JP2012102878A - Thin shock absorbing material and thin shock absorbing laminated body - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a thin shock absorbing material and a thin shock absorbing laminated body having superior shock absorbing performance even if its thickness is insufficient.SOLUTION: The thin shock absorbing material formed by blending a filler (B) in a silicone gel (A) has a thickness of 0.5 to 2.0 mm, wherein the filler (B) includes 1-3.5 pts.wt. of minute hollow body (b1) with an outer shell of a synthetic resin and 10-30 pts.wt. of silica (b2) for 100 pts.wt. of the silicone gel (A), the thin shock absorbing material has an Asker C hardness of 15-60, and the silicone gel (A) has an Asker C hardness of 5-55.

Description

  The present invention relates to a thin shock-absorbing material and a thin shock-absorbing laminate, and more specifically, for example, it is sufficient for a portable device such as a notebook computer, a mobile phone, a portable music information device, a portable game machine, etc. The present invention relates to a thin impact buffer material and a thin impact buffer laminate that can exhibit buffer performance.

In recent years, personal computers have rapidly spread, and at present, the use of portable notebook computers and the like while carrying them is increasing. In addition, portable music information devices, portable devices equipped with camera modules, information devices such as cellular phones, and portable game machines are also increasing in use and are rapidly becoming smaller and thinner. Further, along with the progress of miniaturization technology of the hard disk drive device which is a magnetic recording device, commercialization of a product equipped with the hard disk drive device as a data storage component of the portable device is progressing.
A problem that arises when carrying information devices such as the above-mentioned notebook computers is damage due to drop impact. This is because the mobile device is accidentally dropped by the user, for example, when it is accidentally dropped during transportation, the main body is dropped during operation, or any other unexpected external force is applied. Is used in an environment where there is a high possibility of damage. In addition, when downsizing such portable devices, the mechanical components are mounted with high density in a narrow housing, so that mechanical components can be damaged if an impact due to a drop collision or the like acts on the housing. There is sex. Besides that, there are many opportunities to receive external impacts as you carry them.
Furthermore, since the convenience of carrying increases with the miniaturization, the frequency of being affected by the damage factor increases in the use environment, and a design for ensuring the durability of the product is required. In particular, in a hard disk device as a data storage and an optical system part such as a camera module, precise positioning accuracy is required.
In other words, when the portable device is miniaturized, the two viewpoints are considered: (i) it is vulnerable to impact due to precision, and (ii) the cushioning material becomes thinner because of its thinness, and the cushioning performance is further reduced. Design is important, and the lack of either one tends to be inadequate as a product. In particular, a drop in impact buffering performance when dropped is a significant problem.

  In view of the conventional products from the above-described two viewpoints, as the size is reduced, it becomes difficult to secure a space for providing a shock absorbing material that absorbs an impact, and the thickness of the shock absorbing material must be reduced. However, if the thickness is reduced, sufficient shock-absorbing performance that can protect the internal mounting parts cannot be obtained by simply using a cushioning material made of rubber or gel, as in the case of a mobile phone device as a conventional portable device. .

For this reason, various proposals have been made regarding a cushioning material for a portable device or a system of a device including the cushioning material (see, for example, Patent Documents 1 to 3).
Patent Document 1 discloses a piezoelectric transformer inverter with a shock absorbing measure that can be used for a small inverter used in a portable information device, and the piezoelectric transformer and the piezoelectric transformer are electrically joined. The method used here uses a cushioning material so as to straddle the piezoelectric transformer and the inverter board with the junction between the piezoelectric transformer and the inverter board interposed therebetween. In addition, the buffering method is merely a buffering method based on an arrangement configuration of a buffering material in which a liquid silicone material is changed into a gel or rubber shape at room temperature or a curing agent as a buffering material.
Patent Document 2 discloses a method for providing a portable device that can easily prevent damage due to a drop impact or the like with a simple configuration without increasing the thickness of a buffer material, and that can cope with downsizing. A first camera module unit; a second camera module unit that forms a camera module in combination with the first camera module unit; a housing that houses the first and second camera module units; and the first camera A first buffer material that connects either the module unit or the second camera module unit and the housing; and a second buffer material that connects the first camera module unit and the second camera module unit. It is only a buffer structure by combining two types of buffer materials provided.
Furthermore, Patent Document 3 discloses a housing structure using a gas buffer material inside a portable information processing apparatus including a mobile terminal, but this is only an impact buffering structure based on gas compression elasticity.

Conventionally, various buffer materials have been proposed (see, for example, Patent Documents 4 to 6).
In patent document 4, it consists of the core which consists of silicone gel, and the silicone rubber which coat | covers this core, and either one of this silicone gel and silicone rubber is a phenyl group modified organosiloxane component unit and / or fluoro. A silicone-based cushioning material is disclosed, which contains a modified organopolysiloxane having an alkyl group-modified organosiloxane component unit, and the other contains an unmodified organopolysiloxane.
Further, in Patent Document 5, a silicone gel having a penetration of about 50 to 200 by JIS K2530-1976-50 g load is used as a base material, and 1 to 4% by weight of a large number of minute hollow spheres are mixed therein. A cushioning material is disclosed in which the hollow sphere has a shell made of an elastic synthetic resin capable of self-elastic deformation.
Further, Patent Document 6 discloses an impact absorbing material obtained by mixing 5 to 50 parts of micro hollow beads having a particle size of 200 μm or less with a fracture strength of 200 kg / cm ² or less into silicone rubber.

