JP2012066184A - Spiral membrane module - Google Patents

Spiral membrane module Download PDF

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JP2012066184A
JP2012066184A JP2010212356A JP2010212356A JP2012066184A JP 2012066184 A JP2012066184 A JP 2012066184A JP 2010212356 A JP2010212356 A JP 2010212356A JP 2010212356 A JP2010212356 A JP 2010212356A JP 2012066184 A JP2012066184 A JP 2012066184A
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central tube
connecting member
engaging portion
membrane
spiral membrane
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Yasuhiro Uda
康弘 宇田
Toshimitsu Hamada
敏充 浜田
Shinichi Jizo
眞一 地蔵
Masashi Beppu
雅志 別府
Hideyuki Yamane
英之 山根
Masakatsu Takada
政勝 高田
Kazuhito Yoshida
和仁 吉田
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Nitto Denko Corp
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Nitto Denko Corp
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Priority to JP2010212356A priority Critical patent/JP2012066184A/en
Priority to PCT/JP2011/070622 priority patent/WO2012039302A1/en
Publication of JP2012066184A publication Critical patent/JP2012066184A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10Spiral-wound membrane modules
    • B01D63/106Anti-Telescopic-Devices [ATD]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10Spiral-wound membrane modules
    • B01D63/12Spiral-wound membrane modules comprising multiple spiral-wound assemblies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/02Specific tightening or locking mechanisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2317/00Membrane module arrangements within a plant or an apparatus
    • B01D2317/02Elements in series

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a spiral membrane module for which a connection method and configuration are not complicated and which has a connecting structure in which membrane elements can be securely connected to each other using a central tube.SOLUTION: The spiral membrane module accommodates a plurality of spiral membrane elements E connected in series in a pressure container and is characterized in that the membrane elements E are provided with a central tube 3 that extends from anti-telescoping parts 4 and has engaging parts 3a on an outer circumference, and is characterized by provision of a connecting part 10 which straddles the engaging parts 3a of adjacent membrane elements E and engages with both engaging parts 3a.

Description

本発明は、スパイラル型の膜エレメントが複数連結されて、圧力容器内に収容されているスパイラル型膜モジュールに関し、特に膜エレメントの大型化に対応するための技術として有用である。   The present invention relates to a spiral membrane module in which a plurality of spiral membrane elements are connected and accommodated in a pressure vessel, and is particularly useful as a technique for dealing with an increase in the size of a membrane element.

スパイラル型膜モジュールは、一般的に、スパイラル型の膜エレメントが複数連結されて、圧力容器内に収容されている構造を有する(例えば、特許文献1参照)。この膜エレメントは、その基本構造として、有孔の中心管の周囲に、供給側流路材を膜の分離層側に挟み込んだ二つ折りの膜リーフ、及びこれに隣り合う透過側流路材とからなる分離膜ユニットの単数又は複数の積層体を巻き付けた構造を有する。   A spiral membrane module generally has a structure in which a plurality of spiral membrane elements are connected and accommodated in a pressure vessel (see, for example, Patent Document 1). This membrane element has, as its basic structure, a bifurcated membrane leaf in which a supply-side channel material is sandwiched between membrane separation layers, and a permeation-side channel material adjacent to the perforated central tube. It has a structure in which one or a plurality of laminated bodies of separation membrane units made of

分離膜ユニットの両端には、テレスコープ防止部材が設けられており、分離膜ユニットの外周にはFRP(外装材)が巻き付けられている。運転の際には、その供給側と濃縮側の圧力差に起因する力が、膜エレメントの供給側から濃縮側の向きに作用し、この力を濃縮側に設けられているテレスコープ防止部材で支持して、分離膜ユニットがテレスコープ現象を起こすのを防止する。   Telescope prevention members are provided at both ends of the separation membrane unit, and FRP (exterior material) is wound around the outer periphery of the separation membrane unit. During operation, the force due to the pressure difference between the supply side and the concentration side acts from the supply side of the membrane element to the concentration side, and this force is applied to the telescope prevention member provided on the concentration side. Supporting and preventing the separation membrane unit from causing the telescope phenomenon.

膜エレメント同士を直列に連結する場合、カプラーが中心管に内挿されて両者は接続される。カプラーの両端付近の外周には、環状の溝が設けられ、これに保持されたOリングが、中心管の内周面にそれぞれ当接している。しかし、膜エレメント同士は固定されていないため、運転の起動時および停止時には、相互に軸方向に相対変位を生じ易く、Oリングが摩耗劣化してリークの原因となる。   When membrane elements are connected in series, a coupler is inserted into the central tube and the two are connected. An annular groove is provided on the outer periphery in the vicinity of both ends of the coupler, and O-rings held in the groove are in contact with the inner peripheral surface of the central tube. However, since the membrane elements are not fixed to each other, when the operation is started and stopped, relative displacement tends to occur in the axial direction, and the O-ring wears out and causes leakage.

これを防止するため、特許文献1には、中心管の端部の突き合わせ面にOリングを保持すると共に、テレスコープ防止部材(キャップ)のハブに係合部を設けて、膜エレメント同士を締め付けることでOリングを圧縮可能な膜エレメントの連結構造が開示されている。   In order to prevent this, in Patent Document 1, an O-ring is held on the abutting surface of the end portion of the central tube, and an engaging portion is provided on a hub of a telescope prevention member (cap) to tighten membrane elements together. Thus, a connection structure of membrane elements capable of compressing an O-ring is disclosed.

