JP2012076946A - Curable composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a curable composition which can exhibit excellent performances with respect to heat resistance, chemical resistance, strength and the like, can be colored in a desired color tone, and is excellent also in finish of a film formed therefrom.SOLUTION: The curable composition comprises a dispersion (L) comprising a polyol compound (a), a pigment (b), a surfactant (c) and water (d), an isocyanate compound (M), a cement (N), a fine aggregate (P), and a coarse aggregate (Q), wherein the color tone of the coarse aggregate (Q) is similar to the color tone of a film formed from a composition prepared by removing the coarse aggregate (Q) from the curable composition.

Description

  The present invention relates to a novel curable composition. The composition of the present invention is particularly suitable as a covering material for a floor surface.

  Conventionally, as a floor covering material, various materials such as urethane, epoxy, and acrylic are used. By using such a material, it is possible to protect the floor surface and to impart a desired color to the floor surface. However, when high performance is required in terms of heat resistance, chemical resistance, strength, etc., it is difficult for the above materials to sufficiently satisfy the requirements.

In JP-A-8-169740 (Patent Document 1), a first component composed of an active hydrogen-containing compound, water, and a cement water reducing agent, a second component composed of an isocyanate compound, and a third component composed of a hydraulic cement, A cement curable composition comprising at least three components is disclosed. According to such a curable composition, it is possible to ensure excellent physical properties in terms of heat resistance, chemical resistance, strength, and the like.
Japanese Unexamined Patent Application Publication No. 2004-292209 (Patent Document 2) discloses a resin cement composition in which an aggregate containing polyester polyol, polyphenyl polymethyl polyisocyanate, and hydraulic cement is blended. Specifically, it is described that an insulator of about 0.5 to 3 mm can be used as the aggregate. Such a composition can exhibit physical properties such as anti-slip properties in addition to heat resistance, chemical resistance, strength, and the like.

  However, in the above patent document, no consideration is given to coloring. Even if the composition of the above-mentioned patent document is mixed with a pigment and colored, the formed film is likely to have uneven color and the like, which is insufficient in terms of finish. In particular, when an aggregate having a large particle size is included in the composition, such a problem is likely to be caused.

JP-A-8-169740 JP 2004-292209 A

  The present invention has been made in view of the above-described problems, and can exhibit excellent performance in heat resistance, chemical resistance, strength, etc., and can be colored in a desired color tone. An object of the present invention is to obtain a curable composition having excellent finish in the formed film.

  In order to solve such problems, the present inventors, as a result of intensive studies, have obtained a dispersion containing a polyol compound, a pigment, a surfactant, and water, an isocyanate compound, a cement, a fine aggregate, and a coarse aggregate. The present invention was completed by conceiving that the color tone of the coarse aggregate and the color tone of the film formed by the composition obtained by removing the coarse aggregate from the curable composition are approximate colors. I arrived.

That is, the present invention has the following characteristics.
1. A dispersion (L) containing a polyol compound (a), a pigment (b), a surfactant (c), and water (d), an isocyanate compound (M), a cement (N), a fine aggregate (P), and A curable composition comprising coarse aggregate (Q),
The color tone of the coarse aggregate (Q) is
The curable composition, which is an approximate color of a color tone of a film formed by the composition obtained by removing the coarse aggregate (Q) from the curable composition.
2. The surfactant (c) includes a nonionic surfactant (c1). The curable composition as described.
3. The dispersion (L) further contains fluorine-modified silicone (e). Or 2. The curable composition according to 1.
4). As the polyol compound (a),
1. It contains a polyol (a1) having a hydroxyl group and an amino group. ~ 3. The curable composition according to any one of the above.

  In the curable composition of this invention, while being able to color in a desired color tone, the stable effect can be exhibited also in finish, etc., and the aesthetics of a formed film can be improved. The composition of the present invention can exhibit excellent performance in heat resistance, chemical resistance, strength, anti-slip property, and the like.

  Hereinafter, modes for carrying out the present invention will be described.

  The curable composition of the present invention comprises a dispersion (L), an isocyanate compound (M), a cement (N), a fine aggregate (P), and a coarse aggregate (Q). Among these, the dispersion liquid (L) is obtained by mixing the polyol compound (a), the pigment (b), the surfactant (c), and water (d).