As described above, as a cushioning material for portable devices, for example, when it is dropped, it has an excellent impact cushioning performance even if it is thin, and strongly holds an important internal article with only the cushioning material in a closed space. Although there is a demand, conventionally proposed cushioning materials and cushioning materials for portable devices are not thought of downsizing and thinness of products, and are applied to spaces with limited thickness. It does not consider the viewpoint. This will be described in detail with reference to Patent Document 5 (taken up in Examples / Comparative Examples described later). The buffer material described in Patent Document 5 has a buffer excellent in shock buffering performance as compared with a solid silicone material. Although it is recognized as a material, it has been found that even with this cushioning material, when it becomes thinner than a specific thickness, the impact cushioning performance deteriorates as compared with the solid silicone material. In other words, in a space where the thickness and size are secured, even if the cushioning material has an impact cushioning performance several times that of solid silicone material, the performance will be sufficient in a specific thin area. I can't show it.
Therefore, a new cushioning material having sufficient shock cushioning performance under specific conditions such as thinness and small size is desired.

JP 2006-179545 A JP 2006-146076 A JP 2006-140236 A Japanese Patent Publication No. 07-119091 Japanese Examined Patent Publication No. 06-025304 JP 09-157434 A

  In view of the above problems, an object of the present invention is to provide a thin impact cushioning material and a thin impact cushion laminate having excellent impact cushioning performance even when the thickness is small.

  As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the shock absorbing material using conventional silicone gel and silicone rubber has not been able to obtain excellent shock absorbing performance when the thickness is reduced. It has been surprisingly found that when a specific amount of specific hollow spheres and silica are mixed in the silicone gel, a material that exhibits a remarkable impact buffering performance can be obtained even when the thickness is small. The present invention has been completed based on these findings.

That is, according to 1st invention of this invention, it is a thin impact shock absorbing material with a thickness of 0.5-2.0 mm formed by mix | blending a filler (B) with silicone gel (A), Comprising: B) is a fine hollow body (b1) having an outer shell of 1 to 3.5 parts by weight of synthetic resin and 10 to 30 parts by weight of silica (b2) with respect to 100 parts by weight of the silicone gel (A). The thin impact cushioning material has an Asker C hardness of 15-60, and the silicone gel (A) has an Asker C hardness of 5-55.
According to a second invention of the present invention, in the first invention, the thin impact cushioning material is characterized in that the impact cushioning efficiency in the weight drop test is 70% or more. Provided.
Further, according to a third invention of the present invention, in the first or second invention, the synthetic resin is a vinylidene chloride resin, a copolymer of vinylidene chloride and acrylonitrile, a copolymer of acrylonitrile and methacrylonitrile. A thin impact buffering material is provided, which is at least one selected from the group consisting of terpolymers of vinylidene chloride, acrylonitrile and divinylbenzene.

According to a fourth invention of the present invention, in any one of the first to third inventions, the micro hollow body (b1) having the outer shell of the synthetic resin is a micro sphere containing a thermally expandable substance therein. A thin shock-absorbing material characterized by being thermally expanded is provided.
According to a fifth invention of the present invention, in any one of the first to fourth inventions, at least a part of the surface of the thin impact buffer material is further mixed with the same or different from the thin impact buffer material. A thin shock-absorbing material characterized in that convex protrusions made of a blended material are formed.
Furthermore, according to the sixth aspect of the present invention, at least a part of the surface of the thin shock absorbing material according to any one of the first to fifth aspects, further comprising a single layer or multiple layers, smooth or uneven processing A thin shock-absorbing laminate is provided, which is formed by laminating the prepared resin base materials.

The thin impact buffer material of the present invention has excellent impact buffering performance even when the thickness is small by mixing a specific amount of a specific hollow sphere and silica in a specific silicone gel. In addition, since it is a shock absorbing material of a shock absorbing mechanism that shocks while accompanying volume change, like a shock absorbing material that depends on deformation and softness with volume change, such as rubber or gel buffer material, A space for deformation at the time of shock buffering is not essential, and there is an effect that the installation space for the buffer material can be reduced.
As a result, the thin impact cushioning material of the present invention can be suitably used for portable devices such as notebook computers, mobile phones, portable music information devices, portable game machines, and the like. The flame retardancy required for parts has also been improved, which can contribute to the development of design technology that simultaneously reduces the size of electric and electronic products and provides shock-absorbing properties.

It is a block diagram of the evaluation apparatus of the impact absorption characteristic of the thin impact buffer material of this invention. It is the figure which compared the change of the impact absorption characteristic with respect to the thickness when the impact force of 187N is applied to the thin impact buffer material of this invention with the conventional product (Comparative example 1 and Comparative example 2). It is a figure which shows the evaluation result of the shock absorption characteristic of the thin impact buffer material of this invention. It is a figure which shows the evaluation result of the shock absorption characteristic of the thin impact buffer material of this invention. It is a figure which shows the example (a)-(i) of the shape of the thin impact buffer material of this invention. It is a figure which shows the lamination examples (a)-(f) of the thin impact buffer laminated body of this invention.