また、特許文献2には、留め金を用いて隣接するテレスコープ防止部材同士を連結する構造、特許文献3には、隣接するテレスコープ防止部材に係合部を形成することで両者を連結する構造、特許文献4には、隣接するテレスコープ防止部材の外周溝を利用して、両者の外周溝に跨がるシール部材によって両者を連結する構造が記載されている。このように、何れの従来技術も、隣接するテレスコープ防止部材を利用して、隣接する膜エレメントを連結する構造を採用していた。   Patent Document 2 discloses a structure in which adjacent telescope preventing members are connected to each other by using a clasp, and Patent Document 3 connects both by forming an engaging portion on the adjacent telescope preventing member. Structure, Patent Document 4 describes a structure in which the outer peripheral grooves of adjacent telescope prevention members are used to connect the two by a seal member straddling both outer peripheral grooves. As described above, any of the conventional techniques employs a structure in which adjacent membrane elements are connected using adjacent telescope prevention members.

特表2004−536703号公報JP-T-2004-536703 特表2007−517661号公報Special table 2007-517661 特開2007−190547号公報JP 2007-190547 A 特開2009−226395号公報JP 2009-226395 A

しかしながら、通常、テレスコープ防止部材は樹脂製であるため、それを利用した固定方法では、強度に限界がある。例えば、6本〜7本の膜エレメントを連結した状態で、圧力容器への装填のために吊り上げる場合、強度が不足する恐れがあった。さらに膜エレメントが16インチなどに大型化すると、強度不足の懸念は増大する。   However, since the telescope prevention member is usually made of resin, the fixing method using the telescope prevention member has a limit in strength. For example, when 6 to 7 membrane elements are connected and lifted for loading into a pressure vessel, the strength may be insufficient. Further, when the membrane element is enlarged to 16 inches or the like, the concern about insufficient strength increases.

上記のように、膜エレメントの大型化(口径8インチ→16インチ)に伴い、重量の大幅な増加により、圧力容器への装填方式も変更が検討されている。従来は、横置きにした圧力容器内を滑らせて1本ずつ装填していたものを、重量の大幅増加により押し込むことが困難になったため、例えば、圧力容器を縦置きにして、1本ずつ上方から装填する方法や、複数の膜エレメントを連結後、クレーンで吊り上げて一気に縦方向に装填する方法が検討されている。そのため、膜エレメントを連結して吊り上げる重量に耐え得る膜エレメントの連結方法が望まれている。また、クレーンで吊り上げる際に、曲げ方向の強度も要求される。   As described above, with an increase in the size of the membrane element (caliber 8 inches → 16 inches), a change in the method of loading the pressure vessel is also being considered due to a significant increase in weight. Conventionally, it has become difficult to push what was loaded one by one in a horizontally placed pressure vessel due to a significant increase in weight. A method of loading from above or a method of connecting a plurality of membrane elements and then lifting them with a crane and loading them in the vertical direction at a stretch have been studied. Therefore, there is a demand for a method for connecting membrane elements that can withstand the weight of connecting and lifting membrane elements. Moreover, when it lifts with a crane, the intensity | strength of a bending direction is also requested | required.

これに対して、特許文献1〜4に記載された連結構造では、数百kgレベルの加重に耐え得るものではなく、また、公報に開示された範囲内で加重に耐え得る設計としたとしても、連結時の方法や形態が煩雑(ねじ込む必要や、複数の止め具を用いる必要がある。)であり、手間がかかるという問題があった。   On the other hand, the connection structures described in Patent Documents 1 to 4 do not withstand a load of several hundred kg level, and may be designed to withstand the load within the range disclosed in the publication. The method and form at the time of connection are complicated (need to be screwed or use a plurality of fasteners), and there is a problem that it takes time and effort.

そこで、本発明の目的は、連結時の方法や形態が煩雑でなく、中心管を利用して強固に膜エレメント同士を連結することができる連結構造を有するスパイラル型膜モジュールを提供することにある。   Accordingly, an object of the present invention is to provide a spiral membrane module having a connection structure in which membrane elements are not complicated and the membrane element can be firmly connected using a central tube. .

上記目的は、下記の如き本発明により達成できる。
即ち、本発明のスパイラル型膜モジュールは、スパイラル型の膜エレメントが複数直列に連結されて、圧力容器内に収容されているスパイラル型膜モジュールにおいて、前記膜エレメントは、テレスコープ防止部材から延設されて外周に係合部を有する中心管を備えると共に、隣接する膜エレメントの前記係合部に跨がって両方の係合部に係合する連結部材を設けたことを特徴とする。本発明において、「テレスコープ防止部材」とは、運転時の下流側に設けられるものに限らず、上流側に設けられるものも包含し、膜部を両端から支持する部材を指す。
The above object can be achieved by the present invention as described below.
That is, the spiral membrane module of the present invention is a spiral membrane module in which a plurality of spiral membrane elements are connected in series and accommodated in a pressure vessel. The membrane element extends from a telescope prevention member. In addition, a center tube having an engaging portion on the outer periphery is provided, and a connecting member that engages with both engaging portions is provided across the engaging portions of adjacent membrane elements. In the present invention, the “telescope prevention member” is not limited to a member provided on the downstream side during operation, but also includes a member provided on the upstream side and refers to a member that supports the membrane portion from both ends.

本発明のスパイラル型膜モジュールによると、中心管がテレスコープ防止部材から延設されて外周に係合部を有し、隣接する膜エレメントの前記係合部に跨がって両方の係合部に係合する連結部材を設けたため、連結部材の装着により、連結時の方法や形態が煩雑とならずに、中心管を利用して強固に膜エレメント同士を連結することができる。   According to the spiral membrane module of the present invention, the central tube extends from the telescope prevention member and has an engaging portion on the outer periphery, and both engaging portions straddle the engaging portion of the adjacent membrane element. Since the connecting member that engages is provided, the membrane element can be firmly connected to each other by using the central tube without complicating the method and form during connection by mounting the connecting member.