  Among these, the polyol compound (a) (hereinafter referred to as “component (a)”) acts as a binder. As the component (a), various polyol compounds capable of reacting with the isocyanate (M) can be used. Specific examples include acrylic polyol, polyester polyol, polyether polyol, polydiene polyol, vegetable oil-based polyol, and cellulose compound.

  In the present invention, the component (a) preferably contains a polyol compound (a1) having a hydroxyl group and an amino group (hereinafter also referred to as “component (a1)”). Such (a1) component contributes to the performance improvement in sclerosis | hardenability, finish, etc.

  As the component (a1), an amino group-containing polyether polyol obtained by addition polymerization of a cyclic ether using an amine compound as an initiator is particularly suitable. The hydroxyl value of the amino group-containing polyether polyol is preferably 250 to 900 mgKOH / g, more preferably 300 to 800 mgKOH / g. The pH of the amino group-containing polyether polyol is preferably 8 or higher, more preferably 9 or higher, and still more preferably 10-13. This pH is a value measured by a method defined in JIS K1557.

  Examples of the amine compound used as the initiator in the amino group-containing polyether polyol include an aliphatic amine compound, a saturated cyclic amine compound, and an aromatic amine compound. Among these, examples of the aliphatic amine compound include ethylenediamine, propylenediamine, butylenediamine, hexamethylenediamine, diethylenetriamine, and triethylenetetramine. Examples of the saturated cyclic amine compound include N-aminomethylpiperazine, N- (2-aminoethyl) piperazine and the like. Examples of the aromatic amine compound include 2,4-toluenediamine, 2,6-toluenediamine, diethyltoluenediamine, 4,4′-diaminodiphenylmethane, p-phenylenediamine, o-phenylenediamine, naphthalenediamine, and the like. It is done.

  Examples of the cyclic ether that is addition-polymerized to the amine compound include ethylene oxide, propylene oxide, isobutylene oxide, 1,2-epoxybutane, 2,3-epoxybutane, and the like. Among these, at least one selected from ethylene oxide and propylene oxide is preferable.

  Such component (a1) is 0.1 to 20% by weight (more preferably 0.2 to 10% by weight, still more preferably 0.3 to 3% by weight) in the polyol compound (a) in terms of solid content. It is desirable to be included.

  As the polyol compound (a), it is desirable to include a polyol compound other than the component (a1) together with the component (a1). As the polyol compound other than the component (a1), the above-described various polyol compounds can be used. In the present invention, however, the vegetable oil-based polyol (a2) is particularly suitable.

  Examples of the vegetable oil-based polyol (a2) (hereinafter referred to as “component (a2)”) include soybean oil-based polyol and castor oil-based polyol. Of these, castor oil-based polyol is particularly preferable. As the castor oil-based polyol, castor oil and / or a polyol synthesized using castor oil as a starting material can be used. Among these, polyols synthesized using castor oil as a starting material include, for example, an alkylene oxide adduct of castor oil, an epoxidized product of castor oil, a halide of castor oil, a transesterified product of castor oil and polyhydric alcohol, and a hydride thereof. Etc.

  When the polyol compound (a) includes the component (a1) and the component (a2), the polyol compound (a) is 0.1 to 20% by weight (more preferably) in the polyol compound (a) in terms of solid content. 0.2 to 10% by weight, more preferably 0.3 to 3% by weight), and the component (a2) is 80 to 99.9% by weight (more preferably 90 to 99.8% by weight, The content is preferably 97 to 99.7% by weight). Such a ratio is preferable in terms of curability and finish.

As the pigment (b) (hereinafter referred to as “component (b)”), various colored pigments can be used, and a colored pigment and an extender pigment can be used in combination.
Examples of coloring pigments include titanium oxide, zinc oxide, carbon black, black iron oxide, cobalt black, copper manganese iron black, red pepper, molybdate orange, permanent red, permanent carmine, anthraquinone red, perylene red, quinacridone red, yellow. Examples thereof include iron oxide, titanium yellow, first yellow, benzimidazolone yellow, chrome green, cobalt green, phthalocyanine green, ultramarine, bitumen, cobalt blue, phthalocyanine blue, quinacridone violet, and dioxazine violet. Examples of extender pigments include heavy calcium carbonate, light calcium carbonate, kaolin, clay, diatomaceous earth, talc, and barium sulfate. The particle size of the component (b) is usually less than 50 μm (preferably 0.1 to 30 μm).
In the present invention, it is possible to express various color tones by appropriately selecting and mixing one or more of the component (b).
The ratio of (b) component is 0.5-30 weight part normally with respect to 100 weight part of solid content of (a) component, Preferably it is 1-20 weight part.