Below, the component of the thin impact buffer material of this invention, etc. are demonstrated in detail.
The thin impact cushioning material of the present invention is a thin impact cushioning material having a thickness of 0.5 to 2.0 mm obtained by blending the filler (B) with the silicone gel (A), and the filler (B) It is a thin hollow body (b1) having an outer shell of 1 to 3.5 parts by weight of synthetic resin and 10 to 30 parts by weight of silica (b2) with respect to 100 parts by weight of silicone gel (A), and is thin The shock absorbing material has an Asker C hardness of 15 to 60, and the silicone gel (A) has an Asker C hardness of 5 to 55. Here, the Asker C hardness is a value obtained according to SRIS 0101 (Japan Rubber Association Standard).

The thickness of the thin shock-absorbing material of the present invention is, for example, 2 mm or less in order to be used in a narrow space in a portable information device and exhibit the effect of downsizing, and more specifically, 0.5 mm to 2 mm. In particular, it is 0.5 mm to 1.5 mm.
And as a remarkable effect of this invention, the micro hollow body (b1) which has an outer shell of 1-3.5 weight part synthetic resin with respect to 100 weight part of silicone gel (A) and silicone gel (A). And 10 to 30 parts by weight of silica (b2), and by adjusting the hardness of the thin impact buffer material to an Asker C hardness of 15 to 60 according to the target impact force, 0.5 mm to In the entire range of 2 mm, the shock buffering efficiency in the weight drop test exhibits an excellent performance of 70% or more.
The shock buffering efficiency here is a standard of shock buffering capacity obtained from a weight drop test described later in the examples, and the larger the value, the higher the shock buffering performance and the better the shock buffering material.
Moreover, the hardness of the thin impact buffer material of the present invention exhibits remarkable impact buffering properties when the Asker C hardness is in the range of 15-60. When the Asker C hardness of the thin impact buffer material is less than 15, when the impact is applied due to being too soft, the thin impact buffer material is significantly deformed in the thickness direction and becomes a so-called bottomed state. The effect is significantly reduced. On the other hand, if the Asker C hardness exceeds 60, the thin impact buffering material becomes hard and the bottoming is eliminated, but the repulsive force when an impact is applied increases, and the impact buffering effect decreases.

1. Silicone gel (A)
In the thin impact cushioning material of the present invention, the silicone gel (A) used as the base material has an Asker C hardness of 5 to 55.
When the Asker C hardness of the silicone gel (A) is less than 5, when the resulting thin impact cushioning material is too soft and an impact is applied, the thin impact cushioning material is remarkably in the thickness direction (impact application direction). It is deformed and becomes a so-called bottomed state, and the shock absorbing effect is remarkably reduced. On the other hand, if the Asker C hardness of the silicone gel (A) exceeds 55, the resulting thin impact cushioning material for a portable information device is hardened so that the bottoming is eliminated. The repulsive force from the shock absorbing material is increased, and the shock absorbing effect is reduced.

  As said silicone gel, what is generally used as various silicone materials known conventionally and marketed can be selected suitably, and can be used. Accordingly, any of a heat curable type, a room temperature curable type, a UV curable type, a condensation type or an addition type, etc. can be used. In addition, the group bonded to the silicon atom is not particularly limited, and examples thereof include alkyl groups such as methyl group, ethyl group, and propyl group, cycloalkyl groups such as cyclopentyl group and cyclohexyl group, vinyl groups, and allyl groups. In addition to aryl groups such as alkenyl groups, phenyl groups, and tolyl groups, those in which the hydrogen atoms of these groups are partially substituted with other atoms or linking groups can be mentioned.

2. Filler (B)
In the thin impact buffer material of the present invention, a filler (B) as a filler is blended with the silicone gel (A) used as a base material, and the filler (B) is an elastic synthetic resin capable of self-elastic deformation. These are a substantially spherical micro hollow body (b1) (hereinafter also referred to as a balloon) and silica (b2).

(1) Micro hollow body (b1)
The buffer property of the silicone gel material is improved by blending the silicone gel (A) with a fine hollow body (b1) having a synthetic resin outer shell as the filler (B). Usually, a micro hollow sphere is generally called a microsphere, a micro balloon, a hollow bubble, a syntactic foam material, and a balloon is a name given to a fine hollow sphere usually interposed between 5 μm and 300 μm, There are inorganic and organic types such as glass balloons, but in the present invention, it is an essential requirement to cause a volume change in the shock absorbing material at the time of applying an impact. Use.

  The micro hollow body (b1) used in the present invention has a synthetic resin, for example, a thermoplastic resin as a shell. Examples of the resin include polystyrene, polyvinyl chloride, polyvinylidene chloride, polyvinyl acetate, Examples thereof include acrylic acid esters, polyacrylonitrile, polybutadiene, and copolymer resins thereof. In particular, from the viewpoint of impact buffering by co-operation of the viscoelasticity of the silicone gel (A) and the elastic force of the micro hollow body (b1), a vinylidene chloride resin, a copolymer of vinylidene chloride and acrylonitrile, acrylonitrile and methacrylic acid. A copolymer of nitrile, a terpolymer of vinylidene chloride, acrylonitrile and divinylbenzene, a copolymer resin mainly composed of styrene and acrylic, etc. are preferred, and a copolymer resin of vinylidene chloride and acrylonitrile is more preferred. preferable. These can be used alone or in admixture of two or more. Moreover, what is necessary is just to select the said synthetic resin suitably what has very little hardening inhibitory property with respect to a silicone gel (A).

Moreover, the micro hollow body (b1) used in the present invention contains, for example, a thermoplastic resin as a shell and contains air or other gas inside, and has already been expanded by heat or heat. It is a fine hollow particle. In the present invention, a type that has already been expanded is used because it does not deteriorate its physical properties due to thermal expansion. For example, what expand | swells with heat | fever is what expand | expands at 80-150 degreeC, a diameter becomes 4 times or more, and a volume becomes about 50-100 times or more. The average particle diameter is preferably 1 to 250 μm, more preferably 30 to 150 μm, and the density (true density) is preferably 20 to 50 kg / m ³ .
In addition, low molecular compounds such as low-boiling hydrocarbons other than air, foaming agents, and the like may be present inside the shell wall of the micro hollow body.

As a specific synthetic resin micro hollow sphere, “Expancel (registered trademark) 551DE” manufactured by Nippon Philite Co., Ltd., which is a micro hollow body made of a copolymer of vinylidene chloride and acrylonitrile, for example, “Expancel (registered) (Trademark) 551DE40d42 "(average particle size is 30 to 50 (40) μm, density is 42 kg / m ³ ) or" Expancel (registered trademark) 092DE120d30 "(average particle size is 100 to 140 (manufactured by Nippon Philite). 120) μm, density is 30 kg / m ³ ), “Matsumoto Microsphere (registered trademark)” manufactured by Matsumoto Yushi Seiyaku Co., Ltd., and the like. Moreover, "SARAN MICROSPHERES" provided by DOW CHEMICAL can be used as the polyvinylidene chloride resin balloon.

  Furthermore, “Matsumoto Microsphere (registered trademark) MFL series” provided by Matsumoto Yushi Seiyaku Co., Ltd. as a balloon whose surface is coated with inorganic powders such as calcium carbonate, talc and titanium oxide, and “ "EMC" can also be used.

(2) Silica (b2)
In the thin impact buffer material of the present invention, the silica (b2) used as the filler (B) maintains the viscoelasticity peculiar to the gel at a suitable hardness of the thin impact buffer material, and the impact resistance of the thin impact buffer material. It is considered that it has an effect of imparting strength, and exhibits the excellent shock buffering property of the shock absorbing material in cooperation with the silicone material (A) and the fine hollow body (b1).

Examples of the silica (b2) used in the present invention include wet method silica, dry method silica, and synthetic silicate-based silica. This silica is obtained by pulverizing natural quartz as a raw material, heat treated after pulverization, hydrolyzed silicon tetrachloride as a raw material, or synthesized by oxidizing metal silicon. there may be mentioned, for preparation, but the present invention is not particularly limited as long as it contains 50% or more of silicon oxide (SiO ₂₎ at a volume ratio.

Silica is not particularly limited in terms of particle size, surface area, etc., but it is silica with a small particle size that has a high impact buffering effect. Those having good dispersibility in the silicone gel are preferable in terms of physical properties and processability. The average particle diameter of silica is a primary particle diameter, preferably 10 μm or less, more preferably 0.01 to 10 μm, and still more preferably 0.1 to 5 μm. Further, a specific surface area (BET method) is preferably ^{10 m} 2 / g or more, more preferably 45~280m ² / g.

  Furthermore, as the silica (b2), the surface of the silica can be treated with a silane compound such as dimethyldichlorosilane or hexamethyldisilazane, an epoxy-based silane coupling agent, or the like. By performing these surface treatments, dispersion into silicone is facilitated, which is preferable.

The blending amount of the filler (B) is 1 to 3.5 parts by weight with respect to 100 parts by weight of the silicone gel (A), and preferably 1 to 3.5 parts by weight for the fine hollow body (b1) having a synthetic resin outer shell. 0.5-3 parts by weight, particularly preferably 2.0-3.0 parts by weight. Moreover, about silica (b2), it is 10-30 weight part, Preferably it is 15-25 weight part, Especially preferably, it is 18-22 weight part.
When the blending amount of the micro hollow body (b1) is less than 1 part by weight, a sufficient impact buffering effect cannot be obtained. On the other hand, when the blending amount exceeds 3.5 parts by weight, the uncured silicone material (A ), The viscosity becomes remarkably high and sheet molding becomes difficult, and the resulting cushioning material becomes brittle, so that the tendency to become unusable becomes remarkable. In general, as the amount of the filler added increases, the hardness of the shock absorbing material increases (hardens), but in the particularly preferable range of 2.0 to 3.0 parts by weight, the hardness of the shock absorbing material is increased. Since the change is extremely small, the shock absorbing performance can be easily adjusted by the addition amount of the fine hollow filler.
Further, if the amount of silica (b2) is less than 10 parts by weight, the reinforcing effect of the silicone material (A) is small, and the improvement in impact strength is poor. descend. On the other hand, if the blending amount exceeds 30 parts by weight, the repulsive force when an impact is applied to the resulting thin shock absorbing material is increased, and the shock absorbing effect is reduced.
In addition, when the thickness of the shock absorbing material is 1 mm or less, the shock absorbing material is easily deformed with a small stress in 2.0 to 3.0 parts by weight of the fine hollow filler (b1) which is a particularly preferable blending amount. Therefore, it is easy to obtain high shock buffering properties, so that the shock buffering material that can prevent the bottoming of the shock buffering material due to shocks and has an appropriate bending strength (flexibility) while securing the shock buffering performance. The added amount of silica (b2) that can be obtained is particularly preferably 18 to 22 parts by weight, and can be particularly reduced in thickness and impact buffering properties in cooperation with the fine hollow filler (b).

