JP2011527632A5 - - Google Patents

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JP2011527632A5
JP2011527632A5 JP2011517629A JP2011517629A JP2011527632A5 JP 2011527632 A5 JP2011527632 A5 JP 2011527632A5 JP 2011517629 A JP2011517629 A JP 2011517629A JP 2011517629 A JP2011517629 A JP 2011517629A JP 2011527632 A5 JP2011527632 A5 JP 2011527632A5
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membrane
polydopamine
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vinyl
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膜上にドーパミンを堆積させてポリドーパミン被覆膜を形成するステップ
を含み、前記ポリドーパミン被覆膜が、非改質膜よりも高い水フラックス及び増加した膜表面親水性を有する、膜汚染を減少させる方法。
Depositing dopamine on the membrane to form a polydopamine coating, wherein the polydopamine coating has a higher water flux and increased membrane surface hydrophilicity than the unmodified membrane, How to reduce.
ポリドーパミン被覆膜の純水フラックスが、非改質膜のフラックスの0〜99%を含む、請求項1に記載の方法。   The method according to claim 1, wherein the pure water flux of the polydopamine-coated membrane comprises 0 to 99% of the flux of the unmodified membrane. ポリドーパミン被覆膜の純水フラックスが、非改質膜のフラックスの80〜90%を含む、請求項1に記載の方法。 The method according to claim 1, wherein the pure water flux of the polydopamine-coated membrane comprises 80-90% of the flux of the unmodified membrane. ドーパミンが、ハロゲン、ヒドロキシル基、低級アルキル基、低級アルコキシ基、単環式アリール、低級アシル基及びこれらの組合せの付加から選択される1又は2以上の置換を含む、請求項1〜3のいずれかに記載の方法。 Dopamine, halogen, hydroxyl group, a lower alkyl group, a lower alkoxy group, a monocyclic aryl, including substitution of one or more selected from the addition of lower acyl groups and combinations thereof, any of claim 1-3 the method according to any. 膜が、RO膜、UF膜、NF膜又はこれらの組合せを含む、請求項1〜4のいずれかに記載の方法。 The method according to claim 1, wherein the membrane comprises an RO membrane, a UF membrane, an NF membrane, or a combination thereof. ポリドーパミン被覆膜が、以下のポリメチルメタクリレート、ポリスチレン、ポリカーボネート、ポリイミド、エポキシ樹脂、環式オレフィンコポリマー、環式オレフィンポリマー、アクリレートポリマー、ポリエチレンテレフタレート、ポリフェニレンビニレン、ポリエーテルエーテルケトン、ポリ(N−ビニルカルバゾール)、アクリロニトリル−スチレンコポリマー、又はポリエーテルイミドポリ(フェニレンビニレン)のうちの1又は2以上を含む、請求項1〜5のいずれかに記載の方法。 The polydopamine coating film has the following polymethyl methacrylate, polystyrene, polycarbonate, polyimide, epoxy resin, cyclic olefin copolymer, cyclic olefin polymer, acrylate polymer, polyethylene terephthalate, polyphenylene vinylene, polyether ether ketone, poly (N- vinylcarbazole), acrylonitrile - styrene copolymer, or a polyether containing one or more of the imide poly (phenylene vinylene), the method of any of claims 1-5. ドーパミンが、ROOH、ROSH、RSSH、OH、SO3H、SO3R、SO4R、COOH、NH2、NHR、NR2、CONH2、及びNH−−NH2(式中、Rは、飽和又は不飽和の少なくとも1個の炭素系環を形成することができる、直鎖状又は分岐状炭化水素系鎖;アルキレン、シロキサン、シラン、エーテル、ポリエーテル、チオエーテル、シリレン、及びシラザンを示す)から選択される1又は2以上の官能基を含む、請求項1〜6のいずれかに記載の方法。 Dopamine is ROOH, ROSH, RSSH, OH, SO3H, SO3R, SO4R, COOH, NH2, NHR, NR2, CONH2, and NH--NH2 (wherein R is a saturated or unsaturated at least one carbon system) 1 or 2 or more functional groups selected from linear or branched hydrocarbon-based chains capable of forming a ring; representing alkylene, siloxane, silane, ether, polyether, thioether, silylene, and silazane) The method in any one of Claims 1-6 containing these . ポリドーパミン被覆膜が、1又は2以上のポリスルホン、スチレンとアクリロニトリルポリ(アリーレンオキシド)とのコポリマー、ポリカーボネート、酢酸セルロース、ポリスルホン;ポリ(スチレン)、スチレン含有コポリマー、アクリロニトリルスチレンコポリマー、スチレン−ブタジエンコポリマー、スチレン−ビニルベンジルハライドコポリマー;ポリカーボネート;セルロースポリマー、酢酸セルロース−ブチレート、プロピオン酸セルロース、エチルセルロース、メチルセルロース、ニトロセルロース、ポリアミド、ポリイミド、アリールポリアミド、アリールポリイミド、ポリエーテル、ポリ(アリーレンオキシド)、ポリ(フェニレンオキシド)、ポリ(キシレンオキシド);ポリ(エステルアミド−ジイソシアネート)、ポリウレタン、ポリエステル(ポリアリーレートを含む)、ポリ(エチレンテレフタレート)、ポリ(アルキルメタクリレート)、ポリ(アクリレート)、ポリ(フェニレンテレフタレート)、ポリスルフィド、ポリ(エチレン)、ポリ(プロピレン)、ポリ(ブテン−1)、ポリ(4−メチルペンテン−1)、ポリビニル、ポリ(塩化ビニル)、ポリ(フッ化ビニル)、ポリ(塩化ビニリデン)、ポリ(フッ化ビニリデン)、ポリ(ビニルアルコール)、ポリ(ビニルエステル)、ポリ(酢酸ビニル)、ポリ(プロピオン酸ビニル)、ポリ(ビニルピリジン)、ポリ(ビニルピロリドン)、ポリ(ビニルエーテル)、ポリ(ビニルケトン)、ポリ(ビニルアルデヒド)、ポリ(ビニルホルマール)、ポリ(ビニルブチラール)、ポリ(ビニルアミド)、ポリ(ビニルアミン)、ポリ(ビニルウレタン)、ポリ(ビニル尿素)、ポリ(ビニルホスフェート)、ポリ(ビニルサルフェート)、ポリアリル;ポリ(ベンゾベンズイミダゾール)、ポリヒドラジド、ポリオキサジアゾール、ポリトリアゾール、ポリ(ベンズイミダゾール)、ポリカルボジイミド、ポリホスファジン及びこれらの組合せを含む、請求項1〜7のいずれかに記載の方法。 Polydopamine-coated membrane comprises one or more polysulfones, copolymers of styrene and acrylonitrile poly (arylene oxide), polycarbonate, cellulose acetate, polysulfone; poly (styrene), styrene-containing copolymers, acrylonitrile styrene copolymers, styrene-butadiene copolymers , Styrene-vinyl benzyl halide copolymer; polycarbonate; cellulose polymer, cellulose acetate-butyrate, cellulose propionate, ethyl cellulose, methyl cellulose, nitrocellulose, polyamide, polyimide, aryl polyamide, aryl polyimide, polyether, poly (arylene oxide), poly ( Phenylene oxide), poly (xylene oxide); poly (ester amide-diisocyanate) Polyurethane, polyester (including polyarylate), poly (ethylene terephthalate), poly (alkyl methacrylate), poly (acrylate), poly (phenylene terephthalate), polysulfide, poly (ethylene), poly (propylene), poly (butene- 1), poly (4-methylpentene-1), polyvinyl, poly (vinyl chloride), poly (vinyl fluoride), poly (vinylidene chloride), poly (vinylidene fluoride), poly (vinyl alcohol), poly (vinyl) Ester), poly (vinyl acetate), poly (vinyl propionate), poly (vinyl pyridine), poly (vinyl pyrrolidone), poly (vinyl ether), poly (vinyl ketone), poly (vinyl aldehyde), poly (vinyl formal), Poly (vinyl butyral), poly (bi Luamide), poly (vinylamine), poly (vinylurethane), poly (vinylurea), poly (vinylphosphate), poly (vinylsulfate), polyallyl; poly (benzobenzimidazole), polyhydrazide, polyoxadiazole, poly The method according to any one of claims 1 to 7, comprising triazole, poly (benzimidazole), polycarbodiimide, polyphosphazine and combinations thereof. ポリドーパミン被覆膜に1又は2以上の第2のコーティングを施すステップをさらに含む、請求項1〜8のいずれかに記載の方法。 The method according to any one of claims 1 to 8 , further comprising applying one or more second coatings to the polydopamine-coated membrane. ポリドーパミン被覆膜に1又は2以上の親水性コーティングを施すステップをさらに含む、請求項1〜9のいずれかに記載の方法。 The method according to any one of claims 1 to 9 , further comprising applying one or more hydrophilic coatings to the polydopamine-coated membrane. 浄化膜と、
前記浄化膜上に堆積されてポリドーパミン被覆膜を形成するポリドーパミン層であって、前記ポリドーパミン層が前記浄化膜の親水性を増加させ、前記ポリドーパミン被覆膜が高い水フラックスを有する、ポリドーパミン層と、
分離された液体を収容するために前記ポリドーパミン被覆膜の異なる面に位置付けられた、1又は2以上の容器と
を備える液体分離装置。
A purification membrane;
A polydopamine layer deposited on the purification film to form a polydopamine coating film, wherein the polydopamine layer increases the hydrophilicity of the purification film, and the polydopamine coating film has a high water flux A polydopamine layer,
A liquid separation device comprising one or more containers positioned on different surfaces of the polydopamine-coated membrane to contain the separated liquid.
疎水性浄化膜と、
前記疎水性浄化膜と接触して、非改質疎水性膜よりも高い水フラックス及び高い親水性を有するポリドーパミン被覆疎水性浄化膜を形成する、ポリドーパミン層と、
前記ポリドーパミン層と接触して、複数層の疎水性−ポリドーパミン−親水性浄化膜を形成する、親水性コーティングと
を備える浄化膜。
A hydrophobic purification membrane;
A polydopamine layer in contact with the hydrophobic purification film to form a polydopamine-coated hydrophobic purification film having a higher water flux and higher hydrophilicity than an unmodified hydrophobic film;
A purification membrane comprising a hydrophilic coating that is in contact with the polydopamine layer to form a plurality of hydrophobic-polydopamine-hydrophilic purification membranes.
ポリマーマトリックス浄化膜と、
浄化膜上に堆積されて、非改質膜よりも高い水フラックス及び高い親水性を有する芳香族ジヒドロキシ及びアミン被覆浄化膜を形成する、芳香族ジヒドロキシ及びアミン含有モノマーと
を備える浄化膜。
A polymer matrix purification membrane;
A purification film comprising aromatic dihydroxy and amine-containing monomers deposited on the purification film to form an aromatic dihydroxy and amine-coated purification film having a higher water flux and higher hydrophilicity than an unmodified film.
ポリマーマトリックス浄化膜と、
前記浄化膜上に堆積されて、非改質膜よりも高い水フラックス及び高い親水性を有するポリドーパミン被覆浄化膜を形成する、ポリドーパミン層と
を備える浄化膜。
A polymer matrix purification membrane;
A purification film comprising a polydopamine layer deposited on the purification film to form a polydopamine-coated purification film having a higher water flux and higher hydrophilicity than an unmodified film.
従来型浄化膜の改質のためのポリドーパミン被覆浄化膜システムであって、
供給タンク内に配置されたドーパミン溶液と、
前記供給タンクに接続され、前記ドーパミン溶液を移動させて高い膜間圧を提供する、ポンプと、
前記ポンプを膜に接続して前記ドーパミン溶液を前記膜上に堆積させるための、膜入口接続部と、
前記膜を前記供給タンクに接続して前記ドーパミン溶液を前記供給タンクに戻すための、膜出口接続部と
を備える、ポリドーパミン被覆浄化膜システム。
A polydopamine-coated purification membrane system for modifying a conventional purification membrane,
A dopamine solution located in the supply tank;
A pump connected to the supply tank to move the dopamine solution to provide a high transmembrane pressure;
A membrane inlet connection for connecting the pump to the membrane and depositing the dopamine solution on the membrane;
A polydopamine-coated purification membrane system comprising a membrane outlet connection for connecting the membrane to the supply tank and returning the dopamine solution to the supply tank.
JP2011517629A 2008-07-10 2009-07-09 Water purification membrane with improved contamination resistance Active JP5463355B2 (en)

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US7960808P 2008-07-10 2008-07-10
US61/079,608 2008-07-10
PCT/US2009/050150 WO2010006196A2 (en) 2008-07-10 2009-07-09 Water purification membranes with improved fouling resistance

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JP2011527632A5 true JP2011527632A5 (en) 2012-07-05
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CN (1) CN102149450A (en)
AU (1) AU2009268532B2 (en)
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