜１２０℃である。このような温度において、より高温で処理することにより洗浄効果を上昇させることができる。 In the present invention, the washing temperature is preferably 20 to 120 ° C. At such a temperature, the cleaning effect can be increased by processing at a higher temperature.
以下、本発明を実施例及び比較例により更に詳細に説明するが、本発明はこれら実施例により限定されるものではない。 EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention further in detail, this invention is not limited by these Examples.
実施例１〜６及び比較例１〜５の溶剤組成物を、表１で示される組成で各成分を混合することにより調製した。 The solvent compositions of Examples 1 to 6 and Comparative Examples 1 to 5 were prepared by mixing each component with the composition shown in Table 1.
試験例１ フッ素オイル
（１−１）フッ素オイルの溶解
フッ素オイルとして、ＮＯＫ製バリエルタＪ１００フルード（ＢＡＲＲＩＥＲＴＡ Ｊ１００ ＦＬＵＩＤ、（フッ素オイル(1)））及びソルベイソレクシス社製フォンブリン Ｙ−ＬＶＡＣ（フッ素オイル(2)）を用いた。試験管に、実施例１〜６及び比較例１〜４の各溶剤組成物５ｇを入れた。そこにフッ素オイル１ｇを添加し、充分に撹拌した後、１時間静置させた。静置後、混合液の濁り、分離の発生の有無を目視により判定した。試験例１の結果を表２に示す。
Test Example 1 Dissolution of Fluorine Oil (1-1) Fluorine Oil As fluorinated oil, NOK Varielta J100 Fluid (BARRIERTA J100 FLUID, (Fluorine Oil (1))) and Solvay Solexis Fomblin Y-LVAC (Fluorine Oil) (2)) was used. 5 g of each solvent composition of Examples 1 to 6 and Comparative Examples 1 to 4 was put in a test tube. 1 g of fluorinated oil was added thereto, and after sufficiently stirring, the mixture was allowed to stand for 1 hour. After standing, the presence or absence of turbidity and separation of the liquid mixture was visually determined. The results of Test Example 1 are shown in Table 2.
試験例２ 鉱物油
（２−１）鉱物油を塗布したステンレス板の作成
鉱物油として、出光興産社製アイソールエースを用いた。この鉱物油を、４ｃｍ×４ｃｍ角、厚さ０．４ｍｍのステンレス板に０．１ｇを滴下し、刷毛を用いて全体に塗布し、鉱物油が付着したステンレス板を得た。アイソールエースは、ナフテン系炭化水素及びパラフィン系炭化水素油の混合物を主成分とするものである。
（２−２）被洗浄物の洗浄及び乾燥
被洗浄物の洗浄のため、２００ｍｌのビーカーに、実施例１〜６及び比較例１〜４の各溶剤組成物１５０ｇを入れた。鉱物油が付着したステンレス板を、実施例１〜６及び比較例１〜４の溶剤組成物に浸漬させて、超音波洗浄機（発信周波数３８ｋＨｚ、出力３６０Ｗ）にて、１分間洗浄を行った。洗浄後、ステンレス板を取り出して、室温にて１０分間放置し、ステンレス板状上の鉱物油の液残留を目視により判定した。結果を表３に示す。
(2-2) 150 g of the solvent compositions of Examples 1 to 6 and Comparative Examples 1 to 4 were placed in a 200 ml beaker for cleaning of the object to be cleaned and cleaning of the object to be dried. The stainless steel plate to which the mineral oil was adhered was immersed in the solvent compositions of Examples 1 to 6 and Comparative Examples 1 to 4, and washed for 1 minute with an ultrasonic cleaner (transmitting frequency 38 kHz, output 360 W). . After washing, the stainless steel plate was taken out and allowed to stand at room temperature for 10 minutes, and the residual liquid of mineral oil on the stainless steel plate was visually judged. The results are shown in Table 3.