  Examples of the surfactant (c) in the dispersion liquid (L) include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Among these, in the present invention, an embodiment containing a nonionic surfactant (c1) (hereinafter also referred to as “component (c1)”) is preferable. In the present invention, by including the component (c1), the dispersion stability in the dispersion liquid (L) is increased, and separation over time is suppressed. By using the dispersion liquid (L) thus stabilized, finish, heat resistance, chemical resistance, strength, and the like can be improved. Furthermore, the component (c1) effectively acts on suppressing unevenness in the formed film and improving finish. Moreover, when using the said (a1) component as a polyol compound, the further excellent effect in a pot life, sclerosis | hardenability, etc. can be acquired by combined use of a (a1) component and a (c1) component.

  The type of the nonionic surfactant (c1) is not particularly limited. For example, polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenyl ether, polyoxyethylene distearate, polyoxyethylene lauryl ether, polyoxy Examples include ethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene alkyl ether, polyoxyethylene higher alcohol ether, polyoxyethylene phenyl ether, and the like.

  As the nonionic surfactant (c1), those having an HLB of 9 or more are suitable. The HLB of the component (c1) is more preferably 15 or more, and further preferably 18-20. By using the component (c1) having such an HLB, the above-described effects can be further enhanced. HLB is an abbreviation for hydrophilic-lipophilic balance, and is a numerical representation of the hydrophilic / lipophilic strength ratio of an amphiphilic substance.

  The ratio of the component (c1) is preferably 0.01 to 10 parts by weight, more preferably 0.1 to 5 parts by weight, and still more preferably 0.3 to 100 parts by weight of the component (a) in terms of solid content. 3 parts by weight. With such a ratio, sufficient effects can be obtained in stability, pot life, curability, finish, and the like.

Water (d) (hereinafter referred to as “component (d)”) contributes to a curing reaction or the like when the dispersion liquid (L), the isocyanate compound (M), the cement (N) and the like are mixed.
The ratio of the component (d) is preferably 20 to 200 parts by weight, more preferably 30 to 150 parts by weight with respect to 100 parts by weight of the solid content of the component (a).

  The dispersion (L) in the present invention preferably further contains fluorine-modified silicone (e) (hereinafter referred to as “component (e)”) in addition to the above components. The component (e) is a component that effectively acts on the formation of a colored film exhibiting a uniform finished appearance. In the present invention, by including the component (e), the effect of suppressing unevenness in both the color tone and the glossiness can be enhanced, and a more uniform finished film can be formed. Although its mechanism of action is not clear, in the formation stage of the film formed by mixing and applying the dispersion liquid (L), the isocyanate compound (M), and the cement (N), the component (e) is applied to the surface of the film. It is presumed that proper orientation contributes.

The component (e) is a silicone compound containing a fluorine atom, and a fluorine atom is contained in a part of the compound having a polysiloxane unit as a main chain. Examples of such component (e) include a compound having a polysiloxane unit as a main chain and a perfluoroalkyl group bonded thereto. Such compounds are described, for example, in Japanese Patent Publication No. 41-9434, Japanese Patent Laid-Open No. 50-46800, Japanese Patent Laid-Open No. 2-97529, Japanese Patent Laid-Open No. 7-53719, and the like.
Specifically, examples of the component (e) include fluorine-modified silicone represented by the general formula (1). In the formula, R ¹ is the same or different alkyl group or aryl group having 1 to 20 carbon atoms, R ² is —R ⁴ —Rf (wherein R ⁴ is a divalent alkylene group having 2 to 6 carbon atoms). Rf represents a C 1-12 perfluoroalkyl group.), R ³ is either R ¹ or R ² , m and n are integers, and m = 0 to 500, n = 1 to 500. Moreover, the arrangement of each structural unit represented by the general formula (1) may be any of alternating, block, and random.

  The ratio of the component (e) is preferably 0.01 to 2 parts by weight, more preferably 0.05 to 1 part by weight with respect to 100 parts by weight of the solid content of the component (a). When the ratio of the component (e) is within such a range, it is possible to form a coating film having a sufficiently uniform finish.

  The dispersion (L) can contain a liquid organic compound (f) (hereinafter referred to as “component (f)”) in addition to the above components. By including the component (f) in the dispersion (L), the stability of the dispersion (L) is improved, and the effects of the present invention can be stably obtained. The component (f) is an organic compound that is liquid at room temperature, and specifically, a solvent (f1) and / or a plasticizer (f2) can be used.

  As the solvent (f1), non-aqueous solvents such as aliphatic hydrocarbon solvents, aromatic hydrocarbon solvents, ester solvents and ketone solvents are suitable. Specific examples of the aliphatic hydrocarbon solvent include n-hexane, n-pentane, n-octane, n-nonane, n-decane, n-undecane, n-dodecane, terpin oil and mineral spirits. Etc. Examples of aromatic hydrocarbon solvents include toluene, xylene, solvent naphtha, etc .; Examples of ester solvents include ethyl acetate and butyl acetate; Examples of ketone solvents include methyl ethyl ketone and methyl isobutyl ketone. Is mentioned. As the solvent (f1), one or more of these can be used.

As a plasticizer (f2), a phthalic acid compound, an adipic acid compound, a sebacic acid compound, a phosphoric acid compound, an alkylsulfonic acid ester compound etc. can be used, for example. Specific examples of the phthalic acid compound include di (n-butyl) phthalate, bis (2-ethylhexyl) phthalate, diisononyl phthalate, and butyl benzyl phthalate. Examples of adipic acid compounds include, for example, di (n-butyl) adipate, bis (2-ethylhexyl) adipate, etc .; examples of sebacic acid compounds, such as dibutyl sebacate; Dibutyl and the like; phosphoric acid compounds, for example, tricresyl phosphate, cresyl diphenyl phosphate, etc .; alkyl sulfonic acid ester compounds, for example, decane sulfonic acid phenyl ester, undecane sulfonic acid phenyl ester, dodecane sulfonic acid phenyl ester, Tridecanesulfonic acid phenyl ester, tetradecanesulfonic acid phenyl ester, pentadecanesulfonic acid phenyl ester, pentadecanesulfonic acid cresyl ester, hexadecanesulfonic acid phenyl ester, heptadecanesulfonic acid Eniruesuteru, octadecanoic acid phenyl ester, nona decane sulfonic acid phenyl ester, equalizer San decyl phenyl sulfonate ester. As the plasticizer (f2), one or more of these can be used.
In the present invention, those containing at least a plasticizer (f2) are particularly suitable as the component (f).

  The ratio of the component (f) is preferably about 20 to 200 parts by weight (more preferably 30 to 150 parts by weight) with respect to 100 parts by weight of the solid content of the component (a).

  In the dispersion liquid (L), the above components (a), (b), (c), (d), (e), (f) and the like are uniformly mixed by a conventional method. Can be manufactured. At this time, for example, additives such as an antifoaming agent, a reaction adjusting agent, a water reducing agent, fibers, an antiseptic, an algaeproofing agent and an antifungal agent can be mixed in the dispersion liquid (L).

As the isocyanate compound (M), a compound having two or more isocyanate groups in one molecule can be used. Specifically, for example, 4,4-diphenylmethane diisocyanate (pure-MDI), polymeric MDI, xylylene diisocyanate (XDI), tolylene diisocyanate, hexamethylene diisocyanate (HMDI), isophorone diisocyanate (IPDI), hydrogenated XDI, Hydrogenated MDI or the like, or those derivatized by allophanatization, biuretization, dimerization (uretidioneization), trimerization (isocyanurate conversion), adduct formation, carbodiimidization reaction, etc. can be mentioned. Moreover, the isocyanate group terminal prepolymer obtained by reaction of isocyanate and a polyol can also be used. As an isocyanate compound, these 1 type (s) or 2 or more types can be used.
The mixing ratio of the isocyanate compound (M) is preferably 50 to 800 parts by weight, more preferably 100 to 500 parts by weight with respect to 100 parts by weight of the solid content of the component (a).

Cement (N) includes, for example, ordinary Portland cement, early-strength Portland cement, ultra-high-strength Portland cement, moderately hot Portland cement, sulfate-resistant Portland cement, white Portland cement, etc., as well as alumina cement, ultrafast cement Examples thereof include cement, expanded cement, acidic phosphate cement, silica cement, blast furnace cement, fly ash cement, and keens cement. These may be used alone or in combination of two or more. Among these, Portland cement is preferable.
The mixing ratio of the cement (N) is preferably 100 to 1000 parts by weight, more preferably 200 to 800 parts by weight with respect to 100 parts by weight of the solid content of the component (a).

The composition of the present invention further contains fine aggregate (P) in addition to the above components. By mixing such fine aggregate (P), it is possible to improve the strength of the coating, increase the thickness, and the like.
Examples of the fine aggregate (P) include natural stone pulverized material, ceramic powder, silica sand, ceramic powder, rubber particles, metal particles and the like, or those coated with a colored coating.
The particle diameter of the fine aggregate (P) is usually 50 μm to less than 1000 μm, preferably about 100 to 980 μm. As the fine aggregate (P), two or more kinds having different average particle diameters can be used.
The mixing ratio of the fine aggregate (P) is preferably 200 to 3000 parts by weight, more preferably 500 to 2500 parts by weight with respect to 100 parts by weight of the solid content of the component (a).

In the composition of the present invention, in addition to the above components, coarse aggregate (Q) is further included. Such coarse aggregate (Q) has a larger particle diameter than the fine aggregate (P). In the present invention, by mixing the coarse aggregate (Q), fine irregularities can be formed on the surface of the coating, and slip resistance can be imparted.
The particle diameter of the coarse aggregate (Q) is usually about 1 to 10 mm. As the base material of the coarse aggregate (Q), the same material as that exemplified for the fine aggregate (P) can be used.
The mixing ratio of the coarse aggregate (Q) is preferably 100 to 2000 parts by weight, more preferably 200 to 1000 parts by weight with respect to 100 parts by weight of the solid content of the component (a).

In the present invention, the color tone of the coarse aggregate (Q) is an approximate color of the color tone of the film formed by the composition obtained by removing the coarse aggregate (Q) from the curable composition. In the present invention, the finish can be improved by using the coarse aggregate (Q) having such a color tone.
Usually, the coarse aggregate appears on the surface of the coating and gives fine irregularities to the coating. However, the appearance of the coarse aggregate on the coating surface (density, uneven height, etc.) may slightly change depending on the state of the base, the atmosphere during curing, and the like. In this way, when the appearance of the coarse aggregate is changed, unevenness is likely to occur in the finished appearance of the coating, and the aesthetics are impaired.
On the other hand, in the present invention, by using the coarse aggregate (Q) having a specific color tone, the above-described problems can be solved, and the finish and aesthetics can be improved.

The color tone of the coarse aggregate (Q) is an approximate color of the color tone of a film formed by removing the coarse aggregate (Q) from the curable composition of the present invention (hereinafter referred to as “coarse aggregate-free coating”). And Specifically, the color tone of the coarse aggregate (Q) is desirably set so that the color difference from the color tone of the coarse aggregate-free coating is 20 or less (preferably 15 or less, more preferably 10 or less).
The color difference (ΔE) mentioned here is a value measured using a color difference meter, and can be calculated from the L ^* value, a ^* value, and b ^* value according to the following formula. L ^* , a ^* , b ^* of coarse aggregate (Q) is measured by filling the coarse aggregate (Q) into a rectangular container until the bottom of the container is concealed and flattening the surface. Can be calculated.
^{<Equation> △ E = {(L *} 1 -L * 2) 2 + (a * 1 -a * 2) 2 + (b * 1 -b * 2) 2} 0.5
(In the formula, L ^{* 1} , a ^{* 1} , b ^{* 1} are L ^* , a ^* , b ^{* of the} coarse aggregate (Q), respectively ^. L ^{* 2} , a ^{* 2} , b ^{* 2} are not coarse aggregates, respectively. L ^* , a ^* , b ^* ) of coating

  As the coarse aggregate (Q), those satisfying the above conditions can be used. Specifically, as the coarse aggregate (Q), a natural stone pulverized product, ceramic powder, silica sand, ceramic powder or the like is preferably applied with a colored coating. This color coating can be performed using a colorant including a color pigment and a binder. Among these, as the color pigment, the same pigment as the component (b) can be used. Examples of the binder include organic binders such as polyester resin, vinyl chloride resin, epoxy resin, acrylic resin, urethane resin, acrylic silicon resin, and fluorine resin, and inorganic binders such as water glass, alkoxysilane, and silicon resin. Can be mentioned.

  In the curable composition of the present invention, the dispersion (L), the isocyanate compound (M), and the cement (N) are stored in separate packages at the time of distribution, and these may be mixed at the time of use. . The fine aggregate (P) and the coarse aggregate (Q) are usually mixed in the same package as the component (N). A carbon dioxide absorbent or the like can be mixed with the component (N).

  The curable composition of the present invention can form a film by mixing the above-mentioned components at the time of use and applying the mixture to a base such as mortar or concrete. Since the composition of the present invention can exhibit excellent physical properties in heat resistance, chemical resistance, strength, anti-slip property, etc., it is particularly preferable as a material to be applied to floor surfaces such as concrete.

At the time of application, various methods such as ironing, pouring, and spraying can be employed. The thickness after curing is usually about 2 to 10 mm. Within such a thickness range, it is also possible to divide and paint several times.
The coating and subsequent drying may be usually performed at room temperature (0 to 40 ° C.).

  Examples are given below to clarify the features of the present invention.

(Manufacture of curable composition)
According to the formulation shown in Tables 1 to 4, after each component is uniformly mixed to produce a dispersion, this dispersion, the isocyanate compound, cement, fine aggregate, and coarse aggregate are mixed uniformly. A curable composition was obtained. In each curable composition, the following raw materials were used. The color difference (ΔE) between the coarse aggregate and the coarse aggregate-free coating was measured using a color difference meter.

Resin 1: Amino group-containing polyether polyol (hydroxyl value 450 KOHmg / g, pH 11.0, solid content 100% by weight)
Resin 2: Amino group-containing polyether polyol (hydroxyl value 500 KOHmg / g, pH 11.0, solid content 100% by weight)
Resin 3: Amino group-containing polyether polyol (hydroxyl value 760 KOHmg / g, pH 12.0, solid content 100% by weight)
Resin 4: Polyether polyol (hydroxyl value 385 KOH mg / g, pH 7.0, solid content 100% by weight)
Resin 5: castor oil-based polyol (hydroxyl value 160 KOHmg / g, solid content 100% by weight)
Pigment 1: Yellow iron oxide Pigment 2: Phthalocyanine blue Pigment 3: Titanium oxide Pigment 4: Carbon black Fluorine compound: Fluorine-modified silicone solution (R ¹ and R ³ in the above general formula (1) are —CH ₃ , a compound in which R ² is —C ₂ H ₄ —CF ₃ , a solid content of 2% by weight)
Surfactant 1: Nonionic surfactant (polyoxyethylene alkyl ether, HLB 9.7, solid content 100% by weight)
Surfactant 2: Nonionic surfactant (polyoxyethylene sorbitan trioleate, HLB 11.0, solid content 100% by weight)
Surfactant 3: Nonionic surfactant (polyoxyethylene alkyl ether, HLB 13.4, solid content 100% by weight)
Surfactant 4: Nonionic surfactant (polyoxyethylene alkyl ether, HLB 18.5, solid content 60% by weight)
Surfactant 5: Anionic surfactant (polyoxyethylene alkyl ether sodium acetate, solid content 24% by weight)
Surfactant 6: cationic surfactant (lauryltrimethylammonium chloride, solid content 27% by weight)
・ Liquid organic compound 1: Plasticizer (Bis (2-ethylhexyl) phthalate)
Liquid organic compound 2: Plasticizer (alkyl sulfonic acid phenyl ester)
Additive: Antifoaming agent (non-silicone defoaming agent, solid content 25% by weight)
・ Isocyanate compounds: Polymeric MDI
・ Cement: White Portland cement ・ Fine aggregate: Silica sand (particle size 0.2-0.8mm)
・ Coarse aggregate 1: Gray coarse aggregate (particle size 1-2mm, colored coating of ceramic powder)
-Coarse aggregate 2: Yellow coarse aggregate (particle diameter 1-2mm, colored coating of ceramic powder)
-Coarse aggregate 3: Pale yellow coarse aggregate (particle diameter 1-2mm, colored coating of ceramic powder)
・ Coarse aggregate 4: Green coarse aggregate (particle diameter 1-2mm, colored coating of ceramic powder)
・ Coarse aggregate 5: White coarse aggregate (particle diameter 1-2 mm, ceramic powder)

(Test I)
The following tests were conducted for each curable composition obtained by the above method.

(1) Finishability 1
Each curable composition was coated on a concrete base so that the thickness after curing was 6 mm, and after curing for 7 days, the finish of the coating was visually confirmed. The evaluation is made in three stages (A: A) when the coarse aggregate is uniform and the finish is “A”, and non-uniform finish due to the coarse aggregate is “C” (excellent: A>B> C: Inferior). In addition, both coating and curing were performed in a standard state (temperature 23 ° C., relative humidity 50%).

  Test results are shown in Tables 1-4. Examples 1 to 23 had good finish.

(Test II)
The following tests were conducted for Examples 1 to 23.

(2) Finishability 2
Each curable composition was coated on a slate plate so that the thickness after curing was 6 mm, and after curing for 7 days, the finish of the coating was visually confirmed. The evaluation was made in three stages (excellent: A>B> C: inferior), with “A” indicating that a uniform film without uneven color and gloss was formed, and “C” indicating that uneven color or uneven gloss occurred. ) In addition, both coating and curing were performed in a standard state.

(3) Pot life Time Each curable composition was manufactured and allowed to stand for 60 minutes, and then coated on a slate plate with a thickness of 6 mm. The pot life was evaluated based on the film-forming properties at this time. The evaluation was performed in three stages (excellent: A>B> C: inferior), where “A” indicates that there was no hindrance to the film-forming property and “C” indicates that the problem occurred. In addition, manufacture, leaving, and coating of the curable composition were all performed in a standard state.

(4) Curability Each curable composition was coated on a slate plate so that the thickness after curing was 6 mm, and after curing for 24 hours, the degree of tackiness of the coating was confirmed by finger touch. The evaluation was performed in three stages (excellent: A>B> C: inferior), where “A” indicates that no tackiness was observed and “C” indicates that tackiness was observed. In addition, both coating and curing were performed in a standard state.

(5) Strength Each curable composition was coated on a concrete flat plate so that the thickness after curing was 6 mm and cured for 7 days. In addition, both coating and curing were performed in a standard state.
A steel ball having a height of 1 m to 1 kg was dropped a plurality of times on the surface of the obtained coating. In this test, the steel balls were repeatedly dropped until an abnormality (cracking, peeling, etc.) occurred in the coating. Evaluation is “A” when no abnormality occurs even when the steel ball is dropped 20 times, “B” when abnormality is caused by dropping 11 to 20 times, and abnormality is caused by dropping 10 times or less. It was performed in three stages (excellent: A>B> C: inferior) with the thing as “C”.

(6) Chemical resistance Each curable composition was coated on a concrete flat plate so that the thickness after curing was 6 mm, followed by curing for 72 hours. In addition, both coating and curing were performed in a standard state.
2 ml of chemicals were placed in a spot shape on the surface of the obtained film, and allowed to stand for 24 hours in a standard state, and then the state of the film was visually confirmed. The evaluation was performed in three stages (excellent: A>B> C: inferior), with “A” indicating no abnormality and “C” indicating abnormality such as discoloration.
For chemical resistance 1, a 30% by weight aqueous solution of sodium hydroxide was used. For chemical resistance 2, a 10% by weight aqueous solution of citric acid was used. For chemical resistance 3, ethyl acetate was used.

  Test results are shown in Tables 5-7.

Claims (4)

A dispersion (L) containing a polyol compound (a), a pigment (b), a surfactant (c), and water (d), an isocyanate compound (M), a cement (N), a fine aggregate (P), and A curable composition comprising coarse aggregate (Q),
The color tone of the coarse aggregate (Q) is
The curable composition, which is an approximate color of a color tone of a film formed by the composition obtained by removing the coarse aggregate (Q) from the curable composition.   The curable composition according to claim 1, comprising a nonionic surfactant (c1) as the surfactant (c).   The curable composition according to claim 1 or 2, wherein the dispersion (L) further contains a fluorine-modified silicone (e). As the polyol compound (a),
The curable composition according to any one of claims 1 to 3, comprising a polyol (a1) having a hydroxyl group and an amino group.