上記において、前記連結部材は、前記膜エレメントとほぼ同じ外径を有する外周部と、その内側に配され液体の流通を可能にする中間部と、前記中心管とほぼ同じ内径を有する内周部とを有すると共に、前記内周部の内面側に前記係合部と係合する係合部を設けてあることが好ましい。   In the above, the connecting member includes an outer peripheral portion having substantially the same outer diameter as the membrane element, an intermediate portion disposed on the inner side thereof to allow liquid flow, and an inner peripheral portion having substantially the same inner diameter as the central tube. It is preferable that an engaging portion that engages with the engaging portion is provided on the inner surface side of the inner peripheral portion.

この構成によると、連結部材の中間部により上流側から下流側への液体の流通を確保しながら、膜エレメント同士を連結・固定することができる。また、連結部材の外周部が膜エレメントのテレスコープ防止部材間に介在することによって、より強固な連結構造とすることができる。特に、連結部材の外周部の軸方向長さが、膜エレメントのテレスコープ防止部材間の距離と殆ど同じである場合には、連結状態における曲げ方向の強度を向上させることができる。   According to this configuration, the membrane elements can be connected and fixed while securing the flow of the liquid from the upstream side to the downstream side by the intermediate portion of the connecting member. Further, the outer peripheral portion of the connecting member is interposed between the telescopic prevention members of the membrane element, whereby a stronger connecting structure can be obtained. In particular, when the axial length of the outer peripheral portion of the connecting member is almost the same as the distance between the telescopic preventing members of the membrane element, the strength in the bending direction in the connected state can be improved.

また、前記中心管の係合部は、前記中心管の周方向に連続的又は断続的に設けられた溝であることが好ましい。この構成により、テレスコープ防止部材の装着に支障がなく、中心管のみの改変で、連結部材による膜エレメントの連結が可能となる。また、中心管の周方向に連続的又は断続的に設けることで、膜エレメント同士の相対回転を可能にしたり、あるいは相対回転を防止することができる。   Moreover, it is preferable that the engaging part of the center tube is a groove provided continuously or intermittently in the circumferential direction of the center tube. With this configuration, there is no hindrance to the installation of the telescope prevention member, and the membrane element can be connected by the connecting member by modifying only the central tube. Moreover, by providing continuously or intermittently in the circumferential direction of the central tube, relative rotation between the membrane elements can be made possible, or relative rotation can be prevented.

また、前記中心管及び連結部材は、金属製であることが好ましい。両者を金属製にすることで、より強固に膜エレメントを連結することが可能となる。   The center tube and the connecting member are preferably made of metal. By making both of them metal, it becomes possible to connect the membrane elements more firmly.

また、前記連結部材は、複数に分割可能な本体部を有し、その本体部が螺合により締結可能な構造を有することが好ましい。この構成により、簡易な手法によって、より強固に膜エレメントを連結することが可能となる。   Moreover, it is preferable that the said connection member has a main-body part which can be divided | segmented into plurality, and the main-body part has a structure which can be fastened by screwing. With this configuration, the membrane elements can be more firmly connected by a simple method.

更に、前記テレスコープ防止部材は、外周に環状部を有すると共に、前記連結部材は、前記膜エレメントが連結された状態で、前記テレスコープ防止部材の環状部の端面と、前記連結部材の外周部の端面が当接していることが好ましい。これによって、テレスコープ防止部材を改変することなく、膜エレメント同士が連結した状態における曲げ方向の強度をより向上させることができる。   Further, the telescope prevention member has an annular portion on the outer periphery, and the connection member is connected to the end surface of the annular portion of the telescope prevention member and the outer periphery of the connection member in a state where the membrane element is connected. It is preferable that the end surfaces of these are in contact. Thereby, the strength in the bending direction in a state where the membrane elements are connected to each other can be further improved without modifying the telescope prevention member.

本発明のスパイラル型膜モジュールの一例の要部を示す図であり、(a)は連結構造を示す縦断面図、(b)はその連結部材の一部破断面を示す側面図It is a figure which shows the principal part of an example of the spiral-type membrane module of this invention, (a) is a longitudinal cross-sectional view which shows a connection structure, (b) is a side view which shows the partially broken surface of the connection member. 本発明のスパイラル型膜モジュールの中心管の他の例を示す、一部断面を示した正面図The front view which showed the partial cross section which shows the other example of the center pipe | tube of the spiral membrane module of this invention 本発明のスパイラル型膜モジュールの連結部材の他の例を示す側面図The side view which shows the other example of the connection member of the spiral membrane module of this invention 本発明のスパイラル型膜モジュールの係合部の他の例を示す縦断面図The longitudinal cross-sectional view which shows the other example of the engaging part of the spiral membrane module of this invention

以下、本発明の実施の形態について、図面を参照しながら説明する。本発明のスパイラル型膜モジュールは、スパイラル型の膜エレメントEが複数直列に連結されて、圧力容器(図示省略)内に収容されているものである。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the spiral membrane module of the present invention, a plurality of spiral membrane elements E are connected in series and accommodated in a pressure vessel (not shown).

本発明のスパイラル型膜モジュールは、図1(a)に示すように、膜エレメントEが、テレスコープ防止部材4から延設されて外周に係合部3aを有する中心管3を備えると共に、隣接する膜エレメントEの係合部3aに跨がって両方の係合部3aに係合する連結部材10を設けたことを特徴とする。   In the spiral membrane module of the present invention, as shown in FIG. 1A, the membrane element E includes a central tube 3 that extends from the telescope prevention member 4 and has an engagement portion 3a on the outer periphery, and is adjacent to the membrane tube E. A connecting member 10 is provided to engage with both engaging portions 3a across the engaging portion 3a of the membrane element E to be performed.

スパイラル型の膜エレメントEは、有孔の中心管3のまわりに膜と流路材が多層に巻き付けられたものであり、中心管3が外周に係合部3aを有すること以外は、従来公知の膜エレメントEと同様である。圧力容器(ベッセル)についても、従来公知のものと同様のものが使用可能である。   The spiral type membrane element E is a conventionally known one except that a membrane and a flow path material are wound around a perforated center tube 3 in a multilayer manner, and the center tube 3 has an engaging portion 3a on the outer periphery. This is the same as the membrane element E. The same pressure vessel (vessel) as that conventionally known can be used.

膜エレメントEの例としては、膜と流路材とからなる分離膜ユニット2が有孔の中心管3の周囲に巻回した構造を有する。分離膜ユニット2は、例えば、二つ折りにした分離膜の間に供給側流路材を配置した構成の膜リーフと透過側流路材とを交互に重ねた構造を有する。かかる膜エレメントEは、従来公知の分離膜、透過側流路材、供給側流路材、中心管3などを何れも採用できる。   An example of the membrane element E has a structure in which a separation membrane unit 2 composed of a membrane and a channel material is wound around a perforated central tube 3. The separation membrane unit 2 has a structure in which, for example, a membrane leaf and a permeation-side flow channel material having a configuration in which a supply-side flow channel material is disposed between two folded separation membranes are alternately stacked. As the membrane element E, any of conventionally known separation membranes, permeation side flow path materials, supply side flow path materials, the central tube 3 and the like can be adopted.

例えば、供給側流路材と透過側流路材が複数用いられる場合には、複数の膜リーフが中心管3の周りに巻き付けられた構造となる。膜エレメントEの外周側には、外装材としての繊維補強樹脂であるFRP1が形成されている。また、膜エレメントEは、複数個連結されて圧力容器内に収容されている。   For example, when a plurality of supply side flow path materials and permeation side flow path materials are used, a structure in which a plurality of membrane leaves are wound around the central tube 3 is obtained. On the outer peripheral side of the membrane element E, FRP1, which is a fiber reinforced resin as an exterior material, is formed. A plurality of membrane elements E are connected and accommodated in the pressure vessel.

図1(a)に示すように、分離膜ユニット2の両側端部には、テレスコープ防止部材4が設けられている。テレスコープ防止部材4は、膜エレメントEがテレスコープ状に変形することを防止する。テレスコープ防止部材4には、中心管3の貫通が可能な貫通孔が設けられており、中心管3がその貫通孔に嵌入されている。また、テレスコープ防止部材4には、その貫通孔を中心にしてハブ板4aが放射状に設けられている。   As shown in FIG. 1A, telescope prevention members 4 are provided at both end portions of the separation membrane unit 2. The telescope prevention member 4 prevents the membrane element E from being deformed into a telescope shape. The telescope prevention member 4 is provided with a through hole through which the central tube 3 can penetrate, and the central tube 3 is fitted into the through hole. Further, the telescope preventing member 4 is provided with hub plates 4a radially around the through hole.

また、分離膜ユニット2の上流側に設けられるテレスコープ防止部材4の外周には、環状溝が設けられ、圧力容器と膜エレメントEとの間の間隙をシールする環状のシール部材6が把持されている。シール部材6は、周方向に延びる環状であり、外周側に突出して圧力容器の内壁に密着した状態となる。圧力容器に確実に密着させるため、シール部材6の材質としては、弾性体であることが好ましい。   An annular groove is provided on the outer periphery of the telescope prevention member 4 provided on the upstream side of the separation membrane unit 2, and an annular seal member 6 that seals the gap between the pressure vessel and the membrane element E is gripped. ing. The seal member 6 has an annular shape extending in the circumferential direction, and protrudes toward the outer peripheral side to be in close contact with the inner wall of the pressure vessel. In order to ensure close contact with the pressure vessel, the material of the seal member 6 is preferably an elastic body.

隣接する中心管3の内部には、カプラー9が内挿されていてもよい。カプラー9は、通常、樹脂製又は金属製である。   A coupler 9 may be inserted in the adjacent central tube 3. The coupler 9 is usually made of resin or metal.

カプラー9の両端付近の外周には、環状の溝が設けられ、これにOリング9aが保持され、中心管3の内周面にそれぞれ当接している。このOリング9aにより、透過液と濃縮液との混合を防止することができる。   An annular groove is provided on the outer periphery in the vicinity of both ends of the coupler 9, and an O-ring 9 a is held in the groove and is in contact with the inner peripheral surface of the center tube 3. The O-ring 9a can prevent the permeated liquid and the concentrated liquid from being mixed.

テレスコープ防止部材4には、段差部4bが設けられており、段差部4bと分離膜ユニット2とをFRP1で巻き付けることにより、テレスコープ防止部材4が膜エレメントEに固定されている。これにより、中心管3と分離膜ユニット2とテレスコープ防止部材4を一体化させている。   The telescope prevention member 4 is provided with a step 4b, and the telescope prevention member 4 is fixed to the membrane element E by winding the step 4b and the separation membrane unit 2 with the FRP1. Thereby, the central tube 3, the separation membrane unit 2, and the telescope prevention member 4 are integrated.

中心管3は、テレスコープ防止部材4から延設されており、中心管3同士を当接させた状態で、対向するテレスコープ防止部材4同士は、離間した状態となる。中心管3の延設された部分の外周には、係合部3aを有している。本実施形態では、図1に示すように、係合部3aが、中心管3の周方向に連続的に設けられた溝である例を示す。   The center tube 3 is extended from the telescope prevention member 4, and the telescope prevention members 4 facing each other are in a separated state in a state where the center tubes 3 are in contact with each other. An engaging portion 3 a is provided on the outer periphery of the extended portion of the central tube 3. In the present embodiment, as shown in FIG. 1, an example is shown in which the engaging portion 3 a is a groove provided continuously in the circumferential direction of the central tube 3.

係合部3aを構成する溝は、複数条を設けることも可能である。溝の断面は、連結部材10の装着のし易さの観点から、外周側に拡がるテーパ形状であることが好ましい。テーパ形状の軸芯に対する法線方向からの傾斜角度は、5〜45°が好ましい。   A plurality of grooves can be provided in the groove constituting the engaging portion 3a. The cross section of the groove is preferably a tapered shape that expands to the outer peripheral side from the viewpoint of easy attachment of the connecting member 10. The inclination angle from the normal direction to the taper-shaped axis is preferably 5 to 45 °.