本発明の溶剤組成物は、１，１，１，３，３−ペンタフルオロブタン並びに１種以上の一般式（１）で示されるハイドロフルオロエーテル化合物を主成分として含有するため、塩素系溶剤と比較して毒性が少ない。また、本発明の洗浄用溶剤組成物は、フッ素オイル及び鉱物油をはじめとする様々な種類の油に対して優れた溶解力を発揮し、油が付着した被洗浄物に対して良好な洗浄効果を有する。よって、本発明の溶剤組成物は、油の洗浄剤として工業的に極めて有用である。 Since the solvent composition of the present invention contains 1,1,1,3,3-pentafluorobutane and one or more hydrofluoroether compounds represented by general formula (1) as main components, Less toxic compared. In addition, the cleaning solvent composition of the present invention exhibits excellent dissolving power for various kinds of oils including fluorine oil and mineral oil, and is excellent for cleaning the object to be cleaned. Has an effect. Therefore, the solvent composition of the present invention is industrially extremely useful as an oil cleaning agent.
Claims (2)
（ｂ）１種以上の、一般式（１）：
Ｒ１−Ｏ−Ｒ２ （１）
（式中、
Ｒ１は、少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基であり、
Ｒ２は、炭素原子数１〜４のアルキル基、又は少なくとも１つのフッ素原子で置換された炭素原子数３〜６のアルキル基である）
で示される、ハイドロフルオロエーテル化合物を４０〜４５０重量部含むことを特徴とする、油が付着した被洗浄物を洗浄するための溶剤組成物。 (A) For 100 parts by weight of 1,1,1,3,3-pentafluorobutane,
(B) one or more general formulas (1):
R 1 —O—R 2 (1)
(Where
R 1 is an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom,
R 2 is an alkyl group having 1 to 4 carbon atoms, or an alkyl group having 3 to 6 carbon atoms substituted with at least one fluorine atom)
The solvent composition for washing | cleaning the to-be-washed | cleaned material to which oil adhere | attached characterized by including 40-450 weight part of hydrofluoroether compounds shown by these.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010271709A JP5723583B2 (en) | 2010-12-06 | 2010-12-06 | Cleaning solvent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010271709A JP5723583B2 (en) | 2010-12-06 | 2010-12-06 | Cleaning solvent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012121948A true JP2012121948A (en) | 2012-06-28 |
| JP5723583B2 JP5723583B2 (en) | 2015-05-27 |
Family
ID=46503742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010271709A Active JP5723583B2 (en) | 2010-12-06 | 2010-12-06 | Cleaning solvent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5723583B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014091785A (en) * | 2012-11-02 | 2014-05-19 | Kaneko Kagaku:Kk | Solvent composition for cleaning |
| JP6118450B1 (en) * | 2016-11-10 | 2017-04-19 | 株式会社カネコ化学 | Cleaning composition |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002532237A (en) * | 1998-12-12 | 2002-10-02 | ソルヴェイ | Composition containing 1,1,1,3,3-pentafluorobutane and use of the composition |
| JP2003518144A (en) * | 1999-03-22 | 2003-06-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Azeotropic-like composition of 1,1,1,3,3-pentafluorobutane |
| JP2005075977A (en) * | 2003-09-02 | 2005-03-24 | Toagosei Co Ltd | Detergent for removing stain of fabric |
| JP2006231173A (en) * | 2005-02-23 | 2006-09-07 | Asahi Kasei Chemicals Corp | Method and apparatus for adjusting detergent composition, and washing apparatus |
| WO2010043796A1 (en) * | 2008-10-15 | 2010-04-22 | Arkema France | Cleaning composition |
| JP2011031144A (en) * | 2009-07-30 | 2011-02-17 | Asahi Kasei Chemicals Corp | Washing method having no rinsing process and washing device |
| JP2011116909A (en) * | 2009-12-07 | 2011-06-16 | Asahi Kasei Chemicals Corp | Stain separation-removing method |
| JP5627126B2 (en) * | 2009-04-30 | 2014-11-19 | 旭化成ケミカルズ株式会社 | Draining agent, draining method and draining device |
-
2010
- 2010-12-06 JP JP2010271709A patent/JP5723583B2/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002532237A (en) * | 1998-12-12 | 2002-10-02 | ソルヴェイ | Composition containing 1,1,1,3,3-pentafluorobutane and use of the composition |
| JP2003518144A (en) * | 1999-03-22 | 2003-06-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Azeotropic-like composition of 1,1,1,3,3-pentafluorobutane |
| JP2006152307A (en) * | 1999-03-22 | 2006-06-15 | E I Du Pont De Nemours & Co | Azeotropic composition of 1,1,1,3,3-pentafluorobutane |