3. Flame retardant (C)
In the thin impact buffering material of the present invention, the filler (B) as the filler is blended with the silicone gel (A) used as the base material, and a flame retardant (C) can be further added.
As the flame retardant (C), a known flame retardant can be appropriately selected and added in an appropriate amount within a range that does not impair the buffer performance of the thin impact buffer of the present invention. It is preferable that at least one flame retardant (C) selected from the group consisting of graphite, metal hydroxide and magnetite is blended. And the selection from the group which consists of expanded graphite, a metal hydroxide, and a magnetite should just be performed according to the target flame-retardant level (for example, UL specification V94). More preferably, expanded graphite is preferable because a flame retardant effect can be imparted by adding a small amount.

The expanded graphite used in the present invention is graphite in which a chemical substance is inserted between the graphite layers. For example, natural graphite, pyrolytic graphite, etc., which has a highly crystallized structure, concentrated sulfuric acid and nitric acid are used. A graphite intercalation compound is formed by immersing in a strong oxidizing solution of a mixture of concentrated sulfuric acid and hydrogen peroxide solution, and then rapidly heated to expand the C-axis direction of the graphite crystal. It is a powder obtained by pulverizing a powder obtained by doing this, or a product obtained by rolling it into a sheet.
Moreover, the addition amount of expanded graphite is 3-10 weight part with respect to 100 weight part of silicone gel (A), Preferably it is 5-10 weight part. If the amount of expanded graphite added is less than 3 parts by weight, a sufficient flame retardant effect cannot be obtained. It becomes difficult to secure.

In the present invention, the magnetite used as a flame retardant can be appropriately selected from those having powder characteristics within a range that does not impair the buffer performance of the thin impact buffer material, but from the viewpoint of ease of handling and uniform dispersibility, the particle size distribution D50. Is preferably 0.1 to 0.4 μm. Here, the particle size distribution D50 indicates a range of particle size values when the weight is accumulated from the small value of the particle size obtained by the particle size distribution meter to 50%.
Moreover, what is necessary is just to adjust suitably the addition amount in the range which can make impact buffer performance and a flame-retardant level (for example, UL specification V94) compatible.
Furthermore, the shape of the magnetite is not particularly limited, and can be a desired shape such as a spherical shape, a fibrous shape, or an indefinite shape. In the present invention, in order to obtain high flame resistance, octahedral fine particles are preferable.

  In the present invention, examples of the metal hydroxide used as a flame retardant include aluminum hydroxide and magnesium hydroxide. What is necessary is just to adjust suitably the addition amount in the range which can make impact shock absorbing performance and a flame retardance level (for example, UL specification 94V) compatible.

  The thin impact cushioning material of the present invention comprises the above-mentioned uncured component (A), component (B), component (C), and optional components (for example, pot life adjusting agents, etc.) ) Can be obtained by mixing under reduced pressure or normal pressure, then defoaming, molding and curing. In addition, when blending silica (b2), it is preferable to blend the silicone gel (A) component and silica (b2) under heating to prepare a silicone gel base, and then blend the other components.

  In addition, as one of preferred embodiments, the thin impact cushioning material of the present invention has at least a part of the surface of the thin impact cushioning material, and further has a convex shape made of the same or different blending material as the thin impact cushioning material. A protrusion can be formed. By forming convex protrusions on the surface of the thin shock absorbing material, the contact resistance on the surface of the thin shock absorbing material can be reduced. Therefore, when inserting the thin shock absorbing material into a narrow gap, Can be inserted into the socket, and the workability is improved. Furthermore, when fixing the thin impact cushioning material by attaching or sandwiching it to an attached object (for example, a hard disk drive or the like hereinafter), the convex protrusion can be easily crushed and deformed, so that it can be fixed with a small pressing force, Furthermore, since the compression rate at the time of assembling the shock absorbing material can be reduced, there is an effect that it can be sufficiently exhibited without reducing the shock absorbing performance.

The convex protrusion of the present invention is not particularly limited as long as it protrudes three-dimensionally from the surface of the thin shock absorbing material such as a dome shape or a polygonal pyramid shape, but a dome shape is particularly desirable.
The convex protrusions may be formed by pouring an uncured thin shock-absorbing material into a mold in which a concave hole is formed, and the convex protrusions may be integrally cured with the same constituent material. A structure in which the cushioning performance of the convex protrusions is changed by filling a hardened thin impact buffering material.

The protruding length of the convex protrusion is preferably 1 mm or less, more preferably 0.5 mm or less, for the problem of providing a thin impact buffer. Further, the position and arrangement of the convex protrusions may be appropriately adjusted depending on the protrusion length, width, hardness, etc. of the convex protrusions.
An example of the shape of the thin impact buffer material of the present invention is shown in FIG.

Further, in order to protect and handle the surface of the thin impact buffer material of the present invention, a thin impact in which a single layer or multiple layers of resin base material is further laminated on at least a part of the surface of the thin impact buffer material. It can be set as a buffer laminated body.
The resin base material is not particularly limited as long as it does not impair the impact buffering performance of the thin impact buffer material. For example, a film of polyester, vinyl chloride, polyamide, polyimide, or the like is preferable.
Moreover, in this invention, an adhesion layer and a peeling sheet are also defined as a resin base material. Therefore, taking a PET film provided with an adhesive layer as an example, a multi-layer resin base material in which a resin base material 1 (adhesive layer) and a resin base material 2 (resin film) are laminated is also a resin base material. It is.
In addition, when an adhesive layer is laminated | stacked on a resin film, it laminates | stacks on the side used as a sticking surface with respect to a to-be-mounted thing. Moreover, the release sheet may be laminated | stacked for the handleability. When the pressure-sensitive adhesive layer is laminated on the resin base material, it is easy to attach the thin impact buffer laminate to the attachment object, and the adhesion strength is further improved.

Moreover, you may laminate | stack using the resin base material which has an uneven surface in the outermost layer as said resin base material. The uneven step on the uneven surface of the resin substrate is preferably 1 mm or less, more preferably 0.5 mm or less, for the problem of providing a thin impact buffer laminate. As a specific example, in the case of applying an embossed resin base material, it is possible to reduce the sliding resistance of the outer surface of the thin impact buffer laminate together with the reinforcement effect of the thin impact buffer material. There is an effect of improving workability when the thin impact buffer laminate is inserted into the gap and incorporated.
Further, as another example, a smooth resin base made of the same material or a different resin is applied to a resin base material having convex protrusions vacuum-formed using a vacuum forming die having fine concave portions by vacuum forming. An air cushion sheet formed by laminating materials can be applied. By laminating the thin impact cushioning material and the thin resin air cushion material, there is an effect that the impact cushioning performance can be further improved together with the reinforcing effect of the thin impact cushioning material.

The method for laminating the resin base material and the thin impact buffer material is not particularly limited. For example, a primer is previously applied to the surface of the resin base material, and an uncured mixed raw material to be an impact buffer material is formed thereon. After the contact, it is cured and the impact cushioning material and the resin base material are integrated, the cured impact cushioning material is self-adhesive and the resin base material is adhered and laminated, and the cured impact cushioning material and The resin base material may be laminated with an adhesive.
FIG. 6 shows a configuration example of the thin impact buffer laminate according to the present invention.

4). Thin impact cushioning material and use thereof The thin impact cushioning material of the present invention comprises a silicone gel (A) and a filler (B), and even if the thickness is as thin as 0.5 to 2.0 mm, the impact is remarkable. It is characterized by exhibiting a buffering effect, and when an impact is applied, an impact buffering effect is exhibited with a volume change, so that the installation space can be saved. As a result, it can be used in portable information devices such as notebook computers, mobile phones, portable music information devices, portable game machines, and the like, and further downsizing of the portable devices can be achieved. . It is also useful as an impact buffering protection member by sticking to the outside of a portable device.

  EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not particularly limited to these examples.

[Example 1]
As the silicone gel (A), a two-component addition type thermosetting silicone having a Asker C hardness of 50 (CF5058 manufactured by Toray Dow Corning Co., Ltd.) is used, and a filler (B) is used. “Expansel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd., which is a micro hollow body made of a copolymer of vinylidene chloride and acrylonitrile (average particle size is 30-50 (40) μm, density is 42 kg / m ³ ) 3 parts by weight with respect to 100 parts by weight of the silicone gel, and after depressurizing and defoaming, an appropriate amount of the uncured mixture is poured onto a 100 μm-thick PET film so as not to entrain air bubbles. Another PET film having a thickness of 100 μm is placed on the mixture, formed into a sheet by a calendering machine, and then in a heat curing furnace Thermally cured at 70 ° C., to produce a different shock absorbing material having a thickness of an area of 200 mm × 200 mm. The thickness of the shock absorbing material was adjusted by the gap distance between the upper and lower rolls of the calendar molding machine.

[Example 2]
A silicone gel having an Asker C hardness of 60, using a two-component addition type thermosetting silicone (CF5058 manufactured by Toray Dow Corning Co., Ltd.) with 30% by weight of silica and adjusting the two-component mixing ratio (A ) Was used in the same manner as in Example 1 except that shock-absorbing materials having different thicknesses were produced.

[Example 3]
The same as in Example 1 except that a 15 wt% silica-added two-component addition type thermosetting silicone having a Asker C hardness of 5 (CF5057 manufactured by Toray Dow Corning) was used as the silicone gel (A). Thus, shock-absorbing materials having different thicknesses were produced.

[Example 4]
The thickness is different in the same manner as in Example 1 except that the amount of “Expancel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd. is changed to 1 part by weight with respect to 100 parts by weight of the silicone gel. An impact cushioning material was produced.

[Example 5]
As the silicone gel (A), a two-component addition type thermosetting silicone having a Asker C hardness of 5 (CF5057 manufactured by Toray Dow Corning Co., Ltd.) and a silica 10 wt% addition product was used. An impact cushioning material having a different thickness was produced in the same manner as in Example 1 except that the amount of EXPANSEL (registered trademark) 551DE40d42 was changed to 1 part by weight with respect to 100 parts by weight of the silicone gel.

[Comparative Examples 1-5]
The main production method was the same as in Example 1, and produced thin impact buffer materials for portable information devices of Comparative Examples 1 to 5. The materials used for the production are shown below, and Table 1 outlines the blending amounts and the like.

Comparative Example 1 (conventional cushioning material) is a two-component addition type heat in which the silicone gel (A) does not contain silica and the Asker C hardness is 0 (150 penetration according to JIS K2207-1996 (50 g load)). A curable silicone (CF5106 manufactured by Toray Dow Corning Co., Ltd.) is used, and the amount of “Expancel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd. is 3% by weight.
Comparative Example 2 has the same material configuration as Example 1 except that “Expancel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd. is not added.
Further, Comparative Example 3 has the same material configuration as Example 1 except that a two-component addition type thermosetting silicone (CF5058 manufactured by Toray Dow Corning) was used.
Furthermore, Comparative Example 4 has the same material configuration as Example 3 except that “Expancel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd. is not added.
Further, Comparative Example 5 is a silicone gel having an Asker C hardness of 80 using a two-component addition type thermosetting silicone (CF5058 manufactured by Toray Dow Corning Co., Ltd.) and an adjusted mixture ratio of the two components. Using (A), the amount of “Expansel (registered trademark) 551DE40d42” manufactured by Nippon Philite Co., Ltd. is 4% by weight.

(Evaluation):
Tables 1 and 2 show the blending amount and the hardness of the obtained shock absorbing material for the thin shock absorbing materials obtained in Examples and Comparative Examples. For these thin impact buffer materials, impact buffer performance evaluation was performed based on the following evaluation method.

(I) Buffer performance evaluation test Summary of evaluation method for shock absorption characteristics:
The test piece was a sheet of 20 mm × 20 mm and a thickness of 0.25 mm to 5 mm.
The buffer test was carried out using a company-made weight drop tester. As shown in FIG. 1, the configuration of the testing machine is as follows: a sample stage, a disk weight with an aluminum shaft (impact surface: Φ45 mm), and an acceleration pickup installed on the weight (PV-94 manufactured by Rion). The disc weight with a shaft is supported by a bearing for allowing it to drop naturally along the same track with low resistance.
The acceleration pickup is connected to a computer via an FFT analyzer (AD3542 FFT ANALYZER manufactured by A & D Co., Ltd.), and impact waveform data is recorded and analyzed. To hold and drop a disk weight with a shaft, insert a fixed pin into the shaft of a disk weight with a shaft (hereinafter referred to as a weight), prepare to drop, pull out the fixed pin, I dropped it.
The bottom surface (impact surface) of the weight is flat. In addition, the sample base is a 30 mm thick aluminum (hard aluminum 2017) block and a 12 mm thick synthetic wood board manufactured by Hokuyo Plywood (JAS standard plywood for concrete formwork (F ☆). ) Is attached with an adhesive, and the synthetic plate side is the sample installation surface.

  In addition, the weight drop tester is installed by adjusting the horizontal and vertical levels with respect to the direction of gravity so that the drop energy of the weight with shaft is uniformly applied to the sample stage. When a 125 kg weight is directly collided with a sample table from a drop height of 100 mm (without sample), the maximum impact acceleration measured by the accelerometer is 1500 G, and the maximum impact acceleration Has a structure proportional to the drop height. The drop height at this time is the shortest distance between the surface of the sample table and the bottom surface (impact surface) of the weight.

The test method is to place a test piece on the sample stage so that it becomes the center of the weight and the center of the test piece, drop a weight of 0.125 kg from a predetermined drop height, and place it on the test piece. The impact acceleration in the height direction at the time of collision was detected by the acceleration pickup, and the maximum impact acceleration value Gs of the impact waveform obtained by the FFT analyzer and the computer was obtained.
The drop height h at this time is the shortest distance between the upper surface of the test piece and the bottom surface (impact surface) of the weight.
Next, as blank data, the weight was dropped on the sample stage without a test piece, and the maximum impact acceleration G0 of the blank was obtained in the same manner.
The drop height h at this time is the shortest distance between the surface of the sample table and the bottom surface (impact surface) of the weight, and is set equal to the distance of the test height of the sample piece. The collision force was adjusted by changing the drop height h.
From the results of Gs and G0 obtained as described above, the impact buffering efficiency (energy conversion efficiency) was calculated by Equation 1 to evaluate the impact absorption characteristics. The applied impact force was calculated from Equation 2. The evaluation results are shown in FIGS.

Impact buffer efficiency [%] = (1−Gs / G0) × 100 −−−
Impact force [N] = G0 [G] × weight weight [kg]
In equations (1) and (2), Gs represents the maximum impact acceleration [G] when an impact is applied by freely dropping the weight onto the buffer material, and G0 is an impact applied by freely dropping the weight on the test table. Represents the maximum impact acceleration [G].

FIG. 2 evaluated the impact buffering efficiency when the thickness of the buffer material of Example 1 and Comparative Examples 1 and 2 was changed at a weight falling height of 100 mm (G0 = 1500 G, equivalent to impact force 187N). It is a result.
As is clear from the results of this evaluation, from the comparison between Example 1 and Comparative Example 2, by adjusting the hardness of silicone and adding silica and a hollow filler, in the entire thickness range of 0.5 mm to 2 mm. It can be seen that excellent shock absorbing performance is exhibited.
Further, from the comparison with the conventional product of Comparative Example 1, a high impact buffering effect in the vicinity of 1 mm, which could not be realized with the conventional product, is realized.
This is based on the assumption that a standard 1.8-inch hard disk device (about 51 g) is naturally dropped from a height of 1 m with respect to a wooden floor surface, and the hard disk device bottom surface and the floor surface collide with uniform contact. However, even though the thickness of the shock absorbing material is only 1 mm, the shock absorbing material of 20 mm □ size is installed at four locations on the hard disk collision surface, so that the shock absorbing efficiency is about 80%. This result suggests that the impact buffering efficiency can be realized even when the impact can be reduced and the thickness is only 0.5 mm.