係合部3aの大きさは必要とする荷重耐性に応じて設計すればよいが、例えば係合部3aを構成する溝の深さは、中心管3の厚みの20〜50%が好ましい。また、溝の底面の幅は、3〜10mmが好ましい。円柱形凹部で係合部3aを形成する場合、例えば、直径5〜10mm、深さ2〜5mm程度の円柱形凹部を4〜8個程度、外周面に円周方向一列に設ける方法が挙げられる。   The size of the engaging portion 3a may be designed according to the required load resistance. For example, the depth of the groove constituting the engaging portion 3a is preferably 20 to 50% of the thickness of the central tube 3. The width of the bottom surface of the groove is preferably 3 to 10 mm. When forming the engaging part 3a with a cylindrical recessed part, the method of providing about 4-8 cylindrical recessed parts with a diameter of about 5-10 mm and a depth of about 2-5 mm, and providing a circumferential direction line in an outer peripheral surface is mentioned, for example. .

中心管3の材質としては、従来と同等のFRPや、繊維強化プラスチックなどの樹脂製や、ステンレス鋼(SUS304、SUS316など)やチタン合金などなどの金属製のものを用いることができ、特に限定されるものではない。但し、耐荷重性が高いという点で、繊維強化プラスチックや金属製のものを好ましく用いることができる。また、用いる流体に対して腐食性の低いものを用いることが好ましい。   As the material of the center tube 3, it is possible to use FRP equivalent to the conventional material, resin such as fiber reinforced plastic, or metal such as stainless steel (SUS304, SUS316, etc.) or titanium alloy. Is not to be done. However, a fiber reinforced plastic or metal can be preferably used in terms of high load resistance. Moreover, it is preferable to use a thing with low corrosivity with respect to the fluid to be used.

連結部材10は、図1に示すように、隣接する膜エレメントEの係合部3aに跨がって、両方の係合部3aに係合する係合部13aを有する。本実施形態では、膜エレメントEとほぼ同じ外径を有する外周部11と、その内側に配され液体の流通を可能にする中間部12と、中心管3とほぼ同じ内径を有する内周部13とを有する連結部材10が、内周部13の内面側に係合部13aを有する例を示す。   As shown in FIG. 1, the connecting member 10 has an engaging portion 13 a that engages with both engaging portions 3 a across the engaging portions 3 a of adjacent membrane elements E. In the present embodiment, an outer peripheral portion 11 having substantially the same outer diameter as that of the membrane element E, an intermediate portion 12 that is arranged on the inner side thereof and allows a liquid to flow, and an inner peripheral portion 13 that has substantially the same inner diameter as the central tube 3 An example in which the connecting member 10 having the above has an engaging portion 13 a on the inner surface side of the inner peripheral portion 13 is shown.

連結部材10の係合部13aは、中心管3の係合部3aと係合可能であれば、何れの構造でもよく、内周面の周方向に連続的又は断続的に設けられた凸条又はその他の凸部が挙げられる。本実施形態では、連結部材10の係合部13aが連続的に設けられた凸条である例を示す。   The engaging portion 13a of the connecting member 10 may have any structure as long as it can engage with the engaging portion 3a of the central tube 3, and is provided with a ridge provided continuously or intermittently in the circumferential direction of the inner peripheral surface. Or other convex parts are mentioned. In the present embodiment, an example is shown in which the engaging portion 13a of the connecting member 10 is a ridge provided continuously.

図示した例では、連結部材10の内周部13が、円筒状に形成され、その内周面の両端部に各々凸条(リブ)を有している。係合部13aを構成する凸条は、中心管3の係合部3aを構成する溝と同様に、外周側に拡がるテーパ形状の断面を有することが好ましい。   In the illustrated example, the inner peripheral portion 13 of the connecting member 10 is formed in a cylindrical shape, and has protrusions (ribs) at both ends of the inner peripheral surface. The ridges constituting the engaging portion 13a preferably have a taper-shaped cross section extending to the outer peripheral side, like the grooves constituting the engaging portion 3a of the central tube 3.

中間部12は、液体の流通を可能にするものであれば、何れの形状でもよいが、テレスコープ防止部材4に一般的に採用されているような、放射状のハブ板、スポーク、多孔板、などが採用できる。   The intermediate portion 12 may have any shape as long as it allows liquid to flow, but a radial hub plate, spoke, perforated plate, etc., which are generally employed for the telescope prevention member 4, Etc. can be adopted.

外周部11は、ほぼ円筒状に形成され、対角の位置に、分割構造を締結するための締結部を有していてもよい。外周部11は、膜エレメントEが連結された状態で、外周に環状部を有するテレスコープ防止部材4に対して、自身の端面11cが当接する形状が好ましい。つまり、テレスコープ防止部材4から延設された部分の中心管3の長さの合計と、連結部材10の軸芯方向の幅とが、ほぼ同じであることが好ましい。   The outer peripheral part 11 is formed in a substantially cylindrical shape, and may have a fastening part for fastening the split structure at a diagonal position. The outer peripheral portion 11 preferably has a shape in which its own end surface 11c abuts against the telescope prevention member 4 having an annular portion on the outer periphery in a state where the membrane element E is connected. That is, it is preferable that the total length of the central tube 3 in the portion extending from the telescope prevention member 4 and the width of the connecting member 10 in the axial direction are substantially the same.

本発明では、連結部材10が、複数に分割可能な本体部を有することが好ましい。図示した例は、2分割のタイプが示されているが、更に多数に分割可能な構造であってもよい。また、分割状態からの形状の復元を容易にするために、本体部に対して、ヒンジ部などを設けて、枢支可能な構造にしてもよい(図3(a)参照)。   In this invention, it is preferable that the connection member 10 has a main-body part which can be divided | segmented into plurality. In the illustrated example, a two-divided type is shown, but a structure that can be divided into a larger number may be used. Further, in order to facilitate the restoration of the shape from the divided state, a hinge portion or the like may be provided on the main body portion so that it can be pivotally supported (see FIG. 3A).

連結部材10は、その本体部が螺合により締結可能な構造を有することが好ましい。図示した例は、2本のボルト14によって締結可能な構造とした例である。一方の外周部11には、ボルト14を挿通できる貫通穴11aを有し、他方の外周部11には、ボルト14を螺合できる螺子切部11bを有している。   It is preferable that the connection member 10 has a structure in which the main body portion can be fastened by screwing. The illustrated example is an example of a structure that can be fastened by two bolts 14. One outer peripheral portion 11 has a through hole 11a through which the bolt 14 can be inserted, and the other outer peripheral portion 11 has a screw cut portion 11b into which the bolt 14 can be screwed.

連結部材10の材質は、膜エレメントEを連結した状態で荷重に耐え得るものであれば特に限定されるものではないが、中心管3と同様に、樹脂製や金属製のものを用いることができる。特に、耐荷重性および締結部品(固定ネジ部など)との耐磨耗性の点を考慮すると、金属製のものを用いることが好ましい。金属のうち、流体によって腐食が生じにくい金属であるステンレスやチタン合金などがより好ましい。   The material of the connecting member 10 is not particularly limited as long as the material can withstand the load in a state where the membrane element E is connected. However, like the central tube 3, a resin or metal material may be used. it can. In particular, in view of load resistance and wear resistance with a fastening part (fixed screw portion or the like), it is preferable to use a metal one. Among metals, stainless steel, titanium alloy, and the like that are difficult to be corroded by a fluid are more preferable.

分割した連結部材10は、隣接する膜エレメントEの中心管3を突き合わせた状態で、その係合部3aに自身の係合部13aを位置させるようにして、外周に装着され、2本のボルト14によって、連結部材10の本体部が締結される。   The divided connecting member 10 is attached to the outer periphery so that its engaging portion 13a is positioned in its engaging portion 3a in a state where the central tube 3 of the adjacent membrane element E is abutted, and two bolts 14, the main body of the connecting member 10 is fastened.

膜エレメントEが連結した状態では、連結部材10により中心管3同士が連結されるため、軸芯方向の引っ張り強度が高くなる。このため、例えば複数の膜エレメントを連結後、クレーンで吊り上げて一気に圧力容器内に縦方向に装填する方法を採用する際に、吊り上げ重量(数百kgレベルも可能)に十分耐えることができる。また、連結部材10の端面がテレスコープ防止部材4と当接する構造である場合には、クレーンで吊り上げる際に、曲げ方向の強度も向上するため、吊り上げにより適した形態となる。   In the state where the membrane element E is connected, the central pipes 3 are connected to each other by the connecting member 10, so that the tensile strength in the axial direction is increased. For this reason, for example, when a method of connecting a plurality of membrane elements and then lifting them with a crane and loading them in the pressure vessel at once in the vertical direction can sufficiently withstand the lifting weight (a level of several hundred kg is also possible). In addition, when the end surface of the connecting member 10 is in contact with the telescope prevention member 4, the strength in the bending direction is improved when the crane 10 is lifted by a crane.

[他の実施形態]
(1)前述の実施形態では、中心管3の係合部3aが、中心管3の周方向に連続的に設けられた溝である例を示したが、中心管3の係合部3aは、凸部として形成されていてもよい。例えば、中心管3の外周面の周方向に連続的又は断続的に設けられた凸条又はその他の凸部が挙げられる。その場合、連結部材10の係合部13aとしては、その内周面の周方向に連続的又は断続的に設けられた溝などが挙げられる。
[Other Embodiments]
(1) In the above-described embodiment, the example in which the engaging portion 3a of the central tube 3 is a groove continuously provided in the circumferential direction of the central tube 3 has been described, but the engaging portion 3a of the central tube 3 is Further, it may be formed as a convex portion. For example, the protruding item | line or other convex part provided continuously or intermittently in the circumferential direction of the outer peripheral surface of the center pipe 3 is mentioned. In that case, as the engaging part 13a of the connection member 10, the groove | channel etc. which were provided continuously or intermittently in the circumferential direction of the internal peripheral surface are mentioned.

また、中心管3の係合部3aは、図2(a)に示すように、開口部の形状が、円形又は楕円形である凹部であってもよい。その場合、連結部材10の係合部13aとしては、円形又は楕円形である凸部が挙げられる。このような凹部は、連結時の強度を高める上で、周方向に複数設けるのが好ましい。   Further, as shown in FIG. 2A, the engaging portion 3a of the central tube 3 may be a concave portion in which the shape of the opening is circular or elliptical. In that case, as the engaging portion 13a of the connecting member 10, a convex portion that is circular or elliptical can be mentioned. In order to increase the strength at the time of connection, it is preferable to provide a plurality of such recesses in the circumferential direction.

また、中心管3の係合部3aを溝として形成する場合、図2(b)に示すように、その断面が三角形、四角形、半円などでもよい。但し、連結時の強度を高める上で、係合部3aの端部側には、軸芯方向に垂直な係合面を有することが好ましい。その場合、連結部材10の係合部13aの中央側にも、軸芯方向に垂直な係合面を有することが好ましい。   Further, when the engaging portion 3a of the central tube 3 is formed as a groove, as shown in FIG. 2B, the cross section may be a triangle, a quadrangle, a semicircle, or the like. However, in order to increase the strength at the time of connection, it is preferable to have an engaging surface perpendicular to the axial direction on the end side of the engaging portion 3a. In that case, it is preferable that the center side of the engaging portion 13a of the connecting member 10 also has an engaging surface perpendicular to the axial direction.