| JP2006169539A (en) * | 1999-03-22 | 2006-06-29 | E I Du Pont De Nemours & Co | Azeotrope-like composition of 1,1,1,3,3-pentafluorobutane |
| JP2006183054A (en) * | 1999-03-22 | 2006-07-13 | E I Du Pont De Nemours & Co | Azeotrope-like composition of 1,1,1,3,3-pentafluorobutane |
| JP2005075977A (en) * | 2003-09-02 | 2005-03-24 | Toagosei Co Ltd | Detergent for removing stain of fabric |
| JP2006231173A (en) * | 2005-02-23 | 2006-09-07 | Asahi Kasei Chemicals Corp | Method and apparatus for adjusting detergent composition, and washing apparatus |
| WO2010043796A1 (en) * | 2008-10-15 | 2010-04-22 | Arkema France | Cleaning composition |
| JP5627126B2 (en) * | 2009-04-30 | 2014-11-19 | 旭化成ケミカルズ株式会社 | Draining agent, draining method and draining device |
| JP2011031144A (en) * | 2009-07-30 | 2011-02-17 | Asahi Kasei Chemicals Corp | Washing method having no rinsing process and washing device |
| JP2011116909A (en) * | 2009-12-07 | 2011-06-16 | Asahi Kasei Chemicals Corp | Stain separation-removing method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014091785A (en) * | 2012-11-02 | 2014-05-19 | Kaneko Kagaku:Kk | Solvent composition for cleaning |
| JP6118450B1 (en) * | 2016-11-10 | 2017-04-19 | 株式会社カネコ化学 | Cleaning composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5723583B2 (en) | 2015-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6969385B2 (en) | Solvent composition, draining drying method and flux cleaning method | |
| JP6264510B2 (en) | Solvent composition, cleaning method, coating film forming method, heat transfer medium and thermal cycle system | |
| CN102177231B (en) | Cleaning composition | |
| JP5914296B2 (en) | Cleaning solvent composition | |
| WO1994026864A1 (en) | Cleaning agent, cleaning method and cleaning apparatus | |
| JP4761293B2 (en) | Cleaning composition and cleaning method | |
| JP7417144B2 (en) | Composition | |
| JP2022008478A (en) | Fluorinated surfactant-containing compositions | |
| CN108699495B (en) | Solvent composition, cleaning method, composition for forming coating film, and method for forming coating film | |
| JP7372553B2 (en) | Solvent compositions, solutions, methods for cleaning articles, and methods for forming coatings | |
| JP5723583B2 (en) | Cleaning solvent composition | |
| WO2015174487A1 (en) | Cleaning system and cleaning method using non-azeotropic cleaning agent composition | |
| JP2016088963A (en) | Fluorine-containing olefin composition and cleaning method using the same | |
| JP2017043680A (en) | Solvent composition for cleaning | |
| CN114846129B (en) | Solvent composition and use thereof | |
| JPH0457897A (en) | Detergent composition | |
| JP2007002175A (en) | Method for processing/cleaning metal parts and oil for processing/cleaning for us in the same | |
| EP0805199B1 (en) | Solvents utilizable as cleaning agents | |
| JPWO2008081804A1 (en) | Cleaning agent and cleaning method containing fluorinated cyclic unsaturated hydrocarbon | |
| JP6098473B2 (en) | Carbonate detergent | |
| JP2022058307A (en) | Solvent composition for cleaning | |
| JP2009149701A (en) | Azeotropic mixture composition, azeotropic mixture-like composition, cleaning solvent and coating solvent | |
| EP0864643A1 (en) | Compositions to remove oily substances from substrates amd their use | |
| JP2002012894A (en) | Low ignitable cleanser, method for cleansing and device for cleansing | |
| JP2012121947A (en) | Solvent composition for cleaning |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131204 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140717 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140722 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140917 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150324 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150330 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5723583 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |