JP2012012420A - Ink composition for publishing gravure printing - Google Patents
Ink composition for publishing gravure printing Download PDFInfo
- Publication number
- JP2012012420A JP2012012420A JP2010145015A JP2010145015A JP2012012420A JP 2012012420 A JP2012012420 A JP 2012012420A JP 2010145015 A JP2010145015 A JP 2010145015A JP 2010145015 A JP2010145015 A JP 2010145015A JP 2012012420 A JP2012012420 A JP 2012012420A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- gravure printing
- weight
- ink composition
- antistatic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 238000007646 gravure printing Methods 0.000 title claims abstract description 14
- 239000002216 antistatic agent Substances 0.000 claims abstract description 26
- 239000007787 solid Substances 0.000 claims abstract description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 230000002209 hydrophobic effect Effects 0.000 claims description 7
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- 238000007639 printing Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 235000010724 Wisteria floribunda Nutrition 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- -1 quaternary ammonium salt compound Chemical class 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- WZSFTHVIIGGDOI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[2-methyl-3-[(4,5,6,7-tetrachloro-3-oxoisoindol-1-yl)amino]anilino]isoindol-1-one Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C2=C1C(NC1=CC=CC(NC=3C4=C(C(=C(Cl)C(Cl)=C4Cl)Cl)C(=O)N=3)=C1C)=NC2=O WZSFTHVIIGGDOI-UHFFFAOYSA-N 0.000 description 1
- IYHIFXGFKVJNBB-UHFFFAOYSA-N 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonic acid Chemical compound C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S(O)(=O)=O IYHIFXGFKVJNBB-UHFFFAOYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- REEFSLKDEDEWAO-UHFFFAOYSA-N Chloraniformethan Chemical compound ClC1=CC=C(NC(NC=O)C(Cl)(Cl)Cl)C=C1Cl REEFSLKDEDEWAO-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- VOMZUJSUTZAURW-TXEARYQUSA-N alkali Blue G Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S(O)(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N VOMZUJSUTZAURW-TXEARYQUSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229960001506 brilliant green Drugs 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- UAKOZKUVZRMOFN-JDVCJPALSA-M dimethyl-bis[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CCCCCCCC\C=C/CCCCCCCC UAKOZKUVZRMOFN-JDVCJPALSA-M 0.000 description 1
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- RUAIJHHRCIHFEV-UHFFFAOYSA-N methyl 4-amino-5-chlorothiophene-2-carboxylate Chemical compound COC(=O)C1=CC(N)=C(Cl)S1 RUAIJHHRCIHFEV-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- ROVRRJSRRSGUOL-UHFFFAOYSA-N victoria blue bo Chemical compound [Cl-].C12=CC=CC=C2C(NCC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 ROVRRJSRRSGUOL-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
本発明は、紙(プラスチックフィルム、プラスチックシートを含む)上に被覆させるこ
とにより、基材の表面抵抗値を制御できる出版グラビア印刷用インキ組成物に関する。
The present invention relates to an ink composition for publishing gravure printing which can control the surface resistance value of a substrate by coating on paper (including plastic film and plastic sheet).
出版用グラビア印刷では、静電印刷を行う為、冬場は印刷物に静電気が溜まりやすく、
ページ同士がくっつき易くなる。この影響から、対面するページを読者がめくろうとする
と、読者の目に留まらないページが生じ、通販カタログ等の該当ページ記載商品の売り上
げにも影響がでる等の問題が発生する。
In gravure printing for publishing, electrostatic printing is performed, so static electricity tends to accumulate on printed matter in winter.
The pages can easily stick together. From this influence, when the reader tries to turn the facing page, a page that cannot be seen by the reader is generated, and there is a problem that the sales of the product described in the corresponding page such as a mail-order catalog is affected.
一般的に、静電気障害の対策技術としては、あらかじめ基材に帯電防止剤を練り込むか
、或いは、表面に塗布する方法が実施されている。
In general, as a countermeasure technique against static electricity disturbance, a method in which an antistatic agent is kneaded in advance on a base material or is applied to a surface is carried out.
しかし、従来技術による帯電防止剤の練り込み、塗布法では、表面の帯電抑制効果は出
るものの、帯電防止剤による印刷インキの密着性が劣るようになる。また、インキ塗布量
が多い場合は、帯電抑制効果が不充分であった。その他に、経済的には帯電防止剤の練り
込み工程あるいは塗布工程など、印刷前の工程費用が帯電防止対策のコスト高の要因にな
っている。
However, the kneading and coating method of the antistatic agent according to the prior art has an effect of suppressing the surface charge, but the adhesion of the printing ink by the antistatic agent becomes inferior. Further, when the amount of ink applied was large, the effect of suppressing charging was insufficient. In addition, economically, process costs before printing, such as a kneading process or an application process of an antistatic agent, are a cause of high cost of antistatic measures.
このような欠点を補うものとして、印刷インキ自体に帯電防止剤を付与する方法が発明
されたが、インキ中に添加した場合、インキの安定性が劣り、また塗膜内で帯電防止剤が
不均一となるため、充分な帯電性能を得られなかった。出版グラビア印刷用途のインキお
いては、トルエン単体の溶剤系で構成されているため、親水性基を有する帯電防止剤では
溶解性が不充分であった。さらに、経時で分離、沈殿がし易く、塗布後においても帯電防
止剤が均一にならず、所望するページめくり性が得られないという問題が発生した。
In order to compensate for these drawbacks, a method of applying an antistatic agent to the printing ink itself was invented. However, when added to the ink, the stability of the ink is poor and the antistatic agent is not present in the coating film. Since it became uniform, sufficient charging performance could not be obtained. Ink for publication gravure printing is composed of a solvent system of toluene alone, and therefore, an antistatic agent having a hydrophilic group has insufficient solubility. Furthermore, separation and precipitation easily occur over time, the antistatic agent is not uniform even after coating, and a desired page turning property cannot be obtained.
印刷インキ自体にアルキル基で構成される4級アンモニウム塩型の帯電防止剤を付与す
ることによって、前記課題を解消することを目的とする。
It aims at solving the said subject by providing the quaternary ammonium salt type antistatic agent comprised by an alkyl group to printing ink itself.
本発明は、
硬化ロジンを、インキ全量中、固形分重量比15〜35重量%、
溶剤
および
一般式(1)に示される第四級アンモニウム塩型帯電防止剤を、インキ全量中、固
形分重量比0.5〜3.5重量%
含有することを特徴とする出版グラビア印刷用インキ組成物に関するものである。
一般式(1)
The cured rosin is in a total weight of the ink, and a solid content weight ratio of 15 to 35% by weight,
Solvent and the quaternary ammonium salt type antistatic agent represented by the general formula (1) in the total amount of ink in a solid content weight ratio of 0.5 to 3.5% by weight.
It is related with the ink composition for publication gravure printing characterized by containing.
General formula (1)
また、本発明は、有機ケイ素化合物で表面処理された疎水性シリカを、さらに、インキ
全量中、固形分重量比1〜5重量%含有することを特徴とする上記の出版グラビア印刷用
インキ組成物に関するものである。
The present invention also provides the above-mentioned ink composition for publishing gravure printing, further comprising hydrophobic silica surface-treated with an organosilicon compound, in a total weight ratio of 1 to 5% by weight, based on the solid content. It is about.
本発明は、アルキル基で構成される4級アンモニウム塩化合物を、出版グラビア印刷用
途のインキに含有させることで、帯電防止効果を向上できた。
In the present invention, an antistatic effect can be improved by including a quaternary ammonium salt compound composed of an alkyl group in an ink for publication gravure printing.
本発明における硬化ロジンは、アビチエン酸と2種類以上の金属塩からなり、ロジン金
属塩ともよばれる。硬化ロジンの合成に用いる金属の種類は、マグネシウム、亜鉛、カル
シウムのいずれかからなる。硬化ロジンは、酸価が100以下であることが好ましく、イ
ンキ組成物中に15〜35重量%であることが必要である。15重量%未満であるとドッ
トゲインを抑制するのに十分な粘度を得る事が出来ず、またインキ塗膜中に充分な帯電防
止剤の量を確保できない。35重量%を超えると、インキ粘度が過剰に高くなり流動性が
損なわれ、インキ経時安定性および印刷効果に問題が生じる。さらに、粘度調整用の希釈
量が大幅に増加するため、実質的な帯電防止剤量が減少し、ページめくり性は低下する傾
向にある。
The cured rosin in the present invention is composed of abithienic acid and two or more metal salts, and is also called a rosin metal salt. The type of metal used for the synthesis of the hardened rosin is made of magnesium, zinc, or calcium. The cured rosin preferably has an acid value of 100 or less, and needs to be 15 to 35% by weight in the ink composition. If it is less than 15% by weight, a viscosity sufficient to suppress dot gain cannot be obtained, and a sufficient amount of antistatic agent cannot be ensured in the ink coating film. If it exceeds 35% by weight, the ink viscosity becomes excessively high and the fluidity is impaired, resulting in problems in ink aging stability and printing effect. Further, since the dilution amount for viscosity adjustment is greatly increased, the substantial amount of the antistatic agent is decreased, and the page turning property tends to be decreased.
インキの製造に使用される溶剤としては、通常、印刷インキ用の溶剤としてよく知られ
ている、ベンゼン、トルエン、キシレン等の芳香族炭化水素系溶剤、メタノール、エタノ
ール、イソプロパノール、n-ブタノール等のアルコール系溶剤、アセトン、メチルエチ
ルケトン、メチルイソブチルケトン等のケトン溶剤、酢酸エチル、酢酸ブチル等のエステ
ル系溶剤が挙げられ、これらを単独または2種以上の混合物で用いる。出版グラビア印刷
用途のインキでは、ベンゼン、トルエン、キシレン等の芳香族炭化水素系溶剤が好ましく
、特にトルエンが好ましい。重量部としては、40〜75重量%であることが好ましく、
45〜60重量%であることがより好ましい。
As a solvent used for the production of ink, usually well known as a solvent for printing ink, aromatic hydrocarbon solvents such as benzene, toluene, xylene, methanol, ethanol, isopropanol, n-butanol, etc. Examples include alcohol solvents, ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, and ester solvents such as ethyl acetate and butyl acetate. These are used alone or in a mixture of two or more. In the ink for use in publication gravure printing, aromatic hydrocarbon solvents such as benzene, toluene and xylene are preferable, and toluene is particularly preferable. As a weight part, it is preferable that it is 40 to 75 weight%,
More preferably, it is 45 to 60% by weight.
本発明では、4級アンモニウム塩型帯電防止剤として一般式(1)に示したように炭素
数8〜22のアルキル基を有し、アニオンとしてエトサルフェートを有する帯電防止剤を
使用する。本発明のカチオンにおいては、アルキル基に水酸基、カルボキシル基、アミノ
基等の親水性の官能基を導入すると経時で分離、沈殿がし易く、また印刷時において、当
該帯電防止剤がインキ皮膜表面で不均一となるため、目的とするページめくり性が得られ
ない。また、アニオンがサルフェート以外である場合も同様にページめくり性が不十分で
ある。重量部としては、0.5〜3.5重量%が必要であり、0.5重量%未満であると
ページめくり性の改良効果が不充分であり、3.5重量%を超えるとインキの安定性に問
題が生じる。
In the present invention, an antistatic agent having an alkyl group having 8 to 22 carbon atoms and having ethosulphate as an anion is used as the quaternary ammonium salt type antistatic agent as shown in the general formula (1). In the cation of the present invention, when a hydrophilic functional group such as a hydroxyl group, a carboxyl group, or an amino group is introduced into the alkyl group, it easily separates and precipitates over time, and the antistatic agent is applied to the surface of the ink film during printing. Since it becomes non-uniform, the target page turning property cannot be obtained. Similarly, when the anion is other than sulfate, the page turning property is insufficient. As the part by weight, 0.5 to 3.5% by weight is necessary, and if it is less than 0.5% by weight, the effect of improving the page turning property is insufficient. There is a problem with stability.
本発明に用いるシリカには、親水性シリカと、疎水性処理をしたシリカがあるが、本用
途に使用するシリカは、インキ中での分散安定性を維持するために、疎水性シリカを使用
するのが好ましい。特に、有機ケイ素化合物で処理されたものがより好ましい。このシリ
カの平均粒径は3〜5μmであることが好ましく、平均粒径が3μm未満では、充分なペ
ージめくり性の改良効果を得る為には多量に使用する必要があり、またインキの粘度上昇
の原因となる。平均粒径が5μmを超えると滑り性が向上しページめくり性は得られ易い
が、インキ安定性と塗膜の耐摩擦性および光沢が低下する傾向である。重量部としては、
1〜5重量%を使用するのが好ましい。1重量%未満であると、充分なページめくり性の
改良効果が得られにくく、5重量%を超えると、インキの粘度上昇が顕著に起こり粘度調
整用の希釈量が大幅に増加するため、実質的なシリカ量は減少し、ページめくり性は低下
する傾向にある。市販品の疎水性シリカとしては、のサイロホービックシリーズ(富士シ
リシア化学株式会社)がある。
Silica used in the present invention includes hydrophilic silica and silica subjected to hydrophobic treatment, but silica used in this application uses hydrophobic silica in order to maintain dispersion stability in ink. Is preferred. In particular, those treated with an organosilicon compound are more preferred. The average particle size of the silica is preferably 3 to 5 μm. If the average particle size is less than 3 μm, it is necessary to use a large amount in order to obtain a sufficient effect of improving the page turning property, and the viscosity of the ink is increased. Cause. When the average particle size exceeds 5 μm, the slipping property is improved and the page turning property is easily obtained, but the ink stability, the friction resistance and the gloss of the coating film tend to be lowered. As part by weight,
It is preferred to use 1 to 5% by weight. If it is less than 1% by weight, it is difficult to obtain a sufficient effect of improving the page turning property. If it exceeds 5% by weight, the viscosity of the ink is remarkably increased and the amount of dilution for viscosity adjustment is greatly increased. The amount of silica generally decreases and the page turnability tends to decrease. As a commercially available hydrophobic silica, there is a silo hovic series (Fuji Silysia Chemical Co., Ltd.).
本発明の出版グラビア印刷用インキ組成物は、着色剤を含むことができる。
有機顔料の具体例としては、カーミン6B、レーキレッドC、パーマネントレッド2B
、ジスアゾイエロー、ピラゾロンオレンジ、カーミンFB、クロモフタルイエロー、クロ
モフタルレッド、フタロシアニンブルー、フタロシアニングリーン、ジオキサジンバイオ
レット、キナクリドンマゼンダ、キナクリドンレッド、インダストロンブルー、ピリミジ
ンイエロー、チオインジオボルドー、チオインジゴマゼンタ、ペリレンレッド、ペリノン
オレンジ、イソインドリノンイエロー、アニリンブラック、昼光蛍光顔料等が挙げられる
。
The publication gravure printing ink composition of the present invention may contain a colorant.
Specific examples of organic pigments include Carmine 6B, Lake Red C, and Permanent Red 2B.
, Disazo yellow, pyrazolone orange, carmine FB, chromophthal yellow, chromophthal red, phthalocyanine blue, phthalocyanine green, dioxazine violet, quinacridone magenta, quinacridone red, industron blue, pyrimidine yellow, thioindiobordeaux, thioindigo magenta, perylene Examples thereof include red, perinone orange, isoindolinone yellow, aniline black, and daylight fluorescent pigment.