また、図2(c)に示すように、中心管3の係合部3aを構成する溝を、外周面の周方向に断続的に設けてもよい。その場合、連結部材10の係合部13aを、同じパターンの凸条を形成することにより、膜エレメントE同士の相対回転を抑制することができる。膜エレメントE同士の相対回転を抑制することで、クレーンによる吊り上げをより安全に行うことができる。   Moreover, as shown in FIG.2 (c), you may provide the groove | channel which comprises the engaging part 3a of the center pipe | tube 3 intermittently in the circumferential direction of an outer peripheral surface. In that case, the relative rotation between the membrane elements E can be suppressed by forming the protrusions having the same pattern on the engaging portion 13a of the connecting member 10. By suppressing the relative rotation between the membrane elements E, lifting by a crane can be performed more safely.

(2)前述の実施形態では、外周部11と中間部12と内周部13とを有する連結部材10の例を示したが、連結部材10の構造は、係合部3aに跨がって両方の係合部3aに係合するものであれば、何れの構造でもよい。   (2) In the above-described embodiment, the example of the connecting member 10 having the outer peripheral portion 11, the intermediate portion 12, and the inner peripheral portion 13 has been shown. However, the structure of the connecting member 10 straddles the engaging portion 3a. Any structure may be used as long as it engages both engaging portions 3a.

例えば、図3(a)に示すように、中心管3の外周に装着される環状部に、中心管3の係合部3aに係合する係合部10aを有するような構造でもよい。この例では、一端に設けたヒンジ部15に連結された本体部が、装着時に分割可能であり、本体部の他端にボルト14を挿通する貫通孔を有する締結部を有する構造となっている。貫通孔に挿通したボルト14とナット16によって、本体部が締結される。   For example, as shown to Fig.3 (a), the structure which has the engaging part 10a engaged with the engaging part 3a of the center pipe 3 in the cyclic | annular part with which the outer periphery of the center pipe 3 is mounted | worn may be sufficient. In this example, the main body connected to the hinge portion 15 provided at one end can be divided at the time of mounting, and has a structure having a fastening portion having a through hole through which the bolt 14 is inserted at the other end of the main body. . The main body is fastened by the bolts 14 and the nuts 16 inserted through the through holes.

また、環状の連結部材10に代えて、U字形状やC字形状の連結部材10とすることで、軸芯の法線方向から、連結部材10をはめ込んで、係合部3aと係合部10aとを係合させることも可能である。その場合、連結部材10は弾性変形可能な金属(バネ鋼など)を用いることが好ましい。   Moreover, it replaces with the cyclic | annular connection member 10, and it is set as the U-shaped or C-shaped connection member 10, By inserting the connection member 10 from the normal line direction of an axial center, the engaging part 3a and the engaging part It is also possible to engage with 10a. In that case, the connecting member 10 is preferably made of an elastically deformable metal (spring steel or the like).

(3)前述の実施形態では、連結部材10の外周部11に、分割可能な本体部をボルト14で締結するための締結部を設けた例を示したが、締結の方式や、締結部を設ける位置は何れでもよい。   (3) In the above-described embodiment, the example in which the fastening part for fastening the separable main body part with the bolt 14 is provided on the outer peripheral part 11 of the connecting member 10 is shown. Any position may be provided.

例えば、図3(b)に示すように、連結部材10の内周部13に、ボルト14を螺合できる螺子切部13bを設けてもよい。また、図3(c)に示すように、更に多くのボルト14で締結できるように、連結部材10の外周部11及び内周部13に、螺子切部11b,13bを設けてもよい。   For example, as shown in FIG. 3B, a screw cutting portion 13 b that can screw the bolt 14 may be provided on the inner peripheral portion 13 of the connecting member 10. Further, as shown in FIG. 3C, screw cutting portions 11 b and 13 b may be provided on the outer peripheral portion 11 and the inner peripheral portion 13 of the connecting member 10 so as to be fastened with more bolts 14.

締結の方式としては、ネジのほか、クランプ、パッチン錠、分割した連結部材同士の嵌合、ロック機構付きの嵌合、などを用いることができる。   As a fastening method, a screw, a clamp, a patch lock, fitting between divided connecting members, fitting with a lock mechanism, and the like can be used.

(4)前述の実施形態では、中心管3の係合部3aが周方向に連続的又は断続的に設けられた溝である例を示したが、断続的に溝又は凹部を設ける場合、中心管3の周方向の前後に形成される壁面が、径方向より傾斜した外周側に拡がるテーパ形状であることが好ましい。これにより、連結部材10の装着が容易になると共に、膜エレメントE同士の相対回転をより確実に抑制することができる。   (4) In the above-described embodiment, the example in which the engaging portion 3a of the central tube 3 is a groove that is provided continuously or intermittently in the circumferential direction has been shown. It is preferable that the wall surface formed before and behind the circumferential direction of the pipe 3 has a tapered shape that extends to the outer circumferential side inclined from the radial direction. Thereby, the attachment of the connecting member 10 is facilitated, and the relative rotation between the membrane elements E can be more reliably suppressed.

例えば、図4(a)に示すように、単数又は複数の凹部からなる係合部3aを中心管3に設け、これと係合する凸部からなる係合部13aを連結部材10の内周面に設けることが好ましい。   For example, as shown in FIG. 4A, an engaging portion 3a made of one or a plurality of concave portions is provided in the central tube 3, and an engaging portion 13a made of a convex portion engaged with the engaging portion 3a is provided on the inner periphery of the connecting member 10. It is preferable to provide on the surface.

また、図4(b)に示すように、底面が直線状の凹部からなる係合部3aを中心管3に単数又は複数設け、これと係合する凸部からなる係合部13aを連結部材10の内周面に設けることで、同様の効果を得ることができる。   As shown in FIG. 4 (b), the center tube 3 is provided with one or more engaging portions 3a each having a concave portion having a linear bottom surface, and the engaging portion 13a having a convex portion that engages with the engaging portion 3a is a connecting member. The same effect can be obtained by providing it on the inner peripheral surface of 10.

このような連結構造を、外周部11と中間部12と内周部13とを有する連結部材10に適用することも可能である。   Such a connection structure can also be applied to the connection member 10 having the outer peripheral portion 11, the intermediate portion 12, and the inner peripheral portion 13.

1 FRP
2 分離膜ユニット
3 中心管
3a 中心管の係合部
4 テレスコープ防止部材
10 連結部材
10a 連結部材の係合部
11 外周部
11c 外周部の端面
12 中間部
13 内周部
13a 連結部材の係合部
14 ボルト
E 膜エレメント
1 FRP
2 Separation membrane unit 3 Center tube 3a Center tube engaging portion 4 Telescope prevention member 10 Connecting member 10a Connecting member engaging portion 11 Outer peripheral portion 11c End surface of outer peripheral portion 12 Intermediate portion 13 Inner peripheral portion 13a Engaging of connecting member Part 14 Bolt E Membrane element

Claims (6)

スパイラル型の膜エレメントが複数直列に連結されて、圧力容器内に収容されているスパイラル型膜モジュールにおいて、
前記膜エレメントは、テレスコープ防止部材から延設されて外周に係合部を有する中心管を備えると共に、隣接する膜エレメントの前記係合部に跨がって両方の係合部に係合する連結部材を設けたことを特徴とするスパイラル型膜モジュール。
In a spiral membrane module in which a plurality of spiral membrane elements are connected in series and accommodated in a pressure vessel,
The membrane element includes a central tube extending from the telescope prevention member and having an engaging portion on the outer periphery, and engages with both engaging portions across the engaging portion of the adjacent membrane element. A spiral membrane module comprising a connecting member.
前記連結部材は、前記膜エレメントとほぼ同じ外径を有する外周部と、その内側に配され液体の流通を可能にする中間部と、前記中心管とほぼ同じ内径を有する内周部とを有すると共に、前記内周部の内面側に前記係合部と係合する係合部を設けてある請求項1記載のスパイラル型膜モジュール。   The connecting member has an outer peripheral portion having substantially the same outer diameter as that of the membrane element, an intermediate portion that is arranged on the inner side thereof and allows a liquid to flow, and an inner peripheral portion having substantially the same inner diameter as that of the central tube. The spiral membrane module according to claim 1, further comprising an engaging portion that engages with the engaging portion on an inner surface side of the inner peripheral portion. 前記中心管の係合部は、前記中心管の周方向に連続的又は断続的に設けられた溝である請求項1又は2に記載のスパイラル型膜モジュール。   The spiral membrane module according to claim 1 or 2, wherein the engaging portion of the central tube is a groove provided continuously or intermittently in a circumferential direction of the central tube. 前記中心管及び連結部材は、金属製である請求項1〜3いずれかに記載のスパイラル型膜モジュール。   The spiral membrane module according to claim 1, wherein the central tube and the connecting member are made of metal. 前記連結部材は、複数に分割可能な本体部を有し、その本体部が螺合により締結可能な構造を有する請求項1〜4いずれかに記載のスパイラル型膜モジュール。   The spiral membrane module according to any one of claims 1 to 4, wherein the connecting member has a main body part that can be divided into a plurality of parts, and the main body part has a structure that can be fastened by screwing. 前記テレスコープ防止部材は、外周に環状部を有すると共に、
前記連結部材は、前記膜エレメントが連結された状態で、前記テレスコープ防止部材の環状部の端面と、前記外周部の端面が当接している請求項2〜5いずれかに記載のスパイラル型膜モジュール。
The telescope prevention member has an annular portion on the outer periphery,
The spiral membrane according to any one of claims 2 to 5, wherein the connecting member is in contact with the end surface of the annular portion of the telescope prevention member and the end surface of the outer peripheral portion in a state where the membrane element is connected. module.
JP2010212356A 2010-09-22 2010-09-22 Spiral membrane module Pending JP2012066184A (en)

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PCT/JP2011/070622 WO2012039302A1 (en) 2010-09-22 2011-09-09 Spiral membrane module

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US20160256830A1 (en) * 2013-10-03 2016-09-08 Fujifilm Manufacturing Europe Bv Antitelescoping Device and Clamp for Spiral Wound Modules Comprising a Vent
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WO2014051117A1 (en) * 2012-09-28 2014-04-03 富士フイルム株式会社 Separation module, method for producing separation module, tube body, and winding misalignment prevention member
US20160256830A1 (en) * 2013-10-03 2016-09-08 Fujifilm Manufacturing Europe Bv Antitelescoping Device and Clamp for Spiral Wound Modules Comprising a Vent
US9925498B2 (en) * 2013-10-03 2018-03-27 Fujifilm Manufacturing Europe B.V. Antitelescoping device and clamp for spiral wound modules comprising a vent
KR20160122571A (en) * 2015-04-14 2016-10-24 주식회사 엘지화학 Anti-telescoping device for membrane separation device
KR102045100B1 (en) 2015-04-14 2019-11-14 주식회사 엘지화학 Anti-telescoping device for membrane separation device
JP2020025926A (en) * 2018-08-10 2020-02-20 日東電工株式会社 Separation membrane element and separation membrane module
JP7100531B2 (en) 2018-08-10 2022-07-13 日東電工株式会社 Separation Membrane Element and Separation Membrane Module
WO2020067223A1 (en) * 2018-09-26 2020-04-02 東レ株式会社 Fluid separation element
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US20220032236A1 (en) * 2018-09-26 2022-02-03 Toray Industries, Inc. Fluid separation element
EP3858469A4 (en) * 2018-09-26 2022-06-08 Toray Industries, Inc. Fluid separation element

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