As an example, as shown in FIG. 3 and FIG. 4, the impact buffer material sheets having a thickness of 1 mm produced in Examples 1 to 5 and Comparative Examples 1 to 5 were used, and the fall height of the weight was changed. When the actual measured value of G0 in Formula 1 is in the range of impact acceleration of 400 to 1600 G (in the range of 60 to 200 N in terms of impact force according to Formula 2), the impact buffering efficiency of each impact buffer material shows the hardness of the silicone gel (A) By adjusting the blending amount of the present invention and the blending amount of the present invention and the hardness of the shock-absorbing material, a high impact buffering effect with an impact buffering efficiency of 70% or more can be obtained within the range of the impact force described above. I understand.
On the other hand, as seen in Comparative Examples 1 to 5, if any one of the constituent features of the present invention is removed, the impact cushioning efficiency is lowered, and the impact cushioning material cannot be thinned.
From these facts, it can be said that the thin shock-absorbing material of the present invention has excellent shock-absorbing performance even if the thickness is small.

[Examples 6 to 8]: Effect of flame retardant addition In Example 6, as the flame retardant (C), expanded graphite (EX-MH manufactured by Chuetsu Graphite Co., Ltd.) was added to 100 parts by weight of the silicone gel (A). An impact buffer material having an Asker C hardness of 60 was produced in the same manner as in Example 1 except that 3 parts by weight was blended.
In Example 7, 5 parts by weight of the expanded graphite is blended with respect to 100 parts by weight of the silicone gel (A). Further, in Example 8, the expanded graphite is mixed with 100 parts by weight of the silicone gel (A). On the other hand, an impact buffer material having an Asker C hardness of 60 was produced in the same manner as in Example 6 except that 10 parts by weight was blended.

(Evaluation):
About the impact buffer material of thickness 1mm obtained in Examples 6-8, the combustibility test was implemented based on the following evaluation method. The evaluation results are shown in Table 3 together with Example 1 for reference.

(Ii) Flame retardancy (flame retardant test)
Flame retardant test method overview:
A flame retardant test based on UL94V was conducted to evaluate the flame retardancy. The evaluation results were made in four stages of V0, V1, V2, and NC (class V nonconformity) in the order of difficulty in burning, in accordance with the UL94V combustion test evaluation method.

  As is clear from the evaluation results of Table 3, the thin impact buffer materials of Examples 6 to 8 have good flame retardancy evaluations of V0, V1, or V2. On the other hand, the impact buffer material of Example 1 of the reference comparison that does not contain a flame retardant has an evaluation of flame retardance of NC (non-conforming to class V), and the addition of expanded graphite is effective in imparting flame retardancy. I understand that.

  The thin impact cushioning material of the present invention has excellent impact cushioning performance even when the thickness is small, and the space for deformation during impact cushioning may be small, so the installation space for the thin impact cushioning material can be reduced. For example, it can be suitably used for portable devices such as notebook computers, mobile phones, portable music information devices, and portable game machines, and further improves the flame retardancy required for parts of electrical and electronic products. As a result, it is possible to contribute to the development of design technology that simultaneously reduces the size of electric appliances and electronic products and provides shock absorbing properties.

1: FFT analyzer 2: Charge amplifier 3: Acceleration pickup 4: Shaft weight 5: Shaft weight fixing pin 6: Sample 7: Sample stand 71: Sample stand (synthetic wood board)
72: Sample stage (aluminum block)
8: Bearing 601: Impact buffer material 602: Resin base material 603: Embossed resin base material 604: Adhesive layer 605: Release sheet 606: Air cushion sheet 607: Gas 610: Impact buffer laminate 620: Impact buffer laminate 630: Impact buffer laminate 640: Impact buffer laminate 650: Impact buffer laminate 660: Impact buffer laminate

Claims (6)

A thin impact cushioning material having a thickness of 0.5 to 2.0 mm obtained by blending the filler (B) with the silicone gel (A),
The filler (B) comprises 1 to 3.5 parts by weight of a synthetic resin outer shell (b1) and 10 to 30 parts by weight of silica (b2) with respect to 100 parts by weight of the silicone gel (A). The thin impact buffer material has an Asker C hardness of 15 to 60, and the silicone gel (A) has an Asker C hardness of 5 to 55.   The thin impact cushioning material according to claim 1, wherein the thin impact cushioning material has an impact cushioning efficiency of 70% or more in a weight drop test.   The synthetic resin is selected from the group consisting of a vinylidene chloride resin, a copolymer of vinylidene chloride and acrylonitrile, a copolymer of acrylonitrile and methacrylonitrile, and a terpolymer of vinylidene chloride, acrylonitrile and divinylbenzene. The thin impact buffering material according to claim 1 or 2, wherein at least one kind is used.   The micro hollow body (b1) having an outer shell of the synthetic resin is obtained by thermally expanding micro spheres containing a thermally expandable substance therein. Thin impact cushioning material.   The convex protrusion which consists of the same mixing | blending material as the said thin impact buffering material, or a different mixing | blending material is further formed in at least one part of the surface of the said thin impact buffering material. The thin shock absorbing material according to crab.   A smooth or concavo-convex processed resin base material comprising a single layer or multiple layers is further laminated on at least a part of the surface of the thin impact buffer material according to any one of claims 1 to 5. A thin shock-absorbing laminate.

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