無機顔料の具体例としては、カーボンブラック、アルミニウム粉、ブロンズ粉、クロム
バーミリオン、黄鉛、カドミウムイエロー、カドミウムレッド、群青、紺藍、ベンガラ、
黄色酸化鉄、鉄黒、酸化チタン、酸化亜鉛等が挙げられる。
また染料の具体例としては、タートラジンレーキ、ローダリン6Gレーキ、ビクトリアピ
ュアブルーレーキ、アルカリブルーGトーナー、ブリリアントグリーンレーキ等が挙げら
れ、この他コールタールも用いることができる。
これらに限定されるものではなく、着色剤を含まなくとも、同等の帯電防止効果が得られ
る。
Specific examples of inorganic pigments include carbon black, aluminum powder, bronze powder, chrome vermilion, chrome lead, cadmium yellow, cadmium red, ultramarine, catalyzed, bengara,
Examples include yellow iron oxide, iron black, titanium oxide, and zinc oxide.
Specific examples of the dye include tartrazine lake, rhodarin 6G lake, Victoria pure blue lake, alkali blue G toner, brilliant green lake and the like, and other coal tars can also be used.
However, the present invention is not limited to these, and an equivalent antistatic effect can be obtained without including a colorant.
また、本発明には、更に、レベリング剤、消泡剤、ワックス、可塑剤、赤外線吸収剤、
紫外線吸収剤、難燃剤及び体質顔料を併用する際の顔料分散剤等の添加剤類も必要に応じ
て使用することができる。
Further, the present invention further includes a leveling agent, an antifoaming agent, a wax, a plasticizer, an infrared absorber,
Additives such as a pigment dispersant used in combination with an ultraviolet absorber, a flame retardant, and an extender pigment can be used as necessary.
本発明を実施例及び比較例により、一層具体的に説明する。以下において、「部」とあ
るものは特に断りのない限り、すべて「重量部」を意味するものとする。
The present invention will be described more specifically with reference to examples and comparative examples. In the following description, “part” means “part by weight” unless otherwise specified.
[製造例1]
(帯電防止剤の製造)
内容積30mlのガラス製容器中に、以下の一般式(2)で表されるN,N-ジオクチルア
ミノメチル基を有するポリスチレン (Argonaut Technologies, 800257, PS-Clに塩
基性条件下でジオクチルアミンを作用させてできた化合物。アミン担持量 1.56 mmol
/ g) 0.70 gをトルエン (6 ml)に懸濁 させ、室温にてゆっくりとジメチル硫酸 (
10.6 mmol, 1.34 g)を滴下した。その後140℃に昇温し9時間攪拌した。反応
溶液を90℃まで下げた後、過剰のジメチル硫酸を処理するため水2 mlを加え、90℃
にて7時間攪拌した。反応溶液を室温まで戻し吸引ろ過を行い、得られた固形物をトルエ
ン、水およびジエチルエーテルにて洗浄した後、真空乾燥 (1 mm Hg) を12時間行った
ところ、一般式(3)で表される黄褐色の帯電防止剤Aを得た。
一般式(2)
一般式(3)
(Manufacture of antistatic agents)
In a glass container with an internal volume of 30 ml, polystyrene having an N, N-dioctylaminomethyl group represented by the following general formula (2) (Argonaut Technologies, 8000257, PS-Cl with dioctylamine under basic conditions) Compound made by acting amine loading 1.56 mmol
/ g) Suspend 0.70 g in toluene (6 ml) and slowly add dimethyl sulfate (at room temperature).
10.6 mmol, 1.34 g) was added dropwise. Thereafter, the temperature was raised to 140 ° C. and stirred for 9 hours. After the reaction solution was lowered to 90 ° C., 2 ml of water was added to treat excess dimethyl sulfate, and 90 ° C.
For 7 hours. The reaction solution was returned to room temperature and suction filtered, and the resulting solid was washed with toluene, water, and diethyl ether, and then vacuum-dried (1 mm Hg) for 12 hours. A yellow-brown antistatic agent A was obtained.
General formula (2)
General formula (3)
[実施例1]
トルエン :10部
硬化ロジン樹脂(荒川化学工業(株)製) :15部(固形分)
C.I. ピグメントイエロー12 :6部
上記配合物を顔料分散機(ペイントシェーカー)で2時間分散した。この分散物に
トルエン :52.5部
マレイン化石油樹脂(日石ネオポリマー160ワニス(新日本石油(株)製))
:6部(固形分)
炭酸カルシウム(タンカルPC(白石工業(株)製):10部
帯電防止剤B(エレガン264−WAX(日本油脂株式会社))
:0.5部(固形分)
(帯電防止剤Bは一般式(1)に相当)
上記配合物を添加し黄色の印刷インキ組成物を得た。
次いで、この印刷インキ組成物を、粘度調整溶剤としてトルエンを用い、離合社製のザ
ーンカップNo.3で12秒になるように粘度を調整して希釈したインキ組成物1を得た
。
[Example 1]
Toluene: 10 parts Cured rosin resin (Arakawa Chemical Industries, Ltd.): 15 parts (solid content)
CI Pigment Yellow 12: 6 copies
The above formulation was dispersed for 2 hours with a pigment disperser (paint shaker). Toluene: 52.5 parts maleated petroleum resin (Nisseki Neopolymer 160 Varnish (manufactured by Nippon Oil Corporation))
: 6 parts (solid content)
Calcium carbonate (Tancal PC (manufactured by Shiroishi Kogyo Co., Ltd.): 10 parts Antistatic agent B (Elegan 264-WAX (Nippon Yushi Co., Ltd.)
: 0.5 part (solid content)
(Antistatic agent B corresponds to general formula (1))
The above blend was added to obtain a yellow printing ink composition.
Subsequently, this printing ink composition was used with Zahn Cup No. The ink composition 1 was obtained by adjusting the viscosity so that the viscosity of the ink composition 1 was 12 seconds.
[実施例2〜9および比較例1〜11]
実施例2〜9、比較例1〜11については、表1に示す配合により、実施例1と同様な
方法でインキ組成物2〜20を得た。実施例2〜9、比較例1〜11に用いた樹脂、帯電
防止剤、シリカは下記の通りである。
ロジン変性フェノール樹脂:ハリフェノールP‐292(ハリマ化成(株)社製)
帯電防止剤A:一般式(3)の化合物
帯電防止剤C:ニッサンカチオン2‐OLR(日本油脂株式会社)
(化学名)ジオレイルジメチル‐アンモニウムクロライド
帯電防止剤D:ニッサンカチオンEQ‐01D(日本油脂株式会社)
(化学名)N,N‐ジアシルオキシエチル‐N‐メチルアンモニウム‐メチルサル
フェート
シリカA(富士シリシア化学(株)社製 サイロホービック200)
シリカB(富士シリシア化学(株)社製 サイロホービック100)
シリカC(富士シリシア化学(株)社製 サイロホービック4004)
シリカD(富士シリシア化学(株)社製 サイリシア350)
なお、シリカA,B,Cは有機ケイ素化合物で表面処理した疎水性シリカであり、シリカDは未処理の親水性シリカである。
[Examples 2 to 9 and Comparative Examples 1 to 11]
For Examples 2 to 9 and Comparative Examples 1 to 11, ink compositions 2 to 20 were obtained in the same manner as in Example 1 by the formulation shown in Table 1. Resins, antistatic agents, and silica used in Examples 2 to 9 and Comparative Examples 1 to 11 are as follows.
Rosin modified phenolic resin: Hariphenol P-292 (manufactured by Harima Chemicals Co., Ltd.)
Antistatic agent A: Compound of general formula (3) Antistatic agent C: Nissan Cation 2-OLR (Nippon Yushi Co., Ltd.)
(Chemical name) Dioleyldimethyl-ammonium chloride Antistatic agent D: Nissan cation EQ-01D (Nippon Yushi Co., Ltd.)
(Chemical name) N, N-diacyloxyethyl-N-methylammonium-methylsal
Fate Silica A (Silo Hovic 200 manufactured by Fuji Silysia Chemical Ltd.)
Silica B (Silo Hovic 100 manufactured by Fuji Silysia Chemical Ltd.)
Silica C (Silo Hovic 4004 manufactured by Fuji Silysia Chemical Ltd.)
Silica D (Silicia 350 manufactured by Fuji Silysia Chemical Ltd.)
Silicas A, B, and C are hydrophobic silicas surface-treated with an organosilicon compound, and silica D is untreated hydrophilic silica.
(評価)
実施例1〜9、比較例1〜11で得られたインキ組成物を、岩瀬印刷機械(株)のベビー
印刷機を用い、コンベンショナル20μベタ版(70線/cm)にてサイマーコート紙に印
刷し、印刷物を得た。この印刷物について、以下<ページめくり性><表面固有抵抗値>
<インキ安定性>の評価を行い、結果を表2に示した。以下に評価方法と評価基準を示す
。
(Evaluation)
The ink compositions obtained in Examples 1 to 9 and Comparative Examples 1 to 11 were printed on a simer-coated paper with a conventional 20 μ solid plate (70 lines / cm) using a baby printing machine of Iwase Printing Machinery Co., Ltd. A printed matter was obtained. About this printed matter, the following <page turning property><surfaceresistivity>
<Ink stability> was evaluated and the results are shown in Table 2. The evaluation method and evaluation criteria are shown below.
<ページめくり性>
印刷直後、印刷面と印刷面とを接触させて重ね合わせた後、1Nの加重をかけ、25℃
、24時間放置し、手でめくる際のバリバリ音の大きさを評価した。
◎ ・・・「バリバリ音なし」
○ ・・・「バリバリ音ほとんどなし」
○△・・・「バリバリ音僅かにあり」
△ ・・・「バリバリ音あり」
× ・・・「バリバリ音顕著にあり」
実用レベルは○△以上である。
<Page turning ability>
Immediately after printing, the printed surface and the printed surface are brought into contact with each other, and then a weight of 1N is applied, and 25 ° C.
, Left for 24 hours, and evaluated the level of crisp sound when turning by hand.
◎ ・ ・ ・ “No sound”
○ ・ ・ ・ “There is almost no crisp sound”
○ △ “Slightly crisp”
△ ・ ・ ・ "There is a crisp sound"
× ・ ・ ・ "There is a remarkable buzzing sound"
The practical level is more than ○ △.
<表面固有抵抗値>
25℃、50%RHの環境下で、ヒューレトパッカード社製 HIGH RESISTANCE METER43
29Aにて印刷面の表面固有抵抗値を測定した。(Ω/□)
<Surface specific resistance value>
HIGH RESISTANCE METER43 made by Hewlett-Packard Company in an environment of 25 ° C and 50% RH
The surface resistivity of the printed surface was measured at 29A. (Ω / □)
<インキ安定性>
仕上がり時インキの粘度と40℃‐30日間保管後の粘度を測定し、増粘の程度を評価
した。
粘度は離合社製のザーンカップNo.3で測定した。
また仕上がり時インキと40℃‐30日間保管後のインキの沈殿物の有無を評価した。
○ ・・・「粘度増加10秒未満および沈殿物なし」
○△・・・「粘度増加10秒以上15秒未満および沈殿物ほとんどなし」
△ ・・・「粘度増加20秒未満および/または沈殿物が僅かにみられる」
× ・・・「粘度増加20秒以上および/または沈殿物が顕著にみられる」
実用レベルは○△以上である。
<Ink stability>
The viscosity of the finished ink and the viscosity after storage at 40 ° C. for 30 days were measured to evaluate the degree of thickening.
The viscosity is Zahn Cup No. 3 was measured.
In addition, the presence or absence of a precipitate of ink at the time of finishing and ink after storage at 40 ° C. for 30 days was evaluated.
○ “Viscosity increase less than 10 seconds and no precipitate”
○ △ ・ ・ ・ “Increase in viscosity from 10 seconds to less than 15 seconds and almost no precipitate”
△ "Viscosity increase is less than 20 seconds and / or precipitate is slightly seen"
X ... "viscosity increased for 20 seconds or more and / or precipitates are noticeable"
The practical level is more than ○ △.
表2に示すように、化学式(1)のような4級アンモニウム塩型帯電防止剤を0.5〜
3.5重量%含むインキ組成物は、インキ安定性を維持しながら、高いページめくり性お
よび良好な表面固有抵抗値を示すことがわかった。更に、疎水性シリカ1〜5重量%を添
加することでより良好なページめくり性を示すことがわかった。
As shown in Table 2, the quaternary ammonium salt type antistatic agent represented by the chemical formula (1) is 0.5 to
The ink composition containing 3.5% by weight was found to exhibit high page turnability and good surface resistivity while maintaining ink stability. Furthermore, it turned out that the better page turning property is shown by adding 1 to 5 weight% of hydrophobic silica.
Claims (2)
溶剤
および
一般式(1)に示される第四級アンモニウム塩型帯電防止剤を、インキ全量中、固形
分重量比0.5〜3.5重量%
含有することを特徴とする出版グラビア印刷用インキ組成物。
(式中Rは、炭素数が8〜22のアルキル基である)
The cured rosin is in a total weight of the ink, and a solid content weight ratio of 15 to 35% by weight,
Solvent and the quaternary ammonium salt type antistatic agent represented by the general formula (1) in the total amount of the ink in a solid content weight ratio of 0.5 to 3.5% by weight
An ink composition for publishing gravure printing, comprising:
(Wherein R is an alkyl group having 8 to 22 carbon atoms)
量比1〜5重量%含有することを特徴とする請求項1記載の出版グラビア印刷用インキ組
成物。 2. The ink composition for publishing gravure printing according to claim 1, further comprising 1 to 5% by weight of a solid content weight ratio of hydrophobic silica surface-treated with an organosilicon compound.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013163874A (en) * | 2012-02-10 | 2013-08-22 | Toyo Ink Sc Holdings Co Ltd | Gravure printing paper for publishing and printed material |
CN103599729A (en) * | 2013-11-13 | 2014-02-26 | 中国林业科学研究院林产化学工业研究所 | Rosinyl quaternary ammonium salt dimeric surfactant as well as preparation method and application thereof |
JP2015140390A (en) * | 2014-01-28 | 2015-08-03 | 東洋インキScホールディングス株式会社 | Printed matter |
JP2016108440A (en) * | 2014-12-05 | 2016-06-20 | 林 聖二 | Antistatic gravure white ink for reverse printing and substrate plastic film for dry laminate reverse-printed with use of the white ink |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0812898A (en) * | 1994-06-30 | 1996-01-16 | Tokai Carbon Co Ltd | Granular carbon black having low adhesiveness |
JP2001240787A (en) * | 2000-02-29 | 2001-09-04 | The Inctec Inc | Ink composition |
JP2005220275A (en) * | 2004-02-09 | 2005-08-18 | Kanji Hayashi | Antistatic printing ink for plastic film and plastic film print printed by using the ink |
-
2010
- 2010-06-25 JP JP2010145015A patent/JP5609313B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0812898A (en) * | 1994-06-30 | 1996-01-16 | Tokai Carbon Co Ltd | Granular carbon black having low adhesiveness |
JP2001240787A (en) * | 2000-02-29 | 2001-09-04 | The Inctec Inc | Ink composition |
JP2005220275A (en) * | 2004-02-09 | 2005-08-18 | Kanji Hayashi | Antistatic printing ink for plastic film and plastic film print printed by using the ink |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013163874A (en) * | 2012-02-10 | 2013-08-22 | Toyo Ink Sc Holdings Co Ltd | Gravure printing paper for publishing and printed material |
CN103599729A (en) * | 2013-11-13 | 2014-02-26 | 中国林业科学研究院林产化学工业研究所 | Rosinyl quaternary ammonium salt dimeric surfactant as well as preparation method and application thereof |
JP2015140390A (en) * | 2014-01-28 | 2015-08-03 | 東洋インキScホールディングス株式会社 | Printed matter |
JP2016108440A (en) * | 2014-12-05 | 2016-06-20 | 林 聖二 | Antistatic gravure white ink for reverse printing and substrate plastic film for dry laminate reverse-printed with use of the white ink |
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JP5609313B2 (en) | 2014-10-22 